ES2103976T3 - Polimeros olefinicos lineales sustancialmente elasticos. - Google Patents

Polimeros olefinicos lineales sustancialmente elasticos.

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Publication number
ES2103976T3
ES2103976T3 ES92922757T ES92922757T ES2103976T3 ES 2103976 T3 ES2103976 T3 ES 2103976T3 ES 92922757 T ES92922757 T ES 92922757T ES 92922757 T ES92922757 T ES 92922757T ES 2103976 T3 ES2103976 T3 ES 2103976T3
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ES
Spain
Prior art keywords
linear
polymers
beginning
equal
less
Prior art date
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Expired - Lifetime
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ES92922757T
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English (en)
Inventor
Shih-Yaw Lai
John R Wilson
Georges W Knight
James C Stevens
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
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Dow Chemical Co
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Filing date
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Priority claimed from US07/776,130 external-priority patent/US5272236A/en
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Application granted granted Critical
Publication of ES2103976T3 publication Critical patent/ES2103976T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G83/00Macromolecular compounds not provided for in groups C08G2/00 - C08G81/00
    • C08G83/002Dendritic macromolecules
    • C08G83/003Dendrimers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/022Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/15Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor incorporating preformed parts or layers, e.g. extrusion moulding around inserts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • B32B27/322Layered products comprising a layer of synthetic resin comprising polyolefins comprising halogenated polyolefins, e.g. PTFE
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
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    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
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    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0807Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815Copolymers of ethene with aliphatic 1-olefins
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    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0018Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular optical properties, e.g. fluorescent or phosphorescent
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    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
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    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
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    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
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    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
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    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
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    • C08J2303/00Characterised by the use of starch, amylose or amylopectin or of their derivatives or degradation products
    • C08J2303/04Starch derivatives
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    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04Homopolymers or copolymers of ethene
    • C08J2323/08Copolymers of ethene
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    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Abstract

SE PRESENTAN POLIMEROS DE OLEFINAS LINEALES SUSTANCIALMENTE ELASTICOS QUE TIENEN UNA PROCESABILIDAD SIMILAR AL POLIETILENO DE BAJA DENSIDAD ALTAMENTE RAMIFICADO (LDPE), PERO CON LA FORTALEZA Y RESISTENCIA DEL POLIETILENO DE BAJA DENSIDAD LINEAL (LLDPE). LOS POLIMEROS TIENEN INDICES DE PROCESAMIENTO (PI''S) MENORES O IGUALES AL 70% DE AQUELLOS DE POLIMERO DE OLEFINA LINEAL COMPARATIVA Y UNA VELOCIDAD DE CIZALLA CRITICA AL COMIENZO DE FRACTURA POR FUNDIDO DE SUPERFICIE AL MENOS UN 50% MAYOR QUE LA VELOCIDAD DE CIZALLA CRITICA AL COMIENZO DE LA FRACTURA DE SUPERFICIE FUNDIDA DE UN POLIMERO DE OLEFINA LINEAL TRADICIONAL AL MISMO I2 Y MWMN. LOS NUEVOS POLIMEROS PUEDEN TENER TAMBIEN DESDE 0,01 A 3 RAMIFICACIONES DE CADENA LARGA/1000 CARBONES A LO LARGO DEL ESQUELETO DEL POLIMERO Y TENER VISCOSIDAD DE CIZALLA MAYOR DE BAJO CERO Y VISCOSIDAD DE CIZALLAMIENTO ALTA, MENOR QUE LOS POLIMEROS DE OLEFINAS LINEALES COMPARATIVAS. LOS NUEVOS POLIMEROS PUEDEN SER TAMBIEN CARACTERIZADOS POR TENER UNA PROPORCION DE CAUDAL FUNDIDO, I10/I2 (MAYOR O IGUAL) 5,63, UNA DISTRIBUCION DE PESO MOLECULAR, MW/MN, DEFINIDA POR LA ECUACION: MW/MN (MENOR O IGUAL) (I10/I2) IZALLAMIENTO CRITICO AL COMIENZO DE FRACTURA DE FUNDIDO EN BRUTO MAYOR DE 4 X 106 DYNE/CM (AL CUADRADO) .
ES92922757T 1991-10-15 1992-10-15 Polimeros olefinicos lineales sustancialmente elasticos. Expired - Lifetime ES2103976T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/776,130 US5272236A (en) 1991-10-15 1991-10-15 Elastic substantially linear olefin polymers
US07/939,281 US5278272A (en) 1991-10-15 1992-09-02 Elastic substantialy linear olefin polymers

Publications (1)

Publication Number Publication Date
ES2103976T3 true ES2103976T3 (es) 1997-10-01

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ID=27119153

Family Applications (2)

Application Number Title Priority Date Filing Date
ES97200460T Expired - Lifetime ES2127030T3 (es) 1991-10-15 1992-10-15 Procedimiento para la preparacion de polimeros de etileno.
ES92922757T Expired - Lifetime ES2103976T3 (es) 1991-10-15 1992-10-15 Polimeros olefinicos lineales sustancialmente elasticos.

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ES97200460T Expired - Lifetime ES2127030T3 (es) 1991-10-15 1992-10-15 Procedimiento para la preparacion de polimeros de etileno.

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US (6) US5278272A (es)
EP (4) EP0783006B1 (es)
JP (1) JP2963199B2 (es)
KR (1) KR100262024B1 (es)
CA (1) CA2120766C (es)
DE (4) DE9219173U1 (es)
ES (2) ES2127030T3 (es)
FI (2) FI112663B (es)
TW (2) TW448186B (es)
WO (1) WO1993008221A2 (es)

Families Citing this family (1498)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5621126A (en) * 1987-01-30 1997-04-15 Exxon Chemical Patents Inc. Monocyclopentadienyl metal compounds for ethylene-α-olefin-copolymer production catalysts
US5384299A (en) * 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5408017A (en) * 1987-01-30 1995-04-18 Exxon Chemical Patents Inc. High temperature polymerization process using ionic catalysts to produce polyolefins
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EP0899279A3 (en) 1999-11-10
KR100262024B1 (ko) 2000-07-15
DE69220077D1 (de) 1997-07-03
FI112663B (fi) 2003-12-31
US6348555B1 (en) 2002-02-19
JPH07500622A (ja) 1995-01-19
EP0899278A3 (en) 1999-11-10
EP0608369B1 (en) 1997-05-28
US5278272A (en) 1994-01-11
CA2120766C (en) 2008-07-08
CA2120766A1 (en) 1993-04-29
FI941727A (fi) 1994-05-31
EP0783006B1 (en) 1999-01-20
WO1993008221A3 (en) 1993-08-05
DE9219173U1 (de) 1999-03-25
US6534612B1 (en) 2003-03-18
DE69228265D1 (de) 1999-03-04
DE9219090U1 (de) 1997-09-25
EP0899278A2 (en) 1999-03-03
US6780954B2 (en) 2004-08-24
FI20030362A (fi) 2003-03-11
US20030078357A1 (en) 2003-04-24
EP0783006A2 (en) 1997-07-09
ES2127030T3 (es) 1999-04-01
TW448186B (en) 2001-08-01
FI941727A0 (fi) 1994-04-14
EP0899279A2 (en) 1999-03-03
EP0608369A1 (en) 1994-08-03
US6506867B1 (en) 2003-01-14
EP0783006A3 (en) 1997-07-16
DE69220077T2 (de) 1997-11-20
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US20030195320A1 (en) 2003-10-16
TW279867B (es) 1996-07-01
DE69228265T2 (de) 1999-06-02

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