KR20170120503A - 금속 붕소화물들의 퇴적 - Google Patents
금속 붕소화물들의 퇴적 Download PDFInfo
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- KR20170120503A KR20170120503A KR1020170049172A KR20170049172A KR20170120503A KR 20170120503 A KR20170120503 A KR 20170120503A KR 1020170049172 A KR1020170049172 A KR 1020170049172A KR 20170049172 A KR20170049172 A KR 20170049172A KR 20170120503 A KR20170120503 A KR 20170120503A
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- precursor
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- decaborane
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- 229910052751 metal Inorganic materials 0.000 title claims abstract description 70
- 239000002184 metal Substances 0.000 title claims abstract description 70
- 230000008021 deposition Effects 0.000 title claims description 17
- 239000002243 precursor Substances 0.000 claims abstract description 66
- 238000000034 method Methods 0.000 claims abstract description 44
- 239000000758 substrate Substances 0.000 claims abstract description 42
- 238000006243 chemical reaction Methods 0.000 claims abstract description 36
- 229910001507 metal halide Inorganic materials 0.000 claims abstract description 27
- 150000005309 metal halides Chemical class 0.000 claims abstract description 26
- 238000010926 purge Methods 0.000 claims description 35
- 239000007789 gas Substances 0.000 claims description 13
- VDZMENNHPJNJPP-UHFFFAOYSA-N boranylidyneniobium Chemical compound [Nb]#B VDZMENNHPJNJPP-UHFFFAOYSA-N 0.000 claims description 12
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 10
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 10
- 229910052796 boron Inorganic materials 0.000 claims description 8
- AOLPZAHRYHXPLR-UHFFFAOYSA-I pentafluoroniobium Chemical compound F[Nb](F)(F)(F)F AOLPZAHRYHXPLR-UHFFFAOYSA-I 0.000 claims description 8
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 229910052719 titanium Inorganic materials 0.000 claims description 7
- 239000010936 titanium Substances 0.000 claims description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 5
- 229910052786 argon Inorganic materials 0.000 claims description 5
- 239000001307 helium Substances 0.000 claims description 5
- 229910052734 helium Inorganic materials 0.000 claims description 5
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims description 5
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 5
- 229910019800 NbF 5 Inorganic materials 0.000 claims description 4
- XTDAIYZKROTZLD-UHFFFAOYSA-N boranylidynetantalum Chemical compound [Ta]#B XTDAIYZKROTZLD-UHFFFAOYSA-N 0.000 claims description 4
- YHBDIEWMOMLKOO-UHFFFAOYSA-I pentachloroniobium Chemical compound Cl[Nb](Cl)(Cl)(Cl)Cl YHBDIEWMOMLKOO-UHFFFAOYSA-I 0.000 claims description 4
- 229910004529 TaF 5 Inorganic materials 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- YRGLXIVYESZPLQ-UHFFFAOYSA-I tantalum pentafluoride Chemical compound F[Ta](F)(F)(F)F YRGLXIVYESZPLQ-UHFFFAOYSA-I 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 150000004820 halides Chemical class 0.000 claims description 2
- 150000002431 hydrogen Chemical class 0.000 claims 3
- 238000000151 deposition Methods 0.000 abstract description 13
- 239000010408 film Substances 0.000 description 28
- 238000000231 atomic layer deposition Methods 0.000 description 11
- 230000008569 process Effects 0.000 description 11
- 230000015572 biosynthetic process Effects 0.000 description 10
- 239000011261 inert gas Substances 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 6
- 239000010410 layer Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 238000005229 chemical vapour deposition Methods 0.000 description 5
- 239000002356 single layer Substances 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical compound B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 description 3
- 150000001639 boron compounds Chemical group 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000005240 physical vapour deposition Methods 0.000 description 3
- 229910052814 silicon oxide Inorganic materials 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- -1 transition metal nitrides Chemical class 0.000 description 3
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 229910000577 Silicon-germanium Inorganic materials 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 229910000085 borane Inorganic materials 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000059 patterning Methods 0.000 description 2
- 229910021332 silicide Inorganic materials 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- JBRZTFJDHDCESZ-UHFFFAOYSA-N AsGa Chemical compound [As]#[Ga] JBRZTFJDHDCESZ-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000579895 Chlorostilbon Species 0.000 description 1
- GPXJNWSHGFTCBW-UHFFFAOYSA-N Indium phosphide Chemical compound [In]#P GPXJNWSHGFTCBW-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 1
- LEVVHYCKPQWKOP-UHFFFAOYSA-N [Si].[Ge] Chemical compound [Si].[Ge] LEVVHYCKPQWKOP-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- ZOCHARZZJNPSEU-UHFFFAOYSA-N diboron Chemical compound B#B ZOCHARZZJNPSEU-UHFFFAOYSA-N 0.000 description 1
- 229910052876 emerald Inorganic materials 0.000 description 1
- 239000010976 emerald Substances 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- CJNBYAVZURUTKZ-UHFFFAOYSA-N hafnium(iv) oxide Chemical compound O=[Hf]=O CJNBYAVZURUTKZ-UHFFFAOYSA-N 0.000 description 1
- 238000005658 halogenation reaction Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000004377 microelectronic Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- XROWMBWRMNHXMF-UHFFFAOYSA-J titanium tetrafluoride Chemical compound [F-].[F-].[F-].[F-].[Ti+4] XROWMBWRMNHXMF-UHFFFAOYSA-J 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 229910021561 transition metal fluoride Inorganic materials 0.000 description 1
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 description 1
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- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/455—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
- C23C16/45523—Pulsed gas flow or change of composition over time
- C23C16/45525—Atomic layer deposition [ALD]
- C23C16/45553—Atomic layer deposition [ALD] characterized by the use of precursors specially adapted for ALD
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
- C23C16/38—Borides
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- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/4401—Means for minimising impurities, e.g. dust, moisture or residual gas, in the reaction chamber
- C23C16/4408—Means for minimising impurities, e.g. dust, moisture or residual gas, in the reaction chamber by purging residual gases from the reaction chamber or gas lines
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- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
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- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
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- C23C16/455—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
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- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
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- C23C16/45523—Pulsed gas flow or change of composition over time
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- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
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- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
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- H01L21/28017—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon
- H01L21/28158—Making the insulator
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Abstract
기판 상에 금속 막을 퇴적하기 위한 방법이 개시된다. 특히, 상기 방법은 상기 기판 상으로 금속 할로겐화물 전구체를 펄스하는 단계와, 상기 기판 상으로 데카보레인 전구체를 펄스하는 단계를 포함한다. 상기 금속 할로겐화물 전구체와 상기 데카보레인 전구체 사이의 반응은 금속 막, 구체적으로는 금속 붕소화물을 형성한다.
Description
[1] 본 출원은 "DEPOSITION OF METAL BORIDES"라는 명칭으로 출원된 미국 정규 특허 출원 제15/135,224호와, "DEPOSITION OF METAL BORIDES AND SILICIDES"라는 명칭으로 출원된 미국 정규 출원 제15/135,258호와 관련되며, 이들 개시들의 전문이 여기 참조문헌으로서 병합된다.
[2] 본 개시는 개괄적으로 전자 소자들의 제조를 위한 공정들에 관한 것이다. 좀 더 상세하게는, 본 개시는 원자층 퇴적(ALD)을 통한 금속 게이트들의 형성에 관한 것이다. 구체적으로, 본 개시는 데카보레인(decaborane)을 이용하여 금속 붕소화물들을 형성하는 것에 관한 것이다.
[3] 금속 붕소화물 막들은 다양한 화학적 기상 퇴적(CVD) 방법들을 이용하여 형성되어왔다. CVD 방법들에서, 기체 소스 화학물질들은 동시에 반응 공간 내부로 도입되어, 기판 상에 금속 막의 퇴적을 야기한다. 상기 기체 소스 화학물질들 중 일부를 열적으로 활성화시키기 위해서는, 상기 CVD 방법들은 1200℃만큼 높은 온도에서 일어나는 경향이 있다. 서멀 버짓들(thermal budgets)에 대하여 이러한 높은 기판 온도들은 문제가 있을 수 있으며, 특히 금속화(metallization)와 같은 최신의 반도체 제조 공정들에서 문제가 있을 수 있다.
[4] 추가적으로, 물리적 기상 퇴적(PVD) 방법들이 금속 막들을 퇴적하기 위해 사용되어 왔다. PVD 방법들은 일반적으로 직진선(line-of-sight)을 따라 퇴적한다. 그러나, 직진선 퇴적은 복잡한 기판 윤곽들이 연관되는 특정한 영역들에서 불충분한 박막 커버리지를 야기한다. 또한, 직진선 퇴적은 저휘발성 전구체들이 만나는 최초의 고체 표면 상에 퇴적되는 것을 야기하며, 이는 저-컨포말리티 커버리지를 야기한다.
[5] 원자층 퇴적(ALD)은 금속 탄화물 막들을 형성하기 위해 사용되어 왔다. 예를 들어, Elers의 미국 특허 번호 제 7,611,751호는 금속 소스 화학물질, 환원제, 및 탄소 소스 화학물질의 공간적 및 시간적으로 분리된 기상 펄스들을 통하여 금속 탄화물 막을 형성하는 방법들을 개시한다. 유사하게, Chen et al.의 미국 특허 번호 제 8,841,182호는 ALD 공정을 통한 티타늄 탄화물 막들의 형성을 개시한다. 그러나, 데카보레인을 사용하여 낮은 온도들에서 금속 붕소화물을 퇴적하기 위한 어떤 알려진 ALD 해결책도 존재하지 않는다. 그 결과, 낮은 온도들에서 금속 붕소화물들을 형성하기 위하여 ALD를 사용하는 방법이 요구된다.
본 발명의 목적은 전술한 문제들을 극복하기 위한 것이다.
[6] 본 발명의 적어도 하나의 실시예에 따르면, 금속 붕소화물을 형성하기 위한 방법이 제공된다. 상기 방법은, 반응 챔버 내에 공정을 위한 기판을 제공하는 단계; 상기 기판 상으로 금속 전구체 퇴적을 수행하는 단계로서: 상기 기판 상으로 금속 전구체를 펄스하는 단계; 및 상기 반응 챔버로부터 여분의 상기 금속 전구체를 퍼지하는 단계;를 포함하는, 상기 금속 전구체 퇴적을 수행하는 단계; 및 상기 기판 상으로 데카보레인 전구체 퇴적을 수행하는 단계로서: 상기 기판 상으로 데카보레인 전구체를 펄스하는 단계; 및 상기 반응 챔버로부터 여분의 상기 데카보레인 전구체를 퍼지하는 단계;를 포함하는, 상기 데카보레인 전구체 퇴적을 수행하는 단계;를 포함하고, 상기 금속 전구체는 티타늄 테트라클로라이드(TiCl4), 니오븀 펜타클로라이드(NbCl5), 탄탈륨 펜타플루오라이드(TaF5), 및 니오븀 펜타플루오라이드(NbF5) 중 적어도 하나를 포함하고; 상기 금속 할로겐화물 전구체 및 상기 데카보레인 전구체 사이의 반응은 붕소화 티타늄(TiB), 붕소화 탄탈륨(TaB), 또는 붕소화 니오븀(NbB) 중 적어도 하나를 포함하는 막을 형성하고; 상기 금속 전구체 퇴적 단계는 정해진 횟수 동안 반복되고, 상기 데카보레인 전구체 퇴적 단계는 정해진 횟수 동안 반복된다.
[7] 본 발명의 적어도 하나의 실시예에 따르면, 금속 붕소화물을 형성하기 위한 방법이 제공된다. 상기 방법은, 반응 챔버 내에 공정을 위한 기판을 제공하는 단계; 상기 기판을 금속 할로겐화물 전구체에 노출시키는 단계; 상기 기판을 금속 할로겐화물 전구체에 노출시키는 단계 후에, 상기 기판을 퍼지 기체에 노출시키는 단계; 상기 기판을 데카보레인 전구체에 노출시키는 단계; 상기 기판을 데카보레인 전구체에 노출시키는 단계 후에, 상기 기판을 퍼지 기체에 노출시키는 단계;를 포함하고, 상기 금속 할로겐화물 전구체에 노출시키는 단계는 정해진 횟수 동안 반복되고; 상기 데카보레인 전구체에 노출시키는 단계는 정해진 횟수 동안 반복된다.
[8] 본 발명 및 종래 기술에 대비하여 달성되는 이점들을 요약하기 위한 목적들로서, 본 발명의 특정한 목적들 및 이점들이 이상에서 설명되었다. 물론, 본 발명의 임의의 특정한 실시예에 따라 이러한 목적들 또는 이점들 모두가 필수적으로 달성될 필요는 없음이 이해되어야 할 것이다. 따라서, 예를 들어, 당업자들은 본 발명이 여기서 설명되거나 제시될 수 있는 다른 목적들이나 이점들을 필수적으로 달성하지 않고, 여기서 설명되거나 제시될 수 있는 어떤 하나의 이점 또는 일군의 이점들을 달성하거나 최적화하는 방식으로 구체화되거나 수행될 수 있다는 점을 인식할 것이다.
[9] 이러한 실시예들 모두는 여기 개시된 본 발명의 범위 내에 속할 것이 의도된다. 이러한 실시예들 및 다른 실시예들은 첨부된 도면들을 참조하는 하기의 특정 실시예들에 대한 상세한 설명으로부터 당업자들에게 쉽게 명백해질 것이며, 본 발명이 개시된 어느 특정 실시예(들)에 한정되는 것은 아니다.
[10] 여기 개시된 본 발명의 이러한 및 다른 특징들, 양상들 및 이점들은 특정한 실시예들의 도면들을 참조하여 아래에서 설명되나, 도면들은 본 발명을 도시하도록 의도된 것이며, 본 발명을 제한하도록 의도된 것은 아니다.
[11] 도 1은 본 발명의 적어도 하나의 실시예에 따른 방법의 순서도이다.
[12] 도 2는 본 발명의 적어도 하나의 실시예에 따른 단계의 순서도이다.
[13] 도 3은 본 발명의 적어도 하나의 실시예에 따른 단계의 순서도이다.
[11] 도 1은 본 발명의 적어도 하나의 실시예에 따른 방법의 순서도이다.
[12] 도 2는 본 발명의 적어도 하나의 실시예에 따른 단계의 순서도이다.
[13] 도 3은 본 발명의 적어도 하나의 실시예에 따른 단계의 순서도이다.
[14] 특정한 실시예들 및 실험예들이 아래에 개시되지만, 본 발명이 특정하게 개시된 본 발명의 실시예들 및/또는 용도들 및 이들의 자명한 변경들 및 균등물들을 넘어 확장된다는 것이 당업자에게 이해될 것이다. 따라서, 개시된 본 발명의 범위는 아래 설명되는 특정하게 개시된 실시예들에 의해 제한되어서는 안 된다는 것이 의도된다.
[15] 금속 붕소화물 막들은 이들의 특성들에 기인하여 무수히 많은 응용 분야들에서 가능성 있는 용도를 보여준다. 예를 들어, 이러한 금속 붕소화물 막들은 낮은 일함수 및 낮은 비저항을 갖고, 이는 이러한 막들을 n-금속 게이트 또는 게이트 매립 응용들에 이상적이도록 만든다. 또한, 금속 붕소화물들의 높은 화학 저항성은 이들이 패터닝 층들 및 하드 마스크들에서의 사용을 위하여 응용될 수 있도록 만든다. 더욱이, 금속 붕소화물 막들의 높은 일함수 및 낮은 비저항은 p-금속 스택, 게이트 매립, 및 MIMCAP 전극들(SoC)에서의 응용가능성을 제공한다.
[16] 금속 붕소화물들은 여러 응용분야들에서 사용될 수 있다. 예를 들어, 이들의 낮은 비저항에 기인하여, 금속 붕소화물들은 컨택들, 전극들, 또는 배리어들로서 역할을 할 수 있다. 금속 붕소화물들은 또한 약 3nm 두께에서 일함수가 4.9eV 를 초과하거나 약 5.0eV 내지 5.2eV 범위일 수 있는 PMOS 금속 게이트 응용들에 사용될 수 있다. 약 10nm 두께에서 약 100μΩcm 의 비저항이 얻어질 수 있다. 추가적으로, 금속 붕소화물들은 또한 약 3nm 두께에서 일함수가 4.3eV 보다 작거나 4.1eV 내지 4.2eV 범위일 수 있는 NMOS 금속 게이트 응용들에 사용될 수 있다. 약 10nm 두께에서 약 300μΩcm 보다 작은 비저항이 얻어질 수 있다. 금속 붕소화물들은 집적 회로들에서 전도성 층들로서 역할을 할 수 있으며, 그 비저항은 약 5000μΩcm 보다 작거나, 약 2000μΩcm 보다 작거나, 약 1000μΩcm 보다 작거나, 약 500μΩcm 보다 작거나, 또는 약 250μΩcm 보다 작을 수 있다.
[17] 데카보레인(B10Hx), 예를 들어 B10H14는 다이보레인(B2H6)의 붕소 원자들보다 많은 열 개의 붕소 원자들을 갖는 전구체이다. 따라서, 금속 붕소화물들을 형성하기 위한 전구체로 사용될 때, 데카보레인과 다이보레인 사이에는 속성들에 뚜렷한 차이점들이 있다. 예를 들어, 데카보레인은 상온에서 고체이므로, 다루기 더 편리하다. 반면에, 다이보레인은 상온에서 기체이다. 데카보레인이 고체라는 사실은 그것을 다루기 훨씬 용이하게 하며, 다이보레인에 비하여 줄어든 폭발의 위험이 있으므로 더 안전하게 만든다. 추가적으로, 조건들 및 체류 시간들에 따라, 데카보레인은 300℃, 350℃, 375℃, 또는 400℃를 초과하는 온도들에서 분해되기 시작할 수 있다. 이러한 요소는 반응 챔버의 온도를 설정하는 요인으로 포함할 수 있다.
[18] 도 1은 본 발명의 적어도 하나의 실시예에 따른 금속 게이트 퇴적 방법을 도시한다. 상기 방법은 금속 전구체 펄스/퍼지 단계(100) 및 데카보레인 펄스/퍼지 단계(200)를 포함한다. 상기 단계들은 원자층 퇴적 장치의 반응 챔버 내에서 일어난다. 이러한 장치는 ASM International N.V.로부터의 EmerALD® XP ALD 공정 모듈을 포함할 수 있다. 상기 반응 챔버 내에서, 처리될 기판이 놓여진다. 상기 기판은 실리콘 산화물(SiO2), 실리콘(Si), 실리콘 게르마늄(SiGe), 게르마늄(Ge), 갈륨 비소(GaAs), 또는 인화인듐(InP)으로 만들어질 수 있다. 상기 기판의 표면은 또한 질화 티타늄(TiN), 산화 티타늄(TiO2), 산화 하프늄(HfO2), 산화 실리콘(SiO2), 저유전율 산화 실리콘, 또는 산화 알루미늄(Al2O3) 막을 가질 수 있다. 상기 기판의 표면은 또한 질화물, 전이 금속 질화물들, 탄화물들, 규화물들, 또는 이들의 혼합들을 포함하는 다른 고유전율 막들 또는 도전성 막들을 포함할 수 있다.
[19] 상기 금속 전구체 펄스/퍼지 단계(100)는 경로(300)를 통해 이전 금속할로겐화물 펄스/퍼지 단계 이후 반복될 수 있다. 유사하게, 상기 데카보레인 펄스/퍼지 단계(200)는 경로(310)을 통해 이전의 데카보레인 화합물 펄스/퍼지 단계 이후에 반복 될 수 있다. 추가적으로, 상기 전체 공정이 경로(320)를 통해 반복될 수 있다. 이러한 방식은 요구되는 두께의 금속 붕소화물 막을 형성하기 위하여 바람직할 수 있다. 예를 들어, 상기 금속 전구체 펄스/퍼지 단계(100)의 50 사이클들 및 상기 데카보레인 화합물 펄스/퍼지 단계(200)의 50 사이클들은 200Å 두께의 금속 붕소화물 막의 형성을 야기할 수 있다.
[20] 예를 들어, 경미한 분해가 가능하도록 반응 온도가 선택된다면, 상기 붕소 화합물들의 일부 분해가 일어나는 것이 가능하다. 특정한 실시예들에서, 붕소 화합물의 일 모노레이어 이상이 표면에 흡착된다. 다른 실시예들에 있어, 붕소 화합물의 일 모노레이어 이상이 표면에 흡착되고, 이는 이후 금속 붕소화물을 형성하도록 상기 금속 할로겐화물과 더 반응된다. 일부 실시예들에서, 상기 금속 붕소화물 막은 ALD 타입의 공정으로 형성된다. 일부 실시예들에서, 상기 표면에 대한 붕소 반응은 데카보레인 분해로 인해 하나의 모노레이어로 자기-제한(self-limiting)되지 않을 수 있다. 일부 실시예들에서, 상기 순차적인 공정은 ALD 공정이 아니라, 대신 예를 들어 순차적 CVD 공정일 수 있다. 일부 실시예들에서, 하나 또는 그 이상의 퍼지 단계(들)은 생략될 수 있고, 불활성 기체를 사용하지 않는 배기 또는 제거 단계들로 대체될 수 있다. 일부 실시예들에서, 하나 또는 그 이상의 퍼지 단계(들)은 낮은 농도의 (데카)보레인 전구체를 불활성 기체와 함께 또는 불활성 기체 없이 흐르게 하는 것으로 대체될 수 있다. 일부 실시예들에서, 데카보레인 반응 또는 금속 할로겐화 반응은 층을 형성하지 않을 수 있다; 대신, 형성될 수 있는 것은 각각 붕소나 금속 할로겐화물을 포함하는 물질의 고립된 위치들 또는 가능하게는 분리되거나 부분적으로 연결된 물질의 섬들일 수 있다.
[21] 도 2는 상기 금속 전구체 펄스/퍼지 단계(100)를 도시한다. 상기 금속 전구체 펄스/퍼지 단계는 금속 전구체 펄스(110) 및 불활성 기체 퍼지(120)를 포함한다. 예를 들어, 티타늄 테트라클로라이드(TiCl4), 니오븀 펜타클로라이드(NbCl5), 니오븀 펜타플루오라이드(NbF5), 티타늄 테트라플루오라이드(TiF4), 티타늄 테트라클로라이드(TiCl4), 또는 탄탈륨 펜타플루오라이드(TaF5)와 같은 금속 할로겐화물들이 금속 전구체 펄스(110)에 사용될 수 있다. 금속 전구체 펄스(110) 에서의 다른 금속 할로겐화물들은 전이금속 불화물; Ⅳ-Ⅵ족 할로겐화물들; Ⅳ족 불화물들; 또는 탄탈륨(TaFx), 티타늄(TiFx), 또는 니오븀(NbFx)의 불화물들을 포함할 수 있다. 상기 금속 전구체 펄스(110) 동안, 금속 할로겐화물들은 샤워헤드 전구체 전달 시스템을 통하여 상기 반응 챔버 내로 도입될 수 있고, 기판 상에 입사될 수 있다. 금속 할로겐화물의 모노레이어 막을 형성하도록 상기 금속 할로겐화물은 상기 기판 상의 활성 사이트들과 상호작용할 수 있다.
[22] 최적의 막 형성을 얻기 위해서, 공정을 구동하기 위한 최적 설정들이 존재할 수 있다. 예를 들어, 상기 금속 할로겐화물은 상기 반응 챔버 내로 들어가기 전에 50 내지 120℃, 바람직하게는 90 내지 100℃, 또는 바람직하게는 50 내지 70℃ 범위의 온도로 유지될 수 있다. 상기 금속 할로겐화물 펄스(110) 동안 상기 반응 챔버 내의 온도는 350 내지 450℃, 바람직하게는 370 내지 400℃ 범위일 수 있으며, 이는 낮은 서멀 버짓을 제공하는 것과 같이 이로운 것으로 입증될 수 있다. 추가적으로, 상기 금속 할로겐화물 펄스(110) 동안 상기 반응 챔버 내의 압력은 0.1 내지 10 Torr 일 수 있다. 각각의 금속 할로겐화물 펄스(110)는 0.1 내지 5 초, 바람직하게는 0.5 내지 1 초가 걸릴 수 있다.
[23] 상기 불활성 기체 퍼지(120)는 상기 금속 전구체 펄스 단계(110) 동안상기 반응 챔버 내로 도입된 임의의 여분의 금속 할로겐화물 전구체를 제거하는 목적으로 역할한다. 상기 불활성 기체 퍼지(120) 동안 사용될 수 있는 불활성 기체들은 질소(N2), 아르곤(Ar), 헬륨(He), 수소(H2), 또는 다른 희유 기체들(rare gases)을 포함한다.
[24] 도 3은 본 발명의 적어도 하나의 실시예에 따른 상기 데카보레인 펄스/퍼지 단계(200)를 도시한다. 상기 데카보레인 펄스/퍼지 단계(200)는 데카보레인 펄스(210) 및 불활성 기체 퍼지(220)를 포함한다.
[25] 상기 데카보레인 펄스(210)는 데카보레인 화합물의 펄스를 수반한다. 상기 데카보레인 펄스(210)가 시작될 때, 상기 반응 챔버 내의 상기 기판은 데카보레인을 위한 활성 사이트들로 기능하는 금속 할로겐화물의 일 모노레이어를 가질 수 있다. 예를 들어, 데카보레인 펄스가 상기 반응 챔버로 도입될 때 상기 기판은 니오븀 펜타플루오라이드 한 층을 가질 수 있다. 어떠한 이론도 부인하지 않고, 순수한 붕소화 니오븀 막을 형성하기 위하여 데카보레인이 니오븀 펜타플루오라이드와 다음과 같은 식에 따라 반응하는 것으로 믿어진다.
NbF5 + B10H14 → NbB2 + HF + H2
[26] 상기 순수한 붕소화 니오븀 또는 순수한 붕소화 티타늄 막들의 형성은 예를 들어 적합한 상(phase)에서의 산화 저항성, 높은 화학 저항성, 높은 강성(stiffness) 및 낮은 비저항 속성들로 인해 유리하다. 이는 예를 들어 패터닝 층들, 하드 마스크들, BEOL(back-end-of-lines) 인터커넥트들, 게이트 배리어들, 컨택들, 전극, 또는 게이트 매립들에서 우수한 응용가능성을 갖는다. 이러한 막들은 또한 집적 회로들, MEMS, 마이크로일렉트로닉스(microelectronics), 또는 보호 코팅들에 사용될 수 있다.
[27] 금속 할로겐화물 펄스(110)와 유사하게, 최적의 막 형성을 얻기 위해서, 상기 데카보레인 펄스(210)를 작동하기 위한 최적 설정들이 존재할 수 있다. 예를 들어, 상기 데카보레인 화합물은 상기 반응 챔버 내로 들어가기 전에 65℃를 초과하지 않는 온도, 바람직하게는 55℃를 초과하지 않는 온도로 유지될 수 있다. 상기 데카보레인 펄스(210)동안 상기 반응 챔버 내의 온도는 300℃, 350℃, 375℃, 또는 400℃ 보다 높거나 또는 300 내지 500℃, 바람직하게는 350℃ 내지 450℃ 범위일 수 있고, 이는 낮은 서멀 버짓을 허용한다. 추가적으로, 데카보레인 펄스(210) 동안 상기 반응 챔버 내의 압력은 0.1 내지 10 Torr, 바람직하게는 0.5 내지 5 Torr 일 수 있다. 각각의 데카보레인 화합물 펄스(210)는 0.05 내지 20초, 바람직하게는 0.5 내지 10초가 걸릴 수 있다.
[28] 상기 불활성 기체 퍼지(220)는 상기 데카보레인 화합물 펄스 단계(210) 동안 상기 반응 챔버 내로 도입된 임의의 여분의 보레인 화합물 전구체를 제거하는 목적으로 역할한다. 상기 불활성 기체 퍼지(220) 동안 사용될 수 있는 불활성 기체들은 질소(N2), 아르곤(Ar), 헬륨(He), 수소(H2), 또는 다른 희유 기체들을 포함한다.
[29] 사이클의 결과로, 붕소화 티타늄 또는 붕소화 니오븀 막이 형성될 수 있다. 상기 막은 금속-붕소화물 결합을 포함할 수 있다. 반면에, 진정한 금속-붕소화물 결합 없이 막 내부에 트랩된 금속과 붕소를 포함할 수 있다. 결과적인 막은 예를 들어 MOS 응용에 사용될 수 있다. 상기 막은 다음과 같은 원자 농도들을 가지는 원소들을 포함할 수 있다: (1) 약 30 내지 약 80%, 바람직하게는 약 40 내지 약 80%, 더 바람직하게는 약 50 내지 약 70% 의 붕소; (2) 약 20 내지 70%, 바람직하게는 약 20 내지 약 60%, 더 바람직하게는 약 30 내지 약 50%의 금속; (3) 약 5% 보다 작거나, 바람직하게는 1% 보다 작은 산소; (4) 약 5% 보다 작거나, 바람직하게는 1% 보다 작은 수소; 및 (5) 약 5% 보다 작거나, 바람직하게는 1% 보다 작은 불소.
[30] 본 발명의 적어도 하나의 실시예에 따르면, 0.05 내지 8 Å/사이클(Å/cycle) 범위의 금속 붕소화물의 성장 속도를 얻을 수 있다. 예를 들어, 상기 성장 속도는 0.05 Å/사이클보다 크거나, 약 0.5 Å/사이클보다 크거나, 약 1.0 Å/사이클보다 크거나, 또는 약 1.5 Å/사이클보다 클 수 있다. 상기 성장 속도는 또한 약 8 Å/사이클보다 작거나, 약 6 Å/사이클보다 작거나, 약 5 Å/사이클보다 작거나, 또는 약 4 Å/사이클보다 작을 수 있다. 10 Å/사이클을 초과하는 성장 속도가 달성될 수 있으나, 극도로 높은 상기 반응 챔버의 온도를 요구할 것이다.
[31] 본 발명의 적어도 하나의 실시예에 따르면, 니오븀 펜타플루오라이드 및 데카보레인에 의한 붕소화 니오븀의 형성은 가변적인 성장 속도를 가질 수 있다. 특히, 상기 붕소화 니오븀의 성장 속도는 상기 데카보레인 및 상기 니오븀 펜타플루오라이드 둘 다의 펄스 지속 시간에 따라 달라질 수 있다. 데카보레인 투여(dosage) 기간이 더 길다면 상기 성장 속도는 증가될 수 있는 반면, 니오븀 펜타플루오라이드 투여 기간이 더 길다면 상기 성장 속도는 감소될 수 있다. 추가적으로, 상기 형성된 붕소화 니오븀 막은 막 내에 감지될 수 없는 양의 불소와 함께 주로 NbB2를 포함할 수 있다.
[32] 본 발명의 적어도 하나의 실시예에 따르면, 붕소화 니오븀의 형성은 니오븀 펜타클로라이드 및 데카보레인 펄스들을 이용하여 일어날 수 있다. 상기 형성된 붕소화 니오븀 막은 비정질(amorphous) 및 비-전도성(non-conductive)일 수 있다. 염화물들과 데카보레인 사이의 낮은 반응성은 더 낮은 성장 속도 또는 더 높은 붕소 함량을 야기할 수 있다.
[33] 본 발명의 적어도 하나의 실시예에 따르면, 붕소화 티타늄의 형성은 티타늄 테트라클로라이드 및 데카보레인 펄스들을 이용하여 일어날 수 있다.
[34] 상기 보여지고 설명된 특정한 실행예들은 본 발명 및 그 최적의 방식의 예증이 되며, 이와 달리 어떤 방식으로든 양상들 및 실시예들의 범위를 제한하도록 의도된 것은 아니다. 실제로, 간결성을 위하여, 상기 시스템의 관용적인 제조, 접속, 준비, 및 다른 기능적 측면들은 자세히 설명되지 않았을 수 있다. 더욱이, 다양한 도면들에 나타난 연결 선들은 다양한 요소들 사이의 예시적인 기능적 관계들 및/또는 물리적 연결을 대표하도록 의도된 것이다. 많은 대체적이거나 추가적인 기능적 관계 또는 물리적 연결들이 실제적인 시스템에서 존재할 수 있으며, 그리고/또는 몇몇 실시예들에서는 생략될 수 있다.
[35] 여기 설명된 구성들 및/또는 접근방법들은 본질적으로 예시적인 것이며, 다수의 변형들이 가능하므로, 상기 특정한 실시예들 또는 실험예들은 제한하는 의미로 여겨지지 말아야 한다는 것이 이해되어야 할 것이다. 여기 설명된 특정한 루틴들 또는 방법들은 임의의 수의 공정 전략들 중 하나 또는 그 이상을 나타낼 수 있다. 따라서, 도시된 다양한 행위들은 도시된 순서에 따라, 다른 순서들에 따라 수행될 수 있고, 또는 몇몇의 경우들에는 생략될 수 있다.
[36] 본 개시의 주제는 여기에 개시된 다양한 공정들, 시스템들, 및 구성들의 모든 신규하고 비자명한 조합(combination)들 및 하위조합(subcombination)들 및 다른 특징들, 기능들, 행위들, 및/또는 속성들뿐만 아니라, 이들의 임의의 및 모든 균등물들을 포함한다.
Claims (20)
- 반응 챔버 내에 공정을 위한 기판을 제공하는 단계;
상기 기판 상으로 금속 전구체 퇴적을 수행하는 단계로서:
상기 기판 상으로 금속 전구체를 펄스하는 단계; 및
상기 반응 챔버로부터 여분의 상기 금속 전구체를 퍼지하는 단계를 포함하는, 상기 금속 전구체 퇴적을 수행하는 단계; 및
상기 기판 상으로 데카보레인 전구체 퇴적을 수행하는 단계로서:
상기 기판 상으로 데카보레인 전구체를 펄스하는 단계; 및
상기 반응 챔버로부터 여분의 상기 데카보레인 전구체를 퍼지하는 단계를 포함하는, 상기 데카보레인 전구체 퇴적을 수행하는 단계를 포함하고;
상기 금속 전구체는 티타늄 테트라클로라이드(TiCl4), 니오븀 펜타클로라이드(NbCl5), 탄탈륨 펜타플루오라이드(TaF5), 및 니오븀 펜타플루오라이드(NbF5) 중 하나를 포함하고;
상기 금속 할로겐화물 전구체 및 상기 데카보레인 전구체 사이의 반응은 붕소화 티타늄(TiB), 붕소화 탄탈륨(TaB), 또는 붕소화 니오븀(NbB) 중 적어도 하나를 포함하는 막을 형성하고;
상기 금속 전구체 퇴적 단계는 정해진 횟수 동안 반복되고;
상기 데카보레인 전구체 퇴적 단계는 정해진 횟수 동안 반복되는 것을 특징으로 하는 금속 붕소화물을 갖는 막의 제조 방법. - 제 1 항에 있어서,
상기 반응 챔버의 온도는 300℃ 보다 높은 것을 특징으로 하는 금속 붕소화물을 갖는 막의 제조 방법. - 제 2 항에 있어서,
상기 반응 챔버의 온도는 375℃ 보다 높은 것을 특징으로 하는 금속 붕소화물을 갖는 막의 제조 방법. - 제 1 항에 있어서,
상기 반응 챔버의 압력은 0.1 내지 10Torr 범위인 것을 특징으로 하는 금속 붕소화물을 갖는 막의 제조 방법. - 제 1 항에 있어서,
상기 금속 전구체를 펄스하는 단계는 0.1 내지 5초의 지속 시간을 갖는 것을 특징으로 하는 금속 붕소화물을 갖는 막의 제조 방법. - 제 1 항에 있어서,
상기 데카보레인 전구체를 펄스하는 단계는 0.05 내지 20초의 지속 시간을 갖는 것을 특징으로 하는 금속 붕소화물을 갖는 막의 제조 방법. - 제 1 항에 있어서,
상기 여분의 상기 금속 전구체를 퍼지하는 단계는 질소(N2), 아르곤(Ar), 헬륨(He), 수소(H2), 또는 다른 희유 기체들(rare gases) 중 적어도 하나로 상기 반응 챔버를 퍼지하는 단계를 포함하는 것을 특징으로 하는 금속 붕소화물을 갖는 막의 제조 방법. - 제 1 항에 있어서,
상기 여분의 상기 데카보레인을 퍼지하는 단계는 질소(N2), 아르곤(Ar), 헬륨(He), 수소(H2), 또는 다른 희유 기체들 중 적어도 하나로 상기 반응 챔버를 퍼지하는 단계를 포함하는 것을 특징으로 하는 금속 붕소화물을 갖는 막의 제조 방법. - 제 1 항에 있어서,
상기 막은 약 30 내지 약 80at%(원자 퍼센트), 약 40 내지 약 80at%, 또는 약 30 내지 약 50at%의 붕소 농도를 갖는 것을 특징으로 하는 금속 붕소화물을 갖는 막의 제조 방법. - 제 1 항에 있어서,
상기 막은 약 20 내지 약 70at%, 약 20 내지 약 60at%, 또는 약 30 내지 약 50at%의 금속 농도를 갖는 것을 특징으로 하는 금속 붕소화물을 갖는 막의 제조 방법. - 제 1 항에 있어서,
상기 막은 약 5at% 보다 낮거나, 또는 1at% 보다 낮은 산소 농도를 갖는 것을 특징으로 하는 금속 붕소화물을 갖는 막의 제조 방법. - 제 1 항에 있어서,
상기 막은 약 5at% 보다 낮거나, 또는 1at% 보다 낮은 수소 농도를 갖는 것을 특징으로 하는 금속 붕소화물을 갖는 막의 제조 방법. - 제 1 항에 있어서,
상기 막은 약 5at% 보다 낮거나, 또는 1at% 보다 낮은 할로겐화물 농도를 갖는 것을 특징으로 하는 금속 붕소화물을 갖는 막의 제조 방법. - 반응 챔버 내에 공정을 위한 기판을 제공하는 단계;
상기 기판을 금속 할로겐화물 전구체에 노출시키는 단계;
상기 기판을 상기 금속 할로겐화물 전구체에 노출시키는 단계 후에, 상기 기판을 퍼지 기체에 노출시키는 단계;
상기 기판을 데카보레인 전구체에 노출시키는 단계;
상기 기판을 상기 데카보레인 전구체에 노출시키는 단계 후에, 상기 기판을 상기 퍼지 기체에 노출시키는 단계를 포함하고;
상기 금속 할로겐화물 전구체에 노출시키는 단계는 정해진 횟수 동안 반복되고;
상기 데카보레인 전구체에 노출시키는 단계는 정해진 횟수 동안 반복되는 것을 특징으로 하는 금속 붕소화물을 갖는 막의 제조 방법. - 제 14 항에 있어서,
상기 퍼지 기체는 질소(N2), 아르곤(Ar), 헬륨(He), 수소(H2), 또는 다른 희유 기체들 중 적어도 하나를 포함하는 것을 특징으로 하는 금속 붕소화물을 갖는 막의 제조 방법. - 제 14 항에 있어서,
상기 반응 챔버의 온도는 300℃ 보다 높은 것을 특징으로 하는 금속 붕소화물을 갖는 막의 제조 방법. - 제 16 항에 있어서,
상기 반응 챔버의 온도는 375℃ 보다 높은 것을 특징으로 하는 금속 붕소화물을 갖는 막의 제조 방법. - 제 14 항에 있어서,
상기 기판을 상기 금속 할로겐화물 전구체에 노출시키는 단계는 상기 금속 할로겐화물 전구체를 펄스하는 단계를 포함하는 것을 특징으로 하는 금속 붕소화물을 갖는 막의 제조 방법. - 제 14 항에 있어서,
상기 기판을 상기 데카보레인 전구체에 노출시키는 단계는 상기 데카보레인 전구체를 펄스하는 단계를 포함하는 것을 특징으로 하는 금속 붕소화물을 갖는 막의 제조 방법. - 제 14 항에 있어서,
상기 기판을 상기 퍼지 기체에 노출시키는 단계는 상기 퍼지 기체를 펄스하는 단계를 포함하는 것을 특징으로 하는 금속 붕소화물을 갖는 막의 제조 방법.
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US20190153593A1 (en) | 2019-05-23 |
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