CN1155639C - 制备丙烯均聚物和共聚物的方法和设备 - Google Patents
制备丙烯均聚物和共聚物的方法和设备 Download PDFInfo
- Publication number
- CN1155639C CN1155639C CNB988082934A CN98808293A CN1155639C CN 1155639 C CN1155639 C CN 1155639C CN B988082934 A CNB988082934 A CN B988082934A CN 98808293 A CN98808293 A CN 98808293A CN 1155639 C CN1155639 C CN 1155639C
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- China
- Prior art keywords
- reactor
- gas phase
- propylene
- phase reactor
- polymer
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- Expired - Lifetime
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2415—Tubular reactors
- B01J19/2435—Loop-type reactors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
- B01J8/26—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with two or more fluidised beds, e.g. reactor and regeneration installations
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00121—Controlling the temperature by direct heating or cooling
- B01J2219/00128—Controlling the temperature by direct heating or cooling by evaporation of reactants
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00162—Controlling or regulating processes controlling the pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00164—Controlling or regulating processes controlling the flow
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00184—Controlling or regulating processes controlling the weight of reactants in the reactor vessel
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/905—Polymerization in presence of transition metal containing catalyst in presence of hydrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI972726 | 1997-06-24 | ||
| FI972726A FI111848B (fi) | 1997-06-24 | 1997-06-24 | Menetelmä ja laitteisto propeenin homo- ja kopolymeerien valmistamiseksi |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1268959A CN1268959A (zh) | 2000-10-04 |
| CN1155639C true CN1155639C (zh) | 2004-06-30 |
Family
ID=8549121
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB988082934A Expired - Lifetime CN1155639C (zh) | 1997-06-24 | 1998-06-24 | 制备丙烯均聚物和共聚物的方法和设备 |
Country Status (22)
| Country | Link |
|---|---|
| US (1) | US6455643B1 (enExample) |
| EP (1) | EP0887379B1 (enExample) |
| JP (1) | JP3852957B2 (enExample) |
| KR (1) | KR100576928B1 (enExample) |
| CN (1) | CN1155639C (enExample) |
| AR (1) | AR016088A1 (enExample) |
| AT (1) | ATE285444T1 (enExample) |
| AU (1) | AU726554B2 (enExample) |
| BR (1) | BR9810934A (enExample) |
| CA (1) | CA2295018C (enExample) |
| CZ (1) | CZ300053B6 (enExample) |
| DE (1) | DE69828222T2 (enExample) |
| EA (1) | EA002782B1 (enExample) |
| ES (1) | ES2234087T3 (enExample) |
| FI (1) | FI111848B (enExample) |
| IL (2) | IL133651A0 (enExample) |
| MY (1) | MY124158A (enExample) |
| NZ (1) | NZ502014A (enExample) |
| PL (1) | PL193876B1 (enExample) |
| TW (1) | TW418214B (enExample) |
| WO (1) | WO1998058975A1 (enExample) |
| ZA (1) | ZA985490B (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102822265A (zh) * | 2010-02-26 | 2012-12-12 | 博里利斯股份公司 | 用于管件的无规丙烯共聚物 |
| CN101796081B (zh) * | 2007-09-03 | 2013-02-06 | 英尼奥斯制造业比利时有限公司 | 淤浆相聚合方法 |
Families Citing this family (635)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EA200000899A1 (ru) | 1998-03-04 | 2001-02-26 | Бореалис Текнолоджи Ой | Способ получения полиолефинов |
| FI108448B (fi) * | 1998-03-04 | 2002-01-31 | Borealis Tech Oy | Menetelmõ polyolefiinien valmistuksesta saatavan, reagoimattomia yhdisteitõ sisõltõvõn kaasuvirran kõsittelemiseksi |
| FI990285A0 (fi) * | 1999-02-12 | 1999-02-12 | Borealis As | Menetelmä vedylle herkän alfa-olefiinin polymerointikatalysaattorijärjestelmän valmistamiseksi, prosessissa syntynyt polymerointikatalysaattorijärjestelmä ja sen käyttö alfa-olefiinien polymeroinnissa |
| FI990283A7 (fi) * | 1999-02-12 | 2000-08-13 | Borealis As | alfa-olefiinin polymerointikatalysattorisysteemi ja sen käyttö alfa -olefiinien polymerointiin |
| FI990284A0 (fi) * | 1999-02-12 | 1999-02-12 | Borealis As | Monivaiheinen prosessi erittäin stereosäännöllisen sulakäsiteltävän alfa-olefiinipolymeerituotteen valmistamiseksi |
| FI990282A0 (fi) | 1999-02-12 | 1999-02-12 | Borealis As | Monivaiheinen prosessi sellaisten alfa-olefiinipolymeerien valmistamiseksi, joilla on kontrolloitu stereosäännöllisyys, sekä niistä valmistetut tuotteet |
| DE10025727A1 (de) | 2000-05-25 | 2002-01-03 | Basell Polypropylen Gmbh | Hochfließfähige Propylenblockcopolymerisate |
| EP1270628B1 (en) | 2001-06-27 | 2004-10-06 | Borealis Technology Oy | Propylene random copolymer and process for the production thereof |
| DE60108364T2 (de) * | 2001-06-27 | 2005-12-22 | Borealis Technology Oy | Propylenpolymerharz mit verbesserten Eigenschaften |
| DE60129939T2 (de) * | 2001-06-27 | 2008-05-15 | Borealis Technology Oy | Verfahren zur Herstellung einer Polymerfolie die ein statistisches Propylencopolymer enthält |
| US6916892B2 (en) | 2001-12-03 | 2005-07-12 | Fina Technology, Inc. | Method for transitioning between Ziegler-Natta and metallocene catalysts in a bulk loop reactor for the production of polypropylene |
| WO2004003874A2 (en) | 2002-06-26 | 2004-01-08 | Avery Dennison Corporation | Oriented films comprising polypropylene / olefin elastomer blends |
| US6875828B2 (en) * | 2002-09-04 | 2005-04-05 | Univation Technologies, Llc | Bimodal polyolefin production process and films therefrom |
| US8058371B2 (en) | 2002-09-20 | 2011-11-15 | Exxonmobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization |
| US8008412B2 (en) | 2002-09-20 | 2011-08-30 | Exxonmobil Chemical Patents Inc. | Polymer production at supersolution conditions |
| US20080153997A1 (en) * | 2006-12-20 | 2008-06-26 | Exxonmobil Research And Engineering | Polymer production at supercritical conditions |
| US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| BR0315341B1 (pt) | 2002-10-15 | 2014-02-18 | Adesivos compreendendo poliolefina. | |
| US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| ATE380200T1 (de) * | 2002-10-30 | 2007-12-15 | Borealis Tech Oy | Verfahren und vorrichtung zur herstellung von olefinpolymeren |
| FR2848556B1 (fr) | 2002-12-13 | 2006-06-16 | Bio Merieux | Procede de polymerisation radicalaire controlee |
| EP1553108B1 (en) | 2003-12-30 | 2011-05-18 | Borealis Technology Oy | Polymerization Process |
| US7652108B2 (en) | 2004-10-14 | 2010-01-26 | Basell Poliolefine Italia S.R.L. | Process for the gas-phase polymerization olefins |
| GB0423555D0 (en) | 2004-10-22 | 2004-11-24 | Borealis Tech Oy | Process |
| ES2309445T3 (es) | 2004-12-17 | 2008-12-16 | Borealis Technology Oy | Proceso para la polimerizacion de olefinas en presencia de un catalizador de polimerizacion de las mismas. |
| US7053163B1 (en) † | 2005-02-22 | 2006-05-30 | Fina Technology, Inc. | Controlled comonomer distribution along a reactor for copolymer production |
| EP1717269A1 (en) * | 2005-04-28 | 2006-11-02 | Borealis Technology Oy | Alpha-olefin homo-or copolymer compositions |
| US7955565B2 (en) * | 2005-05-17 | 2011-06-07 | Sumitomo Chemical Company, Limited | Gas-phase fluidized-bed reactor, multivessel polymerization reactor and process for producing olefin polymer |
| EP1726602A1 (en) * | 2005-05-27 | 2006-11-29 | Borealis Technology Oy | Propylene polymer with high crystallinity |
| EP1741725B1 (en) * | 2005-07-08 | 2014-04-09 | Borealis Technology Oy | Propylene polymer composition |
| US7678341B2 (en) * | 2005-07-29 | 2010-03-16 | Exxonmobil Chemical Patents Inc. | Loop reactor heat removal |
| US7098301B1 (en) | 2005-07-29 | 2006-08-29 | Exxonmobil Chemical Patents Inc. | High pressure filter method of separating polymer solids and unreacted monomer |
| CN1923861B (zh) | 2005-09-02 | 2012-01-18 | 北方技术股份有限公司 | 在烯烃聚合催化剂存在下的烯烃聚合方法 |
| CN100457790C (zh) * | 2005-09-29 | 2009-02-04 | 中国石油化工股份有限公司 | 丙烯聚合或共聚合方法及其聚合物 |
| JP5034423B2 (ja) * | 2005-10-12 | 2012-09-26 | 住友化学株式会社 | ポリオレフィンの製造方法 |
| US7423099B2 (en) * | 2005-10-12 | 2008-09-09 | Sumitomo Chemical Company, Limited | Process for producing polyolefin |
| DE602006016462D1 (de) | 2005-10-21 | 2010-10-07 | Borealis Tech Oy | Zusammensetzung |
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| EP1862479A1 (en) | 2006-05-31 | 2007-12-05 | Borealis Technology Oy | Olefin polymerisation catalyst |
| EP1862480B1 (en) | 2006-05-31 | 2016-07-27 | Borealis Technology Oy | Process for preparing an olefin polymerisation catalyst component with improved high temperature activity |
| EP2049333B1 (en) | 2006-06-14 | 2012-12-05 | Avery Dennison Corporation | Conformable and die-cuttable machine direction oriented labelstocks and labels, and process for preparing |
| AU2007261011B2 (en) | 2006-06-20 | 2012-04-05 | Avery Dennison Corporation | Multilayered polymeric film for hot melt adhesive labeling and label stock and label thereof |
| ATE421760T1 (de) | 2006-07-10 | 2009-02-15 | Borealis Tech Oy | Elektrischer isolierfilm |
| EP2208749B1 (en) | 2006-07-10 | 2015-12-16 | Borealis Technology Oy | Biaxially oriented polypropylene films |
| EP1887034B1 (en) | 2006-08-01 | 2009-01-28 | Borealis Technology Oy | Process for the production of impact resistant pipe |
| ES2331091T3 (es) | 2006-08-25 | 2009-12-21 | Borealis Technology Oy | Pelicula soplada de polipropileno. |
| EP1892264A1 (en) | 2006-08-25 | 2008-02-27 | Borealis Technology Oy | Extrusion coated substrate |
| DE602006006061D1 (de) | 2006-08-25 | 2009-05-14 | Borealis Tech Oy | Polypropylenschaumstoff |
| EP1903579B1 (en) | 2006-09-25 | 2010-03-24 | Borealis Technology Oy | Coaxial cable |
| US8143352B2 (en) | 2006-12-20 | 2012-03-27 | Exxonmobil Research And Engineering Company | Process for fluid phase in-line blending of polymers |
| US8242237B2 (en) | 2006-12-20 | 2012-08-14 | Exxonmobil Chemical Patents Inc. | Phase separator and monomer recycle for supercritical polymerization process |
| CN101595137B (zh) * | 2006-12-20 | 2012-03-28 | 埃克森美孚化学专利公司 | 在超临界条件下的聚合物制备 |
| ES2322186T3 (es) | 2006-12-28 | 2009-06-17 | Borealis Technology Oy | Proceso para la fabricacion de polipropileno ramificado. |
| ATE461973T1 (de) | 2007-01-22 | 2010-04-15 | Borealis Tech Oy | Polypropylenzusammensetzung mit niedriger oberflächenenergie |
| US8080610B2 (en) | 2007-03-06 | 2011-12-20 | Exxonmobil Research And Engineering Company | Monomer recycle process for fluid phase in-line blending of polymers |
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| BRPI0815727B1 (pt) | 2007-08-27 | 2019-03-26 | Borealis Technology Oy | Equipamento e processo para produzir pelotas poliméricas, uso do equipamento, e processo para produzir um cabo reticulável |
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| CN101855249B (zh) | 2007-09-13 | 2013-02-13 | 埃克森美孚研究工程公司 | 在线生产增塑聚合物和增塑聚合物共混物的方法 |
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| US7994237B2 (en) | 2007-12-20 | 2011-08-09 | Exxonmobil Research And Engineering Company | In-line process to produce pellet-stable polyolefins |
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| US8318875B2 (en) | 2008-01-18 | 2012-11-27 | Exxonmobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization and polypropylenes made therefrom |
| US9255166B2 (en) | 2008-04-24 | 2016-02-09 | Borealis Ag | High purity heterophasic propylene copolymers |
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| EP2119732A1 (en) | 2008-05-16 | 2009-11-18 | Borealis Technology Oy | Metallocene catalyst compositions with improved properties, process for its preparation and use for preparing polyolefin homo- or copolymers |
| ATE488549T1 (de) | 2008-06-06 | 2010-12-15 | Borealis Ag | Extrusionsbeschichtung einer polyethylenzusammensetzung |
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| CN102066478B (zh) | 2008-06-16 | 2013-04-24 | 博里利斯股份公司 | 通过多级方法生产的具有高流动性和优异的表面质量的热塑性聚烯烃 |
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| WO2010049370A1 (en) | 2008-10-27 | 2010-05-06 | Borealis Ag | Extrusion blown molded bottles with high stiffness and transparency |
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| EP2186831B1 (en) | 2008-11-10 | 2013-01-02 | Borealis AG | Process for the preparation of an unsupported, solid olefin polymerisation catalyst and use in polymerisation of olefins |
| US20100125124A1 (en) * | 2008-11-17 | 2010-05-20 | Fina Technology, Inc. | Methods of catalyst activation |
| EP2186834B1 (en) | 2008-11-18 | 2011-01-12 | Borealis AG | Propylene-hexene random copolymer produced in the presence of a metallocene catalyst |
| US8637625B2 (en) | 2008-11-18 | 2014-01-28 | Borealis Ag | Propylene-butene random copolymer produced in the presence of a metallocene catalyst |
| WO2010057915A1 (en) * | 2008-11-21 | 2010-05-27 | Borealis Ag | Method for improving flowability of heterophasic polypropylene powder |
| US8975333B2 (en) | 2008-11-21 | 2015-03-10 | Borealis Ag | Method for improving flowability of random polypropylene powder |
| EP2216347A1 (en) | 2009-01-30 | 2010-08-11 | Borealis AG | A method of catalyst transitions in olefin polymerizations |
| ATE529450T1 (de) | 2009-02-25 | 2011-11-15 | Borealis Ag | Multimodales polymer aus propylen, zusammensetzung damit und verfahren zur herstellung davon |
| EP2223944A1 (en) | 2009-02-26 | 2010-09-01 | Borealis AG | Process for producing semicrystalline propylene polymers |
| EP2226327A1 (en) | 2009-03-02 | 2010-09-08 | Borealis AG | Preparation of an olefin polymerization catalyst component |
| EP2226337A1 (en) | 2009-03-02 | 2010-09-08 | Borealis AG | Process for the production of polypropylene random copolymers for injection moulding applications |
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| EP2246369B1 (en) | 2009-04-30 | 2012-09-05 | Borealis AG | Linear low density polyethylene with uniform or reversed comonomer composition distribution |
| EP2246372A1 (en) | 2009-04-30 | 2010-11-03 | Borealis AG | Improved multi-stage process for producing multi-modal linear low density polyethylene |
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-
1997
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- 1998-06-24 AT AT98660061T patent/ATE285444T1/de not_active IP Right Cessation
- 1998-06-24 KR KR1019997012304A patent/KR100576928B1/ko not_active Expired - Lifetime
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- 1998-06-24 DE DE69828222T patent/DE69828222T2/de not_active Expired - Lifetime
- 1998-06-24 US US09/103,397 patent/US6455643B1/en not_active Expired - Lifetime
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101796081B (zh) * | 2007-09-03 | 2013-02-06 | 英尼奥斯制造业比利时有限公司 | 淤浆相聚合方法 |
| CN102822265A (zh) * | 2010-02-26 | 2012-12-12 | 博里利斯股份公司 | 用于管件的无规丙烯共聚物 |
| CN102822265B (zh) * | 2010-02-26 | 2014-07-23 | 博里利斯股份公司 | 用于管件的无规丙烯共聚物 |
Also Published As
| Publication number | Publication date |
|---|---|
| NZ502014A (en) | 2002-04-26 |
| IL133651A0 (en) | 2001-04-30 |
| ZA985490B (en) | 1999-01-20 |
| US6455643B1 (en) | 2002-09-24 |
| PL193876B1 (pl) | 2007-03-30 |
| ATE285444T1 (de) | 2005-01-15 |
| EA002782B1 (ru) | 2002-08-29 |
| EP0887379A1 (en) | 1998-12-30 |
| JP3852957B2 (ja) | 2006-12-06 |
| KR100576928B1 (ko) | 2006-05-10 |
| MY124158A (en) | 2006-06-30 |
| FI111848B (fi) | 2003-09-30 |
| PL337714A1 (en) | 2000-08-28 |
| DE69828222D1 (de) | 2005-01-27 |
| AU7921098A (en) | 1999-01-04 |
| DE69828222T2 (de) | 2005-12-08 |
| CZ464699A3 (cs) | 2000-05-17 |
| ES2234087T3 (es) | 2005-06-16 |
| CN1268959A (zh) | 2000-10-04 |
| EP0887379B1 (en) | 2004-12-22 |
| KR20010020518A (ko) | 2001-03-15 |
| EA200000063A1 (ru) | 2000-06-26 |
| TW418214B (en) | 2001-01-11 |
| AU726554B2 (en) | 2000-11-09 |
| FI972726A0 (fi) | 1997-06-24 |
| AR016088A1 (es) | 2001-06-20 |
| CA2295018A1 (en) | 1998-12-30 |
| CA2295018C (en) | 2007-01-30 |
| FI972726A7 (fi) | 1998-12-25 |
| IL133651A (en) | 2006-08-20 |
| BR9810934A (pt) | 2001-11-20 |
| CZ300053B6 (cs) | 2009-01-21 |
| JP2002504953A (ja) | 2002-02-12 |
| WO1998058975A1 (en) | 1998-12-30 |
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