DE68912510D1 - Ruthenium-Phosphin-Komplexe. - Google Patents

Ruthenium-Phosphin-Komplexe.

Info

Publication number
DE68912510D1
DE68912510D1 DE89310901T DE68912510T DE68912510D1 DE 68912510 D1 DE68912510 D1 DE 68912510D1 DE 89310901 T DE89310901 T DE 89310901T DE 68912510 T DE68912510 T DE 68912510T DE 68912510 D1 DE68912510 D1 DE 68912510D1
Authority
DE
Germany
Prior art keywords
ruthenium
phosphine complexes
phosphine
complexes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE89310901T
Other languages
English (en)
Other versions
DE68912510T2 (de
Inventor
Hidemasa Takaya
Kazushi Mashima
Hidenori Kumobayashi
Noboru Sayo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Takasago International Corp
Original Assignee
Takasago International Corp
Takasago Perfumery Industry Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Takasago International Corp, Takasago Perfumery Industry Co filed Critical Takasago International Corp
Publication of DE68912510D1 publication Critical patent/DE68912510D1/de
Application granted granted Critical
Publication of DE68912510T2 publication Critical patent/DE68912510T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2442—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
    • B01J31/2447—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring
    • B01J31/2452—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring with more than one complexing phosphine-P atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/36—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by hydrogenation of carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/31—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by introduction of functional groups containing oxygen only in singly bound form
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046—Ruthenium compounds
    • C07F15/0053—Ruthenium compounds without a metal-carbon linkage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/643—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of R2C=O or R2C=NR (R= C, H)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0261—Complexes comprising ligands with non-tetrahedral chirality
    • B01J2531/0266—Axially chiral or atropisomeric ligands, e.g. bulky biaryls such as donor-substituted binaphthalenes, e.g. "BINAP" or "BINOL"
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE68912510T 1988-10-24 1989-10-23 Ruthenium-Phosphin-Komplexe. Expired - Lifetime DE68912510T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP26794688 1988-10-24
JP1242604A JPH0757758B2 (ja) 1988-10-24 1989-09-19 ルテニウム―ホスフィン錯体

Publications (2)

Publication Number Publication Date
DE68912510D1 true DE68912510D1 (de) 1994-03-03
DE68912510T2 DE68912510T2 (de) 1994-08-11

Family

ID=26535838

Family Applications (1)

Application Number Title Priority Date Filing Date
DE68912510T Expired - Lifetime DE68912510T2 (de) 1988-10-24 1989-10-23 Ruthenium-Phosphin-Komplexe.

Country Status (4)

Country Link
US (1) US4994590A (de)
EP (1) EP0366390B1 (de)
JP (1) JPH0757758B2 (de)
DE (1) DE68912510T2 (de)

Families Citing this family (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4124834B2 (ja) * 1995-08-25 2008-07-23 高砂香料工業株式会社 光学活性ジヒドロスフィンゴシン誘導体の製造方法
JPH0768260B2 (ja) * 1990-03-01 1995-07-26 高砂香料工業株式会社 ２，２’―ビス〔ジ―（３，５―ジアルキルフェニル）ホスフィノ〕―１，１’―ビナフチル及びこれを配位子とする遷移金属錯体
JP2775335B2 (ja) * 1990-08-01 1998-07-16 高砂香料工業株式会社 ルテニウム―ホスフィン錯体及びその製造中間体
JP2739254B2 (ja) * 1990-10-01 1998-04-15 高砂香料工業株式会社 イリジウム―光学活性ホスフィン錯体及びこれを用いた光学活性アルコールの製造方法
JP2681057B2 (ja) * 1990-10-01 1997-11-19 高砂香料工業株式会社 ２，２’―ビス（ジフェニルホスフィノ）―５，５’，６，６’，７，７’，８，８’―オクタヒドロ―１，１’―ビナフチル及びこれを配位子とする遷移金属錯体
US5210243A (en) * 1990-12-10 1993-05-11 Ethyl Corporation Hydrogenation of aromatic-substituted olefins using organometallic catalyst
JP2894525B2 (ja) * 1990-12-20 1999-05-24 住友製薬株式会社 結晶性テトラキス（トリフェニルホスフィン）パラジウム及びその製造法
FR2671079B1 (fr) * 1990-12-28 1994-06-03 Elf Aquitaine Procede d'hydrogenation de composes organiques et catalyseurs au ruthenium pour sa realisation.
DE4128787A1 (de) * 1991-08-30 1993-03-04 Bayer Ag Neue zwischenprodukte und ihre verwendung bei der herstellung von s-ketoprofen
US5144050A (en) * 1991-10-01 1992-09-01 Monsanto Company Ruthenium(II)-BINAP diketonate complexes
JP2850068B2 (ja) * 1991-10-22 1999-01-27 高砂香料工業株式会社 ルテニウム−ホスフィン錯体及びこれを触媒とする光学活性１−置換−１，３−プロパンジオールの製造方法
JP2736947B2 (ja) * 1991-11-21 1998-04-08 高砂香料工業株式会社 水溶性なスルホン酸アルカリ金属塩置換ビナフチルホスフイン遷移金属錯体及びこれを用いた不斉水素化法
JP3310056B2 (ja) * 1992-07-16 2002-07-29 高砂香料工業株式会社 光学活性４−メチル−２−オキセタノンの製造方法
US5412109A (en) * 1992-07-16 1995-05-02 Takasago International Corporation Process for preparing optically active 4-methyl-2-oxetanone
DE69318666T2 (de) 1992-10-05 1998-09-10 Takasago Perfumery Co Ltd Verfahren zur Herstellung von optisch aktiven gamma-Hydroxyketonen
DE4330730A1 (de) * 1993-09-10 1995-03-16 Bayer Ag Neue Bisphosphine für asymmetrische Hydrierkatalysatoren
US5736480A (en) * 1994-02-22 1998-04-07 California Institute Of Technology Supported phase chiral sulfonated BINAP catalyst solubilized in alcohol and method of asymmetric hydrogenation
US5935892A (en) * 1994-02-22 1999-08-10 California Institute Of Technology Supported phase catalyst
DE19522293A1 (de) * 1995-06-20 1997-01-02 Bayer Ag Neue Bisphospine als Katalysatoren für asymmetrische Reaktionen
AU7270896A (en) * 1995-10-13 1997-05-07 K.U. Leuven Research & Development Chiral solid catalyst, its preparation and its use for the production of substantially enantiomerically pure products
DE19548399A1 (de) * 1995-12-22 1997-06-26 Basf Ag Rutheniumkomplexe mit einem chiralen, zweizähnigen Phosphinoxazolin-Liganden zur enantioselektiven Transferhydrierung von prochiralen Ketonen
JP3184758B2 (ja) 1996-02-02 2001-07-09 高砂香料工業株式会社 光学活性４−ヒドロキシ−２−ピロリドンの製造方法
US6159890A (en) * 1996-04-30 2000-12-12 Bp Amoco Corporation Ruthenium-containing catalyst system for olefin metathesis
US6156692A (en) * 1996-04-30 2000-12-05 Bp Amoco Corporation Ruthenium-containing catalyst composition for olefin metathesis
DE19724539A1 (de) * 1997-06-11 1998-12-17 Heino Dr Hermeking Blende zum Implantieren in den Linsenkapselsack eines Auges
US7223879B2 (en) * 1998-07-10 2007-05-29 Massachusetts Institute Of Technology Ligands for metals and improved metal-catalyzed processes based thereon
US6307087B1 (en) 1998-07-10 2001-10-23 Massachusetts Institute Of Technology Ligands for metals and improved metal-catalyzed processes based thereon
IT1308629B1 (it) 1999-02-23 2002-01-09 Recordati Chem Pharm Processo per la produzione di paroxetina.
US6184415B1 (en) 1999-11-01 2001-02-06 Albemarle Corporation Production of chiral non-racemic 2-halopropionic acid or salt thereof
GB0004297D0 (en) 2000-02-23 2000-04-12 Ucb Sa 2-oxo-1 pyrrolidine derivatives process for preparing them and their uses
DE10027154A1 (de) 2000-05-31 2001-12-13 Bayer Ag Verfahren zur Herstellung optisch aktiver Trimethylmilchsäure und ihrer Ester
DE10036516A1 (de) 2000-07-27 2002-02-07 Asta Medica Ag Verfahren zur Herstellung von enantiomerenreinen 6,8-Dihydroxyoctansäureestern durch assymetrische katalytische Hydrierung
US8828902B2 (en) 2001-07-12 2014-09-09 Reaxa Limited Microencapsulated catalyst methods of preparation and method of use thereof
TWI400220B (zh) 2004-09-13 2013-07-01 Takeda Pharmaceutical 光活性胺衍生物的製法
US7816550B2 (en) * 2005-02-10 2010-10-19 Praxair Technology, Inc. Processes for the production of organometallic compounds
GB0822064D0 (en) * 2008-12-03 2009-01-07 Johnson Matthey Plc Process for preparing cationic ruthenium complexes
EP2386536A1 (de) 2010-05-11 2011-11-16 Lonza Ltd. Prozess zur Hydrogenierung von Ketoestern

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3878122A (en) * 1973-10-26 1975-04-15 Phillips Petroleum Co Regeneration of ruthenium hydride complex isomerization catalysts
US4268454A (en) * 1978-12-21 1981-05-19 Allied Chemical Corporation Anionic group VIII metal hydride catalysts
US4506030A (en) * 1984-02-17 1985-03-19 The Board Of Regents, University Of Texas System Catalysts for hydrogenation of aromatic compounds
JPS6163690A (ja) * 1984-09-04 1986-04-01 Takasago Corp ルテニウム−ホスフイン錯体
JPS62265293A (ja) * 1986-05-13 1987-11-18 Takasago Corp ルテニウム−ホスフイン錯体
JPS6341487A (ja) * 1986-08-06 1988-02-22 Takasago Corp ルテニウム−ホスフイン錯体

Also Published As

Publication number Publication date
EP0366390B1 (de) 1994-01-19
EP0366390A3 (en) 1990-07-04
US4994590A (en) 1991-02-19
JPH02191289A (ja) 1990-07-27
DE68912510T2 (de) 1994-08-11
JPH0757758B2 (ja) 1995-06-21
EP0366390A2 (de) 1990-05-02

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Legal Events

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