JP6920068B2 - トレンチの側壁又は平坦面に選択的に窒化ケイ素膜を形成する方法 - Google Patents
トレンチの側壁又は平坦面に選択的に窒化ケイ素膜を形成する方法 Download PDFInfo
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- JP6920068B2 JP6920068B2 JP2017021868A JP2017021868A JP6920068B2 JP 6920068 B2 JP6920068 B2 JP 6920068B2 JP 2017021868 A JP2017021868 A JP 2017021868A JP 2017021868 A JP2017021868 A JP 2017021868A JP 6920068 B2 JP6920068 B2 JP 6920068B2
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- dielectric film
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- side wall
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- 238000000034 method Methods 0.000 title claims description 41
- 229910052581 Si3N4 Inorganic materials 0.000 title description 11
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 title description 11
- 238000001039 wet etching Methods 0.000 claims description 76
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- 229910007991 Si-N Inorganic materials 0.000 claims description 25
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- 238000000137 annealing Methods 0.000 claims description 5
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- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 claims description 4
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- BSYNRYMUTXBXSQ-UHFFFAOYSA-N Aspirin Chemical compound CC(=O)OC1=CC=CC=C1C(O)=O BSYNRYMUTXBXSQ-UHFFFAOYSA-N 0.000 description 1
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- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
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- -1 nitrogen-containing ions Chemical class 0.000 description 1
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- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
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- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76801—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
- H01L21/76829—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing characterised by the formation of thin functional dielectric layers, e.g. dielectric etch-stop, barrier, capping or liner layers
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Description
PEALDによってトレンチを有するSi基板(Φ300mm)にSiN膜を形成し、その1つのサイクルは、図1Aに示されるPEALD装置及び図1Bに示されるガス供給システム(FPS)を用いて表4(堆積サイクル)に示される条件下で行われた。
表5に示される条件下でSiN膜を堆積した。ここで、閾値RFパワーは、実施例1と同様の手法で約400Wに決定された。その後、SiN膜は、表5に示される条件下でウェットエッチングされた。図8は、窒化ケイ素膜の断面の走査電子顕微鏡(Scanning Transmission Electron Microscope(STEM))写真を示す。図8から見られるように、RFパワーが700Wのとき、膜の上部/底部は、ウェットエッチングによって選択的に除去され、上面及びトレンチの底部には実質的に膜が残っていなかった(残存する膜が観察されなかった)。RFパワーが500Wのとき、膜の上部/底部は、ウェットエッチングによって膜の側壁部よりも圧倒的に除去されるが、残りの膜は、上面及びトレンチの底部に残存し、膜の側壁部は、ほとんどが残存していた。RFパワーが300Wのとき、膜の側壁部は、ウェットエッチングによって膜の上部/底部よりも圧倒的に除去され、側壁の一部の領域にも残りの膜が残存しなかったが、膜の上部/底部はほとんどが残存していた。
RFパワーを880Wとした以外は実施例1と同様にSiN膜を堆積した。その後、SiN膜は、実施例1と同一の条件下でウェットエッチングされた。図9は、ウェットエッチング後のSiN膜の断面の走査電子顕微鏡(STEM)写真を示す。図9から見られるように、上面及びトレンチの底部には実質的に膜が残存していなかった(膜の残存が観察されなかった)
RFパワーを600Wとした以外は実施例1と同様にPEALDによりトレンチを有するSi基板(Φ300mm)にSiN膜が堆積される。その後、同一のリアクタ内で、膜は、以下の表6に示される条件下でプラズマによって処理され、ここで、RFパワーは、閾値RFパワーよりも高い800Wであり、それにより、基板の上面及びトレンチの底面に損傷を生じさせ、膜品質を低下させた。反応チャンバから基板を取り出した後、基板は、以下の表6に示される条件下でウェットエッチングされる。
PEALDによってトレンチを有するSi基板(Φ300mm)にSiN膜を形成し、その1つのサイクルは、図1Aに示されるPEALD装置及び図1Bに示されるガス供給システム(FPS)を用いて表7(堆積サイクル)に示される条件下で行われる。
Claims (16)
- 基板の上面に形成されたトレンチにSi−N結合を含む誘電体膜によって構成される層構造を製造する方法であって、
(i)前記上面並びに前記トレンチの底面及び側壁にSi−N結合を含む前記誘電体膜を同時に形成するステップであって、前記上面及び前記底面に形成された前記誘電体膜の上部/底部、並びに前記側壁に形成された前記誘電体膜の側壁部は、2つの電極間に電圧を印加することによって励起されるプラズマの衝突によって異なる化学物質耐性を付与され、前記基板は、前記2つの電極間に前記2つの電極と平行に置かれる、ステップと、
(ii)前記異なる化学物質耐性に従って前記誘電体膜の前記上部/底部及び前記側壁部の一方を他方よりも圧倒的に除去するウェットエッチングによって、前記誘電体膜の前記上部/底部及び前記側壁部の両方ではなく、いずれか一方を実質的に除去するステップと、
を備え、
前記プラズマは、RFパワーを前記2つの電極の一方に印加することによって励起される容量結合プラズマ(capacitively coupled plasma(CCP))で、
前記RFパワーは、前記誘電体膜の前記上部/底部と前記誘電体膜の前記側壁部との化学物質耐性が実質的に等しくなる基準RFパワーより高く又は低くする、方法。 - 前記プラズマは、Ar、N2又はO2のプラズマである請求項1に記載の方法。
- 前記RFパワーは、基準RFパワーよりも高く、前記ウェットエッチングは、前記誘電体膜の前記側壁部に対して選択的に前記誘電体膜の前記上部/底部を除去する請求項1に記載の方法。
- 前記ステップ(i)及び(ii)の前に、前記基準RFパワーを決定するために、
前記RFパワーが変数として変更されることを除いて前記ステップ(i)と同一の条件下で誘電体膜を同時に形成するステップと、
前記ステップ(ii)と同一の条件のウェットエッチングによって前記誘電体膜の前記上部/底部及び前記側壁部の両方ではなく、いずれか一方を実質的に除去するステップと、を繰り返すステップを更に備える請求項1に記載の方法。 - 前記誘電体膜は、SiN膜である請求項1に記載の方法。
- 前記ウェットエッチングは、フッ化水素(HF)の溶液を用いて行われる請求項1に記載の方法。
- 前記ステップ(i)は、
その上面に前記トレンチを有する前記基板を前記2つの電極間に配置するステップと、
反応ガスとして窒素ガスを用いてプラズマエンハンスト原子層堆積(PEALD)によって前記基板上に前記誘電体膜を堆積するステップであって、前記プラズマは、前記PEALDの各サイクルにおいて前記2つの電極の一方にRFパワーを印加することによって励起される容量結合プラズマ(CCP)であり、前記RFパワーは、前記誘電体膜の前記上部/底部と前記誘電体膜の前記側壁部との化学物質耐性が実質的に等しくなる基準RFパワーよりも高く、前記ステップ(ii)の前記ウェットエッチングは、前記誘電体膜の前記側壁部に対して選択的に前記誘電体膜の前記上部/底部を除去する、ステップと、
を備える請求項1に記載の方法。 - 前記PEALDは、前駆体としてアミノシラン、ハロゲン化シラン、モノシラン又はジシランを用いる請求項7に記載の方法。
- 前記ステップ(i)及び(ii)の間にはアニーリングは行われない請求項7に記載の方法。
- 前記ステップ(i)は、
その上面に前記トレンチを有する前記基板を前記2つの電極間に配置するステップと、
反応ガスとして窒素ガスを用いてプラズマエンハンスト原子層堆積(PEALD)によって前記基板上に前記誘電体膜を堆積するステップであって、前記プラズマは、前記PEALDの各サイクルにおいて前記2つの電極の一方にRFパワーを印加することによって励起される容量結合プラズマ(CCP)であり、前記RFパワーは、前記誘電体膜の前記上部/底部と前記誘電体膜の前記側壁部との化学物質耐性が実質的に等しくなる基準RFパワーよりも低く、前記ステップ(ii)の前記ウェットエッチングは、前記誘電体膜の前記上部/底部に対して選択的に前記誘電体膜の前記側壁部を除去する、ステップと、
を備える請求項1に記載の方法。 - 前記PEALDは、前駆体としてアミノシラン、ハロゲン化シラン、モノシラン又はジシランを用いる請求項10に記載の方法。
- 前記ステップ(i)は、
その上面に前記トレンチを有する前記基板上に前記誘電体膜を堆積するステップと、
前記基板を前記2つの電極間に配置するステップと、
膜を堆積せずに、堆積された前記誘電体膜の表面を処理するために前記電極間にプラズマを励起するステップであって、前記プラズマは、前記2つの電極の一方にRFパワーを印加することによって励起される容量結合プラズマ(CCP)であり、前記RFパワーは、前記誘電体膜の前記上部/底部と前記誘電体膜の前記側壁部との化学物質耐性が実質的に等しくなる基準RFパワーよりも高く、前記ステップ(ii)の前記ウェットエッチングは、前記誘電体膜の前記側壁部に対して選択的に前記誘電体膜の前記上部/底部を除去する、ステップと、
を備える請求項1に記載の方法。 - 前記誘電体膜は、原子層堆積(ALD)によって前記基板上に堆積される請求項12に記載の方法。
- 前記ALDは、プラズマエンハンスト原子層堆積(PEALD)であり、前記ステップ(i)は、その全体が同一チャンバで行われる請求項13に記載の方法。
- 前記誘電体膜の堆積後、かつ前記ステップ(ii)の前にアニーリングは行われない請求項12に記載の方法。
- 堆積された前記誘電体膜は、10nm以下の厚さを有する請求項12に記載の方法。
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