TWI353360B - Production process of polyacrylic acid (salt) wate - Google Patents
Production process of polyacrylic acid (salt) wate Download PDFInfo
- Publication number
- TWI353360B TWI353360B TW095112015A TW95112015A TWI353360B TW I353360 B TWI353360 B TW I353360B TW 095112015 A TW095112015 A TW 095112015A TW 95112015 A TW95112015 A TW 95112015A TW I353360 B TWI353360 B TW I353360B
- Authority
- TW
- Taiwan
- Prior art keywords
- water
- mass
- acrylic acid
- absorbent resin
- ppm
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 44
- 229920002125 Sokalan® Polymers 0.000 title claims description 4
- 239000004584 polyacrylic acid Substances 0.000 title claims description 4
- 150000003839 salts Chemical class 0.000 title description 29
- 239000011347 resin Substances 0.000 claims description 144
- 229920005989 resin Polymers 0.000 claims description 144
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 139
- 239000002250 absorbent Substances 0.000 claims description 131
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 100
- 239000000203 mixture Substances 0.000 claims description 96
- 238000006116 polymerization reaction Methods 0.000 claims description 95
- 238000000034 method Methods 0.000 claims description 76
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 74
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 69
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 53
- 238000010521 absorption reaction Methods 0.000 claims description 48
- 150000002894 organic compounds Chemical class 0.000 claims description 34
- 150000001875 compounds Chemical class 0.000 claims description 33
- 229910052742 iron Inorganic materials 0.000 claims description 26
- -1 compound iron oxide Chemical class 0.000 claims description 25
- 238000004132 cross linking Methods 0.000 claims description 23
- 229920000642 polymer Polymers 0.000 claims description 21
- 239000002253 acid Substances 0.000 claims description 20
- 238000001035 drying Methods 0.000 claims description 19
- 238000012360 testing method Methods 0.000 claims description 19
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 18
- 239000003431 cross linking reagent Substances 0.000 claims description 18
- 229920006037 cross link polymer Polymers 0.000 claims description 16
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 14
- 238000010438 heat treatment Methods 0.000 claims description 12
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 12
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 10
- 230000000379 polymerizing effect Effects 0.000 claims description 8
- RNYZJZKPGHQTJR-UHFFFAOYSA-N protoanemonin Chemical compound C=C1OC(=O)C=C1 RNYZJZKPGHQTJR-UHFFFAOYSA-N 0.000 claims description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 8
- 150000007514 bases Chemical class 0.000 claims description 7
- 239000002504 physiological saline solution Substances 0.000 claims description 7
- 235000019260 propionic acid Nutrition 0.000 claims description 7
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 7
- 235000010290 biphenyl Nutrition 0.000 claims description 6
- 239000004305 biphenyl Substances 0.000 claims description 6
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 6
- 239000002738 chelating agent Substances 0.000 claims description 5
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 5
- 229920006395 saturated elastomer Polymers 0.000 claims description 5
- WJFKNYWRSNBZNX-UHFFFAOYSA-N 10H-phenothiazine Chemical compound C1=CC=C2NC3=CC=CC=C3SC2=C1 WJFKNYWRSNBZNX-UHFFFAOYSA-N 0.000 claims description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 4
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 4
- 239000011976 maleic acid Substances 0.000 claims description 4
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 4
- 229950000688 phenothiazine Drugs 0.000 claims description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 4
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 3
- 230000003472 neutralizing effect Effects 0.000 claims description 3
- 206010036790 Productive cough Diseases 0.000 claims description 2
- 229940125904 compound 1 Drugs 0.000 claims description 2
- 208000024794 sputum Diseases 0.000 claims description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims 3
- LIXVMPBOGDCSRM-UHFFFAOYSA-N nonylbenzene Chemical compound CCCCCCCCCC1=CC=CC=C1 LIXVMPBOGDCSRM-UHFFFAOYSA-N 0.000 claims 2
- JLUQTCXCAFSSLD-NXEZZACHSA-N Anemonin Chemical compound C1=CC(=O)O[C@]11[C@@]2(C=CC(=O)O2)CC1 JLUQTCXCAFSSLD-NXEZZACHSA-N 0.000 claims 1
- JLUQTCXCAFSSLD-UHFFFAOYSA-N Anemonin Natural products C1=CC(=O)OC11C2(C=CC(=O)O2)CC1 JLUQTCXCAFSSLD-UHFFFAOYSA-N 0.000 claims 1
- 240000001076 Osbeckia chinensis Species 0.000 claims 1
- 229920000954 Polyglycolide Polymers 0.000 claims 1
- 241000206469 Pulsatilla Species 0.000 claims 1
- 229910000288 alkali metal carbonate Inorganic materials 0.000 claims 1
- 150000008041 alkali metal carbonates Chemical class 0.000 claims 1
- 229940125782 compound 2 Drugs 0.000 claims 1
- 210000000003 hoof Anatomy 0.000 claims 1
- 239000004633 polyglycolic acid Substances 0.000 claims 1
- 239000000178 monomer Substances 0.000 description 76
- 239000000843 powder Substances 0.000 description 37
- 239000007864 aqueous solution Substances 0.000 description 35
- 239000000243 solution Substances 0.000 description 30
- 230000000704 physical effect Effects 0.000 description 28
- 238000006386 neutralization reaction Methods 0.000 description 26
- 238000009835 boiling Methods 0.000 description 24
- 235000011121 sodium hydroxide Nutrition 0.000 description 22
- 230000002745 absorbent Effects 0.000 description 21
- 239000003513 alkali Substances 0.000 description 19
- 239000002245 particle Substances 0.000 description 19
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 description 18
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 15
- 239000007788 liquid Substances 0.000 description 15
- 238000002156 mixing Methods 0.000 description 15
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 14
- 229910052751 metal Inorganic materials 0.000 description 14
- 239000002184 metal Substances 0.000 description 14
- 239000001301 oxygen Substances 0.000 description 13
- 229910052760 oxygen Inorganic materials 0.000 description 13
- 239000003795 chemical substances by application Substances 0.000 description 11
- 239000000499 gel Substances 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 10
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 9
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 9
- 239000006096 absorbing agent Substances 0.000 description 9
- 238000004821 distillation Methods 0.000 description 9
- LHGVFZTZFXWLCP-UHFFFAOYSA-N guaiacol Chemical class COC1=CC=CC=C1O LHGVFZTZFXWLCP-UHFFFAOYSA-N 0.000 description 9
- 239000012535 impurity Substances 0.000 description 9
- 229920001223 polyethylene glycol Polymers 0.000 description 9
- PQUXFUBNSYCQAL-UHFFFAOYSA-N 1-(2,3-difluorophenyl)ethanone Chemical compound CC(=O)C1=CC=CC(F)=C1F PQUXFUBNSYCQAL-UHFFFAOYSA-N 0.000 description 8
- 239000002585 base Substances 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 8
- 239000001257 hydrogen Substances 0.000 description 8
- 229910052739 hydrogen Inorganic materials 0.000 description 8
- 239000003505 polymerization initiator Substances 0.000 description 8
- 229940047670 sodium acrylate Drugs 0.000 description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 7
- 239000002202 Polyethylene glycol Substances 0.000 description 7
- 239000004743 Polypropylene Substances 0.000 description 7
- 229940048053 acrylate Drugs 0.000 description 7
- 150000001413 amino acids Chemical class 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 6
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 6
- 239000004593 Epoxy Substances 0.000 description 6
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 238000007792 addition Methods 0.000 description 6
- 239000000017 hydrogel Substances 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 229920000768 polyamine Polymers 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 6
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 6
- 229920003169 water-soluble polymer Polymers 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
- 150000001299 aldehydes Chemical class 0.000 description 5
- 238000004040 coloring Methods 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 239000003112 inhibitor Substances 0.000 description 5
- 239000003960 organic solvent Substances 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 239000012071 phase Substances 0.000 description 5
- 229920005862 polyol Polymers 0.000 description 5
- 239000011780 sodium chloride Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- CYUZOYPRAQASLN-UHFFFAOYSA-N 3-prop-2-enoyloxypropanoic acid Chemical compound OC(=O)CCOC(=O)C=C CYUZOYPRAQASLN-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
- 239000003638 chemical reducing agent Substances 0.000 description 4
- 238000002425 crystallisation Methods 0.000 description 4
- 230000008025 crystallization Effects 0.000 description 4
- 230000006866 deterioration Effects 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 229910001385 heavy metal Inorganic materials 0.000 description 4
- 150000002431 hydrogen Chemical class 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 238000010557 suspension polymerization reaction Methods 0.000 description 4
- 238000004448 titration Methods 0.000 description 4
- 239000012808 vapor phase Substances 0.000 description 4
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000011358 absorbing material Substances 0.000 description 3
- 230000004520 agglutination Effects 0.000 description 3
- 150000001339 alkali metal compounds Chemical class 0.000 description 3
- 235000001014 amino acid Nutrition 0.000 description 3
- 150000003863 ammonium salts Chemical class 0.000 description 3
- 229960005070 ascorbic acid Drugs 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000013522 chelant Substances 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- 239000003999 initiator Substances 0.000 description 3
- 238000000691 measurement method Methods 0.000 description 3
- 239000007800 oxidant agent Substances 0.000 description 3
- 150000003077 polyols Chemical class 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 238000007873 sieving Methods 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 238000010025 steaming Methods 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 238000004383 yellowing Methods 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- QEGNUYASOUJEHD-UHFFFAOYSA-N 1,1-dimethylcyclohexane Chemical compound CC1(C)CCCCC1 QEGNUYASOUJEHD-UHFFFAOYSA-N 0.000 description 2
- HXVNBWAKAOHACI-UHFFFAOYSA-N 2,4-dimethyl-3-pentanone Chemical compound CC(C)C(=O)C(C)C HXVNBWAKAOHACI-UHFFFAOYSA-N 0.000 description 2
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 2
- RAEOEMDZDMCHJA-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-[2-[2-[bis(carboxymethyl)amino]ethyl-(carboxymethyl)amino]ethyl]amino]acetic acid Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CCN(CC(O)=O)CC(O)=O)CC(O)=O RAEOEMDZDMCHJA-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- PVXLNYCCPHJLIA-UHFFFAOYSA-N C(CCCCCCCCC)OCCCCCCCCCC.C=CC Chemical compound C(CCCCCCCCC)OCCCCCCCCCC.C=CC PVXLNYCCPHJLIA-UHFFFAOYSA-N 0.000 description 2
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical class OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 239000002211 L-ascorbic acid Substances 0.000 description 2
- 235000000069 L-ascorbic acid Nutrition 0.000 description 2
- RJKFOVLPORLFTN-LEKSSAKUSA-N Progesterone Chemical compound C1CC2=CC(=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H](C(=O)C)[C@@]1(C)CC2 RJKFOVLPORLFTN-LEKSSAKUSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000007983 Tris buffer Substances 0.000 description 2
- 150000001491 aromatic compounds Chemical class 0.000 description 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- 125000006267 biphenyl group Chemical group 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 125000006612 decyloxy group Chemical group 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000010894 electron beam technology Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 235000019441 ethanol Nutrition 0.000 description 2
- IIEWJVIFRVWJOD-UHFFFAOYSA-N ethylcyclohexane Chemical compound CCC1CCCCC1 IIEWJVIFRVWJOD-UHFFFAOYSA-N 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 238000007602 hot air drying Methods 0.000 description 2
- 230000006698 induction Effects 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 238000011031 large-scale manufacturing process Methods 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 238000004811 liquid chromatography Methods 0.000 description 2
- 229910000000 metal hydroxide Inorganic materials 0.000 description 2
- 150000004692 metal hydroxides Chemical class 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 150000002923 oximes Chemical class 0.000 description 2
- 229930195143 oxyphenol Natural products 0.000 description 2
- FDPIMTJIUBPUKL-UHFFFAOYSA-N pentan-3-one Chemical compound CCC(=O)CC FDPIMTJIUBPUKL-UHFFFAOYSA-N 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
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- 230000005855 radiation Effects 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 1
- QNODIIQQMGDSEF-UHFFFAOYSA-N (1-hydroxycyclohexyl)-phenylmethanone Chemical compound C=1C=CC=CC=1C(=O)C1(O)CCCCC1 QNODIIQQMGDSEF-UHFFFAOYSA-N 0.000 description 1
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
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- C08F20/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
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- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/42—Use of materials characterised by their function or physical properties
- A61L15/60—Liquid-swellable gel-forming materials, e.g. super-absorbents
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/01—Hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
- C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
- C08F222/102—Esters of polyhydric alcohols or polyhydric phenols of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate
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Families Citing this family (78)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI353360B (en) | 2005-04-07 | 2011-12-01 | Nippon Catalytic Chem Ind | Production process of polyacrylic acid (salt) wate |
| EP1869119B1 (en) * | 2005-04-12 | 2010-03-03 | Nippon Shokubai Co., Ltd. | Particulate water absorbing agent including polyacrylic acid (polyacrylate) based water absorbing resin as a principal component, method for production thereof, water-absorbent core and absorbing article in which the particulate water absorbing agent is used |
| CN101175632B (zh) | 2005-05-13 | 2010-04-14 | 旭化成化学株式会社 | 吸收性复合体及其制造方法 |
| DE102005042608A1 (de) † | 2005-09-07 | 2007-03-08 | Basf Ag | Polymerisationsverfahren |
| TWI394789B (zh) | 2005-12-22 | 2013-05-01 | Nippon Catalytic Chem Ind | 吸水性樹脂組成物及其製造方法、吸收性物品 |
| EP1837348B9 (en) | 2006-03-24 | 2020-01-08 | Nippon Shokubai Co.,Ltd. | Water-absorbing resin and method for manufacturing the same |
| DE602007003397D1 (de) | 2006-03-29 | 2010-01-07 | Nippon Catalytic Chem Ind | Verfahren zur Herstellung von wasserabsorbierendem Polyacrylsäure (Salz)-Harz |
| CN101516925B (zh) | 2006-09-19 | 2011-06-15 | 巴斯夫欧洲公司 | 生产具有低中和度的颜色稳定的吸水性聚合物颗粒的方法 |
| CN102675522B (zh) * | 2007-02-05 | 2014-11-19 | 株式会社日本触媒 | 粒子状吸水剂的制造方法 |
| DE102007045724B4 (de) | 2007-09-24 | 2012-01-26 | Evonik Stockhausen Gmbh | Superabsorbierende Zusammensetzung mit Tanninen zur Geruchskontrolle, Verfahren zu deren Herstellung und Verwendung |
| WO2009130915A1 (ja) * | 2008-04-25 | 2009-10-29 | 株式会社日本触媒 | ポリアクリル酸（塩）系吸水性樹脂およびその製造方法 |
| JP5380434B2 (ja) * | 2008-04-27 | 2014-01-08 | 株式会社日本触媒 | アクリル酸の製造方法ならびにその製造方法を用いた親水性樹脂の製造方法および吸水性樹脂の製造方法 |
| TWI500636B (zh) * | 2008-10-07 | 2015-09-21 | Evonik Degussa Gmbh | 用於製造超吸性聚合物的方法 |
| KR101371932B1 (ko) * | 2008-10-09 | 2014-03-14 | 주식회사 엘지화학 | 흡수성 수지의 흡수 속도를 조절하는 방법 및 그에 의해 흡수 속도가 조절된 흡수성 수지 |
| WO2010052182A1 (de) * | 2008-11-07 | 2010-05-14 | Basf Se | Verfahren zur herstellung wasserabsorbierender polymerpartikel |
| WO2010090324A1 (ja) * | 2009-02-06 | 2010-08-12 | 株式会社日本触媒 | ポリアクリル酸（塩）系吸水性樹脂およびその製造方法 |
| RU2523796C2 (ru) * | 2009-05-15 | 2014-07-27 | Ниппон Сокубаи Ко., Лтд. | Способ получения (мет)акриловой кислоты |
| US8252857B2 (en) * | 2009-05-15 | 2012-08-28 | Basf Se | Process for producing odor-inhibiting water-absorbing polymer particles |
| US9138505B2 (en) | 2009-08-27 | 2015-09-22 | Nippon Shokubai Co., Ltd. | Polyacrylic acid (salt)-type water absorbent resin and method for producing of same |
| JP5616347B2 (ja) | 2009-08-28 | 2014-10-29 | 株式会社日本触媒 | 吸水性樹脂の製造方法 |
| WO2011040472A1 (ja) | 2009-09-29 | 2011-04-07 | 株式会社日本触媒 | 粒子状吸水剤及びその製造方法 |
| JP5731390B2 (ja) * | 2009-09-30 | 2015-06-10 | 株式会社日本触媒 | ポリアクリル酸（塩）系吸水性樹脂およびその製造方法 |
| EP2504038A1 (de) | 2009-11-23 | 2012-10-03 | Basf Se | Verfahren zur herstellung wasserabsorbierender polymerer schäume |
| WO2011061315A1 (de) * | 2009-11-23 | 2011-05-26 | Basf Se | Verfahren zur herstellung wasserabsorbierender, aufgeschäumter polymerpartikel |
| US8623994B2 (en) | 2010-01-20 | 2014-01-07 | Nippon Shokubai, Co., Ltd. | Method for producing water absorbent resin |
| EP2527391B1 (en) | 2010-01-20 | 2023-08-09 | Nippon Shokubai Co., Ltd. | Method for producing water absorbent resin |
| WO2011111657A1 (ja) * | 2010-03-08 | 2011-09-15 | 株式会社日本触媒 | 粒子状含水ゲル状架橋重合体の乾燥方法 |
| EP2371869A1 (en) | 2010-03-30 | 2011-10-05 | Evonik Stockhausen GmbH | A process for the production of a superabsorbent polymer |
| JP5587409B2 (ja) | 2010-06-08 | 2014-09-10 | 株式会社日本触媒 | 粒子状吸水性樹脂の製造方法 |
| US8571499B1 (en) * | 2010-10-12 | 2013-10-29 | Harold Kirkpatrick | Wireless terrestrial communications systems using a line-of-sight frequency for inbound data and a non-line-of-sight frequency for outbound data |
| WO2012091114A1 (ja) | 2010-12-28 | 2012-07-05 | 株式会社日本触媒 | アクリル酸および／またはそのエステルおよびその重合体の製法 |
| EP2700667B1 (en) | 2011-04-20 | 2017-08-09 | Nippon Shokubai Co., Ltd. | Process and apparatus for producing water-absorbable resin of polyacrylic acid (salt) type |
| US20120296297A1 (en) * | 2011-05-18 | 2012-11-22 | Achille Di Cintio | Feminine hygiene absorbent articles comprising water-absorbing polymeric foams |
| DE102011076931A1 (de) | 2011-06-03 | 2012-12-06 | Basf Se | Wässrige Lösung, enthaltend Acrylsäure und deren konjugierte Base |
| CN102492088B (zh) * | 2011-12-02 | 2013-08-21 | 南京大学 | 一种水凝胶及制备方法及其在重金属废水处理中的应用 |
| EP2812365A1 (de) | 2012-02-06 | 2014-12-17 | Basf Se | Verfahren zur herstellung wasserabsorbierender polymerpartikel |
| US20130200305A1 (en) * | 2012-02-06 | 2013-08-08 | Basf Se | Process for Producing Water-Absorbing Polymer Particles |
| KR102000808B1 (ko) | 2012-02-17 | 2019-07-16 | 가부시키가이샤 닛폰 쇼쿠바이 | 폴리아크릴산(염)계 흡수성 수지 및 그의 제조 방법 |
| WO2013137277A1 (ja) * | 2012-03-14 | 2013-09-19 | 株式会社日本触媒 | ３－ヒドロキシプロピオン酸の製造方法、遺伝子組換え微生物、並びに前記方法を利用したアクリル酸、吸水性樹脂、アクリル酸エステル、およびアクリル酸エステル樹脂の製造方法 |
| WO2014059056A1 (en) | 2012-10-09 | 2014-04-17 | Avery Dennison Corporation | Adhesives and related methods |
| JP5883948B2 (ja) | 2012-11-27 | 2016-03-15 | 株式会社日本触媒 | ポリアクリル酸（塩）系吸水性樹脂の製造方法 |
| CA2905602A1 (en) * | 2013-03-15 | 2014-09-18 | Sarah M. Hoyt | Flash evaporation for product purification and recovery |
| JP2016512688A (ja) | 2013-03-15 | 2016-05-09 | カーギル・インコーポレイテッド | ３−ヒドロキシプロピオン酸の回収 |
| CN105229059B (zh) * | 2013-05-10 | 2019-01-04 | 株式会社日本触媒 | 聚丙烯酸(盐)系吸水性树脂的制造方法 |
| KR102373063B1 (ko) | 2013-10-09 | 2022-03-11 | 가부시키가이샤 닛폰 쇼쿠바이 | 흡수성 수지를 주성분으로 하는 입자상 흡수제 및 그의 제조 방법 |
| JP2017006808A (ja) | 2013-11-14 | 2017-01-12 | 株式会社日本触媒 | ポリアクリル酸（塩）系吸水性樹脂の製造方法 |
| JP6521668B2 (ja) * | 2014-02-28 | 2019-05-29 | 株式会社日本触媒 | ポリアクリル酸（塩）系吸水性樹脂の製造方法 |
| US20150322626A1 (en) * | 2014-05-06 | 2015-11-12 | Weyerhaeuser Nr Company | Reduced furfural content in polyacrylic acid crosslinked cellulose fibers |
| US9205405B2 (en) | 2014-05-06 | 2015-12-08 | The Procter & Gamble Company | Reduced furfural content in polyacrylic acid crosslinked cellulose fibers used in absorbent articles |
| KR101725950B1 (ko) * | 2014-06-23 | 2017-04-12 | 주식회사 엘지화학 | 수용성 염을 포함하는 고흡수성 수지 및 그 제조 방법 |
| US10696890B2 (en) | 2014-09-30 | 2020-06-30 | Nippon Shokubai Co., Ltd. | Methods of liquefying and shrinking water-absorbable resins in a water-containing state |
| KR102348349B1 (ko) | 2015-01-07 | 2022-01-10 | 가부시키가이샤 닛폰 쇼쿠바이 | 흡수제 및 그의 제조 방법, 그리고 평가 방법 및 측정 방법 |
| MX2017010047A (es) | 2015-02-05 | 2017-12-18 | Avery Dennison Corp | Conjuntos de etiquetas para entornos adversos. |
| KR101949996B1 (ko) * | 2016-01-28 | 2019-02-19 | 주식회사 엘지화학 | 고흡수성 수지의 제조 방법 |
| KR102056302B1 (ko) | 2016-03-24 | 2019-12-16 | 주식회사 엘지화학 | 고흡수성 수지 섬유의 제조 방법 |
| EP3437730B1 (en) | 2016-03-28 | 2024-04-17 | Nippon Shokubai Co., Ltd. | Method for manufacturing water absorbing agent |
| US11602577B2 (en) | 2016-03-28 | 2023-03-14 | Nippon Shokubai Co., Ltd. | Water-absorbing agent and method for producing same, and absorbent article produced using water-absorbing agent |
| CN109310986B (zh) | 2016-03-28 | 2022-03-15 | 株式会社日本触媒 | 颗粒状吸水剂 |
| EP3308857B1 (en) * | 2016-10-11 | 2020-07-08 | LANXESS Deutschland GmbH | Strong basic polyacrylate anion exchangers |
| US10526511B2 (en) | 2016-12-22 | 2020-01-07 | Avery Dennison Corporation | Convertible pressure sensitive adhesives comprising urethane (meth)acrylate oligomers |
| EP3586957B1 (en) | 2017-02-22 | 2022-03-30 | Nippon Shokubai Co., Ltd. | Absorbent article comprising water-absorbing sheet |
| KR102487977B1 (ko) | 2017-07-28 | 2023-01-11 | 주식회사 엘지화학 | 고흡수성 수지 및 그 제조 방법 |
| JPWO2019074094A1 (ja) | 2017-10-12 | 2020-11-05 | 株式会社日本触媒 | 粒子状吸水剤の物性の測定方法及び粒子状吸水剤 |
| WO2019098244A1 (ja) | 2017-11-16 | 2019-05-23 | 株式会社日本触媒 | 吸水剤および吸収性物品 |
| KR102356629B1 (ko) * | 2017-11-24 | 2022-01-26 | 주식회사 엘지화학 | 고흡수성 수지 조성물 |
| US12201962B2 (en) | 2018-11-07 | 2025-01-21 | Nippon Shokubai Co., Ltd. | Method for producing particulate water absorbent, and particulate water absorbent |
| EP3909674A4 (en) | 2019-01-11 | 2022-09-28 | Nippon Shokubai Co., Ltd. | WATER-ABSORBENT AGENT AND PROCESS FOR THE MANUFACTURE OF A WATER-ABSORBENT AGENT |
| EP3910004A4 (en) | 2019-01-11 | 2022-10-12 | Nippon Shokubai Co., Ltd. | ABSORBENT AGENT HAVING AN ABSORBENT RESIN AS A MAIN COMPONENT, AND METHOD FOR MAKING THE SAME |
| JP7253618B2 (ja) | 2019-05-31 | 2023-04-06 | 株式会社日本触媒 | 吸水剤の製造方法及びポリアクリル酸（塩）系吸水性樹脂 |
| JP7695893B2 (ja) * | 2019-12-23 | 2025-06-19 | 住友精化株式会社 | 吸水性樹脂粒子、吸収体及び吸収性物品 |
| JP7382493B2 (ja) | 2020-03-31 | 2023-11-16 | 株式会社日本触媒 | 粒子状吸水剤 |
| WO2022181771A1 (ja) | 2021-02-26 | 2022-09-01 | 株式会社日本触媒 | 粒子状吸水剤、該吸水剤を含む吸収体及び該吸収体を用いた吸収性物品 |
| WO2023149576A1 (ja) | 2022-02-04 | 2023-08-10 | 株式会社日本触媒 | リサイクル吸水性樹脂を含む吸水性樹脂の製造方法、およびその利用 |
| CN118510612A (zh) | 2022-02-04 | 2024-08-16 | 株式会社日本触媒 | 吸水性树脂的循环再利用方法及吸水性树脂的制造方法 |
| JP7756731B2 (ja) | 2022-02-04 | 2025-10-20 | 株式会社日本触媒 | 吸水性樹脂の重合方法 |
| WO2024101349A1 (ja) | 2022-11-07 | 2024-05-16 | 株式会社日本触媒 | 可溶化ポリマーの製造方法および吸水性樹脂の製造方法 |
| CN116554791A (zh) * | 2023-05-04 | 2023-08-08 | 昆山石梅新材料科技有限公司 | 一种耐黄变高粘结oca光学胶及其制备方法 |
| CN119702075B (zh) * | 2023-12-13 | 2025-11-21 | 中国科学院大连化学物理研究所 | 金属改性树脂催化剂、制备及其在丙烯酸水合中的应用 |
Family Cites Families (465)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US625488A (en) | 1899-05-23 | auspitz | ||
| US632352A (en) | 1899-06-23 | 1899-09-05 | George W Jones | Pan or lid lifter. |
| US670141A (en) | 1900-11-20 | 1901-03-19 | William Otis Shepard | Policeman's club. |
| US922717A (en) | 1909-03-05 | 1909-05-25 | George H Parker | Game. |
| US955086A (en) | 1909-07-09 | 1910-04-12 | Julius Laux | Post-anchor. |
| CA797095A (en) | 1962-02-09 | 1968-10-22 | Doebl Hans | Method of and machine for the continuous treatment of plastic paste |
| CH434208A (de) | 1965-08-14 | 1967-04-30 | List Heinz | Misch- und Knetmaschine mit scheibenförmigen Knetelementen |
| AT279547B (de) | 1967-04-14 | 1970-03-10 | Buchs Metallwerk Ag | Verfahren und Vorrichtung zur Trennung oder Reinigung schmelzflüssiger, flüssiger oder gelöster Stoffe durch fraktioniertes Kristallisieren |
| US3959569A (en) | 1970-07-27 | 1976-05-25 | The Dow Chemical Company | Preparation of water-absorbent articles |
| JPS5538863Y2 (enExample) | 1973-05-22 | 1980-09-10 | ||
| US3935099A (en) | 1974-04-03 | 1976-01-27 | The United States Of America As Represented By The Secretary Of Agriculture | Method of reducing water content of emulsions, suspensions, and dispersions with highly absorbent starch-containing polymeric compositions |
| JPS5166166A (ja) | 1974-12-06 | 1976-06-08 | Hitachi Ltd | Sentakuki |
| US4090013A (en) | 1975-03-07 | 1978-05-16 | National Starch And Chemical Corp. | Absorbent composition of matter |
| JPS51125468A (en) | 1975-03-27 | 1976-11-01 | Sanyo Chem Ind Ltd | Method of preparing resins of high water absorbency |
| US4043952A (en) | 1975-05-09 | 1977-08-23 | National Starch And Chemical Corporation | Surface treatment process for improving dispersibility of an absorbent composition, and product thereof |
| JPS5437188Y2 (enExample) | 1975-05-16 | 1979-11-08 | ||
| JPS5265597A (en) | 1975-11-27 | 1977-05-31 | Sumitomo Chem Co Ltd | Preparation of high polimeric materials with improved water absorption |
| JPS5346389A (en) | 1976-10-07 | 1978-04-25 | Kao Corp | Preparation of self-crosslinking polymer of acrylic alkali metal salt |
| NZ188633A (en) | 1977-10-18 | 1980-10-24 | Unilever Ltd | Absorbent material surface-treated with polyether |
| JPS6055002B2 (ja) | 1977-12-16 | 1985-12-03 | エヌ・テ−・エヌ東洋ベアリング株式会社 | 曲率測定装置 |
| US4224427A (en) | 1978-06-01 | 1980-09-23 | Ciba-Geigy Corporation | Process for preparing hydrogels as spherical beads of large size |
| CA1134977A (en) | 1978-09-07 | 1982-11-02 | Sumitomo Chemical Co., Ltd. | Method for preparing highly absorbent polymers |
| JPS6024807B2 (ja) | 1979-02-19 | 1985-06-14 | 昭和電工株式会社 | 高吸水性ヒドロゲルの製造方法 |
| JPS55133413U (enExample) | 1979-03-14 | 1980-09-22 | ||
| US4286082A (en) | 1979-04-06 | 1981-08-25 | Nippon Shokubai Kagaku Kogyo & Co., Ltd. | Absorbent resin composition and process for producing same |
| JPS56133028U (enExample) | 1980-03-08 | 1981-10-08 | ||
| JPS5924570Y2 (ja) | 1980-03-18 | 1984-07-20 | 株式会社デンソー | 車両用冷房装置 |
| JPS6116903Y2 (enExample) | 1980-06-16 | 1986-05-24 | ||
| JPS5773007U (enExample) | 1980-10-16 | 1982-05-06 | ||
| JPS6056724B2 (ja) | 1980-10-22 | 1985-12-11 | 株式会社クラレ | 吸水性樹脂の製造方法 |
| JPS5794011U (enExample) | 1980-11-29 | 1982-06-09 | ||
| JPS627745Y2 (enExample) | 1980-11-29 | 1987-02-23 | ||
| GB2088392B (en) * | 1980-12-03 | 1984-05-02 | Sumitomo Chemical Co | Production of hydrogels |
| JPS57158209A (en) | 1981-03-25 | 1982-09-30 | Kao Corp | Production of bead-form highly water-absorbing polymer |
| JPS57158209U (enExample) | 1981-03-31 | 1982-10-05 | ||
| DE3128100C2 (de) | 1981-07-16 | 1986-05-22 | Chemische Fabrik Stockhausen GmbH, 4150 Krefeld | Absorptionsmittel für Blut und seröse Körperflüssigkeiten |
| US4985518A (en) | 1981-10-26 | 1991-01-15 | American Colloid Company | Process for preparing water-absorbing resins |
| US4755562A (en) | 1986-06-10 | 1988-07-05 | American Colloid Company | Surface treated absorbent polymers |
| JPS58180233A (ja) | 1982-04-19 | 1983-10-21 | Nippon Shokubai Kagaku Kogyo Co Ltd | 吸収剤 |
| JPS58180233U (ja) | 1982-05-24 | 1983-12-02 | 猶原 通正 | 整形兼セフテイクツシヨンと保温のエア−パツド |
| GB2126591B (en) | 1982-09-02 | 1986-07-30 | Kao Corp | Process for producing highly water absorptive polymer |
| JPS5962665A (ja) * | 1982-09-02 | 1984-04-10 | Kao Corp | 高吸水性ポリマ−の製造法 |
| JPS5962665U (ja) | 1982-10-19 | 1984-04-24 | 株式会社東芝 | 安定器内蔵形放電灯 |
| JPS5980459U (ja) | 1982-11-25 | 1984-05-31 | 石川島播磨重工業株式会社 | 溶融金属中の不純物除去装置 |
| JPS59103314A (ja) | 1982-12-03 | 1984-06-14 | Seiko Instr & Electronics Ltd | 光磁気記録媒体 |
| JPS5992204U (ja) | 1982-12-14 | 1984-06-22 | 山陽国策パルプ株式会社 | ダイヤフラム式アクチユエ−タ |
| US4416711A (en) | 1982-12-17 | 1983-11-22 | Ireco Chemicals | Perchlorate slurry explosive |
| US4455284A (en) | 1983-01-18 | 1984-06-19 | Vsesojuzny Nauchnoissledovatelsky I Proektny Institut Aljuminievoi, Magnievoi I Elektrodnoi Promyshlennosti | Process for desilication of aluminate solution |
| JPS59129232U (ja) | 1983-02-18 | 1984-08-30 | 三洋電機株式会社 | ロツドアンテナのリ−ド線取付装置 |
| US4558091A (en) | 1983-05-13 | 1985-12-10 | Grain Processing Corporation | Method for preparing aluminum and polyhydric alcohol modified liquid absorbing composition |
| US4526937A (en) | 1983-08-31 | 1985-07-02 | The B. F. Goodrich Company | Polycarbonates having plasticizers with fugitive activity |
| JPS6071623U (ja) | 1983-10-18 | 1985-05-21 | 宇都宮 佐喜子 | 内側物入れケ−ス |
| JPS60163956A (ja) | 1984-02-04 | 1985-08-26 | Arakawa Chem Ind Co Ltd | 吸水性樹脂の製法 |
| JPS60158861U (ja) | 1984-03-28 | 1985-10-22 | ニチエイ産業株式会社 | 美容器具 |
| JPS60163956U (ja) | 1984-04-08 | 1985-10-31 | 服部 宅男 | フインガ運動具 |
| JPS60245608A (ja) | 1984-05-22 | 1985-12-05 | Nippon Kayaku Co Ltd | ビニル重合体の製造法 |
| JPS61314A (ja) | 1984-06-14 | 1986-01-06 | ト−ソ−株式会社 | カ−テンモ−タ制御装置 |
| US4734478A (en) | 1984-07-02 | 1988-03-29 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Water absorbing agent |
| US4625001A (en) | 1984-09-25 | 1986-11-25 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Method for continuous production of cross-linked polymer |
| JPS6187702A (ja) | 1984-10-05 | 1986-05-06 | Seitetsu Kagaku Co Ltd | 吸水性樹脂の製造方法 |
| JPS6187702U (enExample) | 1984-11-15 | 1986-06-09 | ||
| JPH0438911Y2 (enExample) | 1984-11-29 | 1992-09-11 | ||
| US4703486A (en) | 1984-12-18 | 1987-10-27 | Advanced Micro Devices, Inc. | Communication data encoder/decoder component system architecture |
| JPS61153110A (ja) | 1984-12-27 | 1986-07-11 | Fuji Electric Co Ltd | 瀘過濃縮装置の瀘過板の固定方法 |
| US4748076A (en) | 1985-02-16 | 1988-05-31 | Hayashikane Shipbuilding & Engineering Co., Ltd. | Water absorbent fibrous product and a method of producing the same |
| JPS61257235A (ja) | 1985-05-08 | 1986-11-14 | Sanyo Chem Ind Ltd | 吸水性樹脂組成物 |
| JPS61265371A (ja) | 1985-05-17 | 1986-11-25 | Shimadzu Corp | 送液ポンプ |
| JPS61275355A (ja) | 1985-05-29 | 1986-12-05 | Kao Corp | 吸収性物品 |
| US4654039A (en) * | 1985-06-18 | 1987-03-31 | The Proctor & Gamble Company | Hydrogel-forming polymer compositions for use in absorbent structures |
| USRE32649E (en) | 1985-06-18 | 1988-04-19 | The Procter & Gamble Company | Hydrogel-forming polymer compositions for use in absorbent structures |
| US4686479A (en) | 1985-07-22 | 1987-08-11 | Young Chung C | Apparatus and control kit for analyzing blood sample values including hematocrit |
| US4690996A (en) | 1985-08-28 | 1987-09-01 | National Starch And Chemical Corporation | Inverse emulsions |
| DE3537276A1 (de) | 1985-10-19 | 1987-04-23 | Basf Ag | Verfahren zur kontinuierlichen herstellung von vernetzten feinteiligen gelfoermigen polymerisaten |
| JPH0639485Y2 (ja) | 1986-12-10 | 1994-10-12 | キヤノン株式会社 | 電気機器 |
| US4771105A (en) | 1986-02-05 | 1988-09-13 | Sekisui Kaseihin Kogyo Kabushiki Kaisha | Water-absorbent resin and process for producing the same |
| JPS63270741A (ja) | 1986-02-05 | 1988-11-08 | Sekisui Plastics Co Ltd | ポリアクリル酸系吸水性樹脂の製造方法 |
| JPH0331306Y2 (enExample) | 1986-02-28 | 1991-07-03 | ||
| US4652001A (en) | 1986-03-10 | 1987-03-24 | Gordon Rathbun | Chuck key assembly |
| DE3609545A1 (de) | 1986-03-21 | 1987-09-24 | Basf Ag | Verfahren zur diskontinuierlichen herstellung von vernetzten, feinteiligen polymerisaten |
| JPH0629294B2 (ja) | 1986-05-19 | 1994-04-20 | 日本合成化学工業株式会社 | 高吸水性樹脂の製造法 |
| JPH078883B2 (ja) | 1986-06-04 | 1995-02-01 | 大洋漁業株式会社 | 改質吸水性樹脂の製造方法 |
| US4783510A (en) | 1986-06-04 | 1988-11-08 | Taiyo Fishery Co., Ltd. | Process for improving a water absorbent polyacrylic acid polymer and an improved polymer produced by said process |
| US4863989A (en) | 1986-06-04 | 1989-09-05 | Seitetsu Kagaku Co., Ltd. | Water-absorbent resin composition |
| JPH0647626B2 (ja) | 1986-07-01 | 1994-06-22 | 三菱油化株式会社 | 吸水性複合材料の製造法 |
| JPS63105064U (enExample) | 1986-12-25 | 1988-07-07 | ||
| IL81975A0 (en) | 1987-03-24 | 1987-10-20 | Haifa Chemicals Ltd | Method for the manufacture of slow-release fertilizers |
| JPS63297408A (ja) | 1987-05-29 | 1988-12-05 | Toho Chem Ind Co Ltd | 改良された高吸水性樹脂の製造方法 |
| US5190815A (en) | 1987-06-09 | 1993-03-02 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Waterproofing tape comprising ethylenic sulfonate polymers |
| EP0303440B1 (en) | 1987-08-10 | 1992-07-22 | Nippon Shokubai Co., Ltd. | Method for production of water absorbent resin |
| KR0130652B1 (ko) | 1987-08-14 | 1998-04-07 | 존 휴즈 | 수분 흡수성 수지의 제조 방법 |
| IT1226741B (it) | 1987-08-19 | 1991-02-05 | Procter & Gamble | Strutture assorbenti con agente gelificante e articoli assorbenti contenenti tali strutture. |
| US5061259A (en) | 1987-08-19 | 1991-10-29 | The Procter & Gamble Company | Absorbent structures with gelling agent and absorbent articles containing such structures |
| JPH0620408Y2 (ja) | 1987-10-06 | 1994-06-01 | 月星化成株式会社 | ゴルフ靴底用モールド |
| JP2530668B2 (ja) | 1987-11-12 | 1996-09-04 | 株式会社日本触媒 | 改良された吸水性樹脂の製造法 |
| DE3741158A1 (de) | 1987-12-04 | 1989-06-15 | Stockhausen Chem Fab Gmbh | Polymerisate mit hoher aufnahmegeschwindigkeit fuer wasser und waessrige fluessigkeiten, verfahren zu ihrer herstellung und verwendung als absorptionsmittel |
| DK157899C (da) | 1987-12-15 | 1990-09-03 | Coloplast As | Hudpladeprodukt |
| JPH0611926Y2 (ja) | 1988-02-23 | 1994-03-30 | 村田機械株式会社 | 物品移載装置 |
| CA1321062C (en) | 1988-04-21 | 1993-08-10 | Stanley Roy Kellenberger | Absorbent products containing hydrogels with ability to swell against pressure |
| US5147343B1 (en) | 1988-04-21 | 1998-03-17 | Kimberly Clark Co | Absorbent products containing hydrogels with ability to swell against pressure |
| CA1333439C (en) | 1988-05-23 | 1994-12-06 | Akito Yano | Method for production of hydrophilic polymer |
| JPH0641319Y2 (ja) | 1988-06-03 | 1994-10-26 | オムロン株式会社 | 電磁継電器 |
| US5244735A (en) | 1988-06-28 | 1993-09-14 | Nippon Shokubai Kagaku Kabushiki Kaisha | Water-absorbent resin and production process |
| US6087002A (en) | 1988-06-28 | 2000-07-11 | Nippon Shokubai Kagaku Kogyo Co. Ltd. | Water absorbent resin |
| KR930007272B1 (ko) | 1988-06-28 | 1993-08-04 | 닙본 쇼쿠바이 가브시기 가이샤 | 흡수성 수지 및 그 제법 |
| TW201758B (enExample) | 1988-06-28 | 1993-03-11 | Catalyst co ltd | |
| JPH0625209B2 (ja) | 1988-07-04 | 1994-04-06 | 株式会社日本触媒 | 吸水性樹脂およびその製造方法 |
| JPH0826085B2 (ja) | 1988-12-08 | 1996-03-13 | 株式会社日本触媒 | 耐久性の優れた吸水性樹脂の製造方法 |
| RU2015141C1 (ru) | 1988-12-08 | 1994-06-30 | Ниппон Сокубаи Кагаку Когио Ко., Лтд. | Способ получения абсорбирующей смолы |
| US4950692A (en) | 1988-12-19 | 1990-08-21 | Nalco Chemical Company | Method for reconstituting superabsorbent polymer fines |
| US5002986A (en) | 1989-02-28 | 1991-03-26 | Hoechst Celanese Corporation | Fluid absorbent compositions and process for their preparation |
| US4948818A (en) | 1989-05-15 | 1990-08-14 | Dow Corning Corporation | Method of making porous hydrophilic-lipophilic copolymeric powders |
| US5185413A (en) | 1989-05-16 | 1993-02-09 | Mitsubishi Petrochemical Company Limited | Process for producing highly water-absortive polymers |
| JP2922216B2 (ja) | 1989-05-16 | 1999-07-19 | 三菱化学株式会社 | 高吸水性ポリマー製造法 |
| JPH07119246B2 (ja) | 1989-06-29 | 1995-12-20 | 東亞合成株式会社 | 吸水性樹脂の製造方法 |
| DE69030971T2 (de) | 1989-09-04 | 1997-12-11 | Nippon Catalytic Chem Ind | Verfahren zur herstellung eines wasserabsorbierenden harzes |
| US5453323A (en) | 1989-09-28 | 1995-09-26 | Hoechst Celanese Corporation | Superabsorbent polymer having improved absorbency properties |
| US5145906A (en) | 1989-09-28 | 1992-09-08 | Hoechst Celanese Corporation | Super-absorbent polymer having improved absorbency properties |
| JPH0680818B2 (ja) | 1989-10-02 | 1994-10-12 | 株式会社東芝 | 電力用圧接型半導体装置 |
| JP2877255B2 (ja) | 1989-12-08 | 1999-03-31 | 株式会社日本触媒 | 耐久性の優れた吸水性樹脂の製造方法 |
| US5030205A (en) | 1989-12-18 | 1991-07-09 | Critikon, Inc. | Catheter assemblies for prevention of blood leakage |
| JPH0395204U (enExample) | 1990-01-16 | 1991-09-27 | ||
| JP2938920B2 (ja) | 1990-01-31 | 1999-08-25 | 住友精化株式会社 | 吸水性樹脂の製造方法 |
| US5149335A (en) | 1990-02-23 | 1992-09-22 | Kimberly-Clark Corporation | Absorbent structure |
| US5164459A (en) | 1990-04-02 | 1992-11-17 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Method for treating the surface of an absorbent resin |
| US5140076A (en) | 1990-04-02 | 1992-08-18 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Method of treating the surface of an absorbent resin |
| JP2901368B2 (ja) | 1990-04-27 | 1999-06-07 | 株式会社日本触媒 | 耐塩性吸水性樹脂の製造方法 |
| DE69022594T2 (de) | 1990-04-27 | 1996-02-29 | Nippon Catalytic Chem Ind | Verfahren und vorrichtung zur kontinuierlichen granulation von stark wasser-absorbierendem harzpulver. |
| EP0454497B1 (en) | 1990-04-27 | 1997-02-26 | Nippon Shokubai Co., Ltd. | Method for production of salt-resistant absorbent resin |
| US5241009A (en) | 1990-05-07 | 1993-08-31 | Kimberly-Clark Corporation | Polymeric composition containing carboxy nueutralized with lithium or potassium |
| JP2921044B2 (ja) | 1990-06-14 | 1999-07-19 | 三菱化学ポリエステルフィルム株式会社 | 導電性フィルム |
| DE4020780C1 (enExample) | 1990-06-29 | 1991-08-29 | Chemische Fabrik Stockhausen Gmbh, 4150 Krefeld, De | |
| DE4021847C2 (de) | 1990-07-09 | 1994-09-08 | Stockhausen Chem Fab Gmbh | Verfahren zur Herstellung wasserquellbarer Produkte unter Verwendung von Feinstanteilen wasserquellbarer Polymerer |
| ES2070369T3 (es) | 1990-07-17 | 1995-06-01 | Sanyo Chemical Ind Ltd | Procedimiento para la fabricacion de resinas absorbentes de agua. |
| IT1243745B (it) | 1990-10-17 | 1994-06-21 | Vectorpharma Int | Composizioni terapeutiche transdermali contenenti farmaco e/o agente promotore dell'assorbimento cutaneo supportato su particelle microporose e microsfere polimeriche e loro preparazione. |
| DE69133620D1 (de) | 1990-12-21 | 2009-09-10 | Nippon Catalytic Chem Ind | Wasserabsorbierendes Material und Verfahren zu seiner Herstellung sowie wasserabsorbierender Artikel und Verfahren zu seiner Herstellung |
| US5478879A (en) | 1991-01-22 | 1995-12-26 | Nippon Shokubai Co., Ltd. | Method for production of absorbent resin |
| TW241279B (enExample) | 1991-02-01 | 1995-02-21 | Catalyst co ltd | |
| DE69225354T2 (de) | 1991-03-19 | 1998-12-03 | The Dow Chemical Co., Midland, Mich. | Runzelige Absorbentpartikel mit grosser effektiver Oberfläche und hoher Aufnahmegeschwindigkeit |
| US5250640A (en) | 1991-04-10 | 1993-10-05 | Nippon Shokubai Co., Ltd. | Method for production of particulate hydrogel polymer and absorbent resin |
| US5419956A (en) | 1991-04-12 | 1995-05-30 | The Procter & Gamble Company | Absorbent structures containing specific particle size distributions of superabsorbent hydrogel-forming materials mixed with inorganic powders |
| GB9107952D0 (en) | 1991-04-15 | 1991-05-29 | Dow Rheinmuenster | Surface crosslinked and surfactant coated absorbent resin particles and method of preparation |
| JP3155294B2 (ja) | 1991-06-20 | 2001-04-09 | 三菱化学株式会社 | 高吸水性ポリマーの製造法 |
| CA2053733C (en) | 1991-08-15 | 2002-04-30 | Chuan-Ling Tsai | Thermal treatment of superabsorbents to enhance their rate of absorbency under load |
| CA2116035A1 (en) | 1991-09-09 | 1993-03-18 | Fredric L. Buchholz | Superabsorbent polymers and process for producing |
| DE69219705T2 (de) | 1991-09-11 | 1997-11-27 | Kimberly Clark Co | Zusammengesetzte absorbierende Materialien und diese enthaltende absorbierende Gegenstände |
| CA2076945C (en) | 1991-09-11 | 2002-10-08 | Shannon Kathleen Byerly | Absorbent composites and absorbent articles containing same |
| DE4131045C1 (enExample) | 1991-09-18 | 1992-11-19 | Cassella Ag, 6000 Frankfurt, De | |
| US5154713A (en) | 1991-10-22 | 1992-10-13 | Nalco Chemical Company | Enhancing absorption rates of superabsorbents by incorporating a blowing agent |
| CA2086031A1 (en) | 1992-01-28 | 1993-07-29 | Shigeki Ueda | Process for producing improved water absorbing resin and resin made by the same |
| JPH05220375A (ja) | 1992-02-12 | 1993-08-31 | Nara Kikai Seisakusho:Kk | 固体粒子の表面改質方法と装置 |
| DE69312126T2 (de) | 1992-03-05 | 1997-11-06 | Nippon Catalytic Chem Ind | Verfahren zu Herstellung eines absorbierenden Harzes |
| GB9208449D0 (en) | 1992-04-16 | 1992-06-03 | Dow Deutschland Inc | Crosslinked hydrophilic resins and method of preparation |
| MY110150A (en) | 1992-04-17 | 1998-02-28 | Kao Corp | Highly absorbent polymer |
| DE69323652T2 (de) | 1992-06-10 | 1999-09-09 | Nippon Shokubai Co. Ltd. | Verfahren zur Herstellung eines hydrophilen Harzes |
| US5543215A (en) | 1992-08-17 | 1996-08-06 | Weyerhaeuser Company | Polymeric binders for binding particles to fibers |
| US5538783A (en) | 1992-08-17 | 1996-07-23 | Hansen; Michael R. | Non-polymeric organic binders for binding particles to fibers |
| US5300192A (en) | 1992-08-17 | 1994-04-05 | Weyerhaeuser Company | Wet laid fiber sheet manufacturing with reactivatable binders for binding particles to fibers |
| US5308896A (en) | 1992-08-17 | 1994-05-03 | Weyerhaeuser Company | Particle binders for high bulk fibers |
| US5352480A (en) | 1992-08-17 | 1994-10-04 | Weyerhaeuser Company | Method for binding particles to fibers using reactivatable binders |
| US5589256A (en) | 1992-08-17 | 1996-12-31 | Weyerhaeuser Company | Particle binders that enhance fiber densification |
| US5288814A (en) | 1992-08-26 | 1994-02-22 | The B. F. Goodrich Company | Easy to disperse polycarboxylic acid thickeners |
| JP3121934B2 (ja) | 1992-09-25 | 2001-01-09 | 株式会社日本触媒 | 吸水性樹脂組成物 |
| JP3259143B2 (ja) | 1992-10-12 | 2002-02-25 | 株式会社日本触媒 | 吸水性樹脂の製造方法 |
| US5447727A (en) | 1992-10-14 | 1995-09-05 | The Dow Chemical Company | Water-absorbent polymer having improved properties |
| US5385983A (en) | 1992-11-12 | 1995-01-31 | The Dow Chemical Company | Process for preparing a water-absorbent polymer |
| JP2541086B2 (ja) | 1992-11-20 | 1996-10-09 | 鹿島建設株式会社 | 超吸水性繊維を用いる固体の仮埋設・引抜き工法 |
| JP2675729B2 (ja) | 1992-12-16 | 1997-11-12 | 株式会社日本触媒 | 吸水性樹脂の製造方法 |
| EP0605215B1 (en) | 1992-12-25 | 1998-03-25 | Nippon Shokubai Co., Ltd. | Absorbent and method for production of absorbent resin |
| DE4244548C2 (de) | 1992-12-30 | 1997-10-02 | Stockhausen Chem Fab Gmbh | Pulverförmige, unter Belastung wäßrige Flüssigkeiten sowie Blut absorbierende Polymere, Verfahren zu ihrer Herstellung und ihre Verwendung in textilen Konstruktionen für die Körperhygiene |
| JP2995276B2 (ja) | 1993-01-18 | 1999-12-27 | 三洋化成工業株式会社 | 吸水性樹脂の製造法 |
| JP3414778B2 (ja) | 1993-01-26 | 2003-06-09 | 株式会社日本触媒 | 吸水性樹脂の表面処理方法 |
| CA2114815C (en) | 1993-02-24 | 2005-06-14 | Mark Kevin Melius | Absorbent composite |
| JPH06262072A (ja) | 1993-03-10 | 1994-09-20 | Nippon Shokubai Co Ltd | 粒状吸油剤の製造方法 |
| US5338766A (en) | 1993-03-26 | 1994-08-16 | The Procter & Gamble Company | Superabsorbent polymer foam |
| US5328935A (en) | 1993-03-26 | 1994-07-12 | The Procter & Gamble Company | Method of makig a superabsorbent polymer foam |
| AU4276893A (en) | 1993-03-29 | 1994-10-24 | Dow Chemical Company, The | Absorbent polymer having reduced dusting tendencies |
| DE69431321T2 (de) | 1993-04-23 | 2003-05-22 | Mitsubishi Chemical Corp., Tokio/Tokyo | Stark wasserabsorbierende Polymere mit verbesserter Gelfestigkeit |
| JP3330716B2 (ja) | 1994-02-16 | 2002-09-30 | 三菱化学株式会社 | 高吸水性ポリマー組成物 |
| JPH07145326A (ja) | 1993-11-11 | 1995-06-06 | Mitsubishi Chem Corp | 体液吸収後のゲルの安定性が改善された高吸水性ポリマー組成物 |
| US5415908A (en) | 1993-05-26 | 1995-05-16 | Naesman; Jan H. | Polymer supports comprising highly reactive grafted polyolefin inescapably enclosed within a mesh fabric bag |
| IL109785A0 (en) | 1993-06-03 | 1994-08-26 | Basf Ag | Azine-substituted phenylacetic acid derivatives and fungicidal compositions containing them |
| DE69428833T2 (de) | 1993-06-18 | 2002-07-11 | Sanyo Chemical Industries, Ltd. | Absorbierende Zusammensetzung und Wegwerfwindel mit dieser Zusammensetzung |
| EP0838483B1 (en) | 1993-06-18 | 2009-09-09 | Nippon Shokubai Co., Ltd. | Process for preparing absorbent resin |
| US5371148A (en) | 1993-06-23 | 1994-12-06 | Union Carbide Chemicals & Plastics Technology Corporation | Reactive polymers having pendant flexible side chains prepared from ethylenically unsaturated carbodiimides |
| IL110134A (en) | 1993-07-09 | 1998-07-15 | Stockhausen Chem Fab Gmbh | Polymers capable of absorbing aqueous liquids and body fluids their preparation and use |
| GB9317867D0 (en) | 1993-08-27 | 1993-10-13 | Dow Deutschland Inc | Aqueous fluid absorbent polymers having a superior balance of absorpitive properties |
| US5314420A (en) | 1993-09-17 | 1994-05-24 | Nalco Chemical Company | Superabsorbent polymer having improved absorption rate and absorption under pressure |
| US5451613A (en) | 1993-09-17 | 1995-09-19 | Nalco Chemical Company | Superabsorbent polymer having improved absorption rate and absorption under pressure |
| DE4333056C2 (de) | 1993-09-29 | 1998-07-02 | Stockhausen Chem Fab Gmbh | Pulverförmige, wäßrige Flüssigkeiten absorbierende Polymere, Verfahren zu ihrer Herstellung und ihre Verwendung als Absorptionsmittel |
| JPH07224204A (ja) | 1994-02-10 | 1995-08-22 | Toagosei Co Ltd | 吸水性樹脂の製造方法 |
| JPH09509343A (ja) | 1994-02-17 | 1997-09-22 | ザ、プロクター、エンド、ギャンブル、カンパニー | 変性表面特性を有する吸収性材料およびその製法 |
| US5843575A (en) | 1994-02-17 | 1998-12-01 | The Procter & Gamble Company | Absorbent members comprising absorbent material having improved absorbent property |
| US5610208A (en) | 1994-02-17 | 1997-03-11 | Nippon Shokubai Co., Ltd. | Water-absorbent agent, method for production thereof, and water-absorbent composition |
| EP0744967B1 (en) | 1994-02-17 | 2002-05-02 | The Procter & Gamble Company | Absorbent members comprising absorbent materials having improved absorbent property |
| AU1608195A (en) | 1994-02-17 | 1995-09-04 | Procter & Gamble Company, The | Absorbent materials having improved absorbent property and methods for making the same |
| US5849405A (en) | 1994-08-31 | 1998-12-15 | The Procter & Gamble Company | Absorbent materials having improved absorbent property and methods for making the same |
| JPH07242709A (ja) | 1994-03-03 | 1995-09-19 | Toagosei Co Ltd | 吸水性樹脂の製造方法 |
| US5599335A (en) | 1994-03-29 | 1997-02-04 | The Procter & Gamble Company | Absorbent members for body fluids having good wet integrity and relatively high concentrations of hydrogel-forming absorbent polymer |
| JPH10500712A (ja) | 1994-04-11 | 1998-01-20 | ヘキスト セラニーズ コーポレーション | 超吸収性ポリマー及びそれから得られる生成物 |
| JP3169133B2 (ja) | 1994-06-06 | 2001-05-21 | 三洋化成工業株式会社 | 改質された衛生用品用吸水性樹脂粒子 |
| JP3597597B2 (ja) | 1994-06-08 | 2004-12-08 | 株式会社日本触媒 | 吸水性樹脂及びその製造方法 |
| US5624967A (en) * | 1994-06-08 | 1997-04-29 | Nippon Shokubai Co., Ltd. | Water-absorbing resin and process for producing same |
| JP3591545B2 (ja) | 1994-06-10 | 2004-11-24 | 花王株式会社 | 吸収性物品 |
| USRE38444E1 (en) | 1994-06-13 | 2004-02-24 | Nippon Shokubai Co., Ltd. | Absorbing agent, process of manufacturing same, and absorbent product containing same |
| DE69524928T2 (de) | 1994-06-13 | 2002-08-29 | Nippon Shokubai Co. Ltd., Osaka | Wasser-absorbent, verfahren zu dessen herstellung und den enthaltender absorbent-gegenstand |
| JP2918808B2 (ja) | 1994-06-13 | 1999-07-12 | 株式会社日本触媒 | 吸収体および吸収性物品 |
| GB9413619D0 (en) | 1994-07-06 | 1994-08-24 | American Colloid Co | Method of increasing the size and/or absorption under load of super-absorbent polymers by surface cross-linking |
| DE69505398T2 (de) | 1994-08-12 | 1999-03-11 | Kao Corp., Tokio/Tokyo | Verfahren zur herstellung von verbesserten superabsorbierenden polymeren |
| JP2938775B2 (ja) | 1994-12-27 | 1999-08-25 | 花王株式会社 | 改良された高吸水性樹脂の製造法 |
| JP3024914B2 (ja) | 1994-09-09 | 2000-03-27 | 花王株式会社 | 高吸水性樹脂組成物 |
| US5668078A (en) | 1994-10-05 | 1997-09-16 | Sanyo Chemical Industries, Ltd. | Water-absorbent resin particles and the production thereof |
| JP3481250B2 (ja) | 1994-10-26 | 2003-12-22 | 株式会社 日本触媒 | 吸水性樹脂組成物およびその製造方法 |
| JP3970818B2 (ja) | 1994-10-26 | 2007-09-05 | 株式会社日本触媒 | 吸水性樹脂の造粒粒子およびこれを含む吸収性物品ならびに吸水性樹脂の造粒粒子の製造方法 |
| JP3603970B2 (ja) | 1994-11-21 | 2004-12-22 | 株式会社日本触媒 | 粉末の吸水性樹脂組成物の製造方法 |
| EP0744435B2 (en) | 1994-12-08 | 2011-03-23 | Nippon Shokubai Co., Ltd. | Water-absorbent resin, process for production thereof, and water-absorbent resin composition |
| JPH10511357A (ja) | 1994-12-22 | 1998-11-04 | スミスクライン・ビーチャム・コーポレイション | フィブリノゲン受容体拮抗物質 |
| US5684072A (en) | 1995-03-22 | 1997-11-04 | Ppg Industries, Inc. | Waterborne coating compositions having improved smoothness |
| JP3294463B2 (ja) | 1995-04-19 | 2002-06-24 | 花王株式会社 | 高吸水性ポリマーの製造方法 |
| WO1996038296A1 (en) | 1995-05-31 | 1996-12-05 | Bell Packaging Corporation | Corrugated board manufacturing system and method |
| WO1997003114A1 (en) | 1995-07-07 | 1997-01-30 | Nippon Shokubai Co., Ltd. | Water absorbent powder and process for the production thereof |
| US5745528A (en) | 1995-07-13 | 1998-04-28 | Zenith Electronics Corporation | VSB mode selection system |
| DE19529348C2 (de) | 1995-08-09 | 1997-11-20 | Stockhausen Chem Fab Gmbh | Absorptionsmittel für Wasser und wäßrige Flüssigkeiten auf Polyacrylatbasis sowie Verfahren zu ihrer Herstellung und Verwendung |
| TW522024B (en) | 1995-09-01 | 2003-03-01 | Nippon Catalytic Chem Ind | Absorbing agent composite, absorbent material, and absorbent product containing absorbent material |
| JP3558756B2 (ja) | 1995-09-13 | 2004-08-25 | 三洋化成工業株式会社 | 吸水剤 |
| EP0763364B1 (en) | 1995-09-14 | 2003-07-16 | Nippon Shokubai Co., Ltd. | Absorbent composite, absorbent article and methods for their production |
| ZA968183B (en) | 1995-09-29 | 1997-04-25 | Sankyo Co | 13-Substituted milbemycin 5-oxime derivatives their preparation and their use against insects and other pests |
| US5601452A (en) | 1995-10-03 | 1997-02-11 | The United States Of America As Represented By The Secretary Of The Navy | Non-arcing clamp for automotive battery jumper cables |
| EP0799640A4 (en) | 1995-10-20 | 1999-07-14 | Nippon Catalytic Chem Ind | ADSORBENT AND METHOD FOR ADSORPING A SURFACTANT AND CARRIER OF THE SURFACTANT |
| JP3103754B2 (ja) | 1995-10-31 | 2000-10-30 | 三洋化成工業株式会社 | 改質された吸水性樹脂粒子およびその製法 |
| JP3606966B2 (ja) | 1995-11-02 | 2005-01-05 | 株式会社日本触媒 | 吸水性樹脂およびその製造方法 |
| JP2890022B2 (ja) | 1995-11-13 | 1999-05-10 | 三洋化成工業株式会社 | 吸水性樹脂粒子およびその製法 |
| DE19646484C2 (de) | 1995-11-21 | 2000-10-19 | Stockhausen Chem Fab Gmbh | Flüssigkeitsabsorbierende Polymere, Verfahren zu deren Herstellung und deren Verwendung |
| DE19543366C2 (de) | 1995-11-21 | 1998-09-10 | Stockhausen Chem Fab Gmbh | Mit ungesättigten Aminoalkoholen vernetzte, wasserquellbare Polymerisate, deren Herstellung und Verwendung |
| DE19543368C2 (de) | 1995-11-21 | 1998-11-26 | Stockhausen Chem Fab Gmbh | Wasserabsorbierende Polymere mit verbesserten Eigenschaften, Verfahren zu deren Herstellung und deren Verwendung |
| WO1997024394A1 (fr) | 1995-12-27 | 1997-07-10 | Nippon Shokubai Co., Ltd. | Produit absorbant l'eau, procede et appareil de fabrication |
| JP3688418B2 (ja) | 1995-12-27 | 2005-08-31 | 株式会社日本触媒 | 吸水剤並びに衛生材料 |
| JP3753828B2 (ja) | 1996-02-13 | 2006-03-08 | 株式会社日本触媒 | 吸水剤組成物およびその製造方法並びに吸水剤 |
| DE19607551A1 (de) | 1996-02-28 | 1997-09-04 | Basf Ag | Wasserabsorbierende, schaumförmige, vernetzte Polymerisate, Verfahren zu ihrer Herstellung und ihre Verwendung |
| US5728742A (en) | 1996-04-04 | 1998-03-17 | The Dow Chemical Company | Absorbent polymers having a reduced caking tendency |
| US6730387B2 (en) | 1996-04-24 | 2004-05-04 | The Procter & Gamble Company | Absorbent materials having improved structural stability in dry and wet states and making methods therefor |
| JP3720118B2 (ja) | 1996-04-24 | 2005-11-24 | ザ プロクター アンド ギャンブル カンパニー | 乾燥状態および湿潤状態における改善された構造的安定性を有する吸収性材料およびその製法 |
| US6194531B1 (en) | 1996-06-05 | 2001-02-27 | Nippon Shokubai Co., Ltd. | Method for production of cross-linked polymer |
| JPH1045812A (ja) | 1996-07-31 | 1998-02-17 | Sekisui Plastics Co Ltd | 繊維含有吸水性樹脂の製造方法 |
| JPH10114801A (ja) | 1996-08-23 | 1998-05-06 | Nippon Shokubai Co Ltd | 高吸水速度吸水性樹脂およびその製造方法 |
| US6107358A (en) | 1996-08-23 | 2000-08-22 | Nippon Shokubai Co., Ltd. | Water-absorbent resin and method for production thereof |
| JP3659746B2 (ja) | 1996-09-05 | 2005-06-15 | 花王株式会社 | 吸収性物品 |
| DE19639491C2 (de) | 1996-09-26 | 1999-11-11 | Fraunhofer Ges Forschung | Verfahren zur Vergrößerung der Oberfläche von Partikeln |
| ID19116A (id) | 1996-10-15 | 1998-06-18 | Nippon Catalytic Chem Ind | Bahan pengabsorpsi air dan proses produksinya |
| CN100345891C (zh) | 1996-10-24 | 2007-10-31 | 株式会社日本触媒 | 吸水性树脂的制造方法 |
| TW399062B (en) | 1996-11-07 | 2000-07-21 | Formosa Plastics Corp | Process for producing superabsorbent polymer |
| JPH10147724A (ja) | 1996-11-19 | 1998-06-02 | Kao Corp | 高吸水性樹脂組成物 |
| EP0844270B1 (en) | 1996-11-20 | 2004-11-17 | Sanyo Chemical Industries, Ltd. | Water absorbing agent and method of producing the same |
| US6951895B1 (en) | 1996-12-02 | 2005-10-04 | Kimberly-Clark Worldwide, Inc. | Absorbent composition |
| JP3205529B2 (ja) | 1997-01-31 | 2001-09-04 | 花王株式会社 | 高吸水性樹脂組成物 |
| CN1252829A (zh) | 1997-02-19 | 2000-05-10 | 普罗克特和甘保尔公司 | 混合床离子交换可形成水凝胶的聚合物组合物以及含相对高浓度这些组合物的吸收性部件 |
| US6232520B1 (en) | 1997-02-19 | 2001-05-15 | The Procter & Gamble Company | Absorbent polymer compositions having high sorption capacities under an applied pressure |
| TW491843B (en) | 1997-03-04 | 2002-06-21 | Nissan Chemical Ind Ltd | 1,3,5-triazine derivative salts of polyacids comprising phosphorus, sulfur, and oxygen and process for producing the same |
| US6184433B1 (en) | 1997-04-14 | 2001-02-06 | Nippon Shokubai Co., Ltd. | Pressure-resistant absorbent resin, disposable diaper using the resin, and absorbent resin, and method for production thereof |
| TW422866B (en) | 1997-04-28 | 2001-02-21 | Formosa Plastics Corp | Method to produce a resin with high water absorption |
| CN1182878C (zh) | 1997-04-29 | 2005-01-05 | 陶氏环球技术公司 | 超吸水性聚合物组合物及其制备方法 |
| WO1998049221A1 (en) | 1997-04-29 | 1998-11-05 | The Dow Chemical Company | Superabsorbent polymers having improved processability |
| US6033974A (en) | 1997-05-12 | 2000-03-07 | Silicon Genesis Corporation | Method for controlled cleaving process |
| US5856410A (en) | 1997-05-23 | 1999-01-05 | Amcol International Corporation | Polyacrylate superabsorbent post-polymerization neutralized with solid, non-hydroxyl neutralizing agent. |
| JP4087500B2 (ja) | 1997-06-13 | 2008-05-21 | 株式会社日本触媒 | 吸収性物品の製造方法 |
| US6228930B1 (en) | 1997-06-18 | 2001-05-08 | Nippon Shokubai Co., Ltd. | Water-absorbent resin granule-containing composition and production process for water-absorbent resin granule |
| JP3979724B2 (ja) | 1997-06-18 | 2007-09-19 | 株式会社日本触媒 | 吸水性樹脂造粒物の乾燥体の製造方法 |
| JPH1171529A (ja) | 1997-07-03 | 1999-03-16 | Nippon Shokubai Co Ltd | 吸水性樹脂及びそれを用いた吸水性物品 |
| JP2883330B1 (ja) | 1997-07-03 | 1999-04-19 | 花王株式会社 | 高吸水性樹脂組成物 |
| SG86324A1 (en) | 1997-07-03 | 2002-02-19 | Kao Corp | Superabsorbent resin composition |
| US5840979A (en) | 1997-07-14 | 1998-11-24 | University Of Saskatchewan | Aliphatic propargylamines as cellular rescue agents |
| US6284362B1 (en) | 1997-07-18 | 2001-09-04 | Sanyo Chemical Industries, Ltd. | Absorbent compositions, methods for producing thereof and absorbent products |
| JP3031306B2 (ja) | 1997-07-31 | 2000-04-10 | 日本電気株式会社 | 移動無線装置 |
| JPH1171425A (ja) | 1997-08-28 | 1999-03-16 | Nippon Shokubai Co Ltd | 吸水剤の製造方法 |
| TW473485B (en) | 1997-12-10 | 2002-01-21 | Nippon Catalytic Chem Ind | The production process of a water-absorbent resin |
| JP3763376B2 (ja) | 1997-12-25 | 2006-04-05 | 株式会社日本触媒 | 親水性樹脂の製造方法 |
| JP4236745B2 (ja) | 1998-01-09 | 2009-03-11 | 株式会社日本触媒 | 粉体の連続造粒方法 |
| TW432092B (en) | 1998-02-12 | 2001-05-01 | Formosa Plastics Corp | An antibacterial, antiodorant, water-absorption resin and method of production therefor |
| US6254990B1 (en) | 1998-02-18 | 2001-07-03 | Nippon Shokubai Co., Ltd. | Surface-crosslinking process for water-absorbent resin |
| JP3389130B2 (ja) | 1998-02-18 | 2003-03-24 | 株式会社日本触媒 | 吸水性樹脂の表面架橋方法 |
| DE19807502B4 (de) | 1998-02-21 | 2004-04-08 | Basf Ag | Verfahren zur Nachvernetzung von Hydrogelen mit 2-Oxazolidinonen, daraus hergestellte Hydrogele und deren Verwendung |
| JPH11240959A (ja) | 1998-02-24 | 1999-09-07 | Nippon Shokubai Co Ltd | 吸水性ポリマー組成物およびその製法 |
| JP4162746B2 (ja) | 1998-02-24 | 2008-10-08 | 株式会社日本触媒 | 吸水剤組成物及びそれを用いた吸収性物品 |
| JP4903926B2 (ja) | 1998-03-03 | 2012-03-28 | 株式会社日本触媒 | 吸水剤、その製造方法およびその用途 |
| US6599989B2 (en) | 1998-03-03 | 2003-07-29 | Nippon Skokubai Co., Ltd. | Water-absorbent agents containing polycarboxylic amine chelating agents |
| DE19809540A1 (de) | 1998-03-05 | 1999-09-09 | Basf Ag | Wasserabsorbierende, schaumförmige, vernetzte Polymerisate, Verfahren zu ihrer Herstellung und ihre Verwendung |
| US6310156B1 (en) | 1998-03-06 | 2001-10-30 | Nippon Shokubai Co., Ltd. | (Meth) acrylic acid polymer and manufacturing method thereof |
| JP3398837B2 (ja) | 1998-08-10 | 2003-04-21 | 株式会社日本触媒 | アクリル酸（塩）−マレイン酸（塩）系共重合体、その製造方法および洗剤組成物 |
| US6444744B1 (en) * | 1998-03-11 | 2002-09-03 | Nippon Shokubai Co., Ltd. | Hydrophilic resin, absorbent article, and acrylic acid for polymerization |
| JPH11279287A (ja) | 1998-03-31 | 1999-10-12 | Nippon Shokubai Co Ltd | 吸水剤組成物および吸水剤の製造方法 |
| EP1084174A1 (de) | 1998-04-28 | 2001-03-21 | Basf Aktiengesellschaft | Mechanisch stabile hydrogele |
| KR100476170B1 (ko) | 1998-04-28 | 2005-03-10 | 니폰 쇼쿠바이 컴파니 리미티드 | 흡수성수지 함수겔상물의 제조방법 |
| SE511857C2 (sv) | 1998-04-28 | 1999-12-06 | Sca Hygiene Prod Ab | Absorberande struktur med förbättrade absorptionsegenskaper innehållande minst 50 vikts% superabsorberande material |
| US6241928B1 (en) | 1998-04-28 | 2001-06-05 | Nippon Shokubai Co., Ltd. | Method for production of shaped hydrogel of absorbent resin |
| US6124391A (en) | 1998-08-18 | 2000-09-26 | Stockhausen Gmbh & Co. Kg | Superabsorbent polymers having anti-caking characteristics |
| JP3494401B2 (ja) | 1998-09-22 | 2004-02-09 | 株式会社日本触媒 | 吸水剤及び吸収性物品 |
| JP2000095965A (ja) | 1998-09-24 | 2000-04-04 | Tokai Carbon Co Ltd | カーボンブラックの改質方法 |
| DE19846413A1 (de) | 1998-10-08 | 2000-04-13 | Basf Ag | Verfahren zur Herstellung von hydrophilen wasserquellbaren Polymeren sowie deren Verwendung |
| KR20010075635A (ko) | 1998-10-15 | 2001-08-09 | 메리 이. 보울러 | 플루오로사이클로부틸 환을 함유하는 중합체 및 그의 제법 |
| TW396173B (en) | 1998-10-22 | 2000-07-01 | Formosa Plastics Corp | Method of preparing superabsorbent polymer |
| US6297319B1 (en) | 1998-11-05 | 2001-10-02 | Nippon Shokubai Co., Ltd. | Water-absorbing agent and production process therefor |
| DE19854574A1 (de) | 1998-11-26 | 2000-05-31 | Basf Ag | Verfahren zur Nachvernetzung von Hydrogelen mit N-Acyl-2-Oxazolidinonen |
| DE19854573A1 (de) | 1998-11-26 | 2000-05-31 | Basf Ag | Verfahren zur Nachvernetzung von Hydrogelen mit 2-Oxo-tetrahydro-1,3-oxazinen |
| JP3259074B2 (ja) | 1998-12-04 | 2002-02-18 | 株式会社日本触媒 | 吸水性樹脂の耐尿性評価方法 |
| US6562743B1 (en) | 1998-12-24 | 2003-05-13 | Bki Holding Corporation | Absorbent structures of chemically treated cellulose fibers |
| US6297335B1 (en) | 1999-02-05 | 2001-10-02 | Basf Aktiengesellschaft | Crosslinked, hydrophilic, highly swellable hydrogels, production thereof and use thereof |
| US6562879B1 (en) | 1999-02-15 | 2003-05-13 | Nippon Shokubai Co., Ltd. | Water-absorbent resin powder and its production process and use |
| JP4380873B2 (ja) | 1999-02-15 | 2009-12-09 | 株式会社日本触媒 | 吸水性樹脂粉末およびその用途 |
| DE19909838A1 (de) | 1999-03-05 | 2000-09-07 | Stockhausen Chem Fab Gmbh | Pulverförmige, vernetzte, wässrige Flüssigkeiten sowie Blut absorbierende Polymere, Verfahren zu ihrer Herstellung und ihre Verwendung |
| DE19909653A1 (de) | 1999-03-05 | 2000-09-07 | Stockhausen Chem Fab Gmbh | Pulverförmige, vernetzte, wässrige Flüssigkeiten sowie Blut absorbierende Polymere, Verfahren zu ihrer Herstellung und ihre Verwendung |
| EP1169379B1 (en) | 1999-03-12 | 2004-09-22 | Basf Aktiengesellschaft | Color-stable superabsorbent polymer composition |
| JP2000290381A (ja) | 1999-04-08 | 2000-10-17 | Dainippon Ink & Chem Inc | 吸水性樹脂の製造方法 |
| JP2000327926A (ja) | 1999-05-25 | 2000-11-28 | Sanyo Chem Ind Ltd | 吸収剤組成物および吸収性物品 |
| JP2002035580A (ja) | 1999-06-24 | 2002-02-05 | Sanyo Chem Ind Ltd | 吸収剤組成物および吸収性物品 |
| US6514615B1 (en) | 1999-06-29 | 2003-02-04 | Stockhausen Gmbh & Co. Kg | Superabsorbent polymers having delayed water absorption characteristics |
| JP2001011341A (ja) | 1999-07-02 | 2001-01-16 | Kansai Research Institute | 水系分散用顔料及び水性顔料分散液 |
| JP3889207B2 (ja) | 1999-07-26 | 2007-03-07 | 株式会社日本触媒 | 吸水剤組成物およびその用途 |
| EP1072630B1 (en) | 1999-07-26 | 2004-12-01 | Nippon Shokubai Co., Ltd. | Water-absorbing composition and its use |
| JP2001040014A (ja) * | 1999-08-04 | 2001-02-13 | Mitsubishi Chemicals Corp | 高吸水性樹脂の製造方法 |
| JP2001040013A (ja) | 1999-08-04 | 2001-02-13 | Mitsubishi Chemicals Corp | 高吸水性樹脂の製造方法 |
| US6239230B1 (en) | 1999-09-07 | 2001-05-29 | Bask Aktiengesellschaft | Surface-treated superabsorbent polymer particles |
| US6376618B1 (en) | 1999-09-07 | 2002-04-23 | Basf Aktiengesellschaft | Surface-treated superabsorbent polymer particles |
| JP4308382B2 (ja) | 1999-10-01 | 2009-08-05 | 株式会社日本触媒 | 吸水剤およびその製造方法 |
| US6414214B1 (en) | 1999-10-04 | 2002-07-02 | Basf Aktiengesellschaft | Mechanically stable hydrogel-forming polymers |
| BR0015230A (pt) | 1999-10-21 | 2002-07-23 | Daiso Co Ltd Daiso Kabushiki K | Agente de reticulação a base de compostos de poli (éter alìlico) |
| JP4679683B2 (ja) | 1999-11-02 | 2011-04-27 | 株式会社日本触媒 | 吸水性重合体の製造方法、及び該重合体の製造装置 |
| JP2001137704A (ja) | 1999-11-18 | 2001-05-22 | Toagosei Co Ltd | 改質された高吸水性樹脂の製造方法 |
| US6433058B1 (en) | 1999-12-07 | 2002-08-13 | Dow Global Technologies Inc. | Superabsorbent polymers having a slow rate of absorption |
| US6579958B2 (en) | 1999-12-07 | 2003-06-17 | The Dow Chemical Company | Superabsorbent polymers having a slow rate of absorption |
| US6469080B2 (en) | 1999-12-15 | 2002-10-22 | Nippon Shokubai Co., Ltd. | Water-absorbent resin composition |
| WO2001045758A1 (en) | 1999-12-23 | 2001-06-28 | The Dow Chemical Company | High permeability, low absorption capacity polymers |
| US20010006267A1 (en) | 1999-12-27 | 2001-07-05 | Nobuyuki Harada | Production processes for basic water-absorbent resin and water-absorbing agent, and use thereof |
| US6417425B1 (en) | 2000-02-01 | 2002-07-09 | Basf Corporation | Absorbent article and process for preparing an absorbent article |
| JP2001226416A (ja) | 2000-02-15 | 2001-08-21 | Toagosei Co Ltd | 吸水性樹脂の製造方法 |
| JP2001224959A (ja) | 2000-02-16 | 2001-08-21 | Unitika Ltd | 吸水剤の製造方法 |
| DE60112630T3 (de) | 2000-02-29 | 2016-03-03 | Nippon Shokubai Co., Ltd. | Verfaren zur Herstellung eines wasserabsorbierenden Harzpulvers |
| JP4676625B2 (ja) | 2000-02-29 | 2011-04-27 | 株式会社日本触媒 | 吸水性樹脂粉末の製造方法 |
| WO2001066056A1 (en) | 2000-03-06 | 2001-09-13 | The Procter & Gamble Company | Process of making absorbent structures comprising absorbent polymer compositions with a permeability maintenance agent |
| US6569373B2 (en) | 2000-03-13 | 2003-05-27 | Object Geometries Ltd. | Compositions and methods for use in three dimensional model printing |
| JP2001252307A (ja) | 2000-03-13 | 2001-09-18 | Oji Paper Co Ltd | 吸収性物品 |
| DE10013217A1 (de) | 2000-03-17 | 2001-09-20 | Basf Ag | Hydrophile, quellfähige Hydrogel-bildende Polymere m it Alumosilikatanteil |
| DE10016041A1 (de) | 2000-03-31 | 2001-10-04 | Stockhausen Chem Fab Gmbh | Pulverförmige an der Oberfläche vernetzte Polymerisate |
| CN100471526C (zh) | 2000-03-31 | 2009-03-25 | 施托克赫森有限公司 | 包括在表面上交联的粉末聚合物的吸液吸收层 |
| US6720073B2 (en) | 2000-04-07 | 2004-04-13 | Kimberly-Clark Worldwide, Inc. | Material enhancement to maintain high absorbent capacity under high loads following rigorous process conditions |
| US6617489B2 (en) | 2000-05-09 | 2003-09-09 | Nippon Shokubai Co., Ltd. | Absorbent, absorbing product based thereon, and water-absorbing resin |
| US6649137B2 (en) | 2000-05-23 | 2003-11-18 | Rohm And Haas Company | Apparatus with improved safety features for high temperature industrial processes |
| WO2001089591A2 (en) | 2000-05-25 | 2001-11-29 | Basf Aktiengesellschaft | Surface-treated superabsorbent polymer particles |
| US6927268B2 (en) | 2000-06-21 | 2005-08-09 | Nippon Shokubai Co., Ltd. | Production process for water-absorbent resin |
| EP1325777B1 (en) | 2000-07-18 | 2010-12-22 | Sanyo Chemical Industries, Ltd. | Absorbents and process for producing the same, absorbable constructs and absorbable articles |
| US6906159B2 (en) | 2000-08-03 | 2005-06-14 | Nippon Shokubai Co., Ltd. | Water-absorbent resin, hydropolymer, process for producing them, and uses of them |
| JP4805490B2 (ja) | 2000-08-03 | 2011-11-02 | 株式会社日本触媒 | 吸水性樹脂の製造方法 |
| DE10043706A1 (de) | 2000-09-04 | 2002-04-25 | Stockhausen Chem Fab Gmbh | Pulverförmige, vernetzte, wässrige Flüssigkeiten sowie Blut absorbierende Polymere, Verfahren zu ihrer Herstellung und ihre Verwendung |
| DE10043710B4 (de) | 2000-09-04 | 2015-01-15 | Evonik Degussa Gmbh | Verwendung pulverförmiger an der Oberfläche nachvernetzter Polymerisate und Hygieneartikel |
| US6809158B2 (en) | 2000-10-20 | 2004-10-26 | Nippon Shokubai Co., Ltd. | Water-absorbing agent and process for producing the same |
| US20040213892A1 (en) | 2003-04-25 | 2004-10-28 | Gerd Jonas | Highly swellable absorption medium with reduced caking tendency |
| DE10052966A1 (de) | 2000-10-25 | 2002-05-02 | Stockhausen Chem Fab Gmbh | Hochquellbare Absorptionsmittel mit einer verminderten Tendenz zum Verbacken |
| DE10053858A1 (de) | 2000-10-30 | 2002-05-08 | Stockhausen Chem Fab Gmbh | Absorbierendes Gebilde mit verbesserten Blockingeigenschaften |
| DE10064642A1 (de) * | 2000-12-22 | 2002-06-27 | Basf Ag | Verfahren zur Herstellung von (Meth)acrylsäure |
| WO2002053198A1 (de) | 2000-12-29 | 2002-07-11 | Basf Aktiengesellschaft | Aborbierende zusammensetzungen |
| EP1363682A1 (de) | 2000-12-29 | 2003-11-26 | Basf Aktiengesellschaft | Hydrogele mit sterischen oder elektrostatischen abstandhaltern beschichtet |
| JP3987348B2 (ja) | 2001-01-26 | 2007-10-10 | 株式会社日本触媒 | 吸水剤の製法 |
| BR0203825A (pt) | 2001-01-26 | 2002-12-17 | Nippon Catalytic Chem Ind | Agente absorvente de água e processo para produção do mesmo e estrutura absorvente de água |
| JP2002241627A (ja) | 2001-02-20 | 2002-08-28 | Kao Corp | 高吸水性樹脂組成物の経時着色防止剤 |
| US7507475B2 (en) | 2001-03-07 | 2009-03-24 | Evonik Stockhausen Gmbh | Pulverulent polymers crosslinked on the surface |
| JP2002265528A (ja) | 2001-03-14 | 2002-09-18 | Toagosei Co Ltd | 吸水性樹脂の製造方法 |
| JP4759153B2 (ja) * | 2001-03-21 | 2011-08-31 | 株式会社日本触媒 | （メタ）アクリル酸溶液の蒸留方法 |
| BR0204831A (pt) | 2001-04-16 | 2003-04-29 | Sumitomo Seika Chemicals | Resina absorvente de água adequada para absorção de lìquidos viscosos contendo polìmero, e núcleo absorvente e artigo absorvente usando a mesma |
| DE10125599A1 (de) | 2001-05-25 | 2002-11-28 | Stockhausen Chem Fab Gmbh | Superabsorber, Verfahren zu ihrer Herstellung und ihre Verwendung |
| JP4326752B2 (ja) | 2001-06-08 | 2009-09-09 | 株式会社日本触媒 | 吸水剤の製造方法 |
| PL204244B1 (pl) | 2001-06-08 | 2009-12-31 | Nippon Catalytic Chem Ind | Środek absorbujący wodę i sposób jego wytwarzania, oraz materiał higieniczny |
| JP2003082250A (ja) | 2001-06-27 | 2003-03-19 | San-Dia Polymer Ltd | 吸水性樹脂組成物及びその製造法 |
| ATE340199T1 (de) | 2001-06-28 | 2006-10-15 | Basf Ag | Saure hochquellfähige hydrogele |
| US6727345B2 (en) | 2001-07-03 | 2004-04-27 | Nippon Shokubai Co., Ltd. | Continuous production process for water-absorbent resin powder and powder surface detector used therefor |
| US6716894B2 (en) | 2001-07-06 | 2004-04-06 | Nippon Shokubai Co., Ltd. | Water-absorbent resin powder and its production process and uses |
| DE10138150A1 (de) | 2001-08-03 | 2003-02-13 | Basf Ag | Verfahren zur Herstellung wasserabsorbierender Harze |
| JP2003165883A (ja) | 2001-09-18 | 2003-06-10 | San-Dia Polymer Ltd | 吸水性重合体とこれを用いてなる吸収性物品 |
| US8426670B2 (en) | 2001-09-19 | 2013-04-23 | Nippon Shokubai Co., Ltd. | Absorbent structure, absorbent article, water-absorbent resin, and its production process and evaluation method |
| JP2003088553A (ja) | 2001-09-19 | 2003-03-25 | Sumitomo Seika Chem Co Ltd | 吸収体およびそれを用いた吸収性物品 |
| JP4261853B2 (ja) | 2001-09-19 | 2009-04-30 | 株式会社日本触媒 | 吸水性樹脂、吸水性樹脂粒子、およびその製造方法 |
| JP2003088554A (ja) | 2001-09-19 | 2003-03-25 | Sumitomo Seika Chem Co Ltd | 吸収体およびそれを用いた吸収性物品 |
| JP4455790B2 (ja) * | 2001-09-28 | 2010-04-21 | 株式会社日本触媒 | （メタ）アクリル酸の製造方法 |
| CN1129628C (zh) | 2001-10-23 | 2003-12-03 | 清华大学 | 一种交联剂及其高吸水性树脂的制备方法 |
| JP2003225565A (ja) | 2001-11-20 | 2003-08-12 | San-Dia Polymer Ltd | 吸水剤、その製法、吸水剤を用いた吸収体並びに吸収性物品 |
| US20030100830A1 (en) * | 2001-11-27 | 2003-05-29 | Sheng-Ping Zhong | Implantable or insertable medical devices visible under magnetic resonance imaging |
| EP1456258B1 (en) * | 2001-12-19 | 2009-04-01 | Nippon Shokubai Co., Ltd. | Water-absorbent resin and production process therefor |
| JP4084648B2 (ja) | 2001-12-19 | 2008-04-30 | 株式会社日本触媒 | 吸水性樹脂の製造方法 |
| DE60233590D1 (de) * | 2001-12-19 | 2009-10-15 | Nippon Catalytic Chem Ind | Acrylsäurezusammensetzung und verfahren zu ihrer herstellung, verfahren zur herstellung von wasserabsorbierendem harz, bei dem diese acrylsäurezusammendes harz |
| US6867269B2 (en) | 2001-12-19 | 2005-03-15 | Nippon Shokubai Co., Ltd. | Water-absorbent resin and production process therefor |
| DE10163543A1 (de) | 2001-12-21 | 2003-07-31 | Basf Ag | Tocopherol-haltige Superabsorber |
| JP2003206381A (ja) | 2002-01-15 | 2003-07-22 | Sumitomo Seika Chem Co Ltd | 吸水性樹脂の着色防止方法 |
| AU2003213458A1 (en) | 2002-03-13 | 2003-09-22 | Honda Giken Kogyo Kabushiki Kaisha | Fine particle generating apparatus, casting apparatus and casting method |
| DE10211686A1 (de) | 2002-03-15 | 2003-10-02 | Stockhausen Chem Fab Gmbh | (Meth)Acrylsäurekristall und Verfahren zur Herstellung und Aufreinigung von wässriger (Meth)Acrylsäure |
| JP2003306609A (ja) | 2002-04-18 | 2003-10-31 | Taimei Chemicals Co Ltd | 吸水性ポリマー組成物、およびその製造方法 |
| DE10221202A1 (de) | 2002-05-13 | 2003-07-10 | Basf Ag | Verfahren zur Herstellung von wässrigen für die Herstellung von Acrylsäurepolymeren geeigneten Acrylsäure-Lösung II |
| DE10221176A1 (de) | 2002-05-13 | 2003-11-27 | Basf Ag | Verfahren zur Herstellung geruchsarmer Hydrogelbildender Polymerisate |
| DE10225943A1 (de) | 2002-06-11 | 2004-01-08 | Basf Ag | Verfahren zur Herstellung von Estern von Polyalkoholen |
| EP1516009A1 (de) | 2002-06-11 | 2005-03-23 | Basf Aktiengesellschaft | (meth)acrylester von polyalkoxyliertem trimethylolpropan |
| BR0311489A (pt) | 2002-06-11 | 2005-03-15 | Basf Ag | éster, processos para a preparação do mesmo e de um hidrogel reticulado, hidrogel reticulado, usos de um polìmero, de uma mistura de reação e de um éster, e, composição de matéria |
| WO2004003036A1 (en) | 2002-06-26 | 2004-01-08 | Dow Global Technologies Inc. | Process for the preparation of iron ion containing water-absorbent polymers with low residual monomer content |
| JP4314193B2 (ja) | 2002-08-23 | 2009-08-12 | ビーエーエスエフ ソシエタス・ヨーロピア | 高吸収性ポリマーおよびその製造方法 |
| JP2004121400A (ja) | 2002-09-30 | 2004-04-22 | San-Dia Polymer Ltd | 吸収剤とこれを用いてなる吸収性物品 |
| US7193006B2 (en) | 2002-12-06 | 2007-03-20 | Nippon Shokubai Co., Ltd. | Process for continuous production of water-absorbent resin product |
| DE10257397A1 (de) * | 2002-12-06 | 2004-06-24 | Basf Ag | Verfahren zur Reduktion des MEHQ Gehalts in Acrylsäure |
| DE10257449A1 (de) * | 2002-12-09 | 2003-11-06 | Basf Ag | Verfahren zur Herstellung geruchsarmer Hydrogel-bildender Polymerisate |
| JP4615853B2 (ja) | 2002-12-26 | 2011-01-19 | 株式会社日本触媒 | 吸水性樹脂組成物 |
| JP2004210924A (ja) | 2002-12-27 | 2004-07-29 | Sumitomo Seika Chem Co Ltd | 吸水性樹脂組成物 |
| JP4739682B2 (ja) | 2003-02-10 | 2011-08-03 | 株式会社日本触媒 | 吸水剤 |
| WO2004069293A1 (en) | 2003-02-10 | 2004-08-19 | Nippon Shokubai Co., Ltd. | Water-absorbent resin composition and its production process |
| BRPI0403937A (pt) | 2003-02-10 | 2005-03-01 | Nippon Catalytic Chem Ind | Absorvente de água particulado contendo resina absorvente de água como principal componente e artigo sanitário para absorver um fluido corporal |
| JP4364665B2 (ja) | 2003-02-10 | 2009-11-18 | 株式会社日本触媒 | 粒子状吸水剤 |
| EP1594556B1 (en) | 2003-02-10 | 2007-04-11 | Nippon Shokubai Co., Ltd. | Particulate water-absorbing agent |
| JP4364020B2 (ja) | 2003-03-14 | 2009-11-11 | 株式会社日本触媒 | 吸水性樹脂粉末の表面架橋処理方法 |
| US7378453B2 (en) | 2003-03-14 | 2008-05-27 | Nippon Shokubai Co., Ltd. | Surface crosslinking treatment method of water-absorbing resin powder |
| US7118781B1 (en) | 2003-04-16 | 2006-10-10 | Cree, Inc. | Methods for controlling formation of deposits in a deposition system and deposition methods including the same |
| JP2004339678A (ja) | 2003-04-24 | 2004-12-02 | Mitsubishi Chemicals Corp | 吸水性樹脂複合体およびその堆積物の製造方法 |
| CN1805975A (zh) | 2003-04-24 | 2006-07-19 | 三菱化学株式会社 | 吸水性聚合物的复合物及其堆积物的制备方法 |
| US20040214499A1 (en) | 2003-04-25 | 2004-10-28 | Kimberly-Clark Worldwide, Inc. | Absorbent structure with superabsorbent material |
| US7169843B2 (en) | 2003-04-25 | 2007-01-30 | Stockhausen, Inc. | Superabsorbent polymer with high permeability |
| JP4460851B2 (ja) | 2003-05-27 | 2010-05-12 | 株式会社日本触媒 | 吸水性樹脂の整粒方法 |
| JP4342213B2 (ja) | 2003-05-30 | 2009-10-14 | 株式会社日本触媒 | 吸水性樹脂の製造法 |
| MX285679B (es) | 2003-06-24 | 2011-04-14 | Nippon Catalytic Chem Ind | Composicion de resina absorbente de agua y metodo de produccion de la misma. |
| JP2005054050A (ja) | 2003-08-04 | 2005-03-03 | Mitsubishi Chemicals Corp | 吸水性樹脂の製造方法 |
| EP2156850A1 (en) | 2003-08-27 | 2010-02-24 | Nippon Shokubai Co., Ltd. | Process for production of surface-treated particulate water-absorbent resin |
| JP4324055B2 (ja) | 2003-08-27 | 2009-09-02 | 株式会社日本触媒 | 表面処理された粒子状吸水性樹脂の製造方法 |
| EP1512417B1 (en) | 2003-09-02 | 2013-06-19 | Nippon Shokubai Co., Ltd. | Particulate water-absorbent resin composition |
| JP2005081204A (ja) | 2003-09-05 | 2005-03-31 | Nippon Shokubai Co Ltd | 吸水性樹脂組成物の製造方法 |
| JP4640923B2 (ja) | 2003-09-05 | 2011-03-02 | 株式会社日本触媒 | 粒子状吸水性樹脂組成物の製造方法 |
| JP4746292B2 (ja) | 2003-09-12 | 2011-08-10 | 株式会社日本触媒 | 吸水性樹脂組成物の製造方法 |
| TWI308570B (en) | 2003-09-19 | 2009-04-11 | Nippon Catalytic Chem Ind | Water absorbent and producing method of same |
| DE602004020159D1 (de) | 2003-09-19 | 2009-05-07 | Nippon Catalytic Chem Ind | Wasserabsorbierendes Harz mit behandelten Oberflächen und Verfahren zu seiner Herstellung |
| US7173086B2 (en) | 2003-10-31 | 2007-02-06 | Stockhausen, Inc. | Superabsorbent polymer with high permeability |
| WO2005044915A1 (en) | 2003-11-07 | 2005-05-19 | Nippon Shokubai Co., Ltd. | Particulate water-absorbent resin composition and its production process |
| JP4926474B2 (ja) | 2004-02-05 | 2012-05-09 | 株式会社日本触媒 | 粒子状吸水剤及びその製造方法並びに吸水性物品 |
| DE602005009599D1 (de) | 2004-03-24 | 2008-10-23 | Nippon Catalytic Chem Ind | Kontinuierliches Herstellungsverfahren für Wasser-absorbierendes Harz |
| JP2005288265A (ja) | 2004-03-31 | 2005-10-20 | Procter & Gamble Co | 水性液吸収剤およびその製造方法 |
| JP4866733B2 (ja) | 2004-03-31 | 2012-02-01 | 株式会社日本触媒 | 水性液吸収剤の製造方法 |
| BRPI0510765A (pt) | 2004-05-07 | 2007-11-20 | Nippon Catalytic Chem Ind | método de produção de um agente de absorção de água, e agente de absorção de água |
| US20050288182A1 (en) | 2004-06-18 | 2005-12-29 | Kazushi Torii | Water absorbent resin composition and production method thereof |
| JP2006008963A (ja) | 2004-06-21 | 2006-01-12 | Inkuriizu:Kk | コーティング材及び光触媒分散用液剤 |
| JP2006068731A (ja) | 2004-08-06 | 2006-03-16 | Nippon Shokubai Co Ltd | 吸水性樹脂を主成分とする粒子状吸水剤、その製造方法及び吸収性物品 |
| AU2005285763A1 (en) | 2004-09-24 | 2006-03-30 | Nippon Shokubai Co., Ltd. | Particulate water-absorbing agent containing water-absorbent resin as a main component |
| DE102004051242A1 (de) | 2004-10-20 | 2006-05-04 | Basf Ag | Feinteilige wasserabsorbierende Polymerpartikel mit hoher Flüssigkeitstransport- und Absorptionsleistung |
| US20090298963A1 (en) | 2004-12-10 | 2009-12-03 | Nippon Shokubai Co., Ltd | Method for production of modified water absorbent resin |
| DE602005011491D1 (de) | 2004-12-10 | 2009-01-15 | Nippon Catalytic Chem Ind | Verfahren zur oberflächenbehandlung von wasserabsorbierendem harz |
| US20060128827A1 (en) | 2004-12-10 | 2006-06-15 | The Procter & Gamble Company | Absorbent members comprising modified water absorbent resin for use in diapers |
| JP2006233008A (ja) | 2005-02-24 | 2006-09-07 | Nippon Shokubai Co Ltd | 吸水性樹脂組成物の製造方法および吸水性樹脂組成物 |
| WO2006098271A1 (ja) | 2005-03-14 | 2006-09-21 | Nippon Shokubai Co., Ltd. | 吸水剤およびその製造方法 |
| TW200635969A (en) | 2005-04-06 | 2006-10-16 | Nippon Catalytic Chem Ind | Particulate water absorbing agent, water-absorbent core and absorbing article |
| TWI353360B (en) | 2005-04-07 | 2011-12-01 | Nippon Catalytic Chem Ind | Production process of polyacrylic acid (salt) wate |
| EP1869119B1 (en) | 2005-04-12 | 2010-03-03 | Nippon Shokubai Co., Ltd. | Particulate water absorbing agent including polyacrylic acid (polyacrylate) based water absorbing resin as a principal component, method for production thereof, water-absorbent core and absorbing article in which the particulate water absorbing agent is used |
| US7786182B2 (en) | 2005-09-16 | 2010-08-31 | Nippon Shokubai Co., Ltd. | Method for production of water absorbing agent |
| TW200712114A (en) | 2005-09-30 | 2007-04-01 | Nippon Catalytic Chem Ind | Method for manufacturing particulate water-absorbing agent and particulate water-absorbing agent |
| TW200720347A (en) | 2005-09-30 | 2007-06-01 | Nippon Catalytic Chem Ind | Water-absorbent agent composition and method for manufacturing the same |
| TW200728324A (en) | 2005-12-22 | 2007-08-01 | Nippon Catalytic Chem Ind | Production method of hydrophilic polymer |
| TWI377222B (en) | 2005-12-22 | 2012-11-21 | Nippon Catalytic Chem Ind | Method for surface crosslinking water-absorbing resin and method for manufacturing water-absorbing resin |
| TWI394789B (zh) | 2005-12-22 | 2013-05-01 | Nippon Catalytic Chem Ind | 吸水性樹脂組成物及其製造方法、吸收性物品 |
| EP1837348B9 (en) | 2006-03-24 | 2020-01-08 | Nippon Shokubai Co.,Ltd. | Water-absorbing resin and method for manufacturing the same |
| WO2007116777A1 (en) | 2006-03-27 | 2007-10-18 | Nippon Shokubai Co., Ltd. | Water absorbing agent, water absorbent core using the agent, and manufacturing method for water absorbing agent |
| DE602007003397D1 (de) | 2006-03-29 | 2010-01-07 | Nippon Catalytic Chem Ind | Verfahren zur Herstellung von wasserabsorbierendem Polyacrylsäure (Salz)-Harz |
| WO2008015980A1 (fr) | 2006-08-04 | 2008-02-07 | Sumitomo Seika Chemicals Co., Ltd. | Particule de résine absorbant l'eau, son procédé de production et matière absorbante qui l'utilise |
| US8596931B2 (en) | 2007-03-29 | 2013-12-03 | Nippon Shokubai Co., Ltd. | Particulate water absorbing agent and method for producing the same |
| US8975339B2 (en) | 2007-10-09 | 2015-03-10 | Nippon Shokubai Co., Ltd. | Surface treatment method for water-absorbent resin |
| JP2010065107A (ja) | 2008-09-10 | 2010-03-25 | San-Dia Polymer Ltd | 吸収性樹脂粒子及び吸収性物品 |
| CN102149754A (zh) | 2008-09-12 | 2011-08-10 | 巴斯夫欧洲公司 | 吸水材料 |
| KR101511820B1 (ko) | 2008-12-26 | 2015-04-13 | 산다이야 폴리마 가부시키가이샤 | 흡수성 수지 입자, 이 제조 방법, 이것을 함유하는 흡수체 및 흡수성 물품 |
| WO2011040472A1 (ja) | 2009-09-29 | 2011-04-07 | 株式会社日本触媒 | 粒子状吸水剤及びその製造方法 |
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Also Published As
| Publication number | Publication date |
|---|---|
| US20080119626A1 (en) | 2008-05-22 |
| US8729191B2 (en) | 2014-05-20 |
| KR20070112833A (ko) | 2007-11-27 |
| EP1866349A4 (en) | 2009-12-30 |
| RU2007140959A (ru) | 2009-05-20 |
| KR100914107B1 (ko) | 2009-08-27 |
| WO2006109845A1 (en) | 2006-10-19 |
| WO2006109842A1 (en) | 2006-10-19 |
| EP1879930A1 (en) | 2008-01-23 |
| JP2008537553A (ja) | 2008-09-18 |
| SG161231A1 (en) | 2010-05-27 |
| TW200702340A (en) | 2007-01-16 |
| JP5269314B2 (ja) | 2013-08-21 |
| TW200708522A (en) | 2007-03-01 |
| EP1866349A1 (en) | 2007-12-19 |
| RU2355711C1 (ru) | 2009-05-20 |
| RU2385328C2 (ru) | 2010-03-27 |
| TWI344469B (en) | 2011-07-01 |
| KR100902218B1 (ko) | 2009-06-11 |
| US20080161512A1 (en) | 2008-07-03 |
| US9062140B2 (en) | 2015-06-23 |
| EP1879930A4 (en) | 2009-12-30 |
| EP1879930B1 (en) | 2013-01-16 |
| KR20070119040A (ko) | 2007-12-18 |
| JP2008534695A (ja) | 2008-08-28 |
| EP1866349B1 (en) | 2012-12-26 |
| JP4647607B2 (ja) | 2011-03-09 |
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