FR2588559B1 - Procede de polymerisation ou de copolymerisation d'alpha-olefines en presence d'un systeme catalytique ziegler-natta ameliore - Google Patents

Procede de polymerisation ou de copolymerisation d'alpha-olefines en presence d'un systeme catalytique ziegler-natta ameliore

Info

Publication number
FR2588559B1
FR2588559B1 FR8515239A FR8515239A FR2588559B1 FR 2588559 B1 FR2588559 B1 FR 2588559B1 FR 8515239 A FR8515239 A FR 8515239A FR 8515239 A FR8515239 A FR 8515239A FR 2588559 B1 FR2588559 B1 FR 2588559B1
Authority
FR
France
Prior art keywords
olefins
alpha
catalyst system
copolymerisation
polymerisation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
FR8515239A
Other languages
English (en)
Other versions
FR2588559A1 (fr
Inventor
Dominique Lassalle
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP Chimie SA
Original Assignee
BP Chimie SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BP Chimie SA filed Critical BP Chimie SA
Priority to FR8515239A priority Critical patent/FR2588559B1/fr
Priority to IN860/DEL/86A priority patent/IN170911B/en
Priority to DE8686307561T priority patent/DE3676041D1/de
Priority to ES86307561T priority patent/ES2019063B3/es
Priority to EP86307561A priority patent/EP0219998B1/fr
Priority to AT86307561T priority patent/ATE58905T1/de
Priority to AU63526/86A priority patent/AU590335B2/en
Priority to CA000519700A priority patent/CA1286837C/fr
Priority to NZ217817A priority patent/NZ217817A/en
Priority to NO863998A priority patent/NO168044C/no
Priority to FI864072A priority patent/FI89370C/fi
Priority to JP61241172A priority patent/JPH0725819B2/ja
Priority to PT83517A priority patent/PT83517B/pt
Priority to BR8604974A priority patent/BR8604974A/pt
Priority to CN86107042A priority patent/CN1007155B/zh
Priority to KR1019860008535A priority patent/KR940006900B1/ko
Publication of FR2588559A1 publication Critical patent/FR2588559A1/fr
Priority to MYPI87001373A priority patent/MY102510A/en
Application granted granted Critical
Publication of FR2588559B1 publication Critical patent/FR2588559B1/fr
Priority to US07/204,984 priority patent/US4894424A/en
Priority to GR90400927T priority patent/GR3001170T3/el
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/908—Containing catalyst of specified particle size
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/909—Polymerization characterized by particle size of product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Polymerisation Methods In General (AREA)
FR8515239A 1985-10-11 1985-10-11 Procede de polymerisation ou de copolymerisation d'alpha-olefines en presence d'un systeme catalytique ziegler-natta ameliore Expired FR2588559B1 (fr)

Priority Applications (19)

Application Number Priority Date Filing Date Title
FR8515239A FR2588559B1 (fr) 1985-10-11 1985-10-11 Procede de polymerisation ou de copolymerisation d'alpha-olefines en presence d'un systeme catalytique ziegler-natta ameliore
IN860/DEL/86A IN170911B (fr) 1985-10-11 1986-09-30
DE8686307561T DE3676041D1 (de) 1985-10-11 1986-10-01 Polymerisation von olefinen mit einem modifizierten ziegler-natta-katalysator.
ES86307561T ES2019063B3 (es) 1985-10-11 1986-10-01 Polimerizacion de olefinas utilizando catalizador de ziegler-natta modificado.
EP86307561A EP0219998B1 (fr) 1985-10-11 1986-10-01 Polymérisation d'oléfines à l'aide d'un catalyseur Ziegler-Natta modifié
AT86307561T ATE58905T1 (de) 1985-10-11 1986-10-01 Polymerisation von olefinen mit einem modifizierten ziegler-natta-katalysator.
AU63526/86A AU590335B2 (en) 1985-10-11 1986-10-03 Polymerisation of olefins using modified ziegler-natta catalyst
CA000519700A CA1286837C (fr) 1985-10-11 1986-10-03 Polymerisation des olefines au catalyseur ziegler-natta modifie
NZ217817A NZ217817A (en) 1985-10-11 1986-10-06 A process for polymerising or copolymerising alpha-olefins in the presence of ziegler-natta catalytic system
NO863998A NO168044C (no) 1985-10-11 1986-10-07 Fremgangsmaate for polymerisasjon av olefiner ved bruk av modifisert ziegler-natta katalysator.
FI864072A FI89370C (fi) 1985-10-11 1986-10-08 Polymerisering av olefiner medelst anvaendning av en modifierad ziegler-natta-katalysator
JP61241172A JPH0725819B2 (ja) 1985-10-11 1986-10-09 改良チ−グラ−−ナツタ触媒を使用したオレフインの重合方法
PT83517A PT83517B (pt) 1985-10-11 1986-10-09 Processo para a polimerizacao ou copolimerizacao de alfa-olefinas usando catalisador de ziegler-natta modificado
BR8604974A BR8604974A (pt) 1985-10-11 1986-10-10 Processo para polimerizacao ou copolimerizacao de alfa-olefinas na presenca de um sistema catalitico de ziegler-natta
CN86107042A CN1007155B (zh) 1985-10-11 1986-10-11 应用改进型齐格勒-纳塔催化剂的链烯烃聚合方法
KR1019860008535A KR940006900B1 (ko) 1985-10-11 1986-10-11 α-올레핀의 중합방법
MYPI87001373A MY102510A (en) 1985-10-11 1987-08-18 Polymerisation of olefins using modified ziegler- natta catalyst.
US07/204,984 US4894424A (en) 1985-10-11 1988-06-08 Polymerisation of olefins using modified ziegler-natta catalyst
GR90400927T GR3001170T3 (en) 1985-10-11 1990-12-06 Polymerisation of olefins using modified ziegler-natta catalyst

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR8515239A FR2588559B1 (fr) 1985-10-11 1985-10-11 Procede de polymerisation ou de copolymerisation d'alpha-olefines en presence d'un systeme catalytique ziegler-natta ameliore

Publications (2)

Publication Number Publication Date
FR2588559A1 FR2588559A1 (fr) 1987-04-17
FR2588559B1 true FR2588559B1 (fr) 1988-03-11

Family

ID=9323820

Family Applications (1)

Application Number Title Priority Date Filing Date
FR8515239A Expired FR2588559B1 (fr) 1985-10-11 1985-10-11 Procede de polymerisation ou de copolymerisation d'alpha-olefines en presence d'un systeme catalytique ziegler-natta ameliore

Country Status (18)

Country Link
US (1) US4894424A (fr)
EP (1) EP0219998B1 (fr)
JP (1) JPH0725819B2 (fr)
KR (1) KR940006900B1 (fr)
CN (1) CN1007155B (fr)
AT (1) ATE58905T1 (fr)
AU (1) AU590335B2 (fr)
BR (1) BR8604974A (fr)
CA (1) CA1286837C (fr)
DE (1) DE3676041D1 (fr)
ES (1) ES2019063B3 (fr)
FI (1) FI89370C (fr)
FR (1) FR2588559B1 (fr)
GR (1) GR3001170T3 (fr)
MY (1) MY102510A (fr)
NO (1) NO168044C (fr)
NZ (1) NZ217817A (fr)
PT (1) PT83517B (fr)

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* Cited by examiner, † Cited by third party
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US5188840A (en) * 1985-09-26 1993-02-23 Chugai Seiyaku Kabushiki Kaisha Slow-release pharmaceutical agent
US5723402A (en) * 1996-05-30 1998-03-03 Pq Corporation Silicas with specific contents of cations as supports for olefin polymerization catalysts
US6242545B1 (en) * 1997-12-08 2001-06-05 Univation Technologies Polymerization catalyst systems comprising substituted hafinocenes
US8497330B2 (en) * 1997-12-08 2013-07-30 Univation Technologies, Llc Methods for polymerization using spray dried and slurried catalyst
CN1098866C (zh) 1998-01-14 2003-01-15 中国石油化工集团公司 气相法全密度聚乙烯高效催化剂
DE19843858A1 (de) * 1998-09-25 2000-04-06 Ticona Gmbh Verfahren zur Herstellung eines Polymers
US6831032B2 (en) 2002-08-19 2004-12-14 Novolen Technology Holdings C.V. Ziegler-Natta catalyst and methods of making and using same
WO2004094487A1 (fr) 2003-03-21 2004-11-04 Dow Global Technologies, Inc. Procede de polymerisation d'olefines avec controle de la morphologie
US6953764B2 (en) 2003-05-02 2005-10-11 Dow Global Technologies Inc. High activity olefin polymerization catalyst and process
CN1279069C (zh) * 2003-12-03 2006-10-11 中国石油化工股份有限公司 一种聚乙烯催化剂及其制备方法
KR100620887B1 (ko) * 2004-07-01 2006-09-19 삼성토탈 주식회사 아릴옥시계 올레핀 (공)중합촉매를 이용한 올레핀 중합체및 올레핀/α-올레핀 공중합체 제조방법
KR100561058B1 (ko) * 2004-09-23 2006-03-17 삼성토탈 주식회사 페녹시계 리간드가 포함된 올레핀 중합용 촉매 및 이를사용한 올레핀 (공)중합방법
EP1803747A1 (fr) 2005-12-30 2007-07-04 Borealis Technology Oy Catalyseur de polymérisation à surface modifiée pour réduire la formation de gels dans des films
US20090186996A1 (en) 2006-05-05 2009-07-23 Boone Harold W Hafnium complexes of carbazolyl substituted imidazole ligands
JP5172205B2 (ja) * 2007-05-17 2013-03-27 東邦チタニウム株式会社 オレフィン類重合用固体触媒成分の製造方法
JP5208544B2 (ja) * 2008-03-06 2013-06-12 東邦チタニウム株式会社 オレフィン類重合用固体触媒成分、その製造方法及び触媒並びにこれを用いたオレフィン類重合体の製造方法
CN107660216B (zh) 2015-05-08 2021-05-14 埃克森美孚化学专利公司 聚合方法
WO2018063764A1 (fr) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Procédé de polymérisation
WO2018063765A1 (fr) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Procédé de polymérisation
WO2018063767A1 (fr) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Processus de polymérisation
WO2018118155A1 (fr) 2016-12-20 2018-06-28 Exxonmobil Chemical Patents Inc. Procédé de polymérisation
WO2019118073A1 (fr) 2017-12-13 2019-06-20 Exxonmobil Chemical Patents Inc. Procédés de désactivation pour composants actifs à partir d'un procédé de polymérisation de polyoléfine en phase gazeuse
WO2019173030A1 (fr) 2018-03-08 2019-09-12 Exxonmobil Chemical Patents Inc. Procédés de préparation et de surveillance d'un lit de germination pour le démarrage d'un réacteur de polymérisation
US11459408B2 (en) 2018-05-02 2022-10-04 Exxonmobil Chemical Patents Inc. Methods for scale-up from a pilot plant to a larger production facility
WO2019213227A1 (fr) 2018-05-02 2019-11-07 Exxonmobil Chemical Patents Inc. Procédés de mise à l'échelle superieure d'une installation pilote à une installation de production de plus grande taille
KR102605269B1 (ko) 2019-12-09 2023-11-23 한화솔루션 주식회사 기상 중합에 의한 올레핀계 중합체의 제조방법

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FR1298690A (fr) * 1961-08-25 1962-07-13 Glanzstoff Ag Procédé pour l'épuration du trichlorure de titane
DE1795272C2 (de) * 1968-08-31 1981-10-22 Hoechst Ag, 6000 Frankfurt Verfahren zur Homo- und Mischpolymerisation von Äthylen
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US4130699A (en) * 1977-11-25 1978-12-19 Standard Oil Company (Indiana) Vapor phase polymerization with temporarily inactive titanium catalyst
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FR2529209A1 (fr) * 1982-06-24 1983-12-30 Bp Chimie Sa Catalyseurs pour la polymerisation et la copolymerisation du propylene et procedes de polymerisation utilisant ces catalyseurs
JPS59176304A (ja) * 1983-03-28 1984-10-05 Idemitsu Kosan Co Ltd ポリα−オレフインの製造方法
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Also Published As

Publication number Publication date
PT83517B (pt) 1989-05-31
EP0219998A1 (fr) 1987-04-29
FI864072A0 (fi) 1986-10-08
ES2019063B3 (es) 1991-06-01
CN86107042A (zh) 1987-04-29
JPH0725819B2 (ja) 1995-03-22
FI89370B (fi) 1993-06-15
PT83517A (en) 1986-11-01
DE3676041D1 (de) 1991-01-17
KR940006900B1 (ko) 1994-07-29
NO168044B (no) 1991-09-30
JPS62119205A (ja) 1987-05-30
AU6352686A (en) 1987-04-16
US4894424A (en) 1990-01-16
AU590335B2 (en) 1989-11-02
FR2588559A1 (fr) 1987-04-17
NZ217817A (en) 1990-01-29
MY102510A (en) 1992-07-31
NO863998D0 (no) 1986-10-07
CA1286837C (fr) 1991-07-23
NO863998L (no) 1987-04-13
FI89370C (fi) 1993-09-27
GR3001170T3 (en) 1992-06-30
ATE58905T1 (de) 1990-12-15
KR870004059A (ko) 1987-05-07
NO168044C (no) 1992-01-08
FI864072A (fi) 1987-04-12
EP0219998B1 (fr) 1990-12-05
CN1007155B (zh) 1990-03-14
BR8604974A (pt) 1987-07-14

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