DE69509403T2 - Polymerisation Katalysatorsysteme, ihre Herstellung und ihre Verwendung - Google Patents

Polymerisation Katalysatorsysteme, ihre Herstellung und ihre Verwendung

Info

Publication number
DE69509403T2
DE69509403T2 DE69509403T DE69509403T DE69509403T2 DE 69509403 T2 DE69509403 T2 DE 69509403T2 DE 69509403 T DE69509403 T DE 69509403T DE 69509403 T DE69509403 T DE 69509403T DE 69509403 T2 DE69509403 T2 DE 69509403T2
Authority
DE
Germany
Prior art keywords
manufacture
polymerization catalyst
catalyst systems
systems
polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69509403T
Other languages
English (en)
Other versions
DE69509403D1 (de
Inventor
Anthony Speca
Jeffrey Brinen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
ExxonMobil Chemical Patents Inc
Original Assignee
Hoechst AG
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/502,231 external-priority patent/US6124230A/en
Application filed by Hoechst AG, Exxon Chemical Patents Inc filed Critical Hoechst AG
Application granted granted Critical
Publication of DE69509403D1 publication Critical patent/DE69509403D1/de
Publication of DE69509403T2 publication Critical patent/DE69509403T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/02—Anti-static agent incorporated into the catalyst
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/61927—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
DE69509403T 1994-10-13 1995-10-12 Polymerisation Katalysatorsysteme, ihre Herstellung und ihre Verwendung Expired - Lifetime DE69509403T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US32267594A 1994-10-13 1994-10-13
US08/502,231 US6124230A (en) 1995-07-13 1995-07-13 Polymerization catalyst systems, their production and use
PCT/US1995/012789 WO1996011961A1 (en) 1994-10-13 1995-10-12 Polymerization catalyst systems, their production and use

Publications (2)

Publication Number Publication Date
DE69509403D1 DE69509403D1 (de) 1999-06-02
DE69509403T2 true DE69509403T2 (de) 1999-10-07

Family

ID=26983548

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69509403T Expired - Lifetime DE69509403T2 (de) 1994-10-13 1995-10-12 Polymerisation Katalysatorsysteme, ihre Herstellung und ihre Verwendung

Country Status (7)

Country Link
EP (1) EP0785956B1 (de)
JP (1) JPH10511706A (de)
KR (1) KR100367964B1 (de)
CN (1) CN1096470C (de)
DE (1) DE69509403T2 (de)
ES (1) ES2132744T3 (de)
WO (1) WO1996011961A1 (de)

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US6063725A (en) * 1995-11-07 2000-05-16 Mitsui Chemicals, Inc. Olefin polymerization catalyst system
US6245868B1 (en) 1998-05-29 2001-06-12 Univation Technologies Catalyst delivery method, a catalyst feeder and their use in a polymerization process
US6894131B2 (en) 1998-08-21 2005-05-17 Univation Technologies, Llc Polymerization process using a metallocene catalyst system
GB9826874D0 (en) 1998-12-07 1999-01-27 Borealis As Process
US6201076B1 (en) 1999-04-29 2001-03-13 Equistar Chemicals, L.P. Olefin polymerization process with fatty amine additives for improved activity and reduced fouling
US6476165B1 (en) 2000-03-08 2002-11-05 Equistar Chemicals, Lp Olefin polymerization process using fatty amine additives and boron-modified supported catalyst
US6593267B2 (en) 2000-12-18 2003-07-15 Univation Technologies, Llc Method for preparing a supported catalyst system and its use in a polymerization process
US6933258B2 (en) 2000-12-19 2005-08-23 Univation Technologies, L.L.C. Catalyst composition and methods for its preparation and use in a polymerization process
WO2003000790A1 (en) 2001-06-22 2003-01-03 Exxonmobil Chemical Patents, Inc. Metallocene-produced very low density polyethylenes or linear lowdensity polyethylenes as impact modifiers
EP1572761A1 (de) 2002-12-16 2005-09-14 Basell Polyolefine GmbH Herstellung unterstützter katalysatorsysteme, die einen reduzierten anteil von aluminoxanen enthält
JP4742221B2 (ja) 2003-03-21 2011-08-10 ダウ グローバル テクノロジーズ エルエルシー モルホロジー制御オレフィン重合プロセス
US7393910B2 (en) 2003-09-23 2008-07-01 Dow Global Technologies Inc. Catalyst composition for ethylene polymerization
US7422786B2 (en) 2003-09-24 2008-09-09 Exxonmobil Chemical Patents Inc. Collation shrink
US7632086B2 (en) 2003-10-03 2009-12-15 Exxonmobil Chemical Patents Inc. Melt fracture reduction
US7183005B2 (en) 2004-08-20 2007-02-27 Exxonmobil Chemical Patents Inc. Impact strength improvement of regrind
US7919569B2 (en) 2005-06-07 2011-04-05 Saudi Basic Industries Corporation Process for the polymerizaion of olefins
EP1731535A1 (de) * 2005-06-07 2006-12-13 Saudi Basic Industries Corporation Inc. Verfahren zur Olefin-Polymerisation
JP4732087B2 (ja) * 2005-09-13 2011-07-27 三井化学株式会社 オレフィン重合触媒用担体、オレフィン重合触媒およびオレフィン系重合体粒子
WO2007130277A1 (en) 2006-05-05 2007-11-15 Exxonmobil Chemical Patents Inc. Linear low density polymer blends and articles made therefrom
WO2008018976A1 (en) 2006-08-04 2008-02-14 Univation Technologies, Llc Method of maintaining heat transfer capacity in a polymerization reaction system
US8198373B2 (en) 2006-10-02 2012-06-12 Exxonmobil Chemical Patents Inc. Plastic toughened plastics
US7985804B2 (en) 2006-11-06 2011-07-26 Exxonmobil Chemical Patents Inc. Rubber toughened compositions, articles, films, and methods of making the same
BRPI0605781A (pt) 2006-12-29 2008-08-19 Braskem Sa composição anti-estática para polimerização ou copolimerização de olefinas em fase gás, processo de polimerização ou copolimerização de olefinas em fase gás, e, polìmero ou copolìmero de olefina assim obtido
EP1995259B2 (de) † 2007-05-25 2014-01-01 Borealis Technology Oy Herstellungsverfahren für ein Alpha-Olefin-Polymerharz
ES2401040T3 (es) 2007-08-16 2013-04-16 Univation Technologies, Llc Aditivos de continuidad y su uso en procesos de polimerización
US8206654B2 (en) 2008-01-07 2012-06-26 Univation Technologies, Llc Catalyst feed systems and methods for using the same
WO2010080871A1 (en) 2009-01-08 2010-07-15 Univation Technologies, Llc Additive for gas phase polymerization processes
RU2527945C2 (ru) 2009-01-08 2014-09-10 Юнивейшн Текнолоджиз, Ллк Добавка для процессов полимеризации полиолефинов
EP2576642B1 (de) * 2010-05-28 2017-08-16 Basell Polyolefine GmbH Verfahren zur herstellung eines geträgerten katalysatorsystems zur olefinpolymerisation, katalysatorsystem und seine verwendung
MY161763A (en) 2010-11-30 2017-05-15 Univation Tech Llc Catalyst composition having improved flow characteristics and methods of making and using the same
BR112013012741B1 (pt) 2010-11-30 2020-04-28 Univation Tech Llc processo de polimerização
ES2640318T3 (es) 2010-12-22 2017-11-02 Univation Technologies, Llc Aditivo para procedimientos de polimerización de olefinas
EP2610269A1 (de) 2011-12-28 2013-07-03 Saudi Basic Industries Corporation Katalysatorzusammensetzung und Herstellungsverfahren dafür
CN104918947A (zh) 2012-12-28 2015-09-16 尤尼威蒂恩技术有限责任公司 将铝氧烷的生产整合到催化剂生产中的方法
BR112015016824B1 (pt) 2013-01-14 2020-10-06 Univation Technologies, Llc. Método para produzir um sistema catalítico e processo de polimerização
CN105189566A (zh) 2013-01-30 2015-12-23 尤尼威蒂恩技术有限责任公司 制造具有改进的流动的催化剂组合物的方法
CA2933157C (en) 2013-12-09 2021-11-16 Univation Technologies, Llc Feeding polymerization additives to polymerization processes
BR112016022780B1 (pt) 2014-04-02 2021-08-17 Univation Technologies, Llc Composição de continuidade
EP3145717A1 (de) 2014-05-20 2017-03-29 E. I. du Pont de Nemours and Company Feinschrumpffolienschutzstruktur
WO2016094281A1 (en) 2014-12-11 2016-06-16 E. I. Du Pont De Nemours And Company Stretch wrapping film
US10414843B2 (en) 2015-03-10 2019-09-17 Univation Technologies, Llc Spray dried catalyst compositions, methods for preparation and use in olefin polymerization processes
SG11201708626SA (en) 2015-04-27 2017-11-29 Univation Tech Llc Supported catalyst compositions having improved flow properties and preparation thereof
KR102035310B1 (ko) * 2015-06-26 2019-10-22 주식회사 엘지화학 폴리올레핀 제조용 촉매 시스템 및 폴리올레핀의 제조방법
KR102569384B1 (ko) * 2016-04-01 2023-08-23 주식회사 레이크머티리얼즈 올레핀 중합용 담지촉매의 제조방법
CN107987191B (zh) * 2016-10-26 2021-03-16 中国石油化工股份有限公司 一种负载型茂金属催化剂及其制备方法和应用
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KR102153777B1 (ko) * 2017-09-11 2020-09-08 주식회사 엘지화학 미량의 대전방지제의 정량분석방법
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Also Published As

Publication number Publication date
CN1096470C (zh) 2002-12-18
EP0785956A1 (de) 1997-07-30
EP0785956B1 (de) 1999-04-28
WO1996011961A1 (en) 1996-04-25
ES2132744T3 (es) 1999-08-16
JPH10511706A (ja) 1998-11-10
KR100367964B1 (ko) 2003-04-26
CN1164861A (zh) 1997-11-12
DE69509403D1 (de) 1999-06-02
KR970706317A (ko) 1997-11-03

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