ES2068821T3 - Polimero bloque dieno y composicion de polimero. - Google Patents

Polimero bloque dieno y composicion de polimero.

Info

Publication number
ES2068821T3
ES2068821T3 ES88119810T ES88119810T ES2068821T3 ES 2068821 T3 ES2068821 T3 ES 2068821T3 ES 88119810 T ES88119810 T ES 88119810T ES 88119810 T ES88119810 T ES 88119810T ES 2068821 T3 ES2068821 T3 ES 2068821T3
Authority
ES
Spain
Prior art keywords
block
polymer
degrees
dieno
melting point
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES88119810T
Other languages
English (en)
Inventor
Yasuo Hattori
Yuichi Moakuresuto Ta Kitagawa
Akira Saito
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Asahi Kasei Corp
Asahi Chemical Industry Co Ltd
Original Assignee
Asahi Chemical Industry Co Ltd
Asahi Kasei Kogyo KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP62297475A external-priority patent/JPH01139608A/ja
Priority claimed from JP63014500A external-priority patent/JPH0784506B2/ja
Priority claimed from JP4459788A external-priority patent/JPH0794515B2/ja
Priority claimed from JP5359788A external-priority patent/JPH0794516B2/ja
Priority claimed from JP5359888A external-priority patent/JPH0794517B2/ja
Priority claimed from JP63125850A external-priority patent/JPH01297415A/ja
Application filed by Asahi Chemical Industry Co Ltd, Asahi Kasei Kogyo KK filed Critical Asahi Chemical Industry Co Ltd
Application granted granted Critical
Publication of ES2068821T3 publication Critical patent/ES2068821T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

UN POLIMERO DIENO EN BLOQUE QUE CONTIENE (A) UN BLOQUE POLIBUTADIENO RESINOSO QUE TIENE UNA TEMPERATURA DE TRANSICION A CRISTAL DE -80 (GRADOS) C O MENOS, UN PUNTO DE FUSION CRISTALINO DE 30 A 130 (GRADOS) C, 80% A 93% DE UNIDADES TRANS, 5 A 15% DE UNIDADES CIS, Y DE 1 A 10% DE UNIDADES VINILO, UN PESO MOLECULAR DE 10000 A 200000 Y UN PESO DISTRIBUCION MW/MN DE 1.2 A 4 Y (B) UN BLOQUE GOMOSO DIENO CONJUGADO QUE TIENE UNA TEMPERATURA DE TRANSICION A CRISTAL DE -20 (GRADOS) C O MENOS Y O NO TIENE UN PUNTO DE FUSION CRISTALINO O TIENE UN PUNTO DE FUSION CRISTALINO DE 0 (GRADOS) C O MENOS, DONDE EL PROMEDIO DE LOS BLOQUES (A) Y (B) ES DE 2 A 80:98 A 20 (PROMEDIO EN PESO), EL PESO MOLECULAR ES DE 20000 A 500000 Y LA DISTRIBUCION DEL PESO MOLECULAR MW/MN ES 1:1 A 5 Y LA COMPOSICION DEL POLIMERO CONTIENE LO MISMO.
ES88119810T 1987-11-27 1988-11-28 Polimero bloque dieno y composicion de polimero. Expired - Lifetime ES2068821T3 (es)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP62297475A JPH01139608A (ja) 1987-11-27 1987-11-27 複合重合体の製造方法
JP63014500A JPH0784506B2 (ja) 1988-01-27 1988-01-27 耐衝撃性ポリスチレン系樹脂の製造方法
JP4459788A JPH0794515B2 (ja) 1988-02-29 1988-02-29 複合重合体及び複合重合体組成物
JP5359788A JPH0794516B2 (ja) 1988-03-09 1988-03-09 ブタジエン系複合重合体及び複合重合体組成物
JP5359888A JPH0794517B2 (ja) 1988-03-09 1988-03-09 トランスブタジエン系複合重合体及び複合重合体組成物
JP63125850A JPH01297415A (ja) 1988-05-25 1988-05-25 ジエン系ブロックポリマー

Publications (1)

Publication Number Publication Date
ES2068821T3 true ES2068821T3 (es) 1995-05-01

Family

ID=27548513

Family Applications (1)

Application Number Title Priority Date Filing Date
ES88119810T Expired - Lifetime ES2068821T3 (es) 1987-11-27 1988-11-28 Polimero bloque dieno y composicion de polimero.

Country Status (6)

Country Link
US (1) US5134199A (es)
EP (1) EP0318052B1 (es)
KR (1) KR920005531B1 (es)
DE (1) DE3853340T2 (es)
ES (1) ES2068821T3 (es)
HK (1) HK1000667A1 (es)

Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1276867B1 (it) * 1994-11-10 1997-11-03 Tecnofilm Spa Composizione termoplastica ad elevata resistenza all'abrasione
DE19638255A1 (de) * 1996-09-19 1998-03-26 Basf Ag Thermoplastische Formmassen
NL1007534C2 (nl) * 1996-12-03 1999-05-12 Japan Elastomer Co Rubberachtig polymeer alsmede werkwijze voor de bereiding daarvan.
TW345589B (en) * 1997-12-13 1998-11-21 Taiwan Synthetic Rubber Corp Tread rubber suitable for high performance tire
US6271313B1 (en) 1998-12-21 2001-08-07 The Goodyear Tire & Rubber Company Styrene-butadiene block copolymer
DE60027704T3 (de) * 1999-09-27 2012-04-05 Asahi Kasei Kabushiki Kaisha Kautschukmischung
US6433105B1 (en) 2000-06-09 2002-08-13 Bridgestone Corporation Process for desolventizing low molecular weight diene polymers
ATE282650T1 (de) 2000-10-17 2004-12-15 Michelin Soc Tech Verfahren zur herstellung eines dienelastomers durch anionische polymerisation
CN100516103C (zh) * 2001-10-31 2009-07-22 米其林技术公司 轮胎胎面组合物用嵌段共聚物的制备方法,和这样的共聚物
JP4225065B2 (ja) * 2002-02-01 2009-02-18 日本ゼオン株式会社 有機粒子および粉体塗料
FR2854635B1 (fr) * 2003-05-07 2006-07-14 Michelin Soc Tech Procede de preparation de copolymeres a blocs pour compositions de bande de roulement de pneumatique, et ces copolymeres
FR2854636B1 (fr) 2003-05-07 2006-07-14 Michelin Soc Tech Procede de preparation de copolymeres a blocs pour compositions de bande de roulement de pneumatique, et ces copolymeres
US7037980B2 (en) * 2003-11-10 2006-05-02 Chevron Phillips Chemical Company, Lp Monovinylarene/conjugated diene copolymers having lower glass transition temperatures
US7193014B2 (en) * 2004-02-20 2007-03-20 Chevron Phillips Chemical Company, Lp Binary and ternary blends comprising monovinylarene/conjugated diene block copolymers and monovinylarene/alkyl (meth)acrylate copolymers
US7351767B2 (en) * 2004-02-20 2008-04-01 Chevron Phillips Chemical Company, Lp Composition for monovinylrenic-based shrink label films
JP5587608B2 (ja) * 2006-12-19 2014-09-10 スティロン ヨーロッパ ゲゼルシャフト ミット ベシュレンクテル ハフツング スルフィド変性弾性ポリマー
SG179498A1 (en) * 2007-03-28 2012-04-27 Denki Kagaku Kogyo Kk Material for md shrink and md shrink film
HUE029872T2 (en) * 2008-06-06 2017-04-28 Trinseo Europe Gmbh Modified elastomeric polymers
JP5591816B2 (ja) * 2008-11-11 2014-09-17 スティロン ヨーロッパ ゲゼルシャフト ミット ベシュレンクテル ハフツング 変性ポリマーの製造からシラノールを除去する方法
US20100272975A1 (en) * 2009-04-23 2010-10-28 Chevron Phillips Chemical Company Lp System and method for the production and use of lamination films
WO2011076377A1 (en) 2009-12-21 2011-06-30 Styron Europe Gmbh Modified polymer compositions
KR101831999B1 (ko) 2009-12-21 2018-02-23 트린세오 유럽 게엠베하 개질된 중합체 조성물
TW201211083A (en) * 2010-06-15 2012-03-16 Styron Europe Gmbh Low vinyl styrene-butadiene polymers and methods of making the same
WO2012041804A2 (en) 2010-09-30 2012-04-05 Styron Europe Gmbh Polymer compositions
ITMI20111198A1 (it) * 2011-06-29 2012-12-30 Polimeri Europa Spa "procedimento per la preparazione di copolimeri di 1,3-butadiene e stirene e loro impiego in composizioni elastomeriche vulcanizzabili"
RU2609166C2 (ru) 2012-09-14 2017-01-30 ТРИНСЕО ЮРОП ГмбХ Полимеры, модифицированные аминосиланом
CN105431463B (zh) 2013-07-22 2019-02-01 盛禧奥欧洲有限公司 聚合引发剂
JP2017526645A (ja) 2014-07-14 2017-09-14 トリンゼオ ヨーロッパ ゲゼルシャフト ミット ベシュレンクテル ハフツング アニオン重合のためのアミノシリル置換ジアリールエテン化合物
PL3045495T3 (pl) * 2015-01-14 2017-10-31 Trinseo Europe Gmbh Funkcjonalizowane kompozycje polimerów elastomerowych, sposoby ich przygotowywania oraz ich usieciowane kompozycje kauczukowe
US9416212B1 (en) * 2015-08-17 2016-08-16 The Goodyear Tire & Rubber Company Pneumatic tire with block copolymer
EP3133093A1 (en) 2015-08-20 2017-02-22 Trinseo Europe GmbH Elastomeric polymer
EP3363804A1 (en) 2017-02-20 2018-08-22 Trinseo Europe GmbH Metallated benzylsilanes and their use as polymerization initiators
US11608404B2 (en) 2020-05-22 2023-03-21 Kraton Corporation Block copolymers and polymer modified bitumen therefrom

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1271265A (en) * 1968-06-08 1972-04-19 Bridgestone Tire Co Ltd Method of preparing conjugated diene polymers using catalysts based on organolithium compounds
US3726824A (en) * 1970-09-16 1973-04-10 Dow Chemical Co Preparation of film-forming latexes of polyvinylaromatic-polydiene block copolymers
JPS4929386A (es) * 1972-07-19 1974-03-15
JPS5535043B2 (es) * 1973-08-06 1980-09-11
JPS5642608B2 (es) * 1974-03-14 1981-10-06
JPS5167387A (en) * 1974-12-09 1976-06-10 Mitsui Petrochemical Ind Kyoyakujenjugotaino seizohoho
JPS5792014A (en) * 1980-11-27 1982-06-08 Sumitomo Rubber Ind Ltd Conjugated diene block polymer
JPS57100112A (en) * 1980-12-16 1982-06-22 Asahi Chem Ind Co Ltd Perfectly random styrene-butadiene copolymer rubber
US4433109A (en) * 1980-12-17 1984-02-21 Japan Synthetic Rubber Co., Ltd. Styrene-butadiene block copolymer
CA1212932A (en) * 1982-04-01 1986-10-21 Derek K. Jenkins Polymerisation of conjugated dienes
JPS6010411A (ja) * 1983-06-29 1985-01-19 Fujitsu Ltd フロツピ−デイスク装置における磁気ヘツドクリ−ニング用デイスク及び磁気ヘツドのクリ−ニング方法
JPS60104111A (ja) * 1983-11-11 1985-06-08 Asahi Chem Ind Co Ltd 耐衝撃性ポリスチレン系樹脂およびその製造法
FR2567135B1 (fr) * 1984-07-03 1989-01-13 Asahi Chemical Ind Polymere ou copolymere de butadiene et procede de preparation
JPH0662727B2 (ja) * 1984-08-27 1994-08-17 日本合成ゴム株式会社 ゴム組成物
US4669518A (en) * 1985-04-15 1987-06-02 Gencorp Inc. Tire tread having high trans butadiene based elastomeric block copolymers and blends
US4616065A (en) * 1985-04-15 1986-10-07 Gencorp Inc. High trans butadiene based elastomeric block copolymers and blends

Also Published As

Publication number Publication date
EP0318052A3 (en) 1991-02-20
EP0318052A2 (en) 1989-05-31
KR890008191A (ko) 1989-07-10
US5134199A (en) 1992-07-28
DE3853340T2 (de) 1996-03-28
HK1000667A1 (en) 1998-04-17
KR920005531B1 (ko) 1992-07-06
EP0318052B1 (en) 1995-03-15
DE3853340D1 (de) 1995-04-20

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