ES2128511T3 - Catalizador y procedimiento para la epoxidacion de compuestos olefinicos. - Google Patents

Catalizador y procedimiento para la epoxidacion de compuestos olefinicos.

Info

Publication number
ES2128511T3
ES2128511T3 ES94303144T ES94303144T ES2128511T3 ES 2128511 T3 ES2128511 T3 ES 2128511T3 ES 94303144 T ES94303144 T ES 94303144T ES 94303144 T ES94303144 T ES 94303144T ES 2128511 T3 ES2128511 T3 ES 2128511T3
Authority
ES
Spain
Prior art keywords
epoxidation
olephine
catalyst
compounds
procedure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94303144T
Other languages
English (en)
Inventor
Gunnar Olason
David C Sherrington
Matthew More Miller
Malcolm John Cunnington
Sydney Simpson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP Chemicals Ltd
Original Assignee
BP Chemicals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BP Chemicals Ltd filed Critical BP Chemicals Ltd
Application granted granted Critical
Publication of ES2128511T3 publication Critical patent/ES2128511T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/165—Polymer immobilised coordination complexes, e.g. organometallic complexes
    • B01J31/1658—Polymer immobilised coordination complexes, e.g. organometallic complexes immobilised by covalent linkages, i.e. pendant complexes with optional linking groups, e.g. on Wang or Merrifield resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/14—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic peracids, or salts, anhydrides or esters thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B01J2231/72—Epoxidation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/50—Complexes comprising metals of Group V (VA or VB) as the central metal
    • B01J2531/56—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/64—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/66—Tungsten

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Epoxy Compounds (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

UNA COMPOSICION CATALIZADORA QUE TIENE UNA ALTA ACTIVIDAD DE EPOXIDACION PARA LA LIXIVIACION DE SU METAL COMPRENDE MOLIBDENO, VANADIO, TUNGSTENO Y/O TITANIO UNIDOS A UN SOPORTE ORGANICO O INORGANICO A TRAVES DE LA INTERMEDIACION DE UN LIGANTE IMIDAZOL. EL CATALIZADOR PUEDE USARSE EN LA EPOXIDACION DE COMPUESTOS OLEFINICOS.
ES94303144T 1993-05-07 1994-04-29 Catalizador y procedimiento para la epoxidacion de compuestos olefinicos. Expired - Lifetime ES2128511T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB939309458A GB9309458D0 (en) 1993-05-07 1993-05-07 Process

Publications (1)

Publication Number Publication Date
ES2128511T3 true ES2128511T3 (es) 1999-05-16

Family

ID=10735115

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94303144T Expired - Lifetime ES2128511T3 (es) 1993-05-07 1994-04-29 Catalizador y procedimiento para la epoxidacion de compuestos olefinicos.

Country Status (6)

Country Link
US (2) US5420313A (es)
EP (1) EP0623389B1 (es)
JP (1) JPH06343872A (es)
DE (1) DE69416539T2 (es)
ES (1) ES2128511T3 (es)
GB (1) GB9309458D0 (es)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL9201482A (nl) * 1992-08-20 1994-03-16 Dsm Nv Epoxidatie Katalysator.
US6028025A (en) * 1996-10-21 2000-02-22 Massachusetts Institute Of Technology Metalloporphyrin oxidation catalyst covalently coupled to an inorganic surface and method making same
US7217754B2 (en) * 1997-02-26 2007-05-15 Integument Technologies, Inc. Polymer composites and methods for making and using same
US6548590B1 (en) 2000-03-22 2003-04-15 Integument Technologies, Inc. Polymer and inorganic-organic hybrid composites and methods for making and using same
US5977241A (en) * 1997-02-26 1999-11-02 Integument Technologies, Inc. Polymer and inorganic-organic hybrid composites and methods for making same
CA2281638C (en) * 1997-02-26 2004-11-23 Integument Technologies, Inc. Polymer composites and methods for making and using same
US6232386B1 (en) 1997-02-26 2001-05-15 Integument Technologies, Inc. Polymer composites having an oxyhalo surface and methods for making same
EP0979220B1 (de) * 1997-04-24 2002-06-19 SASOL Germany GmbH Einstufiges verfahren zur herstellung von alpha-hydroxyethern durch oxidation c=c-ungesättigter verbindungen mit hydroperoxiden
US6045588A (en) 1997-04-29 2000-04-04 Whirlpool Corporation Non-aqueous washing apparatus and method
GB9712596D0 (en) * 1997-06-16 1997-08-20 Bp Chem Int Ltd Chemical process
JP2001151764A (ja) * 1999-11-19 2001-06-05 Nof Corp エポキシ化合物の製造方法
JP2002145872A (ja) * 2000-11-01 2002-05-22 Maruzen Petrochem Co Ltd エポキシ化合物の製造方法
DE60104809T2 (de) * 2001-02-07 2005-01-05 Saudi Basic Industries Corp. Katalysatorzusammensetzung für die Olefinpolymerisation und Verfahren zu ihrer Herstellung
ES2243601T3 (es) * 2001-02-15 2005-12-01 Saudi Basic Industries Corporation Composicion de catalizador soportado para la polimerizacion de olefinas, procedimiento para su preparacion y polimerizacion usando la misma.
DE10164467A1 (de) * 2001-12-20 2003-07-10 Inst Angewandte Chemie Berlin Katalysatoren für die Epoxidierung olefinischer Verbindungen
US7300468B2 (en) 2003-10-31 2007-11-27 Whirlpool Patents Company Multifunctioning method utilizing a two phase non-aqueous extraction process
US7695524B2 (en) 2003-10-31 2010-04-13 Whirlpool Corporation Non-aqueous washing machine and methods
WO2005106105A1 (en) 2004-04-29 2005-11-10 Unilever N.V. Dry cleaning method
US7966684B2 (en) 2005-05-23 2011-06-28 Whirlpool Corporation Methods and apparatus to accelerate the drying of aqueous working fluids
JP4910503B2 (ja) 2005-08-25 2012-04-04 住友化学株式会社 プロピレンオキサイドの製造方法
WO2007050678A2 (en) * 2005-10-25 2007-05-03 University Of Kansas Process for selective oxidation of olefins to epoxides
JP4517155B2 (ja) * 2006-07-10 2010-08-04 国立大学法人 千葉大学 ビスイミダゾリン配位子及びそれを用いた触媒
JP5270932B2 (ja) * 2008-03-03 2013-08-21 株式会社ダイセル エポキシ化合物の製造方法
KR101088197B1 (ko) * 2009-05-11 2011-11-30 서울대학교산학협력단 퓨란계 화합물 합성용 불균일 금속촉매 및 그 제조방법
GB0913318D0 (en) 2009-07-31 2009-09-02 Univ Loughborough Process
CN103539762B (zh) * 2012-07-12 2016-01-13 中国石油化工股份有限公司 丙烯环氧化生产环氧丙烷的方法
JP6213932B2 (ja) * 2013-03-29 2017-10-18 国立大学法人 東京大学 エポキシ化合物の製造方法

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1549184A (es) * 1967-02-07 1968-12-13
US4098727A (en) * 1970-07-23 1978-07-04 Mobil Oil Corporation Insoluble polymers having functional groups containing chemically bonded Group VIII metal
US3980662A (en) * 1973-06-19 1976-09-14 Sumitomo Chemical Company, Limited Process for preparing acid amides
US3985679A (en) * 1975-04-28 1976-10-12 Celanese Corporation Transition metal catalyst supported on particulate high surface area BBB type polymer
JPS51141866A (en) * 1975-05-30 1976-12-07 Mitsui Petrochem Ind Ltd Process for preparing rhodium-imidazole complex
US4066705A (en) * 1975-10-22 1978-01-03 Celanese Corporation Polybenzimidazole fiber supported catalyst
US4189448A (en) * 1978-07-14 1980-02-19 Conoco, Inc. Polypyridinerhodiumcarbonyl and iridium carbonyl hydride and halide hydroformylation catalysts
US4264117A (en) * 1979-12-21 1981-04-28 Amp Incorporated Socket for wedge base incandescent lamp
FR2528852A1 (fr) * 1982-06-21 1983-12-23 Inst Francais Du Petrole Nouveaux complexes peroxydiques du vanadium, du niobium et du tantale, leur procede de fabrication et leur utilisation comme reactifs et comme catalyseurs d'epoxydation des olefines et d'hydroxylation des hydrocarbures
DE3539268A1 (de) * 1985-11-06 1987-05-07 Degussa Verfahren zur katalytischen epoxidation von olefinen mit wasserstoffperoxid
US4800188A (en) * 1987-03-20 1989-01-24 Hoechst Celanese Corp. Method for supporting metalloporphyrins on polybenzimidazole porous articles
EP0283753B1 (de) * 1987-03-25 1990-09-19 Degussa Aktiengesellschaft Verfahren zur katalytischen Epoxidation von Olefinen mit Wasserstoffperoxid
IT1217608B (it) * 1988-05-17 1990-03-30 Istituto Guido Donegami Spa Processo per la preparazione di epossidi
FR2650761B1 (fr) * 1989-08-10 1994-03-04 Elf Aquitaine Ste Nale Catalyseur d'oxydation a base de metalloporphyrine sur support
JPH03235234A (ja) * 1990-02-09 1991-10-21 Canon Inc 情報記録媒体用基板シートの成形用ロール型の製造方法
US5166372A (en) * 1992-02-07 1992-11-24 Arco Chemical Technology, L.P. Epoxidation process

Also Published As

Publication number Publication date
EP0623389A1 (en) 1994-11-09
US5807803A (en) 1998-09-15
DE69416539T2 (de) 1999-06-24
EP0623389B1 (en) 1999-02-17
US5420313A (en) 1995-05-30
DE69416539D1 (de) 1999-03-25
GB9309458D0 (en) 1993-06-23
JPH06343872A (ja) 1994-12-20

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