DE69427095T2 - Polymerisations katalysator systeme, ihre herstellung und verwendung - Google Patents

Polymerisations katalysator systeme, ihre herstellung und verwendung

Info

Publication number
DE69427095T2
DE69427095T2 DE69427095T DE69427095T DE69427095T2 DE 69427095 T2 DE69427095 T2 DE 69427095T2 DE 69427095 T DE69427095 T DE 69427095T DE 69427095 T DE69427095 T DE 69427095T DE 69427095 T2 DE69427095 T2 DE 69427095T2
Authority
DE
Germany
Prior art keywords
production
polymerization catalyst
catalyst systems
systems
polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69427095T
Other languages
English (en)
Other versions
DE69427095D1 (de
Inventor
Olukayode Jejelowo
Lee Bamberger
Ruston Sagar
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/122,213 external-priority patent/US5422325A/en
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Publication of DE69427095D1 publication Critical patent/DE69427095D1/de
Application granted granted Critical
Publication of DE69427095T2 publication Critical patent/DE69427095T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63904—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with another component of C08F4/62
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63908—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
DE69427095T 1993-09-17 1994-08-29 Polymerisations katalysator systeme, ihre herstellung und verwendung Expired - Lifetime DE69427095T2 (de)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US08/122,213 US5422325A (en) 1993-09-17 1993-09-17 Supported polymerization catalysts, their production and use
US17010893A 1993-12-20 1993-12-20
US18224494A 1994-01-14 1994-01-14
PCT/US1994/009629 WO1995007939A1 (en) 1993-09-17 1994-08-29 Polymerization catalyst systems, their production and use

Publications (2)

Publication Number Publication Date
DE69427095D1 DE69427095D1 (de) 2001-05-17
DE69427095T2 true DE69427095T2 (de) 2001-11-15

Family

ID=27382752

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69427095T Expired - Lifetime DE69427095T2 (de) 1993-09-17 1994-08-29 Polymerisations katalysator systeme, ihre herstellung und verwendung

Country Status (6)

Country Link
EP (1) EP0739360B1 (de)
JP (1) JPH09503008A (de)
CA (1) CA2171831A1 (de)
DE (1) DE69427095T2 (de)
ES (1) ES2160634T3 (de)
WO (1) WO1995007939A1 (de)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9613814D0 (en) * 1996-07-02 1996-09-04 Bp Chem Int Ltd Supported polymerisation catalysts
DE19703502A1 (de) 1997-01-31 1998-08-06 Basf Ag Nicht selbstentzündlicher Feststoff
DE19709866A1 (de) 1997-03-11 1998-09-17 Basf Ag Geträgertes Katalysatorsystem zur Polymerisation von Alk-1-enen
CN1098284C (zh) * 1997-09-18 2003-01-08 中国石油化工总公司 烯烃聚合和共聚合用茂金属催化体系及其制备方法
DE19806435A1 (de) 1998-02-17 1999-08-19 Basf Ag Verfahren zur Herstellung eines geträgerten Katalysatorsystems
DE19811934A1 (de) 1998-03-19 1999-09-23 Basf Ag Ethylencopolymere mit enger Comonomerverteilung
WO2000004057A1 (en) * 1998-07-17 2000-01-27 Bp Chemicals Limited Method for preparing an activator for the polymerisation of olefins
WO2006044058A1 (en) 2004-10-12 2006-04-27 Exxonmobil Chemical Patents Inc. Trialkylaluminum treated supports
EP1731536A1 (de) 2005-06-09 2006-12-13 Innovene Manufacturing France SAS Unterstützte Polymerisationskatalysatoren
GB0610667D0 (en) 2006-05-30 2006-07-05 Nova Chem Int Sa Supported polymerization catalysts
BRPI0703586B1 (pt) 2007-10-19 2018-02-06 Braskem S.A Catalisador metaloceno suportado, e, copolímeros de etileno com alfa-olefinas de alto e ultra alto peso molecular
EP2172490A1 (de) 2008-10-03 2010-04-07 Ineos Europe Limited Polimerisationsverfahren
EP2357035A1 (de) 2010-01-13 2011-08-17 Ineos Europe Limited Polymerpulveraufbewahrungs- und/oder -transport- und/oder -entgasungsgefäßen
EP2383301A1 (de) 2010-04-30 2011-11-02 Ineos Europe Limited Polymerisierungsverfahren
EP2383298A1 (de) 2010-04-30 2011-11-02 Ineos Europe Limited Polymerisierungsverfahren
RU2608124C2 (ru) 2010-11-29 2017-01-13 Инеос Коммершиал Сервисиз Юк Лимитед Способ контроля полимеризации
EP2465876A1 (de) 2010-12-15 2012-06-20 INEOS Manufacturing Belgium NV Aktivierung von Trägern
WO2012098045A1 (en) 2011-01-20 2012-07-26 Ineos Commercial Services Uk Limited Activating supports
US8383740B1 (en) 2011-08-12 2013-02-26 Ineos Usa Llc Horizontal agitator
RU2608615C2 (ru) 2011-10-17 2017-01-23 Инеос Юроуп Аг Регулирование процесса дегазации полимеров
WO2013087531A1 (en) 2011-12-14 2013-06-20 Ineos Europe Ag Novel polymers
CN115785308A (zh) * 2022-11-30 2023-03-14 上海化工研究院有限公司 一种用于生产增强聚烯烃的催化剂及其制备和应用

Family Cites Families (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2961381D1 (en) 1978-02-08 1982-01-28 Ciba Geigy Ag Polyalkylpiperidine derivatives of s-triazines, their use as stabilizers for polymers and polymers thus stabilized
DE3240383A1 (de) 1982-11-02 1984-05-03 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von oligomeren aluminoxanen
US4937299A (en) 1983-06-06 1990-06-26 Exxon Research & Engineering Company Process and catalyst for producing reactor blend polyolefins
ZA844157B (en) 1983-06-06 1986-01-29 Exxon Research Engineering Co Process and catalyst for polyolefin density and molecular weight control
US5324800A (en) 1983-06-06 1994-06-28 Exxon Chemical Patents Inc. Process and catalyst for polyolefin density and molecular weight control
US4704491A (en) 1985-03-26 1987-11-03 Mitsui Petrochemical Industries, Ltd. Liquid ethylene-alpha-olefin random copolymer, process for production thereof, and use thereof
US4897455A (en) 1985-06-21 1990-01-30 Exxon Chemical Patents Inc. Polymerization process
CA1268754A (en) 1985-06-21 1990-05-08 Howard Curtis Welborn, Jr. Supported polymerization catalyst
US4808561A (en) 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4665208A (en) 1985-07-11 1987-05-12 Exxon Chemical Patents Inc. Process for the preparation of alumoxanes
US4701432A (en) 1985-11-15 1987-10-20 Exxon Chemical Patents Inc. Supported polymerization catalyst
US5124418A (en) 1985-11-15 1992-06-23 Exxon Chemical Patents Inc. Supported polymerization catalyst
US5055438A (en) 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
JPS63229793A (ja) 1987-03-19 1988-09-26 Fanuc Ltd レ−ザ発振器配管系の異常検出装置
JP2538588B2 (ja) * 1987-04-03 1996-09-25 三井石油化学工業株式会社 オレフイン重合用固体触媒の製法
JP2566889B2 (ja) 1987-07-13 1996-12-25 出光興産株式会社 オレフィン系重合体またはスチレン系重合体の製造方法
IL87717A0 (en) 1987-09-14 1989-02-28 Exxon Chemical Patents Inc Preparation of an active metallocene-alumoxane catalyst in situ during polymerization
EP0315234A1 (de) 1987-10-26 1989-05-10 Texas Alkyls, Inc. Verfahren zur Herstellung von Aluminoxanen
US4912075A (en) 1987-12-17 1990-03-27 Exxon Chemical Patents Inc. Method for preparing a supported metallocene-alumoxane catalyst for gas phase polymerization
US4937217A (en) 1987-12-17 1990-06-26 Exxon Chemical Patents Inc. Method for utilizing triethylaluminum to prepare an alumoxane support for an active metallocene catalyst
US4937301A (en) 1987-12-17 1990-06-26 Exxon Chemical Patents Inc. Method for preparing a supported metallocene-alumoxane catalyst for gas phase polymerization
MY103812A (en) 1988-02-12 1993-09-30 Mitsui Chemicals Inc Olefin polymerization catalyst and process for the polymerization of olefins.
US5017714A (en) 1988-03-21 1991-05-21 Exxon Chemical Patents Inc. Silicon-bridged transition metal compounds
US5120867A (en) 1988-03-21 1992-06-09 Welborn Jr Howard C Silicon-bridged transition metal compounds
US5147949A (en) 1988-03-29 1992-09-15 Exxon Chemical Patents Inc. Polymerization process using a silica gel supported metallocene-alumoxane catalyst
US5008228A (en) 1988-03-29 1991-04-16 Exxon Chemical Patents Inc. Method for preparing a silica gel supported metallocene-alumoxane catalyst
US5086025A (en) 1988-03-29 1992-02-04 Exxon Chemical Patents Inc. Method for preparing a silica gel supported metallocene-alumoxane catalyst
US4871705A (en) 1988-06-16 1989-10-03 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst
KR930002411B1 (ko) 1988-09-14 1993-03-30 미쓰이세끼유 가가꾸고오교오 가부시끼가이샤 벤젠불용성 유기알루미늄 옥시화합물 및 그 제조방법
US4914253A (en) 1988-11-04 1990-04-03 Exxon Chemical Patents Inc. Method for preparing polyethylene wax by gas phase polymerization
US5227440A (en) 1989-09-13 1993-07-13 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing Group IVB transition metal complexes with MAO: supported catalysts for olefin polymerization
US5057475A (en) 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
US5032562A (en) * 1989-12-27 1991-07-16 Mobil Oil Corporation Catalyst composition and process for polymerizing polymers having multimodal molecular weight distribution
WO1991009882A1 (en) * 1990-01-02 1991-07-11 Exxon Chemical Patents Inc. Supported ionic metallocene catalysts for olefin polymerization
PL166690B1 (pl) 1990-06-04 1995-06-30 Exxon Chemical Patents Inc Sposób wytwarzania polimerów olefin PL
ES2079330T5 (es) 1990-06-22 2005-10-01 Exxonmobil Chemical Patents Inc. Catalizadores de metaloceno de monociclopentadienilo exentos de aluminio para la polimerizacion de olefinas.
US5278272A (en) 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers
CA2098381C (en) 1991-10-15 2003-12-02 Peter N. Nickias Preparation of metal coordination complexes
DE4139262A1 (de) * 1991-11-29 1993-06-03 Basf Ag Getraegerte katalysatorsysteme zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alkenen
US5240894A (en) 1992-05-18 1993-08-31 Exxon Chemical Patents Inc. Method for making and using a supported metallocene catalyst system
US5238892A (en) 1992-06-15 1993-08-24 Exxon Chemical Patents Inc. Supported catalyst for 1-olefin(s) (co)polymerization

Also Published As

Publication number Publication date
CA2171831A1 (en) 1995-03-23
JPH09503008A (ja) 1997-03-25
WO1995007939A1 (en) 1995-03-23
DE69427095D1 (de) 2001-05-17
EP0739360B1 (de) 2001-04-11
EP0739360A1 (de) 1996-10-30
ES2160634T3 (es) 2001-11-16

Similar Documents

Publication Publication Date Title
DE69427095D1 (de) Polymerisations katalysator systeme, ihre herstellung und verwendung
DE69421411D1 (de) Polymerisationskatalysatorsysteme, ihre herstellung und verwendung
DE69421287D1 (de) Polymerisationskatalysatorsysteme, ihre herstellung und verwendung
DE69530100D1 (de) Polymerisationkatalysatorsysteme, ihre herstellung und ihre verwendung
DE69525042T2 (de) Polymerisationskatalysatorsysteme, ihre herstellung und ihre verwendung
DE69422410D1 (de) Polymerisationskataylsatoren, ihre herstellung und verwendung
DE69509403T2 (de) Polymerisation Katalysatorsysteme, ihre Herstellung und ihre Verwendung
DE69518922D1 (de) Katalysatorsysteme für die polymerisation, ihre herstellung und verwendung
FI923698A0 (fi) Katalysator anvaendbar vid polymerisation av olefiner.
FI912262A0 (fi) Pao tvenne elektrondonorer baserad katalysator foer polymerisation av olefiner.
DE69405859D1 (de) Fluorhaltige polymere, ihre herstellung und ihre verwendung
DE69408989T2 (de) Metallocen-katalysatorsysteme auf einem träger für die olefinpolymerisation, ihre herstellung und verwendung
DE9404954U1 (de) Katalysator
DE69602329D1 (de) Katalysator für ethylenische Polymerisation
DE69008454D1 (de) Nitrolsothiolderivate, ihre Herstellung und Verwendung.
DE69314784T2 (de) Flourierte polymere, ihre herstellung und verwendung
DE59409541D1 (de) Bicyclen-derivate, ihre herstellung und verwendung
DE59009740D1 (de) Vernetzte Perlpolymerisate und ihre Herstellung.
DE58908788D1 (de) Modifizierte Blockpolymerisate, ihre Herstellung und Verwendung.
FI960562A (fi) Organoaluminoksituote, katalyyttijärjestelmiä, valmistus ja käyttö
FI914001A0 (fi) Katalysator foer polymerisering av alfaolefiner innehaollande trifluorpropyl substituerade silanfoereningar.
ATE87010T1 (de) Katalysator zur regulierung der molekulargewichtsverteilung von aethylenpolymeren.
DE68908389D1 (de) Amidofluoroverbindungen, ihre herstellung und ihre verwendung.
DE69423705T2 (de) Thermoplastische Fluorsilikonharze, ihre Herstellung und Verwendung
DE59200365D1 (de) Cyclische Isolongifolanon-Ketale, ihre Herstellung und ihre Verwendung.

Legal Events

Date Code Title Description
8327 Change in the person/name/address of the patent owner

Owner name: EXXONMOBIL CHEMICAL PATENTS INC., BAYTOWN, TEX., U

8364 No opposition during term of opposition