JP2845163B2 - プラズマ処理方法及びその装置 - Google Patents

プラズマ処理方法及びその装置

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Publication number
JP2845163B2
JP2845163B2 JP7115655A JP11565595A JP2845163B2 JP 2845163 B2 JP2845163 B2 JP 2845163B2 JP 7115655 A JP7115655 A JP 7115655A JP 11565595 A JP11565595 A JP 11565595A JP 2845163 B2 JP2845163 B2 JP 2845163B2
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JP
Japan
Prior art keywords
plasma
electric field
pulse
substrate
discharge
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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JP7115655A
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English (en)
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JPH08181125A (ja
Inventor
誠二 寒川
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NEC Corp
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Nippon Electric Co Ltd
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Publication date
Application filed by Nippon Electric Co Ltd filed Critical Nippon Electric Co Ltd
Priority to JP7115655A priority Critical patent/JP2845163B2/ja
Priority to US08/548,730 priority patent/US5827435A/en
Publication of JPH08181125A publication Critical patent/JPH08181125A/ja
Application granted granted Critical
Publication of JP2845163B2 publication Critical patent/JP2845163B2/ja
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/32009Arrangements for generation of plasma specially adapted for examination or treatment of objects, e.g. plasma sources
    • H01J37/32192Microwave generated discharge
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/302Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
    • H01L21/306Chemical or electrical treatment, e.g. electrolytic etching
    • H01L21/3065Plasma etching; Reactive-ion etching
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/31Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
    • H01L21/3105After-treatment
    • H01L21/311Etching the insulating layers by chemical or physical means
    • H01L21/31105Etching inorganic layers
    • H01L21/31111Etching inorganic layers by chemical means
    • H01L21/31116Etching inorganic layers by chemical means by dry-etching

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Plasma & Fusion (AREA)
  • Power Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • ing And Chemical Polishing (AREA)
  • Drying Of Semiconductors (AREA)

Description

【発明の詳細な説明】
【0001】
【産業上の利用分野】本発明は、表面処理に関し、特に
高周波電界を利用して生成したプラズマを用いて基板表
面の処理を行うプラズマ処理装置に関するものである。
【0002】
【従来の技術】従来、この種のマイクロ波プラズマエッ
チング装置として、図7(A)に示すものがある。例え
ば特開昭56−155535号公報、特開昭60−13
4423号公報参照。この装置はマイクロ波608によ
る電子サイクロトロン共鳴放電中にエッチング試料61
4をセットし、該試料に800kHz〜13.56MH
zの基板バイアスを印加してエッチング処理を行うもの
である。図7(B)はこのときのRF電圧と電子および
イオン入射領域を示す図である。特開平4−10378
3号公報には、高速・異方性エッチングを行いかつエッ
チング速度を均一にするために基板の処理をECR共鳴
光で行いかつ基板バイアス電圧に100〜600kHz
の高周波を印加してエッチングするためのESRプラズ
マエッチング装置が記載されている。
【0003】
【発明が解決しようとする課題】しかし、上述した従来
の技術においては基板表面への電荷蓄積が生じ、高速性
・異方性とダメージの抑制の両立が難しいという問題点
がある。
【0004】本発明は、このような従来の問題点を解決
するためになされたものである。パルス変調プラズマを
用いることでプラズマ中の負イオン密度を増加させ、か
つイオンが追従できる低周波数バイアスを印加すること
で、基板に交互に正イオンと負イオンを入射させること
で電荷蓄積を抑制すると共により一層の高速・異方性エ
ッチングを両立できることを目的とする。
【0005】
【課題を解決するための手段】本発明は、パルス停止時
間を10〜100μ秒の範囲としてプラズマ生成用高周
波をパルス変調し、かつ該プラズマ中に設置した基板に
600kHz以下のバイアスを印加し、該RF電界は放
電用高周波電界のパルス変調に同期させて、かつ、放電
用高周波電界のパルス停止時のみに印加することを特徴
とするプラズマ処理方法とその装置である。
【0006】
【作用】本発明では、パルス停止時間を10〜100μ
に設定してプラズマをパルス変調することにより、プ
ラズマ中の負イオンを連続放電に比べ圧倒的に増加させ
ることができる。これは、負イオンがアフターグロー中
で効率よく生成され、その生成時間が10〜100μ秒
程度であることによる。この時、600kHz以下のR
F電界を該プラズマに印加すると図1(B)に示すよう
に質量の重い正・負イオンがRF電界に追従して基板に
加速され半周期ずつ交互に入射することになる。これに
より、基板表面での電荷蓄積は抑制され、また、正イオ
ンばかりでなく加速されて入射した負イオンによっても
エッチングが進むので、エッチング速度の上昇が期待で
きる。また、磁場を用いたプラズマで顕著に表れる電子
とイオンの運動の違いから生じるダメージや異常エッチ
ングを抑制することができる。
【0007】このようにして表面での電荷蓄積によるデ
バイスへのダメージを抑制できるとともに、高速かつ異
方性エッチングを両立して行うことができる。
【0008】
【実施例】図1(A)は本発明を説明するための装置の
第一の実施例である。本装置は、マイクロ波電界とコイ
ル6による磁界によりプラズマ7を生成するプラズマ生
成室1と基板搬送室とが互いに隣接するように構成され
ている。このプラズマ生成室にはプラズマを生成するた
めのガスを導入するガス系が接続されるとともに、2.
45GHz程度のマイクロ波を導入する導波管2が設置
されている。マイクロ波電源3からの導入マイクロ波は
パルス回路4とファンクションジェネレータ5により1
0〜50μ秒にパルス変調され、プラズマ生成室に設置
された基板ホルダ部8の基板9には400kHzのバイ
アスが印加されている。図1(B)はRF電圧とイオン
及び電子の入射の関係を示す図である。
【0009】図2は酸素プラズマにおけるアフターグロ
ープラズマ中の負イオン生成量の時間変位を示す。RF
パワー0.90kW、酸素圧0.47Paの条件で負イ
オンはパワーOFF(T=15.0msecの時点)後
数μ秒程度から生成し、30μ秒程度で最大値をもつ。
このことから、10〜50μ秒のパルス変調プラズマに
より負イオン生成が効率よくなされることがわかる。
【0010】図3は窒素プラズマ中に設置された基板に
印加する高周波周波数と基板上に生成されるバイアス電
圧(基板シース電圧)の関係を示す。600kHz以下
の周波数になると基板上にバイアス電圧が生じなくなる
ことがわかる。これは、正イオンがバイアス周波数に追
従しイオンと電子が基板に交互に入射するためである。
すなわち、イオンが周波数に追従できるのは600kH
z以下の周波数であることがわかる。
【0011】この実施例から10〜50μ秒のパルス変
調プラズマにより正・負イオンを効率よく生成し、その
正負イオンを600kHz以下の低周波バイアスにより
基板に効率よく交互に入射させることが可能となる。
【0012】また、本発明は放電周波数に依存すること
なく適用でき、さらに、基板バイアスもパルス変調する
ことで基板に入射するバイアス電圧を時間制御でき、よ
り高精度なエッチングが実現できる。
【0013】第二の実施例について説明する。図4に塩
素プラズマ中のアフターグロー中に発生する負イオンの
時間変位を示す。パルスOFF時間が100μ秒程度ま
で負イオンが生成していることがわかる。
【0014】この時、600kHzのRFバイアスを基
板に印加した場合のポリシリコンエッチング速度及び均
一性を図5に示す。放電停止時間が100μ秒程度まで
長くなるにつれてエッチング速度が上昇し、エッチング
均一性が改善されることがわかる。これは、放電停止時
に発生する負イオンによってプラズマポテンシャルが均
一化され、かつ、負イオンが基板に入射してエッチング
に寄与するためである。このことから、100μ秒程度
の放電停止時間が有効であることがわかった。
【0015】図6はマイクロ波、イオン密度、基板バイ
アスを示す図であり、この図6に示す実施例は、パルス
放電における放電停止時間を90%以上とし、多量の負
イオンと正イオンが存在する放電停止中のみに600k
Hzの低周波RFバイアスを印加することで正負イオン
のみでエッチングを行う例である。例えば、ECRプラ
ズマ等では10μ秒程度の放電時間中に十分な密度の正
イオンが生成されるため、その後100μ秒の放電停止
を行うことで多量の正負イオンが生成される。この時、
600kHzのRF電界を放電OFF時のみに印加する
ようにすれば、基板には移動度の同じ正負イオンのみ入
射し、従来の電子及びイオンの移動度の違いによって発
生する電荷蓄積(チャージング)を抑制することが可能
である。この実施例から放電用高周波電界は10〜10
0μ秒の範囲のパルス変調がよいことがわかる。
【0016】
【発明の効果】以上説明したように、本発明のプラズマ
処理方法によれば、電荷蓄積の無い高速・高選択・異方
性エッチングが実現できる。
【図面の簡単な説明】
【図1】本発明を説明するための図。
【図2】アフターグロープラズマ中の負イオンの生成の
時間変位を示す図。
【図3】基板バイアス周波数と基板シース電圧(セルフ
バイアス電圧)の関係を示す図。
【図4】本発明を説明するための図。
【図5】本発明を説明するための図。
【図6】本発明を説明するための図。
【図7】従来例によるプラズマエッチング装置を説明す
るための図。
【符号の説明】
1 プラズマチャンバ(生成管) 2 導波管 3 マイクロ波電源 4 パルス回路 5 ファンクションジェネレータ 6 コイル 7 プラズマ 8 基板電極 9 基板 601 プラズマ生成室 602 反応室 603 ソレノイドコイル 604 プラズマ引き出し窓 605 導波管 607 ガス導入口 608 マイクロ波 609 プラズマ 610 基板ホルダ 614 エッチング材料(基板)

Claims (4)

    (57)【特許請求の範囲】
  1. 【請求項1】 プラズマ生成室内で高周波によって発生
    する電場を利用して処理ガスをプラズマ化し、該プラズ
    マを基板に照射して基板処理を行うプラズマ処理方法に
    おいて、パルス停止時間を10〜100μ秒の範囲とし
    て放電用高周波電界をパルス変調するとともに、該プラ
    ズマ中に設置された基板電極へ600kHz以下のRF
    電界を印加し、該RF電界は放電用高周波電界のパルス
    変調に同期させて、かつ、放電用高周波電界のパルス停
    止時のみに印加することを特徴とするプラズマ処理方
    法。
  2. 【請求項2】 プラズマ生成室内で高周波によって発生
    する電場を利用して処理ガスをプラズマ化し、該プラズ
    マを基板に照射して基板処理を行うプラズマ処理方法に
    おいて、パルス停止時間を10〜100μ秒の範囲とし
    て放電用高周波電界をパルス変調することにより該パル
    ス停止時間中のプラズマのアフターグローにおいて負イ
    オンを生成し、かつ該プラズマ中に設置された基板電極
    へ600kHz以下のRF電界を印加し、該RF電界は
    放電用高周波電界のパルス変調に同期させて、かつ、放
    電用高周波電界のパルス停止時のみに印加することによ
    りプラズマ中の正及び負のイオンを該RF電界の半周期
    ずつ交互に基板に入射させることを特徴とするプラズマ
    処理方法。
  3. 【請求項3】 放電用高周波電界のパルス変調デューテ
    ィ比を10%以下とすることを特徴とする請求項1また
    は請求項2に記載のプラズマ処理方法。
  4. 【請求項4】 プラズマ生成室内に高周波を発生するた
    めの電源と、磁場をかける手段と、前記高周波を10〜
    100μ秒の範囲にパルス停止時間を設定してパルス変
    調するためのパルス回路と、プラズマ生成室内の基板電
    極に600kHz以下のRF電界を印加するRF電源
    と、前記RF電界を放電用高周波電界のパルス変調にお
    けるパルス停止時間のみに基板に印加する同期手段を有
    することを特徴とするプラズマ処理装置。
JP7115655A 1994-10-27 1995-05-15 プラズマ処理方法及びその装置 Expired - Fee Related JP2845163B2 (ja)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP7115655A JP2845163B2 (ja) 1994-10-27 1995-05-15 プラズマ処理方法及びその装置
US08/548,730 US5827435A (en) 1994-10-27 1995-10-26 Plasma processing method and equipment used therefor

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP26376394 1994-10-27
JP6-263763 1994-10-27
JP7115655A JP2845163B2 (ja) 1994-10-27 1995-05-15 プラズマ処理方法及びその装置

Related Child Applications (1)

Application Number Title Priority Date Filing Date
JP10088491A Division JPH10284297A (ja) 1998-04-01 1998-04-01 プラズマ処理方法及びその装置

Publications (2)

Publication Number Publication Date
JPH08181125A JPH08181125A (ja) 1996-07-12
JP2845163B2 true JP2845163B2 (ja) 1999-01-13

Family

ID=26454133

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Country Link
US (1) US5827435A (ja)
JP (1) JP2845163B2 (ja)

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