TWM544519U - 氧化物蝕刻選擇性系統 - Google Patents
氧化物蝕刻選擇性系統 Download PDFInfo
- Publication number
- TWM544519U TWM544519U TW105211878U TW105211878U TWM544519U TW M544519 U TWM544519 U TW M544519U TW 105211878 U TW105211878 U TW 105211878U TW 105211878 U TW105211878 U TW 105211878U TW M544519 U TWM544519 U TW M544519U
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- Prior art keywords
- gas
- substrate processing
- plasma
- region
- processing system
- Prior art date
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- 239000000758 substrate Substances 0.000 claims abstract description 129
- 238000012545 processing Methods 0.000 claims abstract description 94
- 238000005192 partition Methods 0.000 claims abstract description 16
- 125000006850 spacer group Chemical group 0.000 claims description 13
- 239000011148 porous material Substances 0.000 claims description 12
- NJPPVKZQTLUDBO-UHFFFAOYSA-N novaluron Chemical compound C1=C(Cl)C(OC(F)(F)C(OC(F)(F)F)F)=CC=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F NJPPVKZQTLUDBO-UHFFFAOYSA-N 0.000 claims description 7
- 239000007921 spray Substances 0.000 claims 2
- 230000005611 electricity Effects 0.000 claims 1
- 239000002002 slurry Substances 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 91
- 239000002243 precursor Substances 0.000 abstract description 54
- 229910052760 oxygen Inorganic materials 0.000 abstract description 52
- 239000001301 oxygen Substances 0.000 abstract description 52
- 150000001875 compounds Chemical class 0.000 abstract description 31
- 238000005530 etching Methods 0.000 abstract description 31
- 239000011737 fluorine Substances 0.000 abstract description 27
- 229910052731 fluorine Inorganic materials 0.000 abstract description 27
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 abstract description 25
- 238000002156 mixing Methods 0.000 abstract description 19
- 239000007795 chemical reaction product Substances 0.000 abstract description 18
- 238000005516 engineering process Methods 0.000 abstract description 9
- 239000007789 gas Substances 0.000 description 106
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 45
- 230000008569 process Effects 0.000 description 42
- 239000001257 hydrogen Substances 0.000 description 32
- 229910052739 hydrogen Inorganic materials 0.000 description 32
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 29
- 150000002500 ions Chemical class 0.000 description 28
- 239000000463 material Substances 0.000 description 28
- MZLGASXMSKOWSE-UHFFFAOYSA-N tantalum nitride Chemical compound [Ta]#N MZLGASXMSKOWSE-UHFFFAOYSA-N 0.000 description 20
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 19
- 238000009826 distribution Methods 0.000 description 16
- 239000012530 fluid Substances 0.000 description 16
- 238000006243 chemical reaction Methods 0.000 description 12
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 11
- 229910052721 tungsten Inorganic materials 0.000 description 11
- 239000010937 tungsten Substances 0.000 description 11
- -1 fluorine radicals Chemical class 0.000 description 10
- 229910052757 nitrogen Inorganic materials 0.000 description 9
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 9
- 229920005591 polysilicon Polymers 0.000 description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- 229910052799 carbon Inorganic materials 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 229910052758 niobium Inorganic materials 0.000 description 8
- 239000010955 niobium Substances 0.000 description 8
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 8
- 150000003254 radicals Chemical class 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 230000009977 dual effect Effects 0.000 description 7
- 239000004065 semiconductor Substances 0.000 description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 6
- 229910052719 titanium Inorganic materials 0.000 description 6
- 239000010936 titanium Substances 0.000 description 6
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 5
- 229910000420 cerium oxide Inorganic materials 0.000 description 5
- 239000010941 cobalt Substances 0.000 description 5
- 229910017052 cobalt Inorganic materials 0.000 description 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 5
- 230000005284 excitation Effects 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 229910052746 lanthanum Inorganic materials 0.000 description 5
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 5
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 5
- 229910052707 ruthenium Inorganic materials 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 229910052715 tantalum Inorganic materials 0.000 description 5
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 5
- 235000012431 wafers Nutrition 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- 229910052684 Cerium Inorganic materials 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 4
- 229910052734 helium Inorganic materials 0.000 description 4
- 239000001307 helium Substances 0.000 description 4
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229910052787 antimony Inorganic materials 0.000 description 3
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 3
- MRPWWVMHWSDJEH-UHFFFAOYSA-N antimony telluride Chemical compound [SbH3+3].[SbH3+3].[TeH2-2].[TeH2-2].[TeH2-2] MRPWWVMHWSDJEH-UHFFFAOYSA-N 0.000 description 3
- 239000012159 carrier gas Substances 0.000 description 3
- 230000005281 excited state Effects 0.000 description 3
- 239000011261 inert gas Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- QKCGXXHCELUCKW-UHFFFAOYSA-N n-[4-[4-(dinaphthalen-2-ylamino)phenyl]phenyl]-n-naphthalen-2-ylnaphthalen-2-amine Chemical compound C1=CC=CC2=CC(N(C=3C=CC(=CC=3)C=3C=CC(=CC=3)N(C=3C=C4C=CC=CC4=CC=3)C=3C=C4C=CC=CC4=CC=3)C3=CC4=CC=CC=C4C=C3)=CC=C21 QKCGXXHCELUCKW-UHFFFAOYSA-N 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- 229910052762 osmium Inorganic materials 0.000 description 3
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 description 3
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 2
- 229910008051 Si-OH Inorganic materials 0.000 description 2
- 229910006358 Si—OH Inorganic materials 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 229910000410 antimony oxide Inorganic materials 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 238000000231 atomic layer deposition Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- XJHCXCQVJFPJIK-UHFFFAOYSA-M caesium fluoride Chemical compound [F-].[Cs+] XJHCXCQVJFPJIK-UHFFFAOYSA-M 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000001312 dry etching Methods 0.000 description 2
- 125000001153 fluoro group Chemical group F* 0.000 description 2
- 229910052732 germanium Inorganic materials 0.000 description 2
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 2
- 229910052735 hafnium Inorganic materials 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 238000009616 inductively coupled plasma Methods 0.000 description 2
- 229910052741 iridium Inorganic materials 0.000 description 2
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 2
- 238000002955 isolation Methods 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229910052756 noble gas Inorganic materials 0.000 description 2
- 150000002835 noble gases Chemical class 0.000 description 2
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 2
- 125000004430 oxygen atom Chemical group O* 0.000 description 2
- 238000005240 physical vapour deposition Methods 0.000 description 2
- MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 description 1
- NZIHMSYSZRFUQJ-UHFFFAOYSA-N 6-chloro-1h-benzimidazole-2-carboxylic acid Chemical compound C1=C(Cl)C=C2NC(C(=O)O)=NC2=C1 NZIHMSYSZRFUQJ-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 229910018557 Si O Inorganic materials 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910008284 Si—F Inorganic materials 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 1
- SPPCMVNDPDQNRG-UHFFFAOYSA-L [F-].[F-].[Sb++] Chemical compound [F-].[F-].[Sb++] SPPCMVNDPDQNRG-UHFFFAOYSA-L 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- IBKBIJITWRZZBB-UHFFFAOYSA-N azanylidynestibane Chemical compound [Sb]#N IBKBIJITWRZZBB-UHFFFAOYSA-N 0.000 description 1
- DRVWBEJJZZTIGJ-UHFFFAOYSA-N cerium(3+);oxygen(2-) Chemical group [O-2].[O-2].[O-2].[Ce+3].[Ce+3] DRVWBEJJZZTIGJ-UHFFFAOYSA-N 0.000 description 1
- 238000003486 chemical etching Methods 0.000 description 1
- HPQRSQFZILKRDH-UHFFFAOYSA-M chloro(trimethyl)plumbane Chemical compound C[Pb](C)(C)Cl HPQRSQFZILKRDH-UHFFFAOYSA-M 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229910000428 cobalt oxide Inorganic materials 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- IAOQICOCWPKKMH-UHFFFAOYSA-N dithieno[3,2-a:3',2'-d]thiophene Chemical compound C1=CSC2=C1C(C=CS1)=C1S2 IAOQICOCWPKKMH-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 239000003574 free electron Substances 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- NFFIWVVINABMKP-UHFFFAOYSA-N methylidynetantalum Chemical compound [Ta]#C NFFIWVVINABMKP-UHFFFAOYSA-N 0.000 description 1
- 229910000480 nickel oxide Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N nitrate group Chemical group [N+](=O)([O-])[O-] NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- 239000001272 nitrous oxide Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 229920002120 photoresistant polymer Polymers 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 229910001925 ruthenium oxide Inorganic materials 0.000 description 1
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 229910003468 tantalcarbide Inorganic materials 0.000 description 1
- CXXKWLMXEDWEJW-UHFFFAOYSA-N tellanylidenecobalt Chemical compound [Te]=[Co] CXXKWLMXEDWEJW-UHFFFAOYSA-N 0.000 description 1
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000001039 wet etching Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/67005—Apparatus not specifically provided for elsewhere
- H01L21/67011—Apparatus for manufacture or treatment
- H01L21/67017—Apparatus for fluid treatment
- H01L21/67063—Apparatus for fluid treatment for etching
- H01L21/67069—Apparatus for fluid treatment for etching for drying etching
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/32431—Constructional details of the reactor
- H01J37/3244—Gas supply means
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/455—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
- C23C16/45563—Gas nozzles
- C23C16/45565—Shower nozzles
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/50—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating using electric discharges
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/32009—Arrangements for generation of plasma specially adapted for examination or treatment of objects, e.g. plasma sources
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/32009—Arrangements for generation of plasma specially adapted for examination or treatment of objects, e.g. plasma sources
- H01J37/32082—Radio frequency generated discharge
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/32009—Arrangements for generation of plasma specially adapted for examination or treatment of objects, e.g. plasma sources
- H01J37/32357—Generation remote from the workpiece, e.g. down-stream
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/32431—Constructional details of the reactor
- H01J37/32715—Workpiece holder
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/32431—Constructional details of the reactor
- H01J37/32798—Further details of plasma apparatus not provided for in groups H01J37/3244 - H01J37/32788; special provisions for cleaning or maintenance of the apparatus
- H01J37/32899—Multiple chambers, e.g. cluster tools
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02109—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates
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Description
本技術係關於半導體系統、製程和設備。更具體而言,本技術係關於用於蝕刻半導體材料的系統和方法。
藉由在基板表面上產生圖案複雜的材料層的製程可製成積體電路。在基板上產生圖案化的材料要求用於暴露材料的去除的受控方法。化學蝕刻用於多種用途,包括將光刻膠中的圖案轉移到下方層、將層薄化,或者將已存在於表面上的特徵的側向尺寸薄化。通常,期望的是具有一種比蝕刻另一材料更快地蝕刻一種材料以促進例如圖案轉移製程的蝕刻製程。這種蝕刻製程被稱為是對第一材料有選擇性。由於材料、電路和製程的多樣性,蝕刻製程已發展成具有面向於多種材料的選擇性。
在形成在基板處理區域內的局部電漿中產生的幹法蝕刻比濕法蝕刻可以穿透更受限的溝槽,並且使精細的剩餘結構更少變形。然而,即使蝕刻製程可對第二材料上方的第一材料有選擇性,但是仍會發生一些對第二材料的不期望的蝕刻。
因此,需要可用於產生高品質設備和結構的改進系統和改進方法。藉由本技術可解決這些以及其他需求。
本技術的實施方式包括用於選擇性蝕刻的方法和系統。實現氧化矽對包括多晶矽和氮化矽的材料的高度蝕刻選擇性。限定有複數個開口的附加隔板可以影響化合物的流動並增強或抑制某些反應。在一些情況下,該附加隔板可以增加滯留時間及/或電漿產物與含氫和氫的化合物的混合。該等電漿產物和該含氫和氫的化合物可反應以降低可能蝕刻非蝕刻目標的材料的化合物的濃度。另外,該隔板可有助於形成其他化合物,該等其他化合物可蝕刻作為蝕刻目標的氧化矽或其他材料。隨後,與沒有該隔板的製程或系統相比,該隔板可增加蝕刻選擇性。
本技術的實施方式可以包括一種對基板進行蝕刻的方法。該方法可以包括引燃電漿區域中的電漿放電。該方法亦可包括使含氟的前驅物流入該電漿區域中,以便形成電漿流出物。該電漿流出物可流入混合區域中。該方法可進一步包括將含氫和氧的化合物引入該混合區域中,而不首先使該含氫和氧的化合物進入該電漿區域中。另外,該方法可以包括使該含氫和氧的化合物與該電漿流出物在該混合區域中反應,以便形成反應產物。該等反應產物可以經由隔板中的複數個開口流到基板處理區域。該方法亦可包括在該基板處理區域中利用該等反應產物蝕刻該基板。
實施方式可以包括一種基板處理系統。該系統可以包括:第一氣體入口;基座,該基座被配置成支撐基板;噴淋頭;隔板;第二氣體入口;及電源。該噴淋頭可以是限定有複數個開口的導電板。該噴淋頭亦可定位在該第一氣體入口與該基座之間。該隔板可限定有第二複數個開口,並且可定位在該基座與該噴淋頭之間。該第二氣體入口可定位於該噴淋頭處,或定位在該噴淋頭與該隔板之間。電漿區域可限定在該第一氣體入口與該噴淋頭之間。基本無電漿的區域可限定在該噴淋頭與該隔板之間。基板處理區域可限定在該隔板與該基座之間。該電源可配置成引燃該電漿區域中的電漿放電。
實施方式亦可包括一種對基板進行蝕刻的方法。該方法可以包括引燃第一電漿區域中的第一電漿放電。該方法亦可包括引燃第二電漿區域中的第二電漿放電。該方法可進一步包括使含氟的前驅物流入該第一電漿區域中,以便形成電漿流出物。該電漿流出物可流入該第二電漿區域中。在該第二電漿區域中,含氫和氧的化合物和該電漿流出物可反應以形成反應產物。該含氫和氧的化合物在進入該第二電漿區域前,可以不被該第一電漿激發。該方法可以另外包括使該等反應產物經由隔板中的複數個開口流到基板處理區域。該方法亦可包括在該基板處理區域中利用該等反應產物蝕刻該基板。
用於蝕刻材料的一般方法和系統會隨著半導體結構的特徵尺寸減小而具有比期望更低的蝕刻選擇性。在一些製程中,更低品質的氧化物必須比更高品質的氧化物更快地蝕刻。氧化物蝕刻速率可降低,以便增加氧化物類型之間的選擇性。在該較低價氧化物蝕刻方案中,在氧化物與矽或氮化矽之間的蝕刻選擇性可能減小。對矽或氮化矽的不期望的蝕刻可對裝置效能造成不利影響,尤其對於越來越小的半導體裝置。
與一般方法和系統相比,本技術的實施方式增加氧化物相對於矽、氮化矽或其他材料的蝕刻選擇性。製程中的附加隔板更改蝕刻製程中的前驅物和化合物的流動和反應。隔板可定位在電漿區域下游以及含氫和氧的化合物的引入下游。隔板可以降低可蝕刻矽和氮化矽的物質(例如,氟自由基)的濃度,同時增加蝕刻氧化矽的物質(例如,HF
2)形成。因此,與不具有隔板的方法和系統相比,氧化物相對於多晶矽、氮化矽及/或其他材料的蝕刻選擇性可以增加。
圖1示出根據實施方式的蝕刻基板的方法100。該方法可以包括引燃電漿區域中的電漿放電(方塊102)。電漿放電可以是電容耦合的電漿或感應耦合的電漿。方法100亦可包括使含氟的前驅物流入電漿區域中,以便形成電漿流出物(方塊104)。含氟的前驅物可以包括選自由以下項組成的群組的前驅物:原子氟、雙原子氟、三氟化氮、四氟化碳、氟化氫和二氟化氙。其他氣體可隨含氟的前驅物一起流入電漿區域。其他氣體可以包括例如惰性氣體、稀有氣體、氦及/或氬。其他氧源可以用於增加或替換三氟化氮。一般而言,在實施方式中,含氧的前驅物流入電漿區域,並且含氟的前驅物包括選自由以下項組成的群組中的至少一種前驅物:分子氧(O
2)、臭氧(O
3)、一氧化二氮(N
2O)、連二次硝酸鹽(N
2O
2)或二氧化氮(NO
2)。電漿流出物可以包括在由電漿放電激發前存在的氣體中的分子的原子、分子、自由基及/或離子。
另外,方法100可以包括使電漿流出物流入混合區域中(方塊106)。電漿流出物可以流過噴淋頭中的複數個開口。混合區域可以基本不含電漿。「不含電漿」不一定指無電漿的區域。在電漿區域內形成的離子化的物質和自由電子可以以極小的濃度行進通過噴淋頭中的開口。在腔室電漿區域中的電漿的邊界可以經由噴淋頭中的開口小程度地侵入到噴淋頭下游的區域上。此外,低強度的電漿可以形成在噴淋頭下游的區域中,而不消除本文中描述的蝕刻製程的期望特徵。造成在被激發的電漿流出物形成程序中使電漿具有強度比腔室電漿區域低得多的離子密度的所有原因不背離如本文使用的「不含電漿」範圍。
在一些實施方式中,方法100可進一步包括將含氫和氧的化合物引入混合區域中(方塊108),而不首先使該含氫和氧的化合物進入該電漿區域中。含氫和氧的化合物在進入混合區域前,可以不被混合區域外的任何電漿激發或離子化。若含氫和氧的化合物引入到與含氟的前驅物相同的氣體入口中,則含氫和氧的化合物可以離解、離子化或經歷其他反應或激發,其會影響蝕刻反應並且增加製程的複雜性。相反,含氫和氧的化合物可以引入電漿下游,以便遞送該化合物,而不使其離解並且不會不必要地增加製程的複雜性。含氫和氧的化合物可以包括水蒸氣或醇類。在實施方式中,醇類可以包括甲醇、乙醇和異丙醇中的一或多種。含氫和氧的化合物可以包括O-H鍵。
另外,方法100可以包括使該含氫和氧的化合物與電漿流出物在混合區域中反應,以便形成反應產物(方塊110)。混合區域中的反應可以包括氟自由基和水反應物。氟自由基和水可反應以形成產物,包括HF
2 -和OH
-。反應產物可以包括氫、氟及/或氧原子的組合。
該方法可進一步包括使反應產物經由隔板中的複數個開口流到基板處理區域(方塊112)。基板處理區域可以基本上或徹底不含電漿。隔板中的複數個開口的一部分之每一者開口可與或可不與噴淋頭中的複數個開口中的最近開口同心地對準。可或可不同心地對準的複數個開口的部分可為或可不為隔板中的開口的整體。在不旨在受到任何特定理論束縛的情況下,認為隔板增強電漿流出物與含氫和氧的化合物之間的混合。具體而言,隔板可以增加F自由基與水之間的反應,並且因此可以減少可蝕刻多晶矽、氮化矽或其他材料的F自由基。
方法100亦可包括在基板處理區域中利用反應產物蝕刻基板(方塊114)。基板可以包括具有位於晶片頂部上的圖案化層的半導體晶片。基板可以包括暴露的氧化矽部分以及第二暴露部分。第二暴露部分可以具有除了1矽原子比2氧原子外的原子群組成比率。氧化矽可藉由包括以下反應的機制來蝕刻: -Si-O
-+H
+→-Si-OH (1) -Si-OH+HF
2 -→-Si-F+OH
-+HF (2)。 反應(1)示出氧化矽的表面如何可由可能已形成在混合區域中的氫離子質子化。反應(2)示出質子化的表面如何可由HF
2 -攻擊來形成氟化矽。在矽與多於三個的氟原子反應後,SiF
4形成並從表面解吸。附加的三個氟原子可來自於氟自由基及/或HF
2 -。
在實施方式中,第二暴露部分可以包括多晶矽或氮化矽。第一暴露部分可以以比多晶矽蝕刻快500倍的蝕刻速率蝕刻。在一些情況中,蝕刻速率可快600倍、700倍、800倍、900倍、1000倍。另外,第一暴露部分可以比氮化矽蝕刻快200倍的蝕刻速率蝕刻。例如,氧化矽的蝕刻速率可比氮化矽的蝕刻速率要快250倍、300倍、350倍或400倍。在一些實施方式中,基板可以包括兩種類型的氧化矽。一種類型的氧化矽可以比其他類型的氧化矽蝕刻得更快,但是小於2倍。製程溫度可以從0℃至100℃,包括從8℃至15℃。製程壓力可以從0.5托至12托。
實施方式可以包括圖2所示的基板處理系統200。該系統可以包括:第一氣體入口202;基座204,該基座被配置成支撐基板206;噴淋頭208;隔板210;第二氣體入口212;及電源214。第一氣體入口202可配置成從第一氣源203處接收氣體。隔板210可設置成與噴淋頭208相距從1000密爾至4000密爾,包括例如從1000密爾至1500密爾、從1500密爾至2000密爾、從2000密爾至2500密爾、從2500密爾至3000密爾、從3000密爾至3500密爾、或從3500密爾至4000密爾。基座204可設置成與噴淋頭208的面對隔板210的表面相距1000密爾至4000密爾。例如,基座204可與噴淋頭208的背對隔板的表面相距在1000密爾與1500密爾之間、在1500密爾與2000密爾之間、在2000密爾與2500密爾之間、在2500密爾與3000密爾之間、在3000密爾與3500密爾之間、或在3500密爾與4000密爾之間。隔板210可為圓形。隔板210可被稱為流分配板或分配板。隔板210可定位在噴淋頭208與基座204之間的任何距離處。在實施方式中,隔板210與噴淋頭208相距約2800密爾,並且基座204可定位成與噴淋頭208相距從2800密爾至4000密爾。
噴淋頭208可以是限定複數個開口(包括開口216)的導電板。噴淋頭208中的複數個開口之每一者開口可為圓柱形的。在一些實施方式中,開口216可以包括圓柱形的部分以及一或多個錐形部分。錐形部分可遠離或朝向基座逐漸變細。開口216可以包括由兩個錐形部分界定的圓柱形的部分。噴淋頭208亦可定位在第一氣體入口212與基座204之間。隔板210可限定第二複數個開口,並且可定位在基座204與噴淋頭208之間。隔板210中的複數個開口之每一者開口可為圓柱形的。開口218是隔板210中的一個開口的實例。噴淋頭208中的複數個開口之每一者開口的直徑可以等於隔板210中的複數個開口之每一者開口的直徑。在實施方式中,噴淋頭208和隔板210中的至少一個中的複數個開口可以具有不均勻分配的孔尺寸。噴淋頭208可以是圓形的,並且可以具有與隔板210相同的直徑。噴淋頭208可具有在隔板210的直徑的10%、20%、30%、40%或50%內的直徑。
第二氣體入口212可定位於噴淋頭208處,或定位在噴淋頭208與隔板210之間。第二氣體入口212可將氣體從第二氣源220遞送到噴淋頭208中的孔隙222。孔隙222可將氣體引向隔板210,並且不引導氣體與開口216中的電漿流出物混合。以此方式,噴淋頭208可為雙通道噴淋頭。無氣體入口可定位在與隔板210相同的水平處。電漿區域224可限定在第一氣體入口202與噴淋頭208之間。
基本無電漿的區域226可限定在噴淋頭208與隔板210之間。基板處理區域228可限定在隔板210與基座204之間。複數個氣體出口(包括氣體出口230)可定位在隔板210與基座204之間。複數個氣體出口可以通向泵232。複數個氣體出口可佈置在圍繞中心點的某個半徑處。該中心點可位於穿過噴淋頭208的中心和隔板210的中心的線上。可沿具有圍繞中心點的半徑的圓形的圓周均勻地分配複數個氣體出口。無氣體入口可以直接將氣體遞送到基板處理區域。
在一些實施方式中,無氣體出口可定位在隔板210與基座204之間。基板處理區域228中氣體出口的缺乏是由於系統在此位置處不具有氣體出口或泵內襯裝配在氣體出口上以防氣體流過出口。僅僅氣體出口可以位於基座204的與隔板210相對的彼側。推動氣體從基座的下方離開而非徑向離開複數個氣體出口可以提高蝕刻的均勻性。
電源214可配置成引燃電漿區域224中的電漿放電。電源214可為RF電源。用於電容耦合的電漿的電源214可操作為從0 W至2000 W,包括例如,25W至500W。
在一些實施方式中,離子抑制器可定位在噴淋頭與第一氣體入口之間。離子抑制器可以包括第三複數個開口。離子抑制器可以是圓形的,並且可以具有與噴淋頭相同的直徑。離子抑制器可具有在噴淋頭的直徑的10%、20%、30%、40%或50%內的直徑。第三複數個開口可以具有不均勻分配的開口直徑。下文更加詳細地描述離子抑制器的可能實例。離子抑制器、噴淋頭和隔板中的任兩個或三個可以具有相同圖案或分配的複數個開口。在實施方式中,離子抑制器、噴淋頭和隔板中的任兩個或三個可以具有不同圖案或分配的複數個開口。
如圖3所示,實施方式亦可包括一種對基板進行蝕刻的方法300。方法300可以包括引燃第一電漿區域中的第一電漿放電(方塊302)。第一電漿放電可為遠端電漿。該遠端電漿源可以具有0 kW與10 kW之間的功率。
方法300亦可包括引燃第二電漿區域中的第二電漿放電(方塊304)。第二電漿放電可與基板處於相同腔室之中。第二電漿可以是電容耦合的電漿或感應耦合的電漿。用於第二電漿放電的電源可操作為從0 W至500W。方法300可進一步包括使含氟的前驅物流入第一電漿區域中,以便形成電漿流出物(方塊306)。方法300可以包括使電漿流出物流入第二電漿區域中(方塊308)。在第二電漿區域中,含氫和氧的化合物和電漿流出物可反應以形成反應產物(方塊310)。該含氫和氧的化合物在進入該第二電漿區域前,可以不被該第一電漿激發。方法300可以另外包括使反應產物經由隔板中的複數個開口流到基板處理區域(方塊312)。方法300亦可包括在基板處理區域中利用反應產物蝕刻基板(方塊314)。
在電漿流出物進入第二電漿區域前並且在進入蝕刻腔室後,電漿流出物可不流過電接地的噴淋頭及/或離子抑制器中的複數個開口。第二電漿放電可不藉由至噴淋頭或離子抑制器的電連接形成。第二電漿區域可不包括本文中描述的噴淋頭或離子抑制器,或不由噴淋頭或離子抑制器界定。在不旨在受到任何特定理論束縛的情況下,認為,遠端電漿單元結合第二電漿放電使電漿流出物與含氫和氧的化合物充分混合並反應以相較其他材料而言增加氧化物的蝕刻選擇性。
一種用於實施方法300的系統可以包括圖4中的系統400。整體而言,圖4的系統400類似圖2的系統200,不同之處在於,加入遠端電漿源(RPS)單元402並且省略了噴淋頭。在系統400中,第一氣源404將氣體遞送到RPS單元402。RPS單元402被配置成引燃電漿放電,並且可以產生電漿流出物。電漿流出物可以順著氣體入口406向下流動。氣體入口406可以基本不含電漿。
電漿流出物可流入第二電漿區域408中。第二電漿區域408可以在氣體入口406與隔板410之間。第二電漿區域可以包括電漿放電,該電漿放電可利用來自電源412的功率來維持。電源412可為電容耦合在腔室與隔板410之間的RF電源。第二氣體入口414可從第二氣源416遞送氣體。第二氣源416可以包括水或另一含氫和氧的化合物。第二電漿區域中形成的反應產物可以流過隔板410中的複數個開口,諸如開口418。隨後,反應產物可以在限定為在隔板410與基座422之間的基板處理區域420中。基板處理區域420可以基本不含電漿。即使如此,基板處理區域420中的氣體亦會蝕刻基板424的一部分。
與系統200相同,系統400可以包括通向泵428的氣體出口426。氣體出口426可與圖2中的氣體出口230處於類似位置並且採用類似配置。另外,系統400可不包括氣體出口426以及基板處理區域420中的其他類似氣體出口。
一般而言,本文所呈現的方法可以用於相對於各種各樣的材料選擇性地蝕刻氧化矽,而不僅僅相對於多晶矽和氮化矽。該等方法可以用於比鈦、氮化鈦、氧化鈦、矽化鈦、鉿、氧化鉿、矽化鉿、鉭、氧化鉭、氮化鉭、矽化鉭、鈷、氧化鈷、矽化鈷、鎢、氧化鎢、矽化鎢、碳化矽、氮化矽、氮氧化矽、碳氮化矽、C-H膜、C-H-N膜、鍺化矽、鍺、鎳、氧化鎳或矽化鎳更快地選擇性地蝕刻暴露的氧化矽。
根據實施方式,第二暴露部分可以包括來自由以下項組成的群組中的至少一種元素:氮、鉿、鈦、鈷、碳、鉭、鎢和鍺。在實施方式中,第二暴露部分可基本由或由選自包括以下各項的群組的組合物組成:矽、鉭、鉭和氧、鉭和矽、鉭和氮、鈷、鈷和氧、鈷和矽、鎢、鎢和氧、鎢和矽、鎳、鎳和氧、鎳和矽、矽和氮、矽和氧和氮、矽和碳和氮、矽和碳、碳、碳和氫、碳和氫和氮、矽和鍺、鍺、鉿、鉿和氧、鉿和矽、鈦、鈦和氧、鈦和氮、或鈦和矽。 實例
對比具有分配板的蝕刻方法與沒有分配板的其他製程測試蝕刻選擇性。各種方法所得到的結果在圖5中示出。第一柱體的結果是用於蝕刻氧化物的對照配方。該等豎條指明氧化物對多晶矽的蝕刻選擇性大於200並且氧化物對低壓氮化矽(「LP SiN」)的蝕刻選擇性為約100。圖5的第二柱體示出稱為uSMD的蝕刻製程的結果,此蝕刻製程包括不同的離子抑制器,其中該離子抑制器具有不同的開口分配及/或開口直徑。SMD代表選擇性調制設備,即離子抑制器。第三柱體示出具有uSMD開口分配的噴淋頭和包括氦的配方。結果示出氧化物對多晶矽的蝕刻選擇性出現略微增加並且氧化物對低壓氮化矽的蝕刻選擇性大致相同。然而,由於多晶矽的緩慢蝕刻速率及/或實驗的精確度,第三柱體與前兩柱體之間的選擇性上的差異不轉變為用於典型製造製程時的差異。前三柱體示出不同的離子抑制器配置以及不同配方對蝕刻選擇性幾乎無影響。
第四柱體示出具有採用第三柱體的配方的附加流分配板的腔室的蝕刻選擇性結果。氧化物對多晶矽的蝕刻選擇性已增加至約800及以上,並且氧化物對低壓氮化矽的蝕刻選擇性已增加至接近300。第五柱體包括第四柱體的條件以及泵內襯裙狀物(pump liner skirt),以便覆蓋在基座與流分配板之間的腔室壁上的氣體出口。第五柱體的條件下的蝕刻選擇性類似第四柱體的條件下的蝕刻選擇性,從而表明泵內襯裙狀物不會影響蝕刻選擇性。
另外在圖5上示出的是氧化物對更高品質的氧化物的蝕刻選擇性。氧化物及更高品質的氧化物均非熱氧化物。與氧化物相比,更高品質的氧化物可以具有更高的密度和不同的表面條件。用於更高品質的氧化物的更高退火溫度會使更高品質的氧化物更難蝕刻。不管腔室配置以及配方如何,該兩種氧化物之間的蝕刻選擇性大致相同。圖5亦圖示在氧化物與電漿增強的氮化矽(「PE SiN」)之間的蝕刻選擇性,此種蝕刻選擇性同樣在不同製程條件下大致相同。電漿增強的氮化矽可以具有比低壓氮化矽更高的氫含量,並且由此蝕刻機制可類似於氧化物而非多晶矽或低壓氮化矽。因此,對電漿增強的氮化矽蝕刻的選擇性不會增加太多。該等結果示出加入流分配板不對其他蝕刻選擇性造成不利影響。
示例性的處理系統
圖6示出具有位於處理腔室內的分隔開的電漿產生區域的示例性的基板處理腔室1001的橫截面圖。在膜蝕刻期間,製程氣體可以經由氣體入口元件1005流入腔室電漿區域1015。遠端電漿系統(RPS)1002可任選地包括在系統中,並且可以處理第一氣體,隨後,該第一氣體行進通過氣體入口元件1005。製程氣體可以在進入腔室電漿區域1015前,在RPS 1002內被激發。因此,在實施方式中,如前述的含氟的前驅物例如可以穿過RPS 1002或繞過RPS單元。
示出冷卻板1003、面板1017、離子抑制器1023、噴淋頭1025和具有基板1055設置在其上的基板支撐件1065(亦被稱為基座),並且可根據實施方式包括其每一者。基座1065可以具有熱交換通道,熱交換流體流過熱交換通道以便控制基板的溫度。此配置可以允許基板1055溫度被冷卻或加熱,以便維持相對低的溫度,諸如在-20℃至200℃之間。基座1065亦可使用嵌入式加熱器元件來電阻加熱至相對高的溫度,諸如在100℃與1100℃之間。
示例性的配置可以包括使氣體入口元件1005開口到與腔室電漿區域1015由面板1017分隔開的氣體供應區域1058,使得氣體/物質經由在面板1017中的孔流入腔室電漿區域1015。可選擇結構特徵和操作特徵以防止電漿從腔室電漿區域1015顯著地回流到供應區域1058、氣體入口元件1005和流體供應系統1010中。結構特徵可以包括選擇面板1017中的孔隙的尺寸和橫截面幾何形狀以便鈍化回流電漿。操作特徵可以包括維持氣體供應區域1058與腔室電漿區域1015之間的壓力差,從而維持穿過噴淋頭1025的單向電漿流。面板1017(或腔室的導電頂部)和噴淋頭1025被示出為具有定位在特徵之間的絕緣環1020,這允許了AC電勢相對於噴淋頭1025及/或抑制器1023施加至面板1017。可將絕緣環1020定位在面板1017與噴淋頭1025及/或離子抑制器1023之間,從而使得電容耦合的電漿(CCP)能夠形成在腔室電漿區域中。
在離子抑制器1023中的複數個孔可配置成控制活化氣體(即,離子型、自由基及/或中性物質)通過離子抑制器1023。例如,孔的深寬比、或者孔直徑與長度的比及/或孔的幾何形狀可經控制成使得減少經由離子抑制器1023的活化氣體中的帶離子電荷的物質的流量。在離子抑制器1023中的孔可以包括面對腔室電漿區域1015的錐形部分和面對噴淋頭1025的圓柱形部分。圓柱形部分的形狀和尺寸可設定成控制通向噴淋頭1025的離子物質的流量。亦可將可調整的電偏壓施加至離子抑制器1023作為控制經由抑制器的離子物質的流量的附加手段。離子抑制元件1023可以用來減少或消除從電漿產生區域行進到基板的帶離子電荷的物質的量。無電荷的中性和自由基物質仍可穿過在離子抑制器中的開口來與基板反應。
電漿功率可以是多種頻率或多個頻率的組合。在示例性的處理系統中,電漿可由相對於離子抑制器1023和/噴淋頭1025遞送到面板1017的RF功率提供。在實施方式中,RF功率可以在約10瓦特與約5000瓦特之間、約100瓦特與約2000瓦特之間、約200瓦特與約1500瓦特之間或約200瓦特與約1000瓦特之間。在實施方式中,示例性的處理系統中施加的RF頻率可以是低於約200 kHz的低RF頻率、在約10 MHz與約15 MHz之間的高RF頻率、或大於1 GHz或約1 GHz的微波頻率。電漿功率可電容耦合(CCP)或感應耦合(ICP)到遠端電漿區域中。
氣體可從噴淋頭1025流向混合區域1070。混合區域1070可由流分配板1072界定在一側上。流分配板可以是本文中描述的任何隔板,並且本文中的任何隔板可以是流分配板1072。流分配板1072可以具有複數個開口,諸如開口1074。開口1074可以包括面對基板處理區域1033的錐形部分、面對噴淋頭1025的錐形部分及/或圓柱形部分。錐形部分可朝向或遠離其所面對的彼側逐漸變細。
前驅物(例如含氟的前驅物和含氧的前驅物)可以藉由本文中描述的噴淋頭的實施方式流入基板處理區域1033。源自腔室電漿區域1015中的製程氣體的激發物質可以行進通過離子抑制器1023中的孔隙、及/或噴淋頭1025,並與從噴淋頭的單獨部分流入基板處理區域1033的附加前驅物反應。或者,若所有前驅物 質在腔室電漿區域1015中激發,則可無附加的前驅物流過噴淋頭的單獨部分。在遠端電漿蝕刻製程程序中,幾乎沒有或沒有電漿可存在於基板處理區域1033中。前驅物的激發的衍生物可以在基板上方的區域及/或在基板上組合,以便蝕刻結構或將物質從該結構上去除。
處理氣體可以在腔室電漿區域1015中激發,並且可以在激發狀態下穿過噴淋頭1025到達基板處理區域1033。儘管電漿可以在基板處理區域1033中產生,但是電漿可替代地不產生在處理區域之中。在一個實例中,僅僅激發處理氣體或前驅物可以經由激發腔室電漿區域1015中的處理氣體以便在基板處理區域1033中彼此反應進行。如先前所論述,此舉可保護圖案化在基板1055上的結構。
圖7示出影響穿過面板1017的處理氣體分配的特徵的細節圖。用於處理腔室區段1001中的氣體分配元件(諸如噴淋頭1025)可以稱為雙通道噴淋頭(DCSH),並且另外在本文中的圖6以及圖8中描述的實施方式中詳細示出。雙通道噴淋頭可以提供用於蝕刻製程,從而允許在處理區域1033外的蝕刻劑在遞送到處理區域中前分離,以便提供與腔室部件以及彼此的有限相互作用。
噴淋頭1025可以包括上板1014和下板1016。可將板彼此耦接以在板之間限定容積1018。板的耦接可如此來提供穿過上板和下板的第一流體通道1019、以及穿過下板1016的第二流體通道1021。所形成的通道可配置成僅經由第二流體通道1021來提供從容積1018穿過下板1016的流體進出,並且第一流體通道1019可與在板與第二流體通道1021之間的容積1018流體地隔離。可經由氣體分配元件1025的一側流體地進出容積1018。儘管圖6-8的示例性的系統包括雙通道噴淋頭,但應理解,亦可利用使第一前驅物和第二前驅物在進入基板處理區域1033前維持流體地隔離的替代分配組件。例如,可以利用穿孔的板以及板下方的管道,但是其他配置亦可有效降低效率,或不提供如所述的雙通道噴淋頭那樣均勻的處理。
在所示的實施方式中,噴淋頭1025可經由第一流體通道1019來分配製程氣體,該製程氣體在藉由腔室電漿區域1015中的電漿激發後,含有電漿流出物。在實施方式中,引入RPS 1002及/或腔室電漿區域1015中的製程氣體可以含氟,例如NF
3。製程氣體亦可包括載氣,諸如氦、氬、氮(N
2)等等。電漿流出物可以包括製程氣體的離子化或中性衍生物,並且在本文中亦可稱為氟自由基前驅物,該氟自由基前驅物是指引入的製程氣體的原子群組分。含氫和氧的化合物可以流過第二流體通道1021。
圖8是實施方式中的與處理腔室一起使用的噴淋頭1025的仰視圖。噴淋頭1025與圖6中所示的噴淋頭相對應。示出第一流體通道1019的視圖的通孔1031可以具有複數個形狀以及配置以控制和影響穿過噴淋頭1025的前驅物流動。示出第二流體通道1021的視圖的小孔1027可基本上均勻地分配在噴淋頭的表面上方,甚至是在通孔1031之間,與其他配置相比,此舉可有助於在前驅物離開噴淋頭時,使前驅物更均勻地混合。
腔室電漿區域1015或RPS中的區域可以稱為遠端電漿區域。在實施方式中,氟自由基前驅物和氧自由基前驅物形成在遠端電漿區域中,並且行進到基板處理區域中以與含氫和氧的前驅物組合。在實施方式中,含氫和氧的前驅物僅由含氟自由基前驅物和含氧自由基前驅物激發。在實施方式中,電漿功率可基本上僅施加到遠端電漿區域,以便確保氟自由基前驅物和氧自由基前驅物提供主導激發。
幹法蝕刻系統的實施方式可結合到用於生產出積體電路晶片的更大的製造系統中。圖9示出實施方式中的具有沉積腔室、蝕刻腔室、烘烤腔室和固化腔室的一個此類處理系統(主機)1101。在附圖中,一對前開式聯合晶片盒(負載鎖定腔室1102)供應多種尺寸的基板,該等基板由機器人臂1104接收並在被放入基板處理腔室1108a-f中的一個之前放入到低壓固持區域1106中。第二機器人臂1110可以用於將基板晶片從固持區域1106傳輸到基板處理區域1108a-f並傳輸回。每個基板處理腔室1108a-f可裝配來執行許多基板處理操作,該等基板處理操作除了循環層沉積(CLD)、原子層沉積(ALD)、化學氣相沉積(CVD)、物理氣相沉積(PVD)、蝕刻、預先清潔、脫氣、取向和其他基板製程之外,亦包括了本文中描述的幹法蝕刻製程。
在實施方式中,三氟化氮(或另一含氟的前驅物)可以以約1 sccm與約40 sccm之間、約3 sccm與約25 sccm之間或約5 sccm與約10 sccm之間的速率流入腔室電漿區域1020。在實施方式中,氧氣(或另一含氧的前驅物)可以以約10 sccm與約400 sccm之間、約30 sccm與約250 sccm之間或約50 sccm與約150 sccm之間的速率流入腔室電漿區域1020。根據實施方式,水蒸氣可以以約5 sccm與約100 sccm之間、約10 sccm與約50 sccm之間或約15 sccm與約25 sccm之間的速率流入混合區域1070。根據實施方式,含氧的前驅物與含氟的前驅物的流量比可以大於4、大於6或大於10。在實施方式中,含氧的前驅物與含氟的前驅物的流量比可以小於40、小於30或小於20。根據實施方式,上限可與下限組合。
由於通向基板處理區域中的兩個通路不同,因此噴淋頭可稱為雙通道噴淋頭。含氟前驅物和含氧前驅物可以流過雙區域噴淋頭中的通孔,而水蒸氣可以穿過雙區域噴淋頭中的單獨區域。單獨區域可開口到混合區域或基板處理器區域中,但不進入如前述的遠端電漿區域。
進入基板處理區域的水蒸氣和電漿流出物的組合流量可佔據了0.05%至約20%的總氣體混合物的體積;剩餘的是載氣。在實施方式中,流入遠端電漿區域中的含氟前驅物和含氧前驅物而非電漿流出物具有相同的體積流量比。在含氟前驅物的情況下,可以在引入含氟氣體和含氧前驅物之前首先在電漿區域中引進淨化氣體或載氣,以便穩定遠端電漿區域內的壓力。
如本文所使用,「基板」可為具有或沒有層形成在其上的支撐基板。圖案化的基板可為多種摻雜濃度以及分佈的絕緣體或半導體,並且可例如是在積體電路製造中使用的半導體基板的類型。圖案化的基板的暴露的「氧化矽」主要是SiO
2,但是可以包括各濃度的其他元素組分,諸如,例如氮、氫和碳。在一些實施方式中,使用本文所揭示的方法來蝕刻的氧化矽部分基本由矽和氧組成。圖案化的基板的暴露的「氮化矽」主要是Si
3N
4,但是可以包括各濃度的其他元素組分,諸如,例如氧、氫和碳。在一些實施方式中,本文所描述的氮化矽部分基本由矽和氮組成。圖案化的基板的暴露的「氧化鉿」主要為鉿和氧,但是除鉿和氧之外,亦可包括小濃度的其他元素。在一些實施方式中,本文所描述的氧化鉿部分基本由鉿和氧組成。圖案化的基板的暴露的「鎢」主要為鎢,但是除鎢之外,亦可包括小濃度的其他元素。在一些實施方式中,本文所描述的鎢部分基本由鎢組成。類似定義適用本文所述所有材料。
術語「前驅物」用於代表參與反應以將材料從表面去除或將材料沉積到表面上的任何製程氣體。「電漿流出物」描述離開腔室電漿區域並進入基板處理區域的氣體。電漿流出物處於「激發狀態」,其中氣體分子中的至少一些處於振動激發、離解及/或離子化的狀態。「自由基前驅物」用於描述參與反應以將材料從表面去除或將材料沉積到表面上的電漿流出物(正在激發電漿的處於激發態的氣體)。「氟自由基前驅物(Radical-fluorine precursor)」描述含氟但亦可含有其他元素組分的自由基前驅物。「氧自由基前驅物(Radical-oxygen precursor)」描述含氧但亦可含有其他元素組分的自由基前驅物。詞語「惰性氣體」是指在蝕刻膜或併入膜中時不形成化學鍵的任何氣體。示例性的惰性氣體包括稀有氣體,但亦可以包括其他氣體,只要在(通常)痕量被捕陷在膜中時不會形成化學鍵合即可。
在先前描述中,出於解釋目的,已闡明瞭許多細節,以便提供對本技術的各種實施方式的理解。然而,本領域的技藝人士應當清楚,某些實施方式可以在無該等細節中的一些或有附加細節的情況下實踐。
在已描述若干實施方式的情況下,本領域的技藝人士將認識到,在不背離本技術的精神的情況下,可以使用各種修改、替代構造和均等物。另外,多個熟知的製程和元件尚未描述,以便避免不必要地使本技術模糊。另外,任何特定實施方式細節可能並非始終存在於在所述實施方式的變型中,或者可添加到其他實施方式。
在提供值的範圍情況下,應當理解,亦確切地揭示在該範圍的上限與下限之間的每一個居間值,精度為下限單位的十分之一,除非上下文清楚地另外指明。涵蓋在陳述範圍中的任何陳述的值或居間值與該陳述範圍中的任何其他陳述的值或居間值之間的每一個更小範圍。該等更小範圍的上限和下限可獨立地包括或排除於該範圍,並且其中在更小範圍中包括任一限值、並不包括限值或包括兩個限值的每個範圍亦涵蓋在本技術內,根據陳述範圍中的任何確切地排除的限值而定。在陳述範圍包括該等限值中的一或兩個情況下,亦包括排除彼等所包括的限值中的任一個或兩個的範圍
如本文以及在隨附的申請專利範圍中所使用,單數形式「一個」、「一種」和「該」包括複數指稱對象,除非上下文清楚地另外指明。因此,例如,提及「一種方法」包括複數種此類方法,並且提及「電漿流出物」包括指稱本領域的技藝人士所已知的一或多個電漿流出物以及其均等物,等等。出於清楚和理解的目的,現詳細地描述了本技術。然而,應當理解,某些改變以及修改可以在隨附的申請專利範圍之範圍內實踐。
100‧‧‧方法
102~114‧‧‧方塊
200‧‧‧基板處理系統
202‧‧‧第一氣體入口
203‧‧‧第一氣源
204‧‧‧基座
206‧‧‧支撐基板
208‧‧‧噴淋頭
210‧‧‧隔板
212‧‧‧第二氣體入口
214‧‧‧電源
216、218‧‧‧開口
220‧‧‧第二氣源
222‧‧‧孔隙
224‧‧‧電漿區域
226‧‧‧基本無電漿的區域
228‧‧‧基板處理區域
230‧‧‧氣體出口
232‧‧‧泵
300‧‧‧方法
302~314‧‧‧方塊
400‧‧‧系統
402‧‧‧遠端電漿源(RPS)單元
404‧‧‧第一氣源
406‧‧‧氣體入口
408‧‧‧第二電漿區域
410‧‧‧隔板
412‧‧‧電源
414‧‧‧第二氣體入口
416‧‧‧第二氣源
418‧‧‧開口
420‧‧‧基板處理區域
422‧‧‧基座
424‧‧‧基板
426‧‧‧氣體出口
428‧‧‧泵
1001‧‧‧基板處理腔室
1002‧‧‧遠端電漿系統(RPS)
1003‧‧‧冷卻板
1005‧‧‧氣體入口元件
1014‧‧‧上板
1015‧‧‧腔室電漿區域
1016‧‧‧下板
1017‧‧‧面板
1018‧‧‧容積
1019‧‧‧第一流體通道
1020‧‧‧腔室電漿區域
1021‧‧‧第二流體通道
1023‧‧‧離子抑制器
1025‧‧‧噴淋頭
1027‧‧‧小孔
1031‧‧‧通孔
1055‧‧‧基板
1058‧‧‧氣體供應區域
1065‧‧‧基板支撐件
1070‧‧‧混合區域
1072‧‧‧流分配板
1074‧‧‧開口
1101‧‧‧處理系統(主機)
1102‧‧‧負載鎖定腔室
1104‧‧‧機器人臂
1106‧‧‧低壓固持區域
1108a-f‧‧‧基板處理腔室
102~114‧‧‧方塊
200‧‧‧基板處理系統
202‧‧‧第一氣體入口
203‧‧‧第一氣源
204‧‧‧基座
206‧‧‧支撐基板
208‧‧‧噴淋頭
210‧‧‧隔板
212‧‧‧第二氣體入口
214‧‧‧電源
216、218‧‧‧開口
220‧‧‧第二氣源
222‧‧‧孔隙
224‧‧‧電漿區域
226‧‧‧基本無電漿的區域
228‧‧‧基板處理區域
230‧‧‧氣體出口
232‧‧‧泵
300‧‧‧方法
302~314‧‧‧方塊
400‧‧‧系統
402‧‧‧遠端電漿源(RPS)單元
404‧‧‧第一氣源
406‧‧‧氣體入口
408‧‧‧第二電漿區域
410‧‧‧隔板
412‧‧‧電源
414‧‧‧第二氣體入口
416‧‧‧第二氣源
418‧‧‧開口
420‧‧‧基板處理區域
422‧‧‧基座
424‧‧‧基板
426‧‧‧氣體出口
428‧‧‧泵
1001‧‧‧基板處理腔室
1002‧‧‧遠端電漿系統(RPS)
1003‧‧‧冷卻板
1005‧‧‧氣體入口元件
1014‧‧‧上板
1015‧‧‧腔室電漿區域
1016‧‧‧下板
1017‧‧‧面板
1018‧‧‧容積
1019‧‧‧第一流體通道
1020‧‧‧腔室電漿區域
1021‧‧‧第二流體通道
1023‧‧‧離子抑制器
1025‧‧‧噴淋頭
1027‧‧‧小孔
1031‧‧‧通孔
1055‧‧‧基板
1058‧‧‧氣體供應區域
1065‧‧‧基板支撐件
1070‧‧‧混合區域
1072‧‧‧流分配板
1074‧‧‧開口
1101‧‧‧處理系統(主機)
1102‧‧‧負載鎖定腔室
1104‧‧‧機器人臂
1106‧‧‧低壓固持區域
1108a-f‧‧‧基板處理腔室
對實施方式的本質和優點的進一步理解可以參考本說明書剩餘部分以及附圖實現。
圖1示出根據實施方式的蝕刻方法的方塊流程圖。
圖2示出根據實施方式的基板處理系統的簡化圖示。
圖3示出根據實施方式的蝕刻方法的方塊流程圖。
圖4示出根據實施方式的基板處理系統的簡化圖示。
圖5示出根據實施方式的針對不同製程的蝕刻選擇性。
圖6示出根據實施方式的基板處理腔室的示意性截面圖。
圖7示出根據實施方式的基板處理腔室的一部分的示意性截面圖。
圖8示出根據實施方式的噴淋頭的仰視圖。
圖9示出根據實施方式的示例性基板處理系統的俯視圖。
200‧‧‧基板處理系統
202‧‧‧第一氣體入口
203‧‧‧第一氣源
204‧‧‧基座
206‧‧‧支撐基板
208‧‧‧噴淋頭
210‧‧‧隔板
212‧‧‧第二氣體入口
214‧‧‧電源
216、218‧‧‧開口
220‧‧‧第二氣源
222‧‧‧孔隙
224‧‧‧電漿區域
226‧‧‧基本無電漿的區域
228‧‧‧基板處理區域
230‧‧‧氣體出口
232‧‧‧泵
Claims (20)
- 一種基板處理系統,該系統包括: 第一氣體入口; 基座,該基座被配置成支撐基板; 噴淋頭,該噴淋頭定位在該第一氣體入口與該基座之間,該噴淋頭包括限定有第一複數個開口的導電板; 隔板,該隔板定位在該基座與該噴淋頭之間,該隔板限定第二複數個開口; 第二氣體入口,該第二氣體入口定位在該噴淋頭處,或定位在該噴淋頭與該隔板之間; 電漿區域,該電漿區域限定在該第一氣體入口與該噴淋頭之間; 基本無電漿的區域,該基本無電漿的區域限定在該噴淋頭與該隔板之間; 基板處理區域,該基板處理區域限定在該隔板與該基座之間;及 電源,該電源被配置成引燃該電漿區域中的電漿放電。
- 根據請求項1之基板處理系統,其進一步包括: 複數個氣體出口,該複數個氣體出口定位在該隔板與該基座之間,其中: 該複數個氣體出口佈置在圍繞中心點的一半徑處,該中心點位於延伸穿過該噴淋頭的中心和該隔板的中心的線上,並且 該複數個氣體出口沿具有圍繞該中心點的該半徑的圓形的圓周均勻地分配。
- 根據請求項1之基板處理系統,其進一步包括離子抑制器,該離子抑制器包括第三複數個開口,該離子抑制器定位在該噴淋頭與該第一氣體入口之間。
- 根據請求項1之基板處理系統,其進一步包括: 泵;及 氣體出口,該氣體出口將該基板處理區域連接到該泵,其中該氣體出口定位在該基座的與該隔板相對的一側上。
- 根據請求項4之基板處理系統,其中該氣體出口是該基板處理系統的專用氣體出口。
- 根據請求項1之基板處理系統,其中該第二氣體入口被定位成使得流過該第二氣體入口的氣體在進入該基本無電漿的區域前,不首先經由該電漿區域。
- 根據請求項1之基板處理系統,其進一步包括: 第一氣源;及 第二氣源;其中 該第一氣體入口被配置成從該第一氣源處接收第一氣體;及 該第二氣體入口被配置成從該第二氣源處接收第二氣體,並且將該第二氣體遞送到該基本無電漿的區域。
- 根據請求項1之基板處理系統,其中: 該噴淋頭包括複數個孔隙, 該複數個孔隙開口到該基本無電漿的區域中,並且 該複數個孔隙並不開口到該電漿區域中。
- 根據請求項1之基板處理系統,其中該基板處理系統不包括被配置成直接將氣體遞送到該基板處理區域的氣體入口。
- 根據請求項1之基板處理系統,其中該基板處理系統不包括設置在該隔板與該基座之間的氣體出口。
- 一種基板處理系統,該系統包括: 第一氣體入口; 基座,該基座被配置成支撐基板; 噴淋頭,該噴淋頭定位在該第一氣體入口與該基座之間,該噴淋頭包括限定有第一複數個開口的導電板; 隔板,該隔板定位在該基座與該噴淋頭之間,該隔板限定第二複數個開口; 第二氣體入口,該第二氣體入口定位在該噴淋頭處,或定位在該噴淋頭與該隔板之間; 該第一氣體入口被配置成從第一氣源處接收第一氣體; 該第二氣體入口被配置成從第二氣源處接收第二氣體; 電漿區域,該電漿區域限定在該第一氣體入口與該噴淋頭之間; 基本無電漿的區域,該基本無電漿的區域限定在該噴淋頭與該隔板之間; 基板處理區域,該基板處理區域限定在該隔板與該基座之間;及 電源,該電源被配置成引燃該電漿區域中的電漿放電。
- 根據請求項11之基板處理系統,其進一步包括離子抑制器,該離子抑制器包括第三複數個開口,其中該離子抑制器定位在該噴淋頭與該第一氣體入口之間。
- 根據請求項11之基板處理系統,其中: 該噴淋頭包括複數個孔隙, 該複數個孔隙開口到該基本無電漿的區域中, 該複數個孔隙並不開口到該電漿區域中, 該第二氣體入口被定位成使得流過該第二氣體入口的氣體在進入該基本無電漿的區域前,不首先經由該電漿區域, 該噴淋頭具有第一表面和第二表面,並且 該第一表面被設置成比該第二表面更靠近該隔板。
- 根據請求項11之基板處理系統,其進一步包括: 複數個氣體出口,該複數個氣體出口定位在該隔板與該基座之間,其中: 該複數個氣體出口佈置在圍繞中心點的一半徑處,該中心點位於延伸穿過該噴淋頭的中心和該隔板的中心的線上,並且 該複數個氣體出口沿具有圍繞該中心點的該半徑的圓形的圓周均勻地分配。
- 根據請求項11之基板處理系統,其進一步包括氣體出口,該氣體出口定位在該基座的與該隔板相對的一側上。
- 根據請求項15之基板處理系統,其中該氣體出口是該基板處理系統的專用氣體出口。
- 根據請求項11之基板處理系統,其中該基板處理系統不包括被配置成直接將氣體遞送到該基板處理區域的氣體入口。
- 根據請求項11之基板處理系統,其中: 該第一複數個開口之每一者開口是圓柱形的並且具有第一直徑, 該第二複數個開口之每一者開口是圓柱形的並且具有第二直徑,並且 該第一直徑等於該第二直徑。
- 根據請求項13之基板處理系統,其中: 該隔板被設置成與該噴淋頭相距約2500至3000密爾,並且 該基座被設置成與該第一表面相距1000至4000密爾。
- 根據請求項11之基板處理系統,其進一步包括面板,並且其中該電源被配置成將RF功率相對於該噴淋頭遞送到該面板以引燃該電漿放電。
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TWI810272B (zh) * | 2018-04-08 | 2023-08-01 | 美商應用材料股份有限公司 | 具有交錯的氣體供給和去除之氣體分配模組及使用方法 |
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US20170040175A1 (en) | 2017-02-09 |
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KR20170017827A (ko) | 2017-02-15 |
TWI732777B (zh) | 2021-07-11 |
CN106449472B (zh) | 2021-10-12 |
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