JP4918360B2 - 耐候性表層を有する多層シート - Google Patents
耐候性表層を有する多層シート Download PDFInfo
- Publication number
- JP4918360B2 JP4918360B2 JP2006534442A JP2006534442A JP4918360B2 JP 4918360 B2 JP4918360 B2 JP 4918360B2 JP 2006534442 A JP2006534442 A JP 2006534442A JP 2006534442 A JP2006534442 A JP 2006534442A JP 4918360 B2 JP4918360 B2 JP 4918360B2
- Authority
- JP
- Japan
- Prior art keywords
- polymer layer
- layer
- weight
- film
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
- B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/15—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state
- B32B37/153—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state at least one layer is extruded and immediately laminated while in semi-molten state
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/712—Weather resistant
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2327/00—Polyvinylhalogenides
- B32B2327/12—Polyvinylhalogenides containing fluorine
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2605/00—Vehicles
- B32B2605/08—Cars
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31909—Next to second addition polymer from unsaturated monomers
- Y10T428/31913—Monoolefin polymer
- Y10T428/3192—Next to vinyl or vinylidene chloride polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31935—Ester, halide or nitrile of addition polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31938—Polymer of monoethylenically unsaturated hydrocarbon
Landscapes
- Laminated Bodies (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Description
次の耐候性フィルムを使用して多層シート材料を形成した:本願特許出願人によって販売される、0.2重量%のチヌビン(登録商標)328(上記の)および0.5重量%のキマソーブ(登録商標)119を含有し、約0.008mm厚さであるアクリル接着剤で一面がコートされた公称1ミル(0.0254mm)厚さの溶液キャストPVFフィルムであるテドラー(登録商標)PVFフィルムCUA10AH836。アクリル接着剤は本願特許出願人によって販売される商品コード番号68080である。PVFフィルムを3ミル(0.076mm)厚さの二軸延伸PETフィルム(ポリエチレンテレフタレートフィルム)上へキャストする。
Claims (8)
- ポリフッ化ビニル(PVF)およびポリフッ化ビニリデン(PVDF)の群からの耐候性フィルムを含む第1ポリマー層と、
第1ポリマー層の一面上にコーティングされた接着層と、
(1)酸部分の少なくとも35%が金属イオンで中和された、エチレンと、共重合体の重量を基準にして8〜25重量%のC3〜C8α,βエチレン性不飽和モノカルボン酸との共重合体のアイオノマー樹脂および(2)メタロセン触媒による超低密度ポリエチレン(m−VLDPE)からなる群から選択される、接着層上へ押し出された第2ポリマー層であって、顔料、染料、フレークまたはそれらの任意の混合物を含有する第2ポリマー層と、
を含むまたはそれらから製造されることを特徴とする熱成形可能な多層シート。 - 前記第1ポリマー層がキャストPVFフィルム、キャストPVDFフィルム、またはキャストPVDF/ポリメタクリル酸メチルフィルムを含むことを特徴とする請求項1に記載のシート。
- 前記接着層が、UV吸収剤、UV安定剤およびそれらの混合物を含有するアクリル接着層であることを特徴とする請求項1または2に記載のシート。
- 前記第2ポリマー層が前記第2ポリマー層のポリマーの重量を基準にして0.5〜10重量%の顔料、染料、フレーク、またはそれらの任意の混合物を含むことを特徴とする請求項1〜3のいずれか一項に記載のシート。
- 前記第2ポリマー層がエチレンと、共重合体の重量を基準にして12〜18重量%のメタクリル酸または共重合体の重量を基準にして10〜15重量%のアクリル酸とのアイオノマー樹脂よりなり、および亜鉛、リチウム、ナトリウム、マグネシウム、カルシウムおよびそれらの任意の混合物よりなる群から選択される金属イオンで35〜75%中和され、そして0.4〜4.0のメルトインデックスを有し、および顔料、染料、フレークまたはそれらの任意の混合物を含有することを特徴とする請求項1〜4のいずれか一項に記載のシート。
- 前記第2ポリマー層への押出または積層によって適用された第3層をさらに含むことを特徴とする請求項1〜5のいずれか一項に記載のシート。
- 請求項1〜6のいずれか一項に記載のシートを含む製品であって、自動車部品、自動車パネル、トラック部品、またはトラックパネルであることを特徴とする製品。
- 二軸延伸ポリエステルフィルムの支持フィルムと接触している第1ポリマー層上の接着層表面上へ、第2ポリマー層を押し出して、第2ポリマー層を含む構造体を作り出し、前記構造体を圧力下に2つのロールのニップ中へ通し、そして引き続いて前記第2ポリマー層上へ第3ポリマー層を押し出すまたは積層することを特徴とする請求項6に記載のシートを製造するための方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US50918703P | 2003-10-07 | 2003-10-07 | |
US60/509,187 | 2003-10-07 | ||
PCT/US2004/033438 WO2005035243A1 (en) | 2003-10-07 | 2004-10-07 | Multi-layer sheet having a weatherable surface layer |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2007507376A JP2007507376A (ja) | 2007-03-29 |
JP4918360B2 true JP4918360B2 (ja) | 2012-04-18 |
Family
ID=34434950
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2006534442A Expired - Fee Related JP4918360B2 (ja) | 2003-10-07 | 2004-10-07 | 耐候性表層を有する多層シート |
Country Status (9)
Country | Link |
---|---|
US (2) | US7303793B2 (ja) |
EP (1) | EP1677979B1 (ja) |
JP (1) | JP4918360B2 (ja) |
KR (1) | KR20060134922A (ja) |
CN (1) | CN100575071C (ja) |
CA (1) | CA2541061A1 (ja) |
DE (1) | DE602004021619D1 (ja) |
MX (1) | MXPA06003816A (ja) |
WO (1) | WO2005035243A1 (ja) |
Families Citing this family (14)
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US20060057392A1 (en) * | 2003-10-07 | 2006-03-16 | Smillie Benjamin A | Multi-layer sheet having a weatherable surface layer |
WO2005105439A1 (en) * | 2004-04-14 | 2005-11-10 | Mayco Plastics, Inc. | Article having multilayer film including at least one layer containing metallic components and method of making the same |
WO2005105438A1 (en) * | 2004-04-14 | 2005-11-10 | Mayco Plastics, Inc. | Article having a multilayer film outer skin including at least one layer containing a pigmented layer and method of making the same |
WO2005102001A2 (en) * | 2004-04-14 | 2005-11-03 | Mayco Plastics, Inc. | Polymeric article having a multilyer film including at least one pigmented layer, method of making the same, and pigment additive package and composition suitable for use therein |
US8101267B2 (en) * | 2005-12-30 | 2012-01-24 | E. I. Du Pont De Nemours And Company | Multilayer polymeric laminates and high strength laminates produced therefrom |
US20090151773A1 (en) * | 2007-12-14 | 2009-06-18 | E. I. Du Pont De Nemours And Company | Acid Terpolymer Films or Sheets and Articles Comprising the Same |
CN101582459B (zh) * | 2009-06-26 | 2011-04-13 | 上海海优威电子技术有限公司 | 以改性聚偏氟乙烯合金层为耐候保护层的太阳能电池背板 |
US8858850B2 (en) * | 2009-07-02 | 2014-10-14 | E I Du Pont De Nemours And Company | Process for preparing decorative surface appearance in acrylic material employing anisotropic particles |
DE102009059105A1 (de) | 2009-12-18 | 2011-06-22 | Schott Ag, 55122 | Rückseitenfolie für Solarmodule |
US10065404B2 (en) * | 2011-07-29 | 2018-09-04 | Eastman Chemical Company | In-line lamination of heavy-gauge polymer sheet with a pre-formed polymer film |
KR101489996B1 (ko) * | 2012-09-12 | 2015-02-12 | (주)엘지하우시스 | 고내후성 아크릴계 다층 필름 및 그 제조 방법 |
US10300404B2 (en) * | 2016-06-30 | 2019-05-28 | Exxonmobil Chemical Patents Inc. | Process for the recovering of paraxylene |
US10363691B2 (en) * | 2016-09-06 | 2019-07-30 | Fca Us Llc | Metallic resin molding of annular components without visible knit line |
WO2018051516A1 (ja) * | 2016-09-16 | 2018-03-22 | 河西工業株式会社 | シート材料の製造方法及び混合原料の混合方法 |
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-
2004
- 2004-10-07 MX MXPA06003816A patent/MXPA06003816A/es active IP Right Grant
- 2004-10-07 DE DE200460021619 patent/DE602004021619D1/de active Active
- 2004-10-07 CN CN200480036399A patent/CN100575071C/zh not_active Expired - Fee Related
- 2004-10-07 CA CA 2541061 patent/CA2541061A1/en not_active Abandoned
- 2004-10-07 WO PCT/US2004/033438 patent/WO2005035243A1/en active Application Filing
- 2004-10-07 KR KR1020067006782A patent/KR20060134922A/ko not_active Application Discontinuation
- 2004-10-07 EP EP20040794711 patent/EP1677979B1/en not_active Expired - Fee Related
- 2004-10-07 US US10/960,426 patent/US7303793B2/en active Active
- 2004-10-07 JP JP2006534442A patent/JP4918360B2/ja not_active Expired - Fee Related
-
2007
- 2007-10-04 US US11/867,286 patent/US7488399B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
US7488399B2 (en) | 2009-02-10 |
EP1677979B1 (en) | 2009-06-17 |
KR20060134922A (ko) | 2006-12-28 |
US7303793B2 (en) | 2007-12-04 |
CA2541061A1 (en) | 2005-04-21 |
CN100575071C (zh) | 2009-12-30 |
US20050084697A1 (en) | 2005-04-21 |
JP2007507376A (ja) | 2007-03-29 |
WO2005035243A1 (en) | 2005-04-21 |
MXPA06003816A (es) | 2006-06-14 |
CN1890094A (zh) | 2007-01-03 |
EP1677979A1 (en) | 2006-07-12 |
US20080026228A1 (en) | 2008-01-31 |
DE602004021619D1 (de) | 2009-07-30 |
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