TW370537B - Process for the preparation of an ethylene/α-olefin copolymer - Google Patents
Process for the preparation of an ethylene/α-olefin copolymerInfo
- Publication number
- TW370537B TW370537B TW086104786A TW86104786A TW370537B TW 370537 B TW370537 B TW 370537B TW 086104786 A TW086104786 A TW 086104786A TW 86104786 A TW86104786 A TW 86104786A TW 370537 B TW370537 B TW 370537B
- Authority
- TW
- Taiwan
- Prior art keywords
- ethylene
- transition metal
- preparation
- olefin copolymer
- metal complex
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63908—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
Abstract
The invention relates to process for the preparation of an ethylene/α-olefin copolymer and which comprises the use of a transition metal complex and a catalyst. The invention is characterized in that the polymerization is conducted using a transition metal complex consisting of a reduced transition metal complex, chosen from groups 4-6 of the periodic system of the element, with a multidentate monoanionic ligand and with two monoanionic ligands, at a temperature of between 75 and 220 DEG C. In particular the reduced transition metal in the complex is titanium (Ti).
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP96201114 | 1996-05-03 |
Publications (1)
Publication Number | Publication Date |
---|---|
TW370537B true TW370537B (en) | 1999-09-21 |
Family
ID=8223923
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW086104786A TW370537B (en) | 1996-05-03 | 1997-04-14 | Process for the preparation of an ethylene/α-olefin copolymer |
Country Status (10)
Country | Link |
---|---|
EP (1) | EP0896599A1 (en) |
JP (1) | JP2000509741A (en) |
KR (1) | KR20000010946A (en) |
AU (1) | AU2411997A (en) |
BR (1) | BR9709194A (en) |
CA (1) | CA2253542A1 (en) |
EA (1) | EA199800977A1 (en) |
ID (1) | ID16857A (en) |
TW (1) | TW370537B (en) |
WO (1) | WO1997042241A1 (en) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000001766A1 (en) | 1998-07-01 | 2000-01-13 | Exxon Chemical Patents Inc. | Elastic blends comprising crystalline polymer and crystallizable polymers of propylene |
US6403773B1 (en) | 1998-09-30 | 2002-06-11 | Exxon Mobil Chemical Patents Inc. | Cationic group 3 catalyst system |
EP1390417B1 (en) | 2001-04-12 | 2010-10-20 | ExxonMobil Chemical Patents Inc. | Process for polymerizing propylene and ethylene in solution |
US6943215B2 (en) | 2001-11-06 | 2005-09-13 | Dow Global Technologies Inc. | Impact resistant polymer blends of crystalline polypropylene and partially crystalline, low molecular weight impact modifiers |
KR100830317B1 (en) * | 2001-12-27 | 2008-05-16 | 삼성토탈 주식회사 | Method of polymerization or copolymerization of ethylene using cyclopentadiene and carbodiimde ligand chelated catalyst |
JP4728643B2 (en) | 2002-10-02 | 2011-07-20 | ダウ グローバル テクノロジーズ エルエルシー | Liquid and gel-like low molecular weight ethylene polymers |
CN100374494C (en) | 2002-10-17 | 2008-03-12 | 陶氏环球技术公司 | Highly filled polymer compositions |
ES2337936T3 (en) | 2003-08-19 | 2010-04-30 | Dow Global Technologies Inc. | SUITABLE INTERPOLIMEROS FOR USE IN THERMOPLASTIC TAILS AND PROCESSES TO PREPARE THEM. |
JP2012176915A (en) * | 2011-02-28 | 2012-09-13 | Ube Industries Ltd | Alkylcyclopentadiene compound and method for producing the same |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NZ235032A (en) * | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
US5278272A (en) * | 1991-10-15 | 1994-01-11 | The Dow Chemical Company | Elastic substantialy linear olefin polymers |
US5374696A (en) * | 1992-03-26 | 1994-12-20 | The Dow Chemical Company | Addition polymerization process using stabilized reduced metal catalysts |
ATE164858T1 (en) * | 1994-10-31 | 1998-04-15 | Dsm Nv | CATALYTIC COMPOSITION AND METHOD FOR OLEFIN POLYMERIZATION |
-
1997
- 1997-04-14 TW TW086104786A patent/TW370537B/en active
- 1997-05-01 EA EA199800977A patent/EA199800977A1/en unknown
- 1997-05-01 JP JP9539793A patent/JP2000509741A/en active Pending
- 1997-05-01 KR KR1019980709095A patent/KR20000010946A/en not_active Application Discontinuation
- 1997-05-01 AU AU24119/97A patent/AU2411997A/en not_active Abandoned
- 1997-05-01 WO PCT/NL1997/000243 patent/WO1997042241A1/en not_active Application Discontinuation
- 1997-05-01 EP EP97919763A patent/EP0896599A1/en not_active Withdrawn
- 1997-05-01 BR BR9709194A patent/BR9709194A/en unknown
- 1997-05-01 CA CA002253542A patent/CA2253542A1/en not_active Abandoned
- 1997-05-02 ID IDP971471A patent/ID16857A/en unknown
Also Published As
Publication number | Publication date |
---|---|
WO1997042241A1 (en) | 1997-11-13 |
JP2000509741A (en) | 2000-08-02 |
KR20000010946A (en) | 2000-02-25 |
BR9709194A (en) | 1999-08-10 |
ID16857A (en) | 1997-11-13 |
AU2411997A (en) | 1997-11-26 |
CA2253542A1 (en) | 1997-11-13 |
EA199800977A1 (en) | 1999-04-29 |
EP0896599A1 (en) | 1999-02-17 |
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