ES2108766T3 - Preparacion de complejos de coordinacion de metal. - Google Patents
Preparacion de complejos de coordinacion de metal.Info
- Publication number
- ES2108766T3 ES2108766T3 ES92922427T ES92922427T ES2108766T3 ES 2108766 T3 ES2108766 T3 ES 2108766T3 ES 92922427 T ES92922427 T ES 92922427T ES 92922427 T ES92922427 T ES 92922427T ES 2108766 T3 ES2108766 T3 ES 2108766T3
- Authority
- ES
- Spain
- Prior art keywords
- preparation
- coordination complexes
- metal coordination
- metal
- complexes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- HPYIUKIBUJFXII-UHFFFAOYSA-N Cyclopentadienyl radical Chemical class [CH]1C=CC=C1 HPYIUKIBUJFXII-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002736 metal compounds Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/10—Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/28—Titanium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
COMPLEJOS DE METAL DE GEOMETRIA FORZADA QUE SON UTILES EN LA PREPARACION DE CATALIZADORES PARA POLIMERIZACIONES DE OLEFINA, SON PREPARADOS POR PUESTA EN CONTACTO DE CICLOPENTADIENILO CON COMPUESTOS DE METAL.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US77843291A | 1991-10-15 | 1991-10-15 | |
| US77843391A | 1991-10-15 | 1991-10-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2108766T3 true ES2108766T3 (es) | 1998-01-01 |
Family
ID=27119452
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES92922427T Expired - Lifetime ES2108766T3 (es) | 1991-10-15 | 1992-10-13 | Preparacion de complejos de coordinacion de metal. |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP0563365B1 (es) |
| JP (1) | JP3341117B2 (es) |
| KR (1) | KR100236805B1 (es) |
| CA (1) | CA2098381C (es) |
| DE (1) | DE69223035T2 (es) |
| ES (1) | ES2108766T3 (es) |
| WO (1) | WO1993008199A1 (es) |
Families Citing this family (74)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5621126A (en) | 1987-01-30 | 1997-04-15 | Exxon Chemical Patents Inc. | Monocyclopentadienyl metal compounds for ethylene-α-olefin-copolymer production catalysts |
| US5264405A (en) | 1989-09-13 | 1993-11-23 | Exxon Chemical Patents Inc. | Monocyclopentadienyl titanium metal compounds for ethylene-α-olefin-copolymer production catalysts |
| USRE37788E1 (en) * | 1987-01-30 | 2002-07-09 | Exxon Chemical Patents, Inc. | Monocyclopentadienyl metal compounds for ethylene-α-olefin-copolymer production catalysts |
| US6265338B1 (en) * | 1989-09-13 | 2001-07-24 | Exxon Chemical Patents, Inc. | Monocyclopentadienyl titanium metal compounds for ethylene-α-olefin copolymer production catalysts |
| US6143854A (en) | 1993-08-06 | 2000-11-07 | Exxon Chemical Patents, Inc. | Polymerization catalysts, their production and use |
| EP0739360B1 (en) | 1993-09-17 | 2001-04-11 | Exxon Chemical Patents Inc. | Polymerization catalyst systems, their production and use |
| US5359105A (en) * | 1993-11-01 | 1994-10-25 | Albemarle Corporation | Deprotonation of cyclopentadienyl derivatives |
| US5691422A (en) * | 1994-03-07 | 1997-11-25 | Exxon Chemical Patents Inc. | Saturated polyolefins having terminal aldehyde or hydroxy substituents and derivatives thereof |
| US5674950A (en) * | 1994-03-07 | 1997-10-07 | Exxon Chemical Patents Inc. | Polymers having terminal hydroxyl aldehyde, or alkylamino substitutents and derivatives thereof |
| US5648438A (en) * | 1994-04-01 | 1997-07-15 | Exxon Chemical Patents, Inc. | Process for producing polymers with multimodal molecular weight distributions |
| US5936041A (en) * | 1994-06-17 | 1999-08-10 | Exxon Chemical Patents Inc | Dispersant additives and process |
| AU712427B2 (en) * | 1994-07-11 | 1999-11-04 | Exxon Chemical Patents Inc. | Lubricating oil succinimide dispersants derived from heavy polyamine |
| DE4431838A1 (de) * | 1994-09-07 | 1996-03-14 | Basf Ag | Geträgerte Metallocen-Katalysatorsysteme |
| US5495036A (en) * | 1994-09-12 | 1996-02-27 | The Dow Chemical Company | Metal (III) complexes containing conjugated, non-aromatic anionic II-bound groups and addition polymerization catalysts therefrom |
| US5541349A (en) * | 1994-09-12 | 1996-07-30 | The Dow Chemical Company | Metal complexes containing partially delocalized II-bound groups and addition polymerization catalysts therefrom |
| US5565128A (en) * | 1994-10-12 | 1996-10-15 | Exxon Chemical Patents Inc | Lubricating oil mannich base dispersants derived from heavy polyamine |
| US5625015A (en) | 1994-11-23 | 1997-04-29 | Exxon Chemical Patents Inc. | Method for making supported catalyst systems and catalyst systems therefrom |
| US5512693A (en) * | 1994-12-07 | 1996-04-30 | The Dow Chemical Company | Preparation of titanium (II) or zirconium (II) complexes |
| EP0843687B1 (en) | 1995-08-10 | 2002-06-12 | ExxonMobil Chemical Patents Inc. | Metallocene stabilized alumoxane |
| US5652202A (en) * | 1995-08-15 | 1997-07-29 | Exxon Chemical Patents Inc. | Lubricating oil compositions |
| US5558802A (en) * | 1995-09-14 | 1996-09-24 | Exxon Chemical Patents Inc | Multigrade crankcase lubricants with low temperature pumpability and low volatility |
| NL1003002C2 (nl) * | 1996-05-03 | 1997-11-06 | Dsm Nv | Siliciumfunctioneel cyclopentadieen. |
| BR9710518A (pt) * | 1996-07-22 | 1999-08-17 | Dow Chemical Co | Complexo de metal composi-Æo de catalisador e processo de polimeriza-Æo |
| US6107502A (en) * | 1997-10-13 | 2000-08-22 | Sumitomo Chemical Company, Limited | Method for purifying transition metal compound and method for producing the same |
| US6136995A (en) * | 1997-11-07 | 2000-10-24 | Sumitomo Chemical Company, Limited | Process for producing aminosilane compounds |
| AR018359A1 (es) | 1998-05-18 | 2001-11-14 | Dow Global Technologies Inc | Articulo resistente al calor , configurado, irradiado y reticulado, libre de un agente de reticulacion de silano |
| US6417405B2 (en) | 1999-03-03 | 2002-07-09 | The Dow Chemical Company | Synthesis of cyclopentadiene or substituted cyclopentadiene compounds |
| US6310256B1 (en) | 1999-03-03 | 2001-10-30 | The Dow Chemical Company | Synthesis of 4-ketocyclopentene compounds |
| US6339134B1 (en) | 1999-05-06 | 2002-01-15 | Univation Technologies, Llc | Polymerization process for producing easier processing polymers |
| ES2379243T3 (es) * | 1999-12-10 | 2012-04-24 | Dow Global Technologies Llc | Complejos de metal del grupo 4 sustituidos, catalizadores y procedimiento de polimerización de olefinas |
| US6281306B1 (en) | 1999-12-16 | 2001-08-28 | Univation Technologies, Llc | Method of polymerization |
| JP2002097228A (ja) * | 2000-09-20 | 2002-04-02 | Mitsui Chemicals Inc | シンジオタクティックポリプロピレン系共重合体、該共重合体を含む組成物および成形体 |
| US7223822B2 (en) | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
| ES2394304T3 (es) | 2002-10-15 | 2013-01-30 | Exxonmobil Chemical Patents, Inc. | Sistema de múltiples catalizadores para la polimerización de olefinas y polímeros producidos a partir de éstos |
| US7365039B2 (en) | 2003-03-21 | 2008-04-29 | Dow Global Technologies Inc. | Morphology controlled olefin polymerization process |
| JP5198872B2 (ja) | 2004-12-17 | 2013-05-15 | ダウ グローバル テクノロジーズ エルエルシー | レオロジー改変相対的高溶融強度ポリエチレン組成物並びにパイプ、フィルム、シート、およびブロー成型品の製造方法 |
| EP1803747A1 (en) | 2005-12-30 | 2007-07-04 | Borealis Technology Oy | Surface-modified polymerization catalysts for the preparation of low-gel polyolefin films |
| DE602007007931D1 (de) | 2006-05-02 | 2010-09-02 | Dow Global Technologies Inc | Sehr dichte polyethylenzusammensetzungen, verfahren zu deren herstellung, draht- und kabelhüllen, die daraus hergestellt wurden und verfahren zur herstellung derartiger draht- und kabelhüllen |
| US7456244B2 (en) | 2006-05-23 | 2008-11-25 | Dow Global Technologies | High-density polyethylene compositions and method of making the same |
| CN101490163A (zh) | 2007-05-02 | 2009-07-22 | 陶氏环球技术公司 | 高密度聚乙烯组合物、其制备方法、由其制得的注塑制品以及该制品的制备方法 |
| US7981517B2 (en) | 2007-08-28 | 2011-07-19 | Dow Global Technologies Inc. | Bituminous compositions and methods of making and using same |
| TW200932762A (en) | 2007-10-22 | 2009-08-01 | Univation Tech Llc | Polyethylene compositions having improved properties |
| US8318872B2 (en) | 2007-12-18 | 2012-11-27 | Univation Technologies, Llc | Method for controlling bimodal catalyst activity during polymerization |
| EP2172490A1 (en) | 2008-10-03 | 2010-04-07 | Ineos Europe Limited | Controlled polymerisation process |
| CN102257017B (zh) | 2008-12-18 | 2014-02-12 | 尤尼威蒂恩技术有限责任公司 | 用于聚合反应种子床处理的方法 |
| BRPI1005286A2 (pt) | 2009-01-30 | 2016-07-05 | Dow Global Technologies Llc | composição de polietileno de alta densidade, método para produzir uma composição de polietileno de alta densidade, dispositivo de fechamento e método para produzir um dispositivo de fechamento |
| EP2357035A1 (en) | 2010-01-13 | 2011-08-17 | Ineos Europe Limited | Polymer powder storage and/or transport and/or degassing vessels |
| EP2383301A1 (en) | 2010-04-30 | 2011-11-02 | Ineos Europe Limited | Polymerization process |
| EP2383298A1 (en) | 2010-04-30 | 2011-11-02 | Ineos Europe Limited | Polymerization process |
| CN103328518B (zh) | 2010-11-29 | 2016-07-06 | 英力士销售(英国)有限公司 | 聚合控制方法 |
| US8383740B1 (en) | 2011-08-12 | 2013-02-26 | Ineos Usa Llc | Horizontal agitator |
| EP2768870B1 (en) | 2011-10-17 | 2018-01-10 | Ineos Europe AG | Polymer degassing process control |
| US9650453B2 (en) | 2012-12-28 | 2017-05-16 | Univation Technologies, Llc | Methods of integrating aluminoxane production into catalyst production |
| WO2014109832A1 (en) | 2013-01-14 | 2014-07-17 | Univation Technologies, Llc | Methods for preparing catalyst systems with increased productivity |
| SG11201703851UA (en) | 2014-11-25 | 2017-06-29 | Univation Tech Llc | Methods of controlling polyolefin melt index |
| US10377841B2 (en) | 2015-05-08 | 2019-08-13 | Exxonmobil Chemical Patents Inc. | Polymerization process |
| KR101959519B1 (ko) * | 2016-04-12 | 2019-03-18 | (주)디엔에프 | 전이금속 화합물, 이의 제조방법 및 이를 포함하는 전이금속함유 박막증착용 조성물 |
| WO2018063767A1 (en) | 2016-09-27 | 2018-04-05 | Exxonmobil Chemical Patents Inc. | Polymerization process |
| WO2018063764A1 (en) | 2016-09-27 | 2018-04-05 | Exxonmobil Chemical Patents Inc. | Polymerization process |
| WO2018063765A1 (en) | 2016-09-27 | 2018-04-05 | Exxonmobil Chemical Patents Inc. | Polymerization process |
| WO2018118155A1 (en) | 2016-12-20 | 2018-06-28 | Exxonmobil Chemical Patents Inc. | Polymerization process |
| WO2019118073A1 (en) | 2017-12-13 | 2019-06-20 | Exxonmobil Chemical Patents Inc. | Deactivation methods for active components from gas phase polyolefin polymerization process |
| WO2019173030A1 (en) | 2018-03-08 | 2019-09-12 | Exxonmobil Chemical Patents Inc. | Methods of preparing and monitoring a seed bed for polymerization reactor startup |
| CN112055719B (zh) | 2018-05-02 | 2022-11-25 | 埃克森美孚化学专利公司 | 从中试装置放大到较大生产设施的方法 |
| US11459408B2 (en) | 2018-05-02 | 2022-10-04 | Exxonmobil Chemical Patents Inc. | Methods for scale-up from a pilot plant to a larger production facility |
| EP3814390A2 (en) | 2018-06-28 | 2021-05-05 | ExxonMobil Chemical Patents Inc. | Polyethylene compositions, wires and cables, and methods for making the same |
| WO2020014138A1 (en) | 2018-07-09 | 2020-01-16 | Exxonmobil Chemical Patents Inc. | Polyethylene cast films and methods for making the same |
| EP3826833A1 (en) | 2018-07-26 | 2021-06-02 | ExxonMobil Chemical Patents Inc. | Multilayer foam films and methods for making the same |
| EP3880739B1 (en) | 2018-11-13 | 2025-03-19 | ExxonMobil Chemical Patents Inc. | Polyethylene films |
| EP3880738B1 (en) | 2018-11-13 | 2025-03-19 | ExxonMobil Chemical Patents Inc. | Polyethylene blends and films |
| WO2020163079A1 (en) | 2019-02-06 | 2020-08-13 | Exxonmobil Chemical Patents Inc. | Films and backsheets for hygiene articles |
| WO2021126458A1 (en) | 2019-12-17 | 2021-06-24 | Exxonmobil Chemical Patents Inc. | Films made of polyethylene blends for improved sealing performance and mechanical properties |
| WO2021183337A1 (en) | 2020-03-12 | 2021-09-16 | Exxonmobil Chemical Patents Inc. | Films made of polyethylene blends for improved bending stiffness and high md tear resistance |
| US20240209124A1 (en) | 2021-04-30 | 2024-06-27 | Exxonmobil Chemical Patents Inc. | Processes for transitioning between different polymerization catalysts in a polymerization reactor |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5055438A (en) * | 1989-09-13 | 1991-10-08 | Exxon Chemical Patents, Inc. | Olefin polymerization catalysts |
| NZ235032A (en) * | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
| US5064802A (en) * | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
| CA2085581C (en) * | 1990-06-22 | 2002-07-30 | Joann Marie Canich | Aluminum-free monocyclopentadienyl metallocene catalysts for olefin polymerization |
-
1992
- 1992-10-13 CA CA002098381A patent/CA2098381C/en not_active Expired - Fee Related
- 1992-10-13 KR KR1019930701797A patent/KR100236805B1/ko not_active Expired - Fee Related
- 1992-10-13 EP EP92922427A patent/EP0563365B1/en not_active Expired - Lifetime
- 1992-10-13 WO PCT/US1992/008730 patent/WO1993008199A1/en not_active Ceased
- 1992-10-13 JP JP50776293A patent/JP3341117B2/ja not_active Expired - Fee Related
- 1992-10-13 ES ES92922427T patent/ES2108766T3/es not_active Expired - Lifetime
- 1992-10-13 DE DE69223035T patent/DE69223035T2/de not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| DE69223035T2 (de) | 1998-05-07 |
| KR100236805B1 (ko) | 2000-02-01 |
| HK1003596A1 (en) | 1998-10-30 |
| KR930703332A (ko) | 1993-11-29 |
| WO1993008199A1 (en) | 1993-04-29 |
| EP0563365B1 (en) | 1997-11-05 |
| DE69223035D1 (de) | 1997-12-11 |
| CA2098381A1 (en) | 1993-04-16 |
| JP3341117B2 (ja) | 2002-11-05 |
| JPH06503585A (ja) | 1994-04-21 |
| EP0563365A1 (en) | 1993-10-06 |
| CA2098381C (en) | 2003-12-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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