JP2736935B2 - 金属錯体化合物 - Google Patents

金属錯体化合物

Info

Publication number
JP2736935B2
JP2736935B2 JP2242861A JP24286190A JP2736935B2 JP 2736935 B2 JP2736935 B2 JP 2736935B2 JP 2242861 A JP2242861 A JP 2242861A JP 24286190 A JP24286190 A JP 24286190A JP 2736935 B2 JP2736935 B2 JP 2736935B2
Authority
JP
Japan
Prior art keywords
compound according
alkyl
independently
carbon atoms
cyclopentadienyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP2242861A
Other languages
English (en)
Other versions
JPH03139504A (ja
Inventor
シー ステーブンス ジエームス
アール ネイザマー デビツド
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27019786&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=JP2736935(B2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of JPH03139504A publication Critical patent/JPH03139504A/ja
Application granted granted Critical
Publication of JP2736935B2 publication Critical patent/JP2736935B2/ja
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/28—Titanium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は触媒として有用な金属錯体化合物に関する。
〔従来の技術〕
EP−Ａ−0277004にはビス（シクロペンタジエニル）
金属錯体を非配位性の相溶性アニオンを含むブレンステ
ツド酸の塩と反応させることによつて製造した若干のビ
ス（シクロペンタジエニル）金属化合物が記載されてい
る。このEP特許はこのような錯体がオレフイン重合触媒
として有利に使用される事実を開示している。
〔発明が解決しようとする課題〕
上記の従来技術に記載されている触媒の有用性にもか
かわらず、付加重合用の更に効率で有用な触媒を製造す
ることが望ましい。本発明はこの課題を解決するもので
あり、重合触媒として高度に活性であり且つ広範囲の種
類のモノマーおよびモノマー混合物の重合を望ましく可
能にするある種の改良された金属錯体含有化合物を提供
するものである。
〔課題を解決するための手段〕
上記の課題を解決するための手段として、本発明によ
れば、次式 CpMXn＋A- 〔式中、Ｍはチタンまたはジルコニウムであり;Cpは式 〔Ｒ′はそれぞれの場合独立に水素、ハロゲンまたは20
以下の炭素原子をもつアルキル、アリールもしくはハロ
アルキル、シリル基およびそれらの組合せからえらばれ
た基であり； Ｒ″はＲ′であるか又は式 〔Ｙは窒素またはリンであり;Rはそれぞれの場合独立
に10以下の炭素原子もしくはケイ素原子をもつアルキ
ル、アリール、シリルまたはそれらの組合せであり;mは
１〜４の整数である〕のＹを介してＭに共有結合してい
る２価の基である〕 で示されるシクロペンタジエニルもしくは置換シクロペ
ンタジエニル基であり； Ｘはそれぞれの場合独立にハロゲンまたは20以下の炭
素原子をもつアルキル、アリール、アリールオキシまた
はアルコキシであり； ｎは１または２であり；そして A-は〔BQ4〕− 〔Ｂは原子価が３の状態のホウ素であり；そしてＱはそ
れぞれの場合独立にハイドライド、ハロゲンまたは20個
以下の炭素原子をもつジアルキルアミド、アルコキサイ
ド、アリールオキサイド、ヒドロカルビルもしくは置換
ヒドロカルビル基であって但しＱハライドは１個以下で
ある〕 である〕 に相当するモノシクロペンタジエニルまたは置換モノシ
クロペンタジエニル金属錯体含有化合物が今や提供され
る。
このような化合物は配位型重合法に使用して型成形，
フイルム，シート，押出し発泡およびその他の用途に使
用されるポリマーを製造するのに有用である。これらの
化合物はまた水素化反応、接触クラツキングおよびその
他の工業プロセスに使用することもできる。
本発明の化合物は次の（ａ）成分および（ｂ）成分を
不活性非プロトン性溶媒中で混合し、そして所望ならば
生成物を回収することによつて製造することができる。
（ａ）第２成分（以下に述べる）のカチオンと結合する
少なくとも１種の置換分を含む、且つその原子価より１
つ少ない配位数を通常もつカチオンを形成しうる、チタ
ンまたはジルコニウムのモノ（シクロペンタジエニル）
誘導体である少なくとも１種の第１成分；および （ｂ）ブロンステツド酸および非配位性の相溶性アニオ
ンから成る塩である少なくとも１種の第２成分。
上記の第１成分はCpMXn +のカチオンを形成しうるもの
であり、第２成分の非配位性の相溶性アニオンはA-に相
当するものである。
本発明の金属錯体化合物は前記一般式で示されるが、
特に好ましい金属錯体化合物は式 〔Cp＊はＭにη５結合様式で結合した２価のシクロペン
タジェニルまたは置換シクロペンタジェニル基であり； Ｙは窒素またはリンであり;Rはそれぞれの場合独立
に10以下の炭素原子もしくはケイ素原子をもつアルキ
ル、アリール、シリルまたはそれらの組合せであり;mは
１〜４の整数である〕のＹを介してＭに共有結合してい
る２価の基であり、X,nおよびA-は前記のとおりであ
る〕に相当する化合物である。
本発明の化合物の製造に使用しうるモノシクロペンタ
ジエニル金属成分（第一成分）の好適な例は、ヒドロカ
ルビル置換モノシクロペンタジエニル金属化合物、たと
えばシクロペンタジエニルジルコニウムトリメチル，シ
クロペンタジエニルジルコニウムトリエチル，シクロペ
ンタジエニルジルコニウムトリプロピル，シクロペンタ
ジエニルチタントリメチル，シクロペンタジエニルチタ
ントリフエニル，など；ヒドロカルビル置換化合物たと
えばシクロペンタジエニルチタントリイソプロポキサイ
ド，シクロペンタジエニルジルコニウムトリフエノキサ
イドなど；ハロ置換化合物たとえばシクロペンタジエニ
ルジルコニウムトリクロライド，インデニルチタントリ
クロライド，など；および置換基の混合物を含む化合物
たとえばシクロペンタジエニルチタンイソプロポキサイ
ドジメチル，ペンタメチルシクロペンタジエニルジルコ
ニウムメチルジクロライド，（ｔ−ブチルアミド）（テ
トラメチル−η５−シクロペンタジエニル）−1,2−エ
ンタジイルジルコニウムジクロライド，（ｔ−ブチルア
ミド）（テトラメチル−η５−シクロペンタジエニル）
−1,2−エタンジイルチタンジクロライド，（メチルア
ミド）（テトラメチル−η５−シクロペンタジエニル）
−1,2−エタンジイルジルコニウムジクロライド，（メ
チルアミド）（テトラメチル−η５−シクロペンタジエ
ニル）−1,2−エタンジイルチタンジクロライド，（エ
チルアミド）（テトラメチル−η５−シクロペンタジエ
ニル）・メチレンチタンジクロライド，（ｔ−ブチルア
ミド）ジベンジル（テトラメチル−η５−シクロペンタ
ジエニル）シランジルコニウムジベンジル，（ベンジル
アミド）ジメチル（テトラメチル−η５−シクロペンタ
ジエニル）シランチタンジクロライド，（フエニルホス
フイド）ジメチル（テトラメチル−η５−シクロペンタ
ジエニル）シランジルコニウムジベンジルなどである。
上記リストの最後の項にかかげた化合物類はシクロペ
ンタジエニル環の金属原子と置換分との間に共有結合を
含む化合物の例である。好ましい置換分は金属原子にδ
縮合しうる置換分である。このような化合物は対応する
金属クロライドを置換シクロペンタジエニル基（たとえ
ばシクロペンタジエニル・アルカンジイル，シクロペン
タジエニル・シランアミド，またはシクロペンタジエニ
ル・ホスフイド化合物）のジリチウム塩と混合すること
によつて容易に製造することができる。この反応は通常
の合成法を使用して不活性液体（たとえばテトラヒドロ
フラン,C5-10アルカン，トルエンなど）中で行なわれ
る。
本発明の化合物の製造に第２成分として有用な化合物
は次の一般式によつて表わすことができる。
〔Ｌ−Ｈ〕＋〔BQ4〕− ただしＬは中性塩基であり；〔Ｌ−Ｈ〕＋はブロンス
テツド酸であり;Bは原子価３の状態のホウ素であり；そ
してＱは前記定義のとおりである。
本発明の改良触媒の製造に第２成分として使用しうる
ホウ素化合物の例は次のとおりであるが、これらに限定
されない： トリアルキル置換アンモニウム塩たとえばトリエチル
アンモニウムテトラフエニルボレート，トリプロピルア
ンモニウムテトラフエニルボレート，トリ（ｎ−ブチ
ル）アンモニウムテトラフエニルボレート，トリメチル
アンモニウムテトラ（ｐ−トリルボレート），トリブチ
ルアンモニウムテトラキス−ペンタフルオロフエニルボ
レート，トリプロピルアンモニウムテトラキス−2,4−
ジメチルフエニルボレート，トリブチルアンモニウムテ
トラキス−3,5−ジメチルフエニルボレート，トリエチ
ルアンモニウムテトラキス−（3,5−ジ−トリフルオロ
メチルフエニル）ボレートなど。また、N,N−ジアルキ
ルアニリニウム塩たとえばN,N−ジエチルアニリニウム
テトラフエニルボレート,N,N−2,4,6−ペンタメチルア
ニリニウムテトラフエニルボレートなど；ジアルキルア
ンモニウム塩たとえばジ−（ｉ−プロピル）アンモニウ
ムテトラキスペンタフルオロフエニルボレート，ジシク
ロヘキシルアンモニウムテトラフエニルボレートなど；
およびトリアリールホスホニウム塩たとえばトリフエニ
ルホスホニウムテトラフエニルボレート，トリ（メチル
フエニル）ホスホニウムテトラキス−ペンタフルオロフ
エニルボレート，トリ（ジメチルフエニル）ホスホニウ
ムテトラフエニルボレートなど；も好適である。
一般に、そして上記の第１成分の大部分が上記の第２
成分の大部分と組合せられて活性なオレフイン重合触媒
を生じるけれども、第１成分から始めに生成した金属カ
チオンまたはそれらの分解生成物が比較的安定な触媒で
あるということが連続重合操作にとつて重要である。ま
たアンモニウム塩を使用する場合、第２化合物のアニオ
ンが加水分解に対して安定であることも重要である。更
に、第２成分の酸性度が第１成分に対して十分であつ
て、必要なプロトン移動を促進させることも重要であ
る。逆に、金属錯体の塩基性度も必要なプロトン移動を
促進するに十分でなければならない。若干のメタローセ
ン（非金属性）化合物はブロンステツド酸以外のすべて
との反応に対して耐性があり、従つて第２成分のすべて
と本発明の触媒を形成する第１成分として好適ではな
い。最も好ましいモノシクロペンタジエニル金属化合物
は水溶液によつて加水分解しうる化合物である。
本発明の触媒を製造するための第１（金属含有）成分
と第２成分との組合せに関して、活性触媒の製造のため
に組合せられるこれら２成分はアニオン断片とくにアリ
ール基または弗素もしくは水素原子が金属カチオンに移
動して触媒的に不活性な種を形成するのを避けるように
えらばれるべきであることに注目すべきである。これ
は、シクロペンタジエニル炭素上の置換分ならびにアニ
オンの芳香族炭素環上の置換分から生ずる立体障害によ
つて行なうことができる。従つてパーヒドロカルビル置
換シクロペンタジエニル基を含む第１成分は非置換シク
ロペンタジエニル基を第１成分がなしうるよりも広い範
囲の第２成分と共に有効に使用することができる。然し
ながら、シクロペンタジエニル基上の置換分の量と大き
さが減少するにつれて、劣化に対してより耐性のあるア
ニオンを含む第２成分たとえばフエニル環のオルソ位に
置換分をもつものを用いてより有効な触媒がえられる。
アニオンを劣化に対してより耐性にする別の手段はアニ
オン中のフツ素置換基特に完全弗素置換基によつて与え
られる。弗素置換安定性アニオンは次いでより広い範囲
の第１成分と共に使用することができる。
一般に、触媒は約−100℃〜約300℃の範囲内の温度に
おいて好適な溶媒中で上記２成分を混合することによつ
て製造される。この触媒を使用して２〜約18個の炭素原
子をもつα−オレフインおよび／またはアセチレン性不
飽和モノマーおよび／または約４〜約18個の炭素原子を
もつジオレフインを単独でまたは組合せにおいて重合さ
せることができる。この触媒はまたα−オレフイン，ジ
オレフインおよび／またはアセチレン性不飽和モノマー
を他の不飽和モノマーと組合せて重合させるためにも使
用することができる。好ましい態様において、この触媒
はビニル芳香族モノマーとビニル芳香族モノマー以外の
オレフインとのコポリマーとくにスチレンとエチレンま
たはプロピレンとのコポリマーを製造するのに使用され
る。一般に、重合は当業技術において周知の条件におい
て行なうことができる。触媒成分を重合プロセスに直接
に添加し、そして好適な溶媒または希釈剤（凝縮モノマ
ーを包含する）を重合プロセス中に使用するならば、触
媒系はその場で生成することがもちろん理解されるであ
ろう。然しながら、触媒はこれを重合工程に加える前に
好適な溶媒中別の工程で製造するのが好ましい。触媒は
発火性の種を含んではならないけれども、触媒成分は水
分と酸素の双方に敏感であり、不活性雰囲気（たとえば
窒素，アルゴンまたはヘリウム）中で取扱い及び搬送す
べきである。
上記のように、本発明の改良触媒は好ましくは好適な
不活性非プロトン性溶媒もしくは希釈剤中で製造され
る。好適な溶媒または希釈剤としてオレフイン，ジオレ
フインおよびアセチレン性不飽和モノマーの重合におい
て溶媒として有用であることの知られている従来技術に
周知のすべての溶媒をあげることができる。然し好適な
溶媒として次のものをあげることができるが、必ずしも
これらに限定されない：直鎖または枝分かれ鎖の炭化水
素たとえばイソブタン，ブタン，ペンタン，ヘキサン，
ヘプタン，オクタンなど；環状および脂環状炭化水素た
とえばシクロヘキサン，シクロペンタン，メチルシクロ
ペンタン，メチルシクロヘプタンなど；ならびに芳香族
およびアルキル置換芳香族化合物たとえばベンゼン，ト
ルエン，キシレンなど。好適な溶媒はまた液状オレフイ
ン類をも包含する。これらはモノマーまたはコモノマー
としても働き、例としてエチレン，プロピレン，ブタジ
エン，シクロペンテン,1−ヘキセン,3−メチル−１−ペ
ンテン,4−メチル−１−ペンテン,1,4−ヘキサジエン,1
−オクテン,1−デセン，スチレンなどがあげられる。
特定の理論によつて拘束されることを欲しないけれど
も、本発明の改良触媒の製造に使用する２成分を好適な
溶媒または希釈剤中で混合するとき、第２成分（酸性部
分）のカチオンの一部または全部は第１成分の置換基
（Ｘ）の１つと結合する。その結果として、中性化合物
XHが放出され、この中性化合物は溶液中にとどまるか、
あるいはガスとして放出される。この点に関して、第１
成分中のＸがハイドライドであるならば水素ガスが発生
することに注目すべきである。同様に、Ｘがメチル基で
あるならば、メタンがガスとして発生する。Ｘがアルコ
キサイドであるならば、アルコールが生成する。
特定の理論に拘束されることを欲しないけれども、第
１成分の置換基が放出されるとき、触媒製造に使用する
第２成分中に始めから含まれている非配位性のアニオン
は第１成分から生成する金属カチオンまたはその分解生
成物の電荷を均衡させる。この金属カチオンおよび非配
位性アニオンは、触媒が１種またはそれ以上のオレフイ
ン，ジオレフインおよび／またはアセチレン性不飽和モ
ノマーの単独と或いは１種またはそれ以上の他のモノマ
ーまたは別の中性ルイス塩基と接触せしめられるまで、
結合されたまゝでいる。上記の如く、第２成分中に含ま
れるアニオンはモノマーによる迅速な置換を可能にして
重合を促進するに十分に可動性でなければならない。
本発明の触媒を製造する際に起る化学反応は、好まし
いホウ素含有化合物を第２成分として使用するとき、下
記に示す一般式を参照することによつて表わすことがで
きる。
CpMXn+1＋〔Ｌ−Ｈ〕＋〔BQ4〕− →〔CpMXn〕＋〔BQ4〕−＋Ｘ−Ｈ＋Ｌ 〔式中のCp,M,X,nおよびＱは前記の意味をもつ。〕 一般に、上記反応式中の生成物特に金属カチオンの安
定性および生成速度は、溶媒の選択，えらばれた〔Ｌ−
Ｈ〕＋の酸性度，特定のL,アニオン，反応完了時の温
度，およびえらばれた金属の特定のモノシクロペンタジ
エニル誘導体に応じて変化する。一般に、始めに生成す
るイオン対は活性重合触媒であり、α−オレフイン，ジ
オレフインおよびアセチレン性不飽和モノマーのいづれ
か単独または他のモノマーとの組合せを重合させる。然
しながら、ある場合には、始めの金属カチオンは分解し
て活性重合触媒を生じる。
上述の如く、上記のほとんどの第１成分は上記の第２
成分と混合して活性触媒とくに活性重合触媒を生成す
る。然しながら、実際の活性触媒種はその分離と爾後の
確認を可能にするように十分に安定であるとは必ずしも
限らない。その上、および生成する初期金属カチオンの
多くは比較的安定であるけれども、初期に生成する金属
カチオンは多くの場合分解して１種またはそれ以上の他
の触媒的に活性な種になる。
一般に、本発明による触媒はアルミニウムまたはマグ
ネシウム基材の化合物のような共触媒を含むチグラ−・
ナツタ触媒により生成するポリマー中に一般に見出され
る痕跡量の金属を含まないポリマー生成物を生成するよ
うにえらばれる。本発明の触媒により生成するポリマー
は、金属アルキル（たとえばアルミニウムアルキル）ま
たはアルミノキサンを含むより通常のチグラ−・ナツタ
型触媒により生成するポリマーよりも広い範囲の用途を
もつ。この触媒は均一触媒として又は好適な担体（たと
えばアルミナまたはシリカ）に担持させた触媒として使
用することができる。
本発明の最も好ましい態様において、Cpはペンタメチ
ルシクロペンタジエンであり、Ｍはチタンまたはジルコ
ニウムであり、ｎは２であり、ＸはC1 〜 ４アルキルまた
はアルコキサイドであり、Ａはテトラキス・ペンタフル
オロフエニルボレートである。
更に好ましい態様において、触媒は１種またはそれ以
上のC2〜C8α−オレフイン特にエチレンまたはプロピレ
ン、最も好ましくはエチレンを０℃〜200℃好ましくは2
5℃〜100℃の範囲の温度において、大気圧〜1000psig
（7MPa）好ましくは15〜500psig（0.1〜3.5MPa）の範囲
の圧力で重合させるのに使用される。本発明の最も好ま
しい態様において、触媒はエチレンを均一重合させるた
めに又はエチレンとC3〜C8α−オレフイン（スチレンを
包含する）と共重合させてコポリマーを作るために使用
される。この好ましい態様および最も好ましい態様の双
方において、モノマーは約１〜約60分の範囲の通常の保
持時間のあいだ重合条件に保持され、触媒はモノマー１
モル当り約10-7−約10-1モルの範囲の濃度で使用され
る。
〔実施例〕
以上のとおり本発明を広く述べてきたが、本発明は下
記の実施例を参照することによつて更になお明らかにな
るであろう。然しながら、これらの実施例は本発明を具
体的に説明するためにのみ提示するものであつて、本発
明を限定するものと解すべきではない。
実施例１ ペンタメチルシクロペンタジエニルチタンイソプロポキ
サイドジメチルおよびトリエチルアンモニウムテトラキ
ス・ペンタフルオロフエニルボレート 室温の乾燥ボツクスにおいて、33mgのペンタメチルシ
クロペンタジエニルチタンイソプロポキサイドジメチル
〔CpTi（Ｏ−ｉ−Pr）Me2〕（0.12ミリモル）を1mlのベ
ンゼンと混合し、生成溶液をピペツトで250mlの３ツ口
フラスコに入れた。栓，真空ライン用のアダプタ，およ
び固体添加ロートを取付けた。添加ロートに80mg（0.10
ミリモル）のトリエチルアンモニウムテトラキス・ペン
タフルオロフエニルボレート（〔HNEt3〕＋〔Ｂ（C
6F5）４〕−）を充てんした。添加ロートに栓をして装
置を真空ラインに取付けた。ベンゼンを真空下にフラス
コから除き、75mlの新しいベンゼンを真空下−78℃のフ
ラスコに留出させた。室温に加温後、溶液を１気圧（0.
1MPa）のエチレンで覆つた。固体の（〔HNEt3〕＋〔Ｂ
（C6F5）４〕−）を室温で加え、溶液が黄色に変つたこ
とを観察した。20分後に溶液は黒色であり、ポリエチレ
ンの沈殿が観察された。１時間後に、ポリマーをメタノ
ールで沈殿させ、収集し、メタノールで洗浄し、真空下
で一夜乾燥し、0.49gのポリマーを得た。
実施例２ ペンタメチルシクロペンタジエニルチタントリメチルお
よびトリエチルアンモニウムテトラキス・ペンタフルオ
ロフエニルボレート ペンタメチルシクロペンタジエニルチタントリメチル
およびトリエチルアンモニウム・ペンタフルオロフエニ
ルボレートを使用して実施例１の反応条件を実質的にく
りかえした。反応はトルエン中で約10時間室温において
続けた。メタンガスおよびアンモニアの副生物が観察さ
れた。約45℃に１時間加熱後、溶媒を真空下で除去し黒
色固体をえた。この固体を石油エーテルで３回洗浄し、
減圧下に乾燥した。回収した生成物は所望のペンタメチ
ルシクロペンタジエニル・チタンジメチルテトラキス・
ペンタフルオロフエニルボレートであると確信された。
このものは周知のチグラー・ナツタ重合条件下でオレフ
インを重合させるのに使用することができる。
実施例３ （ｔ−ブチルアミド）ジメチル（テトラメチル−η５−
シクロペンタジエニル）シランチタンジメチルおよびト
リエチルアンモニウムテトラキス・ペンタフルオロフエ
ニルボレート 25mlフラスコに275mgの（ｔ−ブチルアミド）（ジメ
チル）（η５−テトラメチルシクロペンタジエニル）シ
ランチタンジクロライド（0.75ミリモル）を充てんし、
これに小さいフリツトガラスを取付けた。このフリツト
を真空にし、15mlのジエチルエーテルをフラスコに真空
で移した。−78℃において、1.1mlのMeLi（ヘキサン中
1.4M,1.54ミリモル,2.05当量）を注射器を使用してサイ
ドアーム・バルブから添加した。調整変化は観察されな
かつた。５分後に内容物を取出し、溶液を室温に加温し
た。１時間後、この溶液は暗緑色で不透明であつた。ジ
エチルエーテルを追出して10mlのヘキサンで置換した。
この溶液を25℃で10分間撹拌してから過した。固体を
約2mlにまで減少させ、溶液を−78℃に冷却し、フリツ
ト冷却フリツプから暗オリーブ色の固体を集めた。減圧
下に30分間乾燥した後に、固体の（ｔ−ブチルアミド）
ジメチル（テトラメチル−η５−シクロペンタジエニ
ル）シランチタンジメチルを単離した（138mg,56％）。
重合 100mgの３つ口フラスコに32mg（98μモル）の（ｔ−
ブチルアミド）ジメチル（テトラメチル−η５−シクロ
ペンタジエニル）シランチタンジメチルを充てんした。
このフラスコに栓，真空ラインアダプターおよび固体添
加ロートを取付けた。この添加ロートに77mgの〔HNE
t3〕＋〔Ｂ（C6H5）４〕−を充てんし、栓をした。この
フラスコを真空にし、50mlのベンゼンを固体上に留出さ
せた。この溶液を25℃に加温し、１気圧（0.1MPa）のエ
チレンで覆つた。次いで固体〔HNEt3〕＋〔Ｂ（C6F5）
４〕−を加え、黄色溶液を得た。１時間後、粘稠黄色溶
液は依然としてエチレンを吸収しつつあつた。生成する
ゼラチン状混合物をメタノールで急冷して白色沈殿をえ
た。この沈殿を過し、メタノールで２回洗浄し、真空
乾燥して0.56gのポリエチレンを得た。
実施例４−12 2Lのステンレス鋼撹はん反応器に1Lの混合C6-8アルカ
ン溶媒を、次いで表Ｉに同定される適量のコモノマーを
満たした。反応器を適温に加熱し、次いでエチレンで加
圧した。水素を用いた場合は次いで75mlの供給容器から
反応器へ膨張させた。数分後、トルエン溶液中の触媒と
共触媒の混合物を転移配管を通して反応器に加え、次い
で5mlのトルエンで転移配管を洗った。反応器を開けて
メタノールと抗酸化剤を加えて反応を停止した。ポリマ
ーを減圧下に一定重量まで乾燥した。結果を表Ｉに示
す。用いたのは次の触媒と共触媒である。
触媒 I.（タートブチルアミド）ジメチル（テトラメチル−η
５−シクロペンタジエニル）シランチタンジメチル II.（タートブチルアミド）ジメチル（テトラメチル−
η５−シクロペンタジエニル）シランジルコニウムメチ
ル 共触媒 A.ジメチルアニリニウム テトラキスパーフルオロフェ
ニルボレート B.トリエチルアンモニウム テトラキスパーフルオロフ
ェニルボレート C.トリエチルアンモニウム メチルトリスパーフルオロ
フェニルボレート D.トリエチルアンモニウム アリルトリスパーフルオロ
フェニルボレート E.トリエチルアンモニウム ｎ−ブチルトリスパーフル
オロフェニルボレート F.トリエチルアンモニウム ベンジルトリスパーフルオ
ロフェニルボレート 結果は表Ｉに含まれる。
───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 昭62−187708（ＪＰ，Ａ) 特開 平１−185302（ＪＰ，Ａ) 特開 平３−188092（ＪＰ，Ａ) 特開 平２−110106（ＪＰ，Ａ)

Claims (11)

    (57)【特許請求の範囲】
  1. 【請求項１】次式 CpMXn＋A- 〔式中、Ｍはチタンまたはジルコニウムであり;Cpは式 〔Ｒ′はそれぞれの場合独立に水素、ハロゲンまたは20
    以下の炭素原子をもつアルキル、アリールもしくはハロ
    アルキル、シリル基およびそれらの組合せからえらばれ
    た基であり； Ｒ″はＲ′であるか又は式 〔Ｙは窒素またはリンであり;Rはそれぞれの場合独立
    に10以下の炭素原子もしくはケイ素原子をもつアルキ
    ル、アリール、シリルまたはそれらの組合せであり;mは
    １〜４の整数である〕のＹを介してＭに共有結合してい
    る２価の基である〕 で示されるシクロペンタジエニルもしくは置換シクロペ
    ンタジエニル基であり； Ｘはそれぞれの場合独立にハロゲンまたは20以下の炭素
    原子をもつアルキル、アリール、アリールオキシまたは
    アルコキシであり； ｎは１または２であり；そして A-は〔BQ4〕− 〔Ｂは原子価が３の状態のホウ素であり；そしてＱはそ
    れぞれの場合独立にハイドライド、ハロゲンまたは20個
    以下の炭素原子をもつジアルキルアミド、アルコキサイ
    ド、アリールオキサイド、ヒドロカルビルもしくは置換
    ヒドロカルビル基であって但しＱハライドは１個以下で
    ある〕 である〕 に相当するモノシクロペンタジエニルまたは置換モノシ
    クロペンタジエニル金属錯体含有化合物。
  2. 【請求項２】Ｒ″が式 〔Ｙは窒素またはリンであり;Rはそれぞれの場合独立
    に10以下の炭素原子もしくはケイ素原子をもつアルキ
    ル、アリール、シリルまたはそれらの組合せであり;mは
    １〜４の整数である〕のＹを介してＭに共有結合してい
    る２価の基であり;nが１である請求項１記載の化合物。
  3. 【請求項３】Ｒ″がＲ′であり、ｎが２である請求項１
    記載の化合物。
  4. 【請求項４】Ｒ′の炭素原子が10以下である請求項１〜
    ３のいずれか１項記載の化合物。
  5. 【請求項５】Ｒ′がメチルである請求項１〜４のいずれ
    か１項記載の化合物。
  6. 【請求項６】Ｍがチタンである請求項１〜５のいずれか
    １項記載の化合物。
  7. 【請求項７】Cpがペンタメチルシクロペンタジェニルで
    あり、Ｘが炭素原子１〜４のアルキルまたはアルコキシ
    である請求項３記載の化合物。
  8. 【請求項８】A-がフルオロ置換アニオンである請求項１
    〜７のいずれか１項記載の化合物。
  9. 【請求項９】A-がパーフルオロ置換アニオンである請求
    項８記載の化合物。
  10. 【請求項１０】A-がテトラキス（ペンタフルオロフェニ
    ル）ボレートである請求項９記載の化合物。
  11. 【請求項１１】（タートブチルアミド）ジメチル（テト
    ラメチル−η５−シクロペンタジェニル）シランチタン
    メチルテトラキス（ペンタフルオロフェニル）ボレート
    である請求項１記載の化合物。
JP2242861A 1989-09-14 1990-09-14 金属錯体化合物 Expired - Lifetime JP2736935B2 (ja)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US40716989A 1989-09-14 1989-09-14
US407169 1989-09-14
US07/547,728 US5064802A (en) 1989-09-14 1990-07-03 Metal complex compounds
US547728 1990-07-03

Related Child Applications (1)

Application Number Title Priority Date Filing Date
JP9217230A Division JP3010349B2 (ja) 1989-09-14 1997-08-12 付加重合触媒及び付加重合方法

Publications (2)

Publication Number Publication Date
JPH03139504A JPH03139504A (ja) 1991-06-13
JP2736935B2 true JP2736935B2 (ja) 1998-04-08

Family

ID=27019786

Family Applications (2)

Application Number Title Priority Date Filing Date
JP2242861A Expired - Lifetime JP2736935B2 (ja) 1989-09-14 1990-09-14 金属錯体化合物
JP9217230A Expired - Lifetime JP3010349B2 (ja) 1989-09-14 1997-08-12 付加重合触媒及び付加重合方法

Family Applications After (1)

Application Number Title Priority Date Filing Date
JP9217230A Expired - Lifetime JP3010349B2 (ja) 1989-09-14 1997-08-12 付加重合触媒及び付加重合方法

Country Status (20)

Country Link
US (2) US5064802A (ja)
EP (2) EP0765882A3 (ja)
JP (2) JP2736935B2 (ja)
KR (1) KR0168048B1 (ja)
CN (1) CN1028369C (ja)
BR (1) BR9004695A (ja)
CA (1) CA2025332C (ja)
DE (1) DE69031413T3 (ja)
ES (1) ES2106021T5 (ja)
FI (1) FI100104B (ja)
GE (1) GEP19991571B (ja)
HK (1) HK1001919A1 (ja)
HU (1) HU218602B (ja)
IL (1) IL95598A (ja)
NO (1) NO302702B1 (ja)
NZ (1) NZ235215A (ja)
RO (1) RO106411B1 (ja)
RU (1) RU2095363C1 (ja)
SG (1) SG43055A1 (ja)
YU (1) YU47114B (ja)

Families Citing this family (844)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5198401A (en) * 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5384299A (en) * 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US7163907B1 (en) * 1987-01-30 2007-01-16 Exxonmobil Chemical Patents Inc. Aluminum-free monocyclopentadienyl metallocene catalysts for olefin polymerization
USRE37788E1 (en) * 1987-01-30 2002-07-09 Exxon Chemical Patents, Inc. Monocyclopentadienyl metal compounds for ethylene-α-olefin-copolymer production catalysts
US5621126A (en) * 1987-01-30 1997-04-15 Exxon Chemical Patents Inc. Monocyclopentadienyl metal compounds for ethylene-α-olefin-copolymer production catalysts
US5055438A (en) * 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
PL276385A1 (en) * 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5264405A (en) 1989-09-13 1993-11-23 Exxon Chemical Patents Inc. Monocyclopentadienyl titanium metal compounds for ethylene-α-olefin-copolymer production catalysts
US5241025A (en) * 1987-01-30 1993-08-31 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5408017A (en) * 1987-01-30 1995-04-18 Exxon Chemical Patents Inc. High temperature polymerization process using ionic catalysts to produce polyolefins
US5830087A (en) * 1995-06-26 1998-11-03 Lisco, Inc. Multi-layer golf ball
GB8914703D0 (en) * 1989-06-27 1989-08-16 Dow Europ Sa Bioriented film
NZ235032A (en) * 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5763547A (en) * 1992-10-02 1998-06-09 The Dow Chemical Company Supported catalyst complexes for olefin in polymerization
US6025448A (en) 1989-08-31 2000-02-15 The Dow Chemical Company Gas phase polymerization of olefins
US5547675A (en) * 1989-09-13 1996-08-20 Exxon Chemical Patents Inc. Modified monocyclopentadienyl transition metal/alumoxane catalyst system for polymerization of olefins
US6825369B1 (en) * 1989-09-14 2004-11-30 The Dow Chemical Company Metal complex compounds
CA2024830A1 (en) * 1989-09-29 1991-03-30 Richard E. Campbell, Jr. Process for preparation of syndiotactic vinyl aromatic polymers
CA2035650C (en) * 1990-02-14 1997-02-25 Hajime Yasuda Process of preparing polymer or copolymer of unsaturated carboxylic acid ester
US5218064A (en) * 1990-02-14 1993-06-08 Showa Denko K.K. Process for preparing narrow molecular weight distribution syndiotactic polymers or copolymers of unsaturated carboxylic acid esters
US6294625B1 (en) 1990-03-20 2001-09-25 Exxonmobil Chemical Patents Inc. Catalyst system of enhanced productivity and its use in polymerization process
US5516739A (en) * 1990-04-20 1996-05-14 The University Of North Carolina At Chapel Hill Late transition metal catalysts for the co- and terpolymerization of olefin and alkyne monomers with carbon monoxide
EP0454231A3 (en) * 1990-04-20 1992-01-15 The University Of North Carolina At Chapel Hill Late transition metal catalysts for olefin polymerization
US5801113A (en) * 1990-06-22 1998-09-01 Exxon Chemical Patents, Inc. Polymerization catalyst systems, their production and use
DE551277T1 (de) * 1990-06-22 1996-10-10 Exxon Chemical Patents Inc., Linden, N.J. Aluminiumfreie monocyclopentadienyl-metallocenkatalysatoren für olefinpolymerisation.
US5272236A (en) * 1991-10-15 1993-12-21 The Dow Chemical Company Elastic substantially linear olefin polymers
JP2545006B2 (ja) * 1990-07-03 1996-10-16 ザ ダウ ケミカル カンパニー 付加重合触媒
US6538080B1 (en) 1990-07-03 2003-03-25 Bp Chemicals Limited Gas phase polymerization of olefins
DE69130320T2 (de) * 1990-07-24 1999-04-08 Mitsui Chemicals Inc Katalysator für alpha-olefinpolymerisation und herstellung von poly(alpha)olefinen damit
CA2070654C (en) * 1990-10-05 2003-06-03 Takuji Okamoto Process for producing cyclic olefin based polymers, cyclic olefin copolymers, compositions and molded articles comprising the copolymers
WO1992009640A1 (en) * 1990-11-30 1992-06-11 Idemitsu Kosan Co., Ltd. Process for producing olefinic polymer
JP2888648B2 (ja) * 1990-12-28 1999-05-10 出光興産株式会社 スチレン系重合体の製造方法及びその触媒
US5206197A (en) * 1991-03-04 1993-04-27 The Dow Chemical Company Catalyst composition for preparation of syndiotactic vinyl aromatic polymers
JP2939354B2 (ja) * 1991-03-26 1999-08-25 出光興産株式会社 スチレン系重合体の製造方法及びその触媒
US5418200A (en) * 1991-03-29 1995-05-23 Chevron Chemical Company Cyclopentadienyl group 6B metal α-olefin polymerization catalysts and process for polymerizing α-olefins
JP3275211B2 (ja) * 1991-05-20 2002-04-15 ザ ダウ ケミカル カンパニー 付加重合触媒の製造方法
DE69219206T2 (de) * 1991-05-31 1997-08-28 Mitsui Petrochemical Ind Fester Katalysatorbestandteil, Katalysator und Verfahren für Olefinpolymerisation
JPH04366109A (ja) * 1991-06-12 1992-12-18 Idemitsu Kosan Co Ltd スチレン系重合体の製造方法及びその触媒
US5721185A (en) * 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5444134A (en) * 1991-07-11 1995-08-22 Idemitsu Kosan Co., Ltd. Process for producing olefin based polymers and olefin polymerization catalyst
US5886117A (en) * 1991-08-05 1999-03-23 The Dow Chemical Company Process using borane derived catalysts for preparation of syndiotactic vinyl aromatic polymers
KR100236805B1 (ko) * 1991-10-15 2000-02-01 그레이스 스티븐 에스. 금속 배위 착화합물의 제조방법
US5525695A (en) * 1991-10-15 1996-06-11 The Dow Chemical Company Elastic linear interpolymers
US5278272A (en) * 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers
US5674342A (en) 1991-10-15 1997-10-07 The Dow Chemical Company High drawdown extrusion composition and process
US5562958A (en) * 1991-10-15 1996-10-08 The Dow Chemical Company Packaging and wrapping film
US5783638A (en) 1991-10-15 1998-07-21 The Dow Chemical Company Elastic substantially linear ethylene polymers
US6448355B1 (en) * 1991-10-15 2002-09-10 The Dow Chemical Company Elastic fibers, fabrics and articles fabricated therefrom
US5582923A (en) 1991-10-15 1996-12-10 The Dow Chemical Company Extrusion compositions having high drawdown and substantially reduced neck-in
US5395471A (en) 1991-10-15 1995-03-07 The Dow Chemical Company High drawdown extrusion process with greater resistance to draw resonance
US5410043A (en) * 1991-12-06 1995-04-25 Schering Aktiengesellschaft Process for the production of mono-N-substituted tetraaza macrocycles
EP0616618B1 (en) * 1991-12-13 1997-07-02 Exxon Chemical Patents Inc. Ethylene/longer alpha-olefin copolymers
EP0619827B1 (en) * 1991-12-30 1996-06-12 The Dow Chemical Company Ethylene interpolymer polymerizations
US6545088B1 (en) 1991-12-30 2003-04-08 Dow Global Technologies Inc. Metallocene-catalyzed process for the manufacture of EP and EPDM polymers
DE69224287T2 (de) * 1992-01-06 1998-08-27 The Dow Chemical Co., Midland, Mich. Katalysatorzusammensetzung
JP3194438B2 (ja) * 1992-01-08 2001-07-30 出光興産株式会社 スチレン系重合体の製造方法及びその触媒
WO1993019103A1 (en) * 1992-03-16 1993-09-30 Exxon Chemical Patents Inc. IONIC CATALYST FOR THE PRODUCTION OF POLY-α-OLEFINS OF CONTROLLED TACTICITY
US5374696A (en) * 1992-03-26 1994-12-20 The Dow Chemical Company Addition polymerization process using stabilized reduced metal catalysts
US6143854A (en) 1993-08-06 2000-11-07 Exxon Chemical Patents, Inc. Polymerization catalysts, their production and use
US5296433A (en) * 1992-04-14 1994-03-22 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
US5350723A (en) * 1992-05-15 1994-09-27 The Dow Chemical Company Process for preparation of monocyclopentadienyl metal complex compounds and method of use
DE4218744C2 (de) * 1992-06-04 1997-11-06 Schering Ag Verfahren zur Herstellung von N-ß-Hxdroxyalkyl-tri-N-carboxylalkyl-1,4,7,10-tetraazacyclododecan- und N-ß-Hydroxyalkyl-tri-N-carboxyalkyl-1,4,8,11-tetraazacyclotetradecan-Derivaten und deren Metallkomplexe
JP3153000B2 (ja) * 1992-06-11 2001-04-03 三菱化学株式会社 α‐オレフィン重合体の製造法
CA2139356C (en) * 1992-07-01 2001-02-06 Donna J. Crowther Transition metal olefin polymerization catalysts
EP0591756B1 (en) * 1992-09-22 1998-11-25 Idemitsu Kosan Company Limited Polymerization catalysts and process for producing polymers
EP0662979B1 (en) * 1992-10-02 1997-07-16 The Dow Chemical Company Supported homogeneous catalyst complexes for olefin polymerization
US5300598A (en) * 1992-10-16 1994-04-05 Northwestern University Method of polymerizing exo-methylene cyclic organic compounds using homogeneous ring-opening catalysts
US5422406A (en) * 1992-10-16 1995-06-06 Northwestern University Rare earth homogeneous catalysts for the ring-opening polymerization and copolymerization of strained-ring olefins
ATE291059T1 (de) 1992-11-13 2005-04-15 Cryovac Inc Wärmeschrumpfbare, durch single-site-katalyse hergestellte copolymere enthaltende folien.
US5554310A (en) 1992-12-17 1996-09-10 Exxon Chemical Patents Inc. Trisubstituted unsaturated polymers
US5859159A (en) * 1992-12-17 1999-01-12 Exxon Chemical Patents Inc. Dilute process for the polymerization of non-ethylene α-olefin homopolymers and copolymers using metallocene catalyst systems
DE69433347T2 (de) * 1993-01-29 2004-04-15 Dow Global Technologies, Inc., Midland Ethylen Copolymerisation
US5347024A (en) * 1993-03-19 1994-09-13 The Dow Chemical Company Preparation of addition polymerization catalysts via Lewis acid mitigated metal center oxidation
ES2156153T3 (es) * 1993-06-15 2001-06-16 Idemitsu Kosan Co Procedimiento de produccion de polimero olefinico, y catalizador para la polimerizacion de una olefina.
US5372682A (en) * 1993-06-24 1994-12-13 The Dow Chemical Company Electrochemical preparation of addition polymerization catalysts
NZ268270A (en) * 1993-06-24 1997-10-24 Dow Chemical Co Titanium (ii)- or zirconium (ii)- containing complexes and addition polymerisation catalysts therefrom (m is ti or zr)
JP3189175B2 (ja) * 1993-07-02 2001-07-16 出光興産株式会社 芳香族ビニル化合物共重合体の製造方法
US5514728A (en) * 1993-07-23 1996-05-07 Minnesota Mining And Manufacturing Company Catalysts and initiators for polymerization
US5455333A (en) * 1993-08-16 1995-10-03 Albemarle Corporation Preparation of metallocenes
US5929128A (en) * 1993-08-18 1999-07-27 The Dow Chemical Company Gaskets made from olefin polymers
US5446117A (en) * 1993-08-19 1995-08-29 Queen's University At Kingston Process for producing amorphous syndiotactic polystyrene
ES2160634T3 (es) 1993-09-17 2001-11-16 Exxonmobil Chem Patents Inc Sistemas catalizadores de polimerizacion, su produccion y uso.
US5504223A (en) * 1994-01-25 1996-04-02 The Dow Chemical Company Synthesis of cyclopentadienyl metal coordination complexes from metal hydrocarbyloxides
FR2715661B1 (fr) * 1994-01-31 1996-04-05 Rhone Poulenc Chimie Nouveaux photoamorceurs organométalliques polymériques et les compositions polyorganosiloxanes qui les comprennent réticulables par voie cationique.
ES2171184T5 (es) * 1994-02-14 2005-09-16 Univation Technologies Llc Sistemas cataliticos de polimerizacion, su produccion y uso.
US5691422A (en) * 1994-03-07 1997-11-25 Exxon Chemical Patents Inc. Saturated polyolefins having terminal aldehyde or hydroxy substituents and derivatives thereof
US5674950A (en) * 1994-03-07 1997-10-07 Exxon Chemical Patents Inc. Polymers having terminal hydroxyl aldehyde, or alkylamino substitutents and derivatives thereof
US5504224A (en) * 1994-03-14 1996-04-02 The Dow Chemical Company Preparation of monocyclopentadienyl metal complexes by nucleophilic substitution of bis(cyclopentadienyl) metal complexes
US5648438A (en) * 1994-04-01 1997-07-15 Exxon Chemical Patents, Inc. Process for producing polymers with multimodal molecular weight distributions
US6008307A (en) * 1994-04-28 1999-12-28 Exxon Chemical Patents Inc Process for producing olefin polymers using cationic catalysts
US6291389B1 (en) 1994-04-28 2001-09-18 Exxonmobil Chemical Patents Inc. Cationic polymerization catalysts
US5439996A (en) * 1994-06-01 1995-08-08 Queen's University At Kingston Synthesis of polymers of vinyl ethers, 1,5-hexadiene and N-vinylcarbazole
WO1995033776A1 (en) * 1994-06-07 1995-12-14 Specs And Biospecs B.V. Novel organo-metallic compounds, methods for preparing same, and a method for the polymerization of unsaturated hydrocarbons using said organo-metallic compounds as catalysts, as well as novel semi-products and catalyst preparations
US5936041A (en) * 1994-06-17 1999-08-10 Exxon Chemical Patents Inc Dispersant additives and process
US6160066A (en) 1994-06-24 2000-12-12 Exxon Chemical Patents, Inc. Monocyclopentadienyl metal compounds for ethylene-α-olefin-copolymer production catalysts
US5955625A (en) * 1995-01-31 1999-09-21 Exxon Chemical Patents Inc Monocyclopentadienyl metal compounds for ethylene-α-olefin-copolymer production catalysts
US5543480A (en) * 1994-06-28 1996-08-06 The Dow Chemical Company Polymerization process using diene containing catalysts
US5486632A (en) * 1994-06-28 1996-01-23 The Dow Chemical Company Group 4 metal diene complexes and addition polymerization catalysts therefrom
US5561216A (en) * 1994-07-01 1996-10-01 University Of North Carolina At Chapel Hill Late transition metal catalysts for the CO- and terpolymerization of olefin and alkyne monomers with carbon monoxide
CA2191483C (en) * 1994-07-11 2003-02-25 Antonio Gutierrez Lubricating oil succinimide dispersants derived from heavy polyamine
US5616664A (en) * 1994-08-02 1997-04-01 The Dow Chemical Company Polymerization process with biscyclopentadienyl diene complex containing catalysts
US6111020A (en) * 1994-09-02 2000-08-29 The Dow Chemical Company Crosslinked foams from blends of ethylene vinyl acetate and ethylene-styrene interpolymers
DE4431838A1 (de) * 1994-09-07 1996-03-14 Basf Ag Geträgerte Metallocen-Katalysatorsysteme
US5541349A (en) * 1994-09-12 1996-07-30 The Dow Chemical Company Metal complexes containing partially delocalized II-bound groups and addition polymerization catalysts therefrom
US5495036A (en) * 1994-09-12 1996-02-27 The Dow Chemical Company Metal (III) complexes containing conjugated, non-aromatic anionic II-bound groups and addition polymerization catalysts therefrom
US5625087A (en) * 1994-09-12 1997-04-29 The Dow Chemical Company Silylium cationic polymerization activators for metallocene complexes
US5883144A (en) * 1994-09-19 1999-03-16 Sentinel Products Corp. Silane-grafted materials for solid and foam applications
US5929129A (en) 1994-09-19 1999-07-27 Sentinel Products Corp. Crosslinked foamable compositions of silane-grafted, essentially linear polyolefins blended with polypropylene
US5932659A (en) 1994-09-19 1999-08-03 Sentinel Products Corp. Polymer blend
US5536797A (en) * 1994-10-03 1996-07-16 The Dow Chemical Company Syndiotactic prochiral olefin polymerization process
US5565128A (en) * 1994-10-12 1996-10-15 Exxon Chemical Patents Inc Lubricating oil mannich base dispersants derived from heavy polyamine
US6030917A (en) * 1996-07-23 2000-02-29 Symyx Technologies, Inc. Combinatorial synthesis and analysis of organometallic compounds and catalysts
US6419881B1 (en) 1994-10-18 2002-07-16 Symyx Technologies, Inc. Combinatorial arrays of organometallic compounds and catalysts
US6440745B1 (en) 1994-10-18 2002-08-27 Symyx Technologies Combinatorial synthesis and screening of organometallic compounds and catalysts
US5985356A (en) 1994-10-18 1999-11-16 The Regents Of The University Of California Combinatorial synthesis of novel materials
US5792534A (en) 1994-10-21 1998-08-11 The Dow Chemical Company Polyolefin film exhibiting heat resistivity, low hexane extractives and controlled modulus
US6300451B1 (en) 1994-10-24 2001-10-09 Exxon Chemical Patents Inc. Long-chain branched polymers and their production
US6043180A (en) * 1994-11-17 2000-03-28 The Dow Chemical Company Supported catalyst component, supported catalyst, their preparation, and addition polymerization process
US6506866B2 (en) * 1994-11-17 2003-01-14 Dow Global Technologies Inc. Ethylene copolymer compositions
US7153909B2 (en) * 1994-11-17 2006-12-26 Dow Global Technologies Inc. High density ethylene homopolymers and blend compositions
US5625015A (en) 1994-11-23 1997-04-29 Exxon Chemical Patents Inc. Method for making supported catalyst systems and catalyst systems therefrom
WO1996016094A1 (en) * 1994-11-23 1996-05-30 The Dow Chemical Company Preparation of syndiotactic polyolefins from prochiral olefins
US5512693A (en) * 1994-12-07 1996-04-30 The Dow Chemical Company Preparation of titanium (II) or zirconium (II) complexes
AU4419496A (en) * 1994-12-12 1996-07-03 Dow Chemical Company, The Hydrogenation of unsaturated polymers using monocyclopentadienyl group iv metal catalysts
US6287613B1 (en) 1994-12-12 2001-09-11 Cryovac Inc Patch bag comprising homogeneous ethylene/alpha-olefin copolymer
US5554775A (en) * 1995-01-17 1996-09-10 Occidental Chemical Corporation Borabenzene based olefin polymerization catalysts
JPH11503113A (ja) * 1995-03-10 1999-03-23 ザ ダウ ケミカル カンパニー 支持された触媒成分、支持された触媒、製造法、重合法、錯体化合物、及びその製造法
US5721183A (en) * 1995-03-10 1998-02-24 The Dow Chemical Company Catalyst system comprising amine or phosphine adducts of tris(organyl)borane compounds
US5527752A (en) * 1995-03-29 1996-06-18 Union Carbide Chemicals & Plastics Technology Corporation Catalysts for the production of polyolefins
US5491246A (en) * 1995-04-24 1996-02-13 The Dow Chemical Company Synthesis of group 4 metal diene complexes
US5578690A (en) * 1995-04-28 1996-11-26 Northwestern University Silyl-terminated interpolymer of ethylene and method for preparing silyl-terminated polyolefins
DE19522013A1 (de) * 1995-06-21 1997-01-02 Hoechst Ag Übergangsmetallverbindung
EP0842939B1 (en) 1995-07-14 2004-10-06 Sumitomo Chemical Company, Limited Olefin polymerization catalyst containing a transition metal complex and process for producing olefin polymers
US5869575A (en) * 1995-08-02 1999-02-09 The Dow Chemical Company Ethylene interpolymerizations
US5652202A (en) * 1995-08-15 1997-07-29 Exxon Chemical Patents Inc. Lubricating oil compositions
CN1080724C (zh) * 1995-08-31 2002-03-13 住友化学工业株式会社 过渡金属配合物,烯烃聚合催化剂及生产烯烃聚合物的方法
US5558802A (en) * 1995-09-14 1996-09-24 Exxon Chemical Patents Inc Multigrade crankcase lubricants with low temperature pumpability and low volatility
US5962714A (en) * 1995-10-02 1999-10-05 Mccullough; Laughlin Gerard Monocyclopentadienyl transition metal catalyst and olefin polymerization process
IT1276070B1 (it) 1995-10-31 1997-10-24 Siac It Additivi Carburanti Processo per la preparazione di polimeri a base di etilene a basso peso molecolare
US5942461A (en) * 1995-11-06 1999-08-24 Minnesota Mining And Manufacturing Company Polymerizable compositions comprising alpha-olefin hydrocarbon monomers and methods of use therefor
US5709921A (en) * 1995-11-13 1998-01-20 Kimberly-Clark Worldwide, Inc. Controlled hysteresis nonwoven laminates
CA2163681C (en) * 1995-11-24 2007-02-13 Daryll G. Harrison Supported monocyclopentadienyl zirconium catalyst
CA2192156C (en) * 1995-12-08 2006-07-11 Nobuhiro Tsujimoto Catalyst and process for producing conjugated diene polymer
US5854362A (en) * 1995-12-11 1998-12-29 The Dow Chemical Company Supported biscyclopentadienyl metal complexes
US5952252A (en) * 1996-02-20 1999-09-14 Kimberly-Clark Worldwide, Inc. Fully elastic nonwoven fabric laminate
US6274752B1 (en) 1996-02-20 2001-08-14 Northwestern University Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations
US5856256A (en) * 1996-02-20 1999-01-05 Northwestern University Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations
US6291695B1 (en) 1996-02-20 2001-09-18 Northwestern University Organo-Lewis acids of enhanced utility, uses thereof, and products based thereon
US5695849A (en) * 1996-02-20 1997-12-09 Kimberly-Clark Worldwide Inc. Elastic, breathable, barrier fabric
IT1282666B1 (it) 1996-02-22 1998-03-31 Enichem Spa Catalizzatore metallocenico sostituito per la (co) polimerizzazione delle olefine
US6063633A (en) 1996-02-28 2000-05-16 The University Of Houston Catalyst testing process and apparatus
US6103647A (en) * 1996-03-14 2000-08-15 Kimberly-Clark Worldwide, Inc. Nonwoven fabric laminate with good conformability
KR20000005027A (ko) * 1996-03-27 2000-01-25 그레이스 스티븐 에스. 분산된 촉매 활성화제를 사용하는 용액 중합 방법
ES2147985T3 (es) * 1996-03-27 2000-10-01 Dow Chemical Co Activador de catalizador de la polimerizacion de olefinas altamente soluble.
EP0889913B1 (en) * 1996-03-27 2003-07-02 Dow Global Technologies Inc. Allyl containing metal complexes and olefin polymerization process
US6225426B1 (en) * 1996-04-10 2001-05-01 Uniroyal Chemical Company, Inc. Process for producing polyolefin elastomer employing a metallocene catalyst
US5844009A (en) 1996-04-26 1998-12-01 Sentinel Products Corp. Cross-linked low-density polymer foam
CA2203595A1 (en) 1996-04-26 1997-10-26 Robert F. Hurley Cross-linked polyolefin tape
US5670680A (en) * 1996-04-26 1997-09-23 The Dow Chemical Company Method for producing octahydrofluorenyl metal complexes
AU2674397A (en) * 1996-05-07 1997-11-26 Dow Chemical Company, The Improved syndiotactic vinylidene aromatic polymerization process
JPH09309926A (ja) * 1996-05-17 1997-12-02 Dow Chem Co:The エチレン共重合体の製造方法
US6066603A (en) * 1996-06-17 2000-05-23 Exxon Chemical Patents Inc. Polar monomer containing copolymers derived from olefins useful as lubricant and useful as lubricant and fuel oil additivies process for preparation of such copolymers and additives and use thereof
US5811379A (en) * 1996-06-17 1998-09-22 Exxon Chemical Patents Inc. Polymers derived from olefins useful as lubricant and fuel oil additives, processes for preparation of such polymers and additives and use thereof (PT-1267)
US6194341B1 (en) 1996-06-17 2001-02-27 Exxon Chemical Patents Inc. Mixed transition metal catalyst systems for olefin polymerization
US6368708B1 (en) 1996-06-20 2002-04-09 3M Innovative Properties Company Polyolefin microspheres
US5959044A (en) * 1996-07-08 1999-09-28 Villar; Juan Carlos Method of controlling continuous ethylene-limited metallocene-catalyzed copolymerization systems
US5882776A (en) 1996-07-09 1999-03-16 Sentinel Products Corp. Laminated foam structures with enhanced properties
US5876813A (en) 1996-07-09 1999-03-02 Senitnel Products Corp Laminated foam structures with enhanced properties
ATE229026T1 (de) * 1996-07-22 2002-12-15 Dow Global Technologies Inc Verbrückte nicht-aromatische anionische dienylgruppen enthaltende metallkomplexe und darauf basierte polymerisatonskatalysatoren
AU718544B2 (en) * 1996-07-23 2000-04-13 Dow Chemical Company, The Olefin polymerization catalyst composition comprising group 13 compound
NZ333878A (en) 1996-08-08 2000-08-25 Dow Chemical Co 3-heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process
US5698022A (en) * 1996-08-14 1997-12-16 Advanced Technology Materials, Inc. Lanthanide/phosphorus precursor compositions for MOCVD of lanthanide/phosphorus oxide films
US5938878A (en) 1996-08-16 1999-08-17 Sentinel Products Corp. Polymer structures with enhanced properties
ZA977909B (en) 1996-09-04 1999-03-03 Dow Chemical Co Compositions comprising a substantially random interpolymer of at least one alpha-olefin and at least one vinylidene aromatic monomer or hindered aliphatic vinylidene monomer
US5849823A (en) * 1996-09-04 1998-12-15 The Dow Chemical Company Homogeneously branched ethylene α-olefin interpolymer compositions for use in gasket applications
AU712414B2 (en) 1996-09-04 1999-11-04 Dow Chemical Company, The Floor, wall or ceiling covering
US5902854A (en) * 1996-09-27 1999-05-11 The Dow Chemical Company Polydimethylsiloxane containing polymer blends
US6271322B1 (en) 1996-10-02 2001-08-07 Mccullough Laughlin Gerard Monocyclopentadienyl transition metal catalyst and olefin polymerization process
US6015868A (en) * 1996-10-03 2000-01-18 The Dow Chemical Company Substituted indenyl containing metal complexes and olefin polymerization process
US6720186B1 (en) 1998-04-03 2004-04-13 Symyx Technologies, Inc. Method of research for creating and testing novel catalysts, reactions and polymers
US5853881A (en) * 1996-10-11 1998-12-29 Kimberly-Clark Worldwide, Inc. Elastic laminates with improved hysteresis
US6610408B1 (en) 1996-11-08 2003-08-26 Solvay Engineered Polymers TPO blends containing multimodal elastomers
US6221928B1 (en) 1996-11-15 2001-04-24 Sentinel Products Corp. Polymer articles including maleic anhydride
US6812289B2 (en) 1996-12-12 2004-11-02 Dow Global Technologies Inc. Cast stretch film of interpolymer compositions
US5783512A (en) 1996-12-18 1998-07-21 The Dow Chemical Company Catalyst component dispersion comprising an ionic compound and solid addition polymerization catalysts containing the same
US5965756A (en) * 1996-12-19 1999-10-12 The Dow Chemical Company Fused ring substituted indenyl metal complexes and polymerization process
DE19781602T1 (de) 1996-12-20 1999-03-11 Sumitomo Chemical Co Olefinpolymer und seine Folie oder Platte und Verfahren zur Herstellung des Olefinpolymers
US6197397B1 (en) * 1996-12-31 2001-03-06 3M Innovative Properties Company Adhesives having a microreplicated topography and methods of making and using same
AU5813498A (en) 1997-01-08 1998-08-03 Hercules Incorporated Fluorinated solid acids as catalysts for the preparation of hydrocarbon resins
EP0853091A1 (en) 1997-01-13 1998-07-15 Bp Chemicals S.N.C. Polymerisation process
US6355757B2 (en) 1997-02-14 2002-03-12 Exxonmobil Chemical Patents, Inc. Processing olefin copolymers
US5964743A (en) * 1997-02-27 1999-10-12 Kimberly-Clark Worldwide, Inc. Elastic absorbent material for personal care products
US7338698B1 (en) 1997-02-28 2008-03-04 Columbia Insurance Company Homogeneously branched ethylene polymer carpet, carpet backing and method for making same
AU6344098A (en) 1997-02-28 1998-09-18 Shaw Industries, Inc. Carpet, carpet backings and methods
US20030211280A1 (en) 1997-02-28 2003-11-13 Shaw Industries, Inc. Carpet, carpet backings and methods
US6552126B2 (en) 1997-03-03 2003-04-22 Spalding Sports Worldwide, Inc. Golf ball cover containing a blend of ionomer and plastomer, and method of making same
CA2200373C (en) * 1997-03-19 2005-11-15 Rupert Edward Von Haken Spence Heteroligand
AR012582A1 (es) 1997-04-14 2000-11-08 Dow Global Technologies Inc Composiciones polimericas de elongacion mejorada y formulaciones adhesivas de fusion en caliente que incluyen dicha composicion
US6420507B1 (en) 1997-05-01 2002-07-16 The Dow Chemical Company Olefin polymers prepared with substituted indenyl containing metal complexes
JP4024312B2 (ja) * 1997-06-20 2007-12-19 ザ ダウ ケミカル カンパニー エチレンポリマー組成物およびそれから加工された品
US6262161B1 (en) 1997-06-26 2001-07-17 The Dow Chemical Company Compositions having improved ignition resistance
US6319969B1 (en) 1997-06-26 2001-11-20 The Dow Chemical Company Interpolymer compositions for use in sound management
US6172015B1 (en) 1997-07-21 2001-01-09 Exxon Chemical Patents, Inc Polar monomer containing copolymers derived from olefins useful as lubricant and fuel oil additives, processes for preparation of such copolymers and additives and use thereof
IT1293759B1 (it) * 1997-07-23 1999-03-10 Pirelli Cavi S P A Ora Pirelli Cavi con rivestimento riciclabile a bassa deformazione residua
US6552112B1 (en) 1997-07-23 2003-04-22 Pirelli Cavi E Sistemi S.P.A. Cable with self-extinguishing properties and flame-retardant composition
US6410651B1 (en) 1997-07-23 2002-06-25 Pirelli Cavi E Sistemi S.P.A. Cables with a halogen-free recyclable coating comprising polypropylene and an ethylene copolymer having high structural uniformity
US6372344B1 (en) 1997-07-23 2002-04-16 Pirelli Cavi E Sistemi S.P.A. Cables with a halogen-free recyclable coating comprising polypropylene and an ethylene copolymer having high elastic recovery
IT1293757B1 (it) 1997-07-23 1999-03-10 Pirelli Cavi S P A Ora Pirelli Cavi con rivestimento riciclabile a distribuzione omogenea
EP1002014A1 (en) 1997-08-08 2000-05-24 The Dow Chemical Company Sheet materials suitable for use as a floor, wall or ceiling covering material, and processes and intermediates for making the same
US6921794B2 (en) 1997-08-12 2005-07-26 Exxonmobil Chemical Patents Inc. Blends made from propylene ethylene polymers
US7232871B2 (en) 1997-08-12 2007-06-19 Exxonmobil Chemical Patents Inc. Propylene ethylene polymers and production process
US6635715B1 (en) 1997-08-12 2003-10-21 Sudhin Datta Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers
DE69828975T2 (de) 1997-08-15 2006-01-12 Dow Global Technologies, Inc., Midland Filme aus im wesentlichen homogenen linearen olefinischen polymerzusammensetzungen
JP2001514273A (ja) 1997-08-27 2001-09-11 ザ ダウ ケミカル カンパニー 改良された加工性を有するエラストマー
US6284698B1 (en) 1997-09-15 2001-09-04 The Dow Chemical Company Highly activated bimetallic complexes and polymerization process
US6235917B1 (en) 1998-08-28 2001-05-22 The Dow Chemical Company Dinuclear complexes and polymerization catalysts therefrom
CA2215444C (en) * 1997-09-15 2005-08-02 Stephen John Brown Catalyst having a ketimide ligand
CA2303519A1 (en) * 1997-09-15 1999-03-25 Liting Li Bimetallic complexes and polymerization catalysts therefrom
EP1036097A1 (en) 1997-12-01 2000-09-20 Asahi Kasei Kabushiki Kaisha Olefin polymerization catalyst and method for polymerizing an olefin using the catalyst
AU2760599A (en) * 1998-02-04 1999-08-23 Friedman, Robert F. Method and apparatus for combining transponders on multiple satellites into virtual channels
US6716786B1 (en) 1998-02-20 2004-04-06 The Dow Chemical Company Supported catalyst comprising expanded anions
ATE243700T1 (de) 1998-02-20 2003-07-15 Dow Global Technologies Inc Expandierte anionen enthaltende katalysatoraktivatoren
DE19809159A1 (de) 1998-03-04 1999-09-09 Bayer Ag Metallorganische Verbindungen
EP1068377A1 (en) 1998-03-11 2001-01-17 The Dow Chemical Company Fibers made from alpha-olefin/vinyl or vinylidene aromatic and/or hindered cycloaliphatic or aliphatic vinyl or vinylidene interpolymers
JP2002506104A (ja) 1998-03-11 2002-02-26 ザ ダウ ケミカル カンパニー エンジニアリング熱可塑性樹脂とブレンドされたアルファ−オレフィンモノマーと１以上のビニルまたはビニリデン芳香族モノマーおよび／又は１以上のヒンダード脂肪族または脂環式ビニルまたはビニリデンモノマーのインターポリマーの熱可塑性組成物
US6699573B1 (en) 1998-03-16 2004-03-02 Dow Global Technologies Inc. Liner compositions
AR018359A1 (es) * 1998-05-18 2001-11-14 Dow Global Technologies Inc Articulo resistente al calor , configurado, irradiado y reticulado, libre de un agente de reticulacion de silano
US6709742B2 (en) 1998-05-18 2004-03-23 Dow Global Technologies Inc. Crosslinked elastic fibers
CA2334908A1 (en) 1998-06-12 1999-12-16 Avery Dennison Corporation Multilayered thermoplastic film and sign cutting method using the same
DE69935815T2 (de) 1998-07-01 2007-12-27 Exxonmobil Chemical Patents Inc., Baytown Elastische Mischung mit Kristallpolymeren und kristallisierbaren Polymeren des Propens
CA2245375C (en) 1998-08-19 2006-08-15 Nova Chemicals Ltd. Dual reactor polyethylene process using a phosphinimine catalyst
DE19837739A1 (de) 1998-08-20 2000-02-24 Bayer Ag Katalysatorsystem auf Basis von Fulven-Cyclopentadienyl-Metallkomplexen
DE19837734C1 (de) 1998-08-20 1999-12-23 Bayer Ag Verfahren zur Herstellung von Katalysatoren auf Basis von Fulven-Metallkomplexen
US6448464B1 (en) 1999-07-30 2002-09-10 Kimberly-Clark Worldwide, Inc. Absorbent article which maintains skin temperature when wet
US6287286B1 (en) 1998-08-25 2001-09-11 Kimberly-Clark Worldwide, Inc. Absorbent article having a reduced viability of candida albicans
US6217890B1 (en) 1998-08-25 2001-04-17 Susan Carol Paul Absorbent article which maintains or improves skin health
US6238379B1 (en) 1998-08-25 2001-05-29 Kimberly-Clark Worldwide, Inc. Absorbent article with increased wet breathability
US6152906A (en) * 1998-08-25 2000-11-28 Kimberly-Clark Worldwide, Inc. Absorbent article having improved breathability
BR9913967B1 (pt) 1998-09-16 2008-11-18 suporte de catalisador funcionalizado, catalisador suportado, mÉtodo para preparar um suporte de catalisador funcionalizado, mÉtodo para preparar uma composiÇço de catalisador suportado e processo de polimerizaÇço.
CA2247703C (en) 1998-09-22 2007-04-17 Nova Chemicals Ltd. Dual reactor ethylene polymerization process
US6924031B2 (en) 1998-09-25 2005-08-02 Pirelli Cavi E Sistemi S.P.A. Low-smoke self-extinguishing electrical cable and flame-retardant composition used therein
US6403773B1 (en) 1998-09-30 2002-06-11 Exxon Mobil Chemical Patents Inc. Cationic group 3 catalyst system
US6649548B1 (en) 1998-10-02 2003-11-18 Kimberly-Clark Worldwide, Inc. Nonwoven web and film laminate with improved strength and method of making the same
US6225427B1 (en) 1998-10-15 2001-05-01 Uniroyal Chemical Company, Inc. Olefin polymerization process employing metallocene catalyst provided by cocatalyst activation of a metallocene procatalyst
DE69943133D1 (de) 1998-11-02 2011-02-24 Dow Global Technologies Inc Unter scherwirkung verflüssigbare ethylen/alpha-olefin/dien polymere und ihre herstellung
US6368444B1 (en) 1998-11-17 2002-04-09 Kimberly-Clark Worldwide, Inc. Apparatus and method for cross-directional stretching of polymeric film and other nonwoven sheet material and materials produced therefrom
US6362389B1 (en) 1998-11-20 2002-03-26 Kimberly-Clark Worldwide, Inc. Elastic absorbent structures
CA2254512C (en) 1998-11-25 2008-02-12 Nova Chemicals Ltd. Slurry polymerization process using an unsupported phosphinimine catalyst
US5993707A (en) * 1998-12-04 1999-11-30 The Dow Chemical Company Enlarged cell size foams made from blends of alkenyl aromatic polymers and alpha-olefin/vinyl or vinylidene aromatic and/or sterically hindered aliphatic or cycloaliphatic vinyl or vinylidene interpolymers
US6231795B1 (en) 1998-12-04 2001-05-15 The Dow Chemical Company Soft and flexible foams made from blends of alkenyl aromatic polymers and alpha-olefin/vinyl or vinylidene aromatic and/or sterically hindered aliphatic or cycloaliphatic vinyl or vinylidene interpolymers
US6048909A (en) * 1998-12-04 2000-04-11 The Dow Chemical Company Foams having increased heat distortion temperature made from blends of alkenyl aromatic polymers and alpha-olefin/vinyl or vinylidene aromatic and/or sterically hindered aliphatic or cycloaliphatic vinyl or vinylidene interpolymers
US6187232B1 (en) 1998-12-04 2001-02-13 The Dow Chemical Company Acoustical insulation foams
US6281289B1 (en) 1998-12-08 2001-08-28 The Dow Chemical Company Polypropylene/ethylene polymer fiber having improved bond performance and composition for making the same
US6583076B1 (en) 1999-01-08 2003-06-24 Kimberly-Clark Worldwide, Inc. Nonwoven fabrics prepared using visbroken single-site catalyzed polypropylene
US6545108B1 (en) 1999-02-22 2003-04-08 Eastman Chemical Company Catalysts containing N-pyrrolyl substituted nitrogen donors
CN1347423A (zh) * 1999-02-22 2002-05-01 伊斯曼化学公司 含有n－吡咯基取代的氮给电体的催化剂
US6313236B1 (en) 1999-03-30 2001-11-06 Eastman Chemical Company Process for producing polyolefins
US6288181B1 (en) 1999-03-30 2001-09-11 Eastman Chemical Company Process for producing polyolefins
US6180552B1 (en) 1999-04-07 2001-01-30 Equistar Chemicals, L.P. Transition metal complexes containing neutral, multidentate azacyclic ligands
CA2365229A1 (en) 1999-04-29 2000-11-09 Dow Global Technologies Inc. Bis(n,n-dihydrocarbylamino)- substituted cyclopentadienes and metal complexes thereof
US6127484A (en) * 1999-04-29 2000-10-03 Equistar Chemicals, Lp Olefin polymerization process
US6020493A (en) * 1999-05-06 2000-02-01 Equistar Chemicals, Lp Single-site catalyst preparation
US6339134B1 (en) 1999-05-06 2002-01-15 Univation Technologies, Llc Polymerization process for producing easier processing polymers
AU3764600A (en) 1999-05-13 2000-12-05 Dow Chemical Company, The Di- and tri-heteroatom substituted indenyl metal complexes
US6646071B1 (en) 1999-05-13 2003-11-11 The Dow Chemical Company Metal complexes containing bridging heteroatom for olefin-polymerization-process
DE60020968T2 (de) 1999-06-04 2006-05-11 Dow Global Technologies, Inc., Midland Borsubstituierte cyclopentadiene und metallkomplexe dieser liganden
US6417301B1 (en) 1999-06-07 2002-07-09 Eastman Chemical Company Process for producing ethylene/olefin interpolymers
US6417299B1 (en) 1999-06-07 2002-07-09 Eastman Chemical Company Process for producing ethylene/olefin interpolymers
US6417298B1 (en) 1999-06-07 2002-07-09 Eastman Chemical Company Process for producing ethylene/olefin interpolymers
US6815062B2 (en) 1999-06-21 2004-11-09 Pirelli Cavi E Sistemi S.P.A. Cable, in particular for electric energy transportation or distribution, and an insulating composition used therein
EP1063871A1 (en) * 1999-06-24 2000-12-27 European Community Divertorfiltering element for a tokamak nuclear fusion reactor, divertor employing the filtering element and tokamak nuclear fusion reactor employing the divertor
CA2278042C (en) 1999-07-19 2008-12-16 Nova Chemicals Corporation Mixed phosphinimine catalyst
IT1313599B1 (it) * 1999-08-05 2002-09-09 Enichem Spa Complessi metallici utilizzabili nella catalisi per la (co)polimerizzazione delle alfa-olefine
US6331597B1 (en) 1999-08-09 2001-12-18 The Dow Chemical Company Azidosilane-modified, moisture-curable polyolefin polymers, process for making, and articles obtained therefrom
US6524702B1 (en) 1999-08-12 2003-02-25 Dow Global Technologies Inc. Electrical devices having polymeric members
US6362270B1 (en) 1999-08-12 2002-03-26 The Dow Chemical Company Thermoplastic compositions for durable goods applications
WO2001012716A2 (en) 1999-08-17 2001-02-22 The Dow Chemical Company Free-flowing polymer composition
US6369176B1 (en) 1999-08-19 2002-04-09 Dupont Dow Elastomers Llc Process for preparing in a single reactor polymer blends having a broad molecular weight distribution
AR025300A1 (es) 1999-08-23 2002-11-20 Kimberly Clark Co Un articulo absorbente descartable con capacidad para respirar en humedo incrementada.
AR027842A1 (es) 1999-08-23 2003-04-16 Kimberly Clark Co Un articulo absorbente el cual mantiene o mejora la salud de la piel
US6187879B1 (en) 1999-08-31 2001-02-13 Eastman Chemical Company Process for producing polyolefins
JP2003522221A (ja) 1999-08-31 2003-07-22 イーストマン ケミカル カンパニー ポリオレフィンの製造方法
US6239062B1 (en) 1999-09-02 2001-05-29 Equistar Chemicals, L.P. Olefin polymerization catalysts containing indolyl-amido ligands
US6265504B1 (en) 1999-09-22 2001-07-24 Equistar Chemicals, Lp Preparation of ultra-high-molecular-weight polyethylene
CA2285723C (en) 1999-10-07 2009-09-15 Nova Chemicals Corporation Multimodal polyolefin pipe
US6475946B1 (en) 1999-10-22 2002-11-05 Exxonmobil Chemical Patents Inc. Olefin polymerization catalysis with aryl substituted carbenium cationic complexes
US6476164B1 (en) 1999-10-22 2002-11-05 Exxonmobil Chemical Patents Inc. Carbenium cationic complexes suitable for polymerization catalysts
US6794024B1 (en) 1999-11-01 2004-09-21 Kimberly-Clark Worldwide, Inc. Styrenic block copolymer breathable elastomeric films
US6479154B1 (en) 1999-11-01 2002-11-12 Kimberly-Clark Worldwide, Inc. Coextruded, elastomeric breathable films, process for making same and articles made therefrom
US6559090B1 (en) 1999-11-01 2003-05-06 W. R. Grace & Co.-Conn. Metallocene and constrained geometry catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation
US6399535B1 (en) 1999-11-01 2002-06-04 W. R. Grace & Co.-Conn. Coordination catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation
US6822057B2 (en) 1999-12-09 2004-11-23 Exxon Mobil Chemical Patents Inc. Olefin polymerization catalysts derived from Group-15 cationic compounds and processes using them
US6489480B2 (en) 1999-12-09 2002-12-03 Exxonmobil Chemical Patents Inc. Group-15 cationic compounds for olefin polymerization catalysts
US6281306B1 (en) 1999-12-16 2001-08-28 Univation Technologies, Llc Method of polymerization
CA2393327A1 (en) 1999-12-20 2001-06-28 Exxon Chemical Patents Inc. Processes for the preparation polyolefin resins using supported ionic catalysts
US6417276B2 (en) 2000-01-07 2002-07-09 The Dow Chemical Company Thermoformable ethylene/styrene interpolymer-based polymer blend film for three-dimensional transfer finish foil
US20020013224A1 (en) * 2000-02-08 2002-01-31 Diamond Gary M. Catalysts, metal complexes, compositions and arrays containing erbium
US6239239B1 (en) 2000-02-17 2001-05-29 Equistar Chemicals, L.P. Quinolinoxy and pyridinoxy single-site catalysts containing benzyl ligands
US7056996B2 (en) * 2000-02-18 2006-06-06 E. I. Du Pont De Nemours And Company Productivity catalysts and microstructure control
US20040127658A1 (en) * 2000-02-18 2004-07-01 Eastman Chemical Company Productivity catalysts and microstructure control
US6605677B2 (en) 2000-02-18 2003-08-12 Eastman Chemical Company Olefin polymerization processes using supported catalysts
US6579823B2 (en) * 2000-02-18 2003-06-17 Eastman Chemical Company Catalysts containing per-ortho aryl substituted aryl or heteroaryl substituted nitrogen donors
US6255415B1 (en) 2000-02-29 2001-07-03 Equistar Chemicals, L.P. Ethylene polymerization process
US6160029A (en) * 2000-03-08 2000-12-12 The Dow Chemical Company Olefin polymer and α-olefin/vinyl or α-olefin/vinylidene interpolymer blend foams
US6649671B2 (en) 2000-03-13 2003-11-18 Dow Global Technologies Inc. Concrete and process to make same
US6809209B2 (en) 2000-04-07 2004-10-26 Exxonmobil Chemical Patents Inc. Nitrogen-containing group-13 anionic compounds for olefin polymerization
US6455638B2 (en) 2000-05-11 2002-09-24 Dupont Dow Elastomers L.L.C. Ethylene/α-olefin polymer blends comprising components with differing ethylene contents
CA2311068C (en) 2000-06-08 2010-03-09 Nova Chemicals Corporation Process to prepare ethylene propylene elastomer
US7078164B1 (en) 2000-06-19 2006-07-18 Symyx Technologies, Inc. High throughput screen for identifying polymerization catalysts from potential catalysts
US6767931B2 (en) 2000-07-20 2004-07-27 Dow Global Technologies Inc. Foam compositions from blend of alkenyl aromatic polymers and alpha-olefin/vinyl or vinylidene aromatic interpolymers
AU2002224547A1 (en) * 2000-07-20 2002-02-05 The Dow Chemical Company Expanded anionic compounds comprising hydroxyl or quiescent reactive functionality and catalyst activators therefrom
NO20013880L (no) 2000-08-22 2002-02-25 Rohm & Haas Matriks og fremgangsmåte for fremstilling av polyolefiner
US6559230B2 (en) 2000-09-29 2003-05-06 Dupont Dow Elastomers L.L.C. Thermosetting ethylene/alpha-olefin composition and safety glass interlayer film made from the composition
US7390861B2 (en) * 2000-10-19 2008-06-24 Exxonmobil Chemical Patents Inc. Cationic group-3 catalyst system
US6943133B2 (en) * 2000-10-20 2005-09-13 Univation Technologies, Llc Diene functionalized catalyst supports and supported catalyst compositions
CA2424887A1 (en) 2000-10-25 2002-08-01 Exxonmobil Chemical Patents Inc. Cationic catalyst system
US6914018B1 (en) 2000-10-27 2005-07-05 Kimberly-Clark Worldwide, Inc. Biaxial stretch, breathable laminate with cloth-like aesthetics and method for making same
US7074736B2 (en) * 2000-10-31 2006-07-11 Rohm And Haas Company Hydrozirconated matrix and process for polyolefin production
US6706891B2 (en) 2000-11-06 2004-03-16 Eastman Chemical Company Process for the preparation of ligands for olefin polymerization catalysts
US6727361B2 (en) * 2000-11-07 2004-04-27 Symyx Technologies, Inc. Phosphino substituted pyridine amine ligands
US6582810B2 (en) 2000-12-22 2003-06-24 Kimberly-Clark Worldwide, Inc. One-step method of producing an elastic, breathable film structure
US6623837B2 (en) 2000-12-27 2003-09-23 Kimberly-Clark Worldwide, Inc. Biaxially extendible material
US6590034B2 (en) 2001-01-02 2003-07-08 Dow Global Technologies Inc. Peelable seal and method of making and using same
US6592967B2 (en) 2001-02-14 2003-07-15 Avery Dennison Corporation Microprism reflective sheeting with improved retention of reflectivity
WO2002068529A2 (en) * 2001-02-27 2002-09-06 Dow Global Technologies Inc. Fabricated articles prepared from blends of substantially random ethylene/propylene/vinyl aromatic interpolymers with polypropylene
MY131000A (en) * 2001-03-16 2007-07-31 Dow Global Technologies Inc High melt strength polymers and method of making same
WO2002077045A2 (en) * 2001-03-27 2002-10-03 Union Carbide Chemicals & Plastics Technology Corporation Gas phase process for polymers with group 4 metal complex catalyst addition
ATE485319T1 (de) 2001-04-12 2010-11-15 Exxonmobil Chem Patents Inc Verfahren zur polymerisation von propylen und ethylen in lösung
US6391988B1 (en) 2001-04-18 2002-05-21 Equistar Chemicals L.P. Tris(pyrazoyl) based anions
EP1401887A1 (en) 2001-04-30 2004-03-31 W.R. Grace & Co.-Conn. Heterogeneous chromium catalysts and processes of polymerization of olefins using same
WO2002088200A1 (en) 2001-04-30 2002-11-07 W.R. Grace & Co.-Conn. Supported dual transition metal catalyst systems
US6943224B2 (en) 2001-04-30 2005-09-13 W. R. Grace & Co.-Conn. Process for preparing supported transition metal catalyst systems and catalyst systems prepared thereby
US6927261B2 (en) 2001-04-30 2005-08-09 W. R. Grace & Co.-Conn. Method of making supported transition metal polymerization catalysts and compositions formed therefrom
WO2002102859A2 (en) 2001-04-30 2002-12-27 W. R. Grace & Co.-Conn. Coordination catalyst systems employing chromium support-agglomerate and method of their preparation
EP1401879A1 (en) * 2001-05-04 2004-03-31 Dow Global Technologies Inc. Random or block co-or terpolymers produced by using of metal complex catalysts
CA2347410C (en) 2001-05-11 2009-09-08 Nova Chemicals Corporation Solution polymerization process catalyzed by a phosphinimine catalyst
JP2005504853A (ja) * 2001-06-15 2005-02-17 ダウ グローバル テクノロジーズ インコーポレイティド アルファ−オレフィンをベースとした枝分れポリマー
US7511104B2 (en) 2001-06-20 2009-03-31 Exxonmobil Chemical Patents Inc. Polyolefins made by catalyst comprising a noncoordinating anion and articles comprising them
ATE328223T1 (de) * 2001-06-21 2006-06-15 Habasit Ag Monolithischer riemen mit ethylen-alpha olefin- copolymeren
US7220801B2 (en) * 2001-06-22 2007-05-22 Exxonmobil Chemical Patents Inc. Metallocene-produced very low density polyethylenes or linear low density polyethylenes as impact modifiers
US6544918B1 (en) 2001-07-17 2003-04-08 Equistar Chemicals, Lp Olefin polymerization catalysts containing chelating dianionic ligands
WO2003008459A1 (en) * 2001-07-20 2003-01-30 University Of Maryland, College Park Method for production of multimodal polyolefins of tunable composition, molecular weight, and polydispersity
US6727329B2 (en) 2001-07-23 2004-04-27 Dow Global Technology Inc. Salts of lewis acid/acid adducts and catalyst activators therefrom
JP2004535319A (ja) 2001-07-25 2004-11-25 ピレリ・プネウマティチ・ソチエタ・ペル・アツィオーニ エラストマー性組成物を連続的に製造するための方法および装置
US7019157B2 (en) * 2001-08-06 2006-03-28 Chisso Corporation Metallocene compounds, production process for olefin polymers using catalysts containing them and olefin polymers produced by the production process
WO2003013806A1 (en) 2001-08-10 2003-02-20 Dow Global Technologies Inc. Wood treatment composition and method of use
WO2003020821A1 (en) * 2001-08-31 2003-03-13 Dow Global Technologies Inc. Multimodal polyethylene material
MY139205A (en) * 2001-08-31 2009-08-28 Pennzoil Quaker State Co Synthesis of poly-alpha olefin and use thereof
JP2003085910A (ja) * 2001-09-11 2003-03-20 Sony Corp ディスクカートリッジ、ディスク記録媒体装置及びディスク記録再生装置
EP1436332A2 (en) * 2001-10-12 2004-07-14 Dow Global Technologies Inc. Metal complex compositions and their use as catalysts to produce polydienes
US7196148B2 (en) * 2001-10-25 2007-03-27 Exxon Mobil Chemical Patents Inc. Cationic catalyst system
WO2003040201A1 (en) 2001-11-06 2003-05-15 Dow Global Technologies Inc. Isotactic propylene copolymers, their preparation and use
US6960635B2 (en) * 2001-11-06 2005-11-01 Dow Global Technologies Inc. Isotactic propylene copolymers, their preparation and use
US6927256B2 (en) 2001-11-06 2005-08-09 Dow Global Technologies Inc. Crystallization of polypropylene using a semi-crystalline, branched or coupled nucleating agent
US6906160B2 (en) 2001-11-06 2005-06-14 Dow Global Technologies Inc. Isotactic propylene copolymer fibers, their preparation and use
US6943215B2 (en) * 2001-11-06 2005-09-13 Dow Global Technologies Inc. Impact resistant polymer blends of crystalline polypropylene and partially crystalline, low molecular weight impact modifiers
US7122689B2 (en) 2001-11-06 2006-10-17 Symyx Technologies, Inc. Titanium substituted pyridyl amine complexes, catalysts and processes for polymerizing ethylene and stryene
US7964128B2 (en) 2001-12-19 2011-06-21 Pirelli Pneumatici S.P.A. Process and apparatus for continuously producing an elastomeric composition
US20030118814A1 (en) * 2001-12-20 2003-06-26 Workman Jerome James Absorbent structures having low melting fibers
US6846448B2 (en) 2001-12-20 2005-01-25 Kimberly-Clark Worldwide, Inc. Method and apparatus for making on-line stabilized absorbent materials
US6596826B1 (en) 2001-12-20 2003-07-22 Equistar Chemicals, Lp Olefin polymerization catalysts containing 1,3-diboretanyl ligands
US20030119406A1 (en) 2001-12-20 2003-06-26 Abuto Francis Paul Targeted on-line stabilized absorbent structures
US6635728B2 (en) 2002-01-10 2003-10-21 Equistar Chemicals, Lp Preparation of ultra-high-molecular-weight polyethylene
EP1470168A1 (en) * 2002-01-22 2004-10-27 Dow Global Technologies Inc. Vinylaromatic polymers having high melt flow
US6780807B2 (en) 2002-02-04 2004-08-24 Equistar Chemicals L.P. Acyclic anionic six-electron-donor ancillary ligands
US20040106739A1 (en) * 2002-02-19 2004-06-03 Cheung Yunwa Wilson Blends of substantially random interpolymers with enhanced thermal performance
ES2281630T3 (es) * 2002-03-11 2007-10-01 Dow Global Technologies Inc. Fibras elasticas fijadas por calor, reversibles y metodo para obtenerlas y articulos obtenidos a partir de ellas.
TWI294939B (en) * 2002-03-11 2008-03-21 Dow Global Technologies Inc Stretch fabrics with improved chemical resistance and durability
EP1860214B1 (en) 2002-03-11 2009-04-29 Dow Global Technologies Inc. Reversible, heat-set, elastic fibers, and method of making and articles made from same
US6825296B2 (en) * 2002-03-29 2004-11-30 The University Of Hong Kong Catalyst component for olefin polymerization
US6794514B2 (en) 2002-04-12 2004-09-21 Symyx Technologies, Inc. Ethylene-styrene copolymers and phenol-triazole type complexes, catalysts, and processes for polymerizing
US7094723B2 (en) * 2002-04-18 2006-08-22 Equistar Chemicals Lp Catalysts containing at least one heterocyclic ligand for improving the catalysts' performance of olefin polymerization
US7060848B2 (en) * 2002-04-24 2006-06-13 Symyx Technologies, Inc. Bridged bi-aromatic catalysts, complexes, and methods of using the same
US7091292B2 (en) 2002-04-24 2006-08-15 Symyx Technologies, Inc. Bridged bi-aromatic catalysts, complexes, and methods of using the same
DE60335459D1 (de) * 2002-04-24 2011-02-03 Symyx Solutions Inc Verbrückte bi-aromatische liganden, komplexe, katalysatoren, verfahren zur polymerisierung und entstehende polymere
CN100575405C (zh) * 2002-06-04 2009-12-30 联合碳化化学及塑料技术有限责任公司 聚合物组合物和由其制作管子的方法
US6762255B2 (en) 2002-06-06 2004-07-13 Equistar Chemicals L.P. Prealkylated olefin polymerization catalysts and olefin polymerization employing such catalysts
BR0212387B1 (pt) 2002-07-11 2011-11-29 processo e aparelho para produzir continuamente uma composição elastomérica.
US6559251B1 (en) 2002-08-02 2003-05-06 Equistar Chemicals, Lp Process for making low-density polyolefins
US6995279B2 (en) * 2002-08-02 2006-02-07 Chisso Corporation Metallocene compounds, processes for the production of olefin polymers using catalysts containing the compounds, and olefin polymers produced by the processes
US6677038B1 (en) 2002-08-30 2004-01-13 Kimberly-Clark Worldwide, Inc. 3-dimensional fiber and a web made therefrom
US6881375B2 (en) * 2002-08-30 2005-04-19 Kimberly-Clark Worldwide, Inc. Method of forming a 3-dimensional fiber into a web
US6896843B2 (en) * 2002-08-30 2005-05-24 Kimberly-Clark Worldwide, Inc. Method of making a web which is extensible in at least one direction
US6846884B2 (en) * 2002-09-27 2005-01-25 Union Carbide Chemicals & Plastics Technology Corporation Control of resin properties
US7943700B2 (en) * 2002-10-01 2011-05-17 Exxonmobil Chemical Patents Inc. Enhanced ESCR of HDPE resins
ES2399364T3 (es) 2002-10-02 2013-03-27 Dow Global Technologies Llc Composiciones poliméricas que comprenden un extendedor de etileno/alfa-olefina homogéneamente ramificado, de baja viscosidad
DE60304595T3 (de) 2002-10-02 2012-01-12 Dow Global Technologies Inc. Flüssige und gelartige niedermolekulare ethylenpolymere
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
WO2004046214A2 (en) 2002-10-15 2004-06-03 Exxonmobil Chemical Patents Inc. Multiple catalyst system for olefin polymerization and polymers produced therefrom
US6884749B2 (en) 2002-10-17 2005-04-26 Equistar Chemicals L.P. Supported catalysts which reduce sheeting in olefin polymerization, process for the preparation and the use thereof
DE60322410D1 (de) * 2002-10-17 2008-09-04 Dow Global Technologies Inc Hochgefüllte polymerzusammensetzungen
US8034440B2 (en) * 2002-10-31 2011-10-11 Kimberly-Clark Worldwide, Inc. Elastomeric film and laminates thereof
US7579407B2 (en) * 2002-11-05 2009-08-25 Dow Global Technologies Inc. Thermoplastic elastomer compositions
US7459500B2 (en) 2002-11-05 2008-12-02 Dow Global Technologies Inc. Thermoplastic elastomer compositions
CA2411183C (en) * 2002-11-05 2011-06-14 Nova Chemicals Corporation Heterogeneous/homogeneous copolymer
US20040096626A1 (en) * 2002-11-14 2004-05-20 Epoli-Espumas De Polietileno Sa Layered structures with enhanced properties
US6989125B2 (en) * 2002-11-21 2006-01-24 Kimberly-Clark Worldwide, Inc. Process of making a nonwoven web
US20040102123A1 (en) * 2002-11-21 2004-05-27 Bowen Uyles Woodrow High strength uniformity nonwoven laminate and process therefor
US20040102125A1 (en) * 2002-11-27 2004-05-27 Morman Michael Tod Extensible laminate of nonwoven and elastomeric materials and process for making the same
ATE472562T1 (de) 2002-12-13 2010-07-15 Dow Global Technologies Inc Olefinpolymerisationskatalysatorzusammensetzung gruppe 13-amid derivate enthaltend
US6716936B1 (en) 2002-12-16 2004-04-06 Equistar Chemicals L.P. Cascaded boiling pool slurry reactors for producing bimodal low to medium density polyethylene polymers
US7320948B2 (en) 2002-12-20 2008-01-22 Kimberly-Clark Worldwide, Inc. Extensible laminate having improved stretch properties and method for making same
US20040131836A1 (en) * 2003-01-02 2004-07-08 3M Innovative Properties Company Acoustic web
US7320739B2 (en) 2003-01-02 2008-01-22 3M Innovative Properties Company Sound absorptive multilayer composite
CA2454507A1 (en) * 2003-01-08 2004-07-08 Dow Global Technologies Inc. Unitary attic rafter vent and insulation dam assembly
WO2004076504A2 (en) * 2003-02-21 2004-09-10 Dow Global Technologies, Inc. Process for homo- or copolymerization of conjugated olefines
US6693155B1 (en) 2003-03-05 2004-02-17 Equistar Chemicals, Lp Propylene polymerization process
EP1611169B1 (en) 2003-03-21 2010-06-02 Dow Global Technologies Inc. Morphology controlled olefin polymerization process
FI20030610A0 (fi) * 2003-04-22 2003-04-22 Raisio Benecol Oy Syötävä tuote
JP4090389B2 (ja) * 2003-06-10 2008-05-28 株式会社日立製作所 核磁気共鳴装置
JP5086637B2 (ja) * 2003-07-09 2012-11-28 ランクセス エラストマーズ ビー．ブイ． エチレン、α−オレフィン、およびビニルノルボルネンのモノマー単位を含むポリマーの製造方法
CA2435986C (en) * 2003-07-24 2011-08-30 Nova Chemicals Corporation Rotomolding process with reduced cycle times
US6818713B1 (en) 2003-08-11 2004-11-16 Equistar Chemicals, Lp Process for making polyethylene
JP2007502352A (ja) 2003-08-13 2007-02-08 ダウ グローバル テクノロジーズ インコーポレイティド 装置、取付具、デバイス、構造物及び器具への配管システム及び配管の接合方法
TR200600545T2 (tr) * 2003-08-13 2006-08-21 Dow Global Technologies Inc. Alt tabakaların ve nesnelerin birleştirilmesi için usul
CN1852959B (zh) 2003-08-19 2010-06-16 陶氏环球技术公司 适用于热熔粘合剂的共聚体及其制备方法
US7932196B2 (en) 2003-08-22 2011-04-26 Kimberly-Clark Worldwide, Inc. Microporous stretch thinned film/nonwoven laminates and limited use or disposable product applications
US7270723B2 (en) 2003-11-07 2007-09-18 Kimberly-Clark Worldwide, Inc. Microporous breathable elastic film laminates, methods of making same, and limited use or disposable product applications
US7220478B2 (en) 2003-08-22 2007-05-22 Kimberly-Clark Worldwide, Inc. Microporous breathable elastic films, methods of making same, and limited use or disposable product applications
US6939930B2 (en) * 2003-09-09 2005-09-06 Equistar Chemicals, Lp Hydrosilane additives for increased polyolefin molecular weight
US7422786B2 (en) * 2003-09-24 2008-09-09 Exxonmobil Chemical Patents Inc. Collation shrink
US7326751B2 (en) * 2003-12-01 2008-02-05 Kimberly-Clark Worlwide, Inc. Method of thermally processing elastomeric compositions and elastomeric compositions with improved processability
US20050118435A1 (en) * 2003-12-01 2005-06-02 Kimberly-Clark Worldwide, Inc. Films and methods of forming films having polyorganosiloxane enriched surface layers
US7662745B2 (en) 2003-12-18 2010-02-16 Kimberly-Clark Corporation Stretchable absorbent composites having high permeability
GB0329348D0 (en) * 2003-12-18 2004-01-21 Bp Chem Int Ltd Polymerisation process
US7985811B2 (en) * 2004-01-02 2011-07-26 Univation Technologies, Llc Method for controlling sheeting in gas phase reactors
US20050148742A1 (en) * 2004-01-02 2005-07-07 Hagerty Robert O. Method for controlling sheeting in gas phase reactors
US20070073012A1 (en) * 2005-09-28 2007-03-29 Pannell Richard B Method for seed bed treatment before a polymerization reaction
US6982305B2 (en) * 2004-01-26 2006-01-03 Equistar Chemicals, Lp Olefin polymerization in the presence of a dehydrogenation catalyst
DE602005017243D1 (de) 2004-01-28 2009-12-03 Idemitsu Kosan Co Inpolymerisierung
JP4831488B2 (ja) * 2004-03-04 2011-12-07 独立行政法人理化学研究所 アイソタクチック３，４−イソプレン系重合体
TW200604224A (en) 2004-03-17 2006-02-01 Dow Global Technologies Inc Catalyst composition comprising shuttling agent for ethylene copolymer formation
ES2397701T3 (es) 2004-03-17 2013-03-08 Dow Global Technologies Llc Composición de catalizador que comprende un agente de transporte para la formación de un copolímero de multi-bloques de olefina superior
AU2005224258B2 (en) 2004-03-17 2010-09-02 Dow Global Technologies Inc. Catalyst composition comprising shuttling agent for ethylene copolymer formation
AU2005224261B2 (en) * 2004-03-19 2010-04-01 Dow Global Technologies, Inc. Film layers made from polymer formulations
WO2005100414A1 (en) * 2004-04-07 2005-10-27 Union Carbide Chemicals & Plastics Technology Corporation Method of controlling olefin polymerization
US6995220B2 (en) 2004-04-29 2006-02-07 Equistar Chemicals, Lp Ethylene polymerization process
GB0411742D0 (en) 2004-05-26 2004-06-30 Exxonmobil Chem Patents Inc Transition metal compounds for olefin polymerization and oligomerization
US7309741B2 (en) * 2004-06-01 2007-12-18 Nova Chemicals (International) S.A. Polyolefin blends and pipe
ATE504349T1 (de) 2004-06-16 2011-04-15 Dow Global Technologies Inc Verfahren zur auswahl von polymerisationsmodifikatoren
EP1763565B1 (en) * 2004-06-28 2010-05-12 Dow Global Technologies Inc. Adhesion promoters for multistrucural laminates
US7938813B2 (en) 2004-06-30 2011-05-10 Kimberly-Clark Worldwide, Inc. Absorbent article having shaped absorbent core formed on a substrate
US20060003154A1 (en) * 2004-06-30 2006-01-05 Snowden Hue S Extruded thermoplastic articles with enhanced surface segregation of internal melt additive
US7772456B2 (en) 2004-06-30 2010-08-10 Kimberly-Clark Worldwide, Inc. Stretchable absorbent composite with low superaborbent shake-out
US7247215B2 (en) 2004-06-30 2007-07-24 Kimberly-Clark Worldwide, Inc. Method of making absorbent articles having shaped absorbent cores on a substrate
US7285595B2 (en) * 2004-06-30 2007-10-23 Kimberly-Clark Worldwide, Inc. Synergistic fluorochemical treatment blend
US20080051537A1 (en) * 2004-08-09 2008-02-28 Carnahan Edmund M Supported Bis(Hydroxylarylaryloxy) Catalysts For Manufacture Of Polymers
DE102004039911A1 (de) * 2004-08-18 2006-02-23 Goldschmidt Gmbh Katalytisches System für die dehydrogenative Kondensation von Polyorganosiloxanen mit Alkoholen und ein Verfahren zur Herstellung von organisch modifizierten Polyorganosiloxanen
US20060041071A1 (en) * 2004-08-19 2006-02-23 Sandstrom Paul H Pneumatic tire having a rubber component containing polyethylene terpolymer
US7183005B2 (en) * 2004-08-20 2007-02-27 Exxonmobil Chemical Patents Inc. Impact strength improvement of regrind
WO2006036748A2 (en) * 2004-09-22 2006-04-06 Symyx Technologies, Inc. Heterocycle-amine ligands, compositions, complexes, and catalysts, and methods of making and using the same
US7256296B2 (en) * 2004-09-22 2007-08-14 Symyx Technologies, Inc. Heterocycle-amine ligands, compositions, complexes, and catalysts
US7402546B2 (en) * 2004-09-23 2008-07-22 Equistar Chemicals, Lp Magnesium chloride support
US7500541B2 (en) * 2004-09-30 2009-03-10 Kimberly-Clark Worldwide, Inc. Acoustic material with liquid repellency
GB0423685D0 (en) * 2004-10-26 2004-11-24 Dow Corning Ireland Ltd Improved method for coating a substrate
EP1805229A1 (en) 2004-10-28 2007-07-11 Dow Gloval Technologies Inc. Method of controlling a polymerization reactor
BRPI0516675A (pt) * 2004-11-05 2008-09-16 Dow Global Technologies Inc composto de ferrocênio substituìdo, processo para a polimerização por adição de um ou mais monÈmeros olefìnicos e processo para a sìntese de um composto organometálico de grupo 3-10
US7705157B2 (en) * 2004-12-16 2010-04-27 Symyx Solutions, Inc. Phenol-heterocyclic ligands, metal complexes, and their uses as catalysts
US7651653B2 (en) 2004-12-22 2010-01-26 Kimberly-Clark Worldwide, Inc. Machine and cross-machine direction elastic materials and methods of making same
CN101142246B (zh) 2005-03-17 2011-05-25 陶氏环球技术公司 用于形成有规立构/无规立构多嵌段共聚物的包含梭移剂的催化剂组合物
AU2006227976A1 (en) 2005-03-17 2006-09-28 Dow Global Technologies Inc. Catalyst composition comprising shuttling agent for regio-irregular multi-block copolymer formation
US9410009B2 (en) 2005-03-17 2016-08-09 Dow Global Technologies Llc Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation
US20060251858A1 (en) * 2005-05-06 2006-11-09 Kimberly-Clark Worldwide, Inc. Elastic, breathable barrier films and laminates
EP1731536A1 (en) 2005-06-09 2006-12-13 Innovene Manufacturing France SAS Supported polymerisation catalysts
MY148274A (en) * 2005-07-08 2013-03-29 Dow Global Technologies Inc Layered film compositions, packages prepared therefrom, and methods of use
KR100789241B1 (ko) * 2005-07-08 2008-01-02 주식회사 엘지화학 전이금속 화합물, 이를 포함하는 촉매 조성물 및 이를이용한 올레핀 중합
KR100789242B1 (ko) * 2005-07-08 2008-01-02 주식회사 엘지화학 전이금속 화합물, 이를 포함하는 촉매 조성물 및 이를이용한 올레핀 중합
ES2398109T3 (es) 2005-07-11 2013-03-13 Dow Global Technologies Llc Composiciones que comprenden polímeros de olefinas injertados con silano y artículos fabricados a partir de las mismas
US7273914B2 (en) * 2005-08-03 2007-09-25 Equistar Chemicals, Lp Olefin polymerization methods
KR101141359B1 (ko) * 2005-09-09 2012-05-03 에스케이이노베이션 주식회사 에틸렌 단독중합체 또는 α-올레핀과의 공중합체 제조용균일 촉매계
EP1934266B1 (en) * 2005-09-09 2015-11-18 SABIC SK Nexlene Company Pte. Ltd. Homogeneous catalyst system for producing ethylene homopolymer or ethylene copolymers with alpha-olefins
AR058449A1 (es) 2005-09-15 2008-02-06 Dow Global Technologies Inc Copolimeros de bloque de olefina cataliticos via un agente de transferencia polimerizable
BRPI0617041B1 (pt) 2005-09-15 2018-01-30 Dow Global Technologies Inc. PROCESSO PARA PREPARAR UM POLÍMERO DIFUNCIONAL EM a, ?"
US8153243B2 (en) 2005-12-09 2012-04-10 Dow Global Technologies Llc Interpolymers suitable for multilayer films
EP1963347B1 (en) 2005-12-14 2011-10-19 ExxonMobil Chemical Patents Inc. Halogen substituted metallocene compounds for olefin polymerization
US20070141352A1 (en) 2005-12-15 2007-06-21 Calhoun Patricia H Cross-directional elastic films with machine direction stiffness
BRPI0620665A2 (pt) 2005-12-16 2011-11-22 Dow Global Technologies Inc complexo metálico, composição, método para formar um produto oligomérico ou polimérico e polìmero
US7608327B2 (en) * 2005-12-20 2009-10-27 Equistar Chemicals, Lp High tear strength film
US7678933B2 (en) * 2005-12-30 2010-03-16 Lg Chem, Ltd. Transition metal complexes and preparation methods thereof
EP1803747A1 (en) 2005-12-30 2007-07-04 Borealis Technology Oy Surface-modified polymerization catalysts for the preparation of low-gel polyolefin films
KR100874032B1 (ko) 2006-02-01 2008-12-17 주식회사 엘지화학 전이 금속 화합물을 포함하는 촉매 조성물 및 이를 이용한올레핀 중합
KR100820542B1 (ko) * 2006-03-24 2008-04-08 주식회사 엘지화학 전이금속 화합물, 이를 포함하는 촉매 조성물 및 이를이용한 올레핀 중합
WO2007130277A1 (en) * 2006-05-05 2007-11-15 Exxonmobil Chemical Patents Inc. Linear low density polymer blends and articles made therefrom
US8101696B2 (en) * 2006-05-17 2012-01-24 Dow Global Technologies Llc Polyolefin solution polymerization process and polymer
GB0610667D0 (en) 2006-05-30 2006-07-05 Nova Chem Int Sa Supported polymerization catalysts
CN109320664A (zh) 2006-06-15 2019-02-12 陶氏环球技术有限责任公司 官能化烯烃共聚体、组合物和由其制成的制品及其制法
US7601255B2 (en) 2006-09-06 2009-10-13 Chemtura Corporation Process for removal of residual catalyst components
EP2067079B1 (en) 2006-09-21 2020-03-18 Union Carbide Chemicals & Plastics Technology LLC Method of controlling properties in multimodal systems
US8198373B2 (en) * 2006-10-02 2012-06-12 Exxonmobil Chemical Patents Inc. Plastic toughened plastics
US8207265B2 (en) * 2006-10-30 2012-06-26 Dow Global Technologies Llc Adhesives films
US7985804B2 (en) * 2006-11-06 2011-07-26 Exxonmobil Chemical Patents Inc. Rubber toughened compositions, articles, films, and methods of making the same
AU2007323916B2 (en) 2006-11-13 2012-12-06 Shaw Industries Group, Inc. Methods and systems for recycling carpet and carpets manufactured from recycled material
KR100852234B1 (ko) * 2006-11-17 2008-08-13 삼성전자주식회사 금속 산화막의 형성 방법, 이를 이용한 게이트 구조물의제조 방법 및 커패시터의 제조 방법
KR100976131B1 (ko) 2007-01-10 2010-08-16 주식회사 엘지화학 전이금속 화합물의 제조 방법, 상기 방법으로 제조된전이금속 화합물 및 상기 전이금속 화합물을 포함하는 촉매조성물
US7399809B1 (en) 2007-01-11 2008-07-15 Equistar Chemicals, Lp Modifying polyethylene made by Ziegler or single-site catalyst with free radical initiator
EP2126934B1 (en) * 2007-03-15 2015-09-23 Union Carbide Chemicals & Plastics Technology LLC Cable insulation with reduded electrical treeing
CA2625385A1 (en) * 2007-04-04 2008-10-04 Nova Chemicals Corporation Produce packaging
ITMI20070878A1 (it) 2007-05-02 2008-11-03 Dow Global Technologies Inc Processo per la polimerizzazine di polimeri tattici con l'uso di catalizzatori chirali
US8281332B2 (en) * 2007-05-02 2012-10-02 Google Inc. Animated video overlays
ITMI20070877A1 (it) 2007-05-02 2008-11-03 Dow Global Technologies Inc Processo per la produzione di copolimeri a blocchi multipli con l'utilizzo di solventi polari
US8163867B2 (en) 2007-05-04 2012-04-24 Sk Innovation Co., Ltd. Process for producing polycarbonates and a coordination complex used therefor
KR100994252B1 (ko) * 2007-05-09 2010-11-12 주식회사 엘지화학 에틸렌 알파-올레핀 공중합체
JP2010533776A (ja) * 2007-07-17 2010-10-28 ダウ グローバル テクノロジーズ インコーポレイティド モノビニリデン芳香族ポリマーおよびエチレン／α−オレフィンコポリマーを含むＥＳＣＲの高い組成物
CA2598960C (en) 2007-08-27 2015-04-07 Nova Chemicals Corporation High temperature process for solution polymerization
CA2598957C (en) 2007-08-27 2014-07-15 Nova Chemicals Corporation Process for high temperature solution polymerization
US8431096B2 (en) 2007-08-27 2013-04-30 Nova Chemicals (International) S.A Process for high temperature solution polymerization
US7981517B2 (en) * 2007-08-28 2011-07-19 Dow Global Technologies Inc. Bituminous compositions and methods of making and using same
JP5437250B2 (ja) * 2007-09-25 2014-03-12 ダウ グローバル テクノロジーズ エルエルシー オレフィン基材間の接着性を調節するためのブレンド成分としてのスチレン性ポリマー
TW200932762A (en) 2007-10-22 2009-08-01 Univation Tech Llc Polyethylene compositions having improved properties
JP5334981B2 (ja) * 2007-11-01 2013-11-06 ダウ グローバル テクノロジーズ エルエルシー シラン官能性樹脂の架橋のための現場での水分発生及び多官能性アルコールの使用
EP2214903A1 (en) * 2007-11-27 2010-08-11 Dow Global Technologies Inc. A multilayer structure for the manufacture of packaging and packaging thereof
WO2009082451A2 (en) 2007-12-18 2009-07-02 Univation Technologies, Llc Method for controlling bimodal catalyst activity during polymerization
WO2009114275A1 (en) * 2008-03-12 2009-09-17 Dow Global Technologies Inc. Clarified polypropylene and ethylene alpha olefin blend
US9234093B2 (en) 2008-03-31 2016-01-12 Exxonmobil Chemical Patents Inc. Thermoplastic vulcanizates
CA2629576C (en) * 2008-04-21 2016-01-05 Nova Chemicals Corporation Closures for bottles
US20090286944A1 (en) * 2008-05-15 2009-11-19 Symyx Technologies, Inc. Select phenol-heterocycle ligands, metal complexes formed therefrom, and their uses as catalysts
CA2726607C (en) * 2008-06-05 2016-10-04 Union Carbide Chemicals & Plastics Technology Llc Method for producing water tree-resistant, trxlpe-type cable sheath
JP2011523968A (ja) * 2008-06-06 2011-08-25 ダウ グローバル テクノロジーズ エルエルシー ポリプロピレンおよびオレフィンインターポリマーの反応処理された高耐熱性組成物
EP2133367A1 (en) 2008-06-09 2009-12-16 INEOS Manufacturing Belgium NV Novel Copolymers
EP2310449B1 (en) 2008-08-05 2016-10-19 Prysmian S.p.A. Flame-retardant electrical cable
EP2172510A1 (en) 2008-10-01 2010-04-07 Dow Global Technologies Inc. Barrier films and method for making and using the same
EP2172490A1 (en) 2008-10-03 2010-04-07 Ineos Europe Limited Controlled polymerisation process
EP2177548A1 (en) 2008-10-14 2010-04-21 Ineos Europe Limited Copolymers and films thereof
JP2012508808A (ja) * 2008-11-12 2012-04-12 ダウ グローバル テクノロジーズ エルエルシー 高充填プロピレン−エチレンコポリマー組成物
US20110209897A1 (en) * 2008-11-21 2011-09-01 David Denton Olefin-Based Polymers, a Process for Making the Same, and a Medium Voltage Cable Sheath Comprising the Same
US20100129924A1 (en) * 2008-11-21 2010-05-27 Sandor Nagy Quality assurance method for olefin polymerization catalysts
KR20110114541A (ko) * 2008-12-23 2011-10-19 다우 글로벌 테크놀로지스 엘엘씨 에틸렌-비닐실란 공중합체의 수분 경화용 촉매계
KR101265891B1 (ko) 2009-01-13 2013-05-20 주식회사 엘지화학 넓은 분자량 분포를 갖는 폴리올레핀 중합 방법
CA2651514C (en) * 2009-01-29 2016-05-03 Nova Chemicals Corporation Stabilized rotomolded parts
EP2411424A2 (en) 2009-03-06 2012-02-01 Dow Global Technologies LLC Catalysts, processes for making catalysts, processes for making polyolefin compositions and polyolefin compositions
EP2440564A4 (en) 2009-06-11 2014-07-09 Grace W R & Co PROCESS FOR PRODUCING ALUMINOXANE AND CATALYSTS COMPRISING ALUMINOXANE THUS PREPARED
WO2010151433A1 (en) 2009-06-26 2010-12-29 Dow Global Technologies Inc. Process selectively polymerizing ethylene and catalyst therefor
MY158186A (en) 2009-07-28 2016-09-15 Univation Tech Llc Polymerization process using a supported constrained geometry catalyst
JP5744868B2 (ja) 2009-07-29 2015-07-08 ダウ グローバル テクノロジーズ エルエルシー 多官能性連鎖シャトリング剤
WO2011016992A2 (en) 2009-07-29 2011-02-10 Dow Global Technologies Inc. Polymeric chain transfer/shuttling agents
ES2651292T3 (es) 2009-07-29 2018-01-25 Dow Global Technologies Llc Agentes de transferencia de cadena de doble o múltiple cabeza y su uso para la preparación de copolímeros de bloque
US8067652B2 (en) 2009-08-13 2011-11-29 Chemtura Corporation Processes for controlling the viscosity of polyalphaolefins
WO2011025784A1 (en) 2009-08-31 2011-03-03 Dow Global Technologies Inc. Catalyst and process for polymerizing an olefin and polyolefin prepared thereby
BR112012006019B1 (pt) 2009-09-16 2021-05-11 Union Carbide Corporation mistura reticulável e artigo moldado sob fusão
KR20120083419A (ko) 2009-09-18 2012-07-25 유니온 카바이드 케미칼즈 앤드 플라스틱스 테크날러지 엘엘씨 가교된 사출 성형품의 제조 방법
CA2688217C (en) * 2009-12-11 2016-07-12 Nova Chemicals Corporation Multi reactor process
EP2357035A1 (en) 2010-01-13 2011-08-17 Ineos Europe Limited Polymer powder storage and/or transport and/or degassing vessels
WO2011087731A1 (en) 2010-01-14 2011-07-21 Exxonmobil Chemical Patents Inc. Processes and apparatus for continuous solution polymerization
CN102762604A (zh) 2010-01-14 2012-10-31 埃克森美孚化学专利公司 连续溶液聚合的方法和设备
WO2011087729A2 (en) 2010-01-14 2011-07-21 Exxonmobil Chemical Patents Inc. Processes and apparatus for polymer finishing and packaging
EP2348057A1 (en) 2010-01-21 2011-07-27 INEOS Manufacturing Belgium NV Novel polymers
WO2011102957A1 (en) 2010-02-16 2011-08-25 Dow Global Technologies Llc Adhesion reduction between a metal conductor and an insulation sheath
KR101827023B1 (ko) 2010-02-19 2018-02-07 다우 글로벌 테크놀로지스 엘엘씨 금속-리간드 착체 및 촉매
WO2011102990A2 (en) 2010-02-19 2011-08-25 Dow Global Technologies Llc Process for polymerizing an olefin monomer and catalyst therefor
US8058461B2 (en) 2010-03-01 2011-11-15 Exxonmobil Chemical Patents Inc. Mono-indenyl transition metal compounds and polymerization therewith
EP2374917B1 (en) 2010-04-07 2013-02-13 Dow Global Technologies LLC Artificial turf yarn
US20110251362A1 (en) 2010-04-09 2011-10-13 Sandor Nagy Olefin polymerization catalysts
TWI523607B (zh) 2010-04-15 2016-03-01 陶氏農業科學公司 使用含有聚二氯乙烯（ｐｖｄｃ）蒸氣障壁之多層薄膜的農用薰蒸技術
EP2383301A1 (en) 2010-04-30 2011-11-02 Ineos Europe Limited Polymerization process
EP2383298A1 (en) 2010-04-30 2011-11-02 Ineos Europe Limited Polymerization process
US8609794B2 (en) 2010-05-17 2013-12-17 Dow Global Technologies, Llc. Process for selectively polymerizing ethylene and catalyst therefor
US8084385B1 (en) 2010-06-09 2011-12-27 Equistar Chemicals, L.P. Catalysts for olefin polymerization
EP2591021A2 (en) 2010-07-06 2013-05-15 Ticona GmbH Ultra-high molecular weight polyethylene, its production and use
US8722819B2 (en) 2010-07-06 2014-05-13 Ticona Gmbh Process for producing high molecular weight polyethylene
KR20130100067A (ko) 2010-07-06 2013-09-09 티코나 게엠베하 고분자량 폴리에틸렌 성형품, 이의 제조 및 용도
JP2013529719A (ja) 2010-07-06 2013-07-22 ティコナ ゲゼルシャフト ミット ベシュレンクテル ハフツング 高分子量ポリエチレンの製造方法
US9212234B2 (en) 2010-07-06 2015-12-15 Ticona Gmbh Process for producing high molecular weight polyethylene
KR20130122905A (ko) 2010-07-06 2013-11-11 티코나 게엠베하 고 분자량 폴리에틸렌 섬유 및 막, 그의 제조 방법 및 용도
KR20130089166A (ko) 2010-07-06 2013-08-09 티코나 게엠베하 고 분자량 폴리에틸렌의 제조 방법
GB201012273D0 (en) 2010-07-22 2010-09-08 Ineos Mfg Belguim Nv Polymer compositon
EP2410011A1 (en) 2010-07-23 2012-01-25 INEOS Manufacturing Belgium NV Polyethylene composition
CA2713042C (en) 2010-08-11 2017-10-24 Nova Chemicals Corporation Method of controlling polymer architecture
WO2012027448A1 (en) 2010-08-25 2012-03-01 Dow Global Technologies Llc Process for polymerizing a polymerizable olefin and catalyst therefor
US8991039B2 (en) 2010-09-30 2015-03-31 Dow Global Technologies Llc Method for manufacturing flexible multilayer electrical articles with improved layer adhesion
WO2012061706A1 (en) 2010-11-04 2012-05-10 Dow Global Technologies Llc Double shuttling of polyolefin polymeryl chains
US8895465B2 (en) 2010-11-22 2014-11-25 Albemarle Corporation Activator compositions, their preparation, and their use in catalysis
JP5667701B2 (ja) 2010-11-24 2015-02-12 エクソンモービル アジア パシフィック リサーチ アンド デベロップメント カンパニー リミテッド フィラー高充填ポリマー組成物
CN103328518B (zh) 2010-11-29 2016-07-06 英力士销售（英国）有限公司 聚合控制方法
CA2724943A1 (en) 2010-12-10 2012-06-10 Nova Chemicals Corporation Catalyst activation in a dual reactor process
EP2465876A1 (en) 2010-12-15 2012-06-20 INEOS Manufacturing Belgium NV Activating supports
JP6457716B2 (ja) 2011-01-14 2019-01-23 ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット 修飾メタロセン触媒の作成法、生成された触媒およびそれらの使用
JP2014508198A (ja) 2011-01-19 2014-04-03 ダウ コーニング コーポレーション シリル官能化ポリオレフィンの製造方法及びシリルモノマーの取り込まれたシリル官能化ポリオレフィン
US9012359B2 (en) 2011-01-20 2015-04-21 Ineos Sales (Uk) Limited Activating supports
KR101262308B1 (ko) * 2011-01-21 2013-05-08 주식회사 엘지화학 올레핀 블록 공중합체 및 이의 제조 방법
CN102153701B (zh) * 2011-01-24 2013-07-10 宁波工程学院 用于降冰片烯与丙烯酸酯、环己烯三元共聚的催化剂及其制备方法以及三元共聚方法
WO2012103080A1 (en) 2011-01-26 2012-08-02 Dow Global Technologies Llc Process for making a polyolefin-polysiloxane block copolymer
US9248630B2 (en) 2011-04-08 2016-02-02 Ineos Europe Ag Laminate comprising a polyolefin layer adhered to a base layer
CA2739969C (en) 2011-05-11 2018-08-21 Nova Chemicals Corporation Improving reactor operability in a gas phase polymerization process
WO2012155022A1 (en) 2011-05-12 2012-11-15 Dow Global Technologies Llc Non-cyclopentadienyl-based chromium catalysts for olefin polymerization
BR112013033155B1 (pt) 2011-06-24 2020-12-22 Ineos Europe Ag Processo de pasta fluida para a polimerização de etileno em um sistema de reator e uso de propano como um diluente e uma concentração de sólidos
US8383740B1 (en) 2011-08-12 2013-02-26 Ineos Usa Llc Horizontal agitator
ITMI20111572A1 (it) 2011-09-01 2013-03-02 R & D Innovaction S R L Composizioni antifiamma e relativo processo di produzione
CA2752407C (en) 2011-09-19 2018-12-04 Nova Chemicals Corporation Polyethylene compositions and closures for bottles
US9371442B2 (en) 2011-09-19 2016-06-21 Nova Chemicals (International) S.A. Polyethylene compositions and closures made from them
EP2768870B1 (en) 2011-10-17 2018-01-10 Ineos Europe AG Polymer degassing process control
US8841379B2 (en) 2011-11-07 2014-09-23 E I Du Pont De Nemours And Company Method to form an aqueous dispersion of an ionomer-polyolefin blend
EP2785786B1 (en) 2011-12-01 2018-05-30 Ineos Europe AG Polymer blends
CA2760264C (en) 2011-12-05 2018-08-21 Nova Chemicals Corporation Passivated supports for use with olefin polymerization catalysts
IN2014CN04332A (ja) 2011-12-14 2015-09-04 Ineos Europe Ag
EP2794687A1 (en) 2011-12-19 2014-10-29 Ticona GmbH Process for producing high molecular weight polyethylene
US9522855B2 (en) 2011-12-29 2016-12-20 Dow Global Technologies Llc Process for producing low molecular weight ethylene- and alpha-olefin-based materials
MX368963B (es) 2011-12-29 2019-10-23 Dow Global Technologies Llc Fluido dielectrico basado en aceite de olefina hiper-ramificado.
CN104205245B (zh) 2012-01-26 2020-06-23 英尼奥斯欧洲股份公司 用于电线和电缆应用的共聚物
US9595365B2 (en) 2012-01-31 2017-03-14 Dow Global Technologies Llc Thermoplastic, semiconductive compositions
BR112014026674B8 (pt) 2012-04-27 2021-10-05 Albemarle Corp Composição de precursor de ativador e processo de formação
CA2777386C (en) 2012-05-17 2020-06-30 Nova Chemicals Corporation Rotomolding resin
PL2671639T3 (pl) 2012-06-04 2017-07-31 Sasol Performance Chemicals Gmbh Kompleksy guanidynianowe i ich zastosowanie jako katalizatorów polimeryzacji z przeniesieniem łańcucha
EP2676903A1 (en) 2012-06-19 2013-12-25 Habasit Italiana S.P.A. Acrylic-free conveyor belt
US9115233B2 (en) 2012-06-21 2015-08-25 Nova Chemicals (International) S.A. Ethylene copolymer compositions, film and polymerization processes
CA2798855C (en) 2012-06-21 2021-01-26 Nova Chemicals Corporation Ethylene copolymers having reverse comonomer incorporation
CA2783494C (en) 2012-07-23 2019-07-30 Nova Chemicals Corporation Adjusting polymer composition
CN104684919A (zh) 2012-07-31 2015-06-03 陶氏环球技术有限责任公司 制备烯烃聚合催化剂活化剂的方法
RU2529020C2 (ru) 2012-10-17 2014-09-27 ЭлДжи КЕМ, ЛТД. Новое металлоценовое соединение, содержащая его каталитическая композиция и способ получения полимеров на основе олефинов с ее применением
JP5959131B2 (ja) 2012-12-11 2016-08-02 エルジー・ケム・リミテッド 新規なリガンド化合物、その製造方法および前記リガンド化合物を含む遷移金属化合物、およびその製造方法
KR20140075589A (ko) 2012-12-11 2014-06-19 주식회사 엘지화학 신규한 리간드 화합물, 이의 제조방법, 전이금속 화합물, 및 이의 제조방법
CA2798854C (en) 2012-12-14 2020-02-18 Nova Chemicals Corporation Polyethylene compositions having high dimensional stability and excellent processability for caps and closures
US9475927B2 (en) 2012-12-14 2016-10-25 Nova Chemicals (International) S.A. Polyethylene compositions having high dimensional stability and excellent processability for caps and closures
US9783663B2 (en) 2012-12-14 2017-10-10 Nova Chemicals (International) S.A. Polyethylene compositions having high dimensional stability and excellent processability for caps and closures
ITMI20122199A1 (it) 2012-12-20 2014-06-21 Versalis Spa Procedimento per la preparazione di (co)polimeri di dieni coniugati in presenza di un sistema catalitico comprendente un complesso bis-imminico di cobalto
ITMI20122206A1 (it) 2012-12-20 2014-06-21 Versalis Spa Procedimento per la preparazione di (co)polimeri di dieni coniugati in presenza di un sistema catalitico comprendente un complesso bis-immino-piridinico di cobalto
ITMI20122203A1 (it) 2012-12-20 2014-06-21 Versalis Spa Procedimento per la preparazione di (co)polimeri di dieni coniugati in presenza di un sistema catalitico comprendente un complesso osso-azotato di cobalto
ITMI20122201A1 (it) 2012-12-20 2014-06-21 Versalis Spa Complesso osso-azotato di cobalto, sistema catalitico comprendente detto complesso osso-azotato e procedimento per la (co)polimerizzazione di dieni coniugati
CA2800056A1 (en) 2012-12-24 2014-06-24 Nova Chemicals Corporation Polyethylene blend compositions
WO2014105412A1 (en) 2012-12-27 2014-07-03 Dow Global Technologies Llc An ethylene based polymer
EP2938644B1 (en) 2012-12-27 2019-08-28 Dow Global Technologies LLC Process for the polymerization of ethylene and octene
KR20150103082A (ko) 2012-12-27 2015-09-09 다우 글로벌 테크놀로지스 엘엘씨 에틸렌계 중합체를 제조하기 위한 중합 방법
US9751998B2 (en) 2012-12-27 2017-09-05 Dow Global Technologies Llc Catalyst systems for olefin polymerization
EP2938648B1 (en) 2012-12-27 2019-01-30 Dow Global Technologies LLC A polymerization process for producing ethylene based polymers
SG10201802443VA (en) 2013-06-28 2018-05-30 Dow Global Technologies Llc Molecular weight control of polyolefins using halogenated bis-phenylphenoxy catalysts
DE102013014918A1 (de) 2013-07-15 2015-01-15 Ewald Dörken Ag Bikomponentenfaser zur Herstellung von Spinnvliesen
DE102013014917A1 (de) 2013-07-15 2015-01-15 Ewald Dörken Ag Bikomponentenfaser zur Herstellung von Spinnvliesen
DE102013014920A1 (de) 2013-07-15 2015-01-15 Ewald Dörken Ag Bikomponentenfaser zur Herstellung von Spinnvliesen
DE102013014919A1 (de) 2013-07-15 2015-01-15 Ewald Dörken Ag Bikomponentenfaser zur Herstellung von Spinnvliesen
KR101623485B1 (ko) 2013-08-01 2016-05-23 주식회사 엘지화학 메탈로센 화합물, 이를 포함하는 촉매 조성물 및 이를 이용하는 올레핀계 중합체의 제조방법
KR101650092B1 (ko) 2013-08-01 2016-08-22 주식회사 엘지화학 메탈로센 화합물, 이를 포함하는 촉매 조성물 및 이를 이용하는 올레핀계 중합체의 제조방법
ITMI20131327A1 (it) 2013-08-02 2015-02-03 R & D Innovaction S R L Granulato a base polietilenica, relativo processo di produzione e suo utilizzo per la produzione di cavi
CA2923072C (en) 2013-09-20 2021-10-26 Dow Global Technologies Llc Process for degassing crosslinked power cables
KR101528102B1 (ko) 2013-09-26 2015-06-10 주식회사 엘지화학 전이금속 화합물, 이를 포함하는 촉매 조성물 및 이를 이용한 중합체의 제조방법
EP2980104B1 (en) 2013-09-26 2020-11-04 LG Chem, Ltd. Catalytic composition and method for preparing polymer including same
US9376519B2 (en) 2013-09-26 2016-06-28 Lg Chem, Ltd. Transition metal compound, catalytic composition including the same, and method for preparing polymer using the same
WO2015046995A1 (ko) 2013-09-30 2015-04-02 주식회사 엘지화학 폴리올레핀
KR101593175B1 (ko) 2013-09-30 2016-02-12 주식회사 엘지화학 폴리프로필렌의 제조방법 및 이로부터 수득되는 폴리프로필렌
KR101657680B1 (ko) 2013-09-30 2016-09-19 주식회사 엘지화학 폴리올레핀
EP3034523B1 (en) 2013-09-30 2021-07-07 LG Chem, Ltd. Method for preparing propylene-1-butene copolymer
WO2015057001A1 (ko) 2013-10-16 2015-04-23 주식회사 엘지화학 헤테로 원자를 갖는 전이금속 화합물, 이를 포함하는 촉매 조성물 및 이를 이용한 중합체의 제조방법
ITMI20131830A1 (it) 2013-11-05 2015-05-06 Versalis Spa Polibutadieni di-blocco stereoregolari a struttura 1,4-cis/1,2 sindiotattica da polimerizzazione stereospecifica
ITMI20131828A1 (it) 2013-11-05 2015-05-06 Versalis Spa Polibutadieni di-blocco stereoregolari a struttura 1,4-cis/1,2 sindiotattica da polimerizzazione stereospecifica
CA2834068C (en) 2013-11-18 2020-07-28 Nova Chemicals Corporation Enhanced escr bimodal rotomolding resin
CN105813742B (zh) 2013-12-19 2020-05-15 陶氏环球技术有限责任公司 金属-配位体络合物、由其衍生的烯烃聚合催化剂以及利用所述催化剂的烯烃聚合方法
CA2837591A1 (en) 2013-12-19 2015-06-19 Nova Chemicals Corporation Polyethylene composition for extrusion coating
US20150204027A1 (en) 2014-01-22 2015-07-23 Dow Global Technologies Llc Artificial turf filaments, and articles made therefrom
CN106536193A (zh) 2014-05-20 2017-03-22 纳幕尔杜邦公司 整理收缩膜保护结构
US10072110B2 (en) 2014-06-10 2018-09-11 Lg Chem, Ltd. Propylene-based elastomer
KR101580591B1 (ko) 2014-06-10 2015-12-28 주식회사 엘지화학 프로필렌계 엘라스토머
KR101666170B1 (ko) 2014-06-18 2016-10-13 주식회사 엘지화학 전이금속 화합물, 이를 포함하는 촉매 조성물 및 폴리올레핀의 제조방법
US20170152377A1 (en) 2014-06-26 2017-06-01 Dow Global Technologies Llc Breathable films and articles incorporating same
MX2016016605A (es) 2014-06-26 2017-04-27 Dow Global Technologies Llc Peliculas sopladas con tenacidad mejorada.
CN106470838B (zh) 2014-06-26 2019-05-17 陶氏环球技术有限责任公司 具有改进的韧性的流延膜
SG11201610692RA (en) 2014-06-30 2017-01-27 Dow Global Technologies Llc Process for olefin polymerization
KR20170027738A (ko) 2014-06-30 2017-03-10 다우 글로벌 테크놀로지스 엘엘씨 줄무늬 다층 필름
ES2949011T3 (es) 2014-06-30 2023-09-25 Dow Global Technologies Llc Sistemas de catalizador para la polimerización de olefinas
EP3578578A1 (en) 2014-07-24 2019-12-11 Dow Global Technologies Llc Bis-biphenylphenoxy catalysts for polymerization of low molecular weight ethylene-based polymers
KR101617870B1 (ko) 2014-09-05 2016-05-03 주식회사 엘지화학 가공성이 우수한 올레핀계 중합체
US10059724B2 (en) 2014-09-17 2018-08-28 Versalis S.P.A. Pyridine complex of zirconium, catalytic system comprising said pyridine complex of zirconium and process of (co)polymerization of conjugated dienes
CA2864573C (en) 2014-09-22 2021-07-06 Nova Chemicals Corporation Shrink film from single site catalyzed polyethylene
KR101784463B1 (ko) 2014-10-06 2017-10-11 주식회사 엘지화학 리간드 화합물, 메탈로센 화합물 및 이를 이용하는 올레핀계 중합체의 제조방법
WO2016056744A1 (ko) 2014-10-06 2016-04-14 주식회사 엘지화학 리간드 화합물, 메탈로센 화합물 및 이를 이용하는 올레핀계 중합체의 제조방법
KR101637982B1 (ko) 2014-11-07 2016-07-11 주식회사 엘지화학 리간드 화합물, 전이금속 화합물 및 이를 포함하는 촉매 조성물
KR101719064B1 (ko) 2014-11-13 2017-03-22 주식회사 엘지화학 리간드 화합물, 전이금속 화합물 및 이를 포함하는 촉매 조성물
CA2967660C (en) 2014-11-25 2023-05-02 Univation Technologies, Llc Methods of controlling polyolefin melt index
US10301412B2 (en) 2014-12-04 2019-05-28 Dow Global Technologies Llc Five-coordinate bis-phenylphenoxy catalysts for the preparation of ethylene-based polymers
WO2016094281A1 (en) 2014-12-11 2016-06-16 E. I. Du Pont De Nemours And Company Stretch wrapping film
CA2874895C (en) 2014-12-16 2022-02-15 Nova Chemicals Corporation High modulus single-site lldpe
KR102036664B1 (ko) 2014-12-17 2019-10-28 주식회사 엘지화학 이종의 전이금속 화합물을 포함하는 혼성 촉매 조성물 및 이를 이용한 올레핀계 공중합체의 제조방법
KR101731177B1 (ko) 2014-12-24 2017-04-27 주식회사 엘지화학 헤테로 원자를 갖는 전이금속 화합물, 이를 포함하는 촉매 조성물 및 이를 이용한 중합체의 제조방법
US10351646B2 (en) 2014-12-31 2019-07-16 Dow Global Technologies Llc Polyolefin composition and method of producing the same
KR101982190B1 (ko) 2015-01-05 2019-05-24 주식회사 엘지화학 올레핀계 공중합체의 제조방법 및 이에 의해 제조된 올레핀계 공중합체
CN106536534B (zh) 2015-01-28 2021-03-12 Lg化学株式会社 金属茂化合物、包含其的催化剂组合物以及使用其制备聚烯烃的方法
CN106661072B (zh) 2015-01-28 2021-03-12 Lg化学株式会社 金属茂化合物、包含其的催化剂组合物以及使用其制备基于烯烃的聚合物的方法
WO2016135590A1 (en) 2015-02-24 2016-09-01 Nova Chemicals (International) S.A. Bottle cap
EP3453452A3 (en) 2015-03-13 2019-06-05 Dow Global Technologies Llc Phosphacycle-containing ligand for chromium complex and olefin oligomerisation catalyst therefrom
KR101792934B1 (ko) 2015-03-26 2017-11-01 주식회사 엘지화학 올레핀계 엘라스토머
KR101847702B1 (ko) 2015-03-26 2018-04-10 주식회사 엘지화학 올레핀계 중합체
KR101953799B1 (ko) 2015-05-08 2019-03-04 주식회사 엘지화학 리간드 화합물 및 전이금속 화합물
KR102018285B1 (ko) 2015-05-08 2019-09-04 주식회사 엘지화학 리간드 화합물 및 전이금속 화합물의 제조방법
EP3093280A1 (en) 2015-05-13 2016-11-16 Sasol Performance Chemicals GmbH Process for the oligomerisation of olefins by coordinative chain transfer polymerisation and catalyst synthesis
CA2891693C (en) 2015-05-21 2022-01-11 Nova Chemicals Corporation Controlling the placement of comonomer in an ethylene copolymer
CA2892552C (en) 2015-05-26 2022-02-15 Victoria Ker Process for polymerization in a fluidized bed reactor
CA2892882C (en) 2015-05-27 2022-03-22 Nova Chemicals Corporation Ethylene/1-butene copolymers with enhanced resin processability
KR101926833B1 (ko) 2015-06-05 2019-03-07 주식회사 엘지화학 메탈로센 화합물
KR102588244B1 (ko) 2015-06-30 2023-10-12 다우 글로벌 테크놀로지스 엘엘씨 에틸렌계 폴리머를 제조하는 중합 방법
KR102588243B1 (ko) 2015-06-30 2023-10-13 다우 글로벌 테크놀로지스 엘엘씨 에틸렌계 폴리머를 제조하는 중합 방법
KR101910701B1 (ko) 2015-07-02 2018-10-22 주식회사 엘지화학 전이금속 화합물 및 이를 포함하는 촉매 조성물
KR101917911B1 (ko) 2015-07-02 2018-11-12 주식회사 엘지화학 전이금속 화합물 및 이를 포함하는 촉매 조성물
EP4321564A3 (en) 2015-07-09 2024-04-24 Ineos Europe AG Copolymers and films thereof
ITUB20152581A1 (it) 2015-07-29 2017-01-29 Versalis Spa Complesso azotato di titanio, sistema catalitico comprendente detto complesso azotato di titanio e procedimento per la (co)polimerizzazione di dieni coniugati
US9758653B2 (en) 2015-08-19 2017-09-12 Nova Chemicals (International) S.A. Polyethylene compositions, process and closures
KR102646587B1 (ko) 2015-09-30 2024-03-13 다우 글로벌 테크놀로지스 엘엘씨 전촉매 및 이를 사용한 중합 방법
CN108377649B (zh) 2015-09-30 2021-04-23 陶氏环球技术有限责任公司 用于产生乙烯类聚合物的聚合方法
JP6832348B2 (ja) 2015-09-30 2021-02-24 ダウ グローバル テクノロジーズ エルエルシー 連鎖シャトリングに有用な多頭性または二頭性組成物、及びそれを調製するためのプロセス
KR101987782B1 (ko) 2015-12-07 2019-06-11 주식회사 엘지화학 폴리프로필렌계 복합재
KR101889598B1 (ko) 2015-12-08 2018-08-17 주식회사 엘지화학 올레핀계 중합체
CA2914166C (en) 2015-12-08 2022-07-26 Nova Chemicals Corporation High density rotomolding resin
KR101967775B1 (ko) 2015-12-08 2019-08-13 주식회사 엘지화학 폴리프로필렌계 복합재
KR102034807B1 (ko) 2015-12-09 2019-10-21 주식회사 엘지화학 신규한 전이금속 화합물
CA2914354C (en) 2015-12-10 2022-11-08 Nova Chemicals Corp. Hot fill process with closures made frm bimodal polyethylene compositions
KR102029087B1 (ko) 2015-12-10 2019-10-07 주식회사 엘지화학 신규한 전이금속 화합물
CA2914353C (en) 2015-12-10 2023-01-24 Nova Chemicals Corp. Hot fill process with closures made from high density polyethylene compositions
KR102034808B1 (ko) 2015-12-22 2019-10-21 주식회사 엘지화학 신규한 전이금속 화합물
KR102054466B1 (ko) 2015-12-22 2019-12-11 주식회사 엘지화학 전이금속 화합물을 포함하는 촉매 조성물 및 이를 이용한 중합체의 제조방법
KR101910232B1 (ko) 2015-12-24 2018-12-19 주식회사 엘지화학 신규한 전이금속 화합물을 포함하는 촉매 조성물
EP3199342B1 (en) 2016-01-29 2019-02-27 Dow Global Technologies LLC Films, and related compositions and methods of making
KR102128569B1 (ko) 2016-02-12 2020-06-30 주식회사 엘지화학 신규한 전이금속 화합물
KR102095007B1 (ko) 2016-02-12 2020-03-30 주식회사 엘지화학 신규한 리간드 화합물 및 전이금속 화합물의 제조방법
KR102077756B1 (ko) 2016-02-12 2020-02-14 주식회사 엘지화학 신규한 전이금속 화합물의 제조방법
WO2017138783A1 (ko) 2016-02-12 2017-08-17 주식회사 엘지화학 신규한 리간드 화합물 및 전이금속 화합물
KR101931234B1 (ko) 2016-02-12 2018-12-21 주식회사 엘지화학 신규한 리간드 화합물 및 전이금속 화합물
PL3214124T5 (pl) 2016-03-02 2022-10-17 Dow Global Technologies Llc Kompozycja kopolimeru etylen/alfa olefina i zawierające ją wyroby
ES2849149T3 (es) 2016-03-03 2021-08-16 Dow Global Technologies Llc Céspedes artificiales y método para fabricarlos
EP3214116B1 (en) 2016-03-03 2021-06-23 Dow Global Technologies LLC Breathable films and method of making the same
ES2703602T3 (es) 2016-03-03 2019-03-11 Dow Global Technologies Llc Composición de polietileno, método para fabricar la misma, y películas fabricadas a partir de la misma
KR102091779B1 (ko) 2016-03-23 2020-03-20 주식회사 엘지화학 헤테로 아로마틱 리간드가 도입된 신규한 전이금속 화합물 및 이를 이용한 중합체의 제조방법
US10919995B2 (en) 2016-03-31 2021-02-16 Dow Global Technologies Llc Olefin polymerization catalyst systems and methods of use thereof
SG11201808184YA (en) 2016-03-31 2018-10-30 Dow Global Technologies Llc Olefin polymerization catalyst systems and methods of use thereof
KR102344637B1 (ko) 2016-03-31 2021-12-30 다우 글로벌 테크놀로지스 엘엘씨 올레핀 중합 촉매
ITUA20163932A1 (it) 2016-05-30 2017-11-30 Versalis Spa Complesso osso-azotato di ferro, sistema catalitico comprendente detto complesso osso-azotato di ferro e procedimento per la (co)polimerizzazione di dieni coniugati
US9783664B1 (en) 2016-06-01 2017-10-10 Nova Chemicals (International) S.A. Hinged component comprising polyethylene composition
EP3490999B1 (en) 2016-07-29 2021-04-14 Dow Global Technologies LLC Synthesis of m-terphenyl pendant bis-ether ligands and metal complex and their use in olefin polymerization
WO2018044414A1 (en) 2016-08-30 2018-03-08 Dow Global Technologies Llc Method for thermally insulating subsea structures
KR102083001B1 (ko) 2016-09-23 2020-02-28 주식회사 엘지화학 올레핀계 공중합체 및 이의 제조 방법
KR102086055B1 (ko) 2016-09-23 2020-03-06 주식회사 엘지화학 폴리프로필렌계 수지 조성물
EP3519190B1 (en) 2016-09-28 2020-09-23 Dow Global Technologies Llc Blown films with improved properties
US20210276303A1 (en) 2016-09-30 2021-09-09 Dow Global Technologies Llc Resins for use as tie layers in multilayer films and multilayer films comprising the same
TWI756272B (zh) 2016-09-30 2022-03-01 美商陶氏全球科技有限責任公司 適用於鏈梭移之封端多頭或雙頭組合物及其製備方法
EP3519469B1 (en) 2016-09-30 2020-07-29 Dow Global Technologies LLC Bis-ligated phosphaguanidine group iv metal complexes and olefin polymerization catalysts produced therefrom
BR112019005993B1 (pt) 2016-09-30 2022-10-11 Dow Global Technologies Llc Sistema de catalisador de polimerização
BR112019006207B1 (pt) 2016-09-30 2022-11-29 Dow Global Technologies Llc Processo para preparar uma composição, processo de polimerização para preparar uma composição polimérica e composição polimérica
JP6990239B2 (ja) 2016-09-30 2022-02-03 ダウ グローバル テクノロジーズ エルエルシー ビスホスファグアニジンおよびポリホスファグアニジン配位子とそれらから製造される第ｉｖ族金属触媒
TW201840572A (zh) 2016-09-30 2018-11-16 美商陶氏全球科技有限責任公司 適用於鏈梭移之多頭或雙頭組合物及其製備方法
EP3312007B1 (en) 2016-10-18 2023-12-27 Dow Global Technologies LLC Multilayer stretch hood compositions and structures
KR102236920B1 (ko) 2016-11-11 2021-04-07 주식회사 엘지화학 전이금속 화합물을 포함하는 촉매 조성물 및 이를 이용한 중합체의 제조방법
KR102223719B1 (ko) 2016-11-14 2021-03-05 주식회사 엘지화학 리간드 화합물, 전이금속 화합물 및 이를 포함하는 촉매 조성물
KR102223718B1 (ko) 2016-11-14 2021-03-05 주식회사 엘지화학 리간드 화합물, 전이금속 화합물 및 이를 포함하는 촉매 조성물
KR102140690B1 (ko) 2016-11-14 2020-08-04 주식회사 엘지화학 리간드 화합물, 전이금속 화합물 및 이를 포함하는 촉매 조성물
KR102236921B1 (ko) 2016-11-16 2021-04-07 주식회사 엘지화학 전이금속 화합물 및 알킬알루미녹산을 포함하는 촉매 조성물, 이를 이용한 중합체의 제조방법, 및 이를 이용하여 제조된 중합체
US11346047B2 (en) 2017-01-04 2022-05-31 Columbia Insurance Company Carpets having an improved delamination strength and fluid barrier properties and methods of making same
BR112019013171B1 (pt) 2017-01-06 2023-03-28 Univation Technologies, Llc Processo de síntese de ligantes de benzilanilinil fenil fenol
WO2018129235A1 (en) 2017-01-06 2018-07-12 Univation Technologies, Llc Synthesis of benzyloxyphenoxy phenol ligands
EP3589693B1 (en) 2017-02-28 2024-01-03 ExxonMobil Chemical Patents Inc. Thermoplastic vulcanizate prepared with oil-extended, bimodal metallocene-synthesized epdm
US11208513B2 (en) 2017-03-09 2021-12-28 Exxonmobil Chemical Patents Inc. Process for producing polyethylene polymers
EP3596146B1 (en) 2017-03-15 2023-07-19 Dow Global Technologies LLC Catalyst system for multi-block copolymer formation
WO2018170138A1 (en) 2017-03-15 2018-09-20 Dow Global Technologies Llc Catalyst system for multi-block copolymer formation
EP3596143B1 (en) 2017-03-15 2023-04-26 Dow Global Technologies LLC Catalyst system for multi-block copolymer formation
EP3596138B1 (en) 2017-03-15 2024-04-03 Dow Global Technologies LLC Catalyst system for multi-block copolymer formation
CN110612315B (zh) 2017-03-15 2022-08-26 陶氏环球技术有限责任公司 用于形成多嵌段共聚物的催化剂体系
US10982383B2 (en) 2017-04-05 2021-04-20 Columbia Insurance Company Floor coverings and floor covering systems and methods of making and installing same
AR111718A1 (es) 2017-04-19 2019-08-14 Dow Global Technologies Llc Estructuras de laminados y materiales de empaque flexibles que las incluyen
AR112359A1 (es) 2017-06-30 2019-10-23 Dow Global Technologies Llc Laminados de polietileno para usar en materiales de embalaje flexibles
AR112245A1 (es) 2017-06-30 2019-10-09 Dow Global Technologies Llc Laminados y películas de polietileno multicapa para usar en materiales de envasado flexibles
WO2019022569A1 (ko) 2017-07-27 2019-01-31 주식회사 엘지화학 신규한 전이금속 화합물 및 이를 제조하는 방법
MX2020002221A (es) 2017-09-22 2020-07-22 Dow Global Technologies Llc Composiciones de pelicula termoformada con tenacidad mejorada despues de procesos de termoformado.
EP3524612B1 (en) 2017-09-25 2022-04-20 LG Chem, Ltd. Ligand compound, transition metal compound, and catalyst composition comprising the transition metal compound
MX2020002911A (es) 2017-09-26 2020-07-22 Dow Global Technologies Llc Composiciones que contienen un catalizador basado en estaño y dióxido de titanio para el curado por humedad de polímeros etilénicos funcionalizados con silano.
JP7221948B2 (ja) 2017-09-29 2023-02-14 ダウ グローバル テクノロジーズ エルエルシー 溶解性を改善させるために金属上にメチレントリアルキルシリコン配位子を有するビスフェニルフェノキシポリオレフィン触媒
IT201700109176A1 (it) 2017-09-29 2019-03-29 Versalis Spa Complesso bis-imminico di titanio, sistema catalitico comprendente detto complesso bis-imminico di titanio e procedimento per la (co)polimerizzazione di dieni coniugati
ES2967951T3 (es) 2017-09-29 2024-05-06 Dow Global Technologies Llc Catalizadores de bis-fenil fenoxi poliolefina que tienen dos ligandos de metilentrialquilsilicio en el metal para mejorar la solubilidad
EP3688043B1 (en) 2017-09-29 2023-06-14 Dow Global Technologies LLC Bis-phenyl-phenoxy polyolefin catalysts having an alkoxy- or amido-ligand on the metal for improved solubility
CN111433236B (zh) 2017-11-17 2023-02-24 埃克森美孚化学专利公司 在线清洁换热器的方法
US11479624B2 (en) 2017-11-17 2022-10-25 Exxonmobil Chemical Patents Inc. PE-RT pipes and processes for making the same
CA3022700A1 (en) 2017-11-27 2019-05-27 Nova Chemicals Corporation Bottle closure assembly comprising a polyethylene composition having good dimensional stability
KR20190063602A (ko) 2017-11-30 2019-06-10 롯데케미칼 주식회사 폴리올레핀 제조용 메탈로센 촉매 시스템 및 이를 이용한 폴리올레핀의 제조방법
CA3022996A1 (en) 2017-12-04 2019-06-04 Nova Chemicals Corporation Bottle closure assembly comprising a polyethylene composition
DE102017129900A1 (de) 2017-12-14 2019-06-19 Ewald Dörken Ag Bauverbundfolie
WO2019126129A1 (en) 2017-12-22 2019-06-27 E. I. Du Pont De Nemours And Company Thermoplastic adhesive composition
KR102268080B1 (ko) 2017-12-22 2021-06-23 주식회사 엘지화학 폴리프로필렌계 복합재
WO2019126189A1 (en) 2017-12-22 2019-06-27 E. I. Du Pont De Nemours And Company Thermoplastic adhesive composition
KR102335315B1 (ko) 2017-12-22 2021-12-06 주식회사 엘지화학 폴리프로필렌계 복합재
KR102423660B1 (ko) 2017-12-26 2022-07-22 주식회사 엘지화학 전이금속 화합물 및 이를 포함하는 촉매 조성물
KR102320012B1 (ko) 2018-01-12 2021-11-02 주식회사 엘지화학 리간드 화합물, 전이금속 화합물 및 이를 포함하는 촉매 조성물
KR102323807B1 (ko) 2018-01-12 2021-11-09 주식회사 엘지화학 촉매 조성물 내 브롬 화합물의 제거 방법
KR102411597B1 (ko) 2018-01-15 2022-06-22 주식회사 엘지화학 전이금속 화합물 및 이를 포함하는 촉매 조성물
KR20190127595A (ko) 2018-05-04 2019-11-13 주식회사 엘지화학 폴리프로필렌계 복합재 및 이의 제조방법
KR20190127594A (ko) 2018-05-04 2019-11-13 주식회사 엘지화학 폴리프로필렌계 복합재 및 이의 제조방법
CA3009299A1 (en) 2018-06-26 2019-12-26 Nova Chemicals Corporation Catalyst injection system for an olefin polymerization reactor
CA3011044A1 (en) 2018-07-12 2020-01-12 Nova Chemicals Corporation Acid resistant polyethylene containers
WO2020023193A1 (en) 2018-07-23 2020-01-30 Exxonmobil Chemical Patents Inc. Preparation of bimodal rubber, thermoplastic vulcanizates, and articles made therefrom
KR102601720B1 (ko) 2018-09-07 2023-11-14 주식회사 엘지화학 리간드 화합물, 전이금속 화합물 및 이를 포함하는 촉매 조성물
SG11202102663QA (en) 2018-09-19 2021-04-29 Exxonmobil Chemical Patents Inc Devolatilization processes
DE102018008583A1 (de) 2018-10-31 2020-04-30 Ewald Dörken Ag Verbundfolie
DE102018008584A1 (de) 2018-10-31 2020-04-30 Ewald Dörken Ag Verbundfolie
DE102018008585A1 (de) 2018-10-31 2020-04-30 Ewald Dörken Ag Verbundfolie
WO2020106107A1 (ko) 2018-11-22 2020-05-28 주식회사 엘지화학 전이금속 화합물 및 이를 포함하는 촉매 조성물
CA3026098A1 (en) 2018-12-03 2020-06-03 Nova Chemicals Corporation Narrow polyethylene homopolymer compositions having good barrier properties
CA3026095A1 (en) 2018-12-03 2020-06-03 Nova Chemicals Corporation Polyethylene homopolymer compositions having good barrier properties
EP3783004B1 (en) 2018-12-12 2023-02-01 Lg Chem, Ltd. Transition metal compound, catalyst composition comprising same, and polymer preparation method using same
CA3028148A1 (en) 2018-12-20 2020-06-20 Nova Chemicals Corporation Polyethylene copolymer compositions and articles with barrier properties
CA3028157A1 (en) 2018-12-20 2020-06-20 Nova Chemicals Corporation Polyethylene copolymer compositions and their barrier properties
BR112021012786A2 (pt) 2018-12-28 2021-09-14 Dow Global Technologies Llc Formulação curável
EP3902807A1 (en) 2018-12-28 2021-11-03 Dow Global Technologies LLC Organometallic chain transfer agents
WO2020139993A1 (en) 2018-12-28 2020-07-02 Dow Global Technologies Llc Curable compositions comprising unsaturated polyolefins
SG11202107057WA (en) 2018-12-28 2021-07-29 Dow Global Technologies Llc Curable compositions comprising unsaturated polyolefins
EP3902852A1 (en) 2018-12-28 2021-11-03 Dow Global Technologies LLC Telechelic polyolefins and processes for preparing the same
CA3032082A1 (en) 2019-01-31 2020-07-31 Nova Chemicals Corporation Polyethylene compositions and articles with good barrier properties
WO2020167399A1 (en) 2019-02-11 2020-08-20 Exxonmobil Chemical Patents Inc. Biphasic polymerization processes and ethylene-based polyolefins therefrom
KR102657796B1 (ko) 2019-02-20 2024-04-17 주식회사 엘지화학 리간드 화합물, 전이금속 화합물 및 이를 포함하는 촉매 조성물
DE102019001343A1 (de) 2019-02-26 2020-08-27 Ewald Dörken Ag Verfahren zur Herstellung einer wasserdampfdurchlässigen flächigen Verbundfolie
BR112021018759A2 (pt) 2019-03-26 2021-11-30 Dow Global Technologies Llc Filme de multicamadas, laminado, e, artigo
KR20200132744A (ko) 2019-05-17 2020-11-25 주식회사 엘지화학 하프늄 화합물 및 이를 포함하는 촉매 조성물
WO2020240401A1 (en) 2019-05-31 2020-12-03 Nova Chemicals (International) S.A. Enhanced escr and ductility bimodal rotomolding resin
KR20210012543A (ko) 2019-07-25 2021-02-03 주식회사 엘지화학 이핵 메탈로센 화합물, 촉매 조성물 및 이를 이용한 올레핀 중합체의 제조방법
CA3138893A1 (en) 2019-07-25 2021-01-28 Celine Bellehumeur Rotomolded parts prepared from bimodal polyethylene
KR20210012693A (ko) 2019-07-26 2021-02-03 주식회사 엘지화학 피리딘계 전이금속 화합물 및 이를 포함하는 촉매 조성물
KR20210017750A (ko) 2019-08-09 2021-02-17 주식회사 엘지화학 촉매 조성물 내 무기물의 제거 방법
KR20210021752A (ko) 2019-08-19 2021-03-02 주식회사 엘지화학 폴리프로필렌계 복합재
CN113661187B (zh) 2019-08-28 2023-05-16 株式会社Lg化学 聚丙烯系复合材料及其制备方法
KR20210037461A (ko) 2019-09-27 2021-04-06 주식회사 엘지화학 전이금속 화합물 및 이를 포함하는 촉매 조성물
KR102682764B1 (ko) 2019-09-27 2024-07-12 주식회사 엘지화학 전이금속 화합물 및 이를 포함하는 촉매 조성물
KR20210037465A (ko) 2019-09-27 2021-04-06 주식회사 엘지화학 전이금속 화합물 및 이를 포함하는 촉매 조성물
KR20210038236A (ko) 2019-09-30 2021-04-07 주식회사 엘지화학 올레핀계 중합체의 품질 특성 예측 방법 및 이를 포함하는 올레핀계 중합체의 제조방법
MX2022003661A (es) 2019-10-01 2022-04-25 Nova Chem Int Sa Control de insaturacion en polimeros producidos en proceso de solucion.
WO2021064546A1 (en) 2019-10-01 2021-04-08 Nova Chemicals (International) S.A. High productivity polymerization with aryloxy ether ligand catalyst
KR20210041453A (ko) 2019-10-07 2021-04-15 주식회사 엘지화학 전이금속 화합물, 리간드 화합물 및 이를 포함하는 촉매 조성물
CA3152079A1 (en) 2019-10-16 2021-04-22 Nova Chemicals Corporation Use of recycled polyethylene in closures for bottles
EP4077424A2 (en) 2019-12-17 2022-10-26 ExxonMobil Chemical Patents Inc. Solution polymerization process for making high-density polyethylene long-chain branching
BR112022012371A2 (pt) 2019-12-26 2022-08-30 Dow Global Technologies Llc Espuma de poliolefina reticulada e processo para produzir a mesma
MX2022007803A (es) 2019-12-30 2022-07-19 Dow Global Technologies Llc Monomero de etileno-propileno-dieno (epdm) extendido con aceite en mezcla curada por humedad.
WO2021144615A1 (en) 2020-01-17 2021-07-22 Nova Chemicals (International) S.A. Polyethylene copolymer compositions and articles with barrier properties
KR20220155594A (ko) 2020-04-20 2022-11-23 노바 케미컬즈 (인터내셔널) 소시에테 아노님 낮은 상대 탄성을 갖는 회전성형 조성물
KR20210145013A (ko) 2020-05-22 2021-12-01 주식회사 엘지화학 폴리프로필렌계 복합재
KR20210145015A (ko) 2020-05-22 2021-12-01 주식회사 엘지화학 폴리프로필렌계 복합재
KR20210144351A (ko) 2020-05-22 2021-11-30 주식회사 엘지화학 폴리프로필렌계 복합재
CN115667390A (zh) 2020-05-27 2023-01-31 陶氏环球技术有限责任公司 聚合物调配物和包含聚合物调配物的灌溉管
KR20210155418A (ko) 2020-06-15 2021-12-23 주식회사 엘지화학 폴리프로필렌계 복합재
JP2023532133A (ja) 2020-07-02 2023-07-26 セラニーズ・インターナショナル・コーポレーション メタロセン多峰性コポリマーゴムを含有する熱可塑性加硫物組成物およびその製造方法
JP2023534659A (ja) 2020-07-17 2023-08-10 ダウ グローバル テクノロジーズ エルエルシー 拘束幾何プロ触媒のためのヒドロカルビル変性メチルアルミノキサン助触媒
KR20220017245A (ko) 2020-08-04 2022-02-11 주식회사 엘지화학 리간드 화합물, 전이금속 화합물 및 이를 포함하는 촉매 조성물
CN111909196B (zh) * 2020-08-10 2023-05-26 万华化学集团股份有限公司 一类含ivb族双金属配合物催化剂及其制备方法与应用
KR20220025392A (ko) 2020-08-24 2022-03-03 주식회사 엘지화학 리간드 화합물, 전이금속 화합물 및 이를 포함하는 촉매 조성물
JPWO2022045175A1 (ja) 2020-08-28 2022-03-03
US20230382929A1 (en) 2020-10-15 2023-11-30 Dow Global Technologies Llc Olefin polymerization catalysts bearing a 6-amino-n-aryl azaindole ligand
WO2022112054A1 (en) 2020-11-26 2022-06-02 Basell Polyolefine Gmbh Low-smoke self-extinguishing electrical cable and flame-retardant composition used therein
CN116648465A (zh) 2020-12-17 2023-08-25 Ａｇｃ株式会社 新型的硼酸盐化合物
EP4330294A1 (en) 2021-04-30 2024-03-06 ExxonMobil Chemical Patents Inc. Processes for transitioning between different polymerization catalysts in a polymerization reactor
EP4136974A1 (en) 2021-08-20 2023-02-22 Fixed Phage Limited Plasma treatment process and apparatus therefor
DE102021130932A1 (de) 2021-11-25 2023-05-25 Ewald Dörken Ag Verbundfolie für den Baubereich
WO2023177129A1 (ko) 2022-03-14 2023-09-21 주식회사 엘지화학 리간드 화합물, 유기 크롬 화합물 및 이를 포함하는 촉매 조성물
KR20230134434A (ko) 2022-03-14 2023-09-21 주식회사 엘지화학 리간드 화합물, 유기 크롬 화합물 및 이를 포함하는 촉매 조성물
KR20240044070A (ko) 2022-09-28 2024-04-04 주식회사 엘지화학 리간드 화합물, 유기 크롬 화합물 및 이를 포함하는 촉매 조성물
CN115710326B (zh) * 2022-10-27 2024-06-25 万华化学集团股份有限公司 一种氧芴桥连的芳氧基金属络合物催化剂及方法与应用

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62187708A (ja) * 1985-11-11 1987-08-17 Idemitsu Kosan Co Ltd スチレン系重合体の製造法
US4791180A (en) * 1985-12-12 1988-12-13 Exxon Chemical Patents Inc. New polymerization catalyst
JPH0780930B2 (ja) * 1985-12-26 1995-08-30 三井石油化学工業株式会社 α−オレフインの重合方法
PL276385A1 (en) * 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
IL85097A (en) * 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
US5055438A (en) * 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
JPH01501487A (ja) * 1987-06-17 1989-05-25 ザ　ダウ　ケミカル　カンパニー シンジオタクチックポリスチレンの製造のための触媒および方法
JPH0757767B2 (ja) * 1988-01-19 1995-06-21 出光興産株式会社 スチレン系重合体の製造方法及び触媒
JP2796972B2 (ja) * 1988-10-19 1998-09-10 旭化成工業株式会社 立体規則性芳香族ビニル重合体の製法
PL286365A1 (en) * 1989-08-03 1991-04-22 Exxon Chemical Patents Inc Method of polymerizing especially ethylene any polymerization catalyst and method of obtaining same
CA2024830A1 (en) * 1989-09-29 1991-03-30 Richard E. Campbell, Jr. Process for preparation of syndiotactic vinyl aromatic polymers
DE551277T1 (de) † 1990-06-22 1996-10-10 Exxon Chemical Patents Inc., Linden, N.J. Aluminiumfreie monocyclopentadienyl-metallocenkatalysatoren für olefinpolymerisation.

Also Published As

Publication number Publication date
NZ235215A (en) 1992-07-28
EP0418044A3 (en) 1992-01-29
IL95598A (en) 1998-08-16
CA2025332C (en) 2001-12-04
JPH1067816A (ja) 1998-03-10
CN1028369C (zh) 1995-05-10
NO903986L (no) 1991-03-15
KR910006307A (ko) 1991-04-29
AU632620B2 (en) 1993-01-07
NO302702B1 (no) 1998-04-14
DE69031413T2 (de) 1998-03-05
AU6247390A (en) 1991-03-21
NO903986D0 (no) 1990-09-13
HUT55039A (en) 1991-04-29
YU172890A (sh) 1992-12-21
HU905892D0 (en) 1991-03-28
EP0765882A2 (en) 1997-04-02
HU218602B (hu) 2000-10-28
RU2095363C1 (ru) 1997-11-10
US5132380A (en) 1992-07-21
EP0765882A3 (en) 1998-02-25
ES2106021T5 (es) 2004-03-16
BR9004695A (pt) 1991-09-10
ES2106021T3 (es) 1997-11-01
EP0418044B2 (en) 2003-08-20
KR0168048B1 (ko) 1999-03-20
CA2025332A1 (en) 1991-03-15
US5064802A (en) 1991-11-12
EP0418044B1 (en) 1997-09-10
JPH03139504A (ja) 1991-06-13
IL95598A0 (en) 1991-06-30
CN1050194A (zh) 1991-03-27
YU47114B (sh) 1994-12-28
JP3010349B2 (ja) 2000-02-21
DE69031413T3 (de) 2004-05-27
EP0418044A2 (en) 1991-03-20
DE69031413D1 (de) 1997-10-16
GEP19991571B (en) 1999-12-17
FI100104B (fi) 1997-09-30
SG43055A1 (en) 1997-10-17
FI904516A0 (fi) 1990-09-13
RO106411B1 (ro) 1993-04-30
HK1001919A1 (en) 1998-07-17

Similar Documents

Publication Publication Date Title
JP2736935B2 (ja) 金属錯体化合物
KR100278426B1 (ko) 모노시클로펜타디에닐 금속 착화합물의 제조방법 및 사용방법
CA2174768C (en) Catalyst for use in olefin polymerization or copolymerization
RU2062649C1 (ru) Способ получения катализатора для полимеризации и сополимеризации альфа -олефинов
CA2233655C (en) Supported catalyst containing tethered cation forming activator
JP2000507560A (ja) アリル含有金属錯体およびオレフィン重合方法
NO315977B1 (no) Katalysatorblanding omfattende reaksjonsproduktet av en organometallforbindelse samt anvendelse derav
JPH10502342A (ja) エチレン−α−オレフィンコポリマー製造触媒のためのモノシクロペンタジエニル金属化合物
US6825369B1 (en) Metal complex compounds
US20040054150A1 (en) Multimetallic catalyst compositions for the polymerization of olefins
KR20000005030A (ko) 헤테로사이클릭 금속 착체 및 올레핀 중합 방법
US6537943B1 (en) Catalyst system composed of metallocenes comprising substituents containing fluorine
US6271322B1 (en) Monocyclopentadienyl transition metal catalyst and olefin polymerization process
US7166684B2 (en) Transition metal compound, catalyst for olefin polymerization and method for producing polyolefin
PL166841B1 (pl) Sposób wytwarzania homo- lub kopolimeru C2 -Ce -α-olefln na orodze polimeryzacji addycyjne]
EP1801131A1 (en) Zwitterionic cyclopentadienyl catalyst
JPH11292911A (ja) オレフィン重合用触媒およびそれを用いたポリオレフィンの製造方法

Legal Events

Date Code Title Description
R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20080116

Year of fee payment: 10

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20090116

Year of fee payment: 11

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20090116

Year of fee payment: 11

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20100116

Year of fee payment: 12

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20110116

Year of fee payment: 13

EXPY Cancellation because of completion of term
FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20110116

Year of fee payment: 13