DE69833571D1 - Polymerisationskatalysatorsysteme, deren verwendung, deren produkte und gegenstände - Google Patents

Polymerisationskatalysatorsysteme, deren verwendung, deren produkte und gegenstände

Info

Publication number
DE69833571D1
DE69833571D1 DE69833571T DE69833571T DE69833571D1 DE 69833571 D1 DE69833571 D1 DE 69833571D1 DE 69833571 T DE69833571 T DE 69833571T DE 69833571 T DE69833571 T DE 69833571T DE 69833571 D1 DE69833571 D1 DE 69833571D1
Authority
DE
Germany
Prior art keywords
objects
products
polymerization catalyst
catalyst systems
systems
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69833571T
Other languages
English (en)
Other versions
DE69833571T2 (de
Inventor
Olukayode Jejelowo
Sun-Chueh Kao
R Loveday
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Univation Technologies LLC
Original Assignee
Univation Technologies LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univation Technologies LLC filed Critical Univation Technologies LLC
Application granted granted Critical
Publication of DE69833571D1 publication Critical patent/DE69833571D1/de
Publication of DE69833571T2 publication Critical patent/DE69833571T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14Monomers containing five or more carbon atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/01Additive used together with the catalyst, excluding compounds containing Al or B
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65904Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04Homopolymers or copolymers of ethene
    • C08J2323/08Copolymers of ethene
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901Monomer polymerized in vapor state in presence of transition metal containing catalyst
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
DE69833571T 1997-12-08 1998-12-08 Polymerisationskatalysatorsysteme, deren Verwendung, deren Produkte und Gegenstände Expired - Lifetime DE69833571T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US986696 1997-12-08
US08/986,696 US6242545B1 (en) 1997-12-08 1997-12-08 Polymerization catalyst systems comprising substituted hafinocenes
PCT/US1998/025977 WO1999029737A1 (en) 1997-12-08 1998-12-08 Polymerization catalyst systems, their use, their products and articles thereof

Publications (2)

Publication Number Publication Date
DE69833571D1 true DE69833571D1 (de) 2006-04-27
DE69833571T2 DE69833571T2 (de) 2006-10-05

Family

ID=25532662

Family Applications (2)

Application Number Title Priority Date Filing Date
DE69833571T Expired - Lifetime DE69833571T2 (de) 1997-12-08 1998-12-08 Polymerisationskatalysatorsysteme, deren Verwendung, deren Produkte und Gegenstände
DE69839198T Expired - Lifetime DE69839198T2 (de) 1997-12-08 1998-12-08 Ein Ethylen-alpha-Olefin Copolymer und daraus hergestellter Film

Family Applications After (1)

Application Number Title Priority Date Filing Date
DE69839198T Expired - Lifetime DE69839198T2 (de) 1997-12-08 1998-12-08 Ein Ethylen-alpha-Olefin Copolymer und daraus hergestellter Film

Country Status (9)

Country Link
US (11) US6242545B1 (de)
EP (2) EP1518868B1 (de)
JP (2) JP2001525457A (de)
AU (1) AU743364B2 (de)
BR (1) BR9813438B1 (de)
CA (1) CA2313215C (de)
DE (2) DE69833571T2 (de)
ES (2) ES2301918T3 (de)
WO (1) WO1999029737A1 (de)

Families Citing this family (213)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8497330B2 (en) * 1997-12-08 2013-07-30 Univation Technologies, Llc Methods for polymerization using spray dried and slurried catalyst
US6242545B1 (en) * 1997-12-08 2001-06-05 Univation Technologies Polymerization catalyst systems comprising substituted hafinocenes
US20060293470A1 (en) * 2005-06-28 2006-12-28 Cao Phuong A Polymerization process using spray-dried catalyst
US6894131B2 (en) * 1998-08-21 2005-05-17 Univation Technologies, Llc Polymerization process using a metallocene catalyst system
CN1184242C (zh) * 1999-10-22 2005-01-12 尤尼威蒂恩技术有限责任公司 催化剂体系及其在聚合反应方法中的应用
US6632911B1 (en) * 1999-11-05 2003-10-14 Japan Polychem Corporation Ethylene/α-olefin copolymer and film made thereof
BR0112383A (pt) * 2000-06-22 2003-12-30 Exxonmobil Chem Patents Inc Misturas de polietileno de densidade muito baixa
US6932592B2 (en) 2000-06-22 2005-08-23 Exxonmobil Chemical Patents Inc. Metallocene-produced very low density polyethylenes
CN1527848A (zh) * 2000-12-06 2004-09-08 ��Ī���Ǽ����������ι�˾ 可熔融加工的耐磨聚乙烯
US20020107343A1 (en) * 2001-02-08 2002-08-08 Mitsui Chemicals, Inc. Ethylene polymer, preparation process thereof and molded articles of the same
JP4000062B2 (ja) * 2001-04-23 2007-10-31 エクソンモービル・ケミカル・パテンツ・インク 電線及びケーブルに用いるためのepdmとメタロセンプラストマーのブレンド
EP1927617A1 (de) 2001-07-19 2008-06-04 Univation Technologies, LLC Polyethylenfolien mit verbesserten physikalischen Eigenschaften
US6936675B2 (en) * 2001-07-19 2005-08-30 Univation Technologies, Llc High tear films from hafnocene catalyzed polyethylenes
ES2361734T3 (es) * 2001-07-19 2011-06-21 Univation Technologies Llc Películas de polietileno con propiedades físicas mejoradas.
EP1338611A1 (de) * 2002-02-22 2003-08-27 Tim Dr. Bast Additiv zur Verbesserung der Leistungsfähigkeit von Polymerisationskatalysatoren
EP1403288A1 (de) * 2002-09-27 2004-03-31 ATOFINA Research Hafnocenverbindungen enthaltendes Dual-site Katalysatorsystem zur Herstellung von bimodalen Polyolefinen
CA2499951C (en) 2002-10-15 2013-05-28 Peijun Jiang Multiple catalyst system for olefin polymerization and polymers produced therefrom
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US7119153B2 (en) * 2004-01-21 2006-10-10 Jensen Michael D Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength
US20050182210A1 (en) 2004-02-17 2005-08-18 Natarajan Muruganandam De-foaming spray dried catalyst slurries
AU2004200897B2 (en) * 2004-03-01 2012-01-12 Universal Entertainment Corporation Gaming machine
US7598328B2 (en) * 2004-04-07 2009-10-06 Dow Global Technologies, Inc. Supported catalysts for manufacture of polymers
US7754830B2 (en) 2004-05-20 2010-07-13 Univation Technologies, Llc Polymerization reaction monitoring with determination of induced condensing agent concentration for preventing discontinuity events
US7683140B2 (en) * 2004-05-20 2010-03-23 Univation Technologies, Llc Method for determining temperature value indicative of resin stickiness from data generated by polymerization reaction monitoring
US7157531B2 (en) * 2004-06-21 2007-01-02 Univation Technologies, Llc Methods for producing polymers with control over composition distribution
US8202940B2 (en) 2004-08-19 2012-06-19 Univation Technologies, Llc Bimodal polyethylene compositions for blow molding applications
US7868092B2 (en) 2005-06-14 2011-01-11 Univation Technologies, Llc Bimodal polyethylene compositions for blow molding applications
GB0423212D0 (en) * 2004-10-19 2004-11-24 Borealis Tech Oy Polymer
TW200631965A (en) * 2004-12-07 2006-09-16 Fina Technology Random copolymers and formulations useful for thermoforming and blow molding applications
US20060247394A1 (en) * 2005-04-29 2006-11-02 Fina Technology, Inc. Process for increasing ethylene incorporation into random copolymers
US7220806B2 (en) * 2005-04-29 2007-05-22 Fina Technology, Inc. Process for increasing ethylene incorporation into random copolymers
US7645834B2 (en) * 2005-04-29 2010-01-12 Fina Technologies, Inc. Catalyst system for production of polyolefins
US7081285B1 (en) 2005-04-29 2006-07-25 Fina Technology, Inc. Polyethylene useful for blown films and blow molding
US7858702B2 (en) 2005-06-14 2010-12-28 Univation Technologies, Llc Enhanced ESCR bimodal HDPE for blow molding applications
US7078467B1 (en) * 2005-06-14 2006-07-18 Univation Technologies, Llc Single catalyst low, medium and high density polyethylenes
US7282546B2 (en) * 2005-06-22 2007-10-16 Fina Technology, Inc. Cocatalysts for reduction of production problems in metallocene-catalyzed polymerizations
US7323526B2 (en) * 2005-07-29 2008-01-29 Univation Technologies, Llc Supported metallocene-alkyl catalyst composition
US20070299222A1 (en) 2006-04-04 2007-12-27 Fina Technology, Inc. Transition metal catalysts and formation thereof
US7683002B2 (en) 2006-04-04 2010-03-23 Fina Technology, Inc. Transition metal catalyst and formation thereof
US20070235896A1 (en) * 2006-04-06 2007-10-11 Fina Technology, Inc. High shrink high modulus biaxially oriented films
US8247065B2 (en) * 2006-05-31 2012-08-21 Exxonmobil Chemical Patents Inc. Linear polymers, polymer blends, and articles made therefrom
CN101472964B (zh) 2006-06-27 2012-09-05 尤尼威蒂恩技术有限责任公司 使用茂金属催化剂的改进聚合方法、其聚合产物及最终用途
MX2009000270A (es) 2006-06-27 2009-02-17 Univation Tech Llc Copolimeros de etileno-alfa olefina y procesos de polimerizacion para hacerlos.
BRPI0712945B1 (pt) 2006-06-27 2018-05-08 Univation Tech Llc Processo para a produção de um Copolímero de Etileno Alfa- Olefina
US20080051538A1 (en) * 2006-07-11 2008-02-28 Fina Technology, Inc. Bimodal pipe resin and products made therefrom
US7449529B2 (en) * 2006-07-11 2008-11-11 Fina Technology, Inc. Bimodal blow molding resin and products made therefrom
US7893181B2 (en) * 2006-07-11 2011-02-22 Fina Technology, Inc. Bimodal film resin and products made therefrom
US7514510B2 (en) 2006-07-25 2009-04-07 Fina Technology, Inc. Fluorenyl catalyst compositions and olefin polymerization process
US7470759B2 (en) * 2006-07-31 2008-12-30 Fina Technology, Inc. Isotactic-atactic polypropylene and methods of making same
BRPI0716245B1 (pt) * 2006-09-07 2018-07-31 Univation Technologies, Llc Método para determinação do valor da temperatura, indicativo de pegajosidade de resina, a partir de dados gerados por monitoração da reação de polimerização
JP2010502812A (ja) * 2006-09-07 2010-01-28 ユニベーション・テクノロジーズ・エルエルシー 溶融開始温度の降下に対するモデルを用いた樹脂粘着性の程度のオンライン決定のための方法
US20080061468A1 (en) * 2006-09-07 2008-03-13 Frank Li Fiber processing of high ethylene level propylene-ethylene random copolymers by use of nucleators
US7538167B2 (en) * 2006-10-23 2009-05-26 Fina Technology, Inc. Syndiotactic polypropylene and methods of preparing same
US20080114130A1 (en) * 2006-11-10 2008-05-15 John Ashbaugh Resin composition for production of high tenacity slit film, monofilaments and fibers
JP5341770B2 (ja) 2006-12-15 2013-11-13 フイナ・テクノロジー・インコーポレーテツド ポリプロピレンインフレーションフィルム
WO2008076386A1 (en) * 2006-12-18 2008-06-26 Univation Technologies, Llc Method for reducing and/or preventing production of excessively low density polymer product during polymerization transitions
KR20090094003A (ko) * 2006-12-29 2009-09-02 피나 테크놀러지, 인코포레이티드 폴리프로필렌 필름 등급 수지를 제조하기 위해 n-부틸메틸디메톡시실란을 사용하는 숙시네이트 함유 중합 촉매 시스템
TWI404730B (zh) 2007-02-05 2013-08-11 Univation Tech Llc 控制聚合物性質之方法
JP2009040894A (ja) * 2007-08-09 2009-02-26 Tosoh Corp エチレン系重合体およびそれよりなるフィルム
TW200932762A (en) * 2007-10-22 2009-08-01 Univation Tech Llc Polyethylene compositions having improved properties
TW200936619A (en) 2007-11-15 2009-09-01 Univation Tech Llc Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom
US20090156764A1 (en) * 2007-12-18 2009-06-18 Malakoff Alan M Ethylene-Based Polymers and Articles Made Therefrom
WO2009082546A2 (en) 2007-12-18 2009-07-02 Exxonmobil Chemical Patents Inc. Polyethylene films and process for production thereof
US20090297810A1 (en) * 2008-05-30 2009-12-03 Fiscus David M Polyethylene Films and Process for Production Thereof
US8507103B2 (en) 2007-12-18 2013-08-13 Exxonmobil Chemical Patents Inc. Polyethylene and process for production thereof
US8436114B2 (en) 2010-10-21 2013-05-07 Exxonmobil Chemical Patents Inc. Polyethylene and process for production thereof
US8431661B2 (en) 2010-10-21 2013-04-30 Exxonmobil Chemical Patents Inc. Polyethylene and process for production thereof
US8765874B2 (en) * 2008-01-28 2014-07-01 Exxonmobil Chemical Patents Inc. Ethylene based polymers and articles made therefrom
US8859084B2 (en) * 2008-01-29 2014-10-14 Fina Technology, Inc. Modifiers for oriented polypropylene
CN101778707B (zh) 2008-01-29 2014-05-21 陶氏环球技术有限责任公司 聚乙烯组合物、制备聚乙烯组合物的方法、由聚乙烯组合物制造的制品和制造制品的方法
US8003741B2 (en) 2008-02-07 2011-08-23 Fina Technology, Inc. Ziegler-Natta catalyst
US20090202770A1 (en) * 2008-02-08 2009-08-13 Fengkui Li Polypropylene/polyisobutylene blends and films prepared from same
US7740070B2 (en) * 2008-06-16 2010-06-22 Halliburton Energy Services, Inc. Wellbore servicing compositions comprising a density segregation inhibiting composite and methods of making and using same
US8399725B2 (en) * 2008-06-20 2013-03-19 Exxonmobil Chemical Patents Inc. Functionalized high vinyl terminated propylene based oligomers
US8372930B2 (en) * 2008-06-20 2013-02-12 Exxonmobil Chemical Patents Inc. High vinyl terminated propylene based oligomers
US8268913B2 (en) * 2008-06-30 2012-09-18 Fina Technology, Inc. Polymeric blends and methods of using same
US8545971B2 (en) * 2008-06-30 2013-10-01 Fina Technology, Inc. Polymeric compositions comprising polylactic acid and methods of making and using same
US8759446B2 (en) 2008-06-30 2014-06-24 Fina Technology, Inc. Compatibilized polypropylene and polylactic acid blends and methods of making and using same
MX2010004504A (es) * 2008-07-10 2010-05-17 Dow Global Technologies Inc Composiciones de polietileno, metodo de produccion de las mismas, fibras elaboradas de las mismas y metodo para elaborar las mismas.
US9334342B2 (en) 2008-10-01 2016-05-10 Fina Technology, Inc. Polypropylene for reduced plate out in polymer article production processes
US20100087602A1 (en) * 2008-10-08 2010-04-08 Fina Technology, Inc. Long chain branched polypropylene for cast film applications
US8715813B2 (en) * 2008-10-23 2014-05-06 Exxonmobil Chemical Patents Inc. High MIR linear polyethylenes and coextruded films therefrom
US8022154B2 (en) * 2008-11-06 2011-09-20 Exxonmobil Chemical Patents Inc. Ethylene polymers, their production and use
US8653198B2 (en) 2009-03-26 2014-02-18 Fina Technology, Inc. Method for the preparation of a heterophasic copolymer and uses thereof
US9090000B2 (en) 2009-03-26 2015-07-28 Fina Technology, Inc. Injection stretch blow molded articles and random copolymers for use therein
US20100247887A1 (en) 2009-03-26 2010-09-30 Fina Technology, Inc. Polyolefin films for in-mold labels
WO2011020620A1 (en) * 2009-08-21 2011-02-24 Basell Polyolefine Gmbh Polyethylene for rotomoulding
WO2011020622A1 (en) * 2009-08-21 2011-02-24 Basell Polyolefine Gmbh Polyethylene for rotomoulding
MX2012002545A (es) 2009-08-28 2012-04-02 Dow Global Technologies Llc Articulos moldeados rotatorios, y metodo para fabricarlos.
US9174384B2 (en) * 2009-09-01 2015-11-03 Fina Technology, Inc. Multilayer polypropylene films and methods of making and using same
US8592535B2 (en) 2010-01-11 2013-11-26 Fina Technology, Inc. Ziegler-natta catalyst systems and polymers formed therefrom
JP2013522491A (ja) 2010-03-19 2013-06-13 ダウ グローバル テクノロジーズ エルエルシー 複合繊維
US10351640B2 (en) 2010-04-22 2019-07-16 Fina Technology, Inc. Formation of Ziegler-Natta catalyst using non-blended components
US8278403B2 (en) 2010-07-08 2012-10-02 Fina Technology, Inc. Multi-component catalyst systems and polymerization processes for forming broad composition distribution polymers
US20120046429A1 (en) 2010-08-23 2012-02-23 Fina Technology, Inc. Sequential Formation of Ziegler-Natta Catalyst Using Non-blended Components
WO2012096698A2 (en) 2010-10-21 2012-07-19 Exxonmobil Chemical Patents Inc. Polyethylene and process for production thereof
BR112013009950A2 (pt) 2010-10-29 2020-09-01 Dow Global Technologies Llc fita
US10711077B2 (en) 2011-02-07 2020-07-14 Fina Technology, Inc. Ziegler-natta catalyst composition with controlled morphology
US8586192B2 (en) 2011-02-15 2013-11-19 Fina Technology, Inc. Compatibilized polymeric compositions comprising polyolefin-polylactic acid copolymers and methods of making the same
US9382347B2 (en) 2011-02-16 2016-07-05 Fina Technology Inc Ziegler-Natta catalysts doped with non-group IV metal chlorides
US8628718B2 (en) 2011-02-18 2014-01-14 Fina Technology, Inc. Modified polylactic acid, polymeric blends and methods of making the same
CA2734167C (en) 2011-03-15 2018-03-27 Nova Chemicals Corporation Polyethylene film
ES2640564T3 (es) 2011-05-27 2017-11-03 Dow Global Technologies Llc Una composición de mezcla de polietileno que tiene acumulación de rodillos de enfriamiento reducida durante el proceso de extrusión
CN103958751B (zh) 2011-10-05 2016-05-04 陶氏环球技术有限责任公司 纺粘无纺织物
US8580893B2 (en) 2011-12-22 2013-11-12 Fina Technology, Inc. Methods for improving multimodal polyethylene and films produced therefrom
US20130266786A1 (en) * 2012-04-06 2013-10-10 Exxonmobil Chemical Patents Inc. Polymers, Polymer Blends, and Articles Made Therefrom
US9115233B2 (en) 2012-06-21 2015-08-25 Nova Chemicals (International) S.A. Ethylene copolymer compositions, film and polymerization processes
CA2798855C (en) 2012-06-21 2021-01-26 Nova Chemicals Corporation Ethylene copolymers having reverse comonomer incorporation
BR112014031192B1 (pt) 2012-06-26 2022-01-04 Dow Global Technologies Llc Composição-mistura de polietileno apropriada para película soprada
CN108106968B (zh) 2012-09-07 2020-09-25 尤尼威蒂恩技术有限责任公司 控制聚合反应器的系统
BR112015005636A2 (pt) 2012-10-12 2017-07-04 Dow Global Technologies Llc composição de polietileno linear de baixa densidade, película estirável e composição mista
US20150259445A1 (en) 2012-10-12 2015-09-17 Dow Global Technologies Llc Linear low density composition suitable for film applications and films made therefrom
WO2014058660A1 (en) 2012-10-12 2014-04-17 Dow Global Technologies Llc Sealant composition
CN104704043B (zh) * 2012-10-12 2017-04-19 陶氏环球技术有限公司 聚烯烃共混物组合物
CA2884569A1 (en) 2012-10-12 2014-04-17 Dow Global Technologies Llc Polyolefin blend composition, and films made therefrom
US11214659B2 (en) 2012-10-26 2022-01-04 Exxonmobil Chemical Patents Inc. Polymer blends and articles made therefrom
EP2922699A1 (de) 2012-11-21 2015-09-30 ExxonMobil Chemical Patents Inc. Folien mit ethylenbasierten polymeren und verfahren zur herstellung davon
CA2797620C (en) * 2012-12-03 2019-08-27 Nova Chemicals Corporation Controlling resin properties in a gas phase polymerization process
MY172940A (en) 2012-12-17 2019-12-16 Dow Global Technologies Llc A polytehlene composition suitable for film applications and films made therefrom
WO2014099356A2 (en) 2012-12-18 2014-06-26 Exxonmobil Chemical Patents Inc. Polyethylene films and method of making same
CA2800056A1 (en) 2012-12-24 2014-06-24 Nova Chemicals Corporation Polyethylene blend compositions
CN105143285B (zh) 2013-02-07 2019-03-08 尤尼威蒂恩技术有限责任公司 聚烯烃的制备
KR102449447B1 (ko) * 2013-03-15 2022-09-30 유니베이션 테크놀로지즈, 엘엘씨 신속한 점착 발생을 갖는 하프노센 촉매화 폴리에틸렌 필름
JP2014229809A (ja) 2013-05-24 2014-12-08 株式会社ブリヂストン 太陽電池用封止膜用組成物、その製造方法及び太陽電池用封止膜
US9206293B2 (en) 2014-01-31 2015-12-08 Fina Technology, Inc. Polyethyene and articles produced therefrom
WO2015123179A1 (en) * 2014-02-11 2015-08-20 Univation Technologies, Llc Producing polyolefin products
CN106062018B (zh) 2014-03-31 2019-04-09 日本聚乙烯株式会社 乙烯-α-烯烃共聚物和烯烃系树脂组合物
JP6569668B2 (ja) 2014-03-31 2019-09-04 日本ポリエチレン株式会社 エチレン・α−オレフィン共重合体及びオレフィン系樹脂組成物
WO2015152268A1 (ja) 2014-03-31 2015-10-08 日本ポリエチレン株式会社 エチレン・α-オレフィン共重合体及びオレフィン系樹脂組成物
SG11201610213SA (en) 2014-06-11 2017-01-27 Fina Technology Chlorine-resistant polyethylene compound and articles made therefrom
US9624321B2 (en) 2014-06-13 2017-04-18 Fina Technology, Inc. Formation of a Ziegler-Natta catalyst
US9650448B2 (en) 2014-06-13 2017-05-16 Fina Technology, Inc. Formation of a Ziegler-Natta catalyst
US9765164B2 (en) 2014-06-27 2017-09-19 Dow Global Technologies Llc Polyolefin compositions and uses thereof
CA2967417C (en) 2014-11-25 2023-09-12 Univation Technologies, Llc Methods of changing polyolefin production rate with the composition of the induced condensing agents
US10329365B2 (en) 2014-11-25 2019-06-25 Univation Technologies, Llc Methods of monitoring and controlling the melt index of a polyolefin product during production
CN107001527B (zh) 2014-11-25 2020-12-11 尤尼威蒂恩技术有限责任公司 改变聚烯烃生产条件以减轻聚烯烃物品中的小凝胶的方法
WO2017069851A1 (en) 2015-10-23 2017-04-27 Exxonmobil Chemical Patents Inc. Production of polyolefins with internal unsaturation structures using a metallocene catalyst system
US9926396B2 (en) 2015-10-23 2018-03-27 Exxonmobil Chemical Patents Inc. Production of polyolefins with internal unsaturation structures using a metallocene catalyst system
CN109071844A (zh) 2016-04-22 2018-12-21 埃克森美孚化学专利公司 聚乙烯片材
WO2018017180A1 (en) 2016-07-21 2018-01-25 Exxonmobil Chemical Patents Inc. Rotomolded compositions, articles, and processes for making the same
EP3504060B1 (de) 2016-08-24 2021-01-13 Dow Global Technologies LLC Mehrschichtigefolien und herstellungsverfahren dafür
WO2018048472A1 (en) 2016-09-09 2018-03-15 Exxonmobil Chemical Patents Inc. Pilot plant scale semi-condensing operation
WO2018071250A1 (en) 2016-10-14 2018-04-19 Exxonmobil Chemical Patents Inc. Oriented films comprising ethylene-based and methods of making same
JP6967073B2 (ja) 2016-10-28 2021-11-17 フイナ・テクノロジー・インコーポレーテツドFina Technology, Incorporated Boppに応用するためのポリプロピレン中の結晶度を下げる作用剤の使用
WO2018102091A1 (en) 2016-12-02 2018-06-07 Exxonmobil Chemical Patents Inc. Polyethylene films
CN110461882B (zh) 2017-02-03 2021-12-14 埃克森美孚化学专利公司 制备聚乙烯聚合物的方法
CN110637049B (zh) 2017-04-06 2022-04-05 埃克森美孚化学专利公司 流延膜及其制造方法
US10442920B2 (en) 2017-04-19 2019-10-15 Nova Chemicals (International) S.A. Means for increasing the molecular weight and decreasing the density of ethylene interpolymers employing homogeneous and heterogeneous catalyst formulations
US10442921B2 (en) 2017-04-19 2019-10-15 Nova Chemicals (International) S.A. Means for increasing the molecular weight and decreasing the density employing mixed homogeneous catalyst formulations
WO2019022801A1 (en) 2017-07-24 2019-01-31 Exxonmobil Chemical Patents Inc. POLYETHYLENE FILMS AND METHODS OF PRODUCING THE SAME
WO2019027524A1 (en) 2017-08-02 2019-02-07 Exxonmobil Chemical Patents Inc. MULTILAYER FILMS AND METHODS OF MANUFACTURE
CN111491959B (zh) 2017-08-04 2023-08-25 埃克森美孚化学专利公司 由聚乙烯组合物制成的膜及其制造方法
US10435527B2 (en) 2017-09-26 2019-10-08 Chevron Phillips Chemical Company Lp Dual component LLDPE copolymers with improved impact and tear resistance
BR112020008024B1 (pt) 2017-10-23 2023-12-05 Exxonmobil Chemical Patents Inc Composições de polietileno, artigos produzidos a partir das mesmas e processo de produção dos mesmos
US10683376B2 (en) 2017-11-07 2020-06-16 Nova Chemicals (International) S.A. Manufacturing ethylene interpolymer products at higher production rate
US10995166B2 (en) 2017-11-07 2021-05-04 Nova Chemicals (International) S.A. Ethylene interpolymer products and films
WO2019094132A1 (en) 2017-11-13 2019-05-16 Exxonmobil Chemical Patents Inc. Polyethylene compositions and articles made therefrom
WO2019094131A1 (en) 2017-11-13 2019-05-16 Exxonmobil Chemical Patents Inc. Polyethylene compositions and articles made therefrom
US11130827B2 (en) 2017-11-14 2021-09-28 Exxonmobil Chemical Patents Inc. Polyethylene compositions and articles made therefrom
US11015002B2 (en) 2017-11-15 2021-05-25 Exxonmobil Chemical Patents Inc. Polymerization processes
WO2019099589A1 (en) 2017-11-15 2019-05-23 Exxonmobil Chemical Patents Inc. Polymerization processes
EP3710501A2 (de) 2017-11-15 2020-09-23 ExxonMobil Chemical Patents Inc. Polymerisierungsverfahren
CN111511781B (zh) 2017-11-28 2023-07-11 埃克森美孚化学专利公司 催化剂体系和使用其的聚合方法
CN111465626B (zh) 2017-11-28 2022-10-18 埃克森美孚化学专利公司 聚乙烯组合物和由其制成的膜
US11691398B2 (en) 2017-11-28 2023-07-04 Exxonmobil Chemical Patents Inc. Multilayer films and methods of making the same
WO2019108327A1 (en) 2017-12-01 2019-06-06 Exxonmobil Chemical Patents Inc. Films comprising polyethylene composition
BR112020010518B1 (pt) 2017-12-18 2023-11-28 Dow Global Technologies Llc Método para fazer uma composição de polietileno
WO2019125880A1 (en) 2017-12-18 2019-06-27 Dow Global Technologies Llc Hafnocene-titanocene catalyst system
SG11202008315TA (en) 2018-03-26 2020-10-29 Dow Global Technologies Llc Spray-dried zirconocene catalyst system
KR102013170B1 (ko) 2018-04-05 2019-08-22 대림산업 주식회사 폴리올레핀 수지 조성물 및 이의 제조방법
CN112055720B (zh) 2018-05-02 2022-11-22 埃克森美孚化学专利公司 从中试装置放大到较大生产设施的方法
US11447587B2 (en) 2018-05-02 2022-09-20 Exxonmobil Chemical Patents Inc. Methods for scale-up from a pilot plant to a larger production facility
US11986992B2 (en) 2018-05-22 2024-05-21 Exxonmobil Chemical Patents Inc. Methods for forming films and their related computing devices
US11629245B2 (en) 2018-06-28 2023-04-18 Exxonmobil Chemical Patents Inc. Polyethylene compositions, wire and cables, and methods for making the same
CN112218873B (zh) 2018-07-03 2023-11-21 埃克森美孚化学专利公司 金属茂合成方法
WO2020014138A1 (en) 2018-07-09 2020-01-16 Exxonmobil Chemical Patents Inc. Polyethylene cast films and methods for making the same
CN112469556B (zh) 2018-07-26 2023-05-02 埃克森美孚化学专利公司 多层泡沫膜及其制造方法
WO2020046406A1 (en) 2018-08-30 2020-03-05 Exxonmobil Chemical Patents Inc. Polymerization processes and polymers made therefrom
US10927205B2 (en) 2018-08-30 2021-02-23 Exxonmobil Chemical Patents Inc. Polymerization processes and polymers made therefrom
US10899860B2 (en) 2018-08-30 2021-01-26 Exxonmobil Chemical Patents Inc. Polymerization processes and polymers made therefrom
US11993699B2 (en) 2018-09-14 2024-05-28 Fina Technology, Inc. Polyethylene and controlled rheology polypropylene polymer blends and methods of use
CN113195603B (zh) 2018-11-13 2023-05-26 埃克森美孚化学专利公司 聚乙烯膜
EP3880738A1 (de) 2018-11-13 2021-09-22 ExxonMobil Chemical Patents Inc. Polyethylenmischungen und -folien
WO2020102057A1 (en) 2018-11-16 2020-05-22 Exxonmobil Chemical Patents Inc. Polyolefin compositions suitable for films
US10882987B2 (en) 2019-01-09 2021-01-05 Nova Chemicals (International) S.A. Ethylene interpolymer products having intermediate branching
KR102116476B1 (ko) 2019-01-18 2020-05-28 대림산업 주식회사 폴리올레핀 중합 촉매 조성물, 폴리올레핀의 제조 방법 및 폴리올레핀 수지
WO2020163079A1 (en) 2019-02-06 2020-08-13 Exxonmobil Chemical Patents Inc. Films and backsheets for hygiene articles
CN113518715B (zh) 2019-02-13 2024-03-22 埃克森美孚化学专利公司 取向的多层聚乙烯膜及其层合材料
US11840596B2 (en) 2019-02-20 2023-12-12 Lg Chem, Ltd. Catalyst composition and method for preparing polyolefin using the same
KR20210127954A (ko) 2019-02-20 2021-10-25 피나 테크놀러지, 인코포레이티드 휨이 적은 중합체 조성물
EP3941950A1 (de) 2019-03-21 2022-01-26 ExxonMobil Chemical Patents Inc. Verfahren zur verbesserung der produktion in der gasphasenpolymerisation
CN113677713A (zh) 2019-03-21 2021-11-19 埃克森美孚化学专利公司 改进气相聚合的方法
US11427703B2 (en) 2019-03-25 2022-08-30 Chevran Phillips Chemical Company LP Dual component LLDPE copolymers with improved impact and tear resistance, and methods of their preparation
US11046843B2 (en) 2019-07-29 2021-06-29 Nova Chemicals (International) S.A. Ethylene copolymers and films with excellent sealing properties
WO2021034400A1 (en) 2019-08-20 2021-02-25 Exxonmobil Chemical Patents Inc. Films and methods of making the same
WO2021040760A1 (en) 2019-08-28 2021-03-04 Exxonmobil Chemical Patents Inc. Polyolefin compositions for films
WO2021126458A1 (en) 2019-12-17 2021-06-24 Exxonmobil Chemical Patents Inc. Films made of polyethylene blends for improved sealing performance and mechanical properties
EP4106994A1 (de) 2020-02-18 2022-12-28 ExxonMobil Chemical Patents Inc. Dehnbarer film mit hoher festigkeit für verbesserte palettenstabilität
KR102547238B1 (ko) 2020-02-26 2023-06-26 한화솔루션 주식회사 혼성 촉매 조성물 및 이를 포함하는 올레핀 중합용 촉매의 제조방법
US20230097375A1 (en) 2020-03-12 2023-03-30 Exxonmobil Chemical Patents Inc. Films made of polyethylene blends for improved bending stiffness and high md tear resistance
KR102579801B1 (ko) * 2020-04-16 2023-09-19 한화솔루션 주식회사 혼성 촉매 조성물, 이를 포함하는 촉매 및 이들의 제조방법
KR102668044B1 (ko) * 2020-05-28 2024-05-23 한화솔루션 주식회사 혼성 촉매 조성물, 이를 포함하는 촉매 및 이들의 제조방법
US20230242745A1 (en) 2020-06-03 2023-08-03 Exxonmobil Chemical Patents Inc Process for Production of Thermoplastic Vulcanizates using Supported Catalyst Systems and Compositions Made Therefrom
WO2022093814A1 (en) 2020-10-28 2022-05-05 Exxonmobil Chemical Patents Inc. Non-aromatic hydrocarbon soluble olefin polymerization catalysts and use thereof
EP4255942A1 (de) 2020-12-02 2023-10-11 ExxonMobil Chemical Patents Inc. Polyethylenzusammensetzungen mittlerer dichte mit breiter orthogonaler zusammensetzungsverteilung
CA3214562A1 (en) 2021-04-26 2022-11-03 Michael Mcleod Thin single-site catalyzed polymer sheets
AR125871A1 (es) 2021-05-19 2023-08-23 Dow Global Technologies Llc Composiciones de polietileno de alta densidad que tienen mejor procesabilidad y artículos moldeados fabricados a partir de las mismas
EP4341344A1 (de) 2021-05-19 2024-03-27 Dow Global Technologies Llc Hochdichte polyethylenzusammensetzungen und daraus hergestellte artikel
EP4352118A1 (de) 2021-06-10 2024-04-17 Dow Global Technologies LLC Katalysatorzusammensetzungen mit modifizierter aktivität und verfahren zu ihrer herstellung
CN117980354A (zh) 2021-10-26 2024-05-03 埃克森美孚化学专利公司 具有卓越加工性和机械性质的高度取向线性低密度聚乙烯膜
WO2023244899A1 (en) 2022-06-13 2023-12-21 Exxonmobil Chemical Patents Inc. Polyethylene compositions and related bicomponent fibers, nonwoven fabrics, and methods
WO2024044423A1 (en) 2022-08-22 2024-02-29 Exxonmobil Chemical Patents, Inc. Polyethylene compositions and films made therefrom
WO2024118536A1 (en) 2022-11-29 2024-06-06 Fina Technology, Inc. Polypropylenes for additive manufacturing

Family Cites Families (93)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4405495A (en) 1980-06-30 1983-09-20 Union Carbide Corporation Catalyst impregnated on fine silica, process for preparing, and use for ethylene polymerization
US5324800A (en) 1983-06-06 1994-06-28 Exxon Chemical Patents Inc. Process and catalyst for polyolefin density and molecular weight control
EP0200351B2 (de) 1985-03-26 1996-10-16 Mitsui Petrochemical Industries, Ltd. Flüssiges statisches Ethylencopolymer, Verfahren zur Herstellung und Anwendung desselben
FR2588559B1 (fr) * 1985-10-11 1988-03-11 Bp Chimie Sa Procede de polymerisation ou de copolymerisation d'alpha-olefines en presence d'un systeme catalytique ziegler-natta ameliore
US5084534A (en) 1987-06-04 1992-01-28 Exxon Chemical Patents, Inc. High pressure, high temperature polymerization of ethylene
US5198401A (en) 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
PL276385A1 (en) 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5264405A (en) 1989-09-13 1993-11-23 Exxon Chemical Patents Inc. Monocyclopentadienyl titanium metal compounds for ethylene-α-olefin-copolymer production catalysts
US5621126A (en) 1987-01-30 1997-04-15 Exxon Chemical Patents Inc. Monocyclopentadienyl metal compounds for ethylene-α-olefin-copolymer production catalysts
US5384299A (en) 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5055438A (en) 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
US5408017A (en) 1987-01-30 1995-04-18 Exxon Chemical Patents Inc. High temperature polymerization process using ionic catalysts to produce polyolefins
US5096867A (en) 1990-06-04 1992-03-17 Exxon Chemical Patents Inc. Monocyclopentadienyl transition metal olefin polymerization catalysts
US4794096A (en) 1987-04-03 1988-12-27 Fina Technology, Inc. Hafnium metallocene catalyst for the polymerization of olefins
US4927797A (en) * 1987-04-09 1990-05-22 Fina Technology, Inc. Catalyst system for the polymerization of olefins
US5026797A (en) 1987-10-22 1991-06-25 Mitsubishi Petrochemical Co., Ltd. Process for producing ethylene copolymers
US4931417A (en) 1987-11-09 1990-06-05 Chisso Corporation Transition-metal compound having a bis-substituted-cyclopentadienyl ligand of bridged structure
US5017714A (en) 1988-03-21 1991-05-21 Exxon Chemical Patents Inc. Silicon-bridged transition metal compounds
US5001205A (en) 1988-06-16 1991-03-19 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene α-olefin elastomer with a metallocene alumoxane catalyst
US5229478A (en) 1988-06-16 1993-07-20 Exxon Chemical Patents Inc. Process for production of high molecular weight EPDM elastomers using a metallocene-alumoxane catalyst system
DE3836059A1 (de) 1988-10-22 1990-05-03 Hoechst Ag Verfahren zur herstellung eines ethylen-propylen-copolymers
US4914253A (en) 1988-11-04 1990-04-03 Exxon Chemical Patents Inc. Method for preparing polyethylene wax by gas phase polymerization
US5234950A (en) * 1988-12-23 1993-08-10 Imperial Chemical Industries Plc Tetrahydrofuran derivatives
ES2118718T5 (es) 1988-12-26 2009-11-05 Mitsui Chemicals, Inc. Copolimeros de olefinas y su produccion.
US5218071A (en) 1988-12-26 1993-06-08 Mitsui Petrochemical Industries, Ltd. Ethylene random copolymers
EP0769505B1 (de) 1988-12-26 2000-05-10 Mitsui Chemicals, Inc. Olefincopolymere und Verfahren zur Herstellung davon
DE3927257A1 (de) 1989-08-18 1991-02-21 Hoechst Ag Verfahren zur herstellung eines polyolefins
AU6337690A (en) * 1989-09-06 1991-04-08 Exxon Chemical Patents Inc. Alpha olefin copolymers having a narrow mwd and broad compositional distribution
US5017800A (en) 1989-09-29 1991-05-21 Wisconsin Alumni Research Foundation AC to DC to AC power conversion apparatus with few active switches and input and output control
EP0443768A3 (en) 1990-02-22 1993-01-27 Hewlett-Packard Company Programming escape from an iconic system
GB9004014D0 (en) 1990-02-22 1990-04-18 Shell Int Research Co-oligomerization process
US5239061A (en) * 1990-06-20 1993-08-24 Research Corporation Technologies, Inc. Modified human hemoglobin, blood substitutes containing the same, and vectors for expressing the modified hemoglobin
US5235671A (en) * 1990-10-15 1993-08-10 Gte Laboratories Incorporated Dynamic bit allocation subband excited transform coding method and apparatus
DE69107006T2 (de) * 1990-10-17 1995-09-21 Idemitsu Kosan Co Verfahren zur Herstellung von Oligomeren auf Basis von Propylen.
US5235672A (en) * 1991-02-06 1993-08-10 Irvine Sensors Corporation Hardware for electronic neural network
US5239238A (en) * 1991-05-08 1993-08-24 U.S. Philips Corporation Electrodeless low-pressure mercury vapour discharge lamp
CA2068939C (en) 1991-05-20 1996-04-09 Takashi Ueda Olefin polymerization catalyst and olefin polymerization
US5258475A (en) 1991-07-12 1993-11-02 Mobil Oil Corporation Catalyst systems for polymerization and copolymerization of olefins
US5416228A (en) * 1991-10-07 1995-05-16 Fina Technology, Inc. Process and catalyst for producing isotactic polyolefins
US5281679A (en) * 1991-11-07 1994-01-25 Exxon Chemical Patents Inc. Catalyst and method of broadening polymer molecular weight distribution and increasing polymer tensile impact strength and products made thereof
TW254950B (de) * 1992-03-02 1995-08-21 Shell Internat Res Schappej Bv
US5710222A (en) 1992-06-22 1998-01-20 Fina Technology, Inc. Method for controlling the melting points and molecular weights of syndiotactic polyolefins using metallocene catalyst systems
WO1994003509A1 (en) 1992-08-05 1994-02-17 Exxon Chemical Patents Inc. Gas phase polymerization of ethylene and c7 to c10 olefins
US5290745A (en) 1992-08-10 1994-03-01 Union Carbide Chemicals & Plastics Technology Corporation Process for producing ethylene polymers having reduced hexane extractable content
EP0662988B2 (de) * 1992-09-16 2011-03-30 ExxonMobil Chemical Patents Inc. Weiche filme mit verbesserten physikalischen eigenschaften
ES2101217T3 (es) 1992-10-23 1997-07-01 Shell Int Research Composicion catalitica para oligomerizacion y co-oligomerizacion de alquenos.
EP0595553B1 (de) * 1992-10-29 1996-12-27 Rolls-Royce And Associates Limited Verbesserung in Weggebern
US5332706A (en) 1992-12-28 1994-07-26 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
US5608019A (en) * 1992-12-28 1997-03-04 Mobil Oil Corporation Temperature control of MW in olefin polymerization using supported metallocene catalyst
US5602067A (en) 1992-12-28 1997-02-11 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
CZ288678B6 (cs) * 1993-01-29 2001-08-15 The Dow Chemical Company Způsob přípravy ethylen/alfa-olefinových interpolymerních kompozic
US6313240B1 (en) 1993-02-22 2001-11-06 Tosoh Corporation Process for producing ethylene/α-olefin copolymer
CA2116259A1 (en) 1993-02-23 1994-08-24 Akira Sano Solid catalyst components for olefin polymerization and use thereof
DE69422410T2 (de) * 1993-08-06 2000-07-06 Exxon Chemical Patents Inc Polymerisationskataylsatoren, ihre herstellung und verwendung
AU697757B2 (en) 1993-10-22 1998-10-15 Mobil Oil Corporation An olefin polymerization or copolymerization catalyst
US5491207A (en) 1993-12-14 1996-02-13 Exxon Chemical Patents Inc. Process of producing high molecular weight ethylene-α-olefin elastomers with an indenyl metallocene catalyst system
CA2174452C (en) 1993-12-21 2007-04-24 Ahmed Hussein Ali Binary cocatalyst compositions for activating heterogeneous polymerization catalysts
US5674795A (en) 1993-12-23 1997-10-07 Union Carbide Chemicals & Plastics Technology Corporation Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture
US5648310A (en) 1993-12-23 1997-07-15 Union Carbide Chemicals & Plastics Technology Corporation Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture
MX9500982A (es) 1994-02-17 1997-02-28 Union Carbide Chem Plastic Composicion catalizadora cargada con metaloceno, secada por rociadura para usarse en la fabricacion de poliolefina.
JP2666208B2 (ja) 1994-03-11 1997-10-22 工業技術院長 有機シラン類の製造法
DE4416894A1 (de) 1994-05-13 1995-11-16 Witco Gmbh Verfahren zur Synthese von Mono- und Dimethylmetallocenen und deren Lösungen speziell für den Einsatz zur Polymerisation von Olefinen
US5541272A (en) 1994-06-03 1996-07-30 Phillips Petroleum Company High activity ethylene selective metallocenes
JP3443941B2 (ja) 1994-06-10 2003-09-08 チッソ株式会社 架橋型メタロセン化合物およびその製造法
US5763543A (en) 1994-09-14 1998-06-09 Exxon Chemical Patents Inc. Olefin polymerization process with little or no scavenger present
NO315857B1 (no) * 1995-03-28 2003-11-03 Japan Polyolefines Co Ltd Etylen-<alfa>-olefin-kopolymer, blanding, film, laminert material, elektrisk isolerende material og strömkabel inneholdende denne
US5621054A (en) * 1995-06-07 1997-04-15 Exxon Chemical Patents Inc. Copolymerization process for the preparation of crystalline copolymers of olefins and cyclic olefins
DE19525178A1 (de) 1995-07-11 1997-01-16 Basf Ag Verfahren zur Umwandlung der achiralen meso-Form eines ansa-Metallkomplexes in die chirale rac.-Form
JP3499334B2 (ja) 1995-08-11 2004-02-23 理研軽金属工業株式会社 大型表示体
ATE153675T1 (de) 1995-09-13 1997-06-15 Witco Gmbh Verfahren zur herstellung von metallocen- katalysatorsystemen auf inerten trägermaterialien unter verwendung von gasphasenreaktoren
ES2104454T3 (es) 1995-09-13 1997-10-01 Witco Gmbh Procedimiento para la preparacion de sistemas de catalizadores del tipo de metalocenos sobre materiales de soporte inertes.
US5767208A (en) * 1995-10-20 1998-06-16 Exxon Chemical Patents Inc. High temperature olefin polymerization process
WO1997022639A1 (en) 1995-12-19 1997-06-26 Exxon Chemical Patents Inc. High temperature solution polymerization process
JPH09176400A (ja) * 1995-12-27 1997-07-08 Nippon Poriorefuin Kk 充填剤含有エチレン・α−オレフィン共重合体組成物およびその組成物を用いた成形品
JPH09183816A (ja) 1995-12-28 1997-07-15 Mitsui Petrochem Ind Ltd エチレン・α−オレフィン共重合体およびこの共重合体から得られるフィルム
WO1997048735A1 (en) * 1996-06-17 1997-12-24 Exxon Chemical Patents Inc. Mixed transition metal catalyst systems for olefin polymerization
US6759499B1 (en) * 1996-07-16 2004-07-06 Exxonmobil Chemical Patents Inc. Olefin polymerization process with alkyl-substituted metallocenes
CA2259905C (en) 1996-07-16 2006-01-31 Exxon Chemical Patents, Inc. Olefin polymerization process with alkyl-substituted metallocenes
US6242545B1 (en) 1997-12-08 2001-06-05 Univation Technologies Polymerization catalyst systems comprising substituted hafinocenes
US20060293470A1 (en) 2005-06-28 2006-12-28 Cao Phuong A Polymerization process using spray-dried catalyst
CA2237231C (en) 1998-05-08 2006-08-08 Nova Chemicals Ltd. Heterogeneous metallocene catalyst
CA2243783C (en) 1998-07-21 2007-06-05 Nova Chemicals Ltd. Bis-phosphinimine catalyst
CA2243775C (en) 1998-07-21 2007-06-12 Nova Chemicals Ltd. Phosphinimine/heteroatom catalyst component
CA2243726C (en) 1998-07-21 2006-12-12 Nova Chemicals Ltd. Cyclopentadienyl/phosphinimine catalyst with one and only one activatable ligand
DE69926339T2 (de) 1998-11-20 2006-01-26 Basell Polyolefine Gmbh Verbrückte metallocene, herstellung und verwendung als olefinpolymerisationskatalysator
CA2254841C (en) 1998-11-26 2007-02-06 Nova Chemicals Ltd. Nitrogen substituted phosphinimine ligand
CA2254601C (en) 1998-11-27 2007-10-23 Nova Chemicals Ltd. Aluminum-phosphinimine complexes as catalysts for the (co)polymerization of ethylene
CA2278042C (en) 1999-07-19 2008-12-16 Nova Chemicals Corporation Mixed phosphinimine catalyst
AU2407800A (en) 1999-10-28 2001-05-08 University Of Maryland At College Park, The Stereospecific living polymerization of olefins by a novel ziegler-natta catalyst composition
US6482903B1 (en) 1999-12-15 2002-11-19 Univation Technologies, Llc Method for preparing a supported catalyst system and its use in a polymerization process
US6281306B1 (en) 1999-12-16 2001-08-28 Univation Technologies, Llc Method of polymerization
US6897273B2 (en) 2000-12-04 2005-05-24 Univation Technologies, Llc Catalyst composition, method of polymerization and polymer therefrom
US6656866B2 (en) 2000-12-04 2003-12-02 Univation Technologies, Llc Catalyst preparation method

Also Published As

Publication number Publication date
US6248845B1 (en) 2001-06-19
US20010018505A1 (en) 2001-08-30
JP2005120385A (ja) 2005-05-12
WO1999029737A1 (en) 1999-06-17
EP1518868B1 (de) 2008-02-27
EP1037930B1 (de) 2006-02-22
US7381783B2 (en) 2008-06-03
DE69839198T2 (de) 2009-02-26
AU743364B2 (en) 2002-01-24
USRE40751E1 (en) 2009-06-16
EP1037930A1 (de) 2000-09-27
US20010020074A1 (en) 2001-09-06
US20080214753A1 (en) 2008-09-04
BR9813438B1 (pt) 2008-11-18
DE69833571T2 (de) 2006-10-05
US20080108768A1 (en) 2008-05-08
US7989564B2 (en) 2011-08-02
DE69839198D1 (de) 2008-04-10
US6528597B2 (en) 2003-03-04
AU1807299A (en) 1999-06-28
US20040249091A1 (en) 2004-12-09
JP2001525457A (ja) 2001-12-11
ES2301918T3 (es) 2008-07-01
EP1518868A3 (de) 2005-08-17
US20010031698A1 (en) 2001-10-18
US6242545B1 (en) 2001-06-05
BR9813438A (pt) 2000-10-10
ES2259219T3 (es) 2006-09-16
CA2313215A1 (en) 1999-06-17
US20040097365A1 (en) 2004-05-20
JP4780949B2 (ja) 2011-09-28
CA2313215C (en) 2008-02-19
US20020040114A1 (en) 2002-04-04
US8227564B2 (en) 2012-07-24
EP1518868A2 (de) 2005-03-30

Similar Documents

Publication Publication Date Title
DE69833571D1 (de) Polymerisationskatalysatorsysteme, deren verwendung, deren produkte und gegenstände
PT830408E (pt) Catalisador processos e produtos polimericos resultantes
DE69421411T2 (de) Polymerisationskatalysatorsysteme, ihre herstellung und verwendung
DE69421287T2 (de) Polymerisationskatalysatorsysteme, ihre herstellung und verwendung
DE69530100D1 (de) Polymerisationkatalysatorsysteme, ihre herstellung und ihre verwendung
DE69525042D1 (de) Polymerisationskatalysatorsysteme, ihre herstellung und ihre verwendung
ATE299898T1 (de) Katalysatorsysteme und deren verwendung in einem polymerisationsverfahren
DE69509403T2 (de) Polymerisation Katalysatorsysteme, ihre Herstellung und ihre Verwendung
ID22443A (id) Metallosena heterosiklik dan polimerisasi katalis
DE69731686D1 (de) Polymerisationskatalysator
DE69805638D1 (de) Polymerisationskatalysatoren
ID27209A (id) Katalis-katalis polimerisasi
ID22033A (id) Katalis polimerisasi
FI962997A0 (fi) Biohajoavia kopolymeerejä ja muovituotteita, jotka käsittävät biohajoavia kopolymeerejä
BG99631A (en) Metallocene-containing catalytic systems, their preparation and application
DE69817432D1 (de) Cycloolefinpolymere und deren Verwendung
AR025430A1 (es) Producto cosmetico en base a oligomeros y polimeros que contienen grupos uretano y/o urea
DE69504652D1 (de) Vinylbenzyl-thyminmonomere und -polymere und daraus hergestellte produkte
ID21382A (id) Katalis polimerisasi dan proses-prosesnya
FI960562A (fi) Organoaluminoksituote, katalyyttijärjestelmiä, valmistus ja käyttö
DE69409055T2 (de) Chromkatalysatorzusammensetzungen und Polymerisationsverfahren unter deren Verwendung
DE69814436D1 (de) Polymerisationsverfahren, produkte und deren verwendung
FI945389A0 (fi) Olefiinien polymerointimenetelmä, katalyyttijärjestelmä ja polymeeri
ID26923A (id) Katalis polimerisasi dan proses-prosesnya
AU9603798A (en) Polymerization catalyst systems, their preparation and use

Legal Events

Date Code Title Description
8364 No opposition during term of opposition