DE69525042D1 - Polymerisationskatalysatorsysteme, ihre herstellung und ihre verwendung - Google Patents
Polymerisationskatalysatorsysteme, ihre herstellung und ihre verwendungInfo
- Publication number
- DE69525042D1 DE69525042D1 DE69525042T DE69525042T DE69525042D1 DE 69525042 D1 DE69525042 D1 DE 69525042D1 DE 69525042 T DE69525042 T DE 69525042T DE 69525042 T DE69525042 T DE 69525042T DE 69525042 D1 DE69525042 D1 DE 69525042D1
- Authority
- DE
- Germany
- Prior art keywords
- production
- polymerization catalyst
- catalyst systems
- systems
- polymerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US19580694A | 1994-02-14 | 1994-02-14 | |
US195806 | 1994-02-14 | ||
PCT/US1995/001763 WO1995021874A1 (en) | 1994-02-11 | 1995-02-13 | Polymerization catalyst systems, their production and use |
Publications (3)
Publication Number | Publication Date |
---|---|
DE69525042D1 true DE69525042D1 (de) | 2002-02-21 |
DE69525042T2 DE69525042T2 (de) | 2002-08-14 |
DE69525042T3 DE69525042T3 (de) | 2005-10-20 |
Family
ID=22722886
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69525042T Expired - Fee Related DE69525042T3 (de) | 1994-02-14 | 1995-02-13 | Polymerisationskatalysatorsysteme, ihre herstellung und ihre verwendung |
Country Status (7)
Country | Link |
---|---|
US (1) | US5639835A (de) |
EP (1) | EP0746574B2 (de) |
JP (1) | JP3553957B2 (de) |
CA (1) | CA2183102C (de) |
DE (1) | DE69525042T3 (de) |
ES (1) | ES2171184T5 (de) |
WO (1) | WO1995021874A1 (de) |
Families Citing this family (53)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19622481A1 (de) * | 1996-06-05 | 1997-12-11 | Hoechst Ag | Geträgertes Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen |
GB9613814D0 (en) * | 1996-07-02 | 1996-09-04 | Bp Chem Int Ltd | Supported polymerisation catalysts |
WO2004094487A1 (en) | 2003-03-21 | 2004-11-04 | Dow Global Technologies, Inc. | Morphology controlled olefin polymerization process |
US6953764B2 (en) | 2003-05-02 | 2005-10-11 | Dow Global Technologies Inc. | High activity olefin polymerization catalyst and process |
US7119153B2 (en) * | 2004-01-21 | 2006-10-10 | Jensen Michael D | Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength |
US7582711B2 (en) | 2005-03-04 | 2009-09-01 | Univation Technologies, Llc | Ziegler-type catalysts having increased productivity |
US20070049711A1 (en) | 2005-09-01 | 2007-03-01 | Chi-I Kuo | Catalyst compositions comprising support materials having an improved particle-size distribution |
EP1803747A1 (de) | 2005-12-30 | 2007-07-04 | Borealis Technology Oy | Oberflächemodifizierte Polymerisationskatalysatoren zur Herstellung von Polyolefinfilmen mit niedrigem Gelgehalt |
RU2008147906A (ru) | 2006-05-05 | 2010-06-10 | Дау Глобал Текнолоджиз Инк. (Us) | Комплексы гафния с замещенными карбазолилом имидазольными лигандами |
TW200932762A (en) | 2007-10-22 | 2009-08-01 | Univation Tech Llc | Polyethylene compositions having improved properties |
TW200936619A (en) | 2007-11-15 | 2009-09-01 | Univation Tech Llc | Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom |
US20110256632A1 (en) | 2009-01-08 | 2011-10-20 | Univation Technologies, Llc | Additive for Polyolefin Polymerization Processes |
WO2010080871A1 (en) | 2009-01-08 | 2010-07-15 | Univation Technologies, Llc | Additive for gas phase polymerization processes |
US8586685B2 (en) | 2009-07-23 | 2013-11-19 | Univation Technologies, Llc | Polymerization reaction system |
ES2543635T3 (es) | 2010-02-18 | 2015-08-20 | Univation Technologies, Llc | Métodos para operación de un reactor de polimerización |
ES2693720T3 (es) | 2010-02-22 | 2018-12-13 | Univation Technologies, Llc | Sistemas catalíticos y métodos para usar los mismos para producir productos poliolefínicos |
MY157091A (en) | 2010-04-13 | 2016-04-29 | Univation Tech Llc | Polymer blends and films made therefrom |
WO2012009215A1 (en) | 2010-07-16 | 2012-01-19 | Univation Technologies, Llc | Systems and methods for measuring static charge on particulates |
CN103097015B (zh) | 2010-07-16 | 2015-11-25 | 尤尼威蒂恩技术有限责任公司 | 测量反应器表面上颗粒积聚的系统与方法 |
WO2012015898A1 (en) | 2010-07-28 | 2012-02-02 | Univation Technologies, Llc | Systems and methods for measuring velocity of a particle/fluid mixture |
EP2651982B1 (de) | 2010-12-17 | 2018-04-11 | Univation Technologies, LLC | Systeme und verfahren zur rückgewinnung von kohlenwasserstoffen aus einem polyolefinspülgasprodukt |
WO2012087560A1 (en) | 2010-12-22 | 2012-06-28 | Univation Technologies, Llc | Additive for polyolefin polymerization processes |
WO2012097146A1 (en) | 2011-01-14 | 2012-07-19 | W. R. Grace & Co.-Conn. | Process of making modified metallocene catalyst, catalyst produced and use thereof |
WO2013028283A1 (en) | 2011-08-19 | 2013-02-28 | Univation Technologies, Llc | Catalyst systems and methods for using same to produce polyolefin products |
US9181371B2 (en) | 2011-11-08 | 2015-11-10 | Univation Technologies, Llc | Methods for producing polyolefins with catalyst systems |
JP6181672B2 (ja) | 2012-03-05 | 2017-08-16 | ユニベーション・テクノロジーズ・エルエルシー | 触媒組成物の製造方法及びそれから製造される重合体生成物 |
US9695254B2 (en) | 2012-11-26 | 2017-07-04 | Braskem S.A. | Metallocene catalyst supported by hybrid supporting means, process for producing same, polymerization process for producing an ethylene homopolymer or copolymer with broad or bimodal molar mass distribution, use of the supported metallocene catalyst and ethylene polymer with broad or bimodal molar mass distribution |
CA2800056A1 (en) | 2012-12-24 | 2014-06-24 | Nova Chemicals Corporation | Polyethylene blend compositions |
ES2918582T3 (es) | 2012-12-28 | 2022-07-19 | Univation Tech Llc | Catalizador soportado con fluidez mejorada |
BR112015018639B1 (pt) | 2013-02-07 | 2021-11-03 | Univation Technologies, Llc | Método para formar partículas de resina |
EP2970524B1 (de) | 2013-03-15 | 2018-03-07 | Univation Technologies, LLC | Dreizahnige stickstoffliganden für olefinpolymerisationskatalysatoren |
US9718900B2 (en) | 2013-03-15 | 2017-08-01 | Univation Technologies, Llc | Ligands for catalysts |
CN105308007B (zh) | 2013-06-05 | 2017-07-21 | 尤尼威蒂恩技术有限责任公司 | 保护酚基 |
BR112017003306B1 (pt) | 2014-08-19 | 2022-03-03 | Univation Technologies, Llc | Método para preparar um suporte de catalisador fluorado e sistema de catalisador |
BR112017003314A2 (pt) | 2014-08-19 | 2018-01-23 | Univation Tech Llc | suportes de catalisador fluorados e sistemas de catalisador |
SG11201701260WA (en) | 2014-08-19 | 2017-03-30 | Univation Tech Llc | Fluorinated catalyst supports and catalyst systems |
EP3247547B1 (de) | 2015-01-21 | 2023-03-22 | Univation Technologies, LLC | Verfahren zur gelverminderung in polyolefinen |
US10471641B2 (en) | 2015-01-21 | 2019-11-12 | Univation Technologies, Llc | Methods for controlling polymer chain scission |
CA2985112C (en) | 2015-05-08 | 2020-06-30 | Exxonmobil Chemical Patents Inc. | Polymerization process comprising 2,2-dimethylpropane as condensing agent |
WO2018063764A1 (en) | 2016-09-27 | 2018-04-05 | Exxonmobil Chemical Patents Inc. | Polymerization process |
WO2018063767A1 (en) | 2016-09-27 | 2018-04-05 | Exxonmobil Chemical Patents Inc. | Polymerization process |
CN109983039B (zh) | 2016-09-27 | 2022-02-18 | 尤尼威蒂恩技术有限责任公司 | 用于聚乙烯生产中长链支化控制的方法 |
WO2018063765A1 (en) | 2016-09-27 | 2018-04-05 | Exxonmobil Chemical Patents Inc. | Polymerization process |
WO2018118155A1 (en) | 2016-12-20 | 2018-06-28 | Exxonmobil Chemical Patents Inc. | Polymerization process |
WO2018147931A1 (en) | 2017-02-07 | 2018-08-16 | Exxonmobil Chemical Patents Inc. | Processes for reducing the loss of catalyst activity of a ziegler-natta catalyst |
US11193008B2 (en) | 2017-04-10 | 2021-12-07 | Exxonmobil Chemical Patents Inc. | Methods for making polyolefin polymer compositions |
ES2939177T3 (es) | 2017-05-10 | 2023-04-19 | Univation Tech Llc | Sistemas catalizadores y procesos para usar los mismos |
US11591417B2 (en) | 2017-12-13 | 2023-02-28 | Exxonmobil Chemical Patents Inc. | Deactivation methods for active components from gas phase polyolefin polymerization processes |
WO2019173030A1 (en) | 2018-03-08 | 2019-09-12 | Exxonmobil Chemical Patents Inc. | Methods of preparing and monitoring a seed bed for polymerization reactor startup |
EP3788082A1 (de) | 2018-05-02 | 2021-03-10 | ExxonMobil Chemical Patents Inc. | Verfahren zur aufskalierung von einer pilotanlage zu einer grösseren produktionsanlage |
CN112055719B (zh) | 2018-05-02 | 2022-11-25 | 埃克森美孚化学专利公司 | 从中试装置放大到较大生产设施的方法 |
CN116234837A (zh) | 2020-07-22 | 2023-06-06 | 埃克森美孚化学专利公司 | 聚烯烃组合物及其制品 |
EP4259669A1 (de) | 2020-12-08 | 2023-10-18 | ExxonMobil Chemical Patents Inc. | Hochdichte polyethylenzusammensetzungen mit langkettiger verzweigung |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ZA844157B (en) † | 1983-06-06 | 1986-01-29 | Exxon Research Engineering Co | Process and catalyst for polyolefin density and molecular weight control |
CA1268754A (en) † | 1985-06-21 | 1990-05-08 | Howard Curtis Welborn, Jr. | Supported polymerization catalyst |
US4808561A (en) * | 1985-06-21 | 1989-02-28 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
US4659685A (en) * | 1986-03-17 | 1987-04-21 | The Dow Chemical Company | Heterogeneous organometallic catalysts containing a supported titanium compound and at least one other supported organometallic compound |
US5241025A (en) * | 1987-01-30 | 1993-08-31 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
US5008228A (en) * | 1988-03-29 | 1991-04-16 | Exxon Chemical Patents Inc. | Method for preparing a silica gel supported metallocene-alumoxane catalyst |
US4871705A (en) * | 1988-06-16 | 1989-10-03 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst |
US5064802A (en) * | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
DE69114087T2 (de) * | 1990-08-21 | 1996-04-11 | Nippon Oil Co Ltd | Polyolefine. |
DE4121368A1 (de) * | 1991-06-28 | 1993-01-07 | Hoechst Ag | Katalysator und verfahren zur herstellung von hochmolekularen polyolefinen |
AU657589B2 (en) * | 1991-11-07 | 1995-03-16 | Exxon Chemical Patents Inc. | Process for producing polyolefin |
US5162466A (en) * | 1991-12-31 | 1992-11-10 | Union Carbide Chemicals & Plastics Technology Corporation | Use of methylene-bridged derivatives of cyclopentadienyl dicarbollide complexes of titanium, zirconium and hafnium as polymerization catalysts |
US5214173A (en) * | 1991-12-31 | 1993-05-25 | The University Of Iowa Research Foundation | Cyclopentadienyl dicarbollide complexes of titanium, zirconium and hafnium |
-
1995
- 1995-02-13 DE DE69525042T patent/DE69525042T3/de not_active Expired - Fee Related
- 1995-02-13 WO PCT/US1995/001763 patent/WO1995021874A1/en active IP Right Grant
- 1995-02-13 CA CA002183102A patent/CA2183102C/en not_active Expired - Fee Related
- 1995-02-13 JP JP52137995A patent/JP3553957B2/ja not_active Expired - Fee Related
- 1995-02-13 ES ES95909537T patent/ES2171184T5/es not_active Expired - Lifetime
- 1995-02-13 EP EP95909537A patent/EP0746574B2/de not_active Expired - Lifetime
- 1995-09-11 US US08/526,241 patent/US5639835A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
DE69525042T2 (de) | 2002-08-14 |
DE69525042T3 (de) | 2005-10-20 |
JPH09508935A (ja) | 1997-09-09 |
CA2183102A1 (en) | 1995-08-17 |
WO1995021874A1 (en) | 1995-08-17 |
ES2171184T5 (es) | 2005-09-16 |
EP0746574A1 (de) | 1996-12-11 |
US5639835A (en) | 1997-06-17 |
ES2171184T3 (es) | 2002-09-01 |
EP0746574B2 (de) | 2005-04-13 |
CA2183102C (en) | 2005-08-23 |
JP3553957B2 (ja) | 2004-08-11 |
EP0746574B1 (de) | 2002-01-16 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
DE69530100D1 (de) | Polymerisationkatalysatorsysteme, ihre herstellung und ihre verwendung | |
DE69525042T2 (de) | Polymerisationskatalysatorsysteme, ihre herstellung und ihre verwendung | |
DE69421411D1 (de) | Polymerisationskatalysatorsysteme, ihre herstellung und verwendung | |
DE69421287T2 (de) | Polymerisationskatalysatorsysteme, ihre herstellung und verwendung | |
DE69509403T2 (de) | Polymerisation Katalysatorsysteme, ihre Herstellung und ihre Verwendung | |
DE69422410T2 (de) | Polymerisationskataylsatoren, ihre herstellung und verwendung | |
DE69518922D1 (de) | Katalysatorsysteme für die polymerisation, ihre herstellung und verwendung | |
ATE233790T1 (de) | Geträgerter katalysatorbestandteil, trägerkatalysator, herstellungsverfahren, polymerisationsverfahren, komplexverbindungen und ihre herstellung | |
DE69405859D1 (de) | Fluorhaltige polymere, ihre herstellung und ihre verwendung | |
DE69529026D1 (de) | Trehalose, ihre Herstellung und ihre Verwendung | |
DE69223476D1 (de) | Cermets, ihre Herstellung und Verwendung | |
FI952359A (fi) | Metalloseenikatalyyttisysteemit, niiden valmistaminen ja käyttö | |
ATE239693T1 (de) | 3,3-diarylpropylamine , ihre verwendung und herstellung | |
DE59709806D1 (de) | Cycloolefincopolymere, ihre verwendung und daraus hergestellte formkörper | |
DE69427095D1 (de) | Polymerisations katalysator systeme, ihre herstellung und verwendung | |
DE69625857D1 (de) | Siliconderivate, ihre Herstellung und Verwendung | |
DE59800590D1 (de) | Polymere organosiliciumverbindungen, deren herstellung und verwendung | |
DE69314784D1 (de) | Flourierte polymere, ihre herstellung und verwendung | |
DE69521595D1 (de) | Optisch-aktives Benzothiepin-Derivate, ihre Herstellung und Verwendung | |
DE59409541D1 (de) | Bicyclen-derivate, ihre herstellung und verwendung | |
DE69608477T2 (de) | Organoaluminoxyprodukt, Katalysatorsystem, deren Herstellung und Verwendung | |
DE58908788D1 (de) | Modifizierte Blockpolymerisate, ihre Herstellung und Verwendung. | |
DE69723463D1 (de) | Cyclische organoselenderivate, ihre herstellung und verwendung | |
DE59606806D1 (de) | Polymerholz-formkörper, ihre herstellung und verwendung | |
ATE310741T1 (de) | Organozinnkatalysator, herstellung und verwendung |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
8363 | Opposition against the patent | ||
8327 | Change in the person/name/address of the patent owner |
Owner name: UNIVATION TECHNOLOGIES, LLC, HOUSTON, TEX., US |
|
8366 | Restricted maintained after opposition proceedings | ||
8339 | Ceased/non-payment of the annual fee |