TW201806082A - 在基板中形成通孔的物件及方法 - Google Patents

在基板中形成通孔的物件及方法 Download PDF

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TW201806082A
TW201806082A TW106118017A TW106118017A TW201806082A TW 201806082 A TW201806082 A TW 201806082A TW 106118017 A TW106118017 A TW 106118017A TW 106118017 A TW106118017 A TW 106118017A TW 201806082 A TW201806082 A TW 201806082A
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substrate
glass
mask
carrier
dlc
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羅伯特艾倫 貝爾曼
士文 劉
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康寧公司
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Abstract

在具有從第一表面延伸之至少一損傷區的基板中形成通孔的方法,蝕刻基板的至少一損傷區以在基板中形成通孔,其中當通孔延伸透過基板的厚度T的同時,基板的第一表面被遮罩。此遮罩在蝕刻後從基板的第一表面移除,及當遮罩移除後,基板的第一表面具有表面粗糙度(Rq)為約小於1.0 nm。

Description

在基板中形成通孔的物件及方法
本申請案依據專利法主張2016年6月1日提出申請之美國臨時申請案第62/343,943號之優先權權益,本申請案依據上述美國臨時申請案的內容,且其內容以引用之方式全部併入本文。
本發明大體上關於在基板中形成通孔的物件及方法。更明確地,本發明係關於在基板中形成貫穿通孔的物件及方法,包括維持基板的表面粗糙度(Rq)的蝕刻處理。
中介物可用於做為電子裝置中的電介面,包括具有射頻(RF)濾波器的裝置,以伸展電連接至更寬的節距或以將電連接改道至不同的電連接。玻璃中介物已經成為矽及纖維強化聚合物的有利替代物。此乃部分地由於玻璃能夠形成大型薄片。然而,由於持續薄化電子裝置,許多應用需要中介物於具有厚度為300 μm或更小。此薄玻璃在製造步驟中會是難以處理的,因為玻璃的脆性與缺乏剛性。為了對抗玻璃基板的脆性與缺乏剛性,已經發展出使用被玻璃基板接合的載具的製造方法。
凡得瓦力可用於暫時地將玻璃物件接合至載具。此暫時接合的能量足以存留於平板製造,同時保持為可拆開的。然而,當玻璃物件的表面粗糙度(Rq)太高時,凡得瓦力會產生弱鍵結(若有的話)。
通常,玻璃中介物需要通孔(孔洞)被導電材料所填充以提供電介接。在玻璃中介物中創造通孔的習知方法是藉由創造損傷區透過玻璃中介物的厚度,隨後將基板浸入蝕刻劑中。蝕刻劑可接著從損傷區移除材料以擴大孔洞。然而,此蝕刻處理不是選擇性的,且材料會從玻璃中介物的兩面被移除及擴大孔洞。此總是創造出範圍外的玻璃中介物表面粗糙度(Rq),於此範圍可適當地形成凡得瓦鍵結。
因此,存在需求於在基板中形成通孔的方法,同時維持低表面粗糙度(Rq),使得基板可被可移除地接合至載具。
在第一態樣中,在具有從第一表面延伸的至少一損傷區的基板中形成通孔的方法包括:蝕刻基板的至少一損傷區以形成基板中的通孔,同時基板的第一表面被遮罩。此遮罩接著從基板的第一表面移除,且遮罩移除後,基板的第一表面具有表面粗糙度(Rq)為約小於1.0 nm。
根據第一態樣的第二態樣,其中此遮罩選自由二苯基矽(diphenylsilicon)、苯基矽(phenylsilicon)、甲基苯基矽(methylphenylsilicon)、及類鑽碳(DLC)所構成的群組。
根據第二態樣的第三態樣,其中此遮罩是DLC,且此DLC是氫化非晶碳。
根據前述任一態樣的第四態樣,其中於遮罩移除後,基板的第一表面具有表面粗糙度(Rq)為約小於0.6 nm。
根據前述任一態樣的第五態樣,其中相對於基板的第一表面之基板的第二表面在蝕刻期間被遮罩。
根據前述任一態樣的第六態樣,其中此遮罩藉由氧化而移除。
根據前述任一態樣的第七態樣,其中通孔是封閉通孔或貫穿通孔。
根據前述任一態樣的第八態樣,其中此遮罩被選擇性施加於基板的第一表面,使得損傷區是未遮罩的。
根據前述任一態樣的第九態樣,其中基板是玻璃、陶瓷、或玻璃-陶瓷。
根據前述任一態樣的第十態樣,進一步包括:藉由將基板的第一表面佈置在載具的接合表面上,將基板可移除地接合至載具。
根據第十態樣的第十一態樣,進一步包括:在將基板可移除地接合至載具後,藉由施加鹼性清洗溶液至基板、溼蝕刻基板、拋光基板、金屬電鍍基板、藉由溼蝕刻金屬圖案化基板、沉積材料於基板上、及退火基板之中至少一者處理基板。
根據第十一態樣的第十二態樣,進一步包括:從基板移除載具。
根據第十至第十二態樣中任一態樣的第十三態樣,其中遮罩被選擇性施加於基板的第一表面,使得損傷區是未遮罩的。
在第十四態樣中,一種物件包括基板,基板包括被厚度T所分隔開的第一表面與第二表面。至少一損傷區在基板中且從第一表面延伸。第一膜層佈置在基板的第一表面的未損傷區上。第一膜層係選自由二苯基矽、苯基矽、甲基苯基矽、及類鑽碳(DLC)所構成的群組。
根據第十四態樣的第十五態樣,進一步包括:第二膜層佈置在基板的第二表面的未損傷區上,第二膜層係選自由二苯基矽、苯基矽、甲基苯基矽、及類鑽碳(DLC)所構成的群組。
根據第十四態樣或第十五態樣的第十六態樣,其中第一膜是DLC,且此DLC是氫化非晶碳。
根據第十四至第十六態樣中任一態樣的第十七態樣,其中基板是玻璃、陶瓷、或玻璃-陶瓷。
額外的特徵與優勢將在之後的詳細說明書中說明,且部分地從說明書或藉由實行本文所述的具體例而認知的,包括之後的詳細說明書、申請專利範圍、及隨附圖式,對於所屬技術領域的熟習技藝者是顯而易見的。
應理解到前述的概略說明與後述的詳細說明敘述各種具體例,且意於提供理解所申請標的之本質與特徵的概觀或架構。隨附圖式被包括以提供進一步理解各種具體例,且被併入與構成本說明書的一部分。圖式繪示本文所述的各種具體例,且與說明書一同做為解釋所申請標的之原理與操作。
大體上參照圖表,本文提供的在基板中創造通孔的物件及方法的具體例容許維持基板的表面粗糙度(Rq),使得基板可被可移除地接合至載具用於進一步處理。將詳細地參照在基板中形成通孔的物件及方法的各種具體例,這些例子繪示在隨附圖式中。儘可能地,相同的元件符號在整個圖式中用於指示相同或類似部件。注意到繪示在圖表中的具體例並非按比例,且相對尺寸與寬度僅被選作說明目的。
維持基板的蝕刻前表面粗糙度的具體例是藉由在用於通孔形成的蝕刻處理期間使用遮罩層。藉由在通孔形成期間維持基板的低表面粗糙度,基板可被可移除地接合至載具用於進一步處理。在處理後,基板可從載具移除,使得載具可被重覆使用於處理另外的基板。形成通孔的物件及方法的各種具體例在接下來詳細地說明。
圖1描繪範例物件100。本文所揭示的物件可例如做為半導體封裝中的中介物,此物件具有蝕刻孔洞(例如通孔)與表面特性,其容許成功的下游處理,包括但不限於,通孔金屬化與半導體裝置、射頻(RF)裝置(例如天線、開關、及類似物)、中介物裝置、微電子裝置、光電裝置、微機電系統(MEMS)裝置的線路重佈(redistribution layer(RDL))應用及其他通孔可發揮重要功效的應用。
圖2描繪大致上繪示出在基板中形成通孔的範例處理的範例流程圖10。描述在流程圖中的步驟在所有各種圖表的說明中將更被詳細地敘述。注意到儘管流程圖10被描繪成具有特定順序,應理解到本發明的具體例並不限於圖1中所示的步驟順序。
參照圖1,物件100通常包括基板110。基板110具有第一與第二表面112、114。至少一損傷區120被顯示在第一表面112上。第一與第二遮罩150a、150b形成在基板110的第一與第二表面112、114的至少一者上。在某些具體例中,遮罩可僅形成在第一或第二表面112、114的其中一者上。在其他具體例中,並如圖1所示,第一與第二遮罩150a、150b形成在基板110的第一與第二表面112、114兩者上。基板110可由各種玻璃組成物所形成,包括而沒有限制,硼矽酸玻璃、鋁矽酸玻璃、鹼金屬鋁矽酸玻璃、鋁硼矽酸玻璃、鹼金屬鋁硼矽酸玻璃、及鹼石灰玻璃。再者,基板110可為強化的(例如藉由離子交換處理)或非強化的。範例基板可包括但不限於,康寧EAGLE XG® 玻璃、化學強化的或非強化的康寧Gorilla® 玻璃,及康寧Willow® 玻璃。在更進一步具體例中,基板110可由諸如陶瓷及玻璃陶瓷的其他材料所製成。
現在參照圖3,基板110的第一與第二表面112、114可被厚度T分隔開,厚度T可取決於應用且不被本文所限制。作為非限制性例子,厚度T可在範圍為從約25 μm至約3000 μm、約25 μm至約2000 μm、約25 μm至約1000 μm、約50 μm至約3000 μm、約50 μm至約2000 μm、約50 μm至約1000 μm、約100 μm至約3000 μm、約100 μm至約2000 μm、約100 μm至約1000 μm、約200 μm至約3000 μm、約200 μm至約2000 μm、約200 μm至約1000 μm、約500 μm至約3000 μm、約500 μm至約2000 μm、約500 μm至約1000 μm、約3000 μm或更小、約2000 μm或更小、約1000 μm或更小、約700 μm或更小、約500 μm或更小、約400 μm或更小、約300 μm或更小、約200 μm或更小、或約100 μm或更小。第一與第二表面112、114亦具有蝕刻前表面粗糙度(Rq)。表面粗糙度(Rq)涉及表面量測的微觀高峰與谷底的均方根(RMS)。表面粗糙度(Rq)可使用原子力顯微鏡(AFM)量測,例如Veeco Dimension Icon。表面粗糙度(Rq)可改變以反應處理步驟,諸如下方所述的蝕刻處理。其在下方提供的例子中會更加明瞭。
參照圖2的方塊11,至少一損傷區120被創造在基板110中。如圖3所指示,至少一損傷區120延伸透過基板110的厚度T。至少一損傷區120可為延伸透過基板110的厚度T的孔洞。在某些具體例中,至少一損傷區120不延伸透過基板的整個厚度。在某些具體例中,有著多個損傷區的結合,其延伸透過基板的厚度T,而多個損傷區不延伸透過基板的整個厚度。至少一損傷區120可以各種方法形成在基板110中。在某些具體例中,至少一損傷區120可被創造,藉由施加高能量雷射脈衝以削磨貫穿基板110的狹窄孔洞。至少一損傷區120於下游蝕刻處理期間容許蝕刻劑在其中流動。
在另一例子中,至少一損傷區120可不為透過基板110的厚度T的孔洞,而是藉由脈衝雷射形成的雷射誘導損傷的線。脈衝雷射可形成損傷線,例如藉由非線性多光子吸收。在蝕刻處理期間,定義至少一損傷區120的雷射誘導損傷的線內的材料移除速率是快過在至少一損傷區120外的材料移除速率。執行雷射損傷創造與後續蝕刻的範例方法揭露在美國專利公告第9,278,886號與美國專利公開第2015/0166395號中,其各自內容以參考方式全部併入本文。
在圖2的流程圖10的方塊12,第一與第二遮罩150a、150b可被分別施加於基板110的第一與第二表面112、114。在某些具體例中,第一與第二遮罩150a、150b被任意地施加於基板110。在這些具體例中,第一與第二遮罩150a、150b在至少一損傷區120被創造在基板110中之前被施加至基板,如上所述。在此類情況中,雷射脈衝可削磨貫穿第一與第二遮罩150a、150b及基板110的孔洞。在其他具體例中,第一與第二遮罩150a、150b在至少一損傷區已經被創造之後被任意地施加至基板。在此例子中,第一與第二遮罩150a、150b在進一步處理之前,可從已經被創造的至少一損傷區120選擇性移除。在更進一步具體例中,第一與第二遮罩150a、150b被選擇性施加至基板110。在這些具體例中,第一與第二遮罩150a、150b可被施加至基板110,以避開已經被創造的至少一損傷區120。如此,第一與第二遮罩150a、150b可具有開口,其與至少一損傷區120對齊,以容許蝕刻劑進入至少一損傷區120。第一與第二遮罩150a、150b可被施加在厚度為小於或等於1 μm。在某些具體例中,遮罩150a、150b可被施加在厚度為小於或等於300 nm。在又進一步具體例中,遮罩150a、150b可被施加在厚度為約60 nm。
第一與第二遮罩150a、150b可為各種材料。例如,且沒有限制,遮罩可由二苯基矽、苯基矽、甲基苯基矽、及類鑽碳(DLC)所製成。在某些具體例中,類鑽碳可為氫化非晶碳。此氫化非晶碳膜可藉由沉積烴類前驅物化合物而形成,諸如化合物為化學式Cn Hy ,其中n是1至6而y是2至14。在某些例子中,n是1至4而y是2至10。此烴類化合物可為直線的或分支的。在某些例子中,此塗佈層藉由沉積烴類前驅物化合物而形成,此塗佈層具有合併的碳與氫含量為至少80重量百分比、至少85重量百分比、至少90重量百分比、或至少95重量百分比。在某些例子中,前驅物化合物被沉積以形成塗佈層,其具有合併的碳與氫含量為至少80重量百分比、至少85重量百分比、至少90重量百分比、至少95重量百分比、至少98重量百分比、至少99重量百分比、或大於99.5重量百分比。
烴類前驅物化合物的例子包括烷烴。烷烴可包括甲烷、乙烷、丙烷、丁烷、戊烷及己烷。在某些例子中,烴類前驅物化合物包括至少一碳-碳雙鍵,例如烯烴。烯烴可包括乙烯、丙烯、丁烯、戊烯及己烯。烯烴中的碳-碳雙鍵可呈現在化合物中的各種位置,例如1-丁烯或2-丁烯。在又其他例子中,烴類前驅物化合物包括至少一碳-碳三鍵,例如炔烴。炔烴可包括乙炔、丙炔、丁炔、戊炔及己炔。在某些例子中,炔烴中的碳-碳三鍵可呈現在化合物中的各種位置,例如1-丁炔或2-丁炔。
意於使第一與第二遮罩150a、150b可全為相同的材料。在其他具體例中,第一與第二遮罩150a、150b可為不同材料。在具體例中,其中遮罩材料是二苯基矽,二苯基矽膜可被施加於基板110的第一與第二表面112、114的至少一者。其中二苯基矽膜被施加於第一與第二表面112、114兩者,有著第一二苯基矽膜層與第二二苯基矽膜層。再者,雖未圖示,二苯基矽膜可被施加於基板110的邊緣表面。此膜可例如藉由氣相沉積而施加。作為例子而非限制,二苯基矽膜由二苯基矽烷與氫所形成,藉由化學氣相沉積,更佳為電漿增強化學氣相沉積。二苯基矽是高效的遮罩材料且抵抗酸性侵蝕。因此,二苯基矽可承受與通常使用在蝕刻處理中的氫氟無機酸混合物接觸。再者,二苯基矽可容易地從玻璃表面移除,而不創造過度的表面粗糙度(Rq)。
在具體例中,遮罩材料是氫化非晶碳,氫化非晶碳膜可施加於基板110的第一與第二表面112、114的至少一者。其中氫化非晶碳膜被施加於第一與第二表面112、114兩者,有著第一氫化非晶碳膜層與第二氫化非晶碳膜層。可藉由化學氣相沉積(CVD)技術及類似方法沉積氫化非晶碳。CVD技術的特定例子包括CVD、低壓CVD、大氣壓力CVD、電漿增強CVD(PECVD)、大氣電漿CVD、原子層沉積(ALD)、電漿ALD、及化學束磊晶。在另一例子中,塗佈層可被沉積,藉由熱分解吹管(pyrolytic torch)於溫度高於600℃、高於800℃、或高於1000℃,包括在其間的任何範圍及次範圍。含有烴類化合物之用於形成塗佈層的氣體混合物亦可包含受控數量的另一化合物,例如載體氣體或工作氣體。其他化合物可包括空氣、氧、氧化亞氮、二氧化碳、水蒸氣、或過氧化氫、及/或一或更多惰性氣體,例如氦、氖、氬、氪、氙。
在使用遮罩的任何選擇性蝕刻處理的最大挑戰之一為遮罩移除。遮罩材料必須足夠堅韌以抵抗蝕刻,但亦必須為易於移除而不損傷基板。諸如光阻之聚合物遮罩經常涉及將被遮罩的基板浸泡在熱溶劑中並機械攪拌。通常,藉由電漿蝕刻移除無機遮罩。例如,PECVD沉積的碳化矽(SiC)通常以含氟電漿移除。然而,在此類處理下,基板在移除期間亦被蝕刻,因而增加基板的表面粗糙度(Rq)。二苯基矽對於傳統遮罩材料是獨特的,其特別容易氧化。在氧化期間,有機基團被熱解並移除,而矽被氧化以形成二氧化矽。此處理容許基板的表面粗糙度被實質地保持。如下方例子3中所示,氫化非晶碳亦被氧化以移除遮罩。預期其他電漿聚合物膜及材料可具有實質上類似於二苯基矽的益處。例如,且非限制,苯基矽、甲基苯基矽、及類鑽碳(DLC)。
參照圖2之流程圖10的方塊13,在已經創造至少一損傷區120及已經施加第一與第二遮罩150a、150b之後,玻璃物件100可被蝕刻。如圖4所示,蝕刻處理可包括將玻璃物件100浸入蝕刻劑180池中。額外地或可替換地,蝕刻劑180可被噴塗在玻璃物件100上。蝕刻劑180可移除在基板110的未遮罩部分的基板110的材料,以擴大至少一損傷區120的直徑。可使用任何合適蝕刻劑。蝕刻劑的非限制性例子包括強無機酸,諸如硝酸、氫氯酸、或帶有含氟蝕刻劑(諸如氫氯酸、二氟化銨、氟化鈉、及類似物)的磷酸。
圖5繪示在已經發生蝕刻後的基板110。如所描繪的,通孔124從圖1所繪示的至少一損傷區120被打開。通孔124被顯示為貫穿通孔,其延伸透過基板的厚度。在其他具體例中,通孔可為封閉通孔,僅延伸透過基板的一部分。在某些具體例中,貫穿通孔從損傷區形成,其延伸透過基板的厚度,而封閉通孔從損傷區形成,其不延伸貫穿基板的厚度。作為例子而非限制,通孔124可具有直徑在範圍於約5 μm至約150 μm、約20 μm至約150 μm、或約5 μm至約20 μm。此通孔可實質為圓柱形,例如具有腰部(沿著通孔具有最小直徑的點)帶有直徑為在第一或第二表面上的通孔的開口的直徑的至少70%、至少75%、或至少80%。
在至少一通孔124已經被打開至所欲直徑後,第一與第二遮罩150a、150b可從基板110移除(圖2的方塊14)。圖6繪示第一與第二遮罩150a、150b已經從基板110移除。在某些具體例中,基板100可被清洗,在移除第一與第二遮罩150a、150b(例如藉由去離子水沖洗)之前及/或之後。例如而非限制,在具體例中,其中二苯基矽是遮罩材料,第一與第二遮罩150a、150b可藉由氧化移除。用於氧化二苯基矽膜的範例工具包括氧光阻去除器或電漿灰化器。遮罩150a、150b可被移除,而不實質地增加基板110的第一與第二表面112、114的表面粗糙度(Rq)(即蝕刻後表面粗糙度(Rq))。實質地增加表面粗糙度(Rq)涉及增加基板110的表面粗糙度(Rq)超過本文所述的凡得瓦鍵結能力。在某些例子中,在移除遮罩150a、150b後的基板110的完成的表面粗糙度(Rq)是小於約1.2 nm、小於約1.1 nm、小於約1.0 nm、小於約0.9 nm、小於約0.8 nm、小於約0.7 nm、小於約0.6 nm、小於約0.5 nm、小於約0.4 nm、或小於約0.3 nm。
在通孔124已經被蝕刻後,基板110可接受額外處理步驟,以獲得額外的中介物性質。圖7繪示範例基板110被可移除地接合至範例載具200,藉由將基板110的第二表面114佈置在載具200的接合表面210上。如上所論述的,玻璃中介物可為非常薄(例如任何地方為從小於300 μm至700 μm)。此薄材料在製造步驟期間會是難以處理的,因為基板110的脆性及缺乏剛性。為了對抗脆性與缺乏剛性,在通孔已經形成及第一與第二遮罩150a、150b已經被移除之後,基板110可被可移除地接合至載具200。將基板100可移除地接合至載具的一種範例方法是藉由使用凡得瓦鍵結,諸如美國專利公開第2014/0170378號所揭示的,其全文被參考並併入本文中。凡得瓦鍵結通常包括將物件的表面佈置在載具的接合表面上,並提高物件的溫度,接著冷卻物件至室溫。成果為物件與載具被可移除地接合在一起。凡得瓦鍵結是有利於下游處理的,因為其能形成能夠承受處理(例如高溫處理)的接合,同時容許基板的整個區域從載具200被移除(一次被全部移除或分段地被移除)。在基板110已經被移除之後,載具200可重覆使用以處理額外基板。
然而,使用凡得瓦表面接合技術以接合基板的挑戰是被接合在一起的表面的粗糙度影響將被接合的表面的能力。作為非限制性例子,表面粗糙度(Rq)大於約1.0 nm可實質地避免自發接合或造成基板110至載具200的弱鍵結。弱鍵結會允許液體從一或更多處理滲透在基板110與載具200之間,因而導致從一處理的分層或如殘留物的處理汙染,其會影響後續處理。
載具200可為任何合適材料,諸如例如玻璃。載具200不需要為玻璃,但可替代為例如陶瓷、玻璃-陶瓷、或金屬。若是以玻璃製成,載具200可為任何合適的組成物,包括但不限於,鋁矽酸玻璃、硼矽酸玻璃、鋁硼矽酸玻璃、鹼石灰矽酸鹽,且可為含鹼金屬或不含鹼金屬,取決於其最終的應用。載具200可具有任何合適厚度。此外,載具200可被製造為一層,如圖示,或為接合在一起(例如藉由積層)的多層(包括多個薄片)。再者,載具200的熱膨脹係數可實質上匹配於基板110的熱膨脹係數,以避免在高溫處理期間,基板110的扭曲或從載具200的基板110的去耦合。基板110的表面粗糙度(Rq)是附加於載具200的表面粗糙度。因此,通常建議載具200具有表面粗糙度(Rq)小於或等於0.6 nm。
參照圖2的方塊16,一旦基板110被充分地接合至載具200,使得載具200與基板110在處理期間不會分開,基板110可接受進一步的處理。處理基板110可包括以下步驟,諸如施加鹼性清洗溶液至基板110、溼蝕刻基板110、拋光基板110、金屬電鍍基板110、藉由溼蝕刻金屬圖案化基板110、藉由沉積而沉積材料至基板110上、及退火基板110。例子
下方的比較例及例子1與2比較由於酸性蝕刻與二苯基矽膜的移除之表面粗糙度(Rq)的改變。在各例子中,玻璃樣品是0.7 mm厚且不具有損傷區。各樣品的表面粗糙度(Rq)藉由Veeco Dimension ICON AFM量測,帶有下列參數:1 Hz、512 掃描/線、及2微米影像尺寸。 比較例
在此比較例中,未遮罩的Eagle XG® 玻璃樣品的表面粗糙度(Rq)被週期地量測,同時此玻璃樣品被6M氫氟酸與1.6M硝酸混合物所蝕刻。已經證實大於1 nm的表面粗糙度(Rq)是在室溫下小於10分鐘並且機械(非超音波)攪拌而達成。此時間量對應於蝕刻深度為40 μm。此結果列表在下方的表1中。注意到在某些例子中超過1.0 nm的表面粗糙度(Rq)可導致弱或無效的凡得瓦鍵結。 表1 例子1
在此例子中,Eagle XG® 玻璃樣品的表面粗糙度(Rq)在二苯基矽膜施加之前、在二苯基矽膜施加之後、與在二苯基矽膜被移除之後被量測。此二苯基矽膜在應用材料公司的P5000通用化學氣相沉積(CVD)系統中被沉積,帶有下列參數:390℃、容積流率為500 sccm的二苯基矽烷、容積流率為600 sccm的氫氣(H2 )、9托、210密耳間隙、300瓦RF、二苯基矽烷起泡器於80℃。此二苯基矽膜具有厚度為60 nm。此二苯基矽膜藉由 Gasonics L3510光阻去除器而移除,具有下列參數:200℃、1200毫托、1000 sccm N2 、100 sccm O2 、900瓦、2.54 GHz、具有30秒過蝕刻的終點控制。列表在下方表2中的結果顯示表面粗糙度(Rq)只稍微地增加,同時仍然良好地處在如上所述凡得瓦鍵結所需的範圍中。注意到在此例子中玻璃基板沒有被酸性蝕刻。 表2 例子2
在此例子中,Eagle XG® 玻璃樣品的表面粗糙度(Rq)在二苯基矽膜施加之後、在蝕刻15分鐘之後、及在二苯基矽膜移除之後被量測。如同例子1,此二苯基矽膜在應用材料公司的P5000通用CVD系統中被沉積,帶有下列參數:390℃、容積流率為500 sccm的二苯基矽烷、容積流率為600 sccm的氫氣(H2 )、9托、210密耳間隙、300瓦RF、二苯基矽烷起泡器於80℃。此二苯基矽膜具有厚度為60 nm。蝕刻劑為3M氫氟酸與1M硝酸的混合物並結合機械(非超音波)攪拌。如同上述例子,此二苯基矽膜藉由 Gasonics L3510光阻去除器而移除,具有下列參數:200℃、1200毫托、1000 sccm N2 、100 sccm O2 、900瓦、2.54 GHz、具有30秒過蝕刻的終點控制。列表在下方表3中的結果顯示表面粗糙度(Rq)良好地處在如上所述凡得瓦鍵結所需的範圍中。此例子亦顯示如本文所論述的對於酸性侵蝕的二苯基矽的抵抗性。 表3 例子3
在此例子中,Eagle XG® 玻璃晶圓的6個樣品具有0.7 mm厚度、150 mm直徑與無損傷區,具有施加的非晶氫化碳膜遮罩。此遮罩由乙烯與氫氣所沉積,於Nextral NE500反應性離子蝕刻器中,在以下情況:30 sccm乙烯、70 sccm氫氣、於壓力為60毫托、於功率為800瓦及頻率為13.56 MHz。此遮罩(沉積完時)的沉積時間與厚度列表在下方表4中。此遮罩的折射率亦被量測(沉積完時)於632 nm。厚度與折射率是使用N&K分析儀而量測。在沉積遮罩後,樣品被蝕刻大約15分鐘於23℃,在10重量%氫氟酸與7重量%硝酸的蝕刻溶液中。在蝕刻後,使用N&K分析儀再次量測遮罩的厚度與在632 nm的折射率,其列表於下方的表4中。厚度與折射率的改變是在實驗誤差的範圍中。接下來,此遮罩藉由 Gasonics L3510光阻去除器而移除,具有下列參數:200℃、1200毫托、1000 sccm N2 、100 sccm O2 、900瓦、2.54 GHz、具有30秒過蝕刻的終點控制。以及各樣品的表面粗糙度(Rq)藉由Veeco Dimension ICON AFM量測,帶有下列參數:1 Hz、512 掃描/線、及2微米影像尺寸。此結果列表在下方表4中。
如可從表4得知,樣品7不具有遮罩且在如具有遮罩的6個樣品的相同條件下被蝕刻。未遮罩的樣品7的表面粗糙度(Rq)是明顯較高的1.13,相較於0.240至0.278。此顯示出此遮罩。 表4
本文提供的其他材料可沉積在基板上,使用應用材料公司P5000通用CVD系統,具有類似參數。例如,苯基矽膜可從帶有氫氣載體氣體的有機矽氫化物前驅物而沉積,在應用材料公司P5000通用CVD系統中,由苯基矽烷與氫氣,帶有下列條件:390℃、容積流率為120 sccm的苯基矽烷、及容積流率為600 sccm的氫氣(H2 )、9托壓力、210密耳間隙、與300瓦13.56 MHz RF。此苯基矽烷安瓿可在30℃。沉積速率可為接近1000 nm/min。甲基苯基矽膜可使用應用材料公司P5000通用CVD系統而沉積,帶有下列處理條件:390℃、容積流率為200 sccm的甲基苯基矽烷、容積流率為600 sccm的氫氣(H2 )、9托、210密耳間隙、與450瓦RF。此甲基苯基矽烷安瓿可在80℃。諸如有機矽鹵化物的其他前驅物可產生類似成果。
應理解到本文所述的具體例提供形成通孔於基板中,而不實質地增加基板的表面粗糙度(Rq)。藉由在通孔形成期間保持基板的低表面粗糙度,基板可被可移除地接合至載具用於進一步處理。在處理後,基板從載具移除,使得載具可重覆使用以處理其他基板。再者,貫穿通孔可被製成實質圓柱形,因為其可從兩端被蝕刻。
在不悖離申請專利標的之精神與範疇下,本文所述具體例的各種修改與變化,對於此技術領域的熟習技藝者是顯而易見的。因此,意於本說明書涵蓋本文所述的各種具體例的修改與變化,提供各種具體例的修改與變化是在隨附的申請專利範圍及其等效物的範疇之中。
10‧‧‧流程圖
11、12、13、14、15、16‧‧‧方塊
100‧‧‧物件
110‧‧‧基板
112‧‧‧第一表面
114‧‧‧第二表面
120‧‧‧損傷區
124‧‧‧通孔
150A‧‧‧第一遮罩
150B‧‧‧第二遮罩
180‧‧‧蝕刻劑
200‧‧‧載具
210‧‧‧接合表面
在圖式中說明的具體例在本質上是圖解與示例性的,且不意於限制由申請專利範圍所定義的申請標的。當與隨後的圖式共同閱讀時,可理解圖解具體例的隨後詳細說明,其中類似結構以相同的元件符號標示且其中:
圖1繪示根據本文所示與所述的一或更多具體例的包括基板與遮罩的物件的透視圖;
圖2繪示根據本文所示與所述的一或更多具體例的敘述製造物件的方法的流程圖;
圖3繪示根據本文所示與所述的一或更多具體例的具有一或多個損傷區形成於其中的圖1的物件的剖面視圖;
圖4繪示根據本文所示與所述的一或更多具體例的浸入蝕刻劑之圖1的物件;
圖5繪示根據本文所示與所述的一或更多具體例的具有一或更多通孔形成於其中之圖1的物件之剖面視圖;
圖6繪示根據本文所示與所述的一或更多具體例的遮罩被移除之圖4的物件之剖面視圖;以及
圖7繪示根據本文所示與所述的一或更多具體例的接合至載具之圖6的物件的透視圖。
國內寄存資訊 (請依寄存機構、日期、號碼順序註記) 無
國外寄存資訊 (請依寄存國家、機構、日期、號碼順序註記) 無
100‧‧‧物件
110‧‧‧基板
112‧‧‧第一表面
114‧‧‧第二表面
124‧‧‧通孔
150A‧‧‧第一遮罩
150B‧‧‧第二遮罩

Claims (10)

  1. 一種在具有從一第一表面延伸之至少一損傷區的一基板中形成一通孔的方法,該方法包含以下步驟: 蝕刻該基板的該至少一損傷區,以在該基板中形成一通孔,同時該基板的該第一表面被遮罩;以及從該基板的該第一表面移除該遮罩,其中於該遮罩移除後,該基板的該第一表面具有一表面粗糙度(Rq)為約小於1.0 nm。
  2. 如請求項1所述之方法,其中該遮罩係選自由二苯基矽(diphenylsilicon)、苯基矽(phenylsilicon)、甲基苯基矽(methylphenylsilicon)、及類鑽碳(DLC)所構成的一群組。
  3. 如請求項2所述之方法,其中該遮罩是DLC,且該DLC是氫化非晶碳。
  4. 如請求項1–3中任一項所述之方法,其中於該遮罩移除後,該基板的該第一表面具有一表面粗糙度(Rq)為約小於0.6 nm。
  5. 如請求項1–3中任一項所述之方法,其中該基板是一玻璃、陶瓷、或玻璃-陶瓷。
  6. 如請求項1–3中任一項所述之方法,進一步包含以下步驟: 藉由將該基板的該第一表面佈置在一載具的一接合表面上,將該基板可移除地接合至該載具。
  7. 一種物件,包含: 一基板,該基板包含一第一表面與一第二表面,該第一表面與該第二表面以一厚度T分隔開; 至少一損傷區,該至少一損傷區在該基板中且從該第一表面延伸;以及 一第一膜層,該第一膜層佈置在該基板的該第一表面的一未損傷區上,該第一膜層係選自由二苯基矽(diphenylsilicon)、苯基矽(phenylsilicon)、甲基苯基矽(methylphenylsilicon)、及類鑽碳(DLC)所構成的一群組。
  8. 如請求項7所述之物件,進一步包含一第二膜層,該第二膜層佈置在該基板的該第二表面的該未損傷區上,該第二膜層係選自由二苯基矽(diphenylsilicon)、苯基矽(phenylsilicon)、甲基苯基矽(methylphenylsilicon)、及類鑽碳(DLC)所構成的一群組。
  9. 如請求項7所述之物件,其中該第一膜是DLC,且該DLC是氫化非晶碳。
  10. 如請求項7–9中任一項所述之物件,其中該基板是一玻璃、陶瓷、或玻璃-陶瓷。
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US20190185373A1 (en) 2017-12-19 2019-06-20 Corning Incorporated Methods for etching vias in glass-based articles employing positive charge organic molecules
CN108191258B (zh) * 2018-01-30 2020-05-05 武汉理工大学 一种dlc薄膜增硬玻璃及其制备方法

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CN111757856A (zh) * 2018-02-22 2020-10-09 康宁股份有限公司 具有低的hf蚀刻后粗糙度的不含碱性硼硅酸盐玻璃
US11554984B2 (en) 2018-02-22 2023-01-17 Corning Incorporated Alkali-free borosilicate glasses with low post-HF etch roughness
TWI794417B (zh) * 2018-02-22 2023-03-01 美商康寧公司 具有低hf蝕刻後粗糙度之無鹼硼矽酸鹽玻璃
CN111757856B (zh) * 2018-02-22 2023-08-22 康宁股份有限公司 具有低的hf蚀刻后粗糙度的不含碱性硼硅酸盐玻璃

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US10410883B2 (en) 2019-09-10
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