FR2865468B1 - Charbon actif a resistance mecanique amelioree, ses utilisations, notamment comme support de catalyseur. - Google Patents

Charbon actif a resistance mecanique amelioree, ses utilisations, notamment comme support de catalyseur.

Info

Publication number
FR2865468B1
FR2865468B1 FR0400568A FR0400568A FR2865468B1 FR 2865468 B1 FR2865468 B1 FR 2865468B1 FR 0400568 A FR0400568 A FR 0400568A FR 0400568 A FR0400568 A FR 0400568A FR 2865468 B1 FR2865468 B1 FR 2865468B1
Authority
FR
France
Prior art keywords
mechanical strength
catalyst support
improved mechanical
active charcoal
charcoal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR0400568A
Other languages
English (en)
Other versions
FR2865468A1 (fr
Inventor
Bec Remi Le
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Carbonisation et Charbons Actifs CECA SA
Original Assignee
Carbonisation et Charbons Actifs CECA SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR0400568A priority Critical patent/FR2865468B1/fr
Application filed by Carbonisation et Charbons Actifs CECA SA filed Critical Carbonisation et Charbons Actifs CECA SA
Priority to EP05717445A priority patent/EP1704117A2/fr
Priority to CN2005800088647A priority patent/CN1934030B/zh
Priority to US10/587,071 priority patent/US20070123419A1/en
Priority to PCT/FR2005/000114 priority patent/WO2005080269A2/fr
Publication of FR2865468A1 publication Critical patent/FR2865468A1/fr
Application granted granted Critical
Publication of FR2865468B1 publication Critical patent/FR2865468B1/fr
Priority to US12/781,521 priority patent/US20100278987A1/en
Priority to US13/295,880 priority patent/US20120175306A1/en
Priority to US14/579,761 priority patent/US20150182949A1/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • B01J20/28064—Surface area, e.g. B.E.T specific surface area being in the range 500-1000 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28069—Pore volume, e.g. total pore volume, mesopore volume, micropore volume
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28069—Pore volume, e.g. total pore volume, mesopore volume, micropore volume
    • B01J20/28073—Pore volume, e.g. total pore volume, mesopore volume, micropore volume being in the range 0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28069—Pore volume, e.g. total pore volume, mesopore volume, micropore volume
    • B01J20/28076—Pore volume, e.g. total pore volume, mesopore volume, micropore volume being more than 1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28078—Pore diameter
    • B01J20/2808—Pore diameter being less than 2 nm, i.e. micropores or nanopores
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28078—Pore diameter
    • B01J20/28083—Pore diameter being in the range 2-50 nm, i.e. mesopores
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28078—Pore diameter
    • B01J20/28085—Pore diameter being more than 50 nm, i.e. macropores
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24—Nitrogen compounds
    • B01J27/26—Cyanides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
    • B01J31/183—Ligands comprising condensed ring systems, e.g. acridine, carbazole with more than one complexing nitrogen atom, e.g. phenanthroline
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/2243—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • B01J35/615—
    • B01J35/617—
    • B01J35/635—
    • B01J35/638—
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/30—Active carbon
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/283—Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/72—Treatment of water, waste water, or sewage by oxidation
    • C02F1/725—Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • C10G25/003—Specific sorbent material, not covered by C10G25/02 or C10G25/03
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B01J2231/76—Dehydrogenation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/025—Ligands with a porphyrin ring system or analogues thereof, e.g. phthalocyanines, corroles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/16—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/26—Zinc
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/50—Complexes comprising metals of Group V (VA or VB) as the central metal
    • B01J2531/56—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel
    • B01J35/30—
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C02F2101/16—Nitrogen compounds, e.g. ammonia
    • C02F2101/18—Cyanides
FR0400568A 2004-01-22 2004-01-22 Charbon actif a resistance mecanique amelioree, ses utilisations, notamment comme support de catalyseur. Expired - Fee Related FR2865468B1 (fr)

Priority Applications (8)

Application Number Priority Date Filing Date Title
FR0400568A FR2865468B1 (fr) 2004-01-22 2004-01-22 Charbon actif a resistance mecanique amelioree, ses utilisations, notamment comme support de catalyseur.
CN2005800088647A CN1934030B (zh) 2004-01-22 2005-01-19 具有改进的抗机械性的活性炭、及其用途、特别是作为催化剂载体
US10/587,071 US20070123419A1 (en) 2004-01-22 2005-01-19 Activated carbon with improved mechanical resistance, and the uses thereof, especially as a catalyst carrier
PCT/FR2005/000114 WO2005080269A2 (fr) 2004-01-22 2005-01-19 Charbon actif a resistance mecanique amelioree, ses utilisations, notament comme support de catalyseur
EP05717445A EP1704117A2 (fr) 2004-01-22 2005-01-19 Charbon actif a resistance mecanique amelioree, ses utilisations, notament comme support de catalyseur
US12/781,521 US20100278987A1 (en) 2004-01-22 2010-05-17 Activated carbon with improved mechanical resistance, and the uses thereof, especially as a catalyst carrier
US13/295,880 US20120175306A1 (en) 2004-01-22 2011-11-14 Activated carbon with improved mechanical resistance, and the uses thereof, especially as a catalyst carrier
US14/579,761 US20150182949A1 (en) 2004-01-22 2014-12-22 Activated carbon with improved mechanical resistance, and the uses thereof, especially as a catalyst carrier

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0400568A FR2865468B1 (fr) 2004-01-22 2004-01-22 Charbon actif a resistance mecanique amelioree, ses utilisations, notamment comme support de catalyseur.

Publications (2)

Publication Number Publication Date
FR2865468A1 FR2865468A1 (fr) 2005-07-29
FR2865468B1 true FR2865468B1 (fr) 2006-04-28

Family

ID=34717333

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0400568A Expired - Fee Related FR2865468B1 (fr) 2004-01-22 2004-01-22 Charbon actif a resistance mecanique amelioree, ses utilisations, notamment comme support de catalyseur.

Country Status (5)

Country Link
US (4) US20070123419A1 (fr)
EP (1) EP1704117A2 (fr)
CN (1) CN1934030B (fr)
FR (1) FR2865468B1 (fr)
WO (1) WO2005080269A2 (fr)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2460586A3 (fr) 2003-08-14 2012-11-14 Monsanto Technology LLC Procédé d'oxydation de l'acide N-(phosphonométhyl)iminodiacétique ou de son sel
CA2598013C (fr) 2005-02-17 2014-11-25 Monsanto Technology Llc Catalyseurs a base de metaux de transition, combinaisons de catalyseurs comprenant des catalyseurs a base de metaux de transition et leur procedes de preparation et d'utilisation en tant que catalyseurs d'oxydation
ES2301381B1 (es) * 2006-08-17 2009-06-08 Charcolive, S.L. Carbon activo de origen vegetal y procedimiento de obtencion.
KR101609484B1 (ko) * 2006-10-30 2016-04-05 쓰리엠 이노베이티브 프로퍼티즈 컴파니 아민 민감성 함침제 및 아민 민감성 기재와의 상용성이 향상된 시아노-함유 오염물을 제거하는 데 효과적인 여과제를 포함하는 필터 매체
EA018289B1 (ru) * 2007-12-19 2013-06-28 Сауди Арабиан Ойл Компани Мембранная биологическая реакторная система на основе суспендированного гранулированного активированного угля
CN101289184B (zh) * 2008-06-04 2010-09-22 福建元力活性炭股份有限公司 一种物理法化学法一体化活性炭生产工艺
CN101857807B (zh) * 2009-04-08 2013-02-13 中国石油天然气股份有限公司 一种液态烃精制的方法
TWI568687B (zh) * 2009-06-15 2017-02-01 沙烏地阿拉伯油品公司 包含懸浮系統與多重生物反應器區域的經懸浮介質膜生物反應器系統及方法
TWI491568B (zh) 2009-07-08 2015-07-11 沙烏地阿拉伯油品公司 低濃度廢水處理系統及方法
CN102548912B (zh) 2009-07-08 2015-06-17 沙特阿拉伯石油公司 包括主要固体的辐射的废水处理系统和方法
CN102553641B (zh) * 2010-12-08 2014-02-12 中国中化股份有限公司 一种含氮活性炭催化剂的制备方法
US9539538B2 (en) * 2011-10-28 2017-01-10 Ada Carbon Solutions, Llc Multi-functional composition of matter for rapid removal of mercury from a flue gas
US10722865B2 (en) 2011-10-28 2020-07-28 Ada Carbon Solutions, Llc Multi-functional composition of matter for removal of mercury from high temperature flue gas streams
WO2013070809A2 (fr) * 2011-11-07 2013-05-16 Delcath Systems, Inc. Appareil pour retirer des composés de chimiothérapie à partir du sang
CN102847432B (zh) * 2012-09-24 2015-04-22 河北科技大学 一种金属改性抗生素菌渣活性炭吸附-催化氧化二氧化硫的方法
CA2899135A1 (fr) * 2013-03-13 2014-09-18 Toyo Tanso Co., Ltd. Materiau adsorbant/desorbant
US10449492B2 (en) 2014-05-30 2019-10-22 Ada Carbon Solutions, Llc Catalytically enhanced compositions for efficient removal of contaminants in flue gas streams
US11285459B2 (en) 2015-08-14 2022-03-29 Ada Carbon Solutions, Llc Sorbent compositions having amorphous halogen species for the sequestration of contaminants
US11219878B2 (en) 2015-08-14 2022-01-11 Ada Carbon Solutions, Llc Sorbent compositions having amorphous halogen species for the sequestration of contaminants
US11173482B2 (en) * 2019-05-28 2021-11-16 Saudi Arabian Oil Company Combustion of spent adsorbents containing HPNA compounds in FCC catalyst regenerator
CN113477215B (zh) * 2021-07-19 2023-03-17 山西新华防化装备研究院有限公司 一种利用螯合剂制备用于脱除氰化物的吸附剂的方法
CN114715970A (zh) * 2022-03-31 2022-07-08 延安大学 煤焦油沥青基片层多孔碳材料吸附去除水中草甘膦的方法
CN114934284B (zh) * 2022-06-16 2024-01-19 河南大学 用于电催化还原二氧化碳的酞菁镍修饰果皮碳框架催化剂及其制备方法和应用
CN115779969A (zh) * 2022-12-07 2023-03-14 山东京博石油化工有限公司 一种用于汽油中硫醇转化的催化剂及其制备方法

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1301844A (fr) * 1960-10-12 1962-08-24 Universal Oil Prod Co Procédé pour le traitement de distillats sulfureux d'hydrocarbures
GB1224816A (en) * 1967-10-06 1971-03-10 Bergwerksverband Gmbh Improvements in or relating to absorption agents
US3969398A (en) * 1974-05-01 1976-07-13 Monsanto Company Process for producing N-phosphonomethyl glycine
US4248694A (en) * 1979-05-17 1981-02-03 Uop Inc. Process for treating a sour petroleum distillate
US4502949A (en) * 1984-02-15 1985-03-05 Uop Inc. Catalytic oxidation of mercaptan in petroleum distillate
FR2560889A1 (fr) * 1984-03-09 1985-09-13 Inst Francais Du Petrole Nouveaux catalyseurs d'oxydation de mercaptans en disulfures, leur procede de preparation et leur application a l'adoucissement de distillats petroliers
US4664683A (en) * 1984-04-25 1987-05-12 Pall Corporation Self-supporting structures containing immobilized carbon particles and method for forming same
FR2601263B1 (fr) * 1986-07-11 1988-11-25 Total France Nouveau produit composite catalytique pour l'oxydation des mercaptans et son utilisation pour l'adoucissement des coupes petrolieres.
US4913802A (en) * 1989-05-08 1990-04-03 Uop Process for sweetening a sour hydrocarbon fraction
CA2037438A1 (fr) * 1991-03-01 1992-09-02 Jack G. Pagotto Charbon de bois active a faible teneur en chrome
US5618573A (en) * 1995-11-20 1997-04-08 Rtd Corporation Production of vodka by supercooling technology
CN1067655C (zh) * 1997-10-29 2001-06-27 胡福昌 果核壳制造高性能活性炭的方法
ATE252519T1 (de) * 1999-06-18 2003-11-15 German Carbon Teterow Gmbh Verfahren zur herstellung von formaktivkohle
FR2806072B1 (fr) * 2000-03-07 2002-06-07 Air Liquide Charbon actif ameliore par traitement a l'acide et son utilisation pour separer des gaz
CN1137874C (zh) * 2000-09-06 2004-02-11 吉林省石油化工设计研究院 对羟基苯甲醛的制备方法

Also Published As

Publication number Publication date
US20150182949A1 (en) 2015-07-02
US20120175306A1 (en) 2012-07-12
EP1704117A2 (fr) 2006-09-27
US20070123419A1 (en) 2007-05-31
WO2005080269A3 (fr) 2006-07-27
FR2865468A1 (fr) 2005-07-29
WO2005080269A2 (fr) 2005-09-01
US20100278987A1 (en) 2010-11-04
CN1934030A (zh) 2007-03-21
CN1934030B (zh) 2012-01-25

Similar Documents

Publication Publication Date Title
FR2865468B1 (fr) Charbon actif a resistance mecanique amelioree, ses utilisations, notamment comme support de catalyseur.
WO2008021156A3 (fr) Anticorps dirigés contre l'il-17a
GB2434691B8 (en) Fuel cell.
AP2152A (en) Fresnel solar collector arrangement.
EP1994984A4 (fr) Acide solide a base de carbone, catalyseur comprenant l'acide solide et reaction utilisant l'acide solide en tant que catalyseur
NL1028877A1 (nl) Katalysatoren.
BRPI0906968A2 (pt) Notificação de eventos de dispositivo móvel.
WO2010077821A8 (fr) Enregistrement chronologique des données de localisation et filtrage basé sur la localisation et le temps
EP1999615A4 (fr) Système de stockage d'égal à égal efficace et fiable
BRPI1010957A2 (pt) variantes de celulase com expressão, atividade e/ou estabilidade aprimorada e uso das mesmas.
FR2934652B1 (fr) Pompe a membrane ondulante de rendement ameliore.
BRPI0923732A2 (pt) "regeneração de catalisador".
BRPI0919184A2 (pt) armazenamento e recuperação de mensagem.
FR2938122B1 (fr) Electrolyte a rigidite abaissee, et systeme electrochimique comportant un tel electrolyte
BRPI0911556A2 (pt) eletrodo enzimático, e, célula de combustível.
DK2219662T3 (da) Aktive, opløselige, post-translationelt modificerede neuregulin- isoformer.
Тулупов ÇÀ ÓÍÈÂÅÐÑÈÒÅÒÑÊÎÃÎ× ÅËÎÂÅÊÀ!
ITTO20050426A1 (it) Catalizzatore a meandro.
FR2886767B1 (fr) Accumulateur alcalin ouvert comportant une membrane microporeuse.
钱易 My Winter Holiday
HK1069714A2 (en) Windmill.
廖少华 et al. Have a Try
FR2921760B1 (fr) Batterie comportant des pieces d'immobilisation des elements d'accumulateur.
刘志存 First-timer shoots up to the top
李同归 et al. Attachment and Life

Legal Events

Date Code Title Description
CA Change of address
PLFP Fee payment

Year of fee payment: 13

PLFP Fee payment

Year of fee payment: 14

ST Notification of lapse

Effective date: 20180928