WO1993008221A2 - Elastic substantially linear olefin polymers - Google Patents

Elastic substantially linear olefin polymers Download PDF

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Publication number
WO1993008221A2
WO1993008221A2 PCT/US1992/008812 US9208812W WO9308221A2 WO 1993008221 A2 WO1993008221 A2 WO 1993008221A2 US 9208812 W US9208812 W US 9208812W WO 9308221 A2 WO9308221 A2 WO 9308221A2
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WO
WIPO (PCT)
Prior art keywords
olefin polymer
polymer
substantially linear
linear olefin
ethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US1992/008812
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English (en)
French (fr)
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WO1993008221A3 (en
Inventor
Shih-Yaw Lai
John R. Wilson
Georges W. Knight
James C. Stevens
Pak-Wing Steve Chum
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Priority claimed from US07/776,130 external-priority patent/US5272236A/en
Priority to DE9219090U priority Critical patent/DE9219090U1/de
Priority to EP19920922757 priority patent/EP0608369B1/en
Priority to KR1019997010981A priority patent/KR100263803B1/ko
Priority to CA 2120766 priority patent/CA2120766C/en
Priority to JP50780592A priority patent/JP2963199B2/ja
Priority to KR1019940701216A priority patent/KR100262024B1/ko
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Priority to DE69220077T priority patent/DE69220077T2/de
Priority to DE9219173U priority patent/DE9219173U1/de
Publication of WO1993008221A2 publication Critical patent/WO1993008221A2/en
Publication of WO1993008221A3 publication Critical patent/WO1993008221A3/en
Priority to FI941727A priority patent/FI112663B/fi
Anticipated expiration legal-status Critical
Priority to FI20030362A priority patent/FI20030362L/fi
Ceased legal-status Critical Current

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Definitions

  • This invention relates to elastic substantially linear olefin polymers having improved processability, e.g., low susceptibilty to melt fracture, even under high shear stress conditions.
  • Such substantially linear ethylene polymers have a critical shear rate at the onset of surface melt fracture substantially higher than, and a processing index substantially less than, that of a linear polyethylene at the same molecular weight distribution and melt index.
  • MWD Molecular weight distribution
  • M w weight average molecular weight
  • M n number average molecular weight
  • I10/I2 ratio measured directly, e.g., by gel permeation chromatography techniques, or more routinely, by measuring I10/I2 ratio, as described in ASTM D-1238.
  • Olefin polymers characterized as substantially linear olefin polymers have now been discovered which have unusual properties, including an unusual combination of properties, which leads to enhanced processability of the novel polymers.
  • the substantially linear olefin polymers have the process ability similar to highly branched low density polyethylene (LDPE), but the strength and toughness of linear low density polyethylene (LLDPE).
  • LLDPE linear low density polyethylene
  • the novel substantially linear olefin polymers are distinctly different from traditional Ziegler polymerized heterogeneous polymers (e.g., LLDPE) and are also different from traditional free radical/high pressure polymerized LDPE.
  • the novel substantially linear olefin polymers are also different from homogeneous olefin polymers having a uniform brandling distribution.
  • the substantially linear olefin polymers are characterized as having: a) a melt flow ratio, I ⁇ o/ ⁇ 2r ⁇ 5.63, b) a molecular weight distribution, M w /M n , defined by the equation:
  • the substantially linear olefin polymers can also be characterized as having: a) a melt flow ratio, I ⁇ o/T-2/ ⁇ 5.63, b) a molecular weight distribution, M w /M n , defined by the equation:
  • the substantially linear olefin polymers are characterized as having: a) a melt flow ratio, I10/I2 / ⁇ 5.63, and b) a molecular weight distribution, M /M n of from 1.5 to 2.5.
  • the substantially linear olefin polymers are characterized as having: a) a melt flow ratio, I10/I2 / ⁇ 5.63, b) a molecular weight distribution, M w /M n of from 1.5 to 2.5, and c) a critical shear rate at onset of surface melt fracture of at least 50 percent greater than the critical shear rate at the onset of surface melt fracture of a linear olefin polymer at about the same I2 and M w /M n .
  • the substantially linear olefin polymers can also be characterized as having a critical shear rate at onset of surface melt fracture of at least 50 percent greater than the critical shear rate at the onset of surface melt fracture of a linear olefin polymer at about the same I2 and M w /M n .
  • the olefin polymer can be characterized as a substantially linear olefin polymer having:
  • compositions comprising the substantially linear olefin polymer and at least one other natural or synthetic polymer are also within the scope of the invention.
  • Elastic substantially linear olefin polymers comprising ethylene homopolymers or an interpolymer of ethylene with at least one C3-C20 -olefin copolymers are espedally preferred.
  • Figure 1 is a schematic representation of a polymerization process suitable for making the polymers of the present invention.
  • Figure 2 plots data describing the relationship between Il ⁇ /l2 and Mw/M for two examples of the invention, and for some comparative examples.
  • Figure 3 plots the shear stress versus shear rate for an example of the invention and for a comparative example, described herein.
  • Figure 4 plots the .shear stress versus shear rate for an example of the invention and for a comparative example, described herein.
  • Figure 5 plots the heat seal strength versus heat seal temperature of film made from examples of the invention, and for comparative examples, described herein.
  • Figure 6 graphically displays dynamic shear viscosity data for an elastic substantially linear olefin polymer of the present invention and for a comparative linear polymer made using single site catalyst technology.
  • Figure 7 graphically displays Il ⁇ /l2 ratio as a function of ethylene concentration in the polymerization reactor for ethylene/propene substantially linear copolymers of the invention.
  • linear olefin polymers used herein means that the olefin polymer does not have long chain branching. That is, the linear olefin polymer has an absence of long chain branching, as for example the traditional linear low density polyethylene polymers or linear high density polyethylene polymers made using Ziegler polymerization processes (e.g., USP 4,076,698 (Anderson et al.)), sometimes called heterogeneous polymers.
  • the term “linear olefin polymers” does not refer to high pressure branched polyethylene, ethylene/vinyl acetate copolymers, or ethylene/vinyl alcohol copolymers which are known to those skilled in the art to have numerous long chain branches.
  • linear olefin polymers also refers to polymers made using uniform branching distribution polymerization processes, sometimes called homogeneous polymers.
  • Such uniformly branched or homogeneous polymers include those made as described in USP 3,645,992 (Elston) and those made using so- called single site catalysts in a batch reactor having relatively high olefin concentrations (as described in U.S. Patent 5,026,798 (Canich) or in U.S. Patent 5,055,438 (Canich)) or those made using constrained geometry catalysts in a batch reactor also having relatively high olefin concentrations (as described in U.S.
  • the uniformly branched/homogeneous polymers are those polymers in which the comonomer is randomly distributed within a given interpolymer molecule and wherein substantially all of the interpolymer molecules have the same ethylene/comonomer ratio within that interpolymer, but these polymers too have an absence of long chain branching, as, for example, Exxon Chemical has taught in their February 1992 Tappi Journal paper.
  • substantially linear polymers means that the polymer backbone is substituted with 0.01 long chain branches/1000 carbons to 3 long chain branches/ 1000 carbons, more preferably from 0.01 long chain branches/1000 carbons to 1 long chain brandies /1000 carbons, and espedally from 0.05 long diain brandies/1000 carbons to 1 long diain brandies/1000 carbons. Similar to the traditional homogeneous polymers, the substantially linear ethylene/ ⁇ -olefin copolymers of the invention have only a single melting point, as opposed to traditional Ziegler polymerized heterogeneous linear ethylene/ ⁇ -olefin copolymers which have two or more melting points (determined using differential scanning calorimetry (DSC)).
  • DSC differential scanning calorimetry
  • Long chain branching is defined herein as a chain length of at least about 6 carbons, above which the length cannot be distinguished using 13 C nudear magnetic resonance spectroscopy.
  • the long chain branch can be as long as about the same length as the length of the polymer back-bone.
  • Melt tension is measured by a specially designed pulley transducer in conjunction with the melt indexer. Melt tension is the load that the extrudate or filament exerts while passing over the pulley at the standard speed of 30 rpm. The melt tension measurement is similar to the "Melt Tension Tester” made by Toyoseiki and is described by John Dealy in “Rheometers for Molten Plastics", published by Van Nostrand Reinhold Co. (1982) on page 250-251.
  • melt tension of these new polymers is also surprisingly good, e.g., as high as about 2 grams or more, especially for the substantially linear olefin polymers which have a very narrow molecular weight distribution (i.e., M w /M n from 1.5 to 2.5).
  • the SCBDI Short Chain Branch Distribution Index
  • CDBI Composition Distribution Branch Index
  • the SCBDI or CDBI for the substantially linear olefin polymers of the present invention is preferably greater than about 30 percent, especially greater than about 50 percent.
  • a unique characteristic of the presently claimed polymers is a highly unexpected flow property where the I 1 0/I2 value is essentially independent of polydispersity index (i.e. M w /M n ). This is contrasted with conventional Ziegler polymerized heterogeneous polyethylene resins and with conventional single site catalyst polymerized homogeneous polyethylene resins having rheological properties such that as the polydispersity index increases, the I 10 /I 2 value also increases.
  • the density of the ethylene or ethylene/ ⁇ -olefin substantially linear olefin polymers in the present invention is measured in accordance with ASTM D-792 and is generally from 0.85 g/cnv 5 to 0.97 g/ ⁇ n3, preferably from 0.85 g/cm ⁇ to 0.955 g/cm.3, and especially from 0.85 g/cm ⁇ to 0.92 g/crxA
  • the molecular weight of the ethylene or ethylene/ ⁇ -olefin substantially linear olefin polymers in the present invention is conveniently indicated using a melt index measurement according to ASTM D-1238, Condition 190°C/2.16 kg (formally known as "Condition (E)” and also known as I2). Melt index is inversely proportional to the molecular weight of the polymer. Thus, the higher the molecular weight, the lower the melt index, although the relationship is not linear.
  • the melt index for the ethylene or ethylene/ ⁇ -olefin substantially linear olefin polymers used herein is generally from 0.01 grams/10 minutes (g/10 min) to 1000 g/10 min, preferably from 0.01 g/10 min to 100 g/10 min, and espedally from 0.01 g/10 min to 10 g/10 min.
  • the I10/I2 ratio indicates the degree of long chain branching, i.e., the higher the I10/I2 ratio, the more long chain branching in the polymer.
  • the I10/I2 ratio of the substantially linear ethylene/ ⁇ -olefin polymers is at least about 5.63, preferably at least about 7, especially at least about 8 or above.
  • Additives such as antioxidants (e.g., hindered phenolics (e.g., Irganox® 1010 made by Ciba Geigy Corp.), phosphites (e.g., Irgafos® 168 made by Ciba Geigy Corp.)), cling additives (e.g., PIB), antiblock additives, pigments, and the like can also be included in the polyethylene compositions, to the extent that they do not interfere with the enhanced properties discovered by Applicants.
  • antioxidants e.g., hindered phenolics (e.g., Irganox® 1010 made by Ciba Geigy Corp.), phosphites (e.g., Irgafos® 168 made by Ciba Geigy Corp.)
  • cling additives e.g., PIB
  • antiblock additives e.g., pigments, and the like
  • the whole interpolymer product samples and the individual interpolymer samples are analyzed by gel permeation chromatography (GPC) on a Waters 150C high temperature diromatographic unit equipped with three mixed porosity columns (Polymer Laboratories 10 3 , 10 4 , 10 5 , and 10 6 ), operating at a system temperature of 140°C.
  • the solvent is 1,2,4-trichlorobenzene, from whidi 0.3 percent by weight solutions of the samples are prepared for injection.
  • the flow rate is 1.0 milliliters /minute and the injection size is 200 microliters.
  • the molecular weight determination is deduced by using narrow molecular weight distribution polystyrene standards (from Polymer Laboratories) in conjunction with their elution volumes.
  • the equivalent polyethylene molecular weights are determined by using appropriate Mark-Houwink coefficients for polyethylene and polystyrene (as described by Williams and Word in Tournal of Polymer Science, Polymer Letters, Vol. 6, (621) 1968) to derive the following equation:
  • M w R wi* M ⁇ , where wi and Mi are the weight fraction and molecular weight, respectively, of the i m fraction eluting from the GPC column.
  • the molecular weight distribution (M w /M n ) for the substantially linear olefin polymers of the invention is generally less than 5, preferably from 1.5 to 2.5, and especially from 1.7 to 2.3.
  • the rheological processing index (PI) is measured by a gas extrusion rheometer (GER).
  • GER gas extrusion rheometer
  • the processing index is measured at a temperature of 190°C, at nitrogen pressure of 2500 psig using a 0.0296 inch (752 micrometers) diameter, 20:1 L/D die having an entrance angle of 180°.
  • the GER processing index is calculated in millipoise units from the following equation:
  • PI 2.15 X 10 6 dynes/cm 2 /(1000 X shear rate), where: 2.15 X 10 6 dynes/cm 2 is the shear stress at 2500 psi, and the shear rate is the shear rate at the wall as represented by the following equation:
  • Q ⁇ is the extrusion rate (gms/min)
  • 0.745 is the melt density of polyethylene (gm/cm 3 )
  • Diameter is the orifice diameter of the capillary (inches).
  • the PI is the apparent viscosity of a material measured at apparent shear stress of 2.15 x 10 6 dyne/cm 2 .
  • the PI is less than or equal to 70 percent of that of a comparative linear olefin polymer at about the same I2 and M /M n .
  • the critical shear rate at onset of surface melt fracture for the substantially linear olefin polymers is at least 50 percent greater than the critical shear rate at the onset of surface melt fracture of a linear olefin polymer having about the same I2 and M w /M n .
  • the critical shear stress at onset of surface melt fracture for the substantially linear olefin polymers of the invention is greater than 2.8 x 10 ⁇ dynes/cm ⁇ .
  • Gross melt fracture occurs at unsteady flow conditions and ranges in detail from regular (alternating rough and smooth, helical, etc.) to random distortions. For commercial acceptability, (e.g., in blown film products), surface defects should be minimal, if not absent.
  • the critical shear rate at onset of surface melt fracture (OSMF) and critical shear stress at onset of gross melt fracture (OGMF) will be used herein based on the changes of surface roughness and configurations of the extrudates extruded by a GER.
  • the critical shear stress at onset of gross melt fracture is preferably greater than 4 x 10 ⁇ dynes/cm 2 .
  • Suitable constrained geometry catalysts for use herein preferably include constrained geometry catalysts as disclosed in U.S. Application Serial Nos.: 545,403, filed July 3, 1990; 758,654, filed September 12, 1991; 758,660, filed September 12, 1991; and 720,041, filed June 24, 1991.
  • the monocyclopentadienyl transition metal olefin polymerization catalysts taught in USP 5,026,798, are also believed to be suitable for use in preparing the polymers of the present invention, so long as the polymerization conditions substantially conform to those.
  • the foregoing catalysts may be further described as comprising a metal coordination complex comprising a metal of groups 3-10 or the Lanthanide series of the Periodic Table of the Elements and a delocalized ⁇ -bonded moiety substituted with a constrain-inducing moiety, said complex having a constrained geometry about the metal atom such that the angle at the metal between the centroid of the delocalized, substituted ⁇ -bonded moiety and the center of at least one remaining substituent is less than such angle in a similar complex containing a similar ⁇ -bonded moiety lacking in such constrain- indudng substituent, and provided further that for such complexes comprising more than one delocalized, substituted ⁇ -bonded moiety, only one thereof for each metal atom of the complex is a cyclic, delocalized, substituted ⁇ -bonded moiety.
  • the catalyst further comprises an activating cocatalyst.
  • Preferred catalyst complexes correspond to the formula:
  • M is a metal of group 3-10, or the Lanthanide series of the Periodic Table of the Elements;
  • Cp* is a cydopentadienyl or substituted cyclopentadienyl group bound in an ⁇ bonding mode to M;
  • Z is a moiety comprising boron, or a member of group 14 of the Periodic Table of the Elements, and optionally sulfur or oxygen, said moiety having up to 20 non-hydrogen atoms, and optionally Cp* and Z together form a fused ring system;
  • X independently each occurrence is an anionic ligand group or neutral Lewis base ligand group having up to 30 non-hydrogen atoms;
  • n 0, 1, 2, 3, or 4 and is 2 less than the valence of M
  • Y is an anionic or nonanionic ligand group bonded to Z and M comprising nitrogen, phosphorus, oxygen or sulfur and having up to 20 non-hydrogen atoms, optionally Y and Z together form a fused ring system.
  • R' each occurrence is independently selected from the group consisting of hydrogen, alkyl, aryl, silyl, germyl, cyano, halo and combinations thereof having up to 20 non-hydrogen atoms;
  • X each occurrence independently is selected from the group consisting of hydride, halo, alkyl, aryl, silyl, germyl, aryloxy, alkoxy, amide, siloxy, neutral Lewis base ligands and combinations thereof having up to 20 non-hydrogen atoms;
  • Y is -O-, -S-, -NR*-, -PR*-, or a neutral two electron donor ligand selected from the group consisting of OR*, SR*, NR*2 or PR*2;
  • R* each occurrence is independently selected from the group consisting of hydrogen, alkyl, aryl, silyl, halogenated alkyl, halogenated aryl groups having up to 20 non-hydrogen atoms, and mixtures thereof, or two or more R* groups from Y, Z, or both Y and Z form a fused ring system; and n is 1 or 2.
  • R', Z, or R* is an electron donating moiety.
  • Y is a nitrogen or phosphorus containing group corresponding to the formula -N(R")- or -P(R")-, wherein R" is QL_IO alkyl or aryl, i.e., an amido or phosphido group.
  • M is titanium, zirconium or hafnium, bound in an ⁇ 5 bonding mode to the cyclopentadienyl group
  • R' each occurrence is independently selected from the group consisting of hydrogen, silyl, alkyl, aryl and combinations thereof having up to 10 carbon or silicon atoms;
  • E is silicon or carbon
  • X independently each occurrence is hydride, halo, alkyl, aryl, aryloxy or alkoxy of up to 10 carbons;
  • n 1 or 2;
  • n 1 or 2.
  • Examples of the above most highly preferred metal coordination compounds include compounds wherein the R' on the amido group is methyl, ethyl, propyl, butyl, pentyl, hexyl, (induding isomers), norbornyl, benzyl, phenyl, etc.; the cydopentadienyl group is cydopentadienyl, indenyl, tetrahydroindenyl, fluorenyl, octahydrofluorenyl, etc.; R' on the foregoing cydopentadienyl groups eadi occurrence is hydrogen, methyl, ethyl, propyl, butyl, pentyl, hexyl, (including isomers), norbornyl, benzyl, phenyl, etc.; and X is chloro, bromo, iodo, methyl, ethyl, propyl, buty
  • the complexes may be prepared by contacting a derivative of a metal, M, and a group I metal derivative or Grignard derivative of the cydopentadienyl compound in a solvent and separating the salt byproduct.
  • Suitable solvents for use in preparing the metal complexes are aliphatic or aromatic liquids such as cyclohexane, methylcyclohexane, pentane, hexane, heptane, tetrahydrofuran, diethyl ether, benzene, toluene, xylene, ethylbenzene, etc., or mixtures thereof.
  • the metal compound is MX n+ ⁇ , i.e., M is in a lower oxidation state than in the corresponding compound, MX n+ 2 and the oxidation state of M in the desired final complex.
  • a noninterfering oxidizing agent may thereafter be employed to raise the oxidation state of the metal. The oxidation is accomplished merely by contacting the reactants utilizing solvents and reaction conditions used in the preparation of the complex itself.
  • noninterfering oxidizing agent is meant a compound having an oxidation potential sufficient to raise the metal oxidation state without interfering with the desired complex formation or subsequent polymerization processes.
  • a particularly suitable noninterfering oxidizing agent is AgCl or an organic halide such as methylene chloride.
  • complexes may be prepared according to the teachings of the copending United States application serial number 778,433 entitled: “Preparation of Metal Coordination Complex (I)", filed in the names of Peter Nickias and David Wilson, on October 15, 1991 and the copending United States application serial number 778,432 entitled: “Preparation of Metal Coordination Complex (II)”, filed in the names of Peter Nickias and David Devore, on October 15, 1991, and the patents issuing therefrom.
  • Suitable cocatalysts for use herein indude polymeric or oligomeric aluminoxanes, especially methyl aluminoxane, as well as inert, compatible, noncoordinating, ion forming compounds.
  • So-called modified methyl aluminoxane (MMAO) is also suitable for use as a cocatlyst.
  • MMAO modified methyl aluminoxane
  • Aluminoxanes can also be made as disclosed in U.S. Patents Nos. 5,542,199; 4,544,762; 5,015,749; and 5,041,585.
  • Preferred cocatalysts are inert, noncoordinating, boron compounds.
  • Ionic active catalyst species which can be used to polymerize the polymers described herein correspond to the formula:
  • M is a metal of group 3-10, or the Lanthanide series of the Periodic Table of the Elements;
  • Cp* is a cydopentadienyl or substituted cydopentadienyl group bound in an ⁇ 5 bonding mode to M;
  • Z is a moiety comprising boron, or a member of group 14 of the Periodic Table of the Elements, and
  • X independently each occurrence is an anionic ligand group or neutral Lewis base ligand group having up to 30 non- hydrogen atoms; n is 0, 1, 2, 3, or 4 and is 2 less than the valence of M; and
  • A- is a noncoordinating, compatible anion.
  • One method of making the ionic catalyst species which can be utilized to make the polymers of the present invention involve combining: a) at least one first component which is a mono(cyclopentadienyl) derivative of a metal of Group 3-10 or the Lanthanide Series of the Periodic Table of the Elements containing at least one substituent which will combine with the cation of a second component (described hereinafter) which first component is capable of forming a cation formally having a coordination number that is one less than its valence, and b) at least one second component which is a salt of a Bronsted add and a noncoordinating, compatible anion.
  • a first component which is a mono(cyclopentadienyl) derivative of a metal of Group 3-10 or the Lanthanide Series of the Periodic Table of the Elements containing at least one substituent which will combine with the cation of a second component (described hereinafter) which first component is capable of forming a cation formally having a coordination number
  • the non-coordinating, compatible anion of the Bronsted add salt may comprise a single coordination complex comprising a charge-bearing metal or metalloid core, which anion is both bulky and non-nucleophilic.
  • metal as used herein, includes non-metals such as boron, phosphorus and the like which exhibit semi-metallic characteristics.
  • Illustrative, but not limiting examples of monocyclopentadienyl metal components (first components) which may be used in the preparation of cationic complexes are derivatives of titanium, zirconium, vanadium, hafnium, chromium, lanthanum, etc.
  • Preferred components are titanium or zirconium compounds.
  • suitable monocyclopentadienyl metal compounds are hydrocarbyl-substituted monocyclopentadienyl metal compounds such as (tert-butylamido)(tetramethyl- ⁇ 5-cydopentadienyl)-l,2- ethanediylzirconium dimethyl, (tert-butylamido)(tetramethyl- ⁇ 5- cydopentadienyl)-l,2-ethanediyltitanium dimethyl, (methylamido)(tetramethyl- ⁇ 5-cydopentadienyI)-l,2- ethanediylzirconium dibenzyl, (methylamido)(tetramethyI- ⁇ 5-cydopentadienyl)-l,2- ethanediyltitanium dimethyl, (ethylamido)(tetramethyl- ⁇ 5- cydopentadie
  • Such components are readily prepared by combining the corresponding metal chloride with a dilithium salt of the substituted cydopentadienyl group sudi as a cyclopentadienyl-alkanediyl, cydopentadienyl—silane amide, or cydopentadienyl— phosphide compound.
  • the reaction is.conducted in an inert liquid such as tetrahydrofuran, C5-10 alkanes, toluene, etc. utilizing conventional synthetic procedures.
  • the first components may be prepared by reaction of a group II derivative of the cydopentadienyl compound in a solvent and separating the salt by-product.
  • Magnesium derivatives of the cydopentadienyl compounds are preferred.
  • the reaction may be conducted in an inert solvent such as cydohexane, pentane, tetrahydrofuran, diethyl ether, benzene, toluene, or mixtures of the like.
  • the resulting metal cydopentadienyl halide complexes may be alkylated using a variety of techniques.
  • the metal cydopentadienyl alkyl or aryl complexes may be prepared by alkylation of the metal cydopentadienyl halide complexes with alkyl or aryl derivatives of group I or group LI metals.
  • Preferred alkylating agents are alkyl lithium and Grignard derivatives using conventional synthetic techniques.
  • the reaction may be conducted in an inert solvent such as cyclohexane, pentane, tetrahydrofuran, diethyl ether, benzene, toluene, or mixtures of the like.
  • a preferred solvent is a mixture of toluene and tetrahydrofuran.
  • Compounds useful as a second component in the preparation of the ionic catalysts useful in this invention will comprise a cation, which is a Bronsted acid capable of donating a proton, and a compatible noncoordinating anion.
  • Preferred anions are those containing a single coordination complex comprising a charge-bearing metal or metalloid core which anion is relatively large (bulky), capable of stabilizing the active catalyst species (the Group 3-10 or Lanthanide Series cation) which is formed when the two components are combined and sufficiently labile to be displaced by olefinic, diolefinic and acetylenically unsaturated substrates or other neutral Lewis bases such as ethers, nitriles and the like.
  • Suitable metals include, but are not limited to, aluminum, gold, platinum and the like.
  • Suitable metalloids include, but are not limited to, boron, phosphorus, silicon and the like.
  • Compounds containing anions which comprise coordination complexes containing a single metal or metalloid atom are, of course, well known and many, particularly such compounds containing a single boron atom in the anion portion, are available commercially. In light of this, salts containing anions comprising a coordination complex containing a single boron atom are preferred.
  • the second component useful in the preparation of the catalysts of this invention may be represented by the following general formula:
  • L is a neutral Lewis base
  • [A]" is a compatible, noncoordinating anion.
  • M' is a metal or metalloid selected from Groups 5-15 of the Periodic Table of the Elements.
  • Q independently each occurrence is selected from the Group consisting of hydride, dialkylamido, halide, alkoxide, aryloxide, hydrocarbyl, and substituted-hydrocarbyl radicals of up to 20 carbons with the proviso that in not more than one occurrence is Q halide and q is one more than the valence of M'.
  • Second components comprising boron which are particularly useful in the preparation of catalysts of this invention may be represented by the following general formula:
  • L is a neutral Lewis base
  • [L-H] + is a Bronsted acid
  • B is boron in a valence state of 3
  • trialkyl- substituted ammonium salts such as trieth
  • N,N-dialkyl anilinium salts such as N,N- dimethyl-aniliniumtetraphenylborate, N,N-diethylanilinium tetraphenylborate, N,N-2,4,6-pentamethylanilinium tetraphenylborate and the like; dialkylammonium salts such as di-(i-propyl) ammonium tetrakis(pentafluorophenyl)borate, dicyclohexylammonium tetraphenylborate and the like; and triaryl phosphonium salts such as triphenylphosphonium tetraphenylborate, tri(methylphenyl)phosphonium tetrakis-pentafluorophenylborate, tri(dimethylphenyl)phosphonium tetraphenylborate and the like.
  • Preferred ionic catalysts are those having a limiting charge separated structure corresponding to the formula:
  • M is a metal of group 3-10, or the Lanthanide series of the Periodic Table of the Elements;
  • Cp* is a cydopentadienyl or substituted cydopentadienyl group bound in an ⁇ bonding mode to M;
  • Z is a moiety comprising boron, or a member of group 14 of the Periodic Table of the Elements, and optionally sulfur or oxygen, said moiety having up to 20 non-hydrogen atoms, and optionally Cp* and Z together form a fused ring system;
  • X independently each occurrence is an anionic ligand group or neutral Lewis base ligand group having up to 30 non-hydrogen atoms;
  • n 0, 1, 2, 3, or 4 and is 2 less than the valence of M
  • XA*- is -XB(C6F 5 ) 3 .
  • This class of cationic complexes may be conveniently prepared by contacting a metal compound corresponding to the formula:
  • Cp*, M, and n are as previously defined, with tris(pentafluorophenyl)borane cocatalyst under conditions to cause abstraction of X and formation of the anion ⁇ XB(C6Fs)3.
  • X in the foregoing ionic catalyst is Ci-Cio hydrocarbyl, most preferably methyl.
  • the preceding formula is referred to as the limiting, charge separated structure.
  • the catalyst may not be fully charge separated. That is, the X group may retain a partial covalent bond to the metal atom, M.
  • the catalysts may be alternately depicted as possessing the formula:
  • the catalysts are preferably prepared by contacting the derivative of a Group 4 or Lanthanide metal with the tris(pentafluorophenyl)borane in an inert diluent such as an organic liquid.
  • Tris(pentafluorphenyl)borane is a commonly available Lewis add that may be readly prepared according to known techniques. The compound is disdosed in Marks, et al. T. Am. Chem. Soc. 1991, 113, 3623-3625 for use in alkyl abstraction of zirconocenes.
  • the metal atom is forced to greater exposure of the active metal site because one or more substituents on the single cydopentadienyl or substituted metal is both bonded to an adjacent covalent moiety and held in asso ation with the cydopentadienyl group through an or other ⁇ -bonding interaction. It is understood that each respective bond between the metal atom and the constituent atoms of the cydopentadienyl or substituted cydopentadienyl group need not be equivalent. That is, the metal may be symmetrically or unsymmetrically ⁇ -bound to the cydopentadienyl or substituted cydopentadienyl group.
  • the geometry of the active metal site is further defined as follows.
  • the centroid of the cydopentadienyl or substituted cydopentadienyl group may be defined as the average of the respective X, Y, and Z coordinates of the atomic centers forming the cydopentadienyl or substituted cydopentadienyl group.
  • the angle, ⁇ , formed at the metal center between the centroid of the cydopentadienyl or substituted cydopentadienyl group and each other ligand of the metal complex may be easily calculated by standard techniques of single crystal X-ray diffraction.
  • each of these angles may increase or decrease depending on the molecular structure of the constrained geometry metal complex.
  • one or more of the above angles, ⁇ decrease by at least 5 percent, more preferably 7.5 percent, compared to the comparative complex.
  • the average value of all bond angles, ⁇ is also less than in the comparative complex.
  • monocyclopentadienyl metal coordination complexes of group 4 or lanthanide metals according to the present invention have constrained geometry such that the smallest angle, ⁇ , between the centroid of the Cp* group and the Y substituent, is less than 115°, more preferably less than 110°, most preferably less than 105°, and especially less than 100°.
  • the improved melt elasticity and processibility of the substantially linear polymers according to the present invention result, it is believed, from their method of production.
  • the polymers may be produced via a continuous (as opposed to a batch) controlled polymerization process using at least one reactor, but can also be produced using multiple reactors (e.g., using a multiple reactor configuration as described in USP 3,914,342) at a polymerization temperature and pressure suffident to produce the interpolymers having the desired properties.
  • a batch reactor process typically operates at an ethylene concentration from about 6.7 to about 12.5 percent by weight of the reactor contents and have a polymer concentration generally less than about 5 percent by weight of the reactor contents, dependent upon the ethylene solubility, which is a function of reactor temperature and pressure.
  • the polymers are produced in a continuous process, as opposed to a batch process.
  • the polymerization temperature of the continuous process is from about 20°C to about 250°C, using constrained geometry catalyst technology.
  • Lf a narrow molecular weight distribution polymer (M w /M n of from about 1.5 to about 2.5) having a higher I10/I2 ratio (e.g. I10/I2 of 7 or more, preferably at least 8, espedally at least 9) is desired
  • the ethylene concentration in the reactor is preferably not more than about 8 percent by weight of the reactor contents, especially not more than about 6 percent by weight of the reactor contents, and most espedally not more than about 4 percent by weight of the reactor contents.
  • the polymerization is performed in a solution polymerization process.
  • manipulation of I10/I2 while holding M /M n relatively low for produdng the novel polymers described herein is a function of reactor temperature and/ or ethylene concentration. Reduced ethylene concentration and higher temperature generally produces higher I ⁇ o/l2- Generally, as the ethylene concentration of the reactor decreases, the polymer concentration increases.
  • the polymer concentration for a continuous solution polymerization process is preferably above about 5 weight percent of the reactor contents, especially above about 6 weight percent of the reactor contents.
  • olefins other than ethylene when using olefins other than ethylene as the primary monomer, suitable adjustments can be made regarding polymerization temperature, pressure and olefin concentration, depending on the olefin to be polymerized or copolymerized, but generally the olefin concentration is less than that normally useful in a batch reactor and the polymer concentration is higher than that normally useful in a batch reactor.
  • the substantially linear polymers of the present invention can be homopolymers of C2-C20 ⁇ -olefins, such as ethylene, propyiene, 4-methyl-l-pentene, etc., or they can be interpolymers of ethylene with at least one C 3 -C2 0 ⁇ -olefin and/or C 2 -C 20 acetylenically unsaturated monomer and/or C 4 -C 1 8 diolefins.
  • the substantially linear polymers of the present invention can also be interpolymers of ethylene with at least one of the above C3-C20 ⁇ -olefins, diolefins and/or acetylenically unsaturated monomers in combination with other unsaturated monomers.
  • Monomers usefully polymerized according to the present invention include, for example, ethylenically unsaturated monomers, acetylenic compounds, conjugated or nonconjugated dienes, polyenes, carbon monoxide, etc.
  • Preferred monomers include the C2-C 1 0 ⁇ - olefins especially ethylene, 1-propene, isobutylene, 1-butene, 1-hexene, 4-methyl-l-pentene, and 1-octene.
  • styrene halo- or alkyl substituted styrenes
  • tetrafluoroethylene vinylbenzocydobutane
  • 1,4-hexadiene 1,4-hexadiene
  • naphthenics e.g., cydo- pentene, cydo-hexene and cydo-octene
  • unsaturated monomers usefully polymerized according to the present invention include, for example, ethylenically unsaturated monomers, conjugated or nonconjugated dienes, polyenes, etc.
  • Preferred monomers indude the C2-C10 ⁇ -olefins espedally ethylene, propene, isobutylene, 1-butene, 1-hexene, 4- methyl-1-pentene, and 1-octene.
  • the polymerization conditions for manufacturing the polymers of the present invention are generally those useful in the solution polymerization process, although the application of the present invention is not limited thereto. Slurry and gas phase polymerization processes are also believed to be useful, provided the proper catalysts and polymerization conditions are employed.
  • Multiple reactor polymerization processes are also useful in the present invention, such as those disdosed in USP 3,914,342.
  • the multiple reactors can be operated in series or in parallel, with at least one constrained geometry catalyst employed in at least one of the reactors.
  • the continuous polymerization according to the present invention may be accomplished at conditions well known in the prior art for Ziegler-Natta or aminsky-Sinn type polymerization reactions, that is, temperatures from O to 250°C and pressures from atmospheric to 1000 atmospheres (100 MPa). Suspension, solution, slurry, gas phase or other process conditions may be employed if desired. A support may be employed but preferably the catalysts are used in a homogeneous (i.e., soluble) manner.
  • the active catalyst system espedally nonionic catalysts
  • the active catalyst system form in situ if the catalyst and the cocatalyst components thereof are added directly to the polymerization process and a suitable solvent or diluent, induding condensed monomer, is used in said polymerization process. It is, however, preferred to form the active catalyst in a separate step in a suitable solvent prior to adding the same to the polymerization mixture.
  • the polymerization conditions for manufacturing the polymers of the present invention are generally those useful in the solution polymerization process, although the application of the present invention is not limited thereto. Gas phase polymerization processes are also believed to be useful, provided the proper catalysts and polymerization conditions are employed.
  • Fabricated articles made from the novel olefin polymers may be prepared using all of the conventional polyolefin processing techniques.
  • Useful articles include films (e.g., cast, blown and extrusion coated), fibers (e.g., staple fibers (including use of a novel olefin polymer disclosed herein as at least one component comprising at least a portion of the fiber's surface), spunbond fibers or melt blown fibers (using, e.g., systems as disclosed in USP 4,340,563, USP 4,663,220, USP 4,668,566, or USP 4,322,027), and gel spun fibers (e.g., the system disclosed in USP 4,413,110)), both woven and nonwoven fabrics (e.g., spunlaced fabrics disclosed in USP 3,485,706) or structures made from such fibers (including, e.g., blends of these fibers with other fibers, e.g., PET or cotton) and molded articles (e.g., made using an injection
  • compositions are also suitably prepared comprising the substantially linear polymers of the present invention and at least one other natural or synthetic polymer.
  • Preferred other polymers include thermoplastics such as styrene-butadiene block copolymers, polystyrene (including high impact polystyrene), ethylene vinyl alcohol copolymers, ethylene acrylic acid copolymers, other olefin copolymers (espedally polyethylene copolymers) and homopolymers (e.g., those made using conventional heterogeneous catalysts).
  • examples indude polymers made by the process of USP 4,076,698, other linear or substantially linear polymers of the present invention, and inixtures thereof.
  • Other substantially linear polymers of the present invention and conventional HDPE and/or LLDPE are preferred for use in the thermoplastic compositions.
  • compositions comprising the substantially linear olefin polymers are formed by any convenient method, induding dry blending the individual components and subsequently melt mixing, either directly in the extruder used to make the finished artide (e.g., film), or by pre-melt mixing in a separate extruder.
  • the polyethylene compositions may also be prepared by multiple reactor polymerization tedmiques. For example, one reactor may polymerize the constrained geometry catalyzed polyethylene and another reactor polymerize the heterogeneous catalyzed polyethylene, either in series or in parallel operation.
  • compositions comprising the olefin polymers can also be formed into fabricated artides such as those previously mentioned using conventional polyolefin processing techniques which are well known to those skilled in the art of polyolefin processing.
  • Lithiated substituted cydopentadienyl compounds may be typically prepared from the corresponding cyclopentadiene and a lithium reagent such as n-butyl lithium.
  • a lithium reagent such as n-butyl lithium.
  • Titanium trichloride (TiCl3) was purchased from Aldrich Chemical Company.
  • the tetrahydrofuran adduct of titanium trichloride, TiCl3(THF)3 was prepared by refluxing ⁇ CI3 in THF overnight, cooling, and isolating the blue solid product, according to the procedure of L. E. Manzer, Inorg. Syn., 21, 135 (1982) .
  • the metal complex solution for Example 1 is prepared as follows:
  • the white powder was identified as [MgCl]2[Me4C5SiMe2N t Bu](THF) x (yield: 6.7 g)- Part 5: Prep of [C5Me4(SiMe2N t Bu)]TiCl2
  • the product is extracted with pentane (4x50 ml) and filtered.
  • the filtrate is combined and the pentane removed under vacuum giving the catalyst as a straw yellow solid.
  • reaction mixture is again cooled to -40°C and 27.81 ml of a 1.4 M MeMgBr solution in toluene/THF (75/25) was added via syringe and the reaction is now allowed to warm slowly to room temperature over 3 hours. After this time the solvent is removed under vacuum and the solid dried. At this point the reaction flask is brought back into the glove box where the product is extracted with pentane (4x50 ml) and filtered. The filtrate is combined and the pentane removed under vacuum giving the catalyst as a tan sohd. The metal complex is then dissolved into a mixture of C ⁇ -Cio saturated hydrocarbons (e.g., IsoparTM E, made by Exxon) and ready for use in polymerization.
  • C ⁇ -Cio saturated hydrocarbons e.g., IsoparTM E, made by Exxon
  • Examples 1-4 are produced in a solution polymerization process using a continuously stirred reactor. Additives (e.g., antioxidants, pigments, etc.) can be incorporated into the interpolymer products either during the pelletization step or after manufacture, with a subsequent re-extrusion. Examples 1-4 are each stabilized with 1250 ppm Calcium Stearate. 200 ppm Irganox 1010, and 1600 ppm Irgafos 168.
  • Additives e.g., antioxidants, pigments, etc.
  • IrgafosTM 168 is a phosphite stabilizer and IrganoxTM 1010 is a hindered polyphenol stabilizer (e.g., tetrakis [methylene 3-(3,5-ditert.butyl-4-hydroxyphenylpropionate)]methane. Both are trademarks of and made by Ciba-Geigy Corporation. A representative schematic for the polymerization process is shown in Figure 1.
  • the ethylene (4) and the hydrogen are combined into one stream (15) before being introduced into the 20 diluent mixture (3).
  • the diluent mixture comprises a mixture of Cs-Cio saturated hydrocarbons (1), (e.g., IsoparTM E, made by Exxon) and the comonomer(s) (2).
  • the comonomer is 1-octene.
  • the reactor feed mixture (6) is continuously 25 injected into the reactor (9).
  • the metal complex (7) and the cocatalyst (8) are combined into a single stream and also continuously injected into the reactor. Sufficient residence time is allowed for the metal complex and cocatalyst to react to the desired extent for use in the polymerization reactions, at least about 10 seconds.
  • the reactor pressure is held constant at about 490 psig. Ethylene content of the reactor, after reaching steady state, is maintained below about 8 percent.
  • the reactor exit stream (14) is introduced into a separator (10) where the molten polymer is separated from the unreacted comonomer(s), unreacted ethylene, unreacted hydrogen, and diluent mixture stream (13).
  • the molten polymer is subsequently strand chopped or pelletized and, after being cooled in a water bath or pelletizer (11), the solid pellets are collected (12).
  • Table 1 describes the polymerization conditions and the resultant polymer properties:
  • the Comonomer/Olefin ratio is defined as the percentage molar ratio of ((l-octene/(l- octene + ethylene))
  • Examples 5, 6 and comparison examples 7-9 with the same melt index are tested for rheology comparison.
  • Examples 5 and 6 are the substantially linear polyethylenes produced by the constrained geometry catalyst technology, as described in Examples 1-4.
  • Examples 5 and 6 are stablized as Examples 1-4.
  • Comparison examples 7, 8 and 9 are conventional heterogeneous Ziegler polymerization blown film resins DowlexTM 2045A, AttaneTM 4201, and AttaneTM 4403, respectively, all of which are ethylene/1-octene copolymers made by The Dow Chemical Company.
  • Comparative example 7 is stablized with 200 ppm IrganoxTM 1010, and 1600 ppm IrgafosTM 168 while comparative examples 8 and 9 are stablized with 200 ppm IrganoxTM 1010 and 800 ppm PEPQTM.
  • PEPQTM is a trademark of Sandoz Chemical, the primary ingredient of which is beheved to be tetrakis-(2,4-di-tertbutyl-phenyl)-4,4' biphenylphosphonite.
  • Example 5 and comparative example 7 with similar melt index and density are also extruded via a Gas Extrusion Rheometer (GER) at 190°C using a 0.0296" diameter, 20 L/D die.
  • the processing index (P.I.) is measured at an apparent shear stress of 2.15 x 10 ⁇ dyne/cm 2 as described previously.
  • the onset of gross melt fracture can easily be identified from the shear stress vs. shear rate plot shown in Figure 3 where a sudden jump of shear rate occurs.
  • a comparison of the shear stresses and corresponding shear rates before the onset of gross melt fracture is listed in Table 3.
  • Example 5 is more than 20 percent lower than the PI of comparative example 7 and that the onset of melt fracture or sharkskin for Example 5 is also at a significantly higher shear stress and shear rate in comparison with the comparative example 7. Furthermore, the Melt Tension (MT) as well as Elastic Modulus of Example 5 are higher than that of comparative example 7.
  • MT Melt Tension
  • Example 6 and comparison example 9 have similar melt index and density, but example 6 has lower I10/I2 (Table 4). These polymers are extruded via a Gas Extrusion Rheometer (GER) at 190°C using a 0.0296 inch diameter, 20:1 L/D die. The processing index (PI) is measured at an apparent shear stress of 2.15 x 10 ⁇ dyne/cm 2 as described previously.
  • GER Gas Extrusion Rheometer
  • the onset of gross melt fracture can easily be identified from the shear stress vs. shear rate plot shown in Figure 4 where a sudden increase of shear rate occurs at an apparent shear stress of about 3.23 x 10 ⁇ dyne/cm 2 (0.323 MPa).
  • a comparison of the shear stresses and corresponding shear rates before the onset of gross melt fracture is listed in Table 4.
  • the PI of Example 6 is surprisingly about the same as comparative example 9, even though the I10/I2 s lower for Example 6.
  • the onset of melt fracture or sharkskin for Example 6 is also at a significantly higher shear stress and shear rate in comparison with the comparative example 9.
  • the Melt Tension (MT) of Example 6 is higher than that of comparative example 9, even though the melt index for Example 6 is slightly higher and the Il ⁇ /l2 is slightly lower than that of comparative example 9.
  • a 2 L stirred autoclave was charged with the desired amounts of a mixed alkane solvent (Isopar® E, available from Exxon Chemicals, Inc.) and 1-octene comonomer.
  • the reactor was heated to the polymerization temperature. Hydrogen was added by differential pressure expansion from a 75 ml addition tank.
  • hydroxide ⁇ psi represents the difference in pressure between the starting and final pressure in the hydrogen addition tank after adding hydrogen to the 21 reactor containing a total of approximately 1200 ml of solvent and 1-octene.
  • the reactor was heated to the polymerization temperature and was saturated with ethylene to the desired pressure.
  • a constant ethylene/solvent pressure of about 500 psig at a temperature of 140 °C corresponds to an ethylene concentration of about 8.4 percent by weight of the reactor contents.
  • Metal complex and cocatalyst were mixed in a drybox by syringing the desired amount of 0.0050 M metal complex solution (in Isopar® E or toluene) into a solution of the cocatalyst (in Isopar® E or toluene). This solution was then transferred to a catalyst addition tank and injected into the reactor. The polymerization was allowed to proceed for the desired time and then the solution was drained from the bottom of the reactor and quenched with isopropanol. About 100 mg of a hindered phenolic antioxidant (Irganox® 1010, available from Ciba-Geigy corporation) was added and the polymer was air dried overnight. The residual solvent was removed in a vacuum oven overnight. The results are shown in Table 5 and 5A:
  • A metal complex of [(C5Me4)SiMe2N(t-Bu)] TiMe2 (as in USP '802)
  • A metal complex of [(C5Me4)SiMe2N(t-Bu)] TiMe2 (as in USP '802)
  • B metal complex of [(C5Me4)SiMe2N(t-Bu)] TiCl2 (as in USP 798)
  • *** methyl aluminoxane (MAO) (as in USP 798)
  • Reactor temperature is constant at about 140 °C
  • Ethylene/solvent pressure is constant at about 500 psig Run time is about 15 minutes
  • the samples were each extruded via a Gas Extrusion Rheometer (GER) at 190°C using 0.0296 inch diameter die having L/D of 20 and entrance angle of 180°, as shown in the attached drawing.
  • GER Gas Extrusion Rheometer
  • the OGMF can easily be identified from the shear stress vs. shear rate plot where a sudden jump of shear rate occurs or when the surface of the extrudate becomes very rough or irregular, or from deep ridges which can be dearly detected by visual observation.
  • OSMF is characterized by fine scale surface irregularities ranging from loss of surface gloss to the more severe form of matte or sharkskin which can easily be seen using microscopy at a magnification of 10X.
  • Comparative Examples 10 - 16 were prepared using the catalyst composition as described in U.S. Patent 5,064,802 (Stevens et al.) as described above.
  • Comparative Examples 17 - 19 were prepared using the catalyst composition described in U.S. Patent 5,026,798 (Canich), as described above. All of the Comparative Polymer Examples made using a batch reactor at an ethylene concentration of about 8.4 percent by weight of the reactor contents or more tested had onset of gross melt fracture at a shear stress of less than or equal to 0.344 MPa (3.44 x 10 6 dynes/cm 2 ).
  • Blown film is fabricated from two novel ethylene/1-octene polymers made in accordance with the present invention and from two comparative conventional polymers made according to conventional Ziegler catalysis.
  • the blown films are tested for physical properties, including heat seal strength versus heat seal temperature (shown in Figure 5 for Examples 20 and 22 and comparative examples 21 and 23), machine (MD) and cross direction (CD) properties (e.g., tensile yield and break, elongation at break and Young's modulus).
  • MD machine
  • CD cross direction
  • Other film properties such as dart, puncture, tear, clarity, haze, 20 degree (20°) gloss and block are also tested.
  • the melt temperature is kept constant by changing the extruder temperature profile.
  • Frost line height is maintained at 12.5 inches (31.7 cm) by adjusting the air flow.
  • the extruder output rate, back pressure and power consumption in amps are monitored throughout the experiment.
  • the polymers of the present invention and the comparative polymers are all ethylene /1-octene copolymers. Table 7 summarizes physical properties of the two polymers of the invention and for the two comparative polymers:
  • Tables 8 and 9 summarize the film properties measured for blown film made from two of these four polymers:
  • the extruder back pressure is about 3500 psi at about 58 amps power consumption for comparative example 21 and about 2550 psi at about 48 amps power consumption for example 20, thus showing the novel polymer of e., ample 10 to have improved processability over that of a conventional heterogeneous Ziegler polymerized polymer.
  • the throughput is also higher for Example 20 than for comparative example 21 at the same screw speed.
  • example 20 has higher pumping efficiency than comparative example 11 (i.e., more polymer goes through per turn of the screw).
  • the polymer products of Examples 1 and 3 are produced in a continuous solution polymerization process using a continuously stirred reactor, as described in copending U.S. apphcation serial number 07/776,130, filed October 15, 1991.
  • the metal complex [C5Me (SiMe2N t Bu)]TiMe2 is prepared as described in copending U.S. apphcation serial number 07/776,130 and the cocatalysts used are tris(pentafluorophenyl) borane (B:Ti ratio of 2:1) and MMAO (Al:Ti ratio of 4:1).
  • B:Ti ratio of 2:1 tris(pentafluorophenyl) borane
  • MMAO Al:Ti ratio of 4:1
  • Additives can be incorporated into the interpolymer products either during the pelletization step or after manufacture, with a subsequent re-extrusion.
  • Examples 24 and 25 are each stabilized with 1250 ppm Calcium Stearate, 200 ppm Irganox 1010, and 1600 ppm Irgafos 168.
  • IrgafosTM 168 is a phosphite stabilizer and IrganoxTM 1010 is a hindered polyphenol stabilizer (e.g., tetrakis [methylene 3-(3,5-ditert.butyl-4- hydroxyphenylpropionate)]methane. Both are trademarks of and made by Ciba-Geigy Corporation.
  • Example 24 is an ethylene/1-octene elastic substantially linear olefin polymer produced as described herein.
  • Comparative Example 26 is an ethylene/ 1-butene copolymer trademarked ExactTM made by Exxon Chemical containing butylated hydroxy toluene (BHT) and IrganoxTM 1076 as polymeric stabilizers. Table 10 summarizes physical properties and rheological performance of example 24 and comparative example 26: Table 10
  • Example 24 and Comparative Example 26 have very similar molecular weight distributions (M w /M n ), I2 and density.
  • Example 24 has a much lower processing index (PI) (38 percent of the PI of Comparative Example 26), a much higher onset of surface melt fracture (264 percent increase in OSMF) and an elastic modulus an order of magnitude higher than Comparative Example 26, demonstrating that Example 24 has much better processability and higher melt elasticity than Comparative Example 26.
  • PI processing index
  • Elastic modulus is indicative of a polymer's melt stability, e.g., more stable bubbles when making blown film and less neck-in. Resultant physical properties of the finished film are also higher. Onset of surface melt fracture is easily identified by visually observing the surface extrudate and noting when the extrudate starts losing gloss and small surface roughness is detected by using 40X magnification.
  • Dynamic shear viscosity of the polymers is also used to show differences between the polymers and measures viscosity change versus shear rate.
  • a Rheometrics Mechanical Spectrometer (Model RMS 800) is used to measure viscosity as a function of shear rate.
  • the RMS 800 is used at 190°C at 15 percent strain and a frequency sweep (i.e., from 0.1-100 rad/sec) under a nitrogen purge.
  • the parallel plates are positioned such that they have a gap of about 1.5-2 mm.
  • Data for Example 24 and Comparative Example 26 are listed in Table 11 and graphically displayed in Figure 6.
  • Example 24 shows a shear thinning behaviour, even though Example 24 has a narrow molecular weight distribution.
  • Comparative Example 26 shows the expected behaviour of a narrow molecular weight distribution polymer, with a flatter viscosity/shear rate curve.
  • elastic substantially linear olefin polymers made in accordance with the present invention have lower melt viscosity than a typical narrow molecular weight distribution linear copolymer made by single site catalyst technology at the melt processing shear rate region of commerdal interest.
  • novel elastic substantially linear olefin polymers have a higher low shear/zero shear viscosity than the Comparative linear polymer, thus demonstrating that the copolymers of the invention have higher "green strength" which is useful for forming and maintaining blended compositions such as those used in the wire and cable coating industry, where the compounded materials must maintain their integrity at low or zero shear without segregating the components.
  • Example 25 is an ethylene/1-octene elastic substantially linear olefin polymer produced in a continuous solution polymerization process as described herein.
  • Comparative Example 27 is an ethylene/propene copolymer made by Mitsui Petrochemical Corporation and trademarked TafmerTM P-0480. Table 12 summarizes physical properties and rheological performance of these two polymers:
  • Example 25 and Comparative Example 27 have similarly narrow molecular weight distributions (M w /M n ), I2, and density, Example 25 has a PI which is 28 percent of that of Comparative Example 27, a 743 percent increase in onset of surface melt fracture and a higher elastic modulus than Comparative Example 27, demonstrating that Example 24 has much better processability than Comparative Example 27.
  • Onset of surface melt fracture is easily identified by visually observing the surface extrudate and noting when the extrudate starts losing gloss and small surface roughness is detected by using 40X magnification. Examples 28-37
  • Examples 28-35 are ethylene/propene copolymers made using the constrained geometry catalyst described herein and in a continuous solution polymerization process.
  • Examples 36 and 37 are ethylene/1- butene copolymers made using the constrained geometry catalyst described herein and in a continuous solution polymerization process.
  • Examples 28-35 each contained approximately 1250 ppm caldum strearate and 200 ppm Irganox 1010. Table 13 and 13A describe the polymerization conditions and Table 14 describes the resultant polymer physical properties for Examples 28-35:
  • Figure 7 graphically displays a best fit line drawn through a plot of the I10/I2 ratio for the ethylene/propene substantially linear polymers of examples 28-35 as a function of ethylene concentration in the polymerization reactor.
  • Table 16 and 16A describe the polymerization conditions and Table 17 describes the resultant polymer physical properties for ethylene/1- butene copolymer Examples 36 and 37:
  • Table 18 shows the critical shear stress and critical shear rate at OGMF and OSMF for examples 36 and 37:
  • Example 4 is essentially repeated except that propyiene is substituted for ethylene in the polymerization.
  • Example 1 is essentially repeated except that propyiene is copolymerized with at least one C2-C20 cc-olefin in the p olymerization.

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DE69220077T DE69220077T2 (de) 1991-10-15 1992-10-15 Elastische, im wesentlichen lineare olefinpolymere
DE9219173U DE9219173U1 (de) 1991-10-15 1992-10-15 Elastische, im wesentlichen lineare Olefinpolymere
EP19920922757 EP0608369B1 (en) 1991-10-15 1992-10-15 Elastic substantially linear olefin polymers
KR1019997010981A KR100263803B1 (ko) 1991-10-15 1992-10-15 탄성을 갖는 실질적인 선형 올레핀 중합체
CA 2120766 CA2120766C (en) 1991-10-15 1992-10-15 Elastic substantially linear olefin polymers
JP50780592A JP2963199B2 (ja) 1991-10-15 1992-10-15 弾性で実質的に線状であるオレフィンポリマー
KR1019940701216A KR100262024B1 (ko) 1991-10-15 1992-10-15 탄성을 갖는 실질적인 선형 올레핀 중합체
DE9219090U DE9219090U1 (de) 1991-10-15 1992-10-15 Elastische, im wesentlichen lineare Olefinpolymere
FI941727A FI112663B (fi) 1991-10-15 1994-04-14 Elastiset, oleellisesti suorat olefiinipolymeerit
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Cited By (232)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1993025590A1 (en) * 1992-06-15 1993-12-23 Exxon Chemical Patents Inc. High temperature polymerization process using ionic catalysts to produce polyolefins
WO1994009060A1 (en) * 1992-10-14 1994-04-28 The Dow Chemical Company Film for packaging purposes
EP0600425A1 (en) 1993-09-20 1994-06-08 W.R. Grace & Co.-Conn. Heat shrinkable films containing single site catalyzed copolymers having long chain branching
WO1994013715A1 (en) * 1992-12-17 1994-06-23 Exxon Chemical Patents Inc. Dilute process for the preparation of ethylene/alpha-olefin copolymer using metallocene catalyst systems
WO1994017112A3 (en) * 1993-01-29 1994-09-15 Dow Chemical Co Ethylene interpolymerizations
US5359105A (en) * 1993-11-01 1994-10-25 Albemarle Corporation Deprotonation of cyclopentadienyl derivatives
WO1994025647A1 (en) * 1993-04-27 1994-11-10 The Dow Chemical Company Elastic fibers, fabrics and articles fabricated therefrom
WO1995000587A1 (en) * 1993-06-24 1995-01-05 The Dow Chemical Company Pouch for packaging flowable materials
WO1995001250A1 (en) * 1993-06-29 1995-01-12 The Dow Chemical Company High drawdown extrusion process
WO1995005427A1 (en) * 1993-08-18 1995-02-23 The Dow Chemical Company Gaskets made from homogeneous linear olefin polymers
WO1995005418A1 (en) * 1993-08-17 1995-02-23 The Dow Chemical Company Elastic materials and articles therefrom
WO1995005426A1 (en) * 1993-08-18 1995-02-23 The Dow Chemical Company Gaskets made from elastic substantially linear olefin polymers
WO1995007314A1 (en) * 1993-09-08 1995-03-16 The Dow Chemical Company Batch inclusion packages
WO1995007942A1 (en) * 1993-09-17 1995-03-23 The Dow Chemical Company Gas phase polymerization of olefins
WO1995007939A1 (en) 1993-09-17 1995-03-23 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
US5408017A (en) * 1987-01-30 1995-04-18 Exxon Chemical Patents Inc. High temperature polymerization process using ionic catalysts to produce polyolefins
WO1995010566A1 (en) * 1993-10-14 1995-04-20 Dupont Canada Inc. Pouches of ethylene copolymer film containing a flowable material
EP0659773A1 (en) * 1993-12-21 1995-06-28 Union Carbide Chemicals & Plastics Technology Corporation Production of polyolefins containing long chain branches by a gas phase process
WO1995021743A1 (en) * 1994-02-08 1995-08-17 Dupont Canada Inc. Multilayer ethylene copolymer film
EP0669347A1 (en) * 1994-02-18 1995-08-30 Mitsui Petrochemical Industries, Ltd. Ethylene polymer, process for preparing the same, solid titanium catalyst component for ethylene polymerization and ethylene polymerization catalyst
WO1995025766A1 (de) * 1994-03-20 1995-09-28 Techno-Polymer Hans-Joachim Kuhl Thermoplastische formmasse, verfahren zu ihrer herstellung und ihre verwendung
US5470927A (en) * 1987-01-30 1995-11-28 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
WO1995033006A1 (en) * 1994-06-01 1995-12-07 The Dow Chemical Company Thermoelastic blend compositions
US5475075A (en) * 1991-12-13 1995-12-12 Exxon Chemical Patents Inc. Ethylene/longer α-olefin copolymers
WO1995033779A1 (en) * 1994-06-09 1995-12-14 Exxon Chemical Patents Inc. DILUTE PROCESS FOR THE POLYMERIZATION OF NON-ETHYLENE α-OLEFIN HOMOPOLYMERS AND COPOLYMERS USING METALLOCENE CATALYST SYSTEMS
WO1996003441A1 (en) * 1994-07-25 1996-02-08 The Dow Chemical Company Chlorinated and chlorosulfonated elastic substantially linear olefin polymers
WO1996007680A1 (en) * 1994-09-07 1996-03-14 The Dow Chemical Company Plastic linear low density polyethylene
EP0701897A2 (en) 1994-09-16 1996-03-20 W.R. Grace & Co.-Conn. Thermoplastic multilayer film for use in packaging water
EP0708117A1 (en) * 1994-10-03 1996-04-24 Sumitomo Chemical Company Limited Process for producing copolymer rubber
WO1996012744A1 (en) * 1994-10-24 1996-05-02 Exxon Chemical Patents Inc. Long-chain branched polymers and their production
WO1996016119A1 (en) * 1994-11-14 1996-05-30 The Dow Chemical Company Extrusion compositions having high drawdown and substantially reduced neck-in
WO1996016093A2 (en) 1994-11-23 1996-05-30 Exxon Chemical Patents Inc. Method for making supported catalyst systems, and catalyst systems therefrom
US5556697A (en) * 1994-03-24 1996-09-17 Bicc Cables Corporation Semiconductive power cable shield
US5558802A (en) * 1995-09-14 1996-09-24 Exxon Chemical Patents Inc Multigrade crankcase lubricants with low temperature pumpability and low volatility
US5565128A (en) * 1994-10-12 1996-10-15 Exxon Chemical Patents Inc Lubricating oil mannich base dispersants derived from heavy polyamine
DE19516801A1 (de) * 1995-05-08 1996-11-14 Hoechst Ag Organometallverbindung
NL1000687C2 (en) * 1995-06-29 1996-12-31 Dsm Nv Ethylene-~a-olefin(-diene) copolymer for prodn. of thermoplastic elastomers
US5589561A (en) * 1989-06-27 1996-12-31 The Dow Chemical Company Bioriented blown film
WO1997001586A1 (en) * 1995-06-29 1997-01-16 Dsm N.V. Elastomeric copolymer
EP0706455A4 (en) * 1993-06-24 1997-02-26 American National Can Co IMPROVED STRUCTURES OF POLYMERS PRODUCED USING SINGLE SITE CATALYSTS
US5614297A (en) * 1994-05-19 1997-03-25 Viskase Corporation Polyolefin stretch film
US5621126A (en) * 1987-01-30 1997-04-15 Exxon Chemical Patents Inc. Monocyclopentadienyl metal compounds for ethylene-α-olefin-copolymer production catalysts
US5629059A (en) * 1992-12-18 1997-05-13 W.R. Grace & Co.-Conn. Multi-layer packaging film and receptacles made therefrom
US5631391A (en) * 1989-09-13 1997-05-20 Canich; Jo Ann M. Monocyclopentadienyl titanium metal compounds for ethylene-α-olefin-copolymer production catalysts
WO1997019965A1 (en) * 1995-11-30 1997-06-05 The Dow Chemical Company Mono-olefin/polyene interpolymers, method of preparation, compositions containing the same, and articles made thereof
US5648438A (en) * 1994-04-01 1997-07-15 Exxon Chemical Patents, Inc. Process for producing polymers with multimodal molecular weight distributions
US5648310A (en) * 1993-12-23 1997-07-15 Union Carbide Chemicals & Plastics Technology Corporation Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture
US5652202A (en) * 1995-08-15 1997-07-29 Exxon Chemical Patents Inc. Lubricating oil compositions
EP0690079A4 (en) * 1993-02-22 1997-08-20 Idemitsu Kosan Co ETHYLENE COPOLYMER, THERMOPLASTIC RESIN COMPOSITION CONTAINING THIS AND METHOD FOR THE PRODUCTION THEREOF
EP0683184A4 (en) * 1993-02-05 1997-08-20 Idemitsu Kosan Co POLYETHYLENE, THERMOPLASTIC RESIN COMPOSITION CONTAINING THE SAME AND METHOD FOR PRODUCING POLYETHYLENE.
WO1997032946A1 (en) * 1996-03-08 1997-09-12 Dupont Dow Elastomers L.L.C. Substantially linear ethylene/alpha-olefin polymers as viscosity index improvers or gelling agents
US5672669A (en) * 1993-12-23 1997-09-30 Union Carbide Chemicals & Plastics Technology Corporation Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture
US5674950A (en) * 1994-03-07 1997-10-07 Exxon Chemical Patents Inc. Polymers having terminal hydroxyl aldehyde, or alkylamino substitutents and derivatives thereof
US5677383A (en) * 1991-10-15 1997-10-14 The Dow Chemical Company Fabricated articles made from ethylene polymer blends
WO1997042237A1 (en) * 1996-05-03 1997-11-13 Dsm N.V. A process for making polyolefins having broad molecular weight distributions
WO1997042232A1 (en) * 1996-05-03 1997-11-13 Dsm N.V. Process for the polymerisation of alpha-olefins
WO1997042240A1 (en) * 1996-05-03 1997-11-13 Dsm N.V. Process for the co-polymerization of an olefin and a vinyl aromatic monomer
WO1997042239A1 (en) * 1996-05-03 1997-11-13 Dsm N.V. PROCESS FOR THE PREPARATION OF A TERPOLYMER OF ETHYLENE, AN α-OLEFIN AND A DIENE
WO1997042241A1 (en) * 1996-05-03 1997-11-13 Dsm N.V. PROCESS FOR THE PREPARATION OF AN ETHYLENE AND α-OLEFIN COPOLYMER
US5691422A (en) * 1994-03-07 1997-11-25 Exxon Chemical Patents Inc. Saturated polyolefins having terminal aldehyde or hydroxy substituents and derivatives thereof
EP0727446A4 (en) * 1993-10-26 1998-02-11 Idemitsu Kosan Co BRANCHED ETHYLENIC MACROMONOMER AND POLYMER PRODUCED THEREFROM
WO1998020062A1 (en) * 1996-11-06 1998-05-14 The Dow Chemical Company Films useful in the modified atmosphere packaging of perishable food
US5759648A (en) * 1996-07-05 1998-06-02 Viskase Corporation Multilayer plastic film, useful for packaging a cook-in foodstuff
WO1998032784A1 (en) * 1997-01-29 1998-07-30 The Dow Chemical Company Heteromorphic polymer compositions
US5792730A (en) * 1994-07-11 1998-08-11 Exxon Chemical Patents, Inc. Lubricating oil succinimide dispersants derived from heavy polyamine
US5798427A (en) * 1995-05-16 1998-08-25 Union Carbide Chemicals & Plastics Technology Corporation Ethylene polymers having enhanced processability
WO1998038376A1 (en) * 1997-02-28 1998-09-03 Shaw Industries, Inc. Carpet, carpet backings and methods
US5804667A (en) * 1994-06-17 1998-09-08 Exxon Chemical Patents Inc. Dispersant additives and process
WO1998049211A1 (en) * 1997-05-01 1998-11-05 The Dow Chemical Company Olefin polymers prepared with substituted indenyl containing metal complexes
US5834077A (en) * 1994-10-04 1998-11-10 W. R. Grace & Co.-Conn. High shrink multilayer film which maintains optics upon shrinking
US5837335A (en) * 1994-10-04 1998-11-17 Cryovac, Inc. High shrink multilayer film which maintains optics upon shrinking
US5847053A (en) * 1991-10-15 1998-12-08 The Dow Chemical Company Ethylene polymer film made from ethylene polymer blends
WO1998038374A3 (en) * 1997-02-28 1998-12-10 Dow Chemical Co Carpet, carpet backing and method for making same using homogeneously branched ethylene polymer
US5852143A (en) * 1995-05-16 1998-12-22 Union Carbide Chemicals & Plastics Technology Corporation Production of polyethylene using stereoisomeric metallocenes
US5859159A (en) * 1992-12-17 1999-01-12 Exxon Chemical Patents Inc. Dilute process for the polymerization of non-ethylene α-olefin homopolymers and copolymers using metallocene catalyst systems
US5869575A (en) * 1995-08-02 1999-02-09 The Dow Chemical Company Ethylene interpolymerizations
US5874139A (en) * 1994-10-21 1999-02-23 The Dow Chemical Company Multilayer polyolefin with balanced sealant properties
US5889121A (en) * 1995-10-06 1999-03-30 Shell Oil Company Method for improving processability of thermoplastics
US5925430A (en) * 1995-01-31 1999-07-20 Owens-Illinois Closure Inc. Lined plastic closure
US5929128A (en) * 1993-08-18 1999-07-27 The Dow Chemical Company Gaskets made from olefin polymers
WO1999051666A1 (en) * 1998-04-03 1999-10-14 Minnesota Mining And Manufacturing Company Anisotropic film
WO2000014129A1 (en) * 1998-09-04 2000-03-16 The Dow Chemical Company Long chain branched ethylene homopolymer made by a slurry process and blends thereof
US6060567A (en) * 1991-10-15 2000-05-09 The Dow Chemical Company Interpolymers formed by continuous processes
WO2000034385A1 (en) * 1998-12-08 2000-06-15 The Dow Chemical Company Mel-bondable polypropylene/ethylene polymer fiber and composition for making the same
US6136995A (en) * 1997-11-07 2000-10-24 Sumitomo Chemical Company, Limited Process for producing aminosilane compounds
US6136930A (en) * 1992-04-09 2000-10-24 Exxon Chemical Patents, Inc. Polymerization catalysts, their production and use
US6140442A (en) * 1991-10-15 2000-10-31 The Dow Chemical Company Elastic fibers, fabrics and articles fabricated therefrom
WO2001005852A1 (en) * 1999-07-15 2001-01-25 The Dow Chemical Company High density ethylene homopolymers and blend compositions
US6187424B1 (en) 1997-08-08 2001-02-13 The Dow Chemical Company Sheet materials suitable for use as a floor, wall or ceiling covering material, and processes and intermediates for making the same
US6204328B1 (en) 1997-05-26 2001-03-20 Chisso Corporation Polyolefin resin composition
US6214954B1 (en) 1994-12-13 2001-04-10 Asahi Kasei Kogyo Kabushiki Kaisha Olefin polymerization catalyst
US6218470B1 (en) 1994-06-01 2001-04-17 The Dow Chemical Company Thermoplastic elastomeric blends
US6232377B1 (en) 1999-02-19 2001-05-15 Nippon Unicar Company Ltd. Flame retardant composition
EP0696302B2 (en) † 1993-04-28 2001-06-27 The Dow Chemical Company Paintable olefinic interpolymer compositions
US6255426B1 (en) 1997-04-01 2001-07-03 Exxon Chemical Patents, Inc. Easy processing linear low density polyethylene
US6258912B1 (en) 1994-04-07 2001-07-10 Bp Chemicals Limited Polyolefin
US6278032B1 (en) 1998-06-11 2001-08-21 Societa' Italiana Additivi Per Carburanti S.R.L. Ethylene polymers with α-olefins
US6313241B1 (en) 1997-10-01 2001-11-06 Cryovac, Inc. Narrow molecular weight distribution copolymers containing long chain branches and process to form same
US6316549B1 (en) 1991-10-15 2001-11-13 The Dow Chemical Company Ethylene polymer fiber made from ethylene polymer blends
US6323285B1 (en) 1998-01-09 2001-11-27 The Dow Chemical Company Heteromorphic polymer compositions
US6355757B2 (en) 1997-02-14 2002-03-12 Exxonmobil Chemical Patents, Inc. Processing olefin copolymers
US6403710B1 (en) 1994-08-29 2002-06-11 The Dow Chemical Company Block copolymer compositions containing substantially inert thermoelastic extenders
US6413900B1 (en) 1995-08-10 2002-07-02 Exxonmobil Chemical Patents Inc. Metallocene stabilized alumoxane
USRE37788E1 (en) * 1987-01-30 2002-07-09 Exxon Chemical Patents, Inc. Monocyclopentadienyl metal compounds for ethylene-α-olefin-copolymer production catalysts
US6462134B1 (en) 1998-07-07 2002-10-08 Basell Polyolefine Gmbh Polyethylene compositions having improved optical and mechanical properties and improved processability in the melted state
US6500508B2 (en) 1996-12-16 2002-12-31 Sumitomo Electric Fine Polymer, Inc. Flame-retardant resin composition, and insulated wire, shielded wire and insulating tube comprising the composition
US6514583B1 (en) 1992-11-13 2003-02-04 Cryovac, Inc. High impact strength film containing single site catalyzed copolymer
WO2003014437A1 (en) * 2001-08-08 2003-02-20 Toyo Boseki Kabushiki Kaisha High-strength polyethylene fiber
US6545088B1 (en) 1991-12-30 2003-04-08 Dow Global Technologies Inc. Metallocene-catalyzed process for the manufacture of EP and EPDM polymers
US6583240B2 (en) 2001-05-23 2003-06-24 Equistar Chemicals, Lp Ethylene polymerization process
US6667351B2 (en) 1998-05-18 2003-12-23 Dow Global Technologies Inc. Articles having elevated temperature elasticity made from irradiated and crosslinked ethylene polymers and method for making the same
US6680265B1 (en) 1999-02-22 2004-01-20 Kimberly-Clark Worldwide, Inc. Laminates of elastomeric and non-elastomeric polyolefin blend materials
WO2004031292A2 (en) 2002-10-02 2004-04-15 Dow Global Technologies Inc. POLYMER COMPOSITIONS COMPRISING A LOW VISCOSITY, HOMOGENEOUSLY BRANCHED ETHYLENE/α-OLEFIN EXTENDER
US6727331B2 (en) 2001-12-28 2004-04-27 Equistar Chemicals, Lp Preparation of polyethylene
WO2004046214A2 (en) 2002-10-15 2004-06-03 Exxonmobil Chemical Patents Inc. Multiple catalyst system for olefin polymerization and polymers produced therefrom
EP0705849B2 (en) † 1993-06-15 2004-06-16 Idemitsu Kosan Company Limited Process for producing olefin polymer and catalyst for olefin polymerization
US6770360B2 (en) 1998-06-12 2004-08-03 Avery Dennison Corporation Multilayered thermoplastic film and sign cutting method using the same
WO2004094487A1 (en) 2003-03-21 2004-11-04 Dow Global Technologies, Inc. Morphology controlled olefin polymerization process
US6858106B1 (en) 2000-05-26 2005-02-22 Tetra Laval Holdings & Finance S.A. Process for producing packaging laminate
RU2248885C2 (ru) * 1998-09-01 2005-03-27 Печини Пластик Пэкэджинг, Инк. Усовершенствованные структуры из полимеров, полученных с применением катализаторов с одним активным центром
WO2005082947A1 (en) 2004-02-17 2005-09-09 Univation Technologies, Llc De-foaming spray dried catalyst slurries
WO2005113622A1 (en) 2004-04-15 2005-12-01 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
EP1624000A1 (en) 1999-05-06 2006-02-08 Univation Technologies, LLC A polymerization process for producing easier processing polymers
US7153909B2 (en) 1994-11-17 2006-12-26 Dow Global Technologies Inc. High density ethylene homopolymers and blend compositions
WO2007008361A1 (en) 2005-07-11 2007-01-18 Equistar Chemicals, Lp Polyethylene compositions
US7208559B2 (en) 2002-12-27 2007-04-24 Mitsui Chemicals, Inc. Ethylened polymer and molded object obtained therefrom
EP1803747A1 (en) 2005-12-30 2007-07-04 Borealis Technology Oy Surface-modified polymerization catalysts for the preparation of low-gel polyolefin films
EP1878757A1 (en) 1999-06-17 2008-01-16 Mitsui Chemicals, Inc. Ethylene (co)polymer and its use
EP1914252A1 (en) 1999-12-16 2008-04-23 Univation Technologies, LLC Method of polymerization
EP1935909A1 (en) * 2006-12-21 2008-06-25 Ineos Europe Limited Copolymers and films thereof
US7422786B2 (en) 2003-09-24 2008-09-09 Exxonmobil Chemical Patents Inc. Collation shrink
US7456244B2 (en) 2006-05-23 2008-11-25 Dow Global Technologies High-density polyethylene compositions and method of making the same
EP2112175A1 (en) 2008-04-16 2009-10-28 ExxonMobil Chemical Patents Inc. Activator for metallocenes comprising one or more halogen substituted heterocyclic heteroatom containing ligand coordinated to an alumoxane
EP2172490A1 (en) 2008-10-03 2010-04-07 Ineos Europe Limited Controlled polymerisation process
US7700708B2 (en) 2003-02-17 2010-04-20 Mitsui Chemicals, Inc. Ethylene polymer and application thereof to moldings
EP2177548A1 (en) 2008-10-14 2010-04-21 Ineos Europe Limited Copolymers and films thereof
WO2010071798A1 (en) 2008-12-18 2010-06-24 Univation Technologies, Llc Method for seed bed treatment for a polymerization reaction
WO2010088265A1 (en) 2009-01-30 2010-08-05 Dow Global Technologies Inc. High-density polyethylene compositions, method of producing the same, closure devices made therefrom, and method of making such closure devices
EP2218751A1 (en) 2004-12-17 2010-08-18 Dow Global Technologies Inc. Rheology modified polyethylene compositions
WO2010094450A1 (en) 2009-02-20 2010-08-26 Basell Polyolefine Gmbh Ethylene copolymers, catalyst system and process for preparing the same
US7813606B2 (en) 2007-01-24 2010-10-12 The Furukawa Electric Co., Ltd. Optical fiber cable
US7858723B2 (en) 2005-01-31 2010-12-28 Mitsui Chemicals, Inc. Ethylene-based resin and molded object obtained therefrom
WO2011002998A1 (en) 2009-07-01 2011-01-06 Dow Global Technologies Inc. Ethylenic polymer and its use
WO2011002986A1 (en) 2009-07-01 2011-01-06 Dow Global Technologies Inc. Ethylenic polymer and its use
US7981517B2 (en) 2007-08-28 2011-07-19 Dow Global Technologies Inc. Bituminous compositions and methods of making and using same
WO2011085937A1 (en) 2010-01-13 2011-07-21 Ineos Europe Limited Polymer powder storage and/or transport and/or degassing vessels
EP2383298A1 (en) 2010-04-30 2011-11-02 Ineos Europe Limited Polymerization process
EP2383301A1 (en) 2010-04-30 2011-11-02 Ineos Europe Limited Polymerization process
WO2012072417A1 (en) 2010-11-29 2012-06-07 Ineos Commercial Services Uk Limited Polymerisation control process
WO2012074710A1 (en) 2010-11-30 2012-06-07 Univation Technologies, Llc. Catalyst composition having improved flow characteristics and methods of making and using the same
WO2012074709A1 (en) 2010-11-30 2012-06-07 Univation Technologies, Llc Processes for the polymerization of olefins with extracted metal carboxylate salts
US8202953B2 (en) 2006-05-17 2012-06-19 Dow Global Technologies Llc High efficiency solution polymerization process
WO2012087560A1 (en) 2010-12-22 2012-06-28 Univation Technologies, Llc Additive for polyolefin polymerization processes
US8299193B2 (en) 2006-07-31 2012-10-30 Mitsui Chemicals, Inc. Film or laminate comprising ethylene-based resin or ethylene-based resin composition
WO2012158260A1 (en) 2011-05-13 2012-11-22 Univation Technologies, Llc Spray-dried catalyst compositions and polymerization processes employing the same
US8318872B2 (en) 2007-12-18 2012-11-27 Univation Technologies, Llc Method for controlling bimodal catalyst activity during polymerization
WO2013025351A1 (en) 2011-08-12 2013-02-21 Ineos Usa Llc Apparatus for stirring polymer particles
WO2013056979A1 (en) 2011-10-17 2013-04-25 Ineos Europe Ag Polymer degassing process control
WO2013070601A2 (en) 2011-11-08 2013-05-16 Univation Technologies, Llc Methods of preparing a catalyst system
US8445594B2 (en) 2006-05-02 2013-05-21 Dow Global Technologies Llc High-density polyethylene compositions, method of making the same, articles made therefrom, and method of making such articles
WO2013099927A1 (ja) 2011-12-28 2013-07-04 三井化学株式会社 エチレン系重合体組成物、及びこれから得られる成形体
US8722832B2 (en) 2007-12-19 2014-05-13 Basell Polyolefine Gmbh Ethylene terpolymers
WO2014105614A1 (en) 2012-12-28 2014-07-03 Univation Technologies, Llc Methods of integrating aluminoxane production into catalyst production
WO2014109832A1 (en) 2013-01-14 2014-07-17 Univation Technologies, Llc Methods for preparing catalyst systems with increased productivity
WO2014120494A1 (en) 2013-01-30 2014-08-07 Univation Technologies, Llc Processes for making catalyst compositions having improved flow
US9051683B2 (en) 1997-02-28 2015-06-09 Columbia Insurance Company Carpet, carpet backings and methods
WO2015153082A1 (en) 2014-04-02 2015-10-08 Univation Technologies, Llc Continuity compositions and methods of making and using the same
WO2016086039A1 (en) 2014-11-25 2016-06-02 Univation Technologies, Llc Methods of controlling polyolefin melt index
US9376769B2 (en) 1997-02-28 2016-06-28 Columbia Insurance Company Homogeneously branched ethylene polymer carpet backsizing compositions
WO2016118566A1 (en) 2015-01-21 2016-07-28 Univation Technologies, Llc Methods for gel reduction in polyolefins
WO2016118599A1 (en) 2015-01-21 2016-07-28 Univation Technologies, Llc Methods for controlling polymer chain scission
WO2016145179A1 (en) 2015-03-10 2016-09-15 Univation Technologies, Llc Spray dried catalyst compositions, methods for preparation and use in olefin polymerization processes
EP3070134A1 (en) 2015-03-18 2016-09-21 Dow Global Technologies LLC Protective films, blends, and methods of making thereof
WO2016168655A1 (en) 2015-04-17 2016-10-20 Univation Technologies, Llc Methods and systems for olefin polymerization
WO2016171810A1 (en) 2015-04-20 2016-10-27 Exxonmobil Chemical Patents Inc. Supported catalyst systems and processes for use thereof
WO2016172567A1 (en) 2015-04-24 2016-10-27 Univation Technologies, Llc Methods for operating a polymerization reactor
WO2016176135A1 (en) 2015-04-27 2016-11-03 Univation Technologies, Llc Supported catalyst compositions having improved flow properties and preparation thereof
WO2016182920A1 (en) 2015-05-08 2016-11-17 Exxonmobil Chemical Patents Inc. Polymerization process
JP2017002428A (ja) * 2015-06-10 2017-01-05 Ｊｘエネルギー株式会社 網状構造体
US9587055B2 (en) 2008-06-09 2017-03-07 Ineos Manufacturing Belgium Nv Copolymers
WO2018017363A1 (en) 2016-07-21 2018-01-25 Dow Global Technologies Llc Composite cushioning structures, and methods of manufacturing thereof
WO2018022588A1 (en) 2016-07-29 2018-02-01 Dow Global Technologies Llc Mixed catalyst systems for producing multimodal elastomers
WO2018064435A1 (en) 2016-09-30 2018-04-05 Dow Global Technologies Llc High processability polyethylene compositions for injection molded articles
WO2018063767A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
WO2018063765A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
WO2018063764A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
EP3309182A2 (en) 2007-11-15 2018-04-18 Univation Technologies, LLC Polymerization catalysts, methods of making; methods of using, and polyolefinproducts made therefrom
WO2018118155A1 (en) 2016-12-20 2018-06-28 Exxonmobil Chemical Patents Inc. Polymerization process
US10029230B1 (en) 2017-01-24 2018-07-24 Chevron Phillips Chemical Company Lp Flow in a slurry loop reactor
EP3372311A1 (en) 2007-10-22 2018-09-12 Univation Technologies, LLC Film comprising a polyethylene composition having improved properties
WO2019006053A1 (en) 2017-06-30 2019-01-03 Dow Global Technologies Llc MULTILAYERED POLYETHYLENE LAMINATES AND FILMS FOR USE IN SOFT PACKAGING MATERIALS
WO2019118073A1 (en) 2017-12-13 2019-06-20 Exxonmobil Chemical Patents Inc. Deactivation methods for active components from gas phase polyolefin polymerization process
WO2019133372A1 (en) 2017-12-26 2019-07-04 Kolthammer, Brian W. Multimodal ethylene-based polymer processing systems and methods
WO2019133400A1 (en) 2017-12-26 2019-07-04 Dow Global Technologies Llc Compositions with multimodal ethylene-based polymers having improved toughness at low temperatures
WO2019133373A1 (en) 2017-12-26 2019-07-04 Dow Global Technologies Llc Multimodal ethylene-based polymer compositions having improved toughness
WO2019133378A1 (en) 2017-12-26 2019-07-04 Dow Global Technologies Llc Process for the production of multimodal ethylene-based polymers
WO2019133368A1 (en) 2017-12-26 2019-07-04 Dow Global Technologies Llc Dual reactor solution process for the production of multimodal ethylene-based polymer
WO2019133394A1 (en) 2017-12-26 2019-07-04 Dow Global Technologies, Llc Compositions comprising multimodal ethylene based polymers and low density polyethylene (ldpe)
WO2019173030A1 (en) 2018-03-08 2019-09-12 Exxonmobil Chemical Patents Inc. Methods of preparing and monitoring a seed bed for polymerization reactor startup
WO2019213227A1 (en) 2018-05-02 2019-11-07 Exxonmobil Chemical Patents Inc. Methods for scale-up from a pilot plant to a larger production facility
WO2019217173A1 (en) 2018-05-02 2019-11-14 Exxonmobil Chemical Patents Inc. Methods for scale-up from a pilot plant to a larger production facility
WO2019241518A1 (en) 2018-06-15 2019-12-19 Dow Global Technologies Llc Blown films comprising bimodal ethylene-based polymers having high molecular weight high density fractions
WO2019241517A1 (en) 2018-06-15 2019-12-19 Dow Global Technologies Llc Cast films comprising bimodal ethylene-based polymers having high molecular weight high density fractions
WO2019241515A1 (en) 2018-06-15 2019-12-19 Dow Global Technologies Llc Process for the production of bimodal ethylene-based polymers having high molecular weight high density fractions
WO2019241475A1 (en) 2018-06-15 2019-12-19 Dow Global Technologies Llc Bimodal ethylene-based polymers having high molecular weight high density fractions
WO2020014138A1 (en) 2018-07-09 2020-01-16 Exxonmobil Chemical Patents Inc. Polyethylene cast films and methods for making the same
WO2020023207A1 (en) 2018-07-26 2020-01-30 Exxonmobil Chemical Patents Inc. Multilayer foam films and methods for making the same
WO2020102380A1 (en) 2018-11-13 2020-05-22 Exxonmobil Chemical Patents Inc. Polyethylene blends and films
WO2020102385A1 (en) 2018-11-13 2020-05-22 Exxonmobil Chemical Patents Inc. Polyethylene films
WO2020109870A2 (en) 2018-06-28 2020-06-04 Exxonmobil Chemical Patents Inc. Polyethylene compositions, wires and cables, and methods for making the same
WO2020112526A1 (en) 2018-11-30 2020-06-04 Dow Global Technologies Llc Polymer-based film with balanced properties
WO2020163079A1 (en) 2019-02-06 2020-08-13 Exxonmobil Chemical Patents Inc. Films and backsheets for hygiene articles
WO2020242789A1 (en) * 2019-05-30 2020-12-03 Dow Global Technologies Llc Method of extruding linear low-density polyethylene (lldpe) without surface fractures in the melt
US10919994B2 (en) 2016-03-04 2021-02-16 Japan Polyethylene Corporation Metallocene compound, catalyst component for olefin polymerization and catalyst for olefin polymerization containing the same, and method for producing olefin polymer using catalyst for olefin polymerization
US10995167B2 (en) 2016-03-15 2021-05-04 Japan Polyethylene Corporation Metallocene compound, catalyst component for olefin polymerization and catalyst for olefin polymerization containing the same, and method for producing olefin polymer using catalyst for olefin polymerization
WO2021126458A1 (en) 2019-12-17 2021-06-24 Exxonmobil Chemical Patents Inc. Films made of polyethylene blends for improved sealing performance and mechanical properties
WO2021183337A1 (en) 2020-03-12 2021-09-16 Exxonmobil Chemical Patents Inc. Films made of polyethylene blends for improved bending stiffness and high md tear resistance
WO2021195501A1 (en) 2020-03-27 2021-09-30 Dow Global Technologies Llc A process for producing long-chain branched ethylene-based polymers
WO2021195504A1 (en) 2020-03-27 2021-09-30 Dow Global Technologies Llc Long-chain branched ethylene-based polymers
WO2021195502A1 (en) 2020-03-27 2021-09-30 Dow Global Technologies Llc Long-chain branched ethylene-based polymers
WO2021195505A1 (en) 2020-03-27 2021-09-30 Dow Global Technologies Llc Long-chain branched ethylene-based polymers
WO2021221904A1 (en) 2020-04-28 2021-11-04 Exxonmobil Chemical Patents Inc. Density and chemical composition control for polymer with good stress crack properties
US11312844B2 (en) 2016-07-28 2022-04-26 Dow Global Technologies Llc Compositions suitable for manufacturing polyethylene foam, and articles thereof
US11326043B2 (en) 2017-08-29 2022-05-10 Dow Chemical Korea Limited Compositions for high reinforced sidewalls
WO2022210843A1 (ja) 2021-03-31 2022-10-06 三井化学株式会社 エチレン－α－オレフィン共重合体、熱可塑性樹脂組成物、フィルムおよび積層体
WO2022210844A1 (ja) 2021-03-31 2022-10-06 三井化学株式会社 エチレン－α－オレフィン共重合体、熱可塑性樹脂組成物、およびフィルム
WO2022210845A1 (ja) 2021-03-31 2022-10-06 三井化学株式会社 エチレン系樹脂組成物および成形体
WO2022232760A1 (en) 2021-04-30 2022-11-03 Exxonmobil Chemical Patents Inc. Processes for transitioning between different polymerization catalysts in a polymerization reactor
WO2023192846A1 (en) 2022-03-31 2023-10-05 Exxonmobil Chemical Patents Inc. Linear low density polyethylenes, polymerizations thereof, and films thereof
WO2024054736A1 (en) 2022-09-07 2024-03-14 Exxonmobil Chemical Patents Inc. Polyethylenes and articles thereof
WO2024129637A1 (en) 2022-12-12 2024-06-20 Univation Technologies, Llc Decreasing triboelectric charging of, and/or reactor fouling by, polyolefin particles
WO2025049301A1 (en) 2023-08-28 2025-03-06 Dow Global Technologies Llc Polymer blends including post-consumer recycled (pcr) ethylene-based polymers

Families Citing this family (1339)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0955321A3 (en) * 1988-12-26 1999-12-08 Mitsui Chemicals, Inc. Olefin copolymers and processes for preparing same
US5830087A (en) * 1995-06-26 1998-11-03 Lisco, Inc. Multi-layer golf ball
US6025448A (en) 1989-08-31 2000-02-15 The Dow Chemical Company Gas phase polymerization of olefins
US6538080B1 (en) 1990-07-03 2003-03-25 Bp Chemicals Limited Gas phase polymerization of olefins
US6747113B1 (en) 1991-01-18 2004-06-08 The Dow Chemical Company Silica supported transition metal catalyst
US6172173B1 (en) 1991-01-18 2001-01-09 The Dow Chemical Company Silica supported transition metal catalyst
US5710224A (en) * 1991-07-23 1998-01-20 Phillips Petroleum Company Method for producing polymer of ethylene
US5582923A (en) * 1991-10-15 1996-12-10 The Dow Chemical Company Extrusion compositions having high drawdown and substantially reduced neck-in
US5674342A (en) 1991-10-15 1997-10-07 The Dow Chemical Company High drawdown extrusion composition and process
US5972444A (en) * 1991-10-15 1999-10-26 The Dow Chemical Company Polyolefin compositions with balanced shrink properties
US5278272A (en) * 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers
US6194532B1 (en) * 1991-10-15 2001-02-27 The Dow Chemical Company Elastic fibers
US6203750B1 (en) 1992-06-05 2001-03-20 Cryovac, Inc Method for making a heat-shrinkable film containing a layer of crystalline polyamides
US6774190B1 (en) 1992-06-17 2004-08-10 Mitsui Chemicals, Inc. Ethylene copolymer composition
DE69329313T3 (de) * 1992-06-17 2008-07-31 Mitsui Chemicals, Inc. Ethylencopolymerzusammensetzung
US5414040A (en) * 1992-09-15 1995-05-09 The Dow Chemical Company Formulated ethylene/α-olefin elastomeric compounds
EP0877050B1 (en) * 1992-09-15 2008-05-21 Dow Global Technologies Inc. Impact modification of thermoplastics
CA2103401C (en) * 1992-11-19 2002-12-17 Mamoru Takahashi Ethylene copolymer composition
CA2103379C (en) * 1992-11-19 2000-05-23 Toshiyuki Tsutsui Catalyst for olefin polymerization, process for olefin polymerization using the same, ethylene/.alpha.-olefin copolymer, graft modified ethylene/.alpha.-olefin copolymer, and ethylene copolymer composition
US6001941A (en) * 1992-11-19 1999-12-14 Mitsui Chemicals, Inc. Ethylene α-olefin copolymer obtained by copolymerizing ethylene with an α-olefin
EP0601495B1 (en) * 1992-12-07 2002-04-24 Mitsubishi Chemical Corporation Resin composition for extruded forms
US5420220A (en) * 1993-03-25 1995-05-30 Mobil Oil Corporation LLDPE films
US6448341B1 (en) 1993-01-29 2002-09-10 The Dow Chemical Company Ethylene interpolymer blend compositions
USH2096H1 (en) * 1993-02-03 2004-01-06 Exxon Chemical Patents, I Thermoplastic elastomer copolymer films
US5656696A (en) * 1993-03-02 1997-08-12 Mitsubishi Chemical Corporation Resin composition for injection molding
US5883188A (en) * 1993-04-28 1999-03-16 The Dow Chemical Company Paintable olefinic interpolymer compositions
AU738756B2 (en) * 1993-04-28 2001-09-27 Dow Chemical Company, The Blends of graft-modified substantially linear ethylene polymers and other thermoplastic polymers
US5346963A (en) * 1993-04-28 1994-09-13 The Dow Chemical Company Graft-modified, substantially linear ethylene polymers and methods for their use
US7316833B1 (en) 1993-06-24 2008-01-08 Penchiney Emballage Flexible Europe Multi-layer thermoplastic films and packages made therefrom
US5723507A (en) * 1996-03-11 1998-03-03 The Dow Chemical Company Foamed gaskets made from homogeneous olefin polymers
US6087429A (en) * 1993-11-24 2000-07-11 Mitsubishi Chemical Corporation Propylene resin composition
US6472042B1 (en) 1994-02-10 2002-10-29 Dow Global Technologies Inc. Highly filled thermoplastic compositions
US5416179A (en) * 1994-03-16 1995-05-16 Phillips Petroleum Company Catalyst compositions and olefin polymerization
US6060136A (en) * 1995-10-13 2000-05-09 Cryovac, Inc. High modulus oxygen-permeable multilayer film
US5491019A (en) * 1994-03-28 1996-02-13 W. R. Grace & Co.-Conn. Oxygen-permeable multilayer film
GB9415930D0 (en) 1994-08-04 1994-09-28 Forbo Nairn Ltd Floor coverings
EP0756607B1 (en) * 1994-04-20 1998-06-03 The Dow Chemical Company Silane-crosslinkable, substantially linear ethylene polymers and their uses
AU2510295A (en) * 1994-05-09 1995-11-29 Dow Chemical Company, The Medium modulus film and fabrication method
US5631069A (en) * 1994-05-09 1997-05-20 The Dow Chemical Company Medium modulus molded material comprising substantially linear polyethlene and fabrication method
US5622780A (en) * 1994-05-11 1997-04-22 W. R. Grace & Co.-Conn. Microwaveable multilayer films with metal-like appearance
US5658625A (en) * 1994-05-25 1997-08-19 W.R. Grace & Co.-Conn. Film containing alpha-olefin/vinyl aromatic copolymer
US6682825B1 (en) 1994-06-06 2004-01-27 Cryovac, Inc. Films having enhanced sealing characteristics and packages containing same
EP0766635A1 (en) 1994-06-28 1997-04-09 W.R. Grace & Co.-Conn. Bag having protective patches
US5543480A (en) * 1994-06-28 1996-08-06 The Dow Chemical Company Polymerization process using diene containing catalysts
CA2152751C (en) 1994-06-30 2007-04-17 Henry Walker Stockley Iii Barrier package for fresh meat products
US5453471B1 (en) 1994-08-02 1999-02-09 Carbide Chemicals & Plastics T Gas phase polymerization process
US6111020A (en) * 1994-09-02 2000-08-29 The Dow Chemical Company Crosslinked foams from blends of ethylene vinyl acetate and ethylene-styrene interpolymers
US5416148B1 (en) * 1994-09-09 1999-03-02 Dow Chemical Co Blends of polycarbonate and ethylene polymers
JP4057657B2 (ja) 1994-09-19 2008-03-05 センチネル・プロダクツ・コープ 線状ポリオレフィンの架橋フォーム構造及びその製造方法
US5929129A (en) 1994-09-19 1999-07-27 Sentinel Products Corp. Crosslinked foamable compositions of silane-grafted, essentially linear polyolefins blended with polypropylene
US5883144A (en) 1994-09-19 1999-03-16 Sentinel Products Corp. Silane-grafted materials for solid and foam applications
US5932659A (en) 1994-09-19 1999-08-03 Sentinel Products Corp. Polymer blend
US5715327A (en) * 1994-09-20 1998-02-03 Neopath, Inc. Method and apparatus for detection of unsuitable conditions for automated cytology scoring
US5741195A (en) * 1994-09-30 1998-04-21 Lisco, Inc. High visibility inflated game ball
ATE208708T1 (de) * 1994-10-19 2001-11-15 Cryovac Inc Heissschrumpfbare mehrschichtfolien
US5858491A (en) * 1994-11-02 1999-01-12 Dow Belgium Hollow molded articles and process for manufacturing them
US5576083A (en) * 1994-11-03 1996-11-19 Kraft Foods, Inc. Blow molding resins
US6291063B1 (en) 1994-11-07 2001-09-18 Cryovac, Inc. Film containing silicon oil and antiblocking agent
US6506866B2 (en) * 1994-11-17 2003-01-14 Dow Global Technologies Inc. Ethylene copolymer compositions
US6287613B1 (en) 1994-12-12 2001-09-11 Cryovac Inc Patch bag comprising homogeneous ethylene/alpha-olefin copolymer
US6150011A (en) * 1994-12-16 2000-11-21 Cryovac, Inc. Multi-layer heat-shrinkage film with reduced shrink force, process for the manufacture thereof and packages comprising it
US6309736B1 (en) 1994-12-20 2001-10-30 Kimberly-Clark Worldwide, Inc. Low gauge films and film/nonwoven laminates
ZA9510604B (en) 1994-12-20 1996-07-03 Kimberly Clark Co Low gauge films and film/nonwoven laminates
TW330217B (en) 1994-12-20 1998-04-21 Kimberly Clark Co Low gauge films and film/nonwoven laminates
USH1798H (en) * 1994-12-22 1999-07-06 Shell Oil Company Soft compounds containing elastomeric metallocene polyolefins and styrenic block copolymers
KR0159685B1 (ko) * 1995-01-19 1998-12-15 사토 아키오 폴리프로필렌 다층블로성형체
US6800690B2 (en) * 1995-01-24 2004-10-05 Acushnet Company Golf balls incorporating polyamide polymers
US5550194A (en) * 1995-01-31 1996-08-27 Shell Oil Company Process for making graft block copolymers by grafting anionic polymer chains onto functionalized polyolefins
US5543458A (en) * 1995-01-31 1996-08-06 Shell Oil Company Process for making graft block copolymers by growing anionic polymer chains from functionalized polyolefin backbones
US5889117A (en) * 1995-03-20 1999-03-30 Bicc Cables Corporation Polymeric compositions for power cables
US5695840A (en) * 1995-03-22 1997-12-09 W. R. Grace & Co.-Conn. Films for medical solution pouches
CA2170961C (en) * 1995-03-22 2005-08-09 Walter B. Mueller Multilayer films for packaging and administering medical solutions
ATE226601T1 (de) * 1995-03-29 2002-11-15 Univation Tech Llc Ethylenpolymere mit enger polydispersität und verfahren zu ihrer herstellung
US5811494A (en) * 1995-04-06 1998-09-22 The Dow Chemical Company Impact modified thinwall polymer compositions
WO1996031568A1 (en) * 1995-04-07 1996-10-10 The Dow Chemical Company Blends of polycarbonate and linear ethylene polymers
US5824718A (en) * 1995-04-20 1998-10-20 The Dow Chemical Company Silane-crosslinkable, substantially linear ethylene polymers and their uses
IT1274469B (it) 1995-05-11 1997-07-17 Spherilene Spa Composizioni poliolefiniche vulcanizzabili dinamicamente
US6884480B2 (en) 1995-05-19 2005-04-26 Cryovac, Inc. Film containing alpha-olefin/vinyl aromatic copolymer
EP0744285B1 (en) * 1995-05-24 1999-12-15 Cryovac, Inc. Multilayer oxygen barrier packaging film
US5693713A (en) * 1995-05-30 1997-12-02 Shell Oil Company Process for making block graft copolymers by grafting halosilanes onto polyolefin/diene polymers
US5574091A (en) * 1995-06-05 1996-11-12 The Dow Chemical Comapny Aqueous dispersions of olefin copolymers
US5539021A (en) * 1995-06-05 1996-07-23 The Dow Chemical Company Process for preparing high internal phase ratio emulsions and latexes derived thereof
WO1996039451A1 (en) * 1995-06-06 1996-12-12 The Dow Chemical Company Segmented multicomponent interpolymers of monovinylidene aromatic monomers
US5925454A (en) * 1995-07-11 1999-07-20 W.R. Grace & Co.-Conn. Film having modified surface characteristics through use of combination of spherical and lamellar particulates
US5866214A (en) * 1995-07-28 1999-02-02 W. R. Grace & Co.-Conn. Film backseamed casings therefrom, and packaged product using same
EP0756931B2 (en) * 1995-07-31 2011-06-22 Kureha Corporation Multilayer film
US5741594A (en) * 1995-08-28 1998-04-21 The Dow Chemical Company Adhesion promoter for a laminate comprising a substantially linear polyolefin
DE69617195T2 (de) * 1995-09-12 2002-04-18 Mitsui Chemicals, Inc. Polymere ethylenische klebstoffarzzusammensetzung und aus der zusammensetzung hergestelltes laminat
US5792560A (en) * 1995-09-28 1998-08-11 Norton Performance Plastics Corporation Thermoplastic interlayer film
US6159608A (en) * 1995-09-28 2000-12-12 Saint-Gobain Performance Plastics Corporation Thermoplastic interlayer film
ATE193715T1 (de) * 1995-09-29 2000-06-15 Dow Chemical Co Vernetzte polyolefinschäume und verfahren zu ihrer herstellung
US5962714A (en) * 1995-10-02 1999-10-05 Mccullough; Laughlin Gerard Monocyclopentadienyl transition metal catalyst and olefin polymerization process
US5795941A (en) * 1995-10-03 1998-08-18 The Dow Chemical Company Crosslinkable bimodal polyolefin compositions
US6723398B1 (en) * 1999-11-01 2004-04-20 Dow Global Technologies Inc. Polymer blend and fabricated article made from diverse ethylene interpolymers
US5653728A (en) 1995-11-13 1997-08-05 Becton, Dickinson And Company Disposable non-latex tourniquet
US5709921A (en) † 1995-11-13 1998-01-20 Kimberly-Clark Worldwide, Inc. Controlled hysteresis nonwoven laminates
DE19548681C2 (de) * 1995-12-23 1998-01-22 Pegulan Tarkett Ag Verfahren zur Herstellung von geschäumten Schichten aus Polyolefin auf Kalandern
NZ324004A (en) * 1995-12-28 2000-01-28 Cryovac Inc Patch bag having one continuous patch
US5858515A (en) * 1995-12-29 1999-01-12 Kimberly-Clark Worldwide, Inc. Pattern-unbonded nonwoven web and process for making the same
ID16442A (id) 1996-01-22 1997-10-02 Dow Chemical Co Polimer etilena berat molekul ultra rendah
TR199801405T2 (xx) * 1996-01-22 1998-10-21 The Dow Chemical Company Geli�tirilmi� �zellikler arzeden poliolefin elastomer harmanlar�.
US6545091B1 (en) 1996-01-25 2003-04-08 E. I. Du Pont De Nemours & Co. Adhesive compositions based on blends of grafted metallocene catalyzed and non-grafted conventional polyethylenes
US5952252A (en) * 1996-02-20 1999-09-14 Kimberly-Clark Worldwide, Inc. Fully elastic nonwoven fabric laminate
US5695849A (en) * 1996-02-20 1997-12-09 Kimberly-Clark Worldwide Inc. Elastic, breathable, barrier fabric
BR9707867A (pt) * 1996-02-23 1999-07-27 Dow Chemical Co Espuma de polímero
US5749202A (en) * 1996-03-12 1998-05-12 Tenneco Packaging Stretch wrap films
US5814399A (en) * 1996-03-12 1998-09-29 Tenneco Packaging Stretch wrap films
US5998017A (en) * 1996-03-12 1999-12-07 Tenneco Packaging Stretch wrap films
US5976682A (en) * 1996-03-12 1999-11-02 Tenneco Packaging Stretch wrap films
USRE38429E1 (en) * 1996-03-12 2004-02-17 Tyco Plastics Services Ag Stretch wrap films
US5902684A (en) * 1996-03-12 1999-05-11 Tenneco Packaging Inc. Multilayered Metallocene stretch wrap films
US5752362A (en) * 1996-03-12 1998-05-19 Tenneco Packaging Stretch wrap films
US6103647A (en) * 1996-03-14 2000-08-15 Kimberly-Clark Worldwide, Inc. Nonwoven fabric laminate with good conformability
ID17196A (id) 1996-03-14 1997-12-11 Dow Chemical Co Bahan-bahan perekat yang mengandung polimer-polimer olefin
US6107430A (en) * 1996-03-14 2000-08-22 The Dow Chemical Company Low application temperature hot melt adhesive comprising ethylene α-olefin
RU2179560C2 (ru) * 1996-03-19 2002-02-20 Юнивэйшн Текнолоджиз, Ллс Полиэтилен, пленка и другие изделия, содержащие полиэтилен
US5807968A (en) * 1996-04-04 1998-09-15 Henkel Corporation Polyamide compositions and related methods
CA2203595A1 (en) 1996-04-26 1997-10-26 Robert F. Hurley Cross-linked polyolefin tape
US5844009A (en) 1996-04-26 1998-12-01 Sentinel Products Corp. Cross-linked low-density polymer foam
JPH09309926A (ja) * 1996-05-17 1997-12-02 Dow Chem Co:The エチレン共重合体の製造方法
US6576305B2 (en) 1996-06-07 2003-06-10 Saint-Gobain Vetrotex America, Inc. Package having a multilayer film disposed around a layered coil of filament strands
US6045924A (en) * 1996-06-19 2000-04-04 Cryovac, Inc. Film from a vinylidene chloride copolymer containing blend
US5843502A (en) * 1996-06-26 1998-12-01 Cryovac, Inc. Package having cooked food product packaged in film having food adhesion layer containing high vicat softening point olefin/acrylic acid copolymer
US5876813A (en) 1996-07-09 1999-03-02 Senitnel Products Corp Laminated foam structures with enhanced properties
US5882776A (en) 1996-07-09 1999-03-16 Sentinel Products Corp. Laminated foam structures with enhanced properties
ZA976110B (en) 1996-07-12 1999-01-11 Dow Chemical Co Elastomers processes for their manufacture and articles made from these elastomers
US5844037A (en) * 1996-07-24 1998-12-01 The Dow Chemical Company Thermoplastic polymer compositions with modified electrical conductivity
US6258308B1 (en) 1996-07-31 2001-07-10 Exxon Chemical Patents Inc. Process for adjusting WVTR and other properties of a polyolefin film
US6107454A (en) * 1996-08-06 2000-08-22 Exxon Chemical Patents, Inc. Method of processing polyethylene
US5939503A (en) * 1996-08-09 1999-08-17 California Institute Of Technology Group IV zwitterion ansa metallocene (ZAM) catalysts for α-olefin polymerization
AU4061497A (en) 1996-08-16 1998-03-06 Cryovac, Inc. Article comprising film having polyamide sealant, polyamide core layer, and O2-barrier layer, and packaged product using same
US5938878A (en) 1996-08-16 1999-08-17 Sentinel Products Corp. Polymer structures with enhanced properties
TW412560B (en) 1996-09-04 2000-11-21 Dow Chemical Co Compositions and adhesives comprising a substantially random interpolymer of at least one vinylidene and at least one vinylidene aromatic monomer or hindered aliphatic vinylidene monomer, and coextruded or laminated multilayer film and tape
US5849823A (en) * 1996-09-04 1998-12-15 The Dow Chemical Company Homogeneously branched ethylene α-olefin interpolymer compositions for use in gasket applications
US5846620A (en) * 1997-02-06 1998-12-08 W. R. Grace & Co.-Conn. High strength flexible film package
US5902854A (en) * 1996-09-27 1999-05-11 The Dow Chemical Company Polydimethylsiloxane containing polymer blends
US6271322B1 (en) 1996-10-02 2001-08-07 Mccullough Laughlin Gerard Monocyclopentadienyl transition metal catalyst and olefin polymerization process
US5853881A (en) * 1996-10-11 1998-12-29 Kimberly-Clark Worldwide, Inc. Elastic laminates with improved hysteresis
US20030161798A1 (en) * 1996-10-16 2003-08-28 Revlon Consumer Products Corporation Cosmetic stick compositions with polyolefin elastomers
US5861463A (en) * 1996-10-31 1999-01-19 The Dow Chemical Company Impact-modified thermoplastic polyolefins and articles fabricated therefrom
KR100478377B1 (ko) 1996-11-13 2005-03-23 다우 글로벌 테크놀로지스 인크. 잘 균형된 특성 또는 개선된 인성을 갖는 수축 필름 및 그의제조 방법
US6333061B1 (en) 1996-11-22 2001-12-25 Cryovac, Inc. Packaging article
CA2272549A1 (en) * 1996-11-25 1998-06-04 Michael K. Laughner Polymer blends with controlled morphologies
BR9713408A (pt) * 1996-11-27 2000-01-25 Dow Chemical Co Composição de mistura de polìmeros.
US6245856B1 (en) 1996-12-17 2001-06-12 Exxon Chemical Patents, Inc. Thermoplastic olefin compositions
WO1998027149A1 (en) 1996-12-19 1998-06-25 Exxon Chemical Patents Inc. Method of melt processing amine containing polyethylenes
EP0887355B1 (en) * 1996-12-20 2006-09-06 Sumitomo Chemical Company, Limited Process for preparing olefin polymers
US6197397B1 (en) * 1996-12-31 2001-03-06 3M Innovative Properties Company Adhesives having a microreplicated topography and methods of making and using same
US5989725A (en) * 1997-01-16 1999-11-23 Tenneco Packaging Clear high molecular weight film
US6667082B2 (en) 1997-01-21 2003-12-23 Cryovac, Inc. Additive transfer film suitable for cook-in end use
US6506842B1 (en) 1997-01-29 2003-01-14 Dupont Dow Elastomers L.L.C. Rheology-modified thermoplastic elastomer compositions and articles fabricated therefrom
US6114457A (en) * 1997-02-07 2000-09-05 Exxon Chemical Patents Inc. High melt strength polyethylene compositions
US5964743A (en) * 1997-02-27 1999-10-12 Kimberly-Clark Worldwide, Inc. Elastic absorbent material for personal care products
US5824745A (en) * 1997-02-28 1998-10-20 Brown; William F. Resin composition
CA2278717A1 (en) 1997-02-28 1998-09-03 Edwin R. Feig Filled polyethylene compositions
US6552126B2 (en) 1997-03-03 2003-04-22 Spalding Sports Worldwide, Inc. Golf ball cover containing a blend of ionomer and plastomer, and method of making same
US6296886B1 (en) 1997-03-17 2001-10-02 Cryovac, Inc. Method of film crease elimination and patch bag without crease within lay-flat bag side
US6013378A (en) * 1997-03-17 2000-01-11 Tenneco Packaging HMW HDPE film with improved impact strength
US6117801A (en) * 1997-03-27 2000-09-12 E. I. Du Pont De Nemours And Company Properties for flash-spun products
US5931823A (en) 1997-03-31 1999-08-03 Kimberly-Clark Worldwide, Inc. High permeability liner with improved intake and distribution
WO1998045187A1 (en) 1997-04-04 1998-10-15 Cryovac Incorporated Patch bag having seal through patches
AR012582A1 (es) 1997-04-14 2000-11-08 Dow Global Technologies Inc Composiciones polimericas de elongacion mejorada y formulaciones adhesivas de fusion en caliente que incluyen dicha composicion
US6420507B1 (en) 1997-05-01 2002-07-16 The Dow Chemical Company Olefin polymers prepared with substituted indenyl containing metal complexes
US5907942A (en) * 1997-05-21 1999-06-01 Tenneco Packaging Stretch wrap films
US6093480A (en) * 1997-05-21 2000-07-25 Tenneco Packaging Stretch wrap films
US5907943A (en) * 1997-06-11 1999-06-01 Tenneco Packaging Inc. Stretch wrap films
US5922441A (en) * 1997-06-11 1999-07-13 Tenneco Packaging Inc. Stretch wrap films
DE69724258T2 (de) * 1997-06-14 2004-06-24 Honam Petrochemical Corp. Vernetzte thermoplastische elastomere auf olefinbasis und ein verfahren zu deren herstellung
JP2002505707A (ja) * 1997-06-14 2002-02-19 ザ ボード オブ トラスティーズ オブ ザ リーランド スタンフォード ジュニア ユニバーシティ エチレン増強高融点熱可塑性エラストマーα−オレフィン重合体合成法（ＰＲＥ／ＥＰＥ効果）
EP0991715B1 (en) * 1997-06-20 2003-04-02 The Dow Chemical Company Ethylene polymer compositions and article fabricated from the same
US6262161B1 (en) 1997-06-26 2001-07-17 The Dow Chemical Company Compositions having improved ignition resistance
WO1999000251A1 (en) 1997-06-30 1999-01-07 Cryovac, Inc. Packaged explosive product and packaging process therefor
US6239235B1 (en) 1997-07-15 2001-05-29 Phillips Petroleum Company High solids slurry polymerization
US6282869B1 (en) 1997-07-21 2001-09-04 Cryovac, Inc. Method of cutting and sealing film
US6025420A (en) * 1997-07-24 2000-02-15 The Dow Chemical Company Compositions for tough and easy melt processible polycarbonate/polyolefin blend resin
US6921794B2 (en) * 1997-08-12 2005-07-26 Exxonmobil Chemical Patents Inc. Blends made from propylene ethylene polymers
US6635715B1 (en) * 1997-08-12 2003-10-21 Sudhin Datta Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers
US7232871B2 (en) * 1997-08-12 2007-06-19 Exxonmobil Chemical Patents Inc. Propylene ethylene polymers and production process
WO1999009096A1 (en) 1997-08-15 1999-02-25 The Dow Chemical Company Films produced from substantially linear homogeneous olefin polymer compositions
US6416833B1 (en) 1997-08-22 2002-07-09 Dupont Canada Inc. Interpolymer film pouch
WO1999010392A1 (en) 1997-08-27 1999-03-04 The Dow Chemical Company Elastomers with improved processability
US5932497A (en) * 1997-09-15 1999-08-03 Kimberly-Clark Worldwide, Inc. Breathable elastic film and laminate
US6096668A (en) * 1997-09-15 2000-08-01 Kimberly-Clark Worldwide, Inc. Elastic film laminates
US6909028B1 (en) 1997-09-15 2005-06-21 Kimberly-Clark Worldwide, Inc. Stable breathable elastic garments
US6045900A (en) 1997-09-15 2000-04-04 Kimberly-Clark Worldwide, Inc. Breathable filled film laminate
ID24895A (id) 1997-09-19 2000-08-31 Dow Chemical Co Komposisi interpolimer yang dioptimumkan secara komposional, mwd sempit, proses pembuatannya dan artikel yang dibuat, dari padanya
US6270819B1 (en) 1997-09-23 2001-08-07 Cryovac, Inc. Patch bag having curved seal and curved patch
US6790468B1 (en) 1997-09-30 2004-09-14 Cryovac, Inc. Patch bag and process of making same
US6083611A (en) * 1997-11-12 2000-07-04 Tenneco Packaging, Inc. Roll wrap film
US6417303B1 (en) * 1997-12-16 2002-07-09 Exxonmobil Research And Engineering Company Substantially linear copolymers
US5998558A (en) * 1997-12-29 1999-12-07 Union Carbide Chemicals & Plastics Technology Corporation Ethylene polymers having enhanced processing ease
US6479685B2 (en) 1998-01-09 2002-11-12 The Board Of Trustees Of The Leland Standard Junior University Metallocene catalysts for synthesis of high-melting polyolefin copolymer elastomers
US6169151B1 (en) 1998-01-09 2001-01-02 The Board Of Trustees Of The Leland Stanford Junior University High-melting polyolefin copolymer elastomers, catalysts and methods of synthesis
US6518378B2 (en) 1998-01-09 2003-02-11 The Board Of Trustees Of The Leland Stanford Junior University High-melting polyolefin copolymer elastomers, catalysts and methods of synthesis
US6346300B1 (en) 1998-01-21 2002-02-12 Dupont Dow Elastomers L.L.C. UV curable elastomer composition
US6506460B2 (en) 1998-01-21 2003-01-14 E. I. Du Pont De Nemours And Company UV curable elastomer composition
US6166142A (en) 1998-01-27 2000-12-26 E. I. Du Pont De Nemours And Company Adhesive compositions based on blends of grafted metallocene catalyzed and polar ethylene copolymers
US6258902B1 (en) 1998-02-11 2001-07-10 The Dow Chemical Company Olefin polymerization process
US6610392B1 (en) 1998-03-04 2003-08-26 Cryovac, Inc. Heat-shrinkable multilayer packaging film comprising inner layer comprising a polyester
ES2203084T3 (es) 1998-03-04 2004-04-01 Cryovac, Inc. Pelicula para embalaje de multiples capas, termorretractil, sellable en pilas.
KR20010041847A (ko) 1998-03-11 2001-05-25 그래햄 이. 테일러 엔지니어링 열가소성 물질과 블렌딩된, 알파-올레핀단량체 및 하나 이상의 비닐 또는 비닐리덴 방향족 단량체및/또는 하나 이상의 장애 지방족 또는 지환족 비닐 또는비닐리덴 단량체의 인터폴리머의 열가소성 조성물
AU755566B2 (en) 1998-03-11 2002-12-12 Dow Global Technologies Inc. Fibers made from alpha-olefin/vinyl or vinylidene aromatic and/or hindered cycloaliphatic or aliphatic vinyl or vinylidene interpolymers
ES2229683T3 (es) * 1998-03-12 2005-04-16 Bp Chemicals Limited Catalizadores de polimerizacion.
US6699573B1 (en) 1998-03-16 2004-03-02 Dow Global Technologies Inc. Liner compositions
US6663905B1 (en) 1998-03-16 2003-12-16 Cryovac, Inc. Patch bag having wrap-around patch
US6709742B2 (en) 1998-05-18 2004-03-23 Dow Global Technologies Inc. Crosslinked elastic fibers
TW460485B (en) 1998-06-19 2001-10-21 Japan Polyolefins Co Ltd Ethylene.Α-olefin copolymer, and combinations, films and use thereof
US6355287B2 (en) 1998-06-22 2002-03-12 Cryovac, Inc. Packaged food product having added liquid
ATE342207T1 (de) 1998-06-22 2006-11-15 Cryovac Inc Verpacktes nahrungsmittel mit hinzugefügter flüssigkeit und verfahren zu seiner herstellung
KR20010077954A (ko) 1998-06-30 2001-08-20 쿠안 낸시 엔 균질 에틸렌 인터폴리머 및 블록 공중합체를 포함하는고온 용융 접착제 조성물
EP1522553B1 (en) 1998-07-01 2007-04-11 ExxonMobil Chemical Patents Inc. Elastic blends comprising crystalline polymer and crystallizable polymers of propylene
US6562443B1 (en) 1998-07-22 2003-05-13 Cryovac, Inc. Cook-in package with tight appearance
BR9914290A (pt) 1998-08-18 2001-06-19 Dow Chemical Co Composições poliméricas de barreira extrudáveis, processo para preparar as composições e estruturas em monocamada ou multicamadas compreendendo as composições
US6152906A (en) * 1998-08-25 2000-11-28 Kimberly-Clark Worldwide, Inc. Absorbent article having improved breathability
US6238379B1 (en) 1998-08-25 2001-05-29 Kimberly-Clark Worldwide, Inc. Absorbent article with increased wet breathability
US6448464B1 (en) 1999-07-30 2002-09-10 Kimberly-Clark Worldwide, Inc. Absorbent article which maintains skin temperature when wet
US6217890B1 (en) 1998-08-25 2001-04-17 Susan Carol Paul Absorbent article which maintains or improves skin health
US6287286B1 (en) 1998-08-25 2001-09-11 Kimberly-Clark Worldwide, Inc. Absorbent article having a reduced viability of candida albicans
DE69911446T2 (de) 1998-10-16 2004-07-01 Exxonmobil Chemical Patents Inc., Baytown Verfahren zur herstellung von mikroporösen, atmungsfähigen polyethylenfolien
US6953510B1 (en) 1998-10-16 2005-10-11 Tredegar Film Products Corporation Method of making microporous breathable film
US6680361B1 (en) * 1998-11-02 2004-01-20 Dupont Dow Elastomers Llc Shear thinning ethylene/α-olefin interpolymers and their preparation
DE69943133D1 (de) * 1998-11-02 2011-02-24 Dow Global Technologies Inc Unter scherwirkung verflüssigbare ethylen/alpha-olefin/dien polymere und ihre herstellung
US6454989B1 (en) 1998-11-12 2002-09-24 Kimberly-Clark Worldwide, Inc. Process of making a crimped multicomponent fiber web
US6362389B1 (en) 1998-11-20 2002-03-26 Kimberly-Clark Worldwide, Inc. Elastic absorbent structures
US6579584B1 (en) 1998-12-10 2003-06-17 Cryovac, Inc. High strength flexible film package utilizing thin film
US6723669B1 (en) * 1999-12-17 2004-04-20 Kimberly-Clark Worldwide, Inc. Fine multicomponent fiber webs and laminates thereof
US6248442B1 (en) * 1998-12-31 2001-06-19 Mobil Oil Corporation Easy opening hermetically sealed film
US6059458A (en) 1999-02-05 2000-05-09 Tenneco Packaging, Inc. Elastic top drawtape bag and method of manufacturing the same
US6433089B1 (en) 1999-04-13 2002-08-13 Asahi Kasei Kabushiki Kaisha Method for producing rubber composition
GB9908602D0 (en) * 1999-04-15 1999-06-09 Northumbria Lyonnaise Technolo Rehabilitation of water supply pipes
ATE286939T1 (de) 1999-06-24 2005-01-15 Dow Chemical Co Polyolefinzusammensetzung mit verbesserten schlagzäheigenschaften
US6682514B1 (en) * 1999-06-30 2004-01-27 Kimberly-Clark Worldwide Inc. Efficient zoned elastic laminate
CA2379424A1 (en) * 1999-07-15 2001-01-25 Phillips Petroleum Company Slotted slurry take off
US6191230B1 (en) 1999-07-22 2001-02-20 Union Carbide Chemicals & Plastics Technology Corporation Polyethylene crosslinkable composition
US6149666A (en) * 1999-07-27 2000-11-21 Becton Dickinson And Company Tourniquet
US6331597B1 (en) 1999-08-09 2001-12-18 The Dow Chemical Company Azidosilane-modified, moisture-curable polyolefin polymers, process for making, and articles obtained therefrom
US6362270B1 (en) 1999-08-12 2002-03-26 The Dow Chemical Company Thermoplastic compositions for durable goods applications
AR027842A1 (es) 1999-08-23 2003-04-16 Kimberly Clark Co Un articulo absorbente el cual mantiene o mejora la salud de la piel
AR025300A1 (es) 1999-08-23 2002-11-20 Kimberly Clark Co Un articulo absorbente descartable con capacidad para respirar en humedo incrementada.
SG97919A1 (en) † 1999-08-31 2003-08-20 Sumitomo Chemical Co Ethylene-alpha-olefin copolymer and polyethylene composition
US6239062B1 (en) 1999-09-02 2001-05-29 Equistar Chemicals, L.P. Olefin polymerization catalysts containing indolyl-amido ligands
US6534137B1 (en) 1999-10-12 2003-03-18 Cryovac, Inc. Two-component, heat-sealable films
US6777056B1 (en) 1999-10-13 2004-08-17 Kimberly-Clark Worldwide, Inc. Regionally distinct nonwoven webs
US6613704B1 (en) * 1999-10-13 2003-09-02 Kimberly-Clark Worldwide, Inc. Continuous filament composite nonwoven webs
US7255903B1 (en) 1999-10-25 2007-08-14 Cryovac, Inc. Patch bag with patch containing high and low crystallinity ethylene copolymers
AU1610401A (en) 1999-11-18 2001-05-30 Dow Chemical Company, The Electromagnetically welded composite and the preparation thereof
BR0016146A (pt) * 1999-12-01 2002-08-13 Univation Tech Llc Compostos catalisadores, sistemas catalisadores dos mesmos e seus usos em um processo de polimerização
US6548572B1 (en) 1999-12-07 2003-04-15 Dupont Canada Inc. Surface printing inks and coatings for use
US6300419B1 (en) 1999-12-08 2001-10-09 The Dow Chemical Company Propylene polymer composition
CN1227272C (zh) 1999-12-20 2005-11-16 埃克森化学专利公司 使用负载的离子催化剂制备聚烯烃树脂的方法
US6593005B2 (en) 2000-01-24 2003-07-15 Dow Global Technologies Inc. Composition and films thereof
US6160029A (en) * 2000-03-08 2000-12-12 The Dow Chemical Company Olefin polymer and α-olefin/vinyl or α-olefin/vinylidene interpolymer blend foams
US6649671B2 (en) 2000-03-13 2003-11-18 Dow Global Technologies Inc. Concrete and process to make same
US6776924B2 (en) * 2000-05-04 2004-08-17 Dow Global Technologies Inc. Molecular melt and methods for making and using the molecular melt
US6608142B1 (en) 2000-05-08 2003-08-19 Teknor Apex Company Polyvinyl chloride compositions
US6833179B2 (en) 2000-05-15 2004-12-21 Kimberly-Clark Worldwide, Inc. Targeted elastic laminate having zones of different basis weights
US8182457B2 (en) * 2000-05-15 2012-05-22 Kimberly-Clark Worldwide, Inc. Garment having an apparent elastic band
US20050106971A1 (en) * 2000-05-15 2005-05-19 Thomas Oomman P. Elastomeric laminate with film and strands suitable for a nonwoven garment
EP1297067B1 (en) * 2000-05-26 2005-05-11 Dow Global Technologies Inc. Polyethylene rich/polypropylene blends and their uses
US6482532B1 (en) 2000-06-07 2002-11-19 Dow Global Technologies Inc. Easy tear non-halogenic food wrap
US7125933B2 (en) * 2000-06-22 2006-10-24 Univation Technologies, Llc Very low density polyethylene blends
US6932592B2 (en) 2000-06-22 2005-08-23 Exxonmobil Chemical Patents Inc. Metallocene-produced very low density polyethylenes
DE60125178T2 (de) * 2000-06-28 2007-11-15 Dow Global Technologies, Inc., Midland Kunststofffasern für verbesserten beton
JP2004504467A (ja) 2000-07-20 2004-02-12 ダウ　グローバル　テクノロジーズ　インコーポレイティド アルケニル芳香族ポリマーとアルファオレフィン／ビニルまたはビニリデン芳香族インターポリマーとをブレンドして得られる発泡組成物
US6399707B1 (en) 2000-09-29 2002-06-04 Exxonmobil Chemical Patents Inc. Impact copolymer and plastomer blend
US6559230B2 (en) 2000-09-29 2003-05-06 Dupont Dow Elastomers L.L.C. Thermosetting ethylene/alpha-olefin composition and safety glass interlayer film made from the composition
US6982231B1 (en) 2000-10-27 2006-01-03 Kimberly-Clark Worldwide, Inc. Elastomeric, breathable laminate with enhanced breathability upon extension
US6914018B1 (en) 2000-10-27 2005-07-05 Kimberly-Clark Worldwide, Inc. Biaxial stretch, breathable laminate with cloth-like aesthetics and method for making same
US6469099B1 (en) 2000-11-14 2002-10-22 Dow Global Technologies Inc. Compatibilized resin blends and the preparation thereof
US7273629B2 (en) * 2000-11-28 2007-09-25 Cryovac, Inc. Meat package with reduced leaker rates
HUP0400649A2 (en) * 2000-12-11 2004-07-28 Dow Global Technologies Inc Thermally bonded fabrics and method of making same
US6800669B2 (en) 2000-12-22 2004-10-05 Dow Global Technologies Inc. Propylene copolymer foams
WO2002053374A1 (en) 2001-01-02 2002-07-11 Dow Global Technologies Inc. Peelable seal and method of making and using same
KR100884294B1 (ko) * 2001-02-08 2009-02-18 미쓰이 가가쿠 가부시키가이샤 에틸렌과 탄소수 3 ~ 20의 α-올레핀의 랜덤 공중합체와 그것을 사용한 성형품
US6592967B2 (en) 2001-02-14 2003-07-15 Avery Dennison Corporation Microprism reflective sheeting with improved retention of reflectivity
US6696524B2 (en) 2001-02-20 2004-02-24 E. I. Du Pont De Nemours And Company Low Tg ethylene-based polymer, cycloolefin polymer blends
KR100848355B1 (ko) * 2001-02-23 2008-07-25 패트 쿠션 엘엘씨 발포 쿠션 및 그의 제조 방법 및 이용 방법
US7173070B2 (en) * 2001-02-23 2007-02-06 Phat Cushion Llc Foam cushion and method of making and using the same
US6545094B2 (en) 2001-03-09 2003-04-08 The Dow Chemical Company Blends of ethylenic polymers with improved modulus and melt strength and articles fabricated from these blends
US6998157B2 (en) 2001-03-30 2006-02-14 E.I. Du Pont De Nemours And Company, Inc. Thermoformable packaging film
ATE485319T1 (de) * 2001-04-12 2010-11-15 Exxonmobil Chem Patents Inc Verfahren zur polymerisation von propylen und ethylen in lösung
CA2444590C (en) * 2001-04-18 2009-12-01 Robert L. Mcginnis Stabilized hemoglobin solutions
US6403692B1 (en) 2001-04-19 2002-06-11 Dow Global Technologies Inc. Filled thermoplastic composition
EP1425345A1 (en) * 2001-06-22 2004-06-09 Exxonmobil Chemical Patents Inc. Metallocene-produced very low density polyethylenes or linear lowdensity polyethylenes as impact modifiers
US7135526B2 (en) * 2001-06-22 2006-11-14 Univation Technologies, Llc Very low density polyethylene and high density polyethylene blends
ES2275891T3 (es) * 2001-07-17 2007-06-16 Dow Global Technologies Inc. Fibras bicomponentes y biconstituyentes elasticas resistentes al calor y a la humedad.
US7338691B2 (en) * 2001-07-27 2008-03-04 Cryovac, Inc. Cook-in patch bag and process for using same
CN1281403C (zh) * 2001-07-31 2006-10-25 艾弗里·丹尼森公司 可整合的全息标签
KR100902462B1 (ko) 2001-08-17 2009-06-11 다우 글로벌 테크놀로지스 인크. 바이모드 폴리에틸렌 조성물 및 그로부터 제조된 물품
US20030047268A1 (en) * 2001-08-23 2003-03-13 Korchnak Gregory J. Method for repairing fuel tanks
US20030044553A1 (en) * 2001-08-23 2003-03-06 Ravi Ramanathan Fuel tanks
KR100895729B1 (ko) * 2001-08-31 2009-04-30 다우 글로벌 테크놀로지스 인크. 다봉 분자량 분포를 갖는 폴리에틸렌 물질
US6706815B2 (en) * 2001-09-06 2004-03-16 Dupont Dow Elastomers L.L.C. Impact resistant rigid PVC compositions using hydrocarbon rubbers and chlorinated polyethylene as impact modifiers
US20050070673A1 (en) * 2001-10-01 2005-03-31 Novak Leo R. Thermoformable propylene polymer compositions
WO2003033263A1 (en) * 2001-10-19 2003-04-24 Dupont Canada Inc. Composite film structure for manufacturing pouches using rotary thermic sealing
US6906160B2 (en) * 2001-11-06 2005-06-14 Dow Global Technologies Inc. Isotactic propylene copolymer fibers, their preparation and use
US6943215B2 (en) 2001-11-06 2005-09-13 Dow Global Technologies Inc. Impact resistant polymer blends of crystalline polypropylene and partially crystalline, low molecular weight impact modifiers
US6733851B2 (en) 2001-11-06 2004-05-11 Cryovac, Inc. Packaging article having heat seal layer containing blend of hyperbranched and semicrystalline olefin polymers
US6960635B2 (en) * 2001-11-06 2005-11-01 Dow Global Technologies Inc. Isotactic propylene copolymers, their preparation and use
US6761965B2 (en) * 2001-11-06 2004-07-13 Cryovac, Inc. Irradiated multilayer film having seal layer containing hyperbranched polymer
WO2003040201A1 (en) 2001-11-06 2003-05-15 Dow Global Technologies Inc. Isotactic propylene copolymers, their preparation and use
US6737130B2 (en) 2001-11-06 2004-05-18 Cryovac, Inc. Hermetically heat-sealable, pressure-reclosable packaging article containing substantially spherical homogeneous polyolefin
US6927256B2 (en) 2001-11-06 2005-08-09 Dow Global Technologies Inc. Crystallization of polypropylene using a semi-crystalline, branched or coupled nucleating agent
WO2003052649A1 (en) * 2001-11-22 2003-06-26 Metso Paper, Inc. Delivery system for consumption and/or spare parts
US20060177384A1 (en) * 2001-12-04 2006-08-10 Brown Dale G Sialagogue coatings for interproximal devices
US20060243297A1 (en) * 2005-04-29 2006-11-02 Brown Dale G Coated monofilament oriented HDPE dental tapes
US20030144423A1 (en) * 2001-12-14 2003-07-31 Marchand Gary R. Impact resistant rigid PVC compositions using hydrocarbon rubbers and chlorinated polyethylene as impact modifiers
US6939334B2 (en) 2001-12-19 2005-09-06 Kimberly-Clark Worldwide, Inc. Three dimensional profiling of an elastic hot melt pressure sensitive adhesive to provide areas of differential tension
US7078089B2 (en) * 2001-12-28 2006-07-18 Kimberly-Clark Worldwide, Inc. Low-cost elastic laminate material
US6902796B2 (en) 2001-12-28 2005-06-07 Kimberly-Clark Worldwide, Inc. Elastic strand bonded laminate
US6849694B2 (en) 2002-01-17 2005-02-01 Dupont Dow Elastomers, Llc Impact modifier compositions for rigid PVC compositions of hydrocarbon rubbers and chlorinated polyethylene
US7226955B2 (en) * 2002-02-22 2007-06-05 Dow Global Technologies Inc. Macrocellular acoustic foam containing particulate additive
EP1860214B1 (en) 2002-03-11 2009-04-29 Dow Global Technologies Inc. Reversible, heat-set, elastic fibers, and method of making and articles made from same
IL163971A0 (en) * 2002-03-11 2005-12-18 Dow Global Technologies Inc Reversible, heat-set, elastic fibers, and method of making and articles made from same
TWI294939B (en) * 2002-03-11 2008-03-21 Dow Global Technologies Inc Stretch fabrics with improved chemical resistance and durability
US6787593B2 (en) 2002-03-27 2004-09-07 Lear Corporation Sound-deadening composites of metallocene copolymers for use in vehicle applications
WO2003085176A1 (en) * 2002-04-09 2003-10-16 Toyo Boseki Kabushiki Kaisha Polyethylene fiber and process for producing the same
EP1356925A1 (en) 2002-04-25 2003-10-29 Amcor Flexibles Transpac Peelable packaging system and method for making same
US6649666B1 (en) 2002-05-21 2003-11-18 Dow Global Technologies Inc. Propylene polymer coupling and foams
US20060148988A1 (en) * 2004-10-06 2006-07-06 Chou Richard T Miscible blends of ethylene copolymers with improved temperature resistance
JP2005529769A (ja) * 2002-06-14 2005-10-06 ダウ グローバル テクノロジーズ インコーポレーテッド 金属基材に直接接合した熱可塑性エラストマー
MXPA04012896A (es) 2002-06-26 2005-03-31 Avery Dennison Corp Peliculas polimericas orientadas en la direccion de mecanizado y metodos de preparacion de las mismas.
US20040002273A1 (en) * 2002-07-01 2004-01-01 Kimberly-Clark Worldwide, Inc. Liquid repellent nonwoven protective material
US6978486B2 (en) 2002-07-02 2005-12-27 Kimberly-Clark Worldwide, Inc. Garment including an elastomeric composite laminate
US7335273B2 (en) * 2002-12-26 2008-02-26 Kimberly-Clark Worldwide, Inc. Method of making strand-reinforced elastomeric composites
US7316840B2 (en) * 2002-07-02 2008-01-08 Kimberly-Clark Worldwide, Inc. Strand-reinforced composite material
US7015155B2 (en) 2002-07-02 2006-03-21 Kimberly-Clark Worldwide, Inc. Elastomeric adhesive
US7316842B2 (en) * 2002-07-02 2008-01-08 Kimberly-Clark Worldwide, Inc. High-viscosity elastomeric adhesive composition
US7051493B2 (en) * 2002-08-21 2006-05-30 Cryovac, Inc. High modulus, temperature-resistant film for form fill and seal packaging
ES2286282T3 (es) * 2002-08-22 2007-12-01 Sealed Air Corporation (Us) Proceso para fabricar un articulo de pelicula laminada que tiene camaras hinchables.
US6846884B2 (en) * 2002-09-27 2005-01-25 Union Carbide Chemicals & Plastics Technology Corporation Control of resin properties
WO2004031250A1 (en) 2002-10-02 2004-04-15 Dow Global Technologies Inc. Liquid and gel-like low molecular weight ethylene polymers
US7691305B2 (en) * 2002-10-15 2010-04-06 Dow Global Technologies, Inc. Articles comprising a fiber-reinforced thermoplastic polymer composition
EP1554343B1 (en) 2002-10-17 2008-07-23 Dow Global Technologies Inc. Highly filled polymer compositions
US7579407B2 (en) * 2002-11-05 2009-08-25 Dow Global Technologies Inc. Thermoplastic elastomer compositions
US7459500B2 (en) * 2002-11-05 2008-12-02 Dow Global Technologies Inc. Thermoplastic elastomer compositions
US7510758B2 (en) * 2002-11-12 2009-03-31 Kimberly-Clark Worldwide, Inc. Breathable elastic multilayer film laminate and method of making a breathable elastic multilayer film laminate
US20040096626A1 (en) * 2002-11-14 2004-05-20 Epoli-Espumas De Polietileno Sa Layered structures with enhanced properties
US6989125B2 (en) * 2002-11-21 2006-01-24 Kimberly-Clark Worldwide, Inc. Process of making a nonwoven web
US20040102123A1 (en) * 2002-11-21 2004-05-27 Bowen Uyles Woodrow High strength uniformity nonwoven laminate and process therefor
US7018495B2 (en) 2002-11-22 2006-03-28 Sealed Air Corporation (Us) Process for making and aging high strength high gas barrier cellular cushioning product
US7223461B2 (en) 2002-11-22 2007-05-29 Sealed Air Corporation (Us) High strength high gas barrier cellular cushioning product
US6982113B2 (en) * 2002-11-22 2006-01-03 Sealed Air Corporation (Us) High strength high gas barrier cellular cushioning product
US7040706B2 (en) * 2002-12-09 2006-05-09 Phat Cushion Llc Seat and method of making same
US7736726B2 (en) 2002-12-17 2010-06-15 Cryovac, Inc. Polymeric film with low blocking and high slip properties
US20040122149A1 (en) * 2002-12-19 2004-06-24 Kadakia Vishal S. Flame-retardant polyvinyl chloride compositions
CA2510061A1 (en) 2002-12-20 2004-07-08 Basell Polyolefin Gmbh Copolymers of ethylene with .alpha.-olefins
WO2004056481A1 (en) 2002-12-20 2004-07-08 Basell Polyolefine Gmbh Monocyclopentadienyl complexes
US20040122409A1 (en) * 2002-12-23 2004-06-24 Thomas Oomman Painumoottil Enhanced elastomer blend
US20040131836A1 (en) * 2003-01-02 2004-07-08 3M Innovative Properties Company Acoustic web
US7320739B2 (en) * 2003-01-02 2008-01-22 3M Innovative Properties Company Sound absorptive multilayer composite
CA2454507A1 (en) * 2003-01-08 2004-07-08 Dow Global Technologies Inc. Unitary attic rafter vent and insulation dam assembly
US8518318B2 (en) 2003-01-16 2013-08-27 Viva Healthcare Packaging Limited Methods, compositions and blends for forming articles having improved environmental stress crack resistance
RU2337705C2 (ru) * 2003-01-29 2008-11-10 Нортфилд Лэборэтериз, Инк. Растворы полимеризованного гемоглобина с пониженным количеством тетрамера и способ их получения
US7736737B2 (en) * 2003-01-30 2010-06-15 Dow Global Technologies Inc. Fibers formed from immiscible polymer blends
MXPA05008305A (es) * 2003-02-04 2005-09-20 Dow Global Technologies Inc Capas de pelicula elaboradas a partir de mezclas polimericas.
US7037592B2 (en) * 2003-02-25 2006-05-02 Dow Coming Corporation Hybrid composite of silicone and organic resins
US7338708B2 (en) * 2003-03-05 2008-03-04 Cryovac, Inc. Thick shrink film having high oxygen transmission rate
US6916750B2 (en) 2003-03-24 2005-07-12 Kimberly-Clark Worldwide, Inc. High performance elastic laminates made from high molecular weight styrenic tetrablock copolymer
EP1611201B1 (en) * 2003-03-28 2007-08-15 Dow Global Technologies Inc. Low gloss thermoformable flooring structure
EP1469104A1 (en) * 2003-04-16 2004-10-20 ATOFINA Research Société Anonyme Metallocene produced polyethylene for fibres applications
TW200504093A (en) * 2003-05-12 2005-02-01 Dow Global Technologies Inc Polymer composition and process to manufacture high molecular weight-high density polyethylene and film therefrom
US7517486B2 (en) * 2003-05-16 2009-04-14 Du Pont Performance Elastomers L.L.C. Process for preparing UV curable sealing assemblies
MXPA05013347A (es) * 2003-06-10 2006-04-05 Dow Global Technologies Inc Capas de pelicula hechas a partir de mezclas de polimeros de etileno.
FR2858817B1 (fr) * 2003-08-13 2006-02-03 Michelin Soc Tech Systeme catalytique pour l'obtention de copolymeres diene(s) conjugue(s)/ mono-olefine(s) et ces copolymeres
AU2004264537B2 (en) * 2003-08-13 2010-07-15 Dow Global Technologies Inc. Method for joining substrates and objects
MXPA06001639A (es) 2003-08-13 2006-05-12 Dow Global Technologies Inc Metodo para unir sistemas de tuberia y tuberia a equipo, accesorios, dispositivos, estructuras e instrumentos.
AU2004274488B2 (en) * 2003-08-19 2010-09-09 Dow Global Technologies Llc Interpolymers suitable for use in hot melt adhesives and processes to prepare same
US8946329B2 (en) 2003-08-25 2015-02-03 Dow Global Technologies Llc Coating compositions
US8779053B2 (en) 2003-08-25 2014-07-15 Dow Global Technologies Llc Coating compositions
US8357749B2 (en) * 2003-08-25 2013-01-22 Dow Global Technologies Llc Coating composition and articles made therefrom
US7803865B2 (en) * 2003-08-25 2010-09-28 Dow Global Technologies Inc. Aqueous dispersion, its production method, and its use
US8158711B2 (en) * 2003-08-25 2012-04-17 Dow Global Technologies Llc Aqueous dispersion, its production method, and its use
US9169406B2 (en) 2003-08-25 2015-10-27 Dow Global Technologies Llc Coating compositions
TW200517426A (en) 2003-08-25 2005-06-01 Dow Global Technologies Inc Aqueous dispersion, its production method, and its use
US8349929B2 (en) * 2003-08-25 2013-01-08 Dow Global Technologies Llc Coating composition and articles made therefrom
US8722787B2 (en) 2003-08-25 2014-05-13 Dow Global Technologies Llc Coating composition and articles made therefrom
US7763676B2 (en) 2003-08-25 2010-07-27 Dow Global Technologies Inc. Aqueous polymer dispersions and products from those dispersions
US7776987B2 (en) * 2003-09-05 2010-08-17 Dow Global Technologies, Inc. Resin compositions for extrusion coating
JP4468303B2 (ja) * 2003-09-19 2010-05-26 株式会社プライムポリマー 延伸フィルム
US20050066463A1 (en) * 2003-09-25 2005-03-31 Brunner Michael S. Substrates and devices for applying a lip care formulation
US7632086B2 (en) * 2003-10-03 2009-12-15 Exxonmobil Chemical Patents Inc. Melt fracture reduction
JP2007508973A (ja) * 2003-10-07 2007-04-12 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー 熱成形可能な多層シート
KR20060134920A (ko) * 2003-10-07 2006-12-28 이 아이 듀폰 디 네모아 앤드 캄파니 이오노머 층을 포함하는 다층 시트
US20060057392A1 (en) * 2003-10-07 2006-03-16 Smillie Benjamin A Multi-layer sheet having a weatherable surface layer
MXPA06003822A (es) * 2003-10-07 2006-06-14 Du Pont Hoja ionomerica de capas multiples que tiene resistencia mejorada a las condiciones ambientales.
CN100575071C (zh) * 2003-10-07 2009-12-30 纳幕尔杜邦公司 具有耐天候表面层的多层片材
US20050095943A1 (en) * 2003-10-30 2005-05-05 Kimberly-Clark Worldwide, Inc. Cross machine direction extensible nonwoven webs
US7223814B2 (en) 2003-11-17 2007-05-29 Eastman Chemical Company Hot melt adhesives with improved performance window
US20050112320A1 (en) 2003-11-20 2005-05-26 Wright Jeffery J. Carpet structure with plastomeric foam backing
US7374416B2 (en) * 2003-11-21 2008-05-20 Kimberly-Clark Worldwide, Inc. Apparatus and method for controlled width extrusion of filamentary curtain
JP5005349B2 (ja) * 2003-11-25 2012-08-22 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー 難燃性の、ハロゲンを含まない組成物
US7906586B2 (en) * 2003-12-09 2011-03-15 Dow Global Technologies Llc Thermoplastic olefinic compositions
US20050127578A1 (en) * 2003-12-11 2005-06-16 Triebes Thomas G. Method of making fiber reinforced elastomeric articles
US20050130522A1 (en) * 2003-12-11 2005-06-16 Kaiyuan Yang Fiber reinforced elastomeric article
US7147930B2 (en) * 2003-12-16 2006-12-12 Curwood, Inc. Heat-shrinkable packaging films with improved sealing properties and articles made thereof
KR20060111583A (ko) 2003-12-18 2006-10-27 다우 글로벌 테크놀로지스 인크. 높은 변형 속도 하에 우수한 내충격성 및 향상된 격변성파열 내성을 갖는 필름
US7662745B2 (en) 2003-12-18 2010-02-16 Kimberly-Clark Corporation Stretchable absorbent composites having high permeability
US20050133948A1 (en) * 2003-12-22 2005-06-23 Cook Michael C. Apparatus and method for multicomponent fibers
US7168932B2 (en) * 2003-12-22 2007-01-30 Kimberly-Clark Worldwide, Inc. Apparatus for nonwoven fibrous web
EP1942152A1 (en) 2003-12-24 2008-07-09 Dow Gloval Technologies Inc. Polymeric composition
EP2050793A3 (en) 2003-12-24 2009-05-13 Dow Global Technologies Inc. Free-radical initiation in the precence of a stable organic free radical and related compositions
US7198742B2 (en) * 2003-12-30 2007-04-03 Kimberly-Clark Worldwide, Inc. Apparatus and method for deforming sheet material
US20050142339A1 (en) * 2003-12-30 2005-06-30 Price Cindy L. Reinforced elastic laminate
US7601657B2 (en) * 2003-12-31 2009-10-13 Kimberly-Clark Worldwide, Inc. Single sided stretch bonded laminates, and methods of making same
US8455574B2 (en) * 2004-02-19 2013-06-04 E I Du Pont De Nemours And Company Composite compositions comprising cellulose and polymeric components
US20050186376A1 (en) * 2004-02-20 2005-08-25 Honeywell International Inc. Multilayer sheets and films composed of PCTFE and cyclic olefin copolymer
US7211308B2 (en) * 2004-02-20 2007-05-01 Honeywell International Inc. Formation of multilayer sheets containing PCTFE and COC for blister packaging applications
US20060019112A1 (en) * 2004-03-15 2006-01-26 Holmes David A Use of branched polyethylenes in multilayer films and resealable closures
US8273826B2 (en) * 2006-03-15 2012-09-25 Dow Global Technologies Llc Impact modification of thermoplastics with ethylene/α-olefin interpolymers
SG183749A1 (en) 2004-03-17 2012-09-27 Dow Global Technologies Llc Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation
EP2327727B1 (en) 2004-03-17 2015-07-22 Dow Global Technologies LLC Catalyst composition comprising shuttling agent for ethylene copolymer formation
US7101622B2 (en) * 2004-03-19 2006-09-05 Dow Global Technologies Inc. Propylene-based copolymers, a method of making the fibers and articles made from the fibers
CN1934184A (zh) * 2004-03-19 2007-03-21 陶氏环球技术公司 由聚合物配方制成的薄膜层
US7101623B2 (en) * 2004-03-19 2006-09-05 Dow Global Technologies Inc. Extensible and elastic conjugate fibers and webs having a nontacky feel
EP1727838B1 (en) 2004-03-24 2013-04-17 ExxonMobil Chemical Patents Inc. Process for making ethylene interpolymers and interpolymers made thereby; compositions and electrical devices containing such interpolymers
US20050220846A1 (en) 2004-04-05 2005-10-06 Puntenney Steven B Use of beta-1,3 (4)-endoglucanohydrolase, beta-1,3 (4) glucan, diatomaceous earth, mineral clay and glucomannan to augment immune function
US7360552B2 (en) * 2004-04-23 2008-04-22 Dow Global Technologies Inc. Injectable structural adhesive
WO2005111282A1 (en) * 2004-04-30 2005-11-24 Dow Global Technologies Inc. Improved nonwoven fabric and fibers
US20050241088A1 (en) * 2004-04-30 2005-11-03 Kimberly-Clark Worldwide, Inc. Device for treating surfaces
US20050245162A1 (en) * 2004-04-30 2005-11-03 Kimberly-Clark Worldwide, Inc. Multi-capable elastic laminate process
US20050241089A1 (en) * 2004-04-30 2005-11-03 Kimberly-Clark Worldwide, Inc. Device for treating surfaces
US20050288440A1 (en) * 2004-06-21 2005-12-29 Chou Richard T Polyolefin foams for footwear foam applications
ES2341977T3 (es) * 2004-06-28 2010-06-30 Dow Global Technologies Inc. Promotores de adhesion para materiales estratificados multiestructurales.
US7285595B2 (en) * 2004-06-30 2007-10-23 Kimberly-Clark Worldwide, Inc. Synergistic fluorochemical treatment blend
US7772456B2 (en) * 2004-06-30 2010-08-10 Kimberly-Clark Worldwide, Inc. Stretchable absorbent composite with low superaborbent shake-out
US7247215B2 (en) 2004-06-30 2007-07-24 Kimberly-Clark Worldwide, Inc. Method of making absorbent articles having shaped absorbent cores on a substrate
US7938813B2 (en) * 2004-06-30 2011-05-10 Kimberly-Clark Worldwide, Inc. Absorbent article having shaped absorbent core formed on a substrate
US20060003656A1 (en) * 2004-06-30 2006-01-05 Kimberly-Clark Worldwide, Inc. Efficient necked bonded laminates and methods of making same
US20060003154A1 (en) * 2004-06-30 2006-01-05 Snowden Hue S Extruded thermoplastic articles with enhanced surface segregation of internal melt additive
ES2416314T3 (es) 2004-08-27 2013-07-31 Chevron Phillips Chemical Company Lp Procesos de producción de poliolefinas
US7846530B2 (en) * 2004-09-27 2010-12-07 Kimberly-Clark Worldwide, Inc. Creped electret nonwoven wiper
US7500541B2 (en) * 2004-09-30 2009-03-10 Kimberly-Clark Worldwide, Inc. Acoustic material with liquid repellency
US20060069365A1 (en) * 2004-09-30 2006-03-30 Sperl Michael D Absorbent composite having selective regions for improved attachment
US20060070712A1 (en) * 2004-10-01 2006-04-06 Runge Troy M Absorbent articles comprising thermoplastic resin pretreated fibers
US20060086472A1 (en) * 2004-10-27 2006-04-27 Kimberly-Clark Worldwide, Inc. Soft durable paper product
US8093341B2 (en) 2004-10-28 2012-01-10 Dow Global Technologies Llc Method of controlling a polymerization reactor
US20070029702A1 (en) * 2004-11-15 2007-02-08 Peterson Curt E Thermoplastic elastomer bonded directly to metal substrate
AU2005307750B2 (en) * 2004-11-16 2011-09-01 Dow Global Technologies Llc Elastomeric compositions with improved resistance to necking for high speed sheet extrusion applications
WO2006060714A1 (en) * 2004-12-03 2006-06-08 Dow Global Technologies Inc. Wood fiber plastic composites
US20060143767A1 (en) * 2004-12-14 2006-07-06 Kaiyuan Yang Breathable protective articles
US7238423B2 (en) * 2004-12-20 2007-07-03 Kimberly-Clark Worldwide, Inc. Multicomponent fiber including elastic elements
EP2281859B1 (en) 2004-12-21 2014-03-26 Dow Global Technologies LLC Polypropylene-based adhesive compounds
CN101084262B (zh) * 2004-12-21 2011-06-01 陶氏环球技术公司 可硫化的卤化弹性体组合物
US20060135932A1 (en) * 2004-12-21 2006-06-22 Abuto Frank P Stretchable absorbent core and wrap
US7651653B2 (en) * 2004-12-22 2010-01-26 Kimberly-Clark Worldwide, Inc. Machine and cross-machine direction elastic materials and methods of making same
US7763061B2 (en) * 2004-12-23 2010-07-27 Kimberly-Clark Worldwide, Inc. Thermal coverings
US20060142712A1 (en) * 2004-12-23 2006-06-29 Kimberly-Clark Worldwide, Inc. Absorbent articles that provide warmth
US7676088B2 (en) * 2004-12-23 2010-03-09 Asml Netherlands B.V. Imprint lithography
US20060140902A1 (en) * 2004-12-23 2006-06-29 Kimberly-Clark Worldwide, Inc. Odor control substrates
US7816285B2 (en) 2004-12-23 2010-10-19 Kimberly-Clark Worldwide, Inc. Patterned application of activated carbon ink
US7338516B2 (en) * 2004-12-23 2008-03-04 Kimberly-Clark Worldwide, Inc. Method for applying an exothermic coating to a substrate
US20060148358A1 (en) * 2004-12-30 2006-07-06 Hall Gregory K Elastic laminate and process therefor
US20060148361A1 (en) * 2004-12-30 2006-07-06 Kimberley-Clark Worldwide, Inc. Method for forming an elastic laminate
US20060148359A1 (en) * 2004-12-30 2006-07-06 Kimberly-Clark Worldwide, Inc. Nonwoven loop material
US8052666B2 (en) * 2004-12-30 2011-11-08 Kimberly-Clark Worldwide, Inc. Fastening system having elastomeric engaging elements and disposable absorbent article made therewith
US7175543B2 (en) 2005-01-26 2007-02-13 Callaway Golf Company Golf ball and thermoplastic material
US7156755B2 (en) 2005-01-26 2007-01-02 Callaway Golf Company Golf ball with thermoplastic material
US7326753B2 (en) 2005-02-08 2008-02-05 Momentive Performance Materials Inc. Process for the production of crosslinked polymer employing low VOC-producing silane crosslinker and resulting crosslinked polymer
JP5241242B2 (ja) * 2005-02-16 2013-07-17 ダウ・コーニング・コーポレイション 強化シリコーン樹脂フィルムおよびその製造方法
US8092910B2 (en) * 2005-02-16 2012-01-10 Dow Corning Toray Co., Ltd. Reinforced silicone resin film and method of preparing same
US7312267B2 (en) * 2005-02-23 2007-12-25 Callaway Golf Company Golf ball and thermoplastic material
US7612134B2 (en) * 2005-02-23 2009-11-03 Callaway Golf Company Golf ball and thermoplastic material
JP5179199B2 (ja) * 2005-03-04 2013-04-10 ダウ グローバル テクノロジーズ エルエルシー 改良された低密度エチレンポリマー組成物、および、その製造方法
EP1858972A1 (en) * 2005-03-04 2007-11-28 Dow Gloval Technologies Inc. Improved polyethylene resin compositions having low mi and high melt strength
US20060210743A1 (en) * 2005-03-17 2006-09-21 Cryovac, Inc. Abuse-resistant retortable packaging film having oxygen barrier layer containing blend of amorphous polyamide and semicrystalline polyamide
US20060210742A1 (en) * 2005-03-17 2006-09-21 Cryovac, Inc. Retortable packaging film with outer layers containing blend of propylene-based polymer and homogeneous polymer
US20060210741A1 (en) * 2005-03-17 2006-09-21 Cryovac, Inc. Retortable packaging film with having seal/product-contact layer containing blend of polyethylenes and skin layer containing propylene-based polymer blended with polyethylene
US20060210744A1 (en) * 2005-03-17 2006-09-21 Cryovac, Inc. Retortable packaging film with grease-resistance
US20060210740A1 (en) * 2005-03-17 2006-09-21 Cryovac, Inc. Retort packaging process and product utilizing high-temperature abuse layer and low-temperature abuse layer
US7807253B2 (en) * 2005-03-21 2010-10-05 Sealed Air Corporation (Us) Formed inflatable cellular cushioning article and method of making same
US8677513B2 (en) 2005-04-01 2014-03-25 Kimberly-Clark Worldwide, Inc. Surgical sleeve for glove retention
DE102005020205A1 (de) † 2005-04-28 2006-11-09 Jowat Ag Nichtreaktive thermoplastische Schmelzklebstoffe auf Basis von metallocenkatalytisch hergestellten Polyolefinen
US20060246802A1 (en) * 2005-04-29 2006-11-02 Hughes Janis W Color change laminate material
US20060245816A1 (en) * 2005-04-29 2006-11-02 Kimberly-Clark Worldwide, Inc. Fabric cleaning article
US20060243409A1 (en) * 2005-04-29 2006-11-02 Fish Jeffrey E Edge-stiffened sheet material probe
US8304496B2 (en) * 2005-05-12 2012-11-06 Dow Global Technologies Llc Thermoformed, extruded sheeting with reduced gloss
AU2006250280A1 (en) * 2005-05-24 2006-11-30 Chevron Phillips Chemical Co Lp An integrated on-line two-dimensional method and device for synchronized analytical temperature rising elution fractionation and gel permeation chromatography
US7399737B2 (en) 2005-06-13 2008-07-15 Exxonmobil Chemical Patents Inc. Lube additives
EP1733873A1 (en) * 2005-06-15 2006-12-20 Total Petrochemicals Research Feluy High clarity easy tear multilayer films
US7685649B2 (en) * 2005-06-20 2010-03-30 Kimberly-Clark Worldwide, Inc. Surgical gown with elastomeric fibrous sleeves
US20070000014A1 (en) * 2005-06-20 2007-01-04 John Rotella Surgical gown with a film sleeve for glove retention and wearer protection
US20070004864A1 (en) * 2005-06-24 2007-01-04 University Of Florida Research Foundation Method to enhance impact strength properties of melt processed polypropylene resins
US8287949B2 (en) 2005-07-07 2012-10-16 Dow Global Technologies Inc. Aqueous dispersions
US20090202829A1 (en) * 2005-07-07 2009-08-13 Fox Richard T Long Fiber-Reinforced Thermoplastic Concentrate and Method for Its Preparation
MY148274A (en) * 2005-07-08 2013-03-29 Dow Global Technologies Inc Layered film compositions, packages prepared therefrom, and methods of use
ES2508140T3 (es) 2005-07-11 2014-10-16 Dow Global Technologies Llc Composiciones que comprenden una mezcla de polímeros de olefina injertados con silano
US7422796B2 (en) 2005-07-19 2008-09-09 E. I. Du Pont De Nemours And Company Film structures having improved oxygen transmission
US7655829B2 (en) 2005-07-29 2010-02-02 Kimberly-Clark Worldwide, Inc. Absorbent pad with activated carbon ink for odor control
WO2007018756A1 (en) * 2005-08-04 2007-02-15 Dow Corning Corporation Reinforced silicone resin film and method of preparing same
DE602006009540D1 (de) * 2005-08-24 2009-11-12 Dow Global Technologies Inc L und herstellungsverfahren dafür
US20070049153A1 (en) * 2005-08-31 2007-03-01 Dunbar Charlene H Textured wiper material with multi-modal pore size distribution
US7416627B2 (en) * 2005-08-31 2008-08-26 Kimberly-Clark Worldwide, Inc. Films and film laminates having cushioning cells and processes of making thereof
US20070048497A1 (en) * 2005-08-31 2007-03-01 Peiguang Zhou Single-faced neck bonded laminates and methods of making same
AU2006291074A1 (en) * 2005-09-12 2007-03-22 Dow Global Technologies Llc Automotive parts prepared from ethylene/alpha -olefins compositions
ATE462563T1 (de) * 2005-09-21 2010-04-15 Rkw Se Selbstklebende oberflächenschutzfolie
US20070078223A1 (en) * 2005-09-30 2007-04-05 Chen John C Compositions and structures having tailored oxygen transmission
US7714082B2 (en) * 2005-10-04 2010-05-11 Univation Technologies, Llc Gas-phase polymerization process to achieve a high particle density
TWI386310B (zh) 2005-10-07 2013-02-21 Dow Global Technologies Llc 多層彈性膜結構物
DE602006015081D1 (de) * 2005-10-31 2010-08-05 Dow Global Technologies Inc Elastomere zusammensetzung auf basis von propylen
BRPI0620542A2 (pt) 2005-11-23 2011-11-16 Dow Global Technologies Inc copolìmero compreendendo etileno interpolimerizado com pelo menos uma (alfa)-olefina c3-10 e mistura de polìmeros
US20070135785A1 (en) * 2005-12-12 2007-06-14 Jian Qin Absorbent articles comprising thermoplastic coated superabsorbent polymer materials
US20070141937A1 (en) * 2005-12-15 2007-06-21 Joerg Hendrix Filament-meltblown composite materials, and methods of making same
US7883604B2 (en) * 2005-12-15 2011-02-08 Kimberly-Clark Worldwide, Inc. Creping process and products made therefrom
US8043713B2 (en) * 2005-12-15 2011-10-25 Dow Global Technologies Llc Compositions and aqueous dispersions
US7879191B2 (en) * 2005-12-15 2011-02-01 Kimberly-Clark Worldwide, Inc. Wiping products having enhanced cleaning abilities
US7422712B2 (en) * 2005-12-15 2008-09-09 Kimberly-Clark Worldwide, Inc. Technique for incorporating a liquid additive into a nonwoven web
US7879189B2 (en) * 2005-12-15 2011-02-01 Kimberly-Clark Worldwide, Inc. Additive compositions for treating various base sheets
US7837831B2 (en) * 2005-12-15 2010-11-23 Kimberly-Clark Worldwide, Inc. Tissue products containing a polymer dispersion
US7794486B2 (en) * 2005-12-15 2010-09-14 Kimberly-Clark Worldwide, Inc. Therapeutic kit employing a thermal insert
US8444811B2 (en) 2005-12-15 2013-05-21 Kimberly-Clark Worldwide, Inc. Process for increasing the basis weight of sheet materials
US7528080B2 (en) * 2005-12-15 2009-05-05 Dow Global Technologies, Inc. Aqueous polyolefin dispersions for textile impregnation
US20070137811A1 (en) * 2005-12-15 2007-06-21 Kimberly-Clark Worldwide, Inc. Premoistened tissue products
US20070142882A1 (en) * 2005-12-15 2007-06-21 Kimberly-Clark Worldwide, Inc. Thermal device having a controlled heating profile
US20070141936A1 (en) * 2005-12-15 2007-06-21 Bunyard William C Dispersible wet wipes with improved dispensing
US7686840B2 (en) 2005-12-15 2010-03-30 Kimberly-Clark Worldwide, Inc. Durable exothermic coating
US7807023B2 (en) * 2005-12-15 2010-10-05 Kimberly-Clark Worldwide, Inc. Process for increasing the basis weight of sheet materials
US7976662B2 (en) * 2005-12-15 2011-07-12 Kimberly-Clark Worldwide, Inc. Laminate containing a fluorinated nonwoven web
US8282776B2 (en) * 2005-12-15 2012-10-09 Kimberly-Clark Worldwide, Inc. Wiping product having enhanced oil absorbency
US7820010B2 (en) * 2005-12-15 2010-10-26 Kimberly-Clark Worldwide, Inc. Treated tissue products having increased strength
US7842163B2 (en) * 2005-12-15 2010-11-30 Kimberly-Clark Worldwide, Inc. Embossed tissue products
US7879188B2 (en) * 2005-12-15 2011-02-01 Kimberly-Clark Worldwide, Inc. Additive compositions for treating various base sheets
ZA200806140B (en) 2005-12-15 2009-12-30 Dow Global Technologies Inc Improved cellulose articles containing an addictive composition
US7837832B2 (en) 2005-12-15 2010-11-23 Dow Global Technologies, Inc. Additive compositions for treating various base sheets
US20070137769A1 (en) * 2005-12-15 2007-06-21 Payne Patrick L Method for forming a printed film-nonwoven laminate
US8137392B2 (en) * 2005-12-15 2012-03-20 Kimberly-Clark Worldwide, Inc. Conformable thermal device
US20070141303A1 (en) * 2005-12-15 2007-06-21 Steindorf Eric C Sheet materials with zoned machine direction extensibility and methods of making
US7647964B2 (en) * 2005-12-19 2010-01-19 Fairmount Minerals, Ltd. Degradable ball sealers and methods for use in well treatment
US20070141373A1 (en) * 2005-12-20 2007-06-21 Sommerfeld Eugene G Segmented copolyesterether adhesive compositions
US7629421B2 (en) * 2005-12-21 2009-12-08 Chevron Phillips Chemical Company Lp Monomer recovery by returning column overhead liquid to the reactor
US8912268B2 (en) * 2005-12-21 2014-12-16 Dow Corning Corporation Silicone resin film, method of preparing same, and nanomaterial-filled silicone composition
ATE515528T1 (de) * 2006-01-19 2011-07-15 Dow Corning Silikonharzfilm, herstellungsverfahren dafür und mit nanomaterial gefüllte silikonzusammensetzung
US20090004159A1 (en) * 2006-01-24 2009-01-01 The Board Of Trustees Of The University Of Illinoi Polymerized Hemoglobin Media and Its Use in Isolation and Transplantation of Islet Cells
US20070196810A1 (en) * 2006-01-24 2007-08-23 Northfield Laboratories Inc. Polymerized Hemoglobin Media and its Use in Isolation and Transplantation of Islet Cells
US7612135B2 (en) * 2006-02-17 2009-11-03 Callaway Golf Company Golf ball and thermoplastic material
WO2007097835A2 (en) * 2006-02-20 2007-08-30 Dow Corning Corporation Silicone resin film, method of preparing same, and nanomaterial-filled silicone composition
US8007978B2 (en) * 2006-03-03 2011-08-30 Dow Global Technologies Llc Aqueous dispersions for use as toners
US9547246B2 (en) * 2006-03-03 2017-01-17 Dow Global Technologies Llc Aqueous dispersions for use as toners
EP1999204B1 (en) * 2006-03-17 2017-05-24 Dow Global Technologies LLC An impact resistant rigid vinyl chloride polymer composition and method of making the same
RU2444546C2 (ru) * 2006-04-07 2012-03-10 ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи Полиолефиновые композиции, изделия из них и методы их получения
US20070255243A1 (en) * 2006-04-28 2007-11-01 Kaun James M Dimensionally stable stretchable absorbent composite
US20100224199A1 (en) * 2006-05-01 2010-09-09 Kimberly-Clark Worldwide, Inc. Respirator
US20070251522A1 (en) * 2006-05-01 2007-11-01 Welchel Debra N Respirator with exhalation vents
US20080110465A1 (en) * 2006-05-01 2008-05-15 Welchel Debra N Respirator with exhalation vents
EP2029356A2 (en) * 2006-05-25 2009-03-04 Dow Global Technologies Inc. Soft and extensible polypropylene based spunbond nonwovens
US20070275196A1 (en) * 2006-05-25 2007-11-29 Cryovac, Inc. Multilayer Film Having High Oxygen Transmission and High Modulus
US7829197B2 (en) 2006-06-13 2010-11-09 E. I. Du Pont De Nemours And Company Variable vapor barrier for humidity control
WO2007146986A1 (en) 2006-06-14 2007-12-21 Avery Dennison Corporation Conformable and die-cuttable machine direction oriented labelstocks and labels, and process for preparing
CN103214624A (zh) 2006-06-15 2013-07-24 陶氏环球技术有限责任公司 官能化烯烃共聚体、组合物和由其制成的制品、以及它们的制造方法
AU2007261011B2 (en) 2006-06-20 2012-04-05 Avery Dennison Corporation Multilayered polymeric film for hot melt adhesive labeling and label stock and label thereof
CN101472958B (zh) 2006-06-28 2012-08-08 陶氏环球技术有限责任公司 氯化乙烯基聚合物和组合物及其制品
CA2654380C (en) * 2006-06-29 2014-07-22 Dow Global Technologies Inc. Protective adhesive films
US7585382B2 (en) * 2006-06-30 2009-09-08 Kimberly-Clark Worldwide, Inc. Latent elastic nonwoven composite
US8916640B2 (en) * 2006-07-06 2014-12-23 Dow Global Technologies Llc Blended polyolefin dispersions
US8785531B2 (en) 2006-07-06 2014-07-22 Dow Global Technologies Llc Dispersions of olefin block copolymers
MX2009000542A (es) * 2006-07-14 2009-03-26 Dow Global Technologies Inc Estructuras compuestas de pelicula-espuma anisotropica.
CN101489787B (zh) * 2006-07-17 2012-12-12 艾利丹尼森公司 非对称多层聚合物膜和标签材料及其标签
US8080607B2 (en) 2006-08-16 2011-12-20 Dow Global Technologies Llc Polymeric material and process for forming and using same
US7964110B2 (en) * 2006-08-30 2011-06-21 Dow Global Technologies Llc Cure system for halogenated elastomer compositions, a curable halogenated elastomer composition, and a method for curing halogenated elastomer compositions
WO2008027754A2 (en) * 2006-08-30 2008-03-06 Dow Global Technologies Inc. A cure system for halogenated elastomer compositions, a curable halogenated elastomer composition, and a method for curing halogenated elastomer compositions
US20080120761A1 (en) * 2006-08-31 2008-05-29 Kaiyuan Yang Thermal Moderating Donnable Elastic Articles
US7803244B2 (en) 2006-08-31 2010-09-28 Kimberly-Clark Worldwide, Inc. Nonwoven composite containing an apertured elastic film
RU2418012C2 (ru) * 2006-09-11 2011-05-10 Дау Глобал Текнолоджиз Инк. Технология полиолефиновой дисперсии, примененная для песка, покрытого смолой
US8581094B2 (en) * 2006-09-20 2013-11-12 Dow Global Technologies, Llc Electronic device module comprising polyolefin copolymer
EP3232279B1 (en) 2006-09-21 2019-08-07 Union Carbide Chemicals & Plastics Technology LLC Method of controlling properties in multimodal systems
US8476326B2 (en) * 2006-09-22 2013-07-02 Dow Global Technologies Llc Fibrillated polyolefin foam
US7659346B2 (en) * 2006-09-27 2010-02-09 Equistar Chemicals, Lp Process for maleating polymerization residues and products
US20080076315A1 (en) * 2006-09-27 2008-03-27 Mccormack Ann L Elastic Composite Having Barrier Properties
JP2010505996A (ja) * 2006-10-05 2010-02-25 ダウ・コーニング・コーポレイション シリコーン樹脂フィルムおよびこれを調製していくとの方法
US20080118728A1 (en) 2006-10-20 2008-05-22 Dow Global Technologies Inc. Aqueous dispersions disposed on glass-based fibers and glass-containing substrates
US8344068B2 (en) 2006-10-23 2013-01-01 Dow Global Technologies Llc Polyethylene compositions, methods of making the same, and articles prepared therefrom
KR101125702B1 (ko) 2006-10-25 2012-03-27 다우 글로벌 테크놀로지스 엘엘씨 폴리올레핀 분산액, 포말 및 발포체
US8404780B2 (en) * 2006-11-01 2013-03-26 Dow Global Technologies Llc Articles comprising nonpolar polyolefin and polyurethane, and methods for their preparation and use
EP2087166B1 (en) * 2006-11-13 2012-07-25 Shaw Industries Group, Inc. Methods and systems for recycling carpet and carpets manufactured from recycled material
US7582178B2 (en) * 2006-11-22 2009-09-01 Kimberly-Clark Worldwide, Inc. Nonwoven-film composite with latent elasticity
US7938921B2 (en) * 2006-11-22 2011-05-10 Kimberly-Clark Worldwide, Inc. Strand composite having latent elasticity
US7785443B2 (en) * 2006-12-07 2010-08-31 Kimberly-Clark Worldwide, Inc. Process for producing tissue products
US7979946B2 (en) 2006-12-15 2011-07-19 Kimberly-Clark Worldwide, Inc. Polish and polishing mitts
US7707655B2 (en) * 2006-12-15 2010-05-04 Kimberly-Clark Worldwide, Inc. Self warming mask
US7863522B2 (en) * 2006-12-20 2011-01-04 Dow Global Technologies Inc. Semi-conducting polymer compositions for the preparation of wire and cable
EP2514788B1 (en) 2006-12-21 2017-02-01 Dow Global Technologies LLC Phosphorus-sulfur flame retardant additives and polymer systems containing same
CN101611088A (zh) * 2006-12-21 2009-12-23 陶氏环球技术公司 填充的热塑性聚烯烃组合物、制备其的方法和由其制得的制品
WO2008080111A1 (en) 2006-12-21 2008-07-03 Dow Global Technologies Inc. Polyolefin compositions and articles prepared therefrom, and methods for making the same
JP2007128899A (ja) * 2006-12-22 2007-05-24 Nippon Unicar Co Ltd 難燃性電線・ケーブル
US7862671B2 (en) * 2007-01-11 2011-01-04 Dow Global Technologies Inc. Welding of a polymeric material and structures formed thereby
PL2137257T3 (pl) * 2007-01-12 2011-03-31 Dow Global Technologies Inc Kompozycja odpowiednia do wyrobów cienkościennych formowanych wtryskowo
SI2109641T1 (sl) * 2007-01-17 2017-08-31 Agrofresh Inc. Dobava etilen blokirnega in promocijskega sedstva
CN101595166A (zh) * 2007-02-06 2009-12-02 陶氏康宁公司 有机硅树脂、有机硅组合物、涂覆基材和增强有机硅树脂膜
US20110039064A1 (en) * 2007-02-08 2011-02-17 Dow Global Technologies Inc. Flexible conductive polymeric sheet
US20100087581A1 (en) * 2007-02-22 2010-04-08 Mark Fisher Reinforced Silicone Resin Film and Method of Preparing Same
JP5426402B2 (ja) * 2007-02-22 2014-02-26 ダウ コーニング コーポレーション 強化シリコーン樹脂フィルム
US8273448B2 (en) * 2007-02-22 2012-09-25 Dow Corning Corporation Reinforced silicone resin films
KR20100014391A (ko) * 2007-02-22 2010-02-10 다우 코닝 코포레이션 강화 실리콘 수지 필름 및 이의 제조방법
US7910795B2 (en) * 2007-03-09 2011-03-22 Kimberly-Clark Worldwide, Inc. Absorbent article containing a crosslinked elastic film
US7868107B2 (en) * 2007-03-09 2011-01-11 Zeon Corporation Process for producing cycloolefin addition polymer, catalyst for addition polymerization of cycloolefin, and transition metal compound
US8895111B2 (en) * 2007-03-14 2014-11-25 Kimberly-Clark Worldwide, Inc. Substrates having improved ink adhesion and oil crockfastness
US8680399B2 (en) * 2007-03-15 2014-03-25 Union Carbide Chemicals & Plastics Technology Llc Cable insulation with reduced electrical treeing
US7588662B2 (en) 2007-03-22 2009-09-15 Kimberly-Clark Worldwide, Inc. Tissue products containing non-fibrous polymeric surface structures and a topically-applied softening composition
US7879747B2 (en) 2007-03-30 2011-02-01 Kimberly-Clark Worldwide, Inc. Elastic laminates having fragrance releasing properties and methods of making the same
EP2136994B1 (en) * 2007-04-03 2018-08-22 Dow Global Technologies LLC Hot film lamination (vacuum assisted) for carpet backing applications
US7754834B2 (en) * 2007-04-12 2010-07-13 Univation Technologies, Llc Bulk density promoting agents in a gas-phase polymerization process to achieve a bulk particle density
ES2908419T3 (es) 2007-04-17 2022-04-29 Lycra Company Uk Ltd Hilos elásticos compuestos y tejidos fabricados con ellos, y métodos y equipos para fabricarlos
KR20100017503A (ko) * 2007-05-01 2010-02-16 다우 코닝 코포레이션 강화 실리콘 수지 필름
WO2008134241A1 (en) * 2007-05-01 2008-11-06 Dow Corining Corporation Nanomaterial-filled silicone composition and reinforced silicone resin film
KR20100014214A (ko) 2007-05-02 2010-02-10 다우 글로벌 테크놀로지스 인크. 고-밀도 폴리에틸렌 조성물, 그의 제조 방법, 그로부터 만들어진 사출 성형 물품, 및 이러한 물품의 제조 방법
US8029190B2 (en) * 2007-05-10 2011-10-04 Kimberly-Clark Worldwide, Inc. Method and articles for sensing relative temperature
US20100018641A1 (en) * 2007-06-08 2010-01-28 Kimberly-Clark Worldwide, Inc. Methods of Applying Skin Wellness Agents to a Nonwoven Web Through Electrospinning Nanofibers
CA2691206C (en) * 2007-06-27 2016-04-05 Dow Global Technologies Inc. Crosslinkable blends of polyolefin elastomers and silane copolymers for increased flexibility cable insulation
US8460588B2 (en) 2007-07-30 2013-06-11 Kimberly-Clark Worldwide, Inc. Cross directional zoned bicomponent films, film laminates, and systems and methods for manufacture of the same
US9642403B2 (en) 2007-08-16 2017-05-09 Kimberly-Clark Worldwide, Inc. Strap fastening system for a disposable respirator providing improved donning
US20090044811A1 (en) 2007-08-16 2009-02-19 Kimberly-Clark Worldwide, Inc. Vent and strap fastening system for a disposable respirator providing improved donning
US8815360B2 (en) * 2007-08-28 2014-08-26 Cryovac, Inc. Multilayer film having passive and active oxygen barrier layers
US9452592B2 (en) * 2007-08-28 2016-09-27 Cryovac, Inc. Multilayer film having an active oxygen barrier layer with radiation enhanced active barrier properties
US20090057456A1 (en) * 2007-08-31 2009-03-05 Thomas Gerard Shannon Rolled Tissue Product Having a Flexible Core
US20090057169A1 (en) * 2007-08-31 2009-03-05 Benjamin Joseph Kruchoski Spindle and Spindle Attachments for Coreless and Flexible Core Rolled Tissue Products
US7843560B2 (en) * 2007-08-31 2010-11-30 Dow Global Technologies Inc. Stable turbidity calibration standards
EP2190918B1 (en) * 2007-09-07 2011-06-15 Dow Global Technologies LLC Filled tpo compositions with good low temperature ductility
EP2207835B1 (en) 2007-09-11 2017-08-23 Dow Global Technologies LLC Compositions and articles prepared therefrom
CN101855028A (zh) * 2007-09-14 2010-10-06 陶氏环球技术公司 经涂覆的聚合物粒子、和涂覆聚合物粒子的方法
EP2205794B1 (en) * 2007-09-24 2018-03-21 Dow Global Technologies LLC Synthetic turf with shock absorption layer
US8080735B2 (en) * 2007-09-25 2011-12-20 Dow Global Technologies Llc Styrenic polymers as blend components to control adhesion between olefinic substrates
CN101878265A (zh) * 2007-09-28 2010-11-03 陶氏环球技术公司 具有改善热变形温度的热塑性烯烃组合物
WO2009045731A2 (en) 2007-09-28 2009-04-09 Dow Global Technologies Inc. Dispersions of higher crystallinity olefins
WO2009043946A1 (es) 2007-10-02 2009-04-09 Dow Global Technologies Inc. Métodos para la reducción de aditivos polares necesarios para uso en poliolefinas
KR20100082766A (ko) * 2007-10-12 2010-07-19 다우 코닝 코포레이션 산화알루미늄 분산액 및 이의 제조방법
ATE515529T1 (de) * 2007-10-12 2011-07-15 Dow Corning Folie aus verstärktem silikonharz und nanofasergefüllte silikonzusammensetzung
US7923392B2 (en) * 2007-10-16 2011-04-12 Kimberly-Clark Worldwide, Inc. Crosslinked elastic material formed from a branched block copolymer
US8349963B2 (en) * 2007-10-16 2013-01-08 Kimberly-Clark Worldwide, Inc. Crosslinked elastic material formed from a linear block copolymer
US8399368B2 (en) * 2007-10-16 2013-03-19 Kimberly-Clark Worldwide, Inc. Nonwoven web material containing a crosslinked elastic component formed from a linear block copolymer
US7923391B2 (en) * 2007-10-16 2011-04-12 Kimberly-Clark Worldwide, Inc. Nonwoven web material containing crosslinked elastic component formed from a pentablock copolymer
EP2205674B1 (en) 2007-10-22 2019-04-17 Trinseo Europe GmbH Polymeric compositions and processes for molding articles
US8475878B2 (en) * 2007-10-25 2013-07-02 Dow Global Technologies Llc Polyolefin dispersion technology used for porous substrates
JP5334981B2 (ja) * 2007-11-01 2013-11-06 ダウ グローバル テクノロジーズ エルエルシー シラン官能性樹脂の架橋のための現場での水分発生及び多官能性アルコールの使用
US8765895B2 (en) 2007-11-08 2014-07-01 Innolene Llc Crosslinked polyolefins for biomedical applications and method of making same
WO2009064692A1 (en) 2007-11-14 2009-05-22 Dow Global Technologies Inc. Articles and methods of making the same
US8859661B2 (en) 2007-11-15 2014-10-14 Dow Global Technologies Llc Coating composition, a coated article, and method of forming such articles
US10793738B2 (en) 2007-11-15 2020-10-06 Dow Global Technologies Llc Coating composition, a coated article, and method of forming such articles
EP2212359B1 (en) 2007-11-19 2013-08-28 Dow Global Technologies LLC Long chain branched propylene-alpha-olefin copolymers
EP2214903A1 (en) * 2007-11-27 2010-08-11 Dow Global Technologies Inc. A multilayer structure for the manufacture of packaging and packaging thereof
EP2217971B1 (en) * 2007-11-29 2018-05-23 Dow Global Technologies LLC Compounds and methods of forming compounds useful as a toner
US20090143535A1 (en) * 2007-11-29 2009-06-04 Dow Global Technologies Inc. Impact modifier composition, an impact resistant composition, method of producing the same, and articles made therefrom
US20090151849A1 (en) * 2007-12-13 2009-06-18 Kimberly-Clark Worldwide, Inc. Cosmetic Wipe that Provides a Visual Indication of its Effectiveness
US20090157032A1 (en) * 2007-12-13 2009-06-18 Kimberly-Clark Worldwide, Inc. Absorbant articles having a compressed tablet
US20090157022A1 (en) * 2007-12-13 2009-06-18 Kimberly-Clark Worldwide, Inc. Absorbent articles having a wetness indicator
US9089454B2 (en) * 2007-12-14 2015-07-28 Kimberly-Clark Worldwide, Inc. Absorbent article having a functional and partially encircling waistband
BRPI0819478B1 (pt) * 2007-12-28 2019-04-24 Dow Global Technologies Inc. Espuma reticulada, método para formar uma espuma reticulada, tufo artificial e sapato
EP2080615A1 (en) 2008-01-18 2009-07-22 Dow Global Technologies Inc. Coated substrates and packages prepared therefrom
US8287677B2 (en) 2008-01-31 2012-10-16 Kimberly-Clark Worldwide, Inc. Printable elastic composite
WO2009114275A1 (en) * 2008-03-12 2009-09-17 Dow Global Technologies Inc. Clarified polypropylene and ethylene alpha olefin blend
JP5714913B2 (ja) * 2008-03-13 2015-05-07 ダウ グローバル テクノロジーズ エルエルシー 他の１種のポリマーと組み合わせた、長鎖分岐（ｌｃｂ）、ブロック、または相互連結エチレンコポリマー
US8404773B2 (en) * 2008-03-17 2013-03-26 Dow Global Technologies Llc Coating composition, method of producing the same, articles made therefrom, and method of making such articles
US20090240220A1 (en) * 2008-03-20 2009-09-24 Kimberly-Clark Worldwide, Inc Compressed Substrates Configured to Deliver Active Agents
US8338508B2 (en) 2008-05-14 2012-12-25 Kimberly-Clark Worldwide, Inc. Water-sensitive film containing an olefinic elastomer
US8709191B2 (en) 2008-05-15 2014-04-29 Kimberly-Clark Worldwide, Inc. Latent elastic composite formed from a multi-layered film
US8563017B2 (en) 2008-05-15 2013-10-22 Kimberly-Clark Worldwide, Inc. Disinfectant wet wipe
US20090299312A1 (en) * 2008-05-30 2009-12-03 Kimberly-Clark Worldwide, Inc. Twisted, Compressed Substrates as Wetness Indicators in Absorbent Articles
US8349945B2 (en) * 2008-06-03 2013-01-08 Dow Global Technologies Llc Composite dispersion, method of producing the same, and articles made therefrom
MX2010013344A (es) * 2008-06-05 2011-01-21 Union Carbide Chem Plastic Metodo para producir funda de cable tipo trxlpe, resistente a arborizacion de agua.
JP2011523968A (ja) * 2008-06-06 2011-08-25 ダウ グローバル テクノロジーズ エルエルシー ポリプロピレンおよびオレフィンインターポリマーの反応処理された高耐熱性組成物
WO2009152772A1 (en) 2008-06-18 2009-12-23 Dow Global Technologies Inc. Polymeric compositions, methods of making the same, and articles prepared from the same
US8679992B2 (en) * 2008-06-30 2014-03-25 Kimberly-Clark Worldwide, Inc. Elastic composite formed from multiple laminate structures
EP2294102B1 (en) * 2008-06-30 2013-08-21 Dow Global Technologies LLC Polyolefin compositions and articles prepared therefrom and methods of making the same
US7968479B2 (en) * 2008-06-30 2011-06-28 Kimberly-Clark Worldwide, Inc. Elastic multilayer composite including pattern unbonded elastic materials, articles containing same, and methods of making same
US8603281B2 (en) 2008-06-30 2013-12-10 Kimberly-Clark Worldwide, Inc. Elastic composite containing a low strength and lightweight nonwoven facing
US8324445B2 (en) * 2008-06-30 2012-12-04 Kimberly-Clark Worldwide, Inc. Collection pouches in absorbent articles
CN102137757A (zh) * 2008-07-01 2011-07-27 陶氏环球技术有限责任公司 膜、从该膜制得的制品、及其制备方法
EP2141016A1 (en) 2008-07-01 2010-01-06 Dow Global Technologies Inc. Films, articles prepared therefrom and methods of making the same
EP2145763A1 (en) 2008-07-16 2010-01-20 Dow Global Technologies Inc. Films, articles prepared therefrom, and method of making the same
WO2010009017A1 (en) * 2008-07-15 2010-01-21 Dow Global Technologies Inc. Method of making a laminated glass/polyolefin film structure
WO2010009825A1 (en) * 2008-07-23 2010-01-28 Saudi Basic Industries Corporation Process for preparing modified polypropylene compositions
CA2732755C (en) * 2008-08-01 2016-10-11 Union Carbide Chemicals & Plastics Technology Llc Silicone-thermoplastic polymer reactive blends and copolymer products
BRPI0913170B1 (pt) * 2008-08-25 2019-05-21 Dow Global Technologies Llc Processo isento de água e peróxido para reticular um polímero contendo grupos carboxila, artigo e aditivo plástico
DE102008045802A1 (de) * 2008-09-05 2010-03-11 Henkel Ag & Co. Kgaa Schmelzklebstoff auf Basis von Metallocene-katalysierten Olefin-α-Olefin Copolymeren
WO2010033601A1 (en) * 2008-09-16 2010-03-25 Dow Global Technologies Inc. Polymeric compositions and foams, methods of making the same, and articles prepared from the same
RU2381236C1 (ru) * 2008-09-25 2010-02-10 Институт Катализа Им. Г.К. Борескова Сибирского Отделения Российской Академии Наук Катализатор и способ получения полиэтилена и сополимеров этилена с альфа-олефинами с узким молекулярно-массовым распределением
CN102239206A (zh) * 2008-10-03 2011-11-09 陶氏环球技术有限责任公司 用于耐磨泡沫体的组合物及其制备方法
ES2478286T3 (es) 2008-10-06 2014-07-21 Dow Global Technologies Llc Cromatografía de polímeros poliolefínicos
CN102256787A (zh) 2008-10-17 2011-11-23 陶氏环球技术有限责任公司 双轴取向膜
ES2628754T3 (es) * 2008-11-06 2017-08-03 Dow Global Technologies Llc Lámina trasera basada en poliolefina multicapa coextruida para módulos de dispositivos electrónicos
CN102292356B (zh) 2008-11-21 2013-09-04 陶氏环球技术有限责任公司 包含基于烯烃的聚合物的中电压缆线外皮
EP2365031B1 (en) 2008-12-10 2017-02-08 Asahi Kasei Kabushiki Kaisha Thermoplastic elastomer composition
JP5883649B2 (ja) * 2008-12-12 2016-03-15 ダウ グローバル テクノロジーズ エルエルシー コーティング組成物、コーティング組成物を製造する工程、コートされた物品、およびそのような物品を形成する方法
US8829083B2 (en) 2008-12-16 2014-09-09 Dow Global Technologies Llc Coating composition, a process of producing a coating composition, a coated article, and a method of making such articles
JP5548699B2 (ja) 2008-12-22 2014-07-16 ダウ グローバル テクノロジーズ エルエルシー 織りカーペット用塗料化合物、関連使用方法、及びそれらから造られる物品
CN102245384B (zh) 2008-12-23 2013-11-06 陶氏环球技术有限责任公司 将多组分反应性系统传递到模塑操作的方法
CA2747898A1 (en) * 2008-12-23 2010-07-01 Dow Global Technologies Llc Catalyst system for moisture cure of ethylene-vinylsilane copolymers
JP5632395B2 (ja) 2009-01-30 2014-11-26 ダウ グローバル テクノロジーズ エルエルシー ポリマー組成物、及び審美性の向上したｔｐｏ物品
CN102307915B (zh) * 2009-02-06 2015-05-13 陶氏环球技术有限责任公司 基于乙烯的聚合物和组合物、其制备方法、和由该聚合物和组合物制造的制品
WO2010096593A2 (en) 2009-02-18 2010-08-26 Northwestern University Beam pen lithography
CN102414258B (zh) 2009-03-16 2014-03-26 陶氏环球技术有限责任公司 分散体、和制备该分散体的方法
US8105463B2 (en) 2009-03-20 2012-01-31 Kimberly-Clark Worldwide, Inc. Creped tissue sheets treated with an additive composition according to a pattern
EP2995449A1 (en) 2009-03-20 2016-03-16 Dow Global Technologies LLC Multilayer structure and method of making the same
WO2010114648A1 (en) 2009-03-30 2010-10-07 Dow Global Technologies Inc. Hybrid dispersions and methods for producing the same
US8808595B2 (en) 2009-04-07 2014-08-19 Cryovac, Inc. Multilayer film for medical solution pouches having reduced proficiency for forming bubbles
US8378042B2 (en) 2009-04-28 2013-02-19 Exxonmobil Chemical Patents Inc. Finishing process for amorphous polymers
MX2011011855A (es) * 2009-05-08 2011-12-06 3M Innovative Properties Co Metodo y kit para el cuidado oral.
US20100297438A1 (en) 2009-05-21 2010-11-25 Ross Allen W Polymer film comprising roughening material
US8722817B2 (en) * 2009-06-05 2014-05-13 Dow Global Technologies Llc Process to make long chain branched (LCB), block, or interconnected copolymers of ethylene
US20100311927A1 (en) 2009-06-05 2010-12-09 Dow Global Technologies Inc. Process to make long chain branched (lcb), block, or interconnected copolymers of ethylene
JP5519409B2 (ja) * 2009-06-09 2014-06-11 日本ポリエチレン株式会社 太陽電池封止材用樹脂シート
US9243087B2 (en) * 2009-06-11 2016-01-26 Dow Global Technologies Llc LDPE enabling high output and good optics when blended with other polymers
US20100317463A1 (en) * 2009-06-12 2010-12-16 Sullivan Michael J Golf balls having layers made from functionalized ethylene copolymers
JP2012530801A (ja) 2009-06-18 2012-12-06 ダウ グローバル テクノロジーズ エルエルシー 色の安定なハロゲンフリー難燃性組成物
EP2275254A1 (en) 2009-07-17 2011-01-19 Dow Global Technologies Inc. Coated substrates and packages prepared therefrom
JP5734972B2 (ja) 2009-07-24 2015-06-17 ダウ グローバル テクノロジーズ エルエルシー 被覆容器デバイス、その製造方法
BR112012000906B1 (pt) 2009-07-24 2019-12-03 Dow Global Technologies Llc Dispositivo de recipiente revestido
WO2011019563A1 (en) 2009-08-10 2011-02-17 Dow Global Technologies Inc. Ldpe for use as a blend component in shrinkage film applications
CN102575050A (zh) 2009-08-10 2012-07-11 联合碳化化学及塑料技术有限责任公司 包含泡沸阻燃剂和非基于磷的阻燃协同剂的热塑性弹性体组合物
CN102695735B (zh) 2009-09-14 2014-11-05 陶氏环球技术有限责任公司 包含源于乙烯和硅氧烷的单元的聚合物
EP2478024B1 (en) 2009-09-14 2018-08-15 Dow Global Technologies LLC Polymers comprising units derived from ethylene and poly(alkoxide)
CN102695734B (zh) 2009-09-14 2015-05-06 陶氏环球技术有限责任公司 包含源于乙烯和聚链烯的单元的聚合物
CN102630237B (zh) 2009-09-16 2015-06-24 联合碳化化学及塑料技术有限责任公司 制备交联的熔融成型的制品的方法
US20120175809A1 (en) 2009-09-18 2012-07-12 Union Carbide Chemicals & Plastics Technology Llc Process for Making Crosslinked Injection Molded Articles
BR112012006025B1 (pt) 2009-09-18 2021-08-31 Dow Global Technologies Llc Processo para rotomoldagem de uma composição de poliolefina termoplástica
CA2774766C (en) 2009-09-22 2016-10-18 Mohamed Esseghir Flexible, molded or extruded articles and semiconductive compounds for their manufacture
US9546446B2 (en) 2009-10-23 2017-01-17 Toyo Boseki Kabushiki Kaisha Highly functional polyethylene fibers, woven or knit fabric, and cut-resistant glove
WO2011053904A1 (en) * 2009-10-30 2011-05-05 Dow Global Technologies Inc. Alkyd dispersion, and a process for producing the same
US20110118679A1 (en) 2009-11-17 2011-05-19 Cryovac, Inc. Radio frequency sealable film
US8858525B2 (en) 2009-11-20 2014-10-14 Cryovac, Inc. Noise dampening film
DE202009019088U1 (de) 2009-11-21 2016-06-01 Tarkett G.D.L. S.A. Fußboden- oder Wandbelag
MX343840B (es) 2009-11-23 2016-11-24 Dow Global Tech Llc * Composiciones, peliculas y metodos para prepararlas.
US8679639B2 (en) * 2009-11-24 2014-03-25 Dow Global Technologies Llc Extrusion coating composition
US8784996B2 (en) 2009-11-24 2014-07-22 Dow Global Technologies Llc Extrusion coating composition
WO2011066177A1 (en) 2009-11-30 2011-06-03 Dow Global Technologies Inc. Thermoformable sound-deadening filled thermoplastic polyolefin composition
CN102741033B (zh) 2009-12-04 2015-01-07 联合碳化化学及塑料技术有限责任公司 挤出机螺杆
EP2510048B1 (en) 2009-12-11 2014-07-09 Dow Global Technologies LLC Thermoplastic polymer blends comprising dynamically crosslinked polyurethane in an olefin polymer matrix
US8859671B2 (en) 2009-12-11 2014-10-14 Dow Global Technologies Llc Photodegradable films with good tensile and dart properties
DE112010004818T5 (de) * 2009-12-15 2012-10-04 Sumitomo Chemical Co., Ltd. Ethylen-α-Olefin-Copolymer
US8609231B2 (en) 2009-12-17 2013-12-17 Dow Global Technologies Llc Composite laminates and uses thereof
EP2513914B1 (en) 2009-12-18 2017-05-10 Dow Global Technologies LLC Halogen-free, flame retardant compositions for wire and cable applications
CN102762377B (zh) 2009-12-18 2015-03-25 陶氏环球技术有限责任公司 薄膜和由其制备的制品
BR112012015319B1 (pt) 2009-12-21 2021-09-28 Union Carbide Corporation Composição e revestimento isolante para cabo de média voltagem
US8318896B2 (en) 2009-12-21 2012-11-27 Dow Global Technologies Llc Chromatography of polyolefin polymers
EP2516543A1 (en) 2009-12-24 2012-10-31 Dow Global Technologies LLC Polymer compositions, methods of making the same, and articles prepared from the same
RU2012132433A (ru) 2009-12-30 2014-02-10 ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи Способ экструзии полимера
MX345781B (es) 2009-12-31 2017-02-15 Dow Global Tech Llc * Composiciones termoplasticas retardantes de flama, libres de halogeno, para aplicaciones de alambre y cable.
EP2348057A1 (en) 2010-01-21 2011-07-27 INEOS Manufacturing Belgium NV Novel polymers
EP2348058B1 (en) 2010-01-22 2014-01-01 Borealis AG Heterophasic polypropylene resin and composition
US20110182134A1 (en) 2010-01-22 2011-07-28 Dow Global Technologies Inc. Mixing system comprising an extensional flow mixer
WO2011102957A1 (en) 2010-02-16 2011-08-25 Dow Global Technologies Llc Adhesion reduction between a metal conductor and an insulation sheath
JP5606558B2 (ja) 2010-02-22 2014-10-15 ダウ グローバル テクノロジーズ エルエルシー 塗装ポリオレフィン物品
EP2618338A3 (en) 2010-03-12 2013-10-23 General Cable Technologies Corporation Insulation with micro oxide particles for cable components
US20110236443A1 (en) * 2010-03-26 2011-09-29 Hall Mark J Multilayer melt-extruded film
BR112012026163A2 (pt) 2010-04-14 2016-06-28 Dow Global Technologies Llc recipiente de combustível, processo para moldar a sopro uma composição de polietileno em um recipiente para combustível e método para preparar uma composição de polietileno
TWI523607B (zh) 2010-04-15 2016-03-01 陶氏農業科學公司 使用含有聚二氯乙烯（ｐｖｄｃ）蒸氣障壁之多層薄膜的農用薰蒸技術
CA2798021C (en) 2010-05-10 2019-09-17 Dow Global Technologies Llc Adhesion promoter system, and method of producing the same
EP2569374B1 (en) 2010-05-10 2017-08-23 Dow Global Technologies LLC Adhesion promoter system, and method of producing the same
WO2011144039A1 (en) 2010-05-21 2011-11-24 Dow Global Technologies Llc Thermoplastic compositions and formed articles thereof
BR112012030036A2 (pt) 2010-05-26 2016-12-13 Dow Global Technologies Llc módulo de dispositivo eletrônico compreendendo copolímero de poliolefina com baixa insaturação e vinil silano opcional
US20130041092A1 (en) 2010-05-27 2013-02-14 Dow Global Technologies Llc Polymer compositions, methods of making the same, and articles prepared from the same
US20130059967A1 (en) 2010-05-27 2013-03-07 Dow Global Technologies Llc Polymer compositions, methods of making the same, and articles prepared from the same
EP2576689B1 (en) 2010-06-03 2014-12-17 Dow Global Technologies LLC Strippable insulation shield for cables
BR112012030650A2 (pt) 2010-06-04 2016-08-16 Dow Global Technologies Llc módulo de dispositivo eletrônico compreendendo película de copolímero de poliolefina homogêneo e silano enxertado
BR112012030649A2 (pt) 2010-06-04 2016-08-16 Dow Global Technologies Llc módulo de dispositivo eletrônico compreendendo película de copolímero de poliolefina homogêneo e polímero de enxerto realçador de propriedade adesiva
MX2012014295A (es) 2010-06-08 2013-02-12 Union Carbide Chem Plastic Cinta termoplastica, reforzada con fibra, como un miembro de refuerzo para alambre y cable.
CA2801077C (en) 2010-06-08 2018-01-09 Dow Global Technologies Llc Partially impregnated, fiber reinforced thermoplastic strength member
WO2011155956A1 (en) 2010-06-08 2011-12-15 Dow Global Technologies Llc Polyolefin elastomer composition for artificial leather applications
CA2799389C (en) 2010-06-08 2017-01-24 Union Carbide Chemicals & Plastics Technology Llc Halogenated flame retardant systems for use in presence of silane grafting process
US9587084B2 (en) 2010-06-08 2017-03-07 Union Carbide Chemicals & Plastics Technology Llc Halogenated flame retardant systems for use in presence of silane grafting process
KR101535326B1 (ko) 2010-06-09 2015-07-08 아사히 가세이 케미칼즈 가부시키가이샤 열가소성 엘라스토머 조성물 및 그 성형품
US8835550B2 (en) 2010-06-15 2014-09-16 Dow Global Technologies Llc Chlorinated polyethylene composition, method of producing the same, and articles made therefrom
EP2582758B1 (en) 2010-06-16 2015-04-08 Union Carbide Chemicals & Plastics Technology LLC Polyurethane/polyolefin blends with improved strain and scratch whitening performance
WO2011159446A1 (en) 2010-06-18 2011-12-22 Union Carbide Chemicals & Plastics Technology Llc Electrically conductive, olefin multiblock copolymer compositions
SG186739A1 (en) 2010-06-18 2013-02-28 Dow Global Technologies Llc Coated polymeric particulates, and a process for coating polymeric particulates
EP2582736B1 (en) 2010-06-18 2015-09-23 Dow Global Technologies LLC Electrically conductive, mesophase-separated olefin multiblock copolymer compositions
US9120887B2 (en) 2010-06-22 2015-09-01 Dow Global Technologies Llc Crosslinked compositions and articles prepared therefrom
JP2013539596A (ja) 2010-06-24 2013-10-24 ダウ グローバル テクノロジーズ エルエルシー エチレンの長鎖分岐した（ｌｃｂ）、ブロック、または相互接続されたコポリマー、および場合によってはシランを含む電子素子モジュール
JP5530828B2 (ja) * 2010-06-25 2014-06-25 日本ポリエチレン株式会社 太陽電池封止材用樹脂組成物の製造方法
US9421743B2 (en) 2010-06-28 2016-08-23 Dow Global Technologies Llc Single polymer film structures for use in stand-up-pouches
IT1400743B1 (it) 2010-06-30 2013-07-02 Dow Global Technologies Inc Composizioni polimeriche
JP2013530898A (ja) 2010-07-01 2013-08-01 ルブリゾル アドバンスド マテリアルズ， インコーポレイテッド ポリ（フェニレンエーテル）組成物の熱成型されたｉｃトレー
WO2012004422A1 (es) 2010-07-06 2012-01-12 Dow Global Technologies Llc Mezclas de polímeros de etileno y artículos orientados con resistencia mejorada a la contracción
KR101248421B1 (ko) 2010-07-15 2013-03-28 에스케이이노베이션 주식회사 탄성 및 가공성이 우수한 에틸렌 공중합체
TR201806954T4 (tr) 2010-07-27 2018-06-21 Dow Global Technologies Llc Düşük yoğunluklu ağ ve bir katkı bileşimini buna uygulama yöntemi.
US8936740B2 (en) 2010-08-13 2015-01-20 Kimberly-Clark Worldwide, Inc. Modified polylactic acid fibers
US10753023B2 (en) 2010-08-13 2020-08-25 Kimberly-Clark Worldwide, Inc. Toughened polylactic acid fibers
WO2012037180A1 (en) 2010-09-16 2012-03-22 Dow Global Technologies Llc Coextruded multilayer film structure
EP2619266B2 (en) 2010-09-22 2022-01-26 Dow Global Technologies LLC Improved sound-deadening filled thermoplastic polyolefin composition
KR101948333B1 (ko) 2010-09-30 2019-02-14 다우 글로벌 테크놀로지스 엘엘씨 개선된 층 접착력을 갖는 가요성 다층 전기 물품의 제조 방법
WO2012050792A1 (en) 2010-09-30 2012-04-19 Union Carbide Chemicals & Plastics Technology Llc Coated conductor with voltage stabilized inner layer
JP5793571B2 (ja) 2010-09-30 2015-10-14 ユニオン カーバイド ケミカルズ アンド プラスティックス テクノロジー エルエルシー 電圧安定剤添加物を伴うポリマー組成物
JP5968321B2 (ja) 2010-09-30 2016-08-10 ダウ グローバル テクノロジーズ エルエルシー ポリマー組成物およびそれを用いたシーラント層
CN103228723B (zh) 2010-09-30 2016-01-13 陶氏环球技术有限责任公司 聚合物组合物和具有所述组合物的密封剂层
AR083516A1 (es) 2010-10-20 2013-03-06 Starlinger & Co Gmbh Una tela recubierta, una bolsa producida a partir de ella, una maquina de envasado para bolsas y un metodo para llenar las bolsas
MY170295A (en) 2010-11-02 2019-07-17 Mitsui Chemicals Inc Encapsulating material for solar cell and solar cell module
US8829090B2 (en) 2010-11-24 2014-09-09 Dow Global Technologies Llc Composition comprising propylene-alpha-olefin copolymer, olefin block copolymer and DPO-BSA molecular melt
EP2813545A1 (en) 2010-12-03 2014-12-17 Dow Global Technologies LLC Processes to prepare ethylene-based polymer compositions
US8889945B2 (en) 2010-12-08 2014-11-18 Kimberly-Clark Worldwide, Inc. Elastic film containing a renewable starch polymer
US20130252005A1 (en) 2010-12-10 2013-09-26 Dow Global Technologies Llc Films with improved coefficient of friction
KR20130138293A (ko) 2010-12-16 2013-12-18 다우 글로벌 테크놀로지스 엘엘씨 실란 함유 열가소성 폴리올레핀 코폴리머 수지, 필름, 그의 제조방법 및 이 수지와 필름을 포함하는 광기전 모듈 라미네이트 구조물
JP2013545858A (ja) 2010-12-17 2013-12-26 ダウ グローバル テクノロジーズ エルエルシー ワイヤおよびケーブル用途向けハロゲンフリー難燃剤組成物
SG191203A1 (en) 2010-12-21 2013-07-31 Dow Global Technologies Llc Olefin-based polymers and dispersion polymerizations
US20140202533A1 (en) 2010-12-21 2014-07-24 Dow Global Technologies Llc Thermoplastic polyolefin copolymer lamination film, laminated structures and processes for their preparation
US9580869B2 (en) 2010-12-30 2017-02-28 Kimberly-Clark Worldwide, Inc. Process for applying high viscosity composition to a sheet with high bulk
BR112013016788B1 (pt) 2010-12-30 2021-02-02 Dow Global Technologies Llc composição granulada e composição reticulada
US8895126B2 (en) 2010-12-31 2014-11-25 Kimberly-Clark Worldwide, Inc. Segmented films with high strength seams
AU2012234463B2 (en) 2011-03-29 2015-12-24 Cryovac, Llc Multilayer heat-shrinkable asymmetrical film
CN103477446A (zh) 2011-03-31 2013-12-25 陶氏环球技术有限公司 包含下转换材料的透光热塑性树脂及其在光伏模块中的用途
EP2694606B2 (en) 2011-04-08 2019-06-05 Dow Global Technologies LLC Process for producing a coating compositon
US9493641B2 (en) 2011-06-10 2016-11-15 Dow Global Technologies Llc Resin compositions for extrusion coating
CA2839031C (en) 2011-06-21 2017-02-14 Dow Global Technologies Llc Halogen-free flame-retardant polymer composition comprising piperazine based intumescent flame retardant
US20120328850A1 (en) 2011-06-27 2012-12-27 Ali Yahiaoui Sheet Materials Having Improved Softness
JP6059721B2 (ja) 2011-06-30 2017-01-11 ダウ グローバル テクノロジーズ エルエルシー 結晶性ブロックコポリマー複合体又はブロックコポリマー複合体を含む層を含む、一体化バックシート及び封入性能を有する多層化ポリオレフィン系フィルム
CN103108909B (zh) 2011-06-30 2015-03-25 陶氏环球技术有限责任公司 绘图清晰的粘合膜
WO2013003541A1 (en) 2011-06-30 2013-01-03 Dow Global Technologies Llc Multilayered polyolefin-based films having a layer comprising a crystalline block copolymer composite or a block copolymer composite resin
US8426521B2 (en) 2011-07-20 2013-04-23 The Procter & Gamble Company Polymer composition
CN103717664A (zh) 2011-07-28 2014-04-09 陶氏环球技术有限责任公司 适合合成皮革应用的聚合物共混物配制物
US8815363B2 (en) 2011-08-30 2014-08-26 E I Du Pont De Nemours And Company Multilayer protective liner
CN103781839B (zh) 2011-09-07 2018-06-01 陶氏环球技术有限责任公司 聚合物组合物以及由其制备的制品
KR101955743B1 (ko) 2011-09-12 2019-03-07 다우 글로벌 테크놀로지스 엘엘씨 조성물 및 그로부터 형성된 제품
KR20180122742A (ko) 2011-09-23 2018-11-13 다우 글로벌 테크놀로지스 엘엘씨 올레핀-계 중합체 조성물 및 그로부터 제조된 제품
CN103842438B (zh) 2011-09-30 2016-01-20 陶氏环球技术有限责任公司 聚碳酸酯和聚丙烯的热塑性阻燃组合物
JP6170052B2 (ja) 2011-10-10 2017-07-26 ダウ グローバル テクノロジーズ エルエルシー 機械的及び熱的応力下の特性の維持が改良されたポリマー組成物
CN103890082A (zh) 2011-10-20 2014-06-25 陶氏环球技术有限责任公司 基于乙烯的聚合物组合物和由其制备的制品
AU2012328677A1 (en) 2011-10-26 2014-04-17 Performance Materials Na, Inc. Multilayer film structure comprising renewably sourced materials
US8841379B2 (en) 2011-11-07 2014-09-23 E I Du Pont De Nemours And Company Method to form an aqueous dispersion of an ionomer-polyolefin blend
US20130115401A1 (en) 2011-11-08 2013-05-09 E I Du Pont De Nemouras And Company Hydrolytic resistant polyamide compositions comprising polyhydroxy polymers
US8399077B1 (en) 2011-11-21 2013-03-19 Cryovac, Inc. Polyglycolic acid-based film
BR112014014853A8 (pt) 2011-12-19 2017-06-13 Dow Global Technologies Llc composição e artigo
US9718258B2 (en) 2011-12-20 2017-08-01 Kimberly-Clark Worldwide, Inc. Multi-layered film containing a biopolymer
US9327438B2 (en) 2011-12-20 2016-05-03 Kimberly-Clark Worldwide, Inc. Method for forming a thermoplastic composition that contains a plasticized starch polymer
BR112014015382B1 (pt) 2011-12-21 2020-12-01 Dow Global Technologies Llc formulação de poliolefina dieletricamente soldável, melhoramento em um método para formar um artigo baseado em poliolefina e artigo de poliolefina soldado por alta frequência
US9617399B2 (en) 2011-12-21 2017-04-11 Dow Global Technologies Llc High frequency weldable polyolefin compositions containing zeolites
EP2809731B1 (en) 2012-01-31 2016-01-20 Dow Global Technologies LLC Thermoplastic, semiconductive compositions
JP6230127B2 (ja) 2012-01-31 2017-11-15 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーＥ．Ｉ．Ｄｕ Ｐｏｎｔ Ｄｅ Ｎｅｍｏｕｒｓ Ａｎｄ Ｃｏｍｐａｎｙ 環状オレフィンコポリマーを含む多層フィルム
US9362436B2 (en) 2012-02-03 2016-06-07 Dow Global Technologies Llc Silane-containing ethylene interpolymer formulation including films and electronic device module comprising same
US8975305B2 (en) 2012-02-10 2015-03-10 Kimberly-Clark Worldwide, Inc. Rigid renewable polyester compositions having a high impact strength and tensile elongation
US8637130B2 (en) 2012-02-10 2014-01-28 Kimberly-Clark Worldwide, Inc. Molded parts containing a polylactic acid composition
US8980964B2 (en) 2012-02-10 2015-03-17 Kimberly-Clark Worldwide, Inc. Renewable polyester film having a low modulus and high tensile elongation
US9040598B2 (en) 2012-02-10 2015-05-26 Kimberly-Clark Worldwide, Inc. Renewable polyester compositions having a low density
US20130210621A1 (en) 2012-02-10 2013-08-15 Kimberly-Clark Worldwide, Inc. Breathable Film Formed from a Renewable Polyester
US10858762B2 (en) 2012-02-10 2020-12-08 Kimberly-Clark Worldwide, Inc. Renewable polyester fibers having a low density
EP2631268A1 (en) * 2012-02-22 2013-08-28 Borealis AG Extrusion coating polyethylene with improved drawdown
BR112014019935B1 (pt) 2012-03-07 2021-03-09 Dow Global Technologies Llc estrutura em multicamada
WO2013137953A1 (en) 2012-03-15 2013-09-19 Exxonmobil Chemical Patents Inc. Oxygen tailoring of polyethylene
ES2593842T3 (es) 2012-03-28 2016-12-13 Tarkett Gdl Revestimiento de superficie multicapa
AU2012375631B2 (en) 2012-03-28 2018-02-15 Tarkett Gdl Multilayer surface covering
KR102223511B1 (ko) 2012-03-30 2021-03-05 다우 글로벌 테크놀로지스 엘엘씨 폴리올레핀 접착제 조성물
US9309337B2 (en) 2012-04-02 2016-04-12 Exxonmobil Research And Engineering Company Branched saturated hydrocarbon polymers as extensional rheology modifiers without impacting shear properties
CN104395395B (zh) 2012-04-12 2016-10-12 陶氏环球技术有限责任公司 聚烯烃共混组合物以及由其制备的制品
US10583628B2 (en) 2012-04-27 2020-03-10 Dow Brasil Indústria E Comércio De Produtos Químicos Ltda Stiff polyethylene film with enhanced optical properties
EP2669086A1 (en) 2012-05-28 2013-12-04 Dow Global Technologies LLC Cast silage film with enhanced cling properties
CN107556597B (zh) 2012-06-05 2021-03-30 陶氏环球技术有限责任公司 包含官能化的基于乙烯的聚合物组合物的膜
JP6298812B2 (ja) 2012-06-19 2018-03-20 ダウ グローバル テクノロジーズ エルエルシー 水性ブレンド組成物およびその製造方法
WO2013191826A1 (en) 2012-06-19 2013-12-27 Dow Global Technologies Llc Aqueous based blend composition and method of producing the same
EP3424995A3 (en) 2012-06-28 2019-03-20 Dow Global Technologies Llc A composite material method of producing the same, and articles made therefrom
UA111661C2 (uk) 2012-07-04 2016-05-25 Таркетт Ґдл Поверхневе покриття
US9676532B2 (en) 2012-08-15 2017-06-13 Avery Dennison Corporation Packaging reclosure label for high alcohol content products
JP6242894B2 (ja) 2012-08-28 2017-12-06 ダウ ブラジル インダストリア エ コメルシオ デ プロダトス クイミコス エルティーディーエイ 官能性エチレン系ポリマー組成物含有皮膜
EP2890739B1 (en) 2012-08-29 2016-09-28 Dow Global Technologies LLC Ethylene-based polymer compositions and foams
WO2014036473A1 (en) 2012-08-31 2014-03-06 Kenji Suzuki Supervised machine learning technique for reduction of radiation dose in computed tomography imaging
US11292234B2 (en) 2012-09-13 2022-04-05 Dow Global Technologies Llc Polyolefin based films suitable for thermoforming
WO2014043013A1 (en) 2012-09-14 2014-03-20 Dow Global Technologies Llc Filled thermoplastic polyolefin composition for use in vehicle sound-deadening applications
JP5894710B2 (ja) 2012-09-27 2016-03-30 ダウ グローバル テクノロジーズ エルエルシー 架橋性エチレン系ポリマー組成物中の過酸化物のマイグレーションを低減するための方法
JP6170169B2 (ja) 2012-11-05 2017-07-26 ダウ グローバル テクノロジーズ エルエルシー 官能化ポリマー組成物およびそれから形成されるフィルム
US9040151B2 (en) 2012-11-06 2015-05-26 Dow Global Technologies Llc Ultra-stiff coextruded shrink films
US8859094B2 (en) 2012-11-09 2014-10-14 The Procter & Gamble Company Combination of elastomeric film composition and adhesive for a stretch laminate
US20140134910A1 (en) 2012-11-09 2014-05-15 The Procter & Gamble Company Combination of Elastomeric Film Composition and Adhesive for a Stretch Laminate
EP2928958B1 (en) 2012-12-05 2019-08-21 ExxonMobil Chemical Patents Inc. Hdpe modified polyethylene blown film compositions having excellent bubble stability
ES2725828T3 (es) 2012-12-17 2019-09-27 Dow Global Technologies Llc Una estructura multicapa y un método para sellar o dar forma usando una estructura multicapa
US20160184210A1 (en) 2012-12-19 2016-06-30 Dow Global Technologies Llc Silicone-containing polyolefins in personal care applications
US9422444B2 (en) 2012-12-28 2016-08-23 Dow Global Technologies Llc Coating compositions
EP2925823B1 (en) 2012-12-28 2021-01-20 Dow Global Technologies LLC A coating composition and articles made therefrom
JP6385364B2 (ja) 2012-12-28 2018-09-05 ダウ グローバル テクノロジーズ エルエルシー 官能性エチレン系ポリマー組成物を含有する多層フィルム
MX2015008564A (es) 2012-12-31 2015-09-07 Dow Global Technologies Llc Una composicion, articulos hechos de la misma, y forma de hacer los articulos.
KR102038178B1 (ko) 2013-01-18 2019-10-29 다우 글로벌 테크놀로지스 엘엘씨 고분자량 폴리올레핀을 위한 중합 방법
US10336046B2 (en) 2013-02-21 2019-07-02 3M Innovative Properties Company Self-adhering tape comprising multilayers of polyolefin polymer materials and method
US9034477B2 (en) 2013-03-05 2015-05-19 Dow Global Technologies Llc Coating composition, a film containing the same, and a method for forming a sealable film
EP2973614B1 (en) 2013-03-12 2017-11-01 Dow Global Technologies LLC Power cable with a thick insulation layer and a method for its manufacture
BR112015021505A2 (pt) 2013-04-18 2017-07-18 Dow Global Technologies Llc condutor revestido
CN105142873B (zh) 2013-05-07 2020-06-23 陶氏环球技术有限责任公司 制造多层电制品的方法
EP2999818A4 (en) 2013-05-22 2017-01-11 Dow Global Technologies LLC Paper composition and process for making the same
US20160120247A1 (en) 2013-06-12 2016-05-05 Kimberly-Clark Worldwide, Inc. Garment Containing a Porous Polymer Material
WO2014199276A1 (en) 2013-06-12 2014-12-18 Kimberly-Clark Worldwide, Inc. Polymeric material for use in thermal insulation
CN105247119B (zh) 2013-06-12 2018-07-06 金伯利-克拉克环球有限公司 多孔聚烯烃纤维
US11084916B2 (en) 2013-06-12 2021-08-10 Kimberly-Clark Worldwide, Inc. Polymeric material with a multimodal pore size distribution
KR102202850B1 (ko) 2013-06-12 2021-01-14 킴벌리-클라크 월드와이드, 인크. 건물 단열재
US11965083B2 (en) 2013-06-12 2024-04-23 Kimberly-Clark Worldwide, Inc. Polyolefin material having a low density
MX374156B (es) 2013-06-12 2025-03-05 Kimberly Clark Co Tecnica de iniciacion de poros.
MX385551B (es) 2013-06-12 2025-03-18 Kimberly Clark Co Artículo absorbente que contiene una película porosa de poliolefina.
US10040888B1 (en) 2013-06-14 2018-08-07 Cooper-Standard Automotive Inc. Composition including silane-grafted polyolefin
CN105307615B (zh) 2013-06-20 2019-04-19 宝洁公司 具有活化友好层合体的吸收制品
KR102034340B1 (ko) 2013-06-24 2019-10-18 다우 글로벌 테크놀로지스 엘엘씨 강화 폴리프로필렌 조성물
US9475928B2 (en) 2013-06-24 2016-10-25 Dow Global Technologies Llc Reinforced polypropylene composition
USD708126S1 (en) 2013-06-28 2014-07-01 Dow Global Technologies Llc Mounting base for photovoltaic module assembly
USD733645S1 (en) 2013-06-28 2015-07-07 Dow Global Technologies Llc Corner connector for a photovoltaic module frame
USD710792S1 (en) 2013-06-28 2014-08-12 Dow Global Technologies Llc Angle corner connector for photovoltaic module frame
USD747262S1 (en) 2013-06-28 2016-01-12 Dow Global Technologies Llc Photovoltaic back panel
USD710298S1 (en) 2013-06-28 2014-08-05 Dow Global Technologies Llc Photovoltaic module assembly
KR102072507B1 (ko) 2013-06-28 2020-02-03 다우 글로벌 테크놀로지스 엘엘씨 플라스틱 광기전력 모듈 프레임 및 랙, 그리고 그 제조를 위한 조성물
USD710793S1 (en) 2013-06-28 2014-08-12 Dow Global Technologies Llc Anchor block for photovoltaic module
US9598569B2 (en) 2013-07-01 2017-03-21 Rohm And Haas Company Composite polymer composition
WO2015002747A1 (en) * 2013-07-02 2015-01-08 Exxonmobile Chemical Patents Inc. Carpet backing compositions and carpet backing comprising the same
WO2015002859A2 (en) 2013-07-02 2015-01-08 Dow Global Technologies Llc Polyolefin/ (meth)acrylic impact modifier and method of preparing same
AU2014287269B2 (en) 2013-07-09 2018-01-18 Dow Global Technologies Llc Ethylene/alpha-olefin interpolymers with improved pellet flowability
US10450484B2 (en) 2013-07-24 2019-10-22 Dow Global Technologies Llc Adhesive compositions containing functionalized ethylene/alpha-olefin interpolymers and rosin-based tackifiers
US10100139B2 (en) 2013-08-01 2018-10-16 Cooper-Standard Automotive Inc. Hose, composition including silane-grafted polyolefin, and process of making a hose
AU2014304189B2 (en) 2013-08-09 2019-03-21 Kimberly-Clark Worldwide, Inc. Delivery system for active agents
AU2014304181B2 (en) 2013-08-09 2017-08-17 Kimberly-Clark Worldwide, Inc. Flexible polymeric material with shape retention properties
RU2630135C2 (ru) 2013-08-09 2017-09-05 Кимберли-Кларк Ворлдвайд, Инк. Микрочастицы, характеризующиеся многомодальным распределением пор
SG11201601706RA (en) 2013-08-09 2016-04-28 Kimberly Clark Co Technique for selectively controlling the porosity of a polymeric material
CN105492513B (zh) 2013-08-09 2019-03-08 金伯利-克拉克环球有限公司 各向异性的聚合物材料
KR102208200B1 (ko) 2013-08-09 2021-01-27 킴벌리-클라크 월드와이드, 인크. 3차원 인쇄용 중합체 물질
CA2922839C (en) 2013-09-13 2021-10-26 Dow Global Technologies Llc Peroxide-crosslinkable compositions and processes for their manufacture
US9783675B2 (en) 2013-10-01 2017-10-10 Asahi Kasei Kabushiki Kaisha Resin composition and molded article thereof
WO2015050749A1 (en) 2013-10-04 2015-04-09 3M Innovative Properties Company Multi-component fibers, nonwoven webs, and articles comprising a polydiorganosiloxane polyamide
KR102519282B1 (ko) 2013-10-15 2023-04-10 다우 글로벌 테크놀로지스 엘엘씨 혼화성 폴리올레핀 블렌드
MY179551A (en) 2013-10-25 2020-11-10 Dow Global Technologies Llc Polyolefin based films with improved water vapor transmission rates
WO2015061516A1 (en) 2013-10-25 2015-04-30 Dow Global Technologies Llc Stiff polyethylene film with enhanced optical properties
AU2014341952B2 (en) 2013-11-01 2018-08-09 Cryovac, Llc Delamination-resistant heat-shrinkable multilayer oxygen barrier film containing polyester
BR112016009343B1 (pt) 2013-11-08 2022-01-04 Dow Global Technologies Llc Composição de tinta sem iniciador, artigo e método
US10066102B2 (en) 2013-11-22 2018-09-04 Trinseo Europe Gmbh Polycarbonate containing compositions
RU2662547C1 (ru) 2013-11-22 2018-07-26 ТРИНСЕО ЮРОП ГмбХ Композиции, содержащие поликарбонат
EP3071644B1 (en) 2013-11-22 2018-07-18 Dow Global Technologies LLC Improved polyolefin composition for vehicle noise vibration and harshness applications
US10695235B2 (en) 2013-11-27 2020-06-30 Kimberly-Clark Worldwide, Inc. Printed 3D-elastic laminates
US10463222B2 (en) 2013-11-27 2019-11-05 Kimberly-Clark Worldwide, Inc. Nonwoven tack cloth for wipe applications
US9913764B2 (en) 2013-12-18 2018-03-13 Kimberly-Clark Worldwide, Inc. Post-bonded grooved elastic materials
KR20160102227A (ko) 2013-12-20 2016-08-29 이 아이 듀폰 디 네모아 앤드 캄파니 푸란계 중합체성 탄화수소 연료 배리어 구조체
US20160312088A1 (en) 2013-12-26 2016-10-27 Dow Global Technologies Llc Adhesive compositions containing modified ethylene-based polymers and compatible tackifiers
BR112016014349B1 (pt) 2013-12-30 2021-02-17 Dow Global Technologies Llc processo para formar um "polímero à base de etileno funcionalizado"
USD746439S1 (en) 2013-12-30 2015-12-29 Kimberly-Clark Worldwide, Inc. Combination valve and buckle set for disposable respirators
KR102311420B1 (ko) 2013-12-31 2021-10-13 다우 글로벌 테크놀로지스 엘엘씨 다층화된 필름, 이들의 제조 방법 및 이를 포함하는 물품
US9499723B2 (en) 2014-01-27 2016-11-22 Equistar Chemicals, Lp Polyolefin-based compositions, adhesives, and related multi-layered structures prepared therefrom
US9365951B2 (en) 2014-01-30 2016-06-14 Kimberly-Clark Worldwide, Inc. Negative polarity on the nanofiber line
ES2656390T3 (es) 2014-02-12 2018-02-27 Omnigen Research, Llc Composición y método para promover la reducción de estrés por calor en animales
WO2015123827A1 (en) 2014-02-19 2015-08-27 Dow Global Technologies Llc High performance sealable co-extruded oriented film, methods of manufacture thereof and articles comprising the same
WO2015123829A1 (en) 2014-02-19 2015-08-27 Dow Global Technologies Llc Multilayer film, methods of manufacture thereof and articles comprising the same
US20150231861A1 (en) 2014-02-19 2015-08-20 Dow Global Technologies Llc Multilayered polyolefin films, methods of manufacture thereof and articles comprising the same
US20150231862A1 (en) 2014-02-19 2015-08-20 Dow Global Technologies Llc Multilayered polyolefin films, methods of manufacture thereof and articles comprising the same
US10184045B2 (en) 2014-02-24 2019-01-22 Dow Global Technologies Llc Thermoplastic polyolefin with reduced gloss for non-carpeted flooring
US9574083B2 (en) 2014-02-27 2017-02-21 Sabic Global Technologies B.V. Synergistic effect of multiple mold release additives in polycarbonate based compositions
EP2921519A1 (en) 2014-03-17 2015-09-23 Dow Global Technologies LLC A multilayer structure
WO2015142547A1 (en) 2014-03-21 2015-09-24 Exxonmobil Chemical Patents Inc. Process to produce ethylene propylene copolymers
ES2866158T3 (es) 2014-04-09 2021-10-19 Dow Global Technologies Llc Películas de polietileno orientado y un método para fabricar las mismas
US10465053B2 (en) 2014-05-15 2019-11-05 Dow Global Technologies Llc Barrier film, methods of manufacture thereof and articles comprising the same
CN106536193A (zh) 2014-05-20 2017-03-22 纳幕尔杜邦公司 整理收缩膜保护结构
BR112016028445B1 (pt) 2014-06-02 2022-05-31 Avery Dennison Corporation Filme orientado com resistência à abrasão, clareza e conformabilidade, conjunto de rótulo compreendendo o filme e método para produzir um artigo rotulado
US11186927B2 (en) 2014-06-06 2021-11-30 Kimberly Clark Worldwide, Inc. Hollow porous fibers
AU2015269616B2 (en) 2014-06-06 2019-06-20 Kimberly-Clark Worldwide, Inc. Thermoformed article formed from a porous polymeric sheet
KR20170019385A (ko) 2014-06-12 2017-02-21 다우 글로벌 테크놀로지스 엘엘씨 분말 코팅
TWI674971B (zh) 2014-06-12 2019-10-21 美商陶氏全球科技有限責任公司 多層膜及由其製造的物件（二）
RU2696435C1 (ru) 2014-06-18 2019-08-01 Дау Глоубл Текнолоджиз Ллк Пленки на основе полиолефинов с улучшенными свойствами сохранения скручивания
ES2743478T3 (es) 2014-06-24 2020-02-19 Dow Global Technologies Llc Lámina posterior fotovoltaica de poliolefina que comprende una capa de polipropileno estabilizado
KR20170023951A (ko) 2014-06-24 2017-03-06 다우 글로벌 테크놀로지스 엘엘씨 유기점토를 포함하는 광전 모듈
AU2015280528B2 (en) 2014-06-27 2019-05-02 Dow Global Technologies Llc. A method for optimizing a hegman rating of a diluted emulsion, a diluted emulsion produced thereby, and a coating made therefrom
CN106457784B (zh) 2014-06-27 2019-11-26 陶氏环球技术有限责任公司 用于电气装置的冷缩制品
US10371292B2 (en) 2014-07-02 2019-08-06 Cooper-Standard Automotive Inc. Hose, abrasion resistant composition, and process of making a hose
US9528040B2 (en) 2014-07-03 2016-12-27 ViChem Speciality Products LLC Additives for boosting performance of water-based drilling fluids, drilling fluids including same, and methods of making and using same
BR112017000855B1 (pt) 2014-07-24 2022-02-08 Dow Global Technologies Llc Processo para formar um polímero à base de etileno
US10357940B2 (en) 2014-08-07 2019-07-23 Dow Global Technologies Llc Multilayer metallized cast film and packaging made therefrom
US20160039181A1 (en) 2014-08-07 2016-02-11 Dow Global Technologies Llc Multilayer Metallized Cast Film and Packaging Made Therefrom
WO2016025168A1 (en) 2014-08-12 2016-02-18 Dow Global Technologies Llc Polyethylene-based composite films, and articles made therefrom
US10421258B2 (en) 2014-08-13 2019-09-24 Performance Materials Na, Inc. Multilayer structure comprising polypropylene
WO2016026121A1 (en) 2014-08-21 2016-02-25 Dow Global Technologies Llc Adhesive compositions comprising low molecular weight functionalized olefin-based polymers
JP2017534485A (ja) 2014-09-26 2017-11-24 ダウ グローバル テクノロジーズ エルエルシー 多層構造体
EP3201265B9 (en) 2014-10-02 2022-05-04 Dow Global Technologies LLC High frequency weldable ethylene-based polymer compositions with good flame retardancy
CN106794683A (zh) 2014-10-03 2017-05-31 纳幕尔杜邦公司 多层食品肠衣或食品膜
EP3209722B1 (en) 2014-10-21 2025-07-16 Nova Chemicals (International) S.A. Ethylene interpolymer product with dilution index
CA2868640C (en) 2014-10-21 2021-10-26 Nova Chemicals Corporation Solution polymerization process
WO2016069075A1 (en) 2014-10-31 2016-05-06 Dow Global Technologies Llc Blow molded multilayer containers having reduced product retention
AU2015353887B2 (en) 2014-11-26 2019-07-04 Kimberly-Clark Worldwide, Inc. Annealed porous polyolefin material
CN107107431B (zh) 2014-11-26 2020-03-06 金伯利-克拉克环球有限公司 双轴拉伸的多孔膜
BR112017011665A2 (pt) 2014-12-01 2018-01-16 Dow Global Technologies Llc composições de polímero, filmes retráteis e métodos de preparar os mesmos
CN107107553A (zh) 2014-12-01 2017-08-29 陶氏环球技术有限责任公司 收缩膜和其制得方法
JP6763857B2 (ja) 2014-12-04 2020-09-30 ダウ グローバル テクノロジーズ エルエルシー エチレン系ポリマーの調製物のための五配位ビス−フェニルフェノキシ触媒
WO2016094281A1 (en) 2014-12-11 2016-06-16 E. I. Du Pont De Nemours And Company Stretch wrapping film
SG10201508406WA (en) 2014-12-23 2016-07-28 Dow Global Technologies Llc Polyolefin dispersion compositions for making high vapor transport hydrophobic coatings
BR112017013933A2 (pt) 2014-12-30 2018-01-09 Dow Global Technologies Llc derivado de sulfonilazida para camada de amarração
EP3040199B1 (en) 2014-12-31 2017-10-04 Dow Global Technologies LLC Self-recyclable barrier packaging
EP3048649A1 (en) 2015-01-23 2016-07-27 Yparex B.V. Electronic device module
WO2016123209A1 (en) 2015-01-28 2016-08-04 E. I. Du Pont De Nemours And Company Multilayer film structures comprising renewable polyester compositions
KR101832683B1 (ko) 2015-01-30 2018-02-26 킴벌리-클라크 월드와이드, 인크. 흡수 용품에 사용하기 위한 소음이 감소된 필름
MX383054B (es) 2015-01-30 2025-03-13 Kimberly Clark Co Empaque de articulo absorbente con ruido reducido.
WO2016132337A1 (en) 2015-02-20 2016-08-25 Sabic Global Technologies B.V. Reinforced polycarbonate composition with improved impact performance
WO2016140253A1 (ja) * 2015-03-03 2016-09-09 古河電気工業株式会社 シラン架橋性ゴム組成物及びシラン架橋ゴム成形体とそれらの製造方法、並びに、シラン架橋ゴム成形品
WO2016140252A1 (ja) * 2015-03-03 2016-09-09 古河電気工業株式会社 シラン架橋性ゴム組成物及びシラン架橋ゴム成形体とそれらの製造方法、並びに、シラン架橋ゴム成形品
SG10201600773QA (en) 2015-03-25 2016-10-28 Dow Global Technologies Llc Water borne polyolefin dispersion coatings, and methods of making
ES2864959T3 (es) 2015-05-13 2021-10-14 Dow Global Technologies Llc Composiciones de resina para revestimientos por extrusión
MX395343B (es) 2015-05-29 2025-03-25 Dow Global Technologies Llc Peliculas recubiertas y envases formados de las mismas.
CN107614490B (zh) 2015-06-16 2021-03-09 陶氏环球技术有限责任公司 杂合焦烧阻滞剂/固化助剂
EP3310852B1 (en) 2015-06-17 2020-10-28 Dow Global Technologies LLC Cable insulation compositions comprising a phosphorus-containing antioxidant
JP6885882B2 (ja) 2015-06-17 2021-06-16 ダウ グローバル テクノロジーズ エルエルシー 硫黄含有第２酸化防止剤を含むケーブル絶縁材組成物
US10647789B2 (en) 2015-06-22 2020-05-12 Dow Global Technologies Llc Process for making ethylene-based polymers using carbon-carbon free radical initiators
EP3112149A1 (en) 2015-06-30 2017-01-04 Dow Global Technologies LLC Multilayer films incorporating starch and articles comprising the same
EP3112150A1 (en) 2015-06-30 2017-01-04 Dow Global Technologies LLC Methods of preparing a peelable seal layer
US20180134012A1 (en) 2015-06-30 2018-05-17 Dow Global Technologies Llc Multi-layered films oriented in the machine direction and articles comprising the same
EP3317100B1 (en) 2015-06-30 2020-11-04 Dow Global Technologies LLC Multi-layered films oriented in the machine direction and articles comprising the same
WO2017006212A1 (en) 2015-07-06 2017-01-12 Sabic Global Technologies B.V. High fatigue thermoplastic formulations
ES2975017T3 (es) 2015-07-09 2024-07-02 Ineos Europe Ag Copolímeros y películas de los mismos
EP3133107A1 (en) 2015-08-18 2017-02-22 Trinseo Europe GmbH Polyolefin compositions containing high concentrations of reinforcing fibers and methods of preparation
ES2758444T3 (es) 2015-08-31 2020-05-05 Dow Global Technologies Llc Resinas para uso como capa de unión en una estructura multicapa y estructuras multicapa que comprenden las mismas
KR102606493B1 (ko) 2015-09-17 2023-11-28 다우 글로벌 테크놀로지스 엘엘씨 감소된 발화 민감도를 가진 폴리머 코팅물 조성물
EP3350236B1 (en) * 2015-09-17 2023-10-04 ExxonMobil Chemical Patents Inc. Polyethylene polymers and articles made therefrom
JP6942694B2 (ja) 2015-09-25 2021-09-29 ダウ グローバル テクノロジーズ エルエルシー 低粘度ポリオレフィンの官能化用の非押出法
JP6595707B2 (ja) 2015-09-29 2019-10-23 ダウ グローバル テクノロジーズ エルエルシー 収縮フィルム、及びその作製方法
KR102606500B1 (ko) 2015-09-30 2023-11-28 다우 글로벌 테크놀로지스 엘엘씨 사슬 왕복에 유용한 다중-헤드 또는 이중-헤드 조성물 및 이를 제조하는 방법
TW201731693A (zh) 2015-10-14 2017-09-16 陶氏全球科技有限責任公司 用於改良之液體釋放之封裝
WO2017087776A1 (en) 2015-11-19 2017-05-26 Dow Global Technologies Llc Polymer blends for use in multilayer structure and multilayer structures comprising the same
EP3173442A1 (en) 2015-11-27 2017-05-31 Borealis AG Semiconductive polyethylene composition
ES2765241T3 (es) * 2015-12-10 2020-06-08 Dow Global Technologies Llc Cintas, fibras o monofilamentos de polietileno que comprenden un polímero de etileno/alfa-olefina
US10857703B2 (en) 2015-12-11 2020-12-08 Dow Global Technologies Llc Mutilayer polyethylene films, and articles made therefrom
BR112018010299B1 (pt) 2015-12-11 2023-02-23 Kimberly-Clark Worldwide, Inc Método para formar fibras porosas
KR20180090835A (ko) 2015-12-11 2018-08-13 다우 글로벌 테크놀로지스 엘엘씨 단층 필름, 및 이로 제조된 물품
EP3387173B1 (en) 2015-12-11 2021-02-03 Kimberly-Clark Worldwide, Inc. Multi-stage drawing technique for forming porous fibers
AU2016370562B2 (en) 2015-12-17 2021-05-13 Kimberly-Clark Worldwide, Inc. Color-changing polymeric material
CN108367555B (zh) 2015-12-18 2023-06-13 陶氏环球技术有限责任公司 适用于热成型应用的多层膜
WO2017132122A1 (en) 2016-01-28 2017-08-03 Dow Global Technologies Llc Fluid useful as coolant containing carbon nanoparticles and dispersed semi-crystalline polymer particles
EP3436518B1 (en) 2016-03-31 2024-01-03 Dow Global Technologies LLC Modified polyethylene resins and method for making the same
MX2018011904A (es) 2016-04-01 2019-02-13 Cryovac Inc Articulo de envasado, termoencogible, libre de polvo.
WO2017180690A1 (en) 2016-04-13 2017-10-19 Cryovac, Inc. VACUUM SKIN PACKAGE HAVING lMPLOSION-RESISTANT TOP WEB
JP6974346B2 (ja) 2016-05-02 2021-12-01 ダウ グローバル テクノロジーズ エルエルシー 改善された損傷耐性のためのポリオレフィン分散液及びエポキシ分散液ブレンド
CA2993283C (en) 2016-05-04 2020-01-28 Avent, Inc. Disposable surgical gown
RU2741434C2 (ru) 2016-05-31 2021-01-26 Дау Глоубл Текнолоджиз, Ллк Пленки с покрытием и упаковки из них
WO2017208945A1 (ja) 2016-05-31 2017-12-07 旭化成株式会社 樹脂組成物、樹脂組成物の製造方法及び成形体
EP3260295A1 (en) 2016-06-22 2017-12-27 Dow Global Technologies LLC Multilayer films and packages formed from same
TWI758301B (zh) 2016-06-28 2022-03-21 美商陶氏全球科技有限責任公司 多層膜、包括多層膜之製品、製造多層膜之方法
EP3263333A1 (en) 2016-06-29 2018-01-03 Dow Global Technologies LLC Multilayer films and packages comprising the same
US10726976B2 (en) 2016-06-30 2020-07-28 Dow Global Technologies Llc Semiconductive shield free of weld lines and protrusions
US20180029343A1 (en) 2016-07-29 2018-02-01 Dow Global Technologies Llc Polyethylene based synthetic paper
CN109478446B (zh) 2016-07-29 2022-02-18 陶氏环球技术有限责任公司 包含生物基流体的驱油组合物
AU2017301367B2 (en) 2016-07-29 2022-09-29 O&M Halyard, Inc., Collar for a disposable surgical gown
CN109790340A (zh) 2016-08-12 2019-05-21 陶氏环球技术有限责任公司 包括碳纤维和至少一种热塑性聚烯烃弹性体的组合物
SG11201901112XA (en) 2016-08-12 2019-03-28 Dow Global Technologies Llc Propylene-based compositions comprising carbon fibers and a thermoplastic polyolefin elastomer
WO2018044275A1 (en) 2016-08-30 2018-03-08 Dow Global Technologies Llc Ethylene/c3-c6 alpha-olefin interpolymers with improved pellet flowability
WO2018044414A1 (en) 2016-08-30 2018-03-08 Dow Global Technologies Llc Method for thermally insulating subsea structures
FR3055629B1 (fr) 2016-09-08 2018-08-17 Arkema France Composition durcissable comprenant un polymere d'ethylene, un monoperoxycarbonate et un hydroperoxyde de t-alkyle
WO2018045559A1 (en) 2016-09-09 2018-03-15 Dow Global Technologies Llc Multilayer films and laminates and articles comprising the same
EP3293002A1 (en) 2016-09-09 2018-03-14 Dow Global Technologies LLC Multilayer films and laminates and packages formed from same
CN109689767B (zh) 2016-09-13 2022-02-18 陶氏环球技术有限责任公司 用于可发泡电缆绝缘材料的成核剂
EP3515984B1 (en) 2016-09-22 2020-10-28 Dow Global Technologies LLC Polyethylene compositions, and articles made therefrom
CN109689770A (zh) 2016-09-22 2019-04-26 陶氏环球技术有限责任公司 聚乙烯组合物和由其制成的制品
KR102720455B1 (ko) 2016-09-28 2024-10-23 다우 글로벌 테크놀로지스 엘엘씨 다층 필름 및 상기 필름을 갖는 파우치
MY191243A (en) 2016-09-29 2022-06-10 Dow Global Technologies Llc Multilayer stretch films and methods thereof
TWI757341B (zh) 2016-09-29 2022-03-11 美商陶氏全球科技有限責任公司 塗佈膜及由其形成之製品
US20180094127A1 (en) 2016-09-30 2018-04-05 Dow Global Technologies Llc Polyolefin based stretched films incorporating dispersed agents for optimization of application
TW201840572A (zh) 2016-09-30 2018-11-16 美商陶氏全球科技有限責任公司 適用於鏈梭移之多頭或雙頭組合物及其製備方法
EP3519181B9 (en) 2016-09-30 2022-09-28 Dow Global Technologies LLC Resins for use as tie layers in multilayer films and multilayer films comprising the same
MY190620A (en) 2016-09-30 2022-04-27 Dow Global Technologies Llc Polyolefin based stretched films incorporating mechanochromic dyes and method to use same
WO2018064540A1 (en) 2016-09-30 2018-04-05 Dow Global Technologies Llc Process for preparing multi- or dual-headed compositions useful for chain shuttling
WO2018071513A1 (en) 2016-10-12 2018-04-19 Dow Global Technologies Llc Multilayer structures, articles comprising the same, and methods of making multilayer structures
US20210363281A1 (en) 2016-10-12 2021-11-25 Dow Global Technologies Llc Method to produce functionalized ethylene-based polymers
US11077598B2 (en) 2016-10-28 2021-08-03 Dow Global Technologies Llc Energy transfer screw and improved extrusion process
GB2570249B (en) 2016-10-31 2022-06-08 Kimberly Clark Co Latent elastic olefin film laminates and methods of making absorbent articles incorporating the same
WO2018085366A1 (en) 2016-11-02 2018-05-11 Dow Global Technologies Llc Flame-retardant, moisture-cured wire and cable constructions with improved glancing impact performance
TW201829574A (zh) 2016-11-16 2018-08-16 美商陶氏全球科技有限責任公司 黏結層組合物及併有黏結層組合物之多層薄膜
BR112019009438B1 (pt) 2016-11-16 2024-02-06 Dow Global Technologies Llc Composição e cabo
MX2019005480A (es) 2016-11-18 2019-08-12 Dow Global Technologies Llc Mezclas de polimeros para usarse en estructuras multicapa y estructuras multicapa que las comprenden.
BR112019009937B1 (pt) 2016-11-18 2024-03-12 Dow Global Technologies Llc Mescla de polímero e estrutura de múltiplas camadas
EP3551453A1 (en) 2016-12-10 2019-10-16 Cooper-Standard Automotive, Inc. Roofing membranes, compositions, and methods of making the same
JP6792644B2 (ja) 2016-12-10 2020-11-25 クーパー−スタンダード・オートモーティブ・インコーポレーテッド 動的シール、組成物、およびこれらを作製する方法
TW201840705A (zh) 2016-12-19 2018-11-16 德商科思創德意志股份有限公司 具有良好機械性質的熱塑性組成物
JP6845005B2 (ja) * 2016-12-27 2021-03-17 Ｅｎｅｏｓ株式会社 粘着テープ
CN110248576B (zh) 2017-01-04 2023-01-03 肖氏工业集团公司 具有改进的脱层强度和流体阻隔性质的地毯及其制造方法
JP6917461B2 (ja) 2017-01-11 2021-08-11 ダウ グローバル テクノロジーズ エルエルシー 多層構造体に使用するポリマーブレンドおよびそれを含む多層構造体
WO2018140308A1 (en) 2017-01-26 2018-08-02 Dow Global Technologies Llc Multilayer films having tunable strain hardening
US10329412B2 (en) 2017-02-16 2019-06-25 Nova Chemicals (International) S.A. Caps and closures
EP3363773A1 (en) 2017-02-17 2018-08-22 Trinseo Europe GmbH Fibrous sheets coated with polyolefin compositions and methods of preparation
EP3363858A1 (en) 2017-02-20 2018-08-22 Trinseo Europe GmbH Compositions of polyolefin dispersions and lactices and polymeric mixtures prepared therefrom
JP2020513045A (ja) 2017-03-03 2020-04-30 ダウ グローバル テクノロジーズ エルエルシー 改善された斜め衝撃性能を有する難燃性、水分硬化性ワイヤおよびケーブル構造
ES2783948T3 (es) 2017-03-10 2020-09-21 Dow Global Technologies Llc Películas multicapa y métodos de las mismas
BR112019019130B1 (pt) 2017-03-15 2023-03-28 Dow Global Technologies Llc Sistema catalisador de polimerização de olefina e processo para preparar um copolímero de múltiplos blocos
CN110546171B (zh) 2017-03-15 2023-02-28 陶氏环球技术有限责任公司 用于形成多嵌段共聚物的催化剂体系
KR102710284B1 (ko) 2017-03-15 2024-09-27 다우 글로벌 테크놀로지스 엘엘씨 다중-블록 공중합체 형성을 위한 촉매 시스템
KR102711048B1 (ko) 2017-03-15 2024-09-27 다우 글로벌 테크놀로지스 엘엘씨 다중-블록 공중합체 형성을 위한 촉매 시스템
JP2020510129A (ja) 2017-03-15 2020-04-02 ダウ グローバル テクノロジーズ エルエルシー マルチブロックコポリマー形成用触媒系
PL3378642T3 (pl) 2017-03-23 2021-12-20 Dow Global Technologies, Llc Folie wielowarstwowe i opakowania je zawierające
WO2018183871A1 (en) 2017-03-30 2018-10-04 Shaw Industries Group, Inc. Carpet tiles and systems and methods of making same
US10982383B2 (en) 2017-04-05 2021-04-20 Columbia Insurance Company Floor coverings and floor covering systems and methods of making and installing same
EP3609698B1 (en) 2017-04-13 2023-06-28 Cryovac, LLC High-shrink, high-strength packaging article exhibiting directional tear
AU2018253215B2 (en) 2017-04-13 2023-11-30 Cryovac, Llc High-shrink, high-strength multilayer film
RU2019132071A (ru) 2017-04-13 2021-05-13 Криовак, Ллк Высокоусадочная высокопрочная многослойная пленка, содержащая трехкомпонентную смесь
US10442921B2 (en) 2017-04-19 2019-10-15 Nova Chemicals (International) S.A. Means for increasing the molecular weight and decreasing the density employing mixed homogeneous catalyst formulations
US10442920B2 (en) 2017-04-19 2019-10-15 Nova Chemicals (International) S.A. Means for increasing the molecular weight and decreasing the density of ethylene interpolymers employing homogeneous and heterogeneous catalyst formulations
WO2018195681A1 (en) 2017-04-24 2018-11-01 Dow Global Technologies Llc Multilayer structures, processes for manufacturing multilayer structures, and related articles
US11447600B2 (en) 2017-05-01 2022-09-20 Dow Global Technologies Llc Polyolefin dispersion and epoxy dispersion blends for improved damage tolerance
ES2928333T3 (es) 2017-05-11 2022-11-17 Dow Global Technologies Llc Películas de invernadero multicapa de poliolefina con alta transparencia
WO2018218469A1 (en) 2017-05-29 2018-12-06 Dow Global Technologies Llc Thermoplastic polyolefin compositions useful for aldehyde abatement
WO2018218467A1 (en) 2017-05-29 2018-12-06 Dow Global Technologies Llc Thermoplastic polyolefin compositions useful for aldehyde abatement
WO2018218470A1 (en) 2017-05-29 2018-12-06 Dow Global Technologies Llc Thermoplastic polyolefin compositions useful for aldehyde abatement
CN110869187A (zh) 2017-05-31 2020-03-06 陶氏环球技术有限责任公司 用于涂覆管道现场接头的方法
RU2020100898A (ru) 2017-06-29 2021-07-14 Дау Глоубл Текнолоджиз Ллк Влагоотверждаемые конструкции проводов и кабелей
JP7229224B2 (ja) 2017-07-18 2023-02-27 ダウ グローバル テクノロジーズ エルエルシー 樹脂、多層フィルム、およびそれを含むパッケージ
EP3431546A1 (en) 2017-07-18 2019-01-23 Dow Global Technologies Llc Resins, multilayer films and packages comprising the same
WO2019027527A1 (en) 2017-07-31 2019-02-07 Dow Global Technologies Llc ENTIRELY POLYETHYLENE LAMINATED FILM STRUCTURES HAVING A BARRIER ADHESIVE LAYER
MX2020001232A (es) 2017-08-01 2020-03-20 O&M Halyard Int Unlimited Co Sistema de bolsillo y manta para proporcionar campos esteriles.
CN111133047A (zh) 2017-08-10 2020-05-08 陶氏环球技术有限责任公司 包含溴化聚合阻燃剂的组合物
EP3676067B1 (en) 2017-08-30 2022-11-23 Dow Global Technologies LLC Continuous extrusion process for manufacturing rheology-modified polyolefin for cable insulation layer
JP2020534216A (ja) 2017-09-22 2020-11-26 ダウ グローバル テクノロジーズ エルエルシー 再閉可能フィルムを含む再閉可能包装およびその作成方法
JP7221942B2 (ja) 2017-09-22 2023-02-14 ダウ グローバル テクノロジーズ エルエルシー 熱成形プロセス後の強化された靭性を有する熱成形フィルム組成物
TWI781221B (zh) 2017-09-22 2022-10-21 美商陶氏全球科技有限責任公司 用於可再閉合包裝之組合物及多層膜
CN111132906A (zh) 2017-09-22 2020-05-08 陶氏环球技术有限责任公司 可再封闭的搭接密封包装
BR112020005570A2 (pt) 2017-09-22 2020-10-06 Dow Global Technologies Llc embalagens refecháveis com geometria de vedação ajustável
KR102591753B1 (ko) 2017-09-26 2023-10-23 다우 글로벌 테크놀로지스 엘엘씨 실란-관능화된 에틸렌성 중합체의 수분 경화를 위한 주석계 촉매 및 이산화티타늄을 포함하는 조성물
BR112020005821B1 (pt) 2017-09-27 2023-05-09 Dow Global Technologies Llc Forro de tubo de múltiplas camadas flexível e compósito flexível
JP7322006B2 (ja) 2017-09-27 2023-08-07 ダウ グローバル テクノロジーズ エルエルシー 変性ポリエチレン組成物およびそれを作製するための方法
ES2902911T3 (es) 2017-09-29 2022-03-30 Dow Global Technologies Llc Películas parcialmente revestidas y envases formados a partir de las mismas
US10995166B2 (en) 2017-11-07 2021-05-04 Nova Chemicals (International) S.A. Ethylene interpolymer products and films
US10683376B2 (en) 2017-11-07 2020-06-16 Nova Chemicals (International) S.A. Manufacturing ethylene interpolymer products at higher production rate
CN111278915B (zh) 2017-11-10 2023-01-13 科思创德国股份有限公司 具有良好机械性质的经矿物填充的热塑性组合物
US11767426B2 (en) 2017-11-10 2023-09-26 Covestro Deutschland Ag Glass fiber filled thermoplastic composition having good mechanical properties
RU2020117127A (ru) 2017-11-16 2021-11-25 Дау Глоубл Текнолоджиз Ллк Способ покрытия трубопроводного монтажного стыка
ES2945721T3 (es) 2017-11-22 2023-07-06 Dow Global Technologies Llc Películas a base de poliolefina con superficie mate y rendimiento de sellado mejorado
WO2019113142A1 (en) 2017-12-06 2019-06-13 Dow Global Technologies Llc Flotation separation aid useful for collection of mineral ore fines
US11539095B2 (en) 2017-12-06 2022-12-27 Asahi Kasei Kabushiki Kaisha In-vehicle lithium ion battery member
US11433158B2 (en) 2017-12-12 2022-09-06 The Procter & Gamble Company Recycle friendly and sustainable absorbent articles
FR3075210B1 (fr) 2017-12-15 2020-05-22 Arkema France Utilisation d'un melange de peroxydes organiques pour la reticulation d'un elastomere de polyolefine
WO2019126129A1 (en) 2017-12-22 2019-06-27 E. I. Du Pont De Nemours And Company Thermoplastic adhesive composition
WO2019126189A1 (en) 2017-12-22 2019-06-27 E. I. Du Pont De Nemours And Company Thermoplastic adhesive composition
MX2020006697A (es) 2017-12-27 2020-08-20 Dow Global Technologies Llc Pelicula de cinta de cierre de burbuja colapsada para mejorar el rendimiento elastico y la rigidez en bolsas para residuos.
WO2019152830A1 (en) 2018-02-01 2019-08-08 Dow Silicones Corporation Composition, polymer composite article formed therewith, and method of preparing same
US11472928B2 (en) 2018-02-14 2022-10-18 Dover Chemical Corporation Use of a polymeric polyphosphite as a polymer processing aid
US20190248960A1 (en) * 2018-02-14 2019-08-15 Dover Chemical Corporation Use of a Polymeric Polyphosphite as a Polymer Processing Aid
MY204757A (en) 2018-02-28 2024-09-11 Dow Global Technologies Llc Polyurethane coated heat-shrinkable film
CN111867830B (zh) 2018-03-29 2023-08-04 陶氏环球技术有限责任公司 用作多层结构中的连接层的树脂和包括所述树脂的多层结构
WO2019190749A1 (en) 2018-03-29 2019-10-03 Dow Global Technologies Llc A method to adjust the elongation required to effect a color change in polymeric stretch films incorporating mechanochromic dyes
MX2020009715A (es) 2018-03-29 2020-10-07 Dow Global Technologies Llc Resinas para usarse como adhesivo de coextrusion en estructura multicapa y estructuras multicapa que las comprenden.
WO2019197270A1 (en) 2018-04-09 2019-10-17 Covestro Deutschland Ag Glass fiber reinforced thermoplastic compositions with good mechanical properties
WO2019209546A1 (en) 2018-04-27 2019-10-31 Dow Global Technologies Llc Non-foam polyolefin compositions for wire and cable coating
BR112020020675B1 (pt) 2018-04-27 2023-11-28 Dow Global Technologies Llc Composição mesclada por fusão, composição reticulada, bainha de fio ou cabo e fio ou cabo
EP3564418B1 (en) 2018-05-03 2021-06-23 Dow Global Technologies LLC Artificial turf yarn with improved processibility and friction management
EP3569411A1 (en) 2018-05-18 2019-11-20 Dow Global Technologies Llc Spout pouch and method of making same
TWI820130B (zh) 2018-05-22 2023-11-01 美商陶氏全球科技有限責任公司 具有對聚酯反應性黏著之催化劑之樹脂
CN112154113B (zh) 2018-06-11 2024-04-05 陶氏环球技术有限责任公司 纵切机和用其形成涂布膜的卷的方法
CN116731283A (zh) 2018-06-11 2023-09-12 陶氏环球技术有限责任公司 制造涂布膜的方法和可以用于制造涂布膜的无溶剂聚氨基甲酸酯前体
JP7358400B2 (ja) 2018-06-11 2023-10-10 ダウ グローバル テクノロジーズ エルエルシー コーティングされたフィルム
US12024621B2 (en) 2018-06-29 2024-07-02 Dow Global Technologies Llc Foam bead and sintered foam structure
US11873400B2 (en) 2018-06-29 2024-01-16 Dow Global Technologies Llc Shelf stable aqueous dispersions suitable for use in food contact applications
WO2020005927A1 (en) 2018-06-29 2020-01-02 Dow Global Technologies Llc Coated films and articles formed from same
EP3590705A1 (en) 2018-07-02 2020-01-08 E. I. du Pont de Nemours and Company Multilayer films incorporating universal thermoplastic adhesives
EP3591019A1 (en) 2018-07-02 2020-01-08 E. I. du Pont de Nemours and Company Universal thermoplastic adhesives for multilayer films
WO2020023694A1 (en) 2018-07-25 2020-01-30 Sealed Air Corporation (Us) Inflatable cellular cushioning article with enhanced performance properties
AU2019323823B2 (en) 2018-08-24 2024-09-26 O&M Halyard, Inc. Personal protection and ventilation system
US11528947B2 (en) 2018-08-24 2022-12-20 O&M Halyard, Inc. Personal protection and ventilation system
US12006423B2 (en) 2018-08-29 2024-06-11 ExxonMobil Engineering & Technology Company Methods of making polymer compositions with enhanced elasticity by employing VTP and HMP catalyst systems in parallel processes
EP3616909B1 (en) 2018-08-29 2021-03-31 Dow Global Technologies LLC Multilayer films for use in flexible packaging materials
WO2020056678A1 (en) 2018-09-20 2020-03-26 Dow Global Technologies Llc Bonding method to attach ethylene-based polymer foam with vulcanized rubber
EP3856824B1 (en) 2018-09-28 2022-10-19 Dow Global Technologies LLC Coated heat-shrinkable films
CN112805325B (zh) 2018-10-03 2023-04-04 联合利华知识产权控股有限公司 包含纳米纤维素的柔性包装膜
CN112867640B (zh) 2018-10-17 2024-03-29 陶氏环球技术有限责任公司 涂料组合物、经涂布织物、制造经涂布织物的方法以及由经涂布织物制成的制品
WO2020081278A1 (en) 2018-10-17 2020-04-23 Dow Global Technologies Llc A coating composition, a coated fabric, a method of making a coated fabric, and an article made from the coated fabric
WO2020081279A1 (en) 2018-10-17 2020-04-23 Dow Global Technologies Llc A coating composition, a coated fabric, a method of making a coated fabric, and an article made from the coated fabric
MX2021004549A (es) 2018-11-12 2021-06-15 Dow Global Technologies Llc Copolimeros reticulables por humedad de etileno y silano hidrolizable.
WO2020107304A1 (en) 2018-11-29 2020-06-04 Dow Global Technologies Llc Thermoplastic polyolefin compositions useful for odor reduction
WO2020107303A1 (en) 2018-11-29 2020-06-04 Dow Global Technologies Llc Thermoplastic polyolefin compositions useful for odor reduction
US11780998B2 (en) 2018-11-29 2023-10-10 Dow Global Technologies Llc Thermoplastic polyolefin compositions useful for odor reduction
JP2022510201A (ja) 2018-12-06 2022-01-26 オーアンドエム ハリヤード インコーポレイテッド サージカルフード用の機械的に結合されたバイザーシステム
EP3899122B1 (en) 2018-12-10 2024-08-07 Dow Global Technologies LLC Airlaid substrates having at least one bicomponent fiber
WO2020123091A1 (en) 2018-12-11 2020-06-18 Dow Global Technologies Llc Silo bags with non-uniform thickness and methods of producing
WO2020139068A1 (en) 2018-12-24 2020-07-02 Dow Global Technologies Llc Sealed multilayer structures and packages comprising sealed multilayer structures
CN113498414A (zh) 2018-12-28 2021-10-12 陶氏环球技术有限责任公司 包括遥爪聚烯烃的可固化组合物
WO2020133156A1 (en) 2018-12-28 2020-07-02 Dow Global Technologies Llc Laminate structures and flexible packaging materials incorporating same
US11958254B2 (en) 2018-12-28 2024-04-16 Dow Global Technologies Llc Polyethylene pouch and the fabrication method thereof
KR20210121026A (ko) 2018-12-28 2021-10-07 다우 글로벌 테크놀로지스 엘엘씨 텔레켈릭 폴리올레핀 및 이의 제조 방법
CN113195217B (zh) 2018-12-28 2024-01-02 陶氏环球技术有限责任公司 层压结构和合并有其的软包装材料
US20220025587A1 (en) 2019-01-03 2022-01-27 Dow Global Technologies Llc Artificial turf grass with natural appearance
WO2020142232A1 (en) 2019-01-03 2020-07-09 Dow Global Technologies Llc Artificial turf having siloxane polymer containing turf infill and compositions for making such turf infill
EP3908162A4 (en) 2019-01-07 2022-08-17 Shaw Industries Group, Inc. CARPET COMPOSITIONS WITH LAMINATED Foil CARPET BACKING AND METHOD OF MANUFACTURE THEREOF
US10882987B2 (en) 2019-01-09 2021-01-05 Nova Chemicals (International) S.A. Ethylene interpolymer products having intermediate branching
BR112021014732A2 (pt) 2019-01-31 2021-09-28 Dow Global Technologies Llc Composição de asfalto, e, método para produzir uma composição de asfalto
TWI841662B (zh) 2019-01-31 2024-05-11 美商陶氏全球科技有限責任公司 多層結構、用於製造多層結構之方法及相關製品
EP3921368A1 (en) 2019-02-06 2021-12-15 Dow Global Technologies LLC Flame-retardant moisture-crosslinkable compositions
WO2020186129A1 (en) 2019-03-14 2020-09-17 Dow Silicones Corporation Polyorganosiloxane hybrid pressure sensitive adhesive and methods for the preparation and use thereof
WO2020190948A1 (en) 2019-03-20 2020-09-24 Dow Global Technologies Llc Methods of making films having target beta ratios and target permeabilities
EP3946938B1 (en) 2019-03-26 2024-08-07 Dow Global Technologies LLC Multilayer films, laminates, and articles comprising multilayer films
AR118648A1 (es) 2019-04-24 2021-10-20 Dow Global Technologies Llc Película multicapa de funda estirable con resistencia al desgarro mejorada
WO2020223488A1 (en) * 2019-04-30 2020-11-05 Dow Global Technologies Llc Alkene functionalized activators
US12129363B2 (en) 2019-05-02 2024-10-29 Dow Global Technologies Llc Polyethylene-based compositions and films and articles comprising the same
BR112021021134A2 (pt) 2019-05-02 2022-03-03 Dow Global Technologies Llc Sistemas e métodos de impressão que incluem filmes com múltiplas camadas
AR118910A1 (es) 2019-05-13 2021-11-10 Dow Global Technologies Llc Películas de espuma polimérica libres de talco formadas con agentes de soplado duales
CN113950491B (zh) 2019-05-31 2024-05-14 陶氏环球技术有限责任公司 可加工性得到改善的低密度聚乙烯
CN114008090B (zh) 2019-05-31 2023-12-22 陶氏环球技术有限责任公司 齐格勒-纳塔催化的聚乙烯树脂和掺入有所述聚乙烯树脂的膜
AR119085A1 (es) 2019-06-06 2021-11-24 Dow Global Technologies Llc Película soplada multicapa
WO2020247563A1 (en) 2019-06-06 2020-12-10 O&M Halyard Inc. Pocket and drape system for providing sterile fields
WO2020247560A1 (en) 2019-06-06 2020-12-10 O&M Halyard Inc. Pocket and drape system for providing sterile fields
US11291517B2 (en) 2019-06-06 2022-04-05 O&M Halyard, Inc. Pocket and drape system for providing sterile fields
US20200383742A1 (en) 2019-06-06 2020-12-10 O&M Halyard, Inc. Pocket and Drape System for Providing Sterile Fields
AR119189A1 (es) 2019-06-28 2021-12-01 Dow Global Technologies Llc Laminados de películas de envasado flexible y método para elaborarlos mediante laminación térmica
AR119229A1 (es) 2019-06-28 2021-12-01 Dow Global Technologies Llc Películas multicapa de polietileno resistentes al calor para líneas de embalaje flexible de alta velocidad
US11046843B2 (en) 2019-07-29 2021-06-29 Nova Chemicals (International) S.A. Ethylene copolymers and films with excellent sealing properties
JP2022543782A (ja) 2019-07-31 2022-10-14 ダウ グローバル テクノロジーズ エルエルシー 多層フィルムおよび多層フィルムを含む物品
GB2600879B (en) 2019-07-31 2023-07-19 Kimberly Clark Co Zoned elastic film and laminates comprising the same
WO2021021184A1 (en) 2019-07-31 2021-02-04 Kimberly-Clark Worldwide, Inc. Zoned elastic film and laminates comprising the same
MX2022001338A (es) 2019-08-01 2022-03-11 Dow Global Technologies Llc Estructuras multicapa que tienen una capacidad de reciclaje mejorada.
EP3772415B1 (en) 2019-08-06 2022-12-14 Dow Global Technologies Llc Multilayer films comprising polyethylene and barrier layers and methods of producing the same
ES2956463T3 (es) 2019-08-06 2023-12-21 Dow Global Technologies Llc Películas multicapa que tienen al menos tres capas, y métodos para producir las mismas
MY210279A (en) 2019-08-06 2025-09-08 Dow Global Technologies Llc Multilayer films that include at least five layers and methods of producing the same
WO2021026135A1 (en) 2019-08-06 2021-02-11 Dow Global Technologies Llc Polyethylene compositions
MX2020008168A (es) 2019-08-06 2021-02-08 Dow Global Technologies Llc Composiciones de polietileno.
CA3099524C (en) 2019-08-07 2021-08-31 Dow Silicones Corporation Solid carrier component including a liquid polyorganosiloxane and methods for preparation and use of the solid carrier component
CN112654679B (zh) 2019-08-07 2023-02-03 美国陶氏有机硅公司 烯基官能化聚二有机硅氧烷组合物及其在形成木塑复合材料中的使用方法
CA3146327A1 (en) 2019-08-07 2021-02-11 Jodi Mecca Polydiorganosiloxane compositions and methods for use thereof in forming wood plastic composites
EP3799595B1 (en) 2019-08-07 2022-07-06 Dow Silicones Corporation Solid carrier component including a liquid polydiorganosiloxane and methods for preparation and use of the solid carrier component
WO2021035709A1 (en) 2019-08-30 2021-03-04 Dow Global Technologies Llc Polyolefin compositions having improved electrical properties
EP4032735A4 (en) 2019-09-20 2023-09-27 Mitsui Chemicals, Inc. Display device
EP3797988A1 (en) 2019-09-30 2021-03-31 Dow Global Technologies Llc Plastomer toughened/stiffened polyolefin multilayer films and laminates comprising same
CA3153140A1 (en) 2019-10-11 2021-04-15 Craig F. GORIN Additive manufacturing using recycled polyolefins with olefin block copolymers and articles made therefrom
AR120210A1 (es) 2019-10-15 2022-02-02 Dow Global Technologies Llc Películas de polietileno multicapa orientadas en la dirección de la máquina y artículos que las comprenden
JP7681582B2 (ja) 2019-10-17 2025-05-22 ダウ グローバル テクノロジーズ エルエルシー 多層フィルムおよび多層フィルムを含む物品
WO2021076541A1 (en) 2019-10-18 2021-04-22 Dow Global Technologies Llc Impact modification of styrenic polymers with polyolefin acrylic polymers
WO2021086750A1 (en) 2019-10-31 2021-05-06 Dow Global Technologies Llc Article made from post consumer resin with smooth surface finish
CN114829140B (zh) 2019-12-10 2023-12-29 陶氏环球技术有限责任公司 定向的聚乙烯膜和包含该聚乙烯膜的制品
WO2021126419A1 (en) 2019-12-16 2021-06-24 Dow Global Technologies Llc Oriented polyethylene films and articles comprising the same
EP3838990A1 (en) 2019-12-20 2021-06-23 Dow Global Technologies Llc A bitumen composition including recycled synthetic turf, and method for making same
BR112022012371A2 (pt) 2019-12-26 2022-08-30 Dow Global Technologies Llc Espuma de poliolefina reticulada e processo para produzir a mesma
BR112022012559A2 (pt) 2019-12-30 2022-09-06 Dow Global Technologies Llc Composição, e, condutor revestido
MX2022008119A (es) 2019-12-31 2022-07-21 Dow Global Technologies Llc Composiciones de polietileno.
DE112020006418T5 (de) 2020-02-24 2022-10-27 Kimberly-Clark Worldwide, Inc. Nicht-blockierende mehrschichtige elastische zusammensetzung
JP2023520142A (ja) 2020-04-06 2023-05-16 ダウ グローバル テクノロジーズ エルエルシー フィルム又はブレンドで使用するための強化溶融強度の低密度ポリエチレン
EP4132997A1 (en) 2020-04-10 2023-02-15 Dow Global Technologies LLC Films including post consumer resin
JP2023525719A (ja) 2020-05-11 2023-06-19 ダウ グローバル テクノロジーズ エルエルシー 照合収縮フィルム
WO2021242619A1 (en) 2020-05-27 2021-12-02 Dow Global Technologies Llc Polymer formulations and irrigation tubing including polymer formulations
JP7712959B2 (ja) 2020-05-29 2025-07-24 ダウ グローバル テクノロジーズ エルエルシー 配向ポリエチレンフィルム及びそれを含む物品
WO2021247163A1 (en) 2020-06-05 2021-12-09 Dow Global Technologies Llc Adhesiveless thermally laminated barrier heat sealing films including polyethylene
JP2023529087A (ja) 2020-06-05 2023-07-07 ダウ グローバル テクノロジーズ エルエルシー ポリエチレンを含むヒートシールバリア積層体
US20230183469A1 (en) 2020-06-19 2023-06-15 Rohm And Haas Company Polyolefin/(meth)acrylic composite polymer composition and method of preparing same
WO2022005533A1 (en) 2020-06-30 2022-01-06 Dow Global Technologies Llc Polyethylene compositions and films including polyethylene compositions
WO2022005532A1 (en) 2020-06-30 2022-01-06 Dow Global Technologies Llc Polyethylene compositions
WO2022015469A1 (en) 2020-07-15 2022-01-20 Dow Global Technologies Llc Polyethylene-based compositions and films made from same
JP2023539412A (ja) 2020-07-15 2023-09-14 ダウ グローバル テクノロジーズ エルエルシー 汚染された熱可塑性物質から汚染物質を除去するためのプロセス
EP4188705A4 (en) 2020-07-30 2024-03-27 Dow Global Technologies LLC MULTILAYER STRUCTURES, LAMINATES AND ASSOCIATED ARTICLES
EP3970760B1 (en) 2020-09-16 2024-05-29 Dow Global Technologies LLC Feminine hygiene articles and films suitable for use in such
US20230365792A1 (en) 2020-09-16 2023-11-16 Dow Global Technologies Llc Copolymers of ethylene with (meth) acrylic ester functionalized polysiloxane
CN116323205B (zh) 2020-10-30 2025-10-17 陶氏环球技术有限责任公司 多层膜和包括该多层膜的制品
WO2022093488A1 (en) 2020-10-30 2022-05-05 Dow Global Technologies Llc Multilayer films and articles comprising the same
EP4000922B1 (en) 2020-11-20 2025-04-30 Dow Global Technologies LLC Multilayer films having at least one matte surface
CA3198297A1 (en) 2020-11-20 2022-05-27 Dow Global Technologies Llc Multilayer structures and articles with coating layers
JP2024500015A (ja) 2020-11-24 2024-01-04 ダウ グローバル テクノロジーズ エルエルシー 高分岐エチレン系ポリマーを使用して製造された押出発泡体
WO2022115378A1 (en) 2020-11-25 2022-06-02 Dow Global Technologies Llc. Polymer blends having increased temperature resistance
MX2023006165A (es) 2020-12-08 2023-06-08 Dow Global Technologies Llc Articulo.
EP4259423A1 (en) 2020-12-08 2023-10-18 Dow Global Technologies LLC Article
MX2023006338A (es) 2020-12-08 2023-06-12 Dow Global Technologies Llc Articulo recubierto.
JP2024500017A (ja) 2020-12-09 2024-01-04 ダウ グローバル テクノロジーズ エルエルシー 組成物、このような組成物から形成された多層フィルム、及び物品
WO2022125637A2 (en) 2020-12-11 2022-06-16 Dow Global Technologes Llc Multilayer structures that include oriented films and sealant layers
US12168843B2 (en) 2020-12-21 2024-12-17 O&M Halyard, Inc. Higher strength calcium carbonate filled fiber spunbond and SMS nonwoven material
PL4284644T3 (pl) 2021-01-26 2025-04-28 Dow Global Technologies Llc Kompozycje, folie i wyroby z polietylenu
EP4284643A1 (en) 2021-01-29 2023-12-06 Dow Global Technologies LLC Coated film
MX2023007915A (es) 2021-01-29 2023-07-13 Dow Global Technologies Llc Pelicula recubierta.
WO2022169572A1 (en) 2021-02-03 2022-08-11 Dow Global Technologies Llc Barrier laminates including ethylene copolymer extruded web layers
US12403455B2 (en) 2021-03-12 2025-09-02 University Of Delaware Catalytic hydroconversion of polypropylene-based plastic waste to lubricant base-oils
EP4307981A1 (en) 2021-03-16 2024-01-24 3M Innovative Properties Company A nonwoven decontamination wipe comprising a small diameter fiber
CN117460770A (zh) 2021-06-07 2024-01-26 陶氏环球技术有限责任公司 包含消费后再循环树脂和气味活性沸石用于减轻味道和气味的组合物
JP2024522543A (ja) 2021-06-07 2024-06-21 ダウ グローバル テクノロジーズ エルエルシー ポスト・コンシューマー・リサイクル樹脂並びに味及び臭気を軽減するための臭気活性ゼオライトを含む組成物
JP2024525294A (ja) 2021-06-22 2024-07-12 ダウ グローバル テクノロジーズ エルエルシー 複数のポリマー成分のための水性分離プロセス
CN117999312A (zh) 2021-07-14 2024-05-07 诺瓦化学品(国际)股份有限公司 不含含氟聚合物的聚合物加工助剂
JP7781163B2 (ja) 2021-08-06 2025-12-05 三井化学株式会社 熱可塑性エラストマー組成物およびこれからなる成形体
WO2023017327A1 (en) 2021-08-12 2023-02-16 Nova Chemicals (International) S.A. Block copolymer polymer processing aids
CN117794733A (zh) 2021-08-23 2024-03-29 陶氏环球技术有限责任公司 包括纵向定向多层膜的多层结构
US20240367416A1 (en) 2021-08-23 2024-11-07 Dow Global Technologies Llc Machine direction oriented (mdo) sealable structures
WO2023043426A1 (en) 2021-09-14 2023-03-23 Dow Global Technologies Llc Zeolite containing polyolefin films
WO2023056339A1 (en) 2021-09-30 2023-04-06 Dow Global Technologies Llc Recyclable polymer foams
CA3234522A1 (en) 2021-10-15 2023-04-20 Akanksha GARG Polymer blends comprising post-consumer recycled resin
WO2023064760A1 (en) 2021-10-15 2023-04-20 Dow Global Technologies Llc Polymer blends comprising post-consumer recycled resin
US20240309186A1 (en) 2021-10-28 2024-09-19 Dow Global Technologies Llc Molded article
AR127609A1 (es) 2021-11-12 2024-02-14 Dow Global Technologies Llc Películas de polietileno de alta rigidez orientadas biaxialmente
KR20240108533A (ko) 2021-11-30 2024-07-09 다우 글로벌 테크놀로지스 엘엘씨 연질 열가소성 올레핀 및 이로부터 제조된 제품
CN118302498A (zh) 2021-12-10 2024-07-05 陶氏环球技术有限责任公司 包含硅烷偶联剂的多层结构
CN118434567A (zh) 2021-12-16 2024-08-02 陶氏环球技术有限责任公司 多层膜和包含多层膜的制品
AR127924A1 (es) 2021-12-16 2024-03-13 Dow Global Technologies Llc Películas multicapa y artículos que comprenden películas multicapa
JP2024546202A (ja) 2021-12-23 2024-12-18 ダウ グローバル テクノロジーズ エルエルシー アスファルテン及びエポキシ官能化エチレンコポリマーを含むアスファルト組成物
US20250101211A1 (en) 2022-01-13 2025-03-27 Dow Global Technologies Llc Polyethylene compositions
EP4219155A1 (en) 2022-01-28 2023-08-02 Dow Global Technologies LLC Multilayer films comprising ethylene-based polymers
EP4219157A1 (en) 2022-01-28 2023-08-02 Dow Global Technologies LLC Multilayer films including ethylene-based copolymers
EP4219156A1 (en) 2022-01-28 2023-08-02 Dow Global Technologies LLC Multilayer films comprising ethylene-based polymers
EP4219158A1 (en) 2022-01-28 2023-08-02 Dow Global Technologies LLC Multilayer films comprising ethylene-based polymers
TW202344403A (zh) 2022-05-09 2023-11-16 美商陶氏全球科技有限責任公司 包含聚烯烴分散體作為層壓黏著劑之可回收層壓結構
AR129318A1 (es) 2022-05-20 2024-08-14 Dow Global Technologies Llc Películas multicapa que comprenden ionómeros de polímeros de etileno y ácido
EP4536463A1 (en) 2022-06-10 2025-04-16 Nova Chemicals (International) S.A. Fluorine free polymer processing aids
CA3256718A1 (en) 2022-06-15 2023-12-21 Nova Chemicals Corporation POLYMER PROCESSING AUXILIARIES BASED ON SEQUENCED COPOLYMERS
JP2025524375A (ja) 2022-06-17 2025-07-30 ダウ グローバル テクノロジーズ エルエルシー 多層ヒートシールフィルム
CN119604552A (zh) 2022-08-31 2025-03-11 陶氏环球技术有限责任公司 低粘度官能化的乙烯共聚物
EP4573135A1 (en) 2022-09-08 2025-06-25 Dow Global Technologies LLC Solvent management via two-phase ethylene feed to second reactor to increase ethylene-based polymer output
WO2024073377A1 (en) 2022-09-26 2024-04-04 Dow Global Technologies Llc Multi stage process for producing ethylene-based polymer with (ultra) high molecular weight polyethylene component
CN120051509A (zh) 2022-10-11 2025-05-27 诺瓦化学品(国际)股份有限公司 作为聚合物加工助剂的金属盐
AR130762A1 (es) 2022-10-18 2025-01-15 Dow Global Technologies Llc Laminado con película multicapa orientada en dirección de la máquina
EP4357134A1 (en) 2022-10-18 2024-04-24 Dow Global Technologies LLC Oriented multilayer film including metal layer
WO2024122591A1 (ja) 2022-12-07 2024-06-13 三井化学株式会社 熱可塑性エラストマー組成物およびこれからなる成形体
EP4646448A1 (en) 2023-01-03 2025-11-12 Dow Global Technologies LLC Direct ethylene injection for dual reactor solution process
KR20250136384A (ko) 2023-01-24 2025-09-16 다우 글로벌 테크놀로지스 엘엘씨 중합체성 포스파이트, 폴리디메틸실록산 및 폴리알킬렌글리콜 기반의 중합체 가공 조제
KR20250143310A (ko) 2023-01-30 2025-10-01 다우 글로벌 테크놀로지스 엘엘씨 재활용성 무용매 접착제
KR20250174638A (ko) 2023-04-06 2025-12-12 다우 글로벌 테크놀로지스 엘엘씨 유체 용융 유동 스트림을 혼합하기 위한 공정
WO2024211052A1 (en) 2023-04-06 2024-10-10 Dow Global Technologies Llc Process for producing a grafted polymer
CN120936477A (zh) 2023-04-06 2025-11-11 陶氏环球技术有限责任公司 用于混合流体熔体流动流的方法
WO2024211051A1 (en) 2023-04-06 2024-10-10 Dow Global Technologies Llc Process for mixing a fluid meltflow stream
WO2024211053A1 (en) 2023-04-06 2024-10-10 Dow Global Technologies Llc Process for mixing a fluid meltflow stream and recycle
KR20250174639A (ko) 2023-04-06 2025-12-12 다우 글로벌 테크놀로지스 엘엘씨 가교결합된 물품을 제조하기 위한 공정
WO2024242932A1 (en) 2023-05-23 2024-11-28 ExxonMobil Technology and Engineering Company Polethylenes, catalysts for their polymerization, and films thereof
WO2024249629A1 (en) 2023-05-30 2024-12-05 Dow Global Technologies Llc Adhesive composition
WO2025003837A1 (en) 2023-06-26 2025-01-02 Nova Chemicals (International) S.A. Polar polymers as processing aids in polyethylene
EP4484156A1 (en) 2023-06-26 2025-01-01 Dow Global Technologies LLC Oriented films including polyethylene
WO2025005968A1 (en) 2023-06-27 2025-01-02 Dow Global Technologies Llc Multi stage process for producing ethylene-based polymer with (ultra) high molecular weight polyethylene component
WO2025006178A1 (en) 2023-06-28 2025-01-02 Dow Global Technologies Llc Polymer films having superior combination of processibility and abuse resistance
EP4484159A1 (en) 2023-06-28 2025-01-01 Dow Global Technologies LLC Development of novel film structures that significantly increase the tear and dart impact properties
EP4484160A1 (en) 2023-06-28 2025-01-01 Dow Global Technologies LLC Enhanced toughness for machine direction orientation of polyethylene films and the method thereof
EP4484161A1 (en) 2023-06-28 2025-01-01 Dow Global Technologies LLC Development of novel film structures that significantly increase the cd tear properties of cast stretch films even when incorporating pcr (post-consumer recycled) resins into standard market film structures
WO2025006180A1 (en) 2023-06-28 2025-01-02 Dow Global Technologies Llc Processes for making multimodal ethylene-based polymers
ES2993659A1 (es) 2023-06-28 2025-01-03 Dow Global Technologies Llc Películas de polietileno con múltiples capas con una capa fina cargada con un mineral y copolímero de etileno
WO2025006179A1 (en) 2023-06-28 2025-01-02 Dow Global Technologies Llc Trimodal ethylene-based polymers
EP4484162A1 (en) 2023-06-28 2025-01-01 Dow Global Technologies LLC Enhanced toughness for machine direction orientation of polyethylene films and the method thereof
WO2025006302A1 (en) 2023-06-28 2025-01-02 Dow Global Technologies Llc High melt strength polyethylene with an ultra-high molecular weight polyethylene component
ES2993746B2 (es) 2023-06-28 2025-10-29 Dow Global Technologies Llc Peliculas multicapa con fluencia, rasgado y dardo mejorados
AR133336A1 (es) 2023-08-01 2025-09-17 Dow Global Technologies Llc Películas multicapa que contienen reciclado posconsumo (pcr) con mayor resistencia al desgarro
WO2025049300A1 (en) 2023-08-28 2025-03-06 Dow Global Technologies Llc Polymer blends comprising trimodal ethylene-based polymers and pcr
WO2025049439A1 (en) 2023-08-28 2025-03-06 Dow Global Technologies Llc Stretch films with post consumer resins
WO2025049435A2 (en) 2023-08-28 2025-03-06 Dow Global Technologies Llc Extrusion visbreaking
WO2025049436A1 (en) 2023-08-28 2025-03-06 Dow Global Technologies Llc Recycled fibers
WO2025048998A1 (en) 2023-08-30 2025-03-06 Dow Global Technologies Llc Tape for artificial turf
WO2025049061A1 (en) 2023-09-01 2025-03-06 Dow Global Technologies Llc Polyethylene compositions and films
WO2025072154A1 (en) 2023-09-29 2025-04-03 Dow Global Technologies Llc Processes for polymerizing ethylene
WO2025072152A1 (en) 2023-09-29 2025-04-03 Dow Global Technologies Llc Process for the production of ldpe
EP4538324A1 (en) 2023-10-10 2025-04-16 Dow Global Technologies LLC Polyolefin compositions
WO2025117421A1 (en) 2023-11-30 2025-06-05 Dow Global Technologies Llc Recyclable polyolefin films and laminates
TW202523766A (zh) 2023-11-30 2025-06-16 美商陶氏全球科技有限責任公司 再循環聚烯烴膜與層壓體
EP4570497A1 (en) 2023-12-11 2025-06-18 Dow Global Technologies LLC Machine direction oriented films
WO2025128519A1 (en) 2023-12-12 2025-06-19 Dow Global Technologies Llc Polymer processing aids based on polydimethylsiloxane and polyethylene glycol
WO2025144707A1 (en) 2023-12-28 2025-07-03 Dow Global Technologies Llc Compositions including recycled ethylene-based polymers and multilayer films incorporating same
WO2025144708A1 (en) 2023-12-28 2025-07-03 Dow Global Technologies Llc Compositions including recycled ethylene-based polymers and multilayer films incorporating same
WO2025165684A1 (en) 2024-01-29 2025-08-07 Dow Global Technologies Llc Polymer processing aids comprising silicone polyethers
WO2025165636A1 (en) 2024-01-31 2025-08-07 Dow Global Technologies Llc Tie layers comprising functionalized polyethylene and multilayer structures incorporating same
EP4596232A1 (en) 2024-01-31 2025-08-06 Dow Global Technologies LLC Tie layers comprising crystalline block composite components and functionalized polyethylene and coated substrates incorporating same
WO2025165633A1 (en) 2024-01-31 2025-08-07 Dow Global Technologies Llc Tie layers comprising olefin block copolymer and multilayer films incorporating same
EP4596233A1 (en) 2024-01-31 2025-08-06 Dow Global Technologies LLC Tie layers comprising propylene-based polymers, functionalized propylene, and modifiers and coated substrates incorporating same
EP4596231A1 (en) 2024-01-31 2025-08-06 Dow Global Technologies LLC Tie layers comprising crystalline block composite components and functionalized polyethylene and multilayer films incorporating same
WO2025199093A1 (en) 2024-03-20 2025-09-25 Dow Global Technologies Llc Polymer blends including recycled ethylene-based polymers
WO2025216983A1 (en) 2024-04-08 2025-10-16 Dow Global Technologies Llc Process for the production of polyethylenes
WO2025226645A1 (en) 2024-04-26 2025-10-30 Dow Global Technologies Llc Bimodal ethylene-based polymers
WO2025226646A1 (en) 2024-04-26 2025-10-30 Dow Global Technologies Llc Bimodal ethylene-based polymers
WO2025226647A1 (en) 2024-04-26 2025-10-30 Dow Global Technologies Llc Toughened polyamides
WO2025231142A1 (en) 2024-04-30 2025-11-06 Dow Global Technologies Llc Laminate with machine direction oriented multilayer film
WO2026006044A1 (en) 2024-06-27 2026-01-02 Dow Global Technologies Llc Epoxide-functionalized polyolefins
WO2026006272A1 (en) 2024-06-28 2026-01-02 Dow Global Technologies Llc Gas phase polymerization processes for making ethylene‑based polymer using catalyst systems containing 2‑amino‑thiazoles
WO2026006156A1 (en) 2024-06-28 2026-01-02 Dow Global Technologies Llc Slurry phase polymerization processes for making ethylene-based polymer using catalyst systems containing 2-amino-thiazoles
WO2026006263A1 (en) 2024-06-28 2026-01-02 Dow Global Technologies Llc Gas phase polymerization processes for making ethylene-based polymer using catalyst systems having improved light off
WO2026006157A1 (en) 2024-06-28 2026-01-02 Dow Global Technologies Llc Ethylene-based polymer produced from 2-amino-thiazole based procatalysts
WO2026005992A1 (en) 2024-06-28 2026-01-02 Dow Global Technologies Llc Ethylene-based polymer produced from heteroleptic 2-amino-imidazole based procatalysts
WO2026006270A1 (en) 2024-06-28 2026-01-02 Dow Global Technologies Llc Gas phase polymerization processes for making ethylene-based polymer having ultra-high molecular weight tailing
WO2026005997A1 (en) 2024-06-28 2026-01-02 Dow Global Technologies Llc Gas phase polymerization processes for making ethylene‑based polymer using catalyst systems having improved light off
WO2026006269A1 (en) 2024-06-28 2026-01-02 Dow Global Technologies Llc Slurry phase polymerization processes for making ethylene-based polymer using catalyst systems containing amino-imidazoles
WO2026005993A1 (en) 2024-06-28 2026-01-02 Dow Global Technologies Llc Gas phase polymerization processes for making ethylene-based polymer using catalyst systems containing 2-amino-imidazoles
WO2026006267A1 (en) 2024-06-28 2026-01-02 Dow Global Technologies Llc Gas phase polymerization processes for making ethylene-based polymer having ultra-high molecular weight tailing

Family Cites Families (191)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US64802A (en) * 1867-05-14 Improvement in gates
USB632416I5 (OSRAM) 1956-03-01 1976-03-09
US3491073A (en) * 1965-08-13 1970-01-20 Dow Chemical Co Process for the polymerization of olefins
CA849081A (en) * 1967-03-02 1970-08-11 Du Pont Of Canada Limited PRODUCTION OF ETHYLENE/.alpha.-OLEFIN COPOLYMERS OF IMPROVED PHYSICAL PROPERTIES
US3485706A (en) 1968-01-18 1969-12-23 Du Pont Textile-like patterned nonwoven fabrics and their production
GB1379853A (en) * 1971-02-17 1975-01-08 Snam Progetti Polyethylenes and a process for the production of the same
US3914342A (en) 1971-07-13 1975-10-21 Dow Chemical Co Ethylene polymer blend and polymerization process for preparation thereof
DE2431353C3 (de) 1974-06-29 1980-07-10 Chemische Werke Huels Ag, 4370 Marl Verfahren zur Herstellung von kristallinen Terpolymeren aus Athen, Buten-1 und Buten - 2
JPS5952643B2 (ja) * 1977-01-27 1984-12-20 三井化学株式会社 エチレン共重合体
US4302566A (en) 1978-03-31 1981-11-24 Union Carbide Corporation Preparation of ethylene copolymers in fluid bed reactor
US4390677A (en) 1978-03-31 1983-06-28 Karol Frederick J Article molded from ethylene hydrocarbon copolymer
IT1110494B (it) * 1978-08-02 1985-12-23 Montedison Spa Polimeri dell etilene e procedimento per la loro preparazione
US4303710A (en) 1978-08-16 1981-12-01 Mobil Oil Corporation Coextruded multi-layer polyethylene film and bag construction
JPS5948046B2 (ja) 1978-08-17 1984-11-24 三井化学株式会社 エチレン共重合ゴム
US4399180A (en) 1978-09-15 1983-08-16 Mobil Oil Corporation Coextruded thermoplastic stretch-wrap
JPS6011925B2 (ja) 1978-10-18 1985-03-29 三井化学株式会社 エチレン共重合体の製造方法
JPS603323B2 (ja) 1978-12-11 1985-01-28 三井化学株式会社 オレフイン類の重合方法
US4303771A (en) 1978-12-14 1981-12-01 Union Carbide Corporation Process for the preparation of high density ethylene polymers in fluid bed reactor
US4383095A (en) 1979-02-16 1983-05-10 Union Carbide Corporation Process for the preparation of high density ethylene polymers in fluid bed reactor
GB2047254B (en) 1979-04-13 1983-03-09 Mitsui Petrochemical Ind Rubbery ethylene/1-butene/polyene copolymers and process for production thereof
US4363904A (en) 1979-06-18 1982-12-14 Union Carbide Corporation High tear strength polymers
US4359561A (en) 1979-06-18 1982-11-16 Union Carbide Corporation High tear strength polymers
JPS5628826A (en) 1979-08-20 1981-03-23 Kohjin Co Ltd Thermoshrinking film and manufacturing thereof
US4467065A (en) 1979-09-10 1984-08-21 Becton Dickinson And Company Semi-crystalline polymers stabilized for irradiation sterilization
US4340641A (en) 1979-10-05 1982-07-20 Mobil Oil Corporation Heat sealable packaging film comprising propylene polymer substrate and a surface layer blend of ethylene copolymer and propylene copolymer
US4340640A (en) 1979-10-05 1982-07-20 Mobil Oil Corporation Heat sealable packaging film comprising propylene polymer substrate and a surface layer blend of ethylene copolymer and propylene copolymer
US4339496A (en) 1979-10-05 1982-07-13 Mobil Oil Corporation Heat sealable packaging film comprising propylene polymer substrate and a surface layer blend of ethylene copolymer and propylene copolymer
US4339493A (en) 1979-10-05 1982-07-13 Mobil Oil Corporation Heat sealable packaging film comprising propylene polymer substrate and olefin surface layer blend of polybutene-1 and an ethylene or a propylene copolymer
US4482687A (en) 1979-10-26 1984-11-13 Union Carbide Corporation Preparation of low-density ethylene copolymers in fluid bed reactor
EP0037182B2 (en) 1980-03-24 1991-06-12 Imperial Chemical Industries Plc Preparation of a dried transition metal product
US4340563A (en) 1980-05-05 1982-07-20 Kimberly-Clark Corporation Method for forming nonwoven webs
WO1982001173A1 (en) * 1980-09-25 1982-04-15 Marine Prod Inc Meacham Disappearing cleat or fitting
US4322027A (en) 1980-10-02 1982-03-30 Crown Zellerbach Corporation Filament draw nozzle
JPS5764551A (en) 1980-10-09 1982-04-19 Mitsui Petrochemical Ind Composite film
US4346834A (en) 1980-11-18 1982-08-31 Mobil Oil Corporation Thermoplastic carrying bag with polyolefin resin blend
JPS57105411A (en) * 1980-12-23 1982-06-30 Mitsubishi Petrochem Co Ltd Ethylenic copolymer
US4597920A (en) 1981-04-23 1986-07-01 E. I. Du Pont De Nemours And Company Shrink films of ethylene/α-olefin copolymers
US4413110A (en) 1981-04-30 1983-11-01 Allied Corporation High tenacity, high modulus polyethylene and polypropylene fibers and intermediates therefore
US4367256A (en) 1981-05-15 1983-01-04 Union Carbide Corporation Cling-wrap polyethylene film
FR2509742B1 (OSRAM) 1981-07-15 1985-11-15 Charbonnages Ste Chimique
US4354009A (en) 1981-07-30 1982-10-12 Union Carbide Corporation Catalyst composition for copolymerizing ethylene
US4349648A (en) 1981-07-31 1982-09-14 Union Carbide Corporation Catalyst composition for copolymerizing ethylene
US4427573A (en) 1981-09-16 1984-01-24 Union Carbide Corporation Polymerization catalyst, process for preparing, and use for ethylene polymerization
DE3141770A1 (de) 1981-10-21 1983-05-05 Linde Ag, 6200 Wiesbaden Verfahren und vorrichtung zur regenerierung von physikalisch wirkenden organischen waschfluessigkeiten
US4464426A (en) 1981-11-03 1984-08-07 Union Carbide Corporation Multilayer film having a layer of low pressure, low density heterogeneous ethylene copolymers
US4513038A (en) 1981-11-03 1985-04-23 Union Carbide Corporation Multilayer film having a layer of low pressure, low density heterogeneous ethylene copolymers
US4370456A (en) 1981-11-23 1983-01-25 Union Carbide Corporation Catalyst composition for copolymerizing ethylene
US4379197A (en) 1981-12-02 1983-04-05 El Paso Polyolefins Company Stretch wrap film composition
US5025072A (en) 1981-12-04 1991-06-18 Mobil Oil Corporation Highly active catalyst composition for polymerizing alpha-olefins
FR2519007B1 (fr) 1981-12-24 1985-12-27 Charbonnages Ste Chimique Copolymeres modifies de l'ethylene et d'au moins une a-olefine et procede pour leur preparation
US4452958A (en) 1981-12-30 1984-06-05 Mobil Oil Corporation Olefin polymerization with catalysts derived from chromium exchanged zeolites
US4532189A (en) 1982-02-19 1985-07-30 W. R. Grace & Co., Cryovac Div. Linear polyethylene shrink films
DE3243612A1 (de) 1982-02-20 1983-11-03 Chemische Werke Hüls AG, 4370 Marl Verfahren zur herstellung von masshaltigen hohlprofilen aus aliphatischen polyamiden und deren verwendung
US4803253A (en) 1982-03-30 1989-02-07 Phillips Petroleum Company Ethylene polymer produced using a catalyst comprising a phosphate and with a bis-(cyclopentadienyl)chromium(II) compound
US4410649A (en) 1982-03-31 1983-10-18 Union Carbide Corporation Ethylene polymer compositions having improved transparency
US4418114A (en) 1982-04-29 1983-11-29 Mobil Oil Corporation Coextruded thermoplastic stretch-wrap
JPS58191705A (ja) * 1982-05-06 1983-11-09 Mitsui Petrochem Ind Ltd エチレン共重合ゴム
US4461873A (en) * 1982-06-22 1984-07-24 Phillips Petroleum Company Ethylene polymer blends
FR2529563B1 (fr) 1982-06-30 1986-01-24 Charbonnages Ste Chimique Compositions de polypropylene et de copolymeres ethylene/a-olefine et leur application a la fabrication de fils mono-orientes
FR2532649B1 (fr) * 1982-09-07 1986-08-29 Bp Chimie Sa Copolymerisation d'ethylene et d'hexene-1 en lit fluidise
US4588650A (en) 1982-09-29 1986-05-13 The Dow Chemical Company Olefin polymer stretch/cling film
US4505970A (en) 1982-09-30 1985-03-19 Union Carbide Corporation Multilayer films comprising mixtures of a melt index and 2 melt index linear low density polyethylene
US4461792A (en) 1982-09-30 1984-07-24 Union Carbide Corporation Poly-1-butene multilayers plastic film
DE3240383A1 (de) 1982-11-02 1984-05-03 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von oligomeren aluminoxanen
US4454281A (en) 1982-12-01 1984-06-12 Union Carbide Corporation Formulation for high clarity linear low density polyethylene film products
US4598128A (en) 1983-03-14 1986-07-01 Phillips Petroleum Company Polymer composition and preparation method
US4485217A (en) 1983-04-13 1984-11-27 Mobil Oil Corporation Method for reducing shrinkage of injection molded linear low density polyethylene
US4500648A (en) 1983-04-25 1985-02-19 Exxon Research & Engineering Co. Long chain branching in polyolefins from ziegler-natta catalysts
JPS59204605A (ja) 1983-05-09 1984-11-20 Mitsubishi Petrochem Co Ltd エチレンの重合法
US4937299A (en) * 1983-06-06 1990-06-26 Exxon Research & Engineering Company Process and catalyst for producing reactor blend polyolefins
US4530914A (en) * 1983-06-06 1985-07-23 Exxon Research & Engineering Co. Process and catalyst for producing polyethylene having a broad molecular weight distribution
US4935474A (en) * 1983-06-06 1990-06-19 Exxon Research & Engineering Company Process and catalyst for producing polyethylene having a broad molecular weight distribution
US5013801A (en) 1983-06-15 1991-05-07 Charles Cozewith Molecular weight distribution modification in a tubular reactor
US4792595A (en) 1983-06-15 1988-12-20 Exxon Research & Engineering Co. Narrow MWD alpha-olefin copolymers
US4789714A (en) 1983-06-15 1988-12-06 Exxon Research & Engineering Co. Molecular weight distribution modification in tubular reactor
US4716207A (en) 1983-06-15 1987-12-29 Exxon Research & Engineering Co. Nodular copolymers comprising narrow MWD alpha-olefin copolymers coupled by non-conjugated dienes
US4540753A (en) 1983-06-15 1985-09-10 Exxon Research & Engineering Co. Narrow MWD alpha-olefin copolymers
US4882406A (en) 1983-06-15 1989-11-21 Exxon Research & Engineering Company Nodular copolymers formed of alpha-olefin copolymers coupled by non-conjugated dienes
US4959436A (en) 1983-06-15 1990-09-25 Exxon Research And Engineering Co. Narrow MWD alpha-olefin copolymers
FI68632C (fi) 1983-06-22 1985-10-10 Neste Oy Foerfarande foer framstaellning av sampolymerer av eten och langkedjade alfa-olefiner
US4547555A (en) 1983-09-01 1985-10-15 Mobil Oil Corporation Method for rapid kill gas injection to gas phase polymerization reactors during power failures
US4666999A (en) 1983-09-01 1987-05-19 Mobil Oil Corporation Method and reactor system for rapid kill gas injection to gas phase polymerization reactors
US4834947A (en) 1983-09-01 1989-05-30 Mobil Oil Corporation Reactor system for rapid kill gas injection to gas phase polymerization reactors
JPS6088016A (ja) * 1983-10-21 1985-05-17 Mitsui Petrochem Ind Ltd エチレン共重合体
US4808635A (en) 1983-11-22 1989-02-28 Hercules Incorporated Method for making a dicyclopentadiene cross-linked polymer and the product thereof
JPS60133042A (ja) 1983-12-20 1985-07-16 Nippon Petrochem Co Ltd 電気絶縁用樹脂組成物
US4617241A (en) 1984-01-23 1986-10-14 W. R. Grace & Co., Cryovac Div. Linear polyethylene stretch/shrink films
JPS60158237A (ja) 1984-01-27 1985-08-19 Nippon Petrochem Co Ltd 回転成形用エチレン共重合体組成物
US4690992A (en) 1984-03-28 1987-09-01 California Institute Of Technology Polymerization of difunctional ring compounds
US4593009A (en) 1984-04-04 1986-06-03 Mobil Oil Corporation Catalyst composition for polymerizing alpha-olefins
US4672096A (en) 1984-04-04 1987-06-09 Mobil Oil Corporation Catalyst composition for polymerizing alpha-olefins
US4649001A (en) 1984-04-17 1987-03-10 Japan Styrene Paper Corporation Process for producing polyethylene extruded foams
US4618662A (en) 1984-04-23 1986-10-21 Mobil Oil Corporation Catalyst composition for polymerizing alpha-olefins
FR2563833B1 (fr) 1984-05-02 1986-09-05 Bp Chimie Sa Procede de copolymerisation en lit fluidise d'ethylene, de propylene et/ou de butene-1 et d'alpha-olefines contenant de 5 a 8 atomes de carbone
US4551380A (en) 1984-05-10 1985-11-05 W. R. Grace & Co., Cryovac Div. Oriented heat-sealable multilayer packaging film
US4568713A (en) 1984-05-30 1986-02-04 Shell Oil Company Hot melt poly(butylene/ethylene) adhesives
US4514465A (en) 1984-05-30 1985-04-30 W. R. Grace & Co., Cryovac Div. Storm window film comprising at least five layers
FR2566781B1 (fr) 1984-06-28 1986-11-14 Bp Chimie Sa Procede de polymerisation ou de copolymerisation d'alpha-olefines en lit fluidise, en presence d'un systeme catalytique ziegler-natta
US4764549A (en) 1984-09-07 1988-08-16 Vulkor, Incorporated Low temperature curing of elastomer
US4613547A (en) 1984-12-19 1986-09-23 Mobil Oil Corporation Multi-layer oriented polypropylene films
US4564559A (en) 1984-12-28 1986-01-14 Mobil Oil Corporation Oriented multi-layer heat sealable film
DE3682928D1 (de) 1985-03-08 1992-01-30 Mitsubishi Petrochemical Co Verfahren zum polymerisieren von aethylen.
US4788232A (en) 1985-03-11 1988-11-29 Phillips Petroleum Company Pigment concentrates for resins
CA1263498A (en) 1985-03-26 1989-11-28 Mitsui Chemicals, Incorporated Liquid ethylene-type random copolymer, process for production thereof, and use thereof
DE3517081A1 (de) 1985-05-11 1986-11-13 Wolff Walsrode Ag, 3030 Walsrode Opake, siegelbare mehrschichtfolien aus polyolefinen
DE3517082A1 (de) 1985-05-11 1986-11-13 Wolff Walsrode Ag, 3030 Walsrode Siegelbare mehrschichtfolien aus polyolefinen
JPH0615227B2 (ja) 1985-06-05 1994-03-02 出光石油化学株式会社 樹脂積層体
DE3520944A1 (de) 1985-06-12 1986-12-18 Wolff Walsrode Ag, 3030 Walsrode Siegelbare mehrschichtenfolien mit geringer gasdurchlaessigkeit und ihre verwendung als verpackungsmaterial
US4976898A (en) 1985-06-17 1990-12-11 Viskase Corporation Process for making puncture resistant, heat-shrinkable films containing very low density polyethylene
US5059481A (en) 1985-06-17 1991-10-22 Viskase Corporation Biaxially stretched, heat shrinkable VLDPE film
US4663220A (en) 1985-07-30 1987-05-05 Kimberly-Clark Corporation Polyolefin-containing extrudable compositions and methods for their formation into elastomeric products including microfibers
US4722971A (en) 1985-08-02 1988-02-02 Exxon Chemical Patents Inc. Easy processing ethylene propylene elastomers
US4668566A (en) 1985-10-07 1987-05-26 Kimberly-Clark Corporation Multilayer nonwoven fabric made with poly-propylene and polyethylene
US4720427A (en) 1985-10-28 1988-01-19 Mobil Oil Corporation Oriented multi-layer heat sealable film
US4798081A (en) 1985-11-27 1989-01-17 The Dow Chemical Company High temperature continuous viscometry coupled with analytic temperature rising elution fractionation for evaluating crystalline and semi-crystalline polymers
US4892911A (en) 1985-11-29 1990-01-09 American National Can Company Films using blends of polypropylene and polyisobutylene
US5073599A (en) 1985-11-29 1991-12-17 American National Can Company Films using blends of polypropylene and polyisobutylene
US4775710A (en) 1985-12-12 1988-10-04 Mallinckrodt, Inc. Stabilized linear low-density polyethylene containing ring-substituted N-acyl-para-aminophenol
US4626467A (en) 1985-12-16 1986-12-02 Hercules Incorporated Branched polyolefin as a quench control agent for spin melt compositions
US4668650A (en) 1986-01-03 1987-05-26 Mobil Oil Corporation Catalyst composition for polymerizing alpha-olefin polymers of relatively narrow molecular weight distribution
US4876321A (en) 1986-01-03 1989-10-24 Mobil Oil Corporation Preparation of alpha-olefin polymers of relatively narrow molecular weight distribution
US4677087A (en) 1986-01-03 1987-06-30 Mobil Oil Corporation Catalyst composition for polymerizing alpha-olefin polymers of relatively narrow molecular weight distribution
USRE33683E (en) 1986-01-24 1991-09-03 Mobil Oil Corporation Catalyst composition for polymerizing alpha-olefins
US4888318A (en) 1986-01-24 1989-12-19 Mobil Oil Corporation Catalyst composition for polymerizing alpha-olefins
US4732882A (en) 1986-01-24 1988-03-22 Mobil Oil Corporation Catalyst composition for polymerizing alpha-olefins
US5055533A (en) 1986-01-24 1991-10-08 Mobil Oil Corporation Process for polymerizing alpha-olefins with trimethylaluminum-activated catalyst
US4710538A (en) 1986-03-10 1987-12-01 Union Carbide Corporation Process for the production of a sticky polymer
DE3611341A1 (de) 1986-04-04 1987-10-08 Hoechst Ag Opake folie fuer den bonbondreheinschlag
US4676922A (en) 1986-04-04 1987-06-30 Gencorp Inc. Preblends
DE3621394A1 (de) 1986-06-26 1988-01-14 Ruhrchemie Ag Mischpolymerisate des ethylens, verfahren zu ihrer herstellung und ihre verwendung
DE3624543A1 (de) 1986-07-19 1988-01-21 Wolff Walsrode Ag Heisssiegelbare mehrschichtfolien aus polyolefinen
DE3631231A1 (de) 1986-09-13 1988-03-24 Hoechst Ag Bedruckbare und beidseitig siegelbare, biaxial orientierte opake polyolefin-mehrschichtfolie, ihre herstellung und ihre verwendung
DE3631232A1 (de) 1986-09-13 1988-03-24 Hoechst Ag Mehrschichtfolie als trennfolie zur herstellung dekorativer schichtstoffplatten
US4719193A (en) 1986-09-30 1988-01-12 Union Carbide Corporation Processes for preparing polyethylene catalysts by heating catalyst precursors
US4820589A (en) 1986-11-17 1989-04-11 Mobil Oil Corporation Cling/no cling-slip stretch wrap film
IL84642A0 (en) * 1986-12-19 1988-04-29 Exxon Chemical Patents Inc Ethylene copolymers and their preparation
US5055438A (en) * 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
US5096867A (en) * 1990-06-04 1992-03-17 Exxon Chemical Patents Inc. Monocyclopentadienyl transition metal olefin polymerization catalysts
US5055338A (en) 1987-03-11 1991-10-08 Exxon Chemical Patents Inc. Metallized breathable films prepared from melt embossed polyolefin/filler precursor films
DE3709252A1 (de) 1987-03-20 1988-09-29 Hoechst Ag Metallisierbare mehrschichtfolie, ihre herstellung und ihre verwendung
US5084039A (en) 1987-03-27 1992-01-28 Clopay Corporation Disposable diapers, absorbent articles and thermoplastic sheet material having improving tape adhesion
US4963388A (en) 1987-04-17 1990-10-16 Mobil Oil Corporation Method for forming particle-impregnated one-sided cling stretch wrap film
US4833017A (en) 1987-04-17 1989-05-23 Mobil Oil Corporation Particle-impregnated one-sided cling stretch wrap film
US4780264A (en) 1987-05-22 1988-10-25 The Dow Chemical Company Linear low density polyethylene cast film
US4826939A (en) 1987-08-31 1989-05-02 Eastman Kodak Company Highly amorphous olefin terpolymer
US5015749A (en) 1987-08-31 1991-05-14 The Dow Chemical Company Preparation of polyhydrocarbyl-aluminoxanes
JPS6468512A (en) 1987-09-05 1989-03-14 Mitsui Petrochemical Ind Molecular oriented formed article of ethylene-polyene copolymer having ultra-high molecular weight
US5024799A (en) 1987-09-14 1991-06-18 Tredegar Industries, Inc. Method for producing an embossed oriented film
US4824889A (en) 1987-10-30 1989-04-25 Shell Oil Company Poly-1-butene blend adhesives
US4830926A (en) 1987-10-30 1989-05-16 Shell Oil Company Poly-1-butene blend adhesives for laminar structure
US4923750A (en) 1987-12-30 1990-05-08 Co-Ex Plastics, Inc. Thermoplastic stretch-wrap material
US5015511A (en) 1988-05-12 1991-05-14 The Dow Chemical Company Linear low density ethylene interpolymers for injection molding
CA1326733C (en) 1988-06-08 1994-02-01 Sumitomo Chemical Co., Ltd. Ethylene-.alpha.-olefin copolymer and process for producing the same
CH675714A5 (OSRAM) 1988-06-14 1990-10-31 Fael Sa
US5229478A (en) * 1988-06-16 1993-07-20 Exxon Chemical Patents Inc. Process for production of high molecular weight EPDM elastomers using a metallocene-alumoxane catalyst system
US5006396A (en) 1988-07-25 1991-04-09 Xerox Corporation Moisture proof thermally actuated binding tape for books
US4966951A (en) 1988-09-26 1990-10-30 Phillips Petroleum Company High strength linear, low density polyethylene polymerization process
US4996094A (en) 1988-09-26 1991-02-26 Mobil Oil Corporation One-sided cling/one-sided slip stretch wrap films
ATE154060T1 (de) * 1988-09-30 1997-06-15 Exxon Chemical Patents Inc Lineare ethylen-copolymermischungen von copolymeren mit engen molekulargewichts- und kompositionsverteilungen
US5382630A (en) 1988-09-30 1995-01-17 Exxon Chemical Patents Inc. Linear ethylene interpolymer blends of interpolymers having narrow molecular weight and composition distribution
US5382631A (en) 1988-09-30 1995-01-17 Exxon Chemical Patents Inc. Linear ethylene interpolymer blends of interpolymers having narrow molecular weight and composition distributions
US5019315A (en) 1988-10-25 1991-05-28 Mobil Oil Corporation Preparing multi-layer coextruded polyolefin stretch wrap films
US5047468A (en) 1988-11-16 1991-09-10 Union Carbide Chemicals And Plastics Technology Corporation Process for the in situ blending of polymers
GB2227448B (en) 1988-11-18 1992-09-30 Grace W R & Co Multi-layer film structure for packaging and bags made therefrom
US4960878A (en) 1988-12-02 1990-10-02 Texas Alkyls, Inc. Synthesis of methylaluminoxanes
US5086024A (en) 1988-12-02 1992-02-04 Texas Alkyls, Inc. Catalyst system for polymerization of olefins
US5041584A (en) 1988-12-02 1991-08-20 Texas Alkyls, Inc. Modified methylaluminoxane
EP0955321A3 (en) * 1988-12-26 1999-12-08 Mitsui Chemicals, Inc. Olefin copolymers and processes for preparing same
ATE166890T1 (de) * 1988-12-26 1998-06-15 Mitsui Chemicals Inc Olefin-kopolymer und verfahren zur herstellung
US5218071A (en) 1988-12-26 1993-06-08 Mitsui Petrochemical Industries, Ltd. Ethylene random copolymers
CA2008315C (en) 1989-01-24 1995-03-21 Toshiyuki Tsutsui Olefin copolymers and processes for preparing same
JPH0373341A (ja) 1989-05-09 1991-03-28 Toray Ind Inc 熱圧着プリントラミネート用フィルム
US5043040A (en) 1989-08-30 1991-08-27 Borden, Inc. Slitting of plastic film
NZ235032A (en) * 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5026798A (en) * 1989-09-13 1991-06-25 Exxon Chemical Patents Inc. Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
US4981826A (en) 1989-11-17 1991-01-01 Exxon Chemical Patents Inc. Polymerization catalyst prepared with a halogenated silane compound
US5055534A (en) 1989-12-28 1991-10-08 Union Carbide Chemicals And Plastics Technology Corporation Preparation of very low molecular weight polyethylene in a fluidized bed
US5068489A (en) 1989-12-28 1991-11-26 Union Carbide Chemicals And Plastics Technology Corporation Preparation of very low molecular weight polyethylene in a fluidized bed
US5041585A (en) 1990-06-08 1991-08-20 Texas Alkyls, Inc. Preparation of aluminoxanes
US5041583A (en) 1990-06-28 1991-08-20 Ethyl Corporation Preparation of aluminoxanes
US5272236A (en) 1991-10-15 1993-12-21 The Dow Chemical Company Elastic substantially linear olefin polymers
US5064796A (en) 1991-01-07 1991-11-12 Exxon Chemical Patents Inc. Support adjuvant for improved vanadium polymerization catalyst
US5084927A (en) 1991-02-08 1992-02-04 Tan Sense Medical Corp. Method for protecting a surface from contaminants
JP3275211B2 (ja) 1991-05-20 2002-04-15 ザ ダウ ケミカル カンパニー 付加重合触媒の製造方法
US5278272A (en) * 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers
US5783638A (en) * 1991-10-15 1998-07-21 The Dow Chemical Company Elastic substantially linear ethylene polymers
US5393599A (en) 1992-01-24 1995-02-28 Fiberweb North America, Inc. Composite nonwoven fabrics
US5334446A (en) 1992-01-24 1994-08-02 Fiberweb North America, Inc. Composite elastic nonwoven fabric
US5322728A (en) 1992-11-24 1994-06-21 Exxon Chemical Patents, Inc. Fibers of polyolefin polymers
US5542199A (en) 1995-07-19 1996-08-06 Hoffman/New Yorker, Inc. Garment pressing apparatus with garment end rotator

Cited By (337)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6121395A (en) * 1987-01-30 2000-09-19 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5621126A (en) * 1987-01-30 1997-04-15 Exxon Chemical Patents Inc. Monocyclopentadienyl metal compounds for ethylene-α-olefin-copolymer production catalysts
US5599761A (en) * 1987-01-30 1997-02-04 Exxon Chemical Patents, Inc. Ionic metallocene catalyst compositions
US6423795B1 (en) 1987-01-30 2002-07-23 Exxonmobil Chemical Patents Inc. Tetramethylcyclopentadienyl titanium compounds for ethylene-α-olefin-copolymer production catalysts
US5408017A (en) * 1987-01-30 1995-04-18 Exxon Chemical Patents Inc. High temperature polymerization process using ionic catalysts to produce polyolefins
US5470927A (en) * 1987-01-30 1995-11-28 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
USRE37788E1 (en) * 1987-01-30 2002-07-09 Exxon Chemical Patents, Inc. Monocyclopentadienyl metal compounds for ethylene-α-olefin-copolymer production catalysts
US5589561A (en) * 1989-06-27 1996-12-31 The Dow Chemical Company Bioriented blown film
US6632898B1 (en) 1989-09-13 2003-10-14 Exxonmobil Chemical Patents Inc. Monocyclopentadienyl titanium metal compounds for ethylene-α-olefin-copolymer production catalysts
US5631391A (en) * 1989-09-13 1997-05-20 Canich; Jo Ann M. Monocyclopentadienyl titanium metal compounds for ethylene-α-olefin-copolymer production catalysts
USRE37400E1 (en) * 1989-09-13 2001-10-02 Exxon Chemical Patents Inc. Monocyclopentadienyl titanium metal compounds for ethylene-α-olefin-copolymer production catalysts
US6060567A (en) * 1991-10-15 2000-05-09 The Dow Chemical Company Interpolymers formed by continuous processes
US6448355B1 (en) 1991-10-15 2002-09-10 The Dow Chemical Company Elastic fibers, fabrics and articles fabricated therefrom
US6111023A (en) * 1991-10-15 2000-08-29 The Dow Chemical Company Fabricated articles made from ethylene polymer blends
US5562958A (en) * 1991-10-15 1996-10-08 The Dow Chemical Company Packaging and wrapping film
US6140442A (en) * 1991-10-15 2000-10-31 The Dow Chemical Company Elastic fibers, fabrics and articles fabricated therefrom
US5847053A (en) * 1991-10-15 1998-12-08 The Dow Chemical Company Ethylene polymer film made from ethylene polymer blends
US5677383A (en) * 1991-10-15 1997-10-14 The Dow Chemical Company Fabricated articles made from ethylene polymer blends
US6436534B1 (en) 1991-10-15 2002-08-20 The Dow Chemical Company Elastic fibers, fabrics and articles fabricated therefrom
US6316549B1 (en) 1991-10-15 2001-11-13 The Dow Chemical Company Ethylene polymer fiber made from ethylene polymer blends
US5475075A (en) * 1991-12-13 1995-12-12 Exxon Chemical Patents Inc. Ethylene/longer α-olefin copolymers
US6545088B1 (en) 1991-12-30 2003-04-08 Dow Global Technologies Inc. Metallocene-catalyzed process for the manufacture of EP and EPDM polymers
US6384158B1 (en) 1992-04-09 2002-05-07 Exxonmobil Chemical Patents Inc. Polymerization catalysts, their production and use
US6136930A (en) * 1992-04-09 2000-10-24 Exxon Chemical Patents, Inc. Polymerization catalysts, their production and use
US6518215B1 (en) 1992-04-09 2003-02-11 Exxonmobil Chemical Patents Inc. Polymerization catalysts, their production and use
US6608000B1 (en) 1992-04-09 2003-08-19 Exxonmobil Chemical Patents Inc. Polymerization catalysts, their production and use
WO1993025590A1 (en) * 1992-06-15 1993-12-23 Exxon Chemical Patents Inc. High temperature polymerization process using ionic catalysts to produce polyolefins
WO1994009060A1 (en) * 1992-10-14 1994-04-28 The Dow Chemical Company Film for packaging purposes
US6514583B1 (en) 1992-11-13 2003-02-04 Cryovac, Inc. High impact strength film containing single site catalyzed copolymer
US5705577A (en) * 1992-12-17 1998-01-06 Exxon Chemical Patents Inc. Dilute process for the polymerization of ethylene/α-olefin copolymer using metallocene catalyst systems
WO1994013715A1 (en) * 1992-12-17 1994-06-23 Exxon Chemical Patents Inc. Dilute process for the preparation of ethylene/alpha-olefin copolymer using metallocene catalyst systems
US5859159A (en) * 1992-12-17 1999-01-12 Exxon Chemical Patents Inc. Dilute process for the polymerization of non-ethylene α-olefin homopolymers and copolymers using metallocene catalyst systems
US5629059A (en) * 1992-12-18 1997-05-13 W.R. Grace & Co.-Conn. Multi-layer packaging film and receptacles made therefrom
WO1994017112A3 (en) * 1993-01-29 1994-09-15 Dow Chemical Co Ethylene interpolymerizations
EP1044995A1 (en) * 1993-01-29 2000-10-18 The Dow Chemical Company Ethylene interpolymerizations
AU688308B2 (en) * 1993-01-29 1998-03-12 Dow Chemical Company, The Ethylene interpolymerizations
US5844045A (en) * 1993-01-29 1998-12-01 The Dow Chemical Company Ethylene interpolymerizations
US6121402A (en) * 1993-02-05 2000-09-19 Idemitsu Kosan Co., Ltd. Polyethylene, thermoplastic resin composition containing same, and process for preparing polyethylene
EP0683184A4 (en) * 1993-02-05 1997-08-20 Idemitsu Kosan Co POLYETHYLENE, THERMOPLASTIC RESIN COMPOSITION CONTAINING THE SAME AND METHOD FOR PRODUCING POLYETHYLENE.
US5747620A (en) * 1993-02-22 1998-05-05 Idemitsu Kosan Co., Ltd. Ethylene copolymer, thermoplastic resin composition containing same, and process for preparing ethylene copolymer
EP0690079A4 (en) * 1993-02-22 1997-08-20 Idemitsu Kosan Co ETHYLENE COPOLYMER, THERMOPLASTIC RESIN COMPOSITION CONTAINING THIS AND METHOD FOR THE PRODUCTION THEREOF
WO1994025647A1 (en) * 1993-04-27 1994-11-10 The Dow Chemical Company Elastic fibers, fabrics and articles fabricated therefrom
EP0696302B2 (en) † 1993-04-28 2001-06-27 The Dow Chemical Company Paintable olefinic interpolymer compositions
EP0705849B2 (en) † 1993-06-15 2004-06-16 Idemitsu Kosan Company Limited Process for producing olefin polymer and catalyst for olefin polymerization
WO1995000587A1 (en) * 1993-06-24 1995-01-05 The Dow Chemical Company Pouch for packaging flowable materials
EP0706455A4 (en) * 1993-06-24 1997-02-26 American National Can Co IMPROVED STRUCTURES OF POLYMERS PRODUCED USING SINGLE SITE CATALYSTS
US5508051A (en) * 1993-06-24 1996-04-16 The Dow Chemical Company Process of preparing a pouch for packaging flowable materials
WO1995001250A1 (en) * 1993-06-29 1995-01-12 The Dow Chemical Company High drawdown extrusion process
JP3414739B2 (ja) 1993-08-17 2003-06-09 ザ・ダウ・ケミカル・カンパニー 弾性材料およびこれから作られる製品
WO1995005418A1 (en) * 1993-08-17 1995-02-23 The Dow Chemical Company Elastic materials and articles therefrom
US5472775A (en) * 1993-08-17 1995-12-05 The Dow Chemical Company Elastic materials and articles therefrom
WO1995005427A1 (en) * 1993-08-18 1995-02-23 The Dow Chemical Company Gaskets made from homogeneous linear olefin polymers
US5929128A (en) * 1993-08-18 1999-07-27 The Dow Chemical Company Gaskets made from olefin polymers
US6235822B1 (en) 1993-08-18 2001-05-22 The Dow Chemical Company Gaskets made from olefin polymers
WO1995005426A1 (en) * 1993-08-18 1995-02-23 The Dow Chemical Company Gaskets made from elastic substantially linear olefin polymers
US5525659A (en) * 1993-09-08 1996-06-11 The Dow Chemical Company Batch inclusion packages
US5580914A (en) * 1993-09-08 1996-12-03 The Dow Chemical Company Batch inclusion packages
US5674944A (en) * 1993-09-08 1997-10-07 The Dow Chemical Company Batch inclusion packages
WO1995007314A1 (en) * 1993-09-08 1995-03-16 The Dow Chemical Company Batch inclusion packages
WO1995007942A1 (en) * 1993-09-17 1995-03-23 The Dow Chemical Company Gas phase polymerization of olefins
CN1043648C (zh) * 1993-09-17 1999-06-16 陶氏化学公司 烯烃的气相聚合法
AU686670B2 (en) * 1993-09-17 1998-02-12 Bp Chemicals Limited Gas phase polymerization of olefins
KR100350544B1 (ko) * 1993-09-17 2003-01-24 비피 케미칼즈 리미티드 올레핀의기상중합
WO1995007939A1 (en) 1993-09-17 1995-03-23 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
US5604043A (en) * 1993-09-20 1997-02-18 W.R. Grace & Co.-Conn. Heat shrinkable films containing single site catalyzed copolymers having long chain branching
EP0600425A1 (en) 1993-09-20 1994-06-08 W.R. Grace & Co.-Conn. Heat shrinkable films containing single site catalyzed copolymers having long chain branching
WO1995008441A1 (en) * 1993-09-20 1995-03-30 W.R. Grace & Co.-Conn. Heat shrinkable films containing single site catalyzed copolymers having long chain branching
WO1995010566A1 (en) * 1993-10-14 1995-04-20 Dupont Canada Inc. Pouches of ethylene copolymer film containing a flowable material
US5955557A (en) * 1993-10-26 1999-09-21 Idemitsu Kosan Co., Ltd. Branched ethylenic macromonomer and its polymer
US6169154B1 (en) 1993-10-26 2001-01-02 Idemitsu Kosan Co., Ltd. Branched ethylenic macromonomer and its polymer
EP0727446A4 (en) * 1993-10-26 1998-02-11 Idemitsu Kosan Co BRANCHED ETHYLENIC MACROMONOMER AND POLYMER PRODUCED THEREFROM
EP0650971A1 (en) * 1993-11-01 1995-05-03 Albemarle Corporation Deprotonation of cyclopentadienyl derivatives
US5359105A (en) * 1993-11-01 1994-10-25 Albemarle Corporation Deprotonation of cyclopentadienyl derivatives
EP0659773A1 (en) * 1993-12-21 1995-06-28 Union Carbide Chemicals & Plastics Technology Corporation Production of polyolefins containing long chain branches by a gas phase process
AU697056B2 (en) * 1993-12-21 1998-09-24 Univation Technologies Llc Production of polyolefins containing long chain branches by a gas phase process
US5672669A (en) * 1993-12-23 1997-09-30 Union Carbide Chemicals & Plastics Technology Corporation Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture
US5674795A (en) * 1993-12-23 1997-10-07 Union Carbide Chemicals & Plastics Technology Corporation Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture
US5648310A (en) * 1993-12-23 1997-07-15 Union Carbide Chemicals & Plastics Technology Corporation Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture
WO1995021743A1 (en) * 1994-02-08 1995-08-17 Dupont Canada Inc. Multilayer ethylene copolymer film
US5972443A (en) * 1994-02-08 1999-10-26 Du Pont Canada Inc. Multilayer ethylene copolymer film
EP0669347A1 (en) * 1994-02-18 1995-08-30 Mitsui Petrochemical Industries, Ltd. Ethylene polymer, process for preparing the same, solid titanium catalyst component for ethylene polymerization and ethylene polymerization catalyst
US5674950A (en) * 1994-03-07 1997-10-07 Exxon Chemical Patents Inc. Polymers having terminal hydroxyl aldehyde, or alkylamino substitutents and derivatives thereof
US5777041A (en) * 1994-03-07 1998-07-07 Exxon Chemical Patents Inc Saturated polyolefins having terminal aldehyde or hydroxy substituents and derivatives thereof
US5780554A (en) * 1994-03-07 1998-07-14 Exxon Chemical Patents Inc. Saturated polyolefins having terminal aldehyde or hydroxy substituents and derivatives thereof
US5691422A (en) * 1994-03-07 1997-11-25 Exxon Chemical Patents Inc. Saturated polyolefins having terminal aldehyde or hydroxy substituents and derivatives thereof
US5919869A (en) * 1994-03-07 1999-07-06 Exxon Chemical Patents, Inc. Polymers having terminal hydroxyl, aldehyde, or alkylamino substituents and derivatives thereof
US5880219A (en) * 1994-03-07 1999-03-09 Exxon Chemical Patents Inc. Polymers having terminal hydroxyl, aldehyde, or alkylamino substituents and derivatives thereof
WO1995025766A1 (de) * 1994-03-20 1995-09-28 Techno-Polymer Hans-Joachim Kuhl Thermoplastische formmasse, verfahren zu ihrer herstellung und ihre verwendung
US5556697A (en) * 1994-03-24 1996-09-17 Bicc Cables Corporation Semiconductive power cable shield
US5648438A (en) * 1994-04-01 1997-07-15 Exxon Chemical Patents, Inc. Process for producing polymers with multimodal molecular weight distributions
US6300437B1 (en) 1994-04-07 2001-10-09 Bp Chemicals Limited Polymerization process
EP1134238A1 (en) * 1994-04-07 2001-09-19 BP Chemicals Limited Copolymers
US6258912B1 (en) 1994-04-07 2001-07-10 Bp Chemicals Limited Polyolefin
US5614297A (en) * 1994-05-19 1997-03-25 Viskase Corporation Polyolefin stretch film
US6184290B1 (en) 1994-06-01 2001-02-06 The Dow Chemical Company Block copolymer compositions containing substantially inert thermoelastic extenders
US6184291B1 (en) 1994-06-01 2001-02-06 The Dow Chemical Company Block copolymer compositions containing substantially inert thermoelastic extenders
WO1995033006A1 (en) * 1994-06-01 1995-12-07 The Dow Chemical Company Thermoelastic blend compositions
US6218470B1 (en) 1994-06-01 2001-04-17 The Dow Chemical Company Thermoplastic elastomeric blends
US6369161B1 (en) 1994-06-01 2002-04-09 The Dow Chemical Company Thermoplastic elastomeric blends
WO1995033779A1 (en) * 1994-06-09 1995-12-14 Exxon Chemical Patents Inc. DILUTE PROCESS FOR THE POLYMERIZATION OF NON-ETHYLENE α-OLEFIN HOMOPOLYMERS AND COPOLYMERS USING METALLOCENE CATALYST SYSTEMS
AU698195B2 (en) * 1994-06-09 1998-10-29 Exxon Chemical Patents Inc. Dilute process for the polymerization of non-ethylene alpha-olefin homopolymers and copolymers using metallocene catalyst systems
US5936041A (en) * 1994-06-17 1999-08-10 Exxon Chemical Patents Inc Dispersant additives and process
US5804667A (en) * 1994-06-17 1998-09-08 Exxon Chemical Patents Inc. Dispersant additives and process
US5792730A (en) * 1994-07-11 1998-08-11 Exxon Chemical Patents, Inc. Lubricating oil succinimide dispersants derived from heavy polyamine
WO1996003441A1 (en) * 1994-07-25 1996-02-08 The Dow Chemical Company Chlorinated and chlorosulfonated elastic substantially linear olefin polymers
US6403710B1 (en) 1994-08-29 2002-06-11 The Dow Chemical Company Block copolymer compositions containing substantially inert thermoelastic extenders
WO1996007680A1 (en) * 1994-09-07 1996-03-14 The Dow Chemical Company Plastic linear low density polyethylene
EP0701897A2 (en) 1994-09-16 1996-03-20 W.R. Grace & Co.-Conn. Thermoplastic multilayer film for use in packaging water
EP0701897A3 (en) * 1994-09-16 1996-12-11 Grace W R & Co Thermoplastic multilayer film for packaging water
EP0708117A1 (en) * 1994-10-03 1996-04-24 Sumitomo Chemical Company Limited Process for producing copolymer rubber
US5834077A (en) * 1994-10-04 1998-11-10 W. R. Grace & Co.-Conn. High shrink multilayer film which maintains optics upon shrinking
US5837335A (en) * 1994-10-04 1998-11-17 Cryovac, Inc. High shrink multilayer film which maintains optics upon shrinking
US5565128A (en) * 1994-10-12 1996-10-15 Exxon Chemical Patents Inc Lubricating oil mannich base dispersants derived from heavy polyamine
US5874139A (en) * 1994-10-21 1999-02-23 The Dow Chemical Company Multilayer polyolefin with balanced sealant properties
WO1996012744A1 (en) * 1994-10-24 1996-05-02 Exxon Chemical Patents Inc. Long-chain branched polymers and their production
US6300451B1 (en) 1994-10-24 2001-10-09 Exxon Chemical Patents Inc. Long-chain branched polymers and their production
WO1996016119A1 (en) * 1994-11-14 1996-05-30 The Dow Chemical Company Extrusion compositions having high drawdown and substantially reduced neck-in
AU691386B2 (en) * 1994-11-14 1998-05-14 Dow Chemical Company, The Extrusion compositions having high drawdown and substantially reduced neck-in
US7645835B2 (en) 1994-11-17 2010-01-12 Dow Global Technologies, Inc. High density ethylene homopolymers and blend compositions
US7153909B2 (en) 1994-11-17 2006-12-26 Dow Global Technologies Inc. High density ethylene homopolymers and blend compositions
WO1996016093A2 (en) 1994-11-23 1996-05-30 Exxon Chemical Patents Inc. Method for making supported catalyst systems, and catalyst systems therefrom
US6214954B1 (en) 1994-12-13 2001-04-10 Asahi Kasei Kogyo Kabushiki Kaisha Olefin polymerization catalyst
US5925430A (en) * 1995-01-31 1999-07-20 Owens-Illinois Closure Inc. Lined plastic closure
DE19516801A1 (de) * 1995-05-08 1996-11-14 Hoechst Ag Organometallverbindung
US5798427A (en) * 1995-05-16 1998-08-25 Union Carbide Chemicals & Plastics Technology Corporation Ethylene polymers having enhanced processability
US5852143A (en) * 1995-05-16 1998-12-22 Union Carbide Chemicals & Plastics Technology Corporation Production of polyethylene using stereoisomeric metallocenes
AU713324B2 (en) * 1995-05-16 1999-11-25 Union Carbide Chemicals & Plastics Technology Corporation Ethylene polymers having enhanced processability
WO1997001586A1 (en) * 1995-06-29 1997-01-16 Dsm N.V. Elastomeric copolymer
NL1000687C2 (en) * 1995-06-29 1996-12-31 Dsm Nv Ethylene-~a-olefin(-diene) copolymer for prodn. of thermoplastic elastomers
US5869575A (en) * 1995-08-02 1999-02-09 The Dow Chemical Company Ethylene interpolymerizations
US6413900B1 (en) 1995-08-10 2002-07-02 Exxonmobil Chemical Patents Inc. Metallocene stabilized alumoxane
US5652202A (en) * 1995-08-15 1997-07-29 Exxon Chemical Patents Inc. Lubricating oil compositions
US5558802A (en) * 1995-09-14 1996-09-24 Exxon Chemical Patents Inc Multigrade crankcase lubricants with low temperature pumpability and low volatility
US5889121A (en) * 1995-10-06 1999-03-30 Shell Oil Company Method for improving processability of thermoplastics
WO1997019965A1 (en) * 1995-11-30 1997-06-05 The Dow Chemical Company Mono-olefin/polyene interpolymers, method of preparation, compositions containing the same, and articles made thereof
US5814714A (en) * 1995-11-30 1998-09-29 The Dow Chemical Company Mono-olefin/polyene interpolymers, method of preparation, compositions containing the same, and articles made thereof
WO1997032946A1 (en) * 1996-03-08 1997-09-12 Dupont Dow Elastomers L.L.C. Substantially linear ethylene/alpha-olefin polymers as viscosity index improvers or gelling agents
WO1997042239A1 (en) * 1996-05-03 1997-11-13 Dsm N.V. PROCESS FOR THE PREPARATION OF A TERPOLYMER OF ETHYLENE, AN α-OLEFIN AND A DIENE
WO1997042237A1 (en) * 1996-05-03 1997-11-13 Dsm N.V. A process for making polyolefins having broad molecular weight distributions
WO1997042240A1 (en) * 1996-05-03 1997-11-13 Dsm N.V. Process for the co-polymerization of an olefin and a vinyl aromatic monomer
WO1997042241A1 (en) * 1996-05-03 1997-11-13 Dsm N.V. PROCESS FOR THE PREPARATION OF AN ETHYLENE AND α-OLEFIN COPOLYMER
WO1997042232A1 (en) * 1996-05-03 1997-11-13 Dsm N.V. Process for the polymerisation of alpha-olefins
US5759648A (en) * 1996-07-05 1998-06-02 Viskase Corporation Multilayer plastic film, useful for packaging a cook-in foodstuff
US6086967A (en) * 1996-11-06 2000-07-11 The Dow Chemical Company Modified atmosphere films useful in the packaging of perishable food
WO1998020062A1 (en) * 1996-11-06 1998-05-14 The Dow Chemical Company Films useful in the modified atmosphere packaging of perishable food
US6500508B2 (en) 1996-12-16 2002-12-31 Sumitomo Electric Fine Polymer, Inc. Flame-retardant resin composition, and insulated wire, shielded wire and insulating tube comprising the composition
WO1998032784A1 (en) * 1997-01-29 1998-07-30 The Dow Chemical Company Heteromorphic polymer compositions
US6417281B1 (en) 1997-02-14 2002-07-09 Exxonmobil Chemical Patents Inc. Processing olefin copolymers
US6355757B2 (en) 1997-02-14 2002-03-12 Exxonmobil Chemical Patents, Inc. Processing olefin copolymers
WO1998038375A3 (en) * 1997-02-28 1998-12-03 Shaw Ind Inc Carpet, carpet backings and methods
WO1998038376A1 (en) * 1997-02-28 1998-09-03 Shaw Industries, Inc. Carpet, carpet backings and methods
US9051683B2 (en) 1997-02-28 2015-06-09 Columbia Insurance Company Carpet, carpet backings and methods
US9376769B2 (en) 1997-02-28 2016-06-28 Columbia Insurance Company Homogeneously branched ethylene polymer carpet backsizing compositions
WO1998038374A3 (en) * 1997-02-28 1998-12-10 Dow Chemical Co Carpet, carpet backing and method for making same using homogeneously branched ethylene polymer
US6255426B1 (en) 1997-04-01 2001-07-03 Exxon Chemical Patents, Inc. Easy processing linear low density polyethylene
US6476171B1 (en) 1997-04-01 2002-11-05 Exxonmobil Chemical Patents Inc. Easy processing linear low density polyethylene
WO1998049211A1 (en) * 1997-05-01 1998-11-05 The Dow Chemical Company Olefin polymers prepared with substituted indenyl containing metal complexes
CN1112383C (zh) * 1997-05-01 2003-06-25 陶氏化学公司 用含取代茚基的金属配合物制备的烯烃聚合物
US6204328B1 (en) 1997-05-26 2001-03-20 Chisso Corporation Polyolefin resin composition
US6187424B1 (en) 1997-08-08 2001-02-13 The Dow Chemical Company Sheet materials suitable for use as a floor, wall or ceiling covering material, and processes and intermediates for making the same
US6313241B1 (en) 1997-10-01 2001-11-06 Cryovac, Inc. Narrow molecular weight distribution copolymers containing long chain branches and process to form same
US6136995A (en) * 1997-11-07 2000-10-24 Sumitomo Chemical Company, Limited Process for producing aminosilane compounds
US6323285B1 (en) 1998-01-09 2001-11-27 The Dow Chemical Company Heteromorphic polymer compositions
WO1999051666A1 (en) * 1998-04-03 1999-10-14 Minnesota Mining And Manufacturing Company Anisotropic film
US6667351B2 (en) 1998-05-18 2003-12-23 Dow Global Technologies Inc. Articles having elevated temperature elasticity made from irradiated and crosslinked ethylene polymers and method for making the same
US6278032B1 (en) 1998-06-11 2001-08-21 Societa' Italiana Additivi Per Carburanti S.R.L. Ethylene polymers with α-olefins
US6770360B2 (en) 1998-06-12 2004-08-03 Avery Dennison Corporation Multilayered thermoplastic film and sign cutting method using the same
US6462134B1 (en) 1998-07-07 2002-10-08 Basell Polyolefine Gmbh Polyethylene compositions having improved optical and mechanical properties and improved processability in the melted state
RU2248885C2 (ru) * 1998-09-01 2005-03-27 Печини Пластик Пэкэджинг, Инк. Усовершенствованные структуры из полимеров, полученных с применением катализаторов с одним активным центром
WO2000014129A1 (en) * 1998-09-04 2000-03-16 The Dow Chemical Company Long chain branched ethylene homopolymer made by a slurry process and blends thereof
US6482896B2 (en) 1998-12-08 2002-11-19 Dow Global Technologies Inc. Polypropylene/ethylene polymer fiber having improved bond performance and composition for making the same
US6482895B2 (en) 1998-12-08 2002-11-19 Dow Global Technologies Inc. Polypropylene/ethylene polymer fiber having improved bond performance and composition for marking the same
WO2000034385A1 (en) * 1998-12-08 2000-06-15 The Dow Chemical Company Mel-bondable polypropylene/ethylene polymer fiber and composition for making the same
US6232377B1 (en) 1999-02-19 2001-05-15 Nippon Unicar Company Ltd. Flame retardant composition
US8314040B2 (en) 1999-02-22 2012-11-20 Kimberly-Clark Worldwide, Inc. Laminates of elastomeric and non-elastomeric polyolefin blend materials
US6680265B1 (en) 1999-02-22 2004-01-20 Kimberly-Clark Worldwide, Inc. Laminates of elastomeric and non-elastomeric polyolefin blend materials
EP1624000A1 (en) 1999-05-06 2006-02-08 Univation Technologies, LLC A polymerization process for producing easier processing polymers
EP1878757A1 (en) 1999-06-17 2008-01-16 Mitsui Chemicals, Inc. Ethylene (co)polymer and its use
US7687579B2 (en) 1999-06-17 2010-03-30 Mitsui Chemicals, Inc. Ethylene (co) polymer and its use
US7563849B2 (en) 1999-06-17 2009-07-21 Mitsui Chemicals, Inc. Ethylene (co) polymer and its use
US7335716B1 (en) 1999-06-17 2008-02-26 Mitsui Chemicals, Inc. Ethylene (co)polymers and uses thereof
WO2001005852A1 (en) * 1999-07-15 2001-01-25 The Dow Chemical Company High density ethylene homopolymers and blend compositions
EP1914252A1 (en) 1999-12-16 2008-04-23 Univation Technologies, LLC Method of polymerization
US6858106B1 (en) 2000-05-26 2005-02-22 Tetra Laval Holdings & Finance S.A. Process for producing packaging laminate
US6583240B2 (en) 2001-05-23 2003-06-24 Equistar Chemicals, Lp Ethylene polymerization process
US7056579B2 (en) 2001-08-08 2006-06-06 Toyo Boseki Kabushiki Kaisha High-strength polyethylene fiber
KR100909559B1 (ko) * 2001-08-08 2009-07-27 토요 보세키 가부시기가이샤 고강도 폴리에틸렌 섬유
KR100951222B1 (ko) * 2001-08-08 2010-04-05 토요 보세키 가부시기가이샤 고강도 폴리에틸렌 섬유
WO2003014437A1 (en) * 2001-08-08 2003-02-20 Toyo Boseki Kabushiki Kaisha High-strength polyethylene fiber
US6727331B2 (en) 2001-12-28 2004-04-27 Equistar Chemicals, Lp Preparation of polyethylene
WO2004031292A2 (en) 2002-10-02 2004-04-15 Dow Global Technologies Inc. POLYMER COMPOSITIONS COMPRISING A LOW VISCOSITY, HOMOGENEOUSLY BRANCHED ETHYLENE/α-OLEFIN EXTENDER
WO2004046214A2 (en) 2002-10-15 2004-06-03 Exxonmobil Chemical Patents Inc. Multiple catalyst system for olefin polymerization and polymers produced therefrom
US7208559B2 (en) 2002-12-27 2007-04-24 Mitsui Chemicals, Inc. Ethylened polymer and molded object obtained therefrom
US7700708B2 (en) 2003-02-17 2010-04-20 Mitsui Chemicals, Inc. Ethylene polymer and application thereof to moldings
WO2004094487A1 (en) 2003-03-21 2004-11-04 Dow Global Technologies, Inc. Morphology controlled olefin polymerization process
US7422786B2 (en) 2003-09-24 2008-09-09 Exxonmobil Chemical Patents Inc. Collation shrink
US7939148B2 (en) 2003-09-24 2011-05-10 Exxonmobil Chemical Patents Inc. Collation shrink
WO2005082947A1 (en) 2004-02-17 2005-09-09 Univation Technologies, Llc De-foaming spray dried catalyst slurries
WO2005113622A1 (en) 2004-04-15 2005-12-01 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
EP2218751A1 (en) 2004-12-17 2010-08-18 Dow Global Technologies Inc. Rheology modified polyethylene compositions
US7858723B2 (en) 2005-01-31 2010-12-28 Mitsui Chemicals, Inc. Ethylene-based resin and molded object obtained therefrom
WO2007008361A1 (en) 2005-07-11 2007-01-18 Equistar Chemicals, Lp Polyethylene compositions
EP1803747A1 (en) 2005-12-30 2007-07-04 Borealis Technology Oy Surface-modified polymerization catalysts for the preparation of low-gel polyolefin films
US8445594B2 (en) 2006-05-02 2013-05-21 Dow Global Technologies Llc High-density polyethylene compositions, method of making the same, articles made therefrom, and method of making such articles
US8202953B2 (en) 2006-05-17 2012-06-19 Dow Global Technologies Llc High efficiency solution polymerization process
US7456244B2 (en) 2006-05-23 2008-11-25 Dow Global Technologies High-density polyethylene compositions and method of making the same
US7560524B2 (en) 2006-05-23 2009-07-14 Dow Global Technologies, Inc. High-density polyethylene compositions and method of making the same
US8299193B2 (en) 2006-07-31 2012-10-30 Mitsui Chemicals, Inc. Film or laminate comprising ethylene-based resin or ethylene-based resin composition
WO2008074689A1 (en) * 2006-12-21 2008-06-26 Ineos Europe Limited Copolymers and films thereof
EP1935909A1 (en) * 2006-12-21 2008-06-25 Ineos Europe Limited Copolymers and films thereof
US8242220B2 (en) 2006-12-21 2012-08-14 Ineos Europe Limited Copolymers and films thereof
US8412011B2 (en) 2007-01-24 2013-04-02 The Furukawa Electric Co., Ltd. Optical fiber cable
US7813606B2 (en) 2007-01-24 2010-10-12 The Furukawa Electric Co., Ltd. Optical fiber cable
US7981517B2 (en) 2007-08-28 2011-07-19 Dow Global Technologies Inc. Bituminous compositions and methods of making and using same
EP3597294A1 (en) 2007-10-22 2020-01-22 Univation Technologies, LLC Polyethylene compositions having improved properties
EP3372311A1 (en) 2007-10-22 2018-09-12 Univation Technologies, LLC Film comprising a polyethylene composition having improved properties
EP3309182A2 (en) 2007-11-15 2018-04-18 Univation Technologies, LLC Polymerization catalysts, methods of making; methods of using, and polyolefinproducts made therefrom
US8318872B2 (en) 2007-12-18 2012-11-27 Univation Technologies, Llc Method for controlling bimodal catalyst activity during polymerization
US8722832B2 (en) 2007-12-19 2014-05-13 Basell Polyolefine Gmbh Ethylene terpolymers
EP2112175A1 (en) 2008-04-16 2009-10-28 ExxonMobil Chemical Patents Inc. Activator for metallocenes comprising one or more halogen substituted heterocyclic heteroatom containing ligand coordinated to an alumoxane
US9587055B2 (en) 2008-06-09 2017-03-07 Ineos Manufacturing Belgium Nv Copolymers
EP2285843B2 (en) † 2008-06-09 2018-10-10 INEOS Manufacturing Belgium NV Pipes comprising a copolymer of ethylene and an alpha-olefin
EP2172490A1 (en) 2008-10-03 2010-04-07 Ineos Europe Limited Controlled polymerisation process
EP2177548A1 (en) 2008-10-14 2010-04-21 Ineos Europe Limited Copolymers and films thereof
WO2010071798A1 (en) 2008-12-18 2010-06-24 Univation Technologies, Llc Method for seed bed treatment for a polymerization reaction
US9056970B2 (en) 2009-01-30 2015-06-16 Dow Global Technologies Llc High-density polyethylene compositions, method of producing the same, closure devices made therefrom, and method of making such closure devices
WO2010088265A1 (en) 2009-01-30 2010-08-05 Dow Global Technologies Inc. High-density polyethylene compositions, method of producing the same, closure devices made therefrom, and method of making such closure devices
WO2010094450A1 (en) 2009-02-20 2010-08-26 Basell Polyolefine Gmbh Ethylene copolymers, catalyst system and process for preparing the same
US8569434B2 (en) 2009-02-20 2013-10-29 Basell Polyolefine Gmbh Ethylene copolymers, catalyst system and process for preparing the same
WO2011002998A1 (en) 2009-07-01 2011-01-06 Dow Global Technologies Inc. Ethylenic polymer and its use
WO2011002986A1 (en) 2009-07-01 2011-01-06 Dow Global Technologies Inc. Ethylenic polymer and its use
US10875947B2 (en) 2009-07-01 2020-12-29 Dow Global Technologies Llc Ethylenic polymer and its use
WO2011085937A1 (en) 2010-01-13 2011-07-21 Ineos Europe Limited Polymer powder storage and/or transport and/or degassing vessels
EP2357035A1 (en) 2010-01-13 2011-08-17 Ineos Europe Limited Polymer powder storage and/or transport and/or degassing vessels
WO2011134798A1 (en) 2010-04-30 2011-11-03 Ineos Commercial Services Uk Limited Polymerization process
WO2011134797A1 (en) 2010-04-30 2011-11-03 Ineos Commercial Services Uk Limited Polymerization process
EP2383298A1 (en) 2010-04-30 2011-11-02 Ineos Europe Limited Polymerization process
EP2383301A1 (en) 2010-04-30 2011-11-02 Ineos Europe Limited Polymerization process
WO2012072417A1 (en) 2010-11-29 2012-06-07 Ineos Commercial Services Uk Limited Polymerisation control process
WO2012074709A1 (en) 2010-11-30 2012-06-07 Univation Technologies, Llc Processes for the polymerization of olefins with extracted metal carboxylate salts
WO2012074710A1 (en) 2010-11-30 2012-06-07 Univation Technologies, Llc. Catalyst composition having improved flow characteristics and methods of making and using the same
WO2012087560A1 (en) 2010-12-22 2012-06-28 Univation Technologies, Llc Additive for polyolefin polymerization processes
WO2012158260A1 (en) 2011-05-13 2012-11-22 Univation Technologies, Llc Spray-dried catalyst compositions and polymerization processes employing the same
WO2013025351A1 (en) 2011-08-12 2013-02-21 Ineos Usa Llc Apparatus for stirring polymer particles
WO2013056979A1 (en) 2011-10-17 2013-04-25 Ineos Europe Ag Polymer degassing process control
WO2013070601A2 (en) 2011-11-08 2013-05-16 Univation Technologies, Llc Methods of preparing a catalyst system
WO2013099927A1 (ja) 2011-12-28 2013-07-04 三井化学株式会社 エチレン系重合体組成物、及びこれから得られる成形体
WO2014105614A1 (en) 2012-12-28 2014-07-03 Univation Technologies, Llc Methods of integrating aluminoxane production into catalyst production
WO2014109832A1 (en) 2013-01-14 2014-07-17 Univation Technologies, Llc Methods for preparing catalyst systems with increased productivity
WO2014120494A1 (en) 2013-01-30 2014-08-07 Univation Technologies, Llc Processes for making catalyst compositions having improved flow
WO2015153082A1 (en) 2014-04-02 2015-10-08 Univation Technologies, Llc Continuity compositions and methods of making and using the same
EP3747913A1 (en) 2014-04-02 2020-12-09 Univation Technologies, LLC Continuity compositions and olefin polymerisation method using the same
WO2016086039A1 (en) 2014-11-25 2016-06-02 Univation Technologies, Llc Methods of controlling polyolefin melt index
EP3915759A1 (en) 2015-01-21 2021-12-01 Univation Technologies, LLC Method for controlling polymer chain scission
WO2016118599A1 (en) 2015-01-21 2016-07-28 Univation Technologies, Llc Methods for controlling polymer chain scission
WO2016118566A1 (en) 2015-01-21 2016-07-28 Univation Technologies, Llc Methods for gel reduction in polyolefins
WO2016145179A1 (en) 2015-03-10 2016-09-15 Univation Technologies, Llc Spray dried catalyst compositions, methods for preparation and use in olefin polymerization processes
WO2016148884A1 (en) 2015-03-18 2016-09-22 Dow Global Technologies Llc Protective films, blends, and methods of making thereof
EP3070134A1 (en) 2015-03-18 2016-09-21 Dow Global Technologies LLC Protective films, blends, and methods of making thereof
EP4063402A1 (en) 2015-04-17 2022-09-28 Univation Technologies, LLC Methods and systems for olefin polymerization
WO2016168655A1 (en) 2015-04-17 2016-10-20 Univation Technologies, Llc Methods and systems for olefin polymerization
WO2016172197A1 (en) 2015-04-20 2016-10-27 Exxonmobil Chemical Patents Inc. Multimodal and broad molecular weight high density polyethylene
WO2016171810A1 (en) 2015-04-20 2016-10-27 Exxonmobil Chemical Patents Inc. Supported catalyst systems and processes for use thereof
WO2016172567A1 (en) 2015-04-24 2016-10-27 Univation Technologies, Llc Methods for operating a polymerization reactor
WO2016176135A1 (en) 2015-04-27 2016-11-03 Univation Technologies, Llc Supported catalyst compositions having improved flow properties and preparation thereof
WO2016182920A1 (en) 2015-05-08 2016-11-17 Exxonmobil Chemical Patents Inc. Polymerization process
JP2017002428A (ja) * 2015-06-10 2017-01-05 Ｊｘエネルギー株式会社 網状構造体
US10328630B2 (en) 2015-06-10 2019-06-25 Jxtg Nippon Oil & Energy Corporation Mesh structure
US11485808B2 (en) 2016-03-04 2022-11-01 Japan Polyethylene Corporation Metallocene compound, catalyst component for olefin polymerization and catalyst for olefin polymerization containing the same, and method for producing olefin polymer using catalyst for olefin polymerization
US10919994B2 (en) 2016-03-04 2021-02-16 Japan Polyethylene Corporation Metallocene compound, catalyst component for olefin polymerization and catalyst for olefin polymerization containing the same, and method for producing olefin polymer using catalyst for olefin polymerization
US10995167B2 (en) 2016-03-15 2021-05-04 Japan Polyethylene Corporation Metallocene compound, catalyst component for olefin polymerization and catalyst for olefin polymerization containing the same, and method for producing olefin polymer using catalyst for olefin polymerization
WO2018017363A1 (en) 2016-07-21 2018-01-25 Dow Global Technologies Llc Composite cushioning structures, and methods of manufacturing thereof
US11312844B2 (en) 2016-07-28 2022-04-26 Dow Global Technologies Llc Compositions suitable for manufacturing polyethylene foam, and articles thereof
WO2018022588A1 (en) 2016-07-29 2018-02-01 Dow Global Technologies Llc Mixed catalyst systems for producing multimodal elastomers
US11155658B2 (en) 2016-07-29 2021-10-26 Dow Global Technologies Llc Mixed catalyst systems for producing multimodal elastomers
WO2018063765A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
WO2018063767A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
WO2018063764A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
WO2018064435A1 (en) 2016-09-30 2018-04-05 Dow Global Technologies Llc High processability polyethylene compositions for injection molded articles
US11174377B2 (en) 2016-09-30 2021-11-16 Dow Global Technologies Llc High processability polyethylene compositions for injection molded articles
WO2018118155A1 (en) 2016-12-20 2018-06-28 Exxonmobil Chemical Patents Inc. Polymerization process
US10029230B1 (en) 2017-01-24 2018-07-24 Chevron Phillips Chemical Company Lp Flow in a slurry loop reactor
US11548270B2 (en) 2017-06-30 2023-01-10 Dow Global Technologies Llc Multilayer polyethylene laminates and films for use in flexible packaging materials
WO2019006053A1 (en) 2017-06-30 2019-01-03 Dow Global Technologies Llc MULTILAYERED POLYETHYLENE LAMINATES AND FILMS FOR USE IN SOFT PACKAGING MATERIALS
US11326043B2 (en) 2017-08-29 2022-05-10 Dow Chemical Korea Limited Compositions for high reinforced sidewalls
WO2019118073A1 (en) 2017-12-13 2019-06-20 Exxonmobil Chemical Patents Inc. Deactivation methods for active components from gas phase polyolefin polymerization process
US11384229B2 (en) 2017-12-26 2022-07-12 Dow Global Technologies Llc Compositions comprising multimodal ethylene-based polymers and low density polyethylene (LDPE)
US11680120B2 (en) 2017-12-26 2023-06-20 Dow Global Technologies Llc Dual reactor solution process for the production of multimodal ethylene-based polymer
US11680119B2 (en) 2017-12-26 2023-06-20 Dow Global Technologies Llc Process for the production of multimodal ethylene-based polymers
US11603452B2 (en) 2017-12-26 2023-03-14 Dow Global Technologies Llc Multimodal ethylene-based polymer compositions having improved toughness
US11555084B2 (en) 2017-12-26 2023-01-17 Dow Global Technologies Llc Multimodal ethylene-based polymer processing systems and methods
WO2019133372A1 (en) 2017-12-26 2019-07-04 Kolthammer, Brian W. Multimodal ethylene-based polymer processing systems and methods
WO2019133400A1 (en) 2017-12-26 2019-07-04 Dow Global Technologies Llc Compositions with multimodal ethylene-based polymers having improved toughness at low temperatures
WO2019133373A1 (en) 2017-12-26 2019-07-04 Dow Global Technologies Llc Multimodal ethylene-based polymer compositions having improved toughness
WO2019133378A1 (en) 2017-12-26 2019-07-04 Dow Global Technologies Llc Process for the production of multimodal ethylene-based polymers
WO2019133368A1 (en) 2017-12-26 2019-07-04 Dow Global Technologies Llc Dual reactor solution process for the production of multimodal ethylene-based polymer
WO2019133394A1 (en) 2017-12-26 2019-07-04 Dow Global Technologies, Llc Compositions comprising multimodal ethylene based polymers and low density polyethylene (ldpe)
WO2019173030A1 (en) 2018-03-08 2019-09-12 Exxonmobil Chemical Patents Inc. Methods of preparing and monitoring a seed bed for polymerization reactor startup
WO2019217173A1 (en) 2018-05-02 2019-11-14 Exxonmobil Chemical Patents Inc. Methods for scale-up from a pilot plant to a larger production facility
WO2019213227A1 (en) 2018-05-02 2019-11-07 Exxonmobil Chemical Patents Inc. Methods for scale-up from a pilot plant to a larger production facility
US11873393B2 (en) 2018-06-15 2024-01-16 Dow Global Technologies Llc Bimodal ethylene-based polymers having high molecular weight high density fractions
US11873377B2 (en) 2018-06-15 2024-01-16 Dow Global Technologies Llc Blown films comprising bimodal ethylene-based polymers having high molecular weight high density fractions
US11926684B2 (en) 2018-06-15 2024-03-12 Dow Global Technologies Llc Cast films comprising bimodal ethylene-based polymers having high molecular weight high density fractions
WO2019241517A1 (en) 2018-06-15 2019-12-19 Dow Global Technologies Llc Cast films comprising bimodal ethylene-based polymers having high molecular weight high density fractions
US11814456B2 (en) 2018-06-15 2023-11-14 Dow Global Technologies Llc Process for the production of bimodal ethylene-based polymers having high molecular weight high density fractions
WO2019241475A1 (en) 2018-06-15 2019-12-19 Dow Global Technologies Llc Bimodal ethylene-based polymers having high molecular weight high density fractions
WO2019241515A1 (en) 2018-06-15 2019-12-19 Dow Global Technologies Llc Process for the production of bimodal ethylene-based polymers having high molecular weight high density fractions
WO2019241518A1 (en) 2018-06-15 2019-12-19 Dow Global Technologies Llc Blown films comprising bimodal ethylene-based polymers having high molecular weight high density fractions
WO2020109870A2 (en) 2018-06-28 2020-06-04 Exxonmobil Chemical Patents Inc. Polyethylene compositions, wires and cables, and methods for making the same
WO2020014138A1 (en) 2018-07-09 2020-01-16 Exxonmobil Chemical Patents Inc. Polyethylene cast films and methods for making the same
WO2020023207A1 (en) 2018-07-26 2020-01-30 Exxonmobil Chemical Patents Inc. Multilayer foam films and methods for making the same
WO2020102385A1 (en) 2018-11-13 2020-05-22 Exxonmobil Chemical Patents Inc. Polyethylene films
WO2020102380A1 (en) 2018-11-13 2020-05-22 Exxonmobil Chemical Patents Inc. Polyethylene blends and films
US12440823B2 (en) 2018-11-30 2025-10-14 Dow Global Technologies Llc Polymer-based film with balanced properties
WO2020112526A1 (en) 2018-11-30 2020-06-04 Dow Global Technologies Llc Polymer-based film with balanced properties
WO2020163079A1 (en) 2019-02-06 2020-08-13 Exxonmobil Chemical Patents Inc. Films and backsheets for hygiene articles
CN113784829A (zh) * 2019-05-30 2021-12-10 陶氏环球技术有限责任公司 挤出熔体中无表面破裂的线性低密度聚乙烯（lldpe）的方法
WO2020242789A1 (en) * 2019-05-30 2020-12-03 Dow Global Technologies Llc Method of extruding linear low-density polyethylene (lldpe) without surface fractures in the melt
WO2021126458A1 (en) 2019-12-17 2021-06-24 Exxonmobil Chemical Patents Inc. Films made of polyethylene blends for improved sealing performance and mechanical properties
WO2021183337A1 (en) 2020-03-12 2021-09-16 Exxonmobil Chemical Patents Inc. Films made of polyethylene blends for improved bending stiffness and high md tear resistance
WO2021195502A1 (en) 2020-03-27 2021-09-30 Dow Global Technologies Llc Long-chain branched ethylene-based polymers
WO2021195504A1 (en) 2020-03-27 2021-09-30 Dow Global Technologies Llc Long-chain branched ethylene-based polymers
WO2021195501A1 (en) 2020-03-27 2021-09-30 Dow Global Technologies Llc A process for producing long-chain branched ethylene-based polymers
WO2021195505A1 (en) 2020-03-27 2021-09-30 Dow Global Technologies Llc Long-chain branched ethylene-based polymers
US20230125442A1 (en) * 2020-03-27 2023-04-27 Dow Global Technologies Llc Long-chain branched ethylene-based polymers
US12497472B2 (en) 2020-03-27 2025-12-16 Dow Global Technologies Llc Long-chain branched ethylene-based polymers
US11976146B2 (en) 2020-03-27 2024-05-07 Dow Global Technologies Llc Long-chain branched ethylene-based polymers
US12479937B2 (en) 2020-03-27 2025-11-25 Dow Global Technologies Llc Process for producing long-chain branched ethylene-based polymers
WO2021221904A1 (en) 2020-04-28 2021-11-04 Exxonmobil Chemical Patents Inc. Density and chemical composition control for polymer with good stress crack properties
WO2022210845A1 (ja) 2021-03-31 2022-10-06 三井化学株式会社 エチレン系樹脂組成物および成形体
WO2022210844A1 (ja) 2021-03-31 2022-10-06 三井化学株式会社 エチレン－α－オレフィン共重合体、熱可塑性樹脂組成物、およびフィルム
WO2022210843A1 (ja) 2021-03-31 2022-10-06 三井化学株式会社 エチレン－α－オレフィン共重合体、熱可塑性樹脂組成物、フィルムおよび積層体
WO2022232760A1 (en) 2021-04-30 2022-11-03 Exxonmobil Chemical Patents Inc. Processes for transitioning between different polymerization catalysts in a polymerization reactor
WO2023192846A1 (en) 2022-03-31 2023-10-05 Exxonmobil Chemical Patents Inc. Linear low density polyethylenes, polymerizations thereof, and films thereof
WO2024054736A1 (en) 2022-09-07 2024-03-14 Exxonmobil Chemical Patents Inc. Polyethylenes and articles thereof
WO2024129637A1 (en) 2022-12-12 2024-06-20 Univation Technologies, Llc Decreasing triboelectric charging of, and/or reactor fouling by, polyolefin particles
WO2025049301A1 (en) 2023-08-28 2025-03-06 Dow Global Technologies Llc Polymer blends including post-consumer recycled (pcr) ethylene-based polymers

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US6506867B1 (en) 2003-01-14
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US20030078357A1 (en) 2003-04-24
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US20030195320A1 (en) 2003-10-16
DE69228265D1 (de) 1999-03-04
EP0783006A3 (en) 1997-07-16
DE69228265T2 (de) 1999-06-02
US6534612B1 (en) 2003-03-18
JP2963199B2 (ja) 1999-10-12
ES2103976T3 (es) 1997-10-01
DE9219090U1 (de) 1997-09-25
EP0608369A1 (en) 1994-08-03
ES2127030T3 (es) 1999-04-01
DE69220077T2 (de) 1997-11-20
DE9219173U1 (de) 1999-03-25
US5278272A (en) 1994-01-11
TW279867B (OSRAM) 1996-07-01
FI941727A0 (fi) 1994-04-14
US6348555B1 (en) 2002-02-19
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EP0899279A3 (en) 1999-11-10
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