TW370537B - Process for the preparation of an ethylene/α-olefin copolymer - Google Patents

Process for the preparation of an ethylene/α-olefin copolymer

Info

Publication number
TW370537B
TW370537B TW086104786A TW86104786A TW370537B TW 370537 B TW370537 B TW 370537B TW 086104786 A TW086104786 A TW 086104786A TW 86104786 A TW86104786 A TW 86104786A TW 370537 B TW370537 B TW 370537B
Authority
TW
Taiwan
Prior art keywords
ethylene
transition metal
preparation
olefin copolymer
metal complex
Prior art date
Application number
TW086104786A
Other languages
Chinese (zh)
Inventor
Jacob Renkema
Beek Johannus Antonius Maria Van
Bernardus Johanna Muskens
Doremaele Gerardus Henricus Josephus Van
Original Assignee
Dsm Nv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dsm Nv filed Critical Dsm Nv
Application granted granted Critical
Publication of TW370537B publication Critical patent/TW370537B/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63908—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

The invention relates to process for the preparation of an ethylene/α-olefin copolymer and which comprises the use of a transition metal complex and a catalyst. The invention is characterized in that the polymerization is conducted using a transition metal complex consisting of a reduced transition metal complex, chosen from groups 4-6 of the periodic system of the element, with a multidentate monoanionic ligand and with two monoanionic ligands, at a temperature of between 75 and 220 DEG C. In particular the reduced transition metal in the complex is titanium (Ti).
TW086104786A 1996-05-03 1997-04-14 Process for the preparation of an ethylene/α-olefin copolymer TW370537B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP96201114 1996-05-03

Publications (1)

Publication Number Publication Date
TW370537B true TW370537B (en) 1999-09-21

Family

ID=8223923

Family Applications (1)

Application Number Title Priority Date Filing Date
TW086104786A TW370537B (en) 1996-05-03 1997-04-14 Process for the preparation of an ethylene/α-olefin copolymer

Country Status (10)

Country Link
EP (1) EP0896599A1 (en)
JP (1) JP2000509741A (en)
KR (1) KR20000010946A (en)
AU (1) AU2411997A (en)
BR (1) BR9709194A (en)
CA (1) CA2253542A1 (en)
EA (1) EA199800977A1 (en)
ID (1) ID16857A (en)
TW (1) TW370537B (en)
WO (1) WO1997042241A1 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1098934A1 (en) 1998-07-01 2001-05-16 Exxon Chemical Patents Inc. Elastic blends comprising crystalline polymer and crystallizable polymers of propylene
US6403773B1 (en) 1998-09-30 2002-06-11 Exxon Mobil Chemical Patents Inc. Cationic group 3 catalyst system
EP1390417B1 (en) 2001-04-12 2010-10-20 ExxonMobil Chemical Patents Inc. Process for polymerizing propylene and ethylene in solution
US6943215B2 (en) 2001-11-06 2005-09-13 Dow Global Technologies Inc. Impact resistant polymer blends of crystalline polypropylene and partially crystalline, low molecular weight impact modifiers
KR100830317B1 (en) * 2001-12-27 2008-05-16 삼성토탈 주식회사 Method of polymerization or copolymerization of ethylene using cyclopentadiene and carbodiimde ligand chelated catalyst
DE60304595T3 (en) 2002-10-02 2012-01-12 Dow Global Technologies Inc. LIQUID AND LIQUID LOW-MOLECULAR ETHYLENE POLYMERS
DE60322410D1 (en) 2002-10-17 2008-09-04 Dow Global Technologies Inc HIGH-FILLED POLYMER COMPOSITIONS
US7531601B2 (en) 2003-08-19 2009-05-12 Dow Global Technologies, Inc. Interpolymers suitable for use in hot melt adhesives and processes to prepare same
JP2012176915A (en) * 2011-02-28 2012-09-13 Ube Industries Ltd Alkylcyclopentadiene compound and method for producing the same

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NZ235032A (en) * 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5278272A (en) * 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers
US5374696A (en) * 1992-03-26 1994-12-20 The Dow Chemical Company Addition polymerization process using stabilized reduced metal catalysts
ES2116776T3 (en) * 1994-10-31 1998-07-16 Dsm Nv CATALYTIC COMPOSITION AND PROCEDURE FOR THE POLYMERIZATION OF AN OLEPHINE.

Also Published As

Publication number Publication date
KR20000010946A (en) 2000-02-25
EP0896599A1 (en) 1999-02-17
WO1997042241A1 (en) 1997-11-13
CA2253542A1 (en) 1997-11-13
AU2411997A (en) 1997-11-26
BR9709194A (en) 1999-08-10
EA199800977A1 (en) 1999-04-29
ID16857A (en) 1997-11-13
JP2000509741A (en) 2000-08-02

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