EA199800979A1 - Каталитическая композиция на носителе и способ полимеризации олефиновых мономеров - Google Patents

Каталитическая композиция на носителе и способ полимеризации олефиновых мономеров

Info

Publication number
EA199800979A1
EA199800979A1 EA199800979A EA199800979A EA199800979A1 EA 199800979 A1 EA199800979 A1 EA 199800979A1 EA 199800979 A EA199800979 A EA 199800979A EA 199800979 A EA199800979 A EA 199800979A EA 199800979 A1 EA199800979 A1 EA 199800979A1
Authority
EA
Eurasian Patent Office
Prior art keywords
transition metal
polymerization
media
olefin monomers
catalytic composition
Prior art date
Application number
EA199800979A
Other languages
English (en)
Inventor
Мориц Фредерик Хендрик Ван Тол
Йоханус Антониус Мария Ван Бек
Original Assignee
Дсм Н.В.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Дсм Н.В. filed Critical Дсм Н.В.
Publication of EA199800979A1 publication Critical patent/EA199800979A1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Описывается каталитическая система, содержащая материал-носитель, по меньшей мере, один комплекс переходного металла и необязательно, по меньшей мере, один сокатализатор. Комплекс переходного металла состоит из восстановленного переходного металла (например титана), выбранного из 4-6 групп Периодической таблицы элементов, с полидентатным моноанионным лигандом и двумя моноанионными лигандами. Изобретение также относится к способу получения полимеров с использованием этой каталитической системы и к полученным полимерным продуктам.Международная заявка была опубликована вместе с отчетом о международном поиске.
EA199800979A 1996-05-03 1997-05-01 Каталитическая композиция на носителе и способ полимеризации олефиновых мономеров EA199800979A1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP96201119 1996-05-03
PCT/NL1997/000238 WO1997042228A1 (en) 1996-05-03 1997-05-01 Supported catalyst composition and process for the polymerization of olefin monomers

Publications (1)

Publication Number Publication Date
EA199800979A1 true EA199800979A1 (ru) 1999-04-29

Family

ID=8223927

Family Applications (1)

Application Number Title Priority Date Filing Date
EA199800979A EA199800979A1 (ru) 1996-05-03 1997-05-01 Каталитическая композиция на носителе и способ полимеризации олефиновых мономеров

Country Status (10)

Country Link
EP (1) EP0896589A1 (ru)
JP (1) JP2000509740A (ru)
KR (1) KR20000010947A (ru)
AU (1) AU2411497A (ru)
BR (1) BR9708973A (ru)
CA (1) CA2253460A1 (ru)
EA (1) EA199800979A1 (ru)
ID (1) ID17297A (ru)
NO (1) NO985128L (ru)
WO (1) WO1997042228A1 (ru)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6100414A (en) * 1998-04-02 2000-08-08 Eastman Chemical Company Cyclopentadienyl transition metal compounds useful as polymerization catalysts
WO1999057159A1 (en) 1998-05-01 1999-11-11 Exxon Chemical Patents Inc. Tridentate ligand-containing metal catalyst complexes for olefin polymerization
US6403773B1 (en) 1998-09-30 2002-06-11 Exxon Mobil Chemical Patents Inc. Cationic group 3 catalyst system
EP1013670B1 (en) * 1998-12-21 2004-04-14 SABIC Polyethylenes B.V. Process for the polymerisation of olefins
CA2424370A1 (en) 2000-10-19 2002-04-25 Exxonmobil Chemical Patents Inc. Cationic group-3 catalyst system
MXPA03003647A (es) 2000-10-25 2004-01-26 Exxonmobil Chem Patents Inc Sistema catalizador cationico.
US7196148B2 (en) 2001-10-25 2007-03-27 Exxon Mobil Chemical Patents Inc. Cationic catalyst system
US9695254B2 (en) 2012-11-26 2017-07-04 Braskem S.A. Metallocene catalyst supported by hybrid supporting means, process for producing same, polymerization process for producing an ethylene homopolymer or copolymer with broad or bimodal molar mass distribution, use of the supported metallocene catalyst and ethylene polymer with broad or bimodal molar mass distribution

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4139262A1 (de) * 1991-11-29 1993-06-03 Basf Ag Getraegerte katalysatorsysteme zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alkenen
KR100287389B1 (ko) * 1992-10-02 2001-04-16 그래햄 이. 테일러 올레핀 중합반응을 위한 지지된 균일한 촉매(supported homogeneous catalyst complexes for olefin polymerization)
ES2140557T3 (es) * 1993-11-19 2000-03-01 Exxon Chemical Patents Inc Sistemas cataliticos de polimerizacion, su produccion y uso.
ES2116776T3 (es) * 1994-10-31 1998-07-16 Dsm Nv Composicion catalitica y procedimiento para la polimerizacion de una olefina.

Also Published As

Publication number Publication date
ID17297A (id) 1997-12-18
NO985128D0 (no) 1998-11-03
AU2411497A (en) 1997-11-26
JP2000509740A (ja) 2000-08-02
KR20000010947A (ko) 2000-02-25
EP0896589A1 (en) 1999-02-17
CA2253460A1 (en) 1997-11-13
NO985128L (no) 1998-11-03
BR9708973A (pt) 1999-08-03
WO1997042228A1 (en) 1997-11-13

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