JPS5819462A - 電縫溶接鋼管 - Google Patents
電縫溶接鋼管Info
- Publication number
- JPS5819462A JPS5819462A JP11668381A JP11668381A JPS5819462A JP S5819462 A JPS5819462 A JP S5819462A JP 11668381 A JP11668381 A JP 11668381A JP 11668381 A JP11668381 A JP 11668381A JP S5819462 A JPS5819462 A JP S5819462A
- Authority
- JP
- Japan
- Prior art keywords
- steel pipe
- welded steel
- pipe
- strain aging
- annealing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 47
- 239000010959 steel Substances 0.000 title claims abstract description 47
- 239000012535 impurity Substances 0.000 claims abstract description 3
- 230000032683 aging Effects 0.000 abstract description 19
- 238000000137 annealing Methods 0.000 abstract description 15
- 239000000463 material Substances 0.000 abstract description 7
- 239000000203 mixture Substances 0.000 abstract description 6
- 229910052758 niobium Inorganic materials 0.000 abstract description 5
- 229910052720 vanadium Inorganic materials 0.000 abstract description 4
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 2
- 230000002093 peripheral effect Effects 0.000 abstract 1
- 238000001816 cooling Methods 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 238000003466 welding Methods 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 230000007423 decrease Effects 0.000 description 3
- 239000006104 solid solution Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 230000006698 induction Effects 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910018663 Mn O Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000011888 autopsy Methods 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 238000005219 brazing Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000009751 slip forming Methods 0.000 description 1
- 230000010512 thermal transition Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
め要約のデータは記録されません。
Description
【発明の詳細な説明】
この発明は電縫溶接鋼管の組成に関し、特に溶接後のボ
ストアニールによる熱影響部の歪時効脆化を防止して靭
性を改嵐した電縫溶接鋼管を提供するものである。
ストアニールによる熱影響部の歪時効脆化を防止して靭
性を改嵐した電縫溶接鋼管を提供するものである。
周知のように電縫鋼管の製造工程において社、硬化した
溶接部の組織を改善するため、溶接後に溶接部を局部的
に加熱する新調ポストアニールを施すことが多い、この
ようなボストアニール工程を含む電縫鋼管の製造工程の
代表例を第1図に示す。第1図において、一般に帯状ス
ケルプと称される素材帯鋼lを成形ライン2において連
続的に管状体に成形した後、コンタクトチップもしくは
誘導加熱コイルからなる高周波給電体3によシ帯鋼両端
を溶接温度まで加熱し、スクイズロール4によって加圧
溶接し、得られた溶接管(電縫鋼管)5の内外面の溶接
ビードを切削した後、ボストアニーラと称する局部1導
加熱装置6によって溶接部を局部的にオーステナイト化
温度まで加熱し、続いて空冷ゾーン7において溶接部が
400〜500℃以下となるまで空冷し、その後水冷ゾ
ーン8において水冷を施した後、ただちにサイプと称す
る定形機9によって所定の外径、真円度に成形し、矯正
機所定の寸法に切断することによって製品となる。
溶接部の組織を改善するため、溶接後に溶接部を局部的
に加熱する新調ポストアニールを施すことが多い、この
ようなボストアニール工程を含む電縫鋼管の製造工程の
代表例を第1図に示す。第1図において、一般に帯状ス
ケルプと称される素材帯鋼lを成形ライン2において連
続的に管状体に成形した後、コンタクトチップもしくは
誘導加熱コイルからなる高周波給電体3によシ帯鋼両端
を溶接温度まで加熱し、スクイズロール4によって加圧
溶接し、得られた溶接管(電縫鋼管)5の内外面の溶接
ビードを切削した後、ボストアニーラと称する局部1導
加熱装置6によって溶接部を局部的にオーステナイト化
温度まで加熱し、続いて空冷ゾーン7において溶接部が
400〜500℃以下となるまで空冷し、その後水冷ゾ
ーン8において水冷を施した後、ただちにサイプと称す
る定形機9によって所定の外径、真円度に成形し、矯正
機所定の寸法に切断することによって製品となる。
しかるに上述のような製造工程によって得られた電縫鋼
管においては、溶接部から10〜39ss離れた位置に
おける靭性が他の部分よシ低下する現象が生じることが
ある。すなわち本発明者等が通常鋼成分の電縫銅管の管
周方向各部位についてシャルピー衝撃値を調べたところ
、後述する第3図の破線(比較例I)で示すように、溶
接部周辺の10〜30■の部位においてはボストアニー
ル(局部加熱処理)によシ焼鈍され九溶接部や電縫鋼管
母材の他の部分よシも衝撃値が低下していることが確認
された。このように局部的に衝撃特性が低下すれば、特
に寒冷地に使用されるラインパづプ等においてはパイプ
の破壊事故原因となることもあシ、安全性の点から重要
な問題となる。
管においては、溶接部から10〜39ss離れた位置に
おける靭性が他の部分よシ低下する現象が生じることが
ある。すなわち本発明者等が通常鋼成分の電縫銅管の管
周方向各部位についてシャルピー衝撃値を調べたところ
、後述する第3図の破線(比較例I)で示すように、溶
接部周辺の10〜30■の部位においてはボストアニー
ル(局部加熱処理)によシ焼鈍され九溶接部や電縫鋼管
母材の他の部分よシも衝撃値が低下していることが確認
された。このように局部的に衝撃特性が低下すれば、特
に寒冷地に使用されるラインパづプ等においてはパイプ
の破壊事故原因となることもあシ、安全性の点から重要
な問題となる。
ところで上述のような電縫鋼管にあける局部的脆化現象
の原因について本発明者等が種々調査研究を行なったと
ころ、次のような事実が判明した。
の原因について本発明者等が種々調査研究を行なったと
ころ、次のような事実が判明した。
すなわち、繭述の電縫鋼管製造工程において、局部誘導
加熱装置6によってボストアニールを行った後、水冷ゾ
ーン8に至るまでの間の空冷ゾーン7における電縫鋼管
の管周方向の各部位の温度推移を精密に調定し九ところ
、第2図に示すように溶接部周辺10〜30■の位置に
おいては水冷シー78に至るまでの間400〜200℃
程度の温11に比較的長時間保持されることが判明し友
、このことから、剖記部位においてはいわゆる青熱脆化
現象が発生し、歪時効によって靭性の低下を招いている
ものと推定された。すなわち、従来使用されている通常
成分の鋼においては鋼中の窒素軸が充分に固定されてい
ない丸め、成形曲げ加工によって生じ九残留歪に加えて
ボストアニール処理後の空冷時における200〜400
℃の長時間保持によシ歪時効現象が生じているものと考
えられる。もちろん前記部位が400〜200℃に保持
される時間は造管速度(う1ン速F#L)によって異な
り、シたがって歪時効による硬化の程度(脆化の程度)
は造管速度によりて異なシ、造管速度が速いほど硬化度
が小さくなって脆化が少なくなる。
加熱装置6によってボストアニールを行った後、水冷ゾ
ーン8に至るまでの間の空冷ゾーン7における電縫鋼管
の管周方向の各部位の温度推移を精密に調定し九ところ
、第2図に示すように溶接部周辺10〜30■の位置に
おいては水冷シー78に至るまでの間400〜200℃
程度の温11に比較的長時間保持されることが判明し友
、このことから、剖記部位においてはいわゆる青熱脆化
現象が発生し、歪時効によって靭性の低下を招いている
ものと推定された。すなわち、従来使用されている通常
成分の鋼においては鋼中の窒素軸が充分に固定されてい
ない丸め、成形曲げ加工によって生じ九残留歪に加えて
ボストアニール処理後の空冷時における200〜400
℃の長時間保持によシ歪時効現象が生じているものと考
えられる。もちろん前記部位が400〜200℃に保持
される時間は造管速度(う1ン速F#L)によって異な
り、シたがって歪時効による硬化の程度(脆化の程度)
は造管速度によりて異なシ、造管速度が速いほど硬化度
が小さくなって脆化が少なくなる。
しかしながら一般に高強度電縫鋼管になるほど成形機2
による成形速度が遅くなシ、またその後のスフ1ズロー
ル4による加圧成形速度が遅くなり、その結果ライン速
度が遅くなって第2図に示すように100秒程度以上の
長時間にわたって400〜200℃の温度に保持され、
歪時効にょる脆化が著しくなるのである。
による成形速度が遅くなシ、またその後のスフ1ズロー
ル4による加圧成形速度が遅くなり、その結果ライン速
度が遅くなって第2図に示すように100秒程度以上の
長時間にわたって400〜200℃の温度に保持され、
歪時効にょる脆化が著しくなるのである。
この発明は以上の事情を背景としてなされたものであシ
、電縫鋼管の溶接部周辺10〜3o■の部位、すなわち
ボストアニール熱影響部が歪時効によシ脆化することを
防止して、電縫鋼管の局所的靭性低下を防止することを
目的とするものである。すなわち本発明者等は、鋼中に
固溶されているNが歪時効現象に大きな影響を与えるこ
とに着目して種々実験・研究を重ねた結果、通常鋼に不
6丁避的に含有されるNを0.0030 %以下に抑え
た鋼を素材とすることによってボストアニール熱、影響
部の歪時効脆化を防止し得ることを見出し、この発明を
なすに至ったのである。
、電縫鋼管の溶接部周辺10〜3o■の部位、すなわち
ボストアニール熱影響部が歪時効によシ脆化することを
防止して、電縫鋼管の局所的靭性低下を防止することを
目的とするものである。すなわち本発明者等は、鋼中に
固溶されているNが歪時効現象に大きな影響を与えるこ
とに着目して種々実験・研究を重ねた結果、通常鋼に不
6丁避的に含有されるNを0.0030 %以下に抑え
た鋼を素材とすることによってボストアニール熱、影響
部の歪時効脆化を防止し得ることを見出し、この発明を
なすに至ったのである。
具体的にはこの発明の電縫鋼管は、C0,4S以下、8
i0.81以下、Mn O,3〜1.80 Ss AJ
o、ol〜o、1o*、INo、0030s以下t’含
有するとともに、Nb O,01〜0.10%、 Vo
、010〜0、151のうち1種以上を含有し、残部が
Feおよび不可避的不純物からなることを特徴とするも
のであシ、このようKNを0.0030−以下に規制す
るとともにNbおよび/またはVを添加することによっ
てボストアニール熱影響部の歪時効脆化を防止し、管周
方向に均一な靭性値を有するようにしたものである。
i0.81以下、Mn O,3〜1.80 Ss AJ
o、ol〜o、1o*、INo、0030s以下t’含
有するとともに、Nb O,01〜0.10%、 Vo
、010〜0、151のうち1種以上を含有し、残部が
Feおよび不可避的不純物からなることを特徴とするも
のであシ、このようKNを0.0030−以下に規制す
るとともにNbおよび/またはVを添加することによっ
てボストアニール熱影響部の歪時効脆化を防止し、管周
方向に均一な靭性値を有するようにしたものである。
以下この発明をさらに詳細に説明する。
先ずこの発明の電縫鋼管の化学成分の限定理由を説明す
ると、Cは最も安定して強度を向上させる元素であるが
、0.4011を越えれば電縫鋼管製造時に詔いて溶接
割れを起こし易いから、溶接品質を確保するため上限を
0.40−とし丸、但し特に寒冷地等に使用される場合
には低温靭性をよ〕良好にするため0.04〜0.16
−の範囲とすることが望ましい。
ると、Cは最も安定して強度を向上させる元素であるが
、0.4011を越えれば電縫鋼管製造時に詔いて溶接
割れを起こし易いから、溶接品質を確保するため上限を
0.40−とし丸、但し特に寒冷地等に使用される場合
には低温靭性をよ〕良好にするため0.04〜0.16
−の範囲とすることが望ましい。
siは鋼中の脱酸元素として有効なものであるが、過剰
に含有されれば電縫溶接時に8102成分によるペネト
レータ欠陥が溶接部に発生し易く、そのため0.80
f4以下に制限しえ。
に含有されれば電縫溶接時に8102成分によるペネト
レータ欠陥が溶接部に発生し易く、そのため0.80
f4以下に制限しえ。
MtはCと同様に鋼の強度を向上させる元素であシ、靭
性改善にも有効であるが、0.3−未満ではこれらの効
果が充分ではなぐ、一方過剰にMnを添加した場合には
MmOを主体としたペネトレータ欠陥が浴接部に発生し
易いから、上限を1.8096とした。
性改善にも有効であるが、0.3−未満ではこれらの効
果が充分ではなぐ、一方過剰にMnを添加した場合には
MmOを主体としたペネトレータ欠陥が浴接部に発生し
易いから、上限を1.8096とした。
局祉鋼の脱酸元素として有効であるとともに結晶粒微細
化作用によ如鋼の強度、靭性を向上させるが、0.1(
lを越えればがえりて靭性を低下させるばかシでなく、
溶接性をも低下させるから、上限を0.10慢とした。
化作用によ如鋼の強度、靭性を向上させるが、0.1(
lを越えればがえりて靭性を低下させるばかシでなく、
溶接性をも低下させるから、上限を0.10慢とした。
NtiAJ添加により一部はMNとして固定されるが一
部は固溶Nとして存在し、歪時効脆化を促進する。そ、
こでこの発明では固溶Nによる歪時効脆化の促進を防止
する九めN含有量を極力抑制することとした。そして後
述する実施例で示すようにN含有量が0.0030−を
越える場合には歪時効脆化の防止効果が得難くなること
から、Nの上限を0.00301とした。
部は固溶Nとして存在し、歪時効脆化を促進する。そ、
こでこの発明では固溶Nによる歪時効脆化の促進を防止
する九めN含有量を極力抑制することとした。そして後
述する実施例で示すようにN含有量が0.0030−を
越える場合には歪時効脆化の防止効果が得難くなること
から、Nの上限を0.00301とした。
Nb 、 Vはともに結晶粒t−m化および炭化物とし
ての析出によって強度および靭性を向上させるに効果が
あ、9、Nb、Vのうち1種以上を添加すれば良い。N
bは0.Ol−未満で杜上記効果が不充分であり、一方
0.10 饅を越えればかえって靭性が低)してしまう
ことから、Nbの添加量は0.O1〜0.10優とする
。またVは0.01慢未満では上記効果が不充分であシ
、一方0.15 %を越えればかえって靭性が低下する
ことからVの添加量は0.01〜0.15チとする。
ての析出によって強度および靭性を向上させるに効果が
あ、9、Nb、Vのうち1種以上を添加すれば良い。N
bは0.Ol−未満で杜上記効果が不充分であり、一方
0.10 饅を越えればかえって靭性が低)してしまう
ことから、Nbの添加量は0.O1〜0.10優とする
。またVは0.01慢未満では上記効果が不充分であシ
、一方0.15 %を越えればかえって靭性が低下する
ことからVの添加量は0.01〜0.15チとする。
なお、1述のようにNを0.0030チ(30ppm
)以下に規制するためには、素材製造時において溶鋼を
取鍋から注入する際に、大気と溶鋼との接触による溶鋼
のN吸収を防止するべく周囲をArガス等の不活性ガス
雰囲気とすれば良い。
)以下に規制するためには、素材製造時において溶鋼を
取鍋から注入する際に、大気と溶鋼との接触による溶鋼
のN吸収を防止するべく周囲をArガス等の不活性ガス
雰囲気とすれば良い。
以)にこの発明の実施例および比較例を記す。
夾り例
第1表の試料A−Hに示す本発明組成範囲内の化学成分
を有する素材を用いて、第1図の工程によシ管規格AP
I 5LX−X60.管外fi 5081111、肉厚
7,14■の電縫鋼管を製造した。
を有する素材を用いて、第1図の工程によシ管規格AP
I 5LX−X60.管外fi 5081111、肉厚
7,14■の電縫鋼管を製造した。
比較例
第1表の試料F−Iに示す本発明組成範囲外の化学成分
を有する素材を用いて、前記同様な電縫鋼管を製造した
。
を有する素材を用いて、前記同様な電縫鋼管を製造した
。
以上の各実施例および比較例の電縫銅管のうち、試料記
号C(本発明)およびH(比較例)の電縫鋼管について
溶接部から管周方向各位置における0℃シャルピー衝撃
値を調べた結果を第3図に示し、また実施例および比較
例のすべての電縫鋼管について溶接部から管周方向へ2
0■の位置におV)る0℃シャルピー衝撃値を調べた結
果を各試料のN含有量と対応して第4図に示す。第3図
から、従来の電縫鋼管(比較例試料H)では溶接部から
10〜30霞の位置において衝撃値が低下して、局部的
に歪時効による脆化が生じていることが明瞭であり、こ
れに対しこの発明の電縫鋼管(試料C)においては溶接
部では衝撃値が若干高いものの、その他の部分では管周
方向90°の位置まで衝撃値がほぼ均一となっておシ、
歪時・効による脆化がほとんど生じていないことが明ら
かである。
号C(本発明)およびH(比較例)の電縫鋼管について
溶接部から管周方向各位置における0℃シャルピー衝撃
値を調べた結果を第3図に示し、また実施例および比較
例のすべての電縫鋼管について溶接部から管周方向へ2
0■の位置におV)る0℃シャルピー衝撃値を調べた結
果を各試料のN含有量と対応して第4図に示す。第3図
から、従来の電縫鋼管(比較例試料H)では溶接部から
10〜30霞の位置において衝撃値が低下して、局部的
に歪時効による脆化が生じていることが明瞭であり、こ
れに対しこの発明の電縫鋼管(試料C)においては溶接
部では衝撃値が若干高いものの、その他の部分では管周
方向90°の位置まで衝撃値がほぼ均一となっておシ、
歪時・効による脆化がほとんど生じていないことが明ら
かである。
また第4図から、鋼中Nの含有量を0.0030 %以
下に規制することによってボストアニール熱影響部の歪
時効脆化を防止して靭性を著しく改善し得ることが明ら
かである。
下に規制することによってボストアニール熱影響部の歪
時効脆化を防止して靭性を著しく改善し得ることが明ら
かである。
以上の説明で明らかなように仁の発明の電縫鋼管は、ボ
ストアニール処理後の空冷時におけるボストアニール熱
影響部の歪時効脆化による局部的靭性低下を有効に防止
して、管網方向に均一な靭性を得ることができ、したが
って寒冷地に使用されろう1ンパイブ等に使用してもボ
ストアニール熱影響部の歪時効脆化に起因する破壊事故
の発生を有効に防止することができる等の効果が得られ
る。
ストアニール処理後の空冷時におけるボストアニール熱
影響部の歪時効脆化による局部的靭性低下を有効に防止
して、管網方向に均一な靭性を得ることができ、したが
って寒冷地に使用されろう1ンパイブ等に使用してもボ
ストアニール熱影響部の歪時効脆化に起因する破壊事故
の発生を有効に防止することができる等の効果が得られ
る。
第1図は電縫溶接鋼管の一般的な製造工程の一例を示す
ブロック図、第2図は第1図の工程中のボストアニール
処理後の空冷ゾーンにおける溶接鋼管の各部位の温政推
移を示すグラフ、第3図はこの発明の実施例および比較
例の電縫鋼管における溶接部から管周方向各位置の0℃
シャルピー衝撃値の分布を示すグラフ、第4図はこの発
明の実施例および比較例の電縫鋼管における溶接部から
管周方向20■の位置での0℃シャルピー衝撃値とN含
有量との関係を示すグラフである。
ブロック図、第2図は第1図の工程中のボストアニール
処理後の空冷ゾーンにおける溶接鋼管の各部位の温政推
移を示すグラフ、第3図はこの発明の実施例および比較
例の電縫鋼管における溶接部から管周方向各位置の0℃
シャルピー衝撃値の分布を示すグラフ、第4図はこの発
明の実施例および比較例の電縫鋼管における溶接部から
管周方向20■の位置での0℃シャルピー衝撃値とN含
有量との関係を示すグラフである。
Claims (1)
- c O,4* (重量−1以下同じ)以下、810.8
%以下、Mm 03〜1.8 S、AJ O,01〜0
.1011、N O,0030−以下を含有するととも
K Nb O,01〜0.1(1、Vo、01〜0.1
511のうち1種以上を含有し、残部が?・および不可
避的不純物からなることを特徴とする電縫溶接鋼管。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11668381A JPS5819462A (ja) | 1981-07-24 | 1981-07-24 | 電縫溶接鋼管 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11668381A JPS5819462A (ja) | 1981-07-24 | 1981-07-24 | 電縫溶接鋼管 |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS5819462A true JPS5819462A (ja) | 1983-02-04 |
Family
ID=14693283
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP11668381A Pending JPS5819462A (ja) | 1981-07-24 | 1981-07-24 | 電縫溶接鋼管 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5819462A (ja) |
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