ES2160634T3 - Sistemas catalizadores de polimerizacion, su produccion y uso. - Google Patents

Sistemas catalizadores de polimerizacion, su produccion y uso.

Info

Publication number
ES2160634T3
ES2160634T3 ES94927237T ES94927237T ES2160634T3 ES 2160634 T3 ES2160634 T3 ES 2160634T3 ES 94927237 T ES94927237 T ES 94927237T ES 94927237 T ES94927237 T ES 94927237T ES 2160634 T3 ES2160634 T3 ES 2160634T3
Authority
ES
Spain
Prior art keywords
catalyst system
supported
metalocene
activator
binding
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94927237T
Other languages
English (en)
Inventor
Moses Olukayode Jejelowo
Robert Lee Bamberger
Vispi Ruston Sagar
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/122,213 external-priority patent/US5422325A/en
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Application granted granted Critical
Publication of ES2160634T3 publication Critical patent/ES2160634T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63904—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with another component of C08F4/62
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63908—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

LA INVENCION GENERALMENTE SE DIRIGE HACIA UN SISTEMA CATALIZADOR SOPORTADO UTIL PARA LA POLIMERIZACION DE OLEFINAS. EL METODO PARA SOPORTAR EL CATALIZADOR DE LA INVENCION SUMINISTRA UN CATALIZADOR SOPORTADO SOBRE UN METALOCENO DE UN METAL DE TRANSICION Y UN LIGANDO QUE TIENE UNA ACTIVIDAD MEJORADA QUE CUANDO SE UTILIZA EN UN PROCESO DE POLIMERIZACION REDUCE SUBSTANCIALMENTE EL ENSUCIAMIENTO Y LA FORMACION DE COSTRAS EN EL REACTOR PARTICULARMENTE EN UN PROCESO DE POLIMERIZACION DE FASE DE GAS. EN UNA REALIZACION, SE SUMINISTRA UN METODO PARA PRODUCIR UN SISTEMA DE CATALIZADOR SOPORTADO SOBRE UN METALOCENO DE UN METAL DE TRANSICION Y UN LIGANDO MEDIANTE LA PUESTA EN CONTACTO DE UN PORTADOR POROSO CON AL MENOS UN COMPUESTO LIGANTE DE METALES DE TRANSICION, TAL COMO UN METALOCENO, SEGUIDA POR LA ADICION DE UN COCATALIZADOR O ACTIVADOR. EN OTRA REALIZACION, SE SUMINISTRA UN METODO PARA PRODUCIR UN SISTEMA DE CATALIZADOR SOPORTADO MEDIANTE LA PUESTA EN CONTACTO DE UN PORTADOR POROSO CON UN COMPUESTO ORGANOMETALICO AÑADIENDO ENTONCES AL MENOS UN COMPONENTE DE METALOCENO SEGUIDO POR UN ACTIVADOR. EN OTRA CONFORMACION, EL ACTIVADOR DE LA INVENCION SE HIDROLIZA AL MENOS UNA VEZ DESPUES DE SU FORMACION INICIAL. EN OTRA REALIZACION DE LA INVENCION, SE SUMINISTRA UN PROCESO PARA PRODUCIR POLIOLEFINAS MEDIANTE LA PUESTA EN CONTACTO DE UN MONOMERO DE OLEFINA, OPCIONALMENTE CON UN COMONOMERO EN PRESENCIA DEL SISTEMA CATALIZADOR DESCRITO ANTERIORMENTE.
ES94927237T 1993-09-17 1994-08-29 Sistemas catalizadores de polimerizacion, su produccion y uso. Expired - Lifetime ES2160634T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/122,213 US5422325A (en) 1993-09-17 1993-09-17 Supported polymerization catalysts, their production and use
US17010893A 1993-12-20 1993-12-20
US18224494A 1994-01-14 1994-01-14

Publications (1)

Publication Number Publication Date
ES2160634T3 true ES2160634T3 (es) 2001-11-16

Family

ID=27382752

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94927237T Expired - Lifetime ES2160634T3 (es) 1993-09-17 1994-08-29 Sistemas catalizadores de polimerizacion, su produccion y uso.

Country Status (6)

Country Link
EP (1) EP0739360B1 (es)
JP (1) JPH09503008A (es)
CA (1) CA2171831A1 (es)
DE (1) DE69427095T2 (es)
ES (1) ES2160634T3 (es)
WO (1) WO1995007939A1 (es)

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DE19806435A1 (de) * 1998-02-17 1999-08-19 Basf Ag Verfahren zur Herstellung eines geträgerten Katalysatorsystems
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BRPI0703586B1 (pt) 2007-10-19 2018-02-06 Braskem S.A Catalisador metaloceno suportado, e, copolímeros de etileno com alfa-olefinas de alto e ultra alto peso molecular
EP2172490A1 (en) 2008-10-03 2010-04-07 Ineos Europe Limited Controlled polymerisation process
EP2357035A1 (en) 2010-01-13 2011-08-17 Ineos Europe Limited Polymer powder storage and/or transport and/or degassing vessels
EP2383298A1 (en) 2010-04-30 2011-11-02 Ineos Europe Limited Polymerization process
EP2383301A1 (en) 2010-04-30 2011-11-02 Ineos Europe Limited Polymerization process
US9394381B2 (en) 2010-11-29 2016-07-19 Ineos Sales (Uk) Limited Polymerisation control process
EP2465876A1 (en) 2010-12-15 2012-06-20 INEOS Manufacturing Belgium NV Activating supports
US9012359B2 (en) 2011-01-20 2015-04-21 Ineos Sales (Uk) Limited Activating supports
US8383740B1 (en) 2011-08-12 2013-02-26 Ineos Usa Llc Horizontal agitator
ES2665545T3 (es) 2011-10-17 2018-04-26 Ineos Europe Ag Control del proceso de desgasificación del polímero
CN104105722B (zh) 2011-12-14 2016-11-09 英尼奥斯欧洲股份公司 聚合物
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Also Published As

Publication number Publication date
DE69427095T2 (de) 2001-11-15
EP0739360A1 (en) 1996-10-30
DE69427095D1 (de) 2001-05-17
JPH09503008A (ja) 1997-03-25
CA2171831A1 (en) 1995-03-23
WO1995007939A1 (en) 1995-03-23
EP0739360B1 (en) 2001-04-11

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