AR045271A1 - Catalizadores que contienen metales de transicion, procesos para su preparacion y su uso como catalizadores de oxidacion y deshidrogenacion - Google Patents

Catalizadores que contienen metales de transicion, procesos para su preparacion y su uso como catalizadores de oxidacion y deshidrogenacion

Info

Publication number
AR045271A1
AR045271A1 ARP040102948A ARP040102948A AR045271A1 AR 045271 A1 AR045271 A1 AR 045271A1 AR P040102948 A ARP040102948 A AR P040102948A AR P040102948 A ARP040102948 A AR P040102948A AR 045271 A1 AR045271 A1 AR 045271A1
Authority
AR
Argentina
Prior art keywords
oxidation
formaldehyde
catalyst
carbon
preparation
Prior art date
Application number
ARP040102948A
Other languages
English (en)
Inventor
Fuchen Liu
Juan Arhancet
Robert Mccall
David A Morgenstern
Kam-To Wan
Original Assignee
Monsanto Technology Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Technology Llc filed Critical Monsanto Technology Llc
Publication of AR045271A1 publication Critical patent/AR045271A1/es

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24Nitrogen compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/20Carbon compounds
    • B01J27/22Carbides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/617500-1000 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/618Surface area more than 1000 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • B01J37/082Decomposition and pyrolysis
    • B01J37/084Decomposition of carbon-containing compounds into carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00Nanotechnology for materials or surface science, e.g. nanocomposites
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/68Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C249/00Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C249/02Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton of compounds containing imino groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/38Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808Acyclic saturated acids which can have further substituents on alkyl
    • C07F9/3813N-Phosphonomethylglycine; Salts or complexes thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72Copper
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/582Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Nanotechnology (AREA)
  • Molecular Biology (AREA)
  • Health & Medical Sciences (AREA)
  • Composite Materials (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • General Health & Medical Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Biochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Catálisis heterogénea y más particularmente catalizadores que incluyen soportes de carbón a partir de los cuales se forman preparados que contiene un metal de transmisión combinado con nitrógeno y/o carbono. La presente se relaciona además con los campos de las reacciones de oxidación y deshidrogenación catalíticas, que incluyen la preparación de aminas secundarias mediante la oxidación catalítica de aminas terciarias y la preparación de ácidos carboxílicos mediante la deshidrogenación de alcoholes. Reivindicación 154: Un proceso para la oxidación de un sustrato orgánico, caracterizado porque dicho proceso comprende poner en contacto dicho sustrato con un agente oxidante en presencia de un catalizador de oxidación, donde dicho catalizador de oxidación comprende un soporte de carbón sobre el cual se ha formado una composición de un metal de transición que comprende un metal de transición, carbono y nitrógeno; caracterizándose dicho catalizador por su eficacia para catalizar la oxidación de formaldehído, de modo tal que cuando una solución acuosa representativa que contiene aproximadamente 0,8 % en peso de formaldehído y un pH de aproximadamente 1,5 se pone en contacto con un agente oxidante en presencia de dicho catalizador a una temperatura de aproximadamente 100° C, al menos aproximadamente el 5 % de dicho formaldehído se transforma en ácido fórmico, dióxido de carbono y/o agua; o de modo tal que cuando una solución acuosa representativa que contiene aproximadamente 0,8 % en peso de formaldehído y aproximadamente 6 % en peso de ácido N-(fosfonometil)iminodiacético y que tiene un pH de aproximadamente 1,5 se pone en contacto con un agente oxidante en presencia de dicho catalizador a una temperatura de aproximadamente 100° C, al menos aproximadamente el 50 % del formaldehído se transforma en ácido fórmico, dióxido de carbono y/o agua.
ARP040102948A 2003-08-14 2004-08-17 Catalizadores que contienen metales de transicion, procesos para su preparacion y su uso como catalizadores de oxidacion y deshidrogenacion AR045271A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US49548103P 2003-08-14 2003-08-14

Publications (1)

Publication Number Publication Date
AR045271A1 true AR045271A1 (es) 2005-10-19

Family

ID=34193315

Family Applications (2)

Application Number Title Priority Date Filing Date
ARP040102948A AR045271A1 (es) 2003-08-14 2004-08-17 Catalizadores que contienen metales de transicion, procesos para su preparacion y su uso como catalizadores de oxidacion y deshidrogenacion
ARP110103686A AR083305A2 (es) 2003-08-14 2011-10-04 Catalizador, proceso para prepararlo, proceso para la oxidacion de un sustrato organico y proceso para preparar una sal de acido carboxilico

Family Applications After (1)

Application Number Title Priority Date Filing Date
ARP110103686A AR083305A2 (es) 2003-08-14 2011-10-04 Catalizador, proceso para prepararlo, proceso para la oxidacion de un sustrato organico y proceso para preparar una sal de acido carboxilico

Country Status (11)

Country Link
US (3) US7932419B2 (es)
EP (2) EP2460586A3 (es)
CN (2) CN102276644B (es)
AR (2) AR045271A1 (es)
AU (1) AU2004264436B2 (es)
BR (1) BRPI0413586A (es)
CA (1) CA2534819C (es)
ES (1) ES2407031T3 (es)
MX (1) MXPA06001800A (es)
TW (1) TW200517179A (es)
WO (1) WO2005016519A1 (es)

Families Citing this family (93)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1491253A1 (en) * 2003-06-26 2004-12-29 Urea Casale S.A. Fluid bed granulation process and apparatus
WO2005016519A1 (en) * 2003-08-14 2005-02-24 Monsanto Technology Llc Transition metal-carbide and nitride containing catalysts , their preparation and use as oxidation and dehydrogenation catalysts
WO2006031938A2 (en) * 2004-09-15 2006-03-23 Monsanto Technology Llc Oxidation catalyst and its use for catalyzing liquid phase oxidation reactions
US8198479B2 (en) 2005-02-17 2012-06-12 Monsanto Technology Llc Transition metal-containing catalysts and catalyst combinations including transition metal-containing catalysts and processes for their preparation and use as oxidation catalysts
CN102792969B (zh) 2005-03-04 2015-01-21 孟山都技术公司 减轻用除草剂草甘膦制剂处理的草甘膦耐受性转基因棉花植物内的坏死
BRPI0607713A2 (pt) 2005-04-01 2009-09-22 Monsanto Technology Llc métodos para monitorar ou detectar a conversão do ácido n-(fosfonometil) iminodiacético para n-(fosfonometil)glicina ou outro intermediário para n-(fosfonometil)glicina no curso da oxidação catalìtica de ácido n-(fosfonometil)iminodiacético em um meio aquoso
US7767616B2 (en) * 2005-05-26 2010-08-03 Uchicago Argonne, Llc Aligned carbon nanotube with electro-catalytic activity for oxygen reduction reaction
US20070254206A1 (en) * 2006-01-17 2007-11-01 Gillan Edward G Methods for production of metals on carbon nitride powders and composites and their use as catalysts in fuel cell electrochemistry
CN102600808A (zh) * 2006-01-30 2012-07-25 高级技术材料公司 纳米多孔碳材料,以及利用其的系统和方法
CA2642226A1 (en) * 2006-02-17 2007-08-30 Monsanto Technology Llc Transition metal-containing catalysts and processes for their preparation and use as fuel cell catalysts
US7704553B2 (en) * 2006-03-06 2010-04-27 National Institute Of Aerospace Associates Depositing nanometer-sized particles of metals onto carbon allotropes
US20080233402A1 (en) * 2006-06-08 2008-09-25 Sid Richardson Carbon & Gasoline Co. Carbon black with attached carbon nanotubes and method of manufacture
CN101143329A (zh) * 2006-09-11 2008-03-19 德古萨股份公司 Mo-O-K基催化剂、其制备方法及其在甲硫醇合成中的应用
EP1941946A1 (en) 2007-01-04 2008-07-09 Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. Carbonitrides as catalysts
US7771494B2 (en) 2007-01-31 2010-08-10 Monsanto Technology Llc Process for selective removal of water and impurities from N-(phosphonomethyl)glycine
JP5571547B2 (ja) 2007-04-09 2014-08-13 プレジデント アンド フェローズ オブ ハーバード カレッジ 銅の相互接続体のための窒化コバルト層及びそれらを形成する方法
EP2135313B1 (en) * 2007-04-12 2011-09-14 3M Innovative Properties Company High performance, high durability non-precious metal fuel cell catalysts
WO2009014959A2 (en) * 2007-07-20 2009-01-29 United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Tailorable dielectric material with complex permittivity characteristics
WO2009029539A1 (en) * 2007-08-24 2009-03-05 Monsanto Technology Llc Mixtures and catalyst systems including transition metal-containing catalysts and noble metal-containing catalysts, processes for their preparation, and processes for their use in oxidation reactions
US8852547B2 (en) * 2008-01-25 2014-10-07 Hyperion Catalysis International, Inc. Processes for the recovery of catalytic metal and carbon nanotubes
US20110008715A1 (en) * 2008-03-28 2011-01-13 Belabbes Merzougui Platinum loaded substrate for a fuel cell and method for producing same
US20100055422A1 (en) * 2008-08-28 2010-03-04 Bob Kong Electroless Deposition of Platinum on Copper
KR101753918B1 (ko) 2009-04-17 2017-07-04 시어스톤 엘엘씨 탄소 산화물을 환원시켜 고형 탄소를 제조하는 방법
US8669396B2 (en) 2009-05-18 2014-03-11 Monsanto Technology Llc Recovery of phosphorus values and salt impurities from aqueous waste streams
JP5538760B2 (ja) * 2009-07-03 2014-07-02 清蔵 宮田 酸化触媒、還元触媒及び排気ガス浄化触媒
CN102802787A (zh) * 2009-11-26 2012-11-28 日清纺控股株式会社 用于分解有害物质的碳催化剂、有害物质分解材料以及分解有害物质的方法
CN101829590A (zh) * 2010-05-06 2010-09-15 东华大学 易回收氮掺杂核-壳结构ZnO/TiO2可见光光催化剂的制备
CN101869843B (zh) * 2010-06-24 2013-04-24 钱仰东 载体上金属碳化物制备和作为二乙醇胺脱氢催化剂
WO2012035501A1 (en) * 2010-09-14 2012-03-22 Basf Se Process for producing carbon-comprising support
US8709964B2 (en) 2010-09-14 2014-04-29 Basf Se Process for producing a carbon-comprising support
US8679231B2 (en) 2011-01-19 2014-03-25 Advanced Technology Materials, Inc. PVDF pyrolyzate adsorbent and gas storage and dispensing system utilizing same
CN104284861A (zh) 2012-04-16 2015-01-14 赛尔斯通股份有限公司 处理含有碳氧化物的废气的方法
CN104302575B (zh) 2012-04-16 2017-03-22 赛尔斯通股份有限公司 通过还原二氧化碳来产生固体碳的方法
JP6328611B2 (ja) 2012-04-16 2018-05-23 シーアストーン リミテッド ライアビリティ カンパニー 非鉄触媒で炭素酸化物を還元するための方法および構造
MX354526B (es) 2012-04-16 2018-03-07 Seerstone Llc Metodos y sistemas para capturar y secuestrar carbono y para reducir la masa de oxidos de carbono en una corriente de gas de desechos.
NO2749379T3 (es) 2012-04-16 2018-07-28
US9896341B2 (en) 2012-04-23 2018-02-20 Seerstone Llc Methods of forming carbon nanotubes having a bimodal size distribution
US10815124B2 (en) 2012-07-12 2020-10-27 Seerstone Llc Solid carbon products comprising carbon nanotubes and methods of forming same
JP6284934B2 (ja) 2012-07-12 2018-02-28 シーアストーン リミテッド ライアビリティ カンパニー カーボンナノチューブを含む固体炭素生成物およびそれを形成する方法
MX2015000580A (es) 2012-07-13 2015-08-20 Seerstone Llc Metodos y sistemas para formar productos de carbono solido y amoniaco.
US9779845B2 (en) 2012-07-18 2017-10-03 Seerstone Llc Primary voltaic sources including nanofiber Schottky barrier arrays and methods of forming same
JP6389824B2 (ja) 2012-11-29 2018-09-12 シーアストーン リミテッド ライアビリティ カンパニー 固体炭素材料を製造するための反応器および方法
US10086349B2 (en) 2013-03-15 2018-10-02 Seerstone Llc Reactors, systems, and methods for forming solid products
ES2900814T3 (es) 2013-03-15 2022-03-18 Seerstone Llc Electrodos que comprenden carbono nanoestructurado
WO2014151144A1 (en) 2013-03-15 2014-09-25 Seerstone Llc Carbon oxide reduction with intermetallic and carbide catalysts
EP3129133A4 (en) 2013-03-15 2018-01-10 Seerstone LLC Systems for producing solid carbon by reducing carbon oxides
WO2014150944A1 (en) 2013-03-15 2014-09-25 Seerstone Llc Methods of producing hydrogen and solid carbon
US20150273453A1 (en) * 2014-03-25 2015-10-01 Uop Llc Bismuth-modified molecular sieves and methods for preparing and using bismuth-modified molecular sieves
WO2015195773A1 (en) 2014-06-18 2015-12-23 Sid Richardson Carbon, Ltd Nanospike hybrid carbon black
CN104181206B (zh) * 2014-08-12 2016-06-08 天津大学 金掺杂多孔硅/氧化钒纳米棒气敏材料的制备方法
CN105032460B (zh) * 2015-06-23 2018-02-02 华南理工大学 基于氮化物纳米粒子的低铂催化剂及其制备方法
US10385462B2 (en) 2015-07-09 2019-08-20 Saudi Arabian Oil Company Electrode material for electrolytic hydrogen generation
CN105536835A (zh) * 2015-12-18 2016-05-04 济宁学院 一种杂原子掺杂的碳负载碳化铁/碳化钼或钨催化剂及其制备方法和应用
CN105854801A (zh) * 2016-05-10 2016-08-17 江苏大学 一种氮掺杂的多孔碳材料及其制备方法和用途
WO2018022999A1 (en) 2016-07-28 2018-02-01 Seerstone Llc. Solid carbon products comprising compressed carbon nanotubes in a container and methods of forming same
CN108070874B (zh) * 2016-11-16 2020-10-30 中国科学院大连化学物理研究所 一种原子分散的水氧化催化剂及其制备和应用
US11264630B2 (en) * 2017-02-28 2022-03-01 Okinawa Institute Of Science And Technology School Corporation Process for preparing a supported catalytic material, and supported catalytic material
US11909046B2 (en) 2017-03-07 2024-02-20 The Research Foundation For The State University Of New York Synthetic methods for crystallite size control of bimetallic polyanionic battery compositions
KR101969407B1 (ko) * 2017-09-12 2019-08-20 한국화학연구원 선택적 수소화용 촉매 및 그것을 이용하는 선택적 수소화법
CN107572498B (zh) * 2017-09-29 2019-09-20 程杰 一种碳化物掺杂多孔炭及其制备方法
CN108325549A (zh) * 2018-01-09 2018-07-27 中山大学 一种用于甲醛净化的过渡金属和氮共掺杂碳复合材料及其制备方法
CN108435225B (zh) * 2018-03-09 2020-12-11 浙江工业大学 一种Fe-N/C复合催化剂及其制备方法和应用
US10883183B2 (en) * 2018-04-13 2021-01-05 Honda Motor Co., Ltd. Method of preparing copper-copper nitride nanocatalysts for carbon dioxides reduction reaction
CN110756796B (zh) * 2018-07-25 2021-08-27 石家庄铁道大学 一种核壳结构的复合粉末及其制备方法
CN109126845B (zh) * 2018-09-03 2021-05-28 西北大学 负载型过渡金属碳化物催化剂及其一步法合成方法
CN109261182B (zh) * 2018-11-02 2021-08-03 湘潭大学 一种氮掺杂活性炭负载Cu催化剂的制备方法及其在催化糠醛加氢中的应用
CN109482212B (zh) * 2018-11-12 2020-11-13 大连理工大学 一种低温自组装碳化钼纳米线催化剂的制备及其生物质加氢脱氧应用
CN109590004B (zh) * 2018-12-13 2021-09-24 黑龙江大学 一种制备氮化钼-铜/石墨烯三元复合体的方法
CN109659535B (zh) * 2018-12-18 2021-07-16 中科廊坊过程工程研究院 一种碳化钼/碳复合材料及其制备方法和应用
CN110085863B (zh) * 2019-04-26 2024-03-12 桑顿新能源科技有限公司 石墨负极材料及其制备方法、电池
US11929512B2 (en) 2019-04-30 2024-03-12 The Board Of Trustees Of The Leland Stanford Junior University Oxidized surface layer on transition metal nitrides: active catalysts for the oxygen reduction reaction
CN111889096B (zh) * 2019-05-06 2023-07-11 中国石油化工股份有限公司 贵金属用量减少的高活性有机储氢化合物脱氢制氢气催化剂及其制备方法
CN110484930B (zh) * 2019-07-10 2020-08-11 浙江工商大学 一种用于还原二氧化碳产甲酸的电极及其制备方法和应用
CN110420655B (zh) * 2019-07-29 2022-07-08 中南民族大学 一种石墨碳包裹铁-氮-碳固相芬顿催化剂的制备方法及其应用
BR102019020257A2 (pt) * 2019-09-27 2021-04-20 Mmf&T Desenvolvimento Tecnológico E Inovação Ltda composição para saúde oral e processo de elaboração de composição para saúde oral
CN112569984B (zh) * 2019-09-30 2023-07-07 国家能源投资集团有限责任公司 含负载型θ碳化铁组合物及其制备方法、催化剂和应用以及费托合成的方法
CN110773214A (zh) * 2019-11-13 2020-02-11 广东工业大学 一种碳层嵌入式的碳化铁及其制备方法和碳层嵌入式的碳化铁作为费托合成催化剂的应用
US11187044B2 (en) 2019-12-10 2021-11-30 Saudi Arabian Oil Company Production cavern
CN111589463B (zh) * 2020-03-10 2022-08-23 上海电力大学 一种碳化铁复合一氧化钛的纳米颗粒光热催化剂及其制备
CN111672529B (zh) * 2020-04-24 2023-02-03 中国科学院金属研究所 一种纳米碳负载钴氮碳催化材料及其制备方法和应用
CN113751008B (zh) * 2020-06-05 2023-07-14 中国石油化工股份有限公司 碳包覆氧化镍的纳米复合材料及其制备方法和应用
CN111468121B (zh) * 2020-06-11 2022-06-24 北京林业大学 一种MXene改性生物质碳纳米金属催化剂的制备及应用
CN111883783A (zh) * 2020-06-19 2020-11-03 上海交通大学 一种中空非贵金属氧还原催化剂的制备方法及应用
US11460330B2 (en) 2020-07-06 2022-10-04 Saudi Arabian Oil Company Reducing noise in a vortex flow meter
CA3212507A1 (en) * 2021-03-04 2022-09-09 Monsanto Technology Llc Two-compartment bipolar membrane electrodialysis of salts of amino acids
CN113398962B (zh) * 2021-06-18 2023-04-07 润泰新材料股份有限公司 用于高选择性制备异丁醛的Co@CuC/Al2O3催化剂的制备方法
CN113304770B (zh) * 2021-06-28 2022-04-12 四川大学 一种氮改性含铬革屑制备富氮金属催化剂的方法及应用
CN113624821B (zh) * 2021-08-11 2022-11-01 山东大学 含mn2o2单元的碳材料、制备方法与检测no的应用
CN115710185B (zh) * 2021-08-23 2024-05-03 中国石油化工股份有限公司 利用金属碳化物催化剂生产甲胺的方法
CN116060003B (zh) * 2021-10-31 2024-05-07 中国石油化工股份有限公司 一种酯加氢催化剂及其制备方法和应用
CN114672846B (zh) * 2022-05-06 2023-08-11 西南科技大学 一种用于电催化co2还原的双金属催化材料的制备及应用
CN114849688B (zh) * 2022-05-23 2023-04-07 中国科学院山西煤炭化学研究所 合成丁二酸酐的金属碳化物催化剂及其制备方法和应用
CN116371407A (zh) * 2022-12-19 2023-07-04 上海船舶工艺研究所(中国船舶集团有限公司第十一研究所) 一种蛋黄型核壳催化剂Ni@HSS及其制备方法

Family Cites Families (71)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2384817A (en) * 1942-09-05 1945-09-18 Carbide & Carbon Chem Corp Catalytic alkaline oxidation of alcohols
US3143511A (en) * 1960-04-20 1964-08-04 Exxon Research Engineering Co Hydrocracking of paraffins
US3799758A (en) 1971-08-09 1974-03-26 Monsanto Co N-phosphonomethyl-glycine phytotoxicant compositions
US3871998A (en) * 1971-12-27 1975-03-18 Howard F Rase Hydrodesulfurization of heavy hydrocarbon feedstocks with nonstoichiometric titanium carbide catalyst support
US3950402A (en) * 1972-05-31 1976-04-13 Monsanto Company Process for producing N-phosphonomethyl glycine
US3950996A (en) * 1974-02-04 1976-04-20 Hydril Company Fluid pressure transducer
US3969398A (en) 1974-05-01 1976-07-13 Monsanto Company Process for producing N-phosphonomethyl glycine
US4264776A (en) * 1976-01-02 1981-04-28 Monsanto Company Production of secondary amines
JPS589764B2 (ja) 1980-04-18 1983-02-22 宇部興産株式会社 金属炭窒化物の製法
US4345038A (en) * 1980-12-15 1982-08-17 Exxon Research & Engineering Co. CO Hydrogenation process using steam and molybdenum oxycarbonitride catalyst
US4476102A (en) * 1980-11-24 1984-10-09 Exxon Research And Engineering Co. Molybdenum oxycarbonitride compositions and process for preparing the same
US4325843A (en) * 1980-12-08 1982-04-20 Shell Oil Company Process for preparing a supported tungsten carbide composition
US4325842A (en) * 1980-12-08 1982-04-20 Shell Oil Company Process for preparing a supported molybdenum carbide composition
US4326992A (en) * 1980-12-08 1982-04-27 Shell Oil Company Process for preparing a supported molybdenum carbide composition
US4522706A (en) * 1982-06-16 1985-06-11 Exxon Research & Engineering Co. Hydrocarbon treating processes using perovskite-containing catalytic compositions
FR2543152B1 (fr) 1983-03-25 1985-06-14 Eurotungstene Poudres Catalyseurs de reformage a base de carbures de tungstene et/ou molybdene et leur methode d'utilisation
GB2148287B (en) 1983-10-05 1987-04-15 Nippon Catalytic Chem Ind Preparation of aminocarboxylic acid salts from amino alcohols
US4624937A (en) * 1984-05-10 1986-11-25 Monsanto Company Process for removing surface oxides from activated carbon catalyst
US4775498A (en) 1984-12-05 1988-10-04 Monsanto Company Process for preparing N,N-diacetic acid aminomethylenephosphonic acid
US4579689A (en) * 1985-02-11 1986-04-01 Monsanto Company Oxidation with coated catalyst
US4582650A (en) * 1985-02-11 1986-04-15 Monsanto Company Oxidation with encapsulated co-catalyst
US4696772A (en) * 1985-02-28 1987-09-29 Monsanto Company Amine oxidation using carbon catalyst having oxides removed from surface
US4895680A (en) * 1987-01-02 1990-01-23 Sun Refining And Marketing Company Hydrocarbon oxidations catalyzed by nitride-activated metal coordination complexes
US4853159A (en) * 1987-10-26 1989-08-01 Monsanto Company Process for producing N-phosphonomethylglycine
US5138111A (en) * 1988-05-23 1992-08-11 Exxon Research And Engineering Company Eta phase materials, methods of producing the same, and use thereof as catalysts for alcohol synthesis, hydrocarbon synthesis, hydrocarbon hydrogenation and hydrocarbon conversion reactions
DK0439445T3 (da) 1990-01-26 1995-12-27 Monsanto Co Fremgangsmåde til fremstilling af N-phosphonomethylglycin
ES2021229A6 (es) 1990-03-12 1991-10-16 Ercros Sa Perfeccionamientos introducidos en un procedimiento de obtencion de n-fosfonometilglicina por oxidacion de n-fosfonometiliminodiacetico.
US5023369A (en) * 1990-06-25 1991-06-11 Monsanto Company Process for producing N-phosphonomethylglycine
US5043475A (en) * 1990-06-25 1991-08-27 Monsanto Company Peroxide process for producing N-phosphonomethylglycine
FR2684091B1 (fr) 1991-11-21 1994-02-25 Pechiney Recherche Procede de fabrication de carbures metalliques a grande surface specifique sous balayage de gaz inerte a pression atmospherique.
US5240893A (en) * 1992-06-05 1993-08-31 General Motors Corporation Method of preparing metal-heterocarbon-nitrogen catalyst for electrochemical cells
US5338716A (en) 1992-12-01 1994-08-16 Akzo Nobel Nv Non-oxide metal ceramic catalysts comprising metal oxide support and intermediate ceramic passivating layer
US5292936A (en) 1993-04-12 1994-03-08 Monsanto Company Process to prepare amino carboxylic acid salts
EP0694030B2 (en) 1993-04-12 2003-01-02 Monsanto Company Process to prepare amino carboxylic acid salts
DE4336829C2 (de) 1993-10-28 1997-04-10 Daub Joachim Dipl Geol Oek Verfahren zur Herstellung von dotierten Metall-Trägerkatalysatoren und deren Verwendung
JPH07141575A (ja) 1993-11-18 1995-06-02 Casio Comput Co Ltd 商品情報問い合せ応答方法
US5573991A (en) * 1994-02-24 1996-11-12 Akzo Nobel N.V. Preparation of metal carbide catalyst supported on carbon
US5689000A (en) 1994-07-01 1997-11-18 Monsanto Company Process for preparing carboxylic acid salts and catalysts useful in such process
US5606107A (en) 1995-06-07 1997-02-25 Monsanto Company Formic acid and formaldehyde destruction in waste streams
US6329478B1 (en) * 1995-07-14 2001-12-11 Sumitmo Chemical Company, Limited Transition metal complex, process for producing the same, olefin polymerization catalyst containing the transition metal complex and process for producing olefin polymers
WO1998001481A1 (de) * 1996-07-04 1998-01-15 Basf Aktiengesellschaft Verfahren zur herstellung von geträgerten übergangsmetallkatalysatoren
US6169152B1 (en) * 1996-07-05 2001-01-02 Jsr Corporation Olefin polymerization catalyst comprising transition metal compound containing a cyclic ligand having at least two nitrogen atoms in its main chain skeleton
HUP9904636A3 (en) 1996-09-26 2000-08-28 Akzo Nobel Nv Catalyst for dehydrogenation of amino alcohols or of ethylene glycol(derivatives), method for their production and their use
US5989648A (en) 1997-05-06 1999-11-23 The Penn State Research Foundation Plasma generation of supported metal catalysts
EP1062221B1 (en) * 1998-02-12 2006-05-10 Monsanto Technology LLC Process for making glyphosate by oxidizing n-substituted glyphosates
DE19806435A1 (de) * 1998-02-17 1999-08-19 Basf Ag Verfahren zur Herstellung eines geträgerten Katalysatorsystems
US6417133B1 (en) * 1998-02-25 2002-07-09 Monsanto Technology Llc Deeply reduced oxidation catalyst and its use for catalyzing liquid phase oxidation reactions
US6436816B1 (en) 1998-07-31 2002-08-20 Industrial Technology Research Institute Method of electroless plating copper on nitride barrier
US6809229B2 (en) 1999-01-12 2004-10-26 Hyperion Catalysis International, Inc. Method of using carbide and/or oxycarbide containing compositions
US6936565B2 (en) * 1999-01-12 2005-08-30 Hyperion Catalysis International, Inc. Modified carbide and oxycarbide containing catalysts and methods of making and using thereof
EA200101087A1 (ru) 1999-04-15 2002-04-25 Е.И.Дюпон Де Немур Энд Компани Катализатор на основе оксида ванадия - фосфора с теплопроводящим носителем
AUPP976499A0 (en) 1999-04-16 1999-05-06 Commonwealth Scientific And Industrial Research Organisation Multilayer carbon nanotube films
CA2381412A1 (en) * 1999-08-11 2001-02-22 Basf Aktiengesellschaft Method for the production of phosphonomethylglycin
FR2798079B1 (fr) 1999-09-02 2001-09-28 Inst Francais Du Petrole Catalyseur comprenant un nitrure de metal du groupe vib, du phosphore et son utilisation pour l'hydrodesulfuration et l'hydrogenation des coupes aromatiques
FR2798135B1 (fr) 1999-09-02 2001-10-26 Inst Francais Du Petrole Procede d'isomerisation d'une charge comprenant des paraffines a l'aide d'un catalyseur comprenant du phosphore et un nitrure de metal du groupe vib
US6461539B1 (en) 1999-10-18 2002-10-08 Conoco Inc. Metal carbide catalysts and process for producing synthesis gas
WO2001046208A2 (en) 1999-12-21 2001-06-28 Monsanto Technology Llc Use of a supplemental promoter in conjunction with a carbon-supported, noble-metal-containing catalyst in liquid phase oxidation reactions
US6448454B1 (en) 2000-04-07 2002-09-10 The University Of Kansas Catalytic oxidation of organic substrates by transition metal complexes in organic solvent media expanded by supercritical or subcritical carbon dioxide
US6376708B1 (en) 2000-04-11 2002-04-23 Monsanto Technology Llc Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts
DK1283841T3 (da) * 2000-05-22 2006-04-10 Monsanto Technology Llc Reaktionssystem til fremstilling af N-(phosphonomethyl)glycinforbindelser
US6632770B2 (en) 2000-12-22 2003-10-14 Univation Technologies, Llc Catalyst system and its use in a polymerization process
EP1236509A1 (en) 2001-02-23 2002-09-04 Degussa Aktiengesellschaft Catalytic precious metal-treated carbon black
US6696384B2 (en) * 2001-04-11 2004-02-24 Meadwestvaco Corporation Method of making shaped activated carbon
WO2002098557A1 (en) 2001-06-04 2002-12-12 Conoco Inc. Supported rhodium-lanthanide based catalysts and process for producing synthesis gas
US6689711B2 (en) * 2001-10-09 2004-02-10 Metallic Power, Inc. Methods of producing oxygen reduction catalyst
WO2003068387A1 (en) 2002-02-14 2003-08-21 Monsanto Technology Llc Oxidation catalyst and process for its preparation and process for oxidation using it
AU2003233738A1 (en) * 2002-06-05 2003-12-22 University Technologies International Inc. Oxygen reduction catalyst
US6764874B1 (en) 2003-01-30 2004-07-20 Motorola, Inc. Method for chemical vapor deposition of single walled carbon nanotubes
WO2005016519A1 (en) * 2003-08-14 2005-02-24 Monsanto Technology Llc Transition metal-carbide and nitride containing catalysts , their preparation and use as oxidation and dehydrogenation catalysts
FR2865468B1 (fr) 2004-01-22 2006-04-28 Ceca Sa Charbon actif a resistance mecanique amelioree, ses utilisations, notamment comme support de catalyseur.
CA2642226A1 (en) * 2006-02-17 2007-08-30 Monsanto Technology Llc Transition metal-containing catalysts and processes for their preparation and use as fuel cell catalysts

Also Published As

Publication number Publication date
CA2534819A1 (en) 2005-02-24
TW200517179A (en) 2005-06-01
AU2004264436A1 (en) 2005-02-24
CN102276644B (zh) 2014-09-03
MXPA06001800A (es) 2006-05-04
US7932419B2 (en) 2011-04-26
EP1684900A1 (en) 2006-08-02
CA2534819C (en) 2013-07-02
CN1867404B (zh) 2011-06-22
EP2460586A2 (en) 2012-06-06
US20050176989A1 (en) 2005-08-11
BRPI0413586A (pt) 2006-10-17
ES2407031T3 (es) 2013-06-11
EP1684900B1 (en) 2013-02-27
CN102276644A (zh) 2011-12-14
AR083305A2 (es) 2013-02-13
EP2460586A3 (en) 2012-11-14
US20110301381A1 (en) 2011-12-08
US8697904B2 (en) 2014-04-15
US20140235432A1 (en) 2014-08-21
WO2005016519A1 (en) 2005-02-24
US9120081B2 (en) 2015-09-01
AU2004264436B2 (en) 2010-11-25
CN1867404A (zh) 2006-11-22

Similar Documents

Publication Publication Date Title
AR045271A1 (es) Catalizadores que contienen metales de transicion, procesos para su preparacion y su uso como catalizadores de oxidacion y deshidrogenacion
ES2194505T3 (es) Proceso de dos fases para la produccion de 1,3-propanodiol por hidrogenacion catalitica de 3-hidroxipropanal.
AR055033A1 (es) Catalizadores que contienen metales de transicion y combinaciones de catalizadores que incluyen catalizadores que contienen metales de transicion y procesos para su preparacion y uso como catalizadores de oxidacion
BR0008825A (pt) Processo para a oxidação catalìtica em fase gasosa de acroleìna para ácido acrìlico
AR029852A1 (es) Produccion de acidos carboxilicos aromaticos
BR0304777A (pt) Processo para a preparação de um catalisador para oxidação e amoxidação de olefinas
BR9911431A (pt) Processo para produção de uma solução aquosa de ácido monoéster peroxicarboxìlico
TR200103844T2 (tr) 3-Hidroksipropanal'ın 1,3-Propandiyol'e katalitik hidrojenasyonu
ES2160634T3 (es) Sistemas catalizadores de polimerizacion, su produccion y uso.
BRPI0512020A (pt) processo de regeneração de catalisador
CO5050382A1 (es) Catalizador a base de ferrierita hierro para la reduccion catalitica del contenido de gas en protoxido de nitrogeno, su procedimiento de obtencion, aplicacion al tratamiento de gases industriales
PE65199A1 (es) Catalizador de acetato de vinilo que comprende paladio, oro, cobre y un cuarto metal
BR0207175B1 (pt) sistema catalisador para polimerizaÇço de olefina, processo para preparaÇço do referido sistema e processo de polimerizaÇço de olefina.
BR9207023A (pt) Processo para a preparação de ácidos carboxílicos ou ésteres deles derivados pela clivagem oxidativa de ácidos graxos insaturados ou ésteres deles derivados
MXPA05008754A (es) Catalizador para producir acido metacrilico y metodo de preparacion del mismo.
ES2149620T3 (es) Procedimiento para la preparacion de polioleteres.
RU2008108096A (ru) Способ получения 4,4'-дифторбензофенона
BR0014456A (pt) Processos para ativação por hidrogênio em alta temperatupa e alta pressão de ferro passivado, e para hidrogenação na presença d um catalizador heterogênio, métodos para uso de nitrilas, e para uso de ferro, e, ferro catalìtico
PT1385850E (pt) Novo processo para a preparacao de oxabispidinas
ES2069982T3 (es) Preparacion de catalizador a partir de oxidos metalicos por reduccion y carburacion parcial por los gases reaccionantes.
AR045964A1 (es) Procedimiento para producir 1,3-propanodiol mediante hidrogenacion catalitica de 3-hidroxipropanal en presencia de un co-catalizador de hidratacion
BR0010302A (pt) Catalisadores de cianeto metálico duplo para a produção de polieterpolióis
AR042396A1 (es) Procedimiento para la preparacion de un catalizador de alcoxilacion fluido de tierras raras y un procedimiento para la preparacion de oxido de alquileno
BR0103412A (pt) Processo para fabricação de (all-rac)-alfa-tocoferol
BR9901155A (pt) Método para a preparação de sais de ácidos carboxìlicos.

Legal Events

Date Code Title Description
FG Grant, registration