ES2188751T3 - Componente catalitico soportado, catalizador soportado, procedimiento de preparacion, procedimiento de polimerizacion, compuestos complejos, y su preparacion. - Google Patents

Componente catalitico soportado, catalizador soportado, procedimiento de preparacion, procedimiento de polimerizacion, compuestos complejos, y su preparacion.

Info

Publication number
ES2188751T3
ES2188751T3 ES96910361T ES96910361T ES2188751T3 ES 2188751 T3 ES2188751 T3 ES 2188751T3 ES 96910361 T ES96910361 T ES 96910361T ES 96910361 T ES96910361 T ES 96910361T ES 2188751 T3 ES2188751 T3 ES 2188751T3
Authority
ES
Spain
Prior art keywords
preparation
procedure
supported
catalyst
complex compounds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES96910361T
Other languages
English (en)
Inventor
Grant Berent Jacobsen
Peter Wijkens
Johann Jastrzebski
Koten Gerard Van
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Global Technologies LLC
Original Assignee
Dow Global Technologies LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies LLC filed Critical Dow Global Technologies LLC
Application granted granted Critical
Publication of ES2188751T3 publication Critical patent/ES2188751T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/02Boron compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/603Component covered by group C08F4/60 with a metal or compound covered by group C08F4/44 other than an organo-aluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61908Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61916Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

UN CATALIZADOR EN SOPORTE QUE COMPRENDE (A) UN MATERIAL EN SOPORTE, UN COMPUESTO ORGANOMETALICO Y (B) UN COMPUESTO ACTIVADOR QUE COMPRENDE B.1) UN CATION QUE ES CAPAZ DE REACCIONAR CON UN COMPUESTO DE UN METAL DE TRANSICION FORMANDO UN COMPLEJO CON UN METAL DE TRANSICION CATALITICAMENTE ACTIVO Y B.2) UN ANION COMPATIBLE QUE TIENE HASTA 100 ATOMOS QUE NO SON HIDROGENO Y QUE CONTIENE AL MENOS UN SUSTITUYENTE QUE COMPRENDE UN RESTO DE HIDROGENO ACTIVO; UN CATALIZADOR EN SOPORTE QUE COMPRENDE EL COMPUESTO CATALIZADOR EN SOPORTE Y UN COMPUESTO DE UN METAL DE TRANSICION; PROCEDIMIENTO PARA LA PREPARACION DEL MISMO; UN PROCEDIMIENTO PARA LA PRODUCCION DEL MISMO; UN PROCEDIMIENTO DE POLIMERIZACION POR ADICION QUE UTILIZA EL CATALIZADOR EN SOPORTE; COMPUESTOS COMPLEJOS Y UN METODO PARA LA PREPARACION DEL MISMO.
ES96910361T 1995-03-10 1996-03-04 Componente catalitico soportado, catalizador soportado, procedimiento de preparacion, procedimiento de polimerizacion, compuestos complejos, y su preparacion. Expired - Lifetime ES2188751T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US40243795A 1995-03-10 1995-03-10

Publications (1)

Publication Number Publication Date
ES2188751T3 true ES2188751T3 (es) 2003-07-01

Family

ID=23591882

Family Applications (1)

Application Number Title Priority Date Filing Date
ES96910361T Expired - Lifetime ES2188751T3 (es) 1995-03-10 1996-03-04 Componente catalitico soportado, catalizador soportado, procedimiento de preparacion, procedimiento de polimerizacion, compuestos complejos, y su preparacion.

Country Status (22)

Country Link
US (1) US5834393A (es)
EP (1) EP0856014B1 (es)
JP (1) JPH11503113A (es)
KR (1) KR100420432B1 (es)
CN (1) CN1116309C (es)
AR (1) AR001183A1 (es)
AT (1) ATE233790T1 (es)
AU (1) AU712417B2 (es)
BR (1) BR9604776A (es)
CO (1) CO4560463A1 (es)
CZ (1) CZ285397A3 (es)
DE (1) DE69626531T2 (es)
ES (1) ES2188751T3 (es)
HU (1) HUP9801224A3 (es)
IL (1) IL117408A0 (es)
NO (1) NO315977B1 (es)
PL (1) PL186697B1 (es)
RU (1) RU2160283C2 (es)
TR (1) TR199700932T1 (es)
TW (1) TW372240B (es)
WO (1) WO1996028480A1 (es)
ZA (1) ZA961910B (es)

Families Citing this family (99)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5384299A (en) * 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
ATE171957T1 (de) * 1994-06-03 1998-10-15 Pcd Polymere Ag Katalysatorträger, geträgerte metallocenkatalysatoren und deren verwendung für die herstellung von polyolefinen
US6143686A (en) * 1994-08-03 2000-11-07 Exxon Chemical Patents, Inc. Supported ionic catalyst compositions
CA2195879C (en) * 1994-08-03 2001-01-09 John Flexer Walzer Jr. Supported ionic catalyst composition
DE4431838A1 (de) * 1994-09-07 1996-03-14 Basf Ag Geträgerte Metallocen-Katalysatorsysteme
US7153909B2 (en) 1994-11-17 2006-12-26 Dow Global Technologies Inc. High density ethylene homopolymers and blend compositions
US6506866B2 (en) 1994-11-17 2003-01-14 Dow Global Technologies Inc. Ethylene copolymer compositions
US5939347A (en) * 1995-01-25 1999-08-17 W.R. Grace & Co. -Conn. Supported catalytic activator
US5885924A (en) * 1995-06-07 1999-03-23 W. R. Grace & Co.-Conn. Halogenated supports and supported activators
BR9611772A (pt) * 1995-11-27 1999-02-23 Dow Chemical Co Suporte para uso na preparação de catalisadores para polimerizações por adição catalisador suportado e processo de polimerização por adição
EP0880598A4 (en) 1996-01-23 2005-02-23 Affymetrix Inc RAPID EVALUATION OF NUCLEIC ACID ABUNDANCE DIFFERENCE, WITH A HIGH-DENSITY OLIGONUCLEOTIDE SYSTEM
DE19606166A1 (de) * 1996-02-20 1997-08-21 Basf Ag Verfahren zur Herstellung von Polymerisaten von Alkenen durch Suspensionspolymerisation
JPH09309926A (ja) * 1996-05-17 1997-12-02 Dow Chem Co:The エチレン共重合体の製造方法
DE19622207A1 (de) 1996-06-03 1997-12-04 Hoechst Ag Chemische Verbindung
EP0824112B1 (de) 1996-08-13 2006-05-10 Basell Polyolefine GmbH Geträgerte chemische Verbindung
ATE202365T1 (de) * 1996-08-13 2001-07-15 Basell Polyolefine Gmbh Geträgertes katalysatorsystem, verfahren zu seiner herstellung und seine verwendung zur polymerisation von olefinen
US5783512A (en) 1996-12-18 1998-07-21 The Dow Chemical Company Catalyst component dispersion comprising an ionic compound and solid addition polymerization catalysts containing the same
DE19703478A1 (de) * 1997-01-31 1998-08-06 Hoechst Ag Verfahren zur Herstellung eines Matallocen-Katalysatorsystems
KR100538590B1 (ko) * 1997-04-04 2005-12-22 비피 케미칼즈 리미티드 폴리올레핀의 고수율 합성을 위한 촉매 시스템
US6228795B1 (en) * 1997-06-05 2001-05-08 Exxon Chemical Patents, Inc. Polymeric supported catalysts
US6100214A (en) * 1997-06-05 2000-08-08 Exxon Chemical Patents Inc. Polymeric supported catalysts for olefin polymerization
JP2001515114A (ja) 1997-08-15 2001-09-18 ザ ダウ ケミカル カンパニー 実質的に線状の均一なオレフィン重合体組成物から製造されるフィルム
ID24325A (id) 1997-08-29 2000-07-13 Dow Chemical Co Komposit polimer pengisi yang homogen
CA2245326C (en) * 1997-09-29 2005-04-05 Elf Atochem North America, Inc. Heterogeneous organotin catalysts
KR20010032116A (ko) 1997-12-01 2001-04-16 보 구스타프쏜 수분 흡수 장치
DE69823969T2 (de) * 1997-12-22 2005-05-12 Mitsui Chemicals, Inc. Katalysatorbestandteil, Katalysator und Verfahren zur Polymerisation von äthylenisch ungesättigten Monomeren
WO1999045042A1 (en) 1998-03-04 1999-09-10 Exxon Chemical Patents Inc. Noncoordinating anions for olefin polymerization
US6177375B1 (en) * 1998-03-09 2001-01-23 Pq Corporation High activity olefin polymerization catalysts
BR9911158A (pt) 1998-06-12 2001-04-03 Univation Tech Llc Processos de polimerização de olefinas usando complexos ativados ácido-base de lewis
US6329312B1 (en) * 1998-06-19 2001-12-11 Phillips Petroleum Company Metallocycle metallocenes and their use
ATE355308T1 (de) * 1998-07-16 2006-03-15 Univation Tech Llc Lewis-säure cokatalysatoren auf aluminium-basis für die olefinpolymerisation
WO2000014129A1 (en) * 1998-09-04 2000-03-16 The Dow Chemical Company Long chain branched ethylene homopolymer made by a slurry process and blends thereof
US6159888A (en) * 1998-09-09 2000-12-12 Phillips Petroleum Company Polymerization catalyst systems, their preparation, and use
JP2002524621A (ja) * 1998-09-16 2002-08-06 ザ ダウ ケミカル カンパニー 機能化した触媒担体及び担持触媒系
US6184171B1 (en) * 1998-10-05 2001-02-06 W.R. Grace & Co. -Conn Supported bidentate and tridentate catalyst compositions and olefin polymerization using same
CA2345628C (en) * 1998-10-23 2010-02-16 Exxonmobil Chemical Patents Inc. Bridged metallocenes for olefin copolymerization
US6486088B1 (en) 1998-10-23 2002-11-26 Exxonmobil Chemical Patents Inc. High activity carbenium-activated polymerization catalysts
ATE284421T1 (de) * 1998-10-23 2004-12-15 Exxonmobil Chem Patents Inc Verbrückte hafnocenen für die copolymerisation von olefinen
US6300433B1 (en) 1998-10-23 2001-10-09 Exxonmobil Chemical Patents Inc. Olefin copolymerization process with bridged hafnocenes
US6054623A (en) * 1998-12-18 2000-04-25 Alliedsignal Inc. Hydroxythiol grignard reaction synthesis
US6465385B1 (en) 1999-02-12 2002-10-15 Sunoco, Inc. (R&M) Zwitterionic polymerization catalyst
JP2002542348A (ja) 1999-04-20 2002-12-10 ビーピー ケミカルズ リミテッド 遅延活性支持オレフィン重合触媒組成物、並びにその作成および使用方法
BR9917422A (pt) * 1999-07-15 2002-05-07 Dow Chemical Co Homopolìmeros de etileno de alta densidade e composições de mistura
KR100336618B1 (ko) * 1999-09-28 2002-05-16 박호군 아민기가 치환된 유기실란을 포함한 신규의 메탈로센 화합물
HU226659B1 (en) 1999-10-05 2009-06-29 Mallinckrodt Inc Carbon monoxide source for preparation of transition-metal-carbonyl-complexes
CA2370799A1 (en) * 2000-02-24 2001-08-30 Basell Technology Company Bv Organometallic compound useful as cocatalyst for polymerizing olefins
US6809209B2 (en) 2000-04-07 2004-10-26 Exxonmobil Chemical Patents Inc. Nitrogen-containing group-13 anionic compounds for olefin polymerization
MXPA02012672A (es) * 2000-06-23 2004-04-21 Exxonmobil Chem Patents Inc Activadores de co-catalizador siloxi sustituidos para polimerizacion de olefinas.
US6541410B1 (en) 2000-06-23 2003-04-01 Exxonmobil Chemical Patents Inc. Siloxy substituted cocatalyst activators for olefin polymerization
BR0112516A (pt) * 2000-07-17 2003-09-09 Univation Tech Llc Sistema catalisador e seu emprego em um processo de polimerização
DE10047461A1 (de) * 2000-09-21 2002-04-11 Basf Ag Aminosäurekomplexe und ihre Verwendung zur Herstellung von Olefinpolymerisaten
US6852659B1 (en) * 2000-11-16 2005-02-08 Univation Technologies, Llc Method for preparing a catalyst composition and its use in a polymerization process
EP1366089A2 (en) * 2000-11-17 2003-12-03 Univation Technologies LLC A method for preparing a catalyst composition and its use in a polymerization process
ATE320455T1 (de) * 2000-12-06 2006-04-15 Omlidon Technologies Llc Schmelzverarbeitbares, verschleissfestes polyethylen
MXPA03010095A (es) * 2001-05-04 2004-03-16 Dow Global Technologies Inc Copolimeros o terpolimeros aleatorios o de bloques, producidos usando catalizadores de complejo metalico.
DE60224671T2 (de) 2001-06-15 2009-01-08 Dow Global Technologies, Inc., Midland Verzweigte polymere auf alpha-olefin basis
CN1301292C (zh) * 2001-08-17 2007-02-21 陶氏环球技术公司 双峰聚乙烯组合物及其制品和该组合物的应用
EP1436332A2 (en) * 2001-10-12 2004-07-14 Dow Global Technologies Inc. Metal complex compositions and their use as catalysts to produce polydienes
JP2003128720A (ja) * 2001-10-19 2003-05-08 Sunallomer Ltd オレフィン重合用固体助触媒成分、オレフィン重合用触媒およびイオン含有化合物
AU2003202796B2 (en) * 2002-01-29 2008-09-11 Plus Orthopedics Ag Sintering ultrahigh molecular weight polyethylene
US20050209096A1 (en) * 2002-08-20 2005-09-22 Jacobsen Grant B Supported polymerisation catalysts
US7309677B2 (en) 2002-08-20 2007-12-18 B.P. Chemicals Limited Supported polymerisation catalysts
TWI315314B (en) * 2002-08-29 2009-10-01 Ineos Europe Ltd Polymerisation process
TWI300782B (en) * 2002-08-29 2008-09-11 Ineos Europe Ltd Supported polymerisation catalysts
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
BR0315341B1 (pt) 2002-10-15 2014-02-18 Adesivos compreendendo poliolefina.
US7550528B2 (en) 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US7541402B2 (en) 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
ES2427626T3 (es) * 2003-02-21 2013-10-31 Styron Europe Gmbh Procedimiento para homo- o copolimerización de olefinas conjugadas
WO2004078804A2 (en) * 2003-03-06 2004-09-16 Basell Polyolefine Gmbh Catalyst system for the polymerization of olefins
GB0329348D0 (en) * 2003-12-18 2004-01-21 Bp Chem Int Ltd Polymerisation process
JP2008509277A (ja) * 2004-08-09 2008-03-27 ダウ グローバル テクノロジーズ インコーポレイティド ポリマーの製造のための担持ビス(ヒドロキシアリールアリールオキシ)触媒
US7323523B2 (en) * 2004-12-07 2008-01-29 Nova Chemicals (International) S.A. Adjusting polymer characteristics through process control
EP1693388A1 (en) * 2005-02-21 2006-08-23 Innovene Europe Limited Polymerisation catalysts
US7531602B2 (en) * 2005-10-05 2009-05-12 Nova Chemicals (International) S.A. Polymer blends
US8871131B2 (en) * 2006-10-30 2014-10-28 Smith And Nephew Orthopaedics Ag Processes comprising crosslinking polyethylene or using crosslinked polyethylene
CA2588352A1 (en) * 2007-05-11 2008-11-11 Nova Chemicals Corporation Method to estimate pent values
US20080289274A1 (en) * 2007-05-22 2008-11-27 Nova Chemicals (International) S.A Half panel
EP2025403A1 (en) * 2007-07-24 2009-02-18 Total Petrochemicals Research Feluy Preparation of activating supports
WO2009018506A1 (en) * 2007-08-01 2009-02-05 Albemarle Corporation Processes for making catalyst activators
CA2605044C (en) * 2007-10-01 2014-12-02 Nova Chemicals Corporation Polymerization process using a mixed catalyst system
EP2172490A1 (en) 2008-10-03 2010-04-07 Ineos Europe Limited Controlled polymerisation process
RU2549541C2 (ru) 2009-07-28 2015-04-27 Юнивейшн Текнолоджиз, Ллк Способ полимеризации с использованием нанесенного катализатора с затрудненной геометрией
EP2357035A1 (en) 2010-01-13 2011-08-17 Ineos Europe Limited Polymer powder storage and/or transport and/or degassing vessels
EP2383301A1 (en) 2010-04-30 2011-11-02 Ineos Europe Limited Polymerization process
EP2383298A1 (en) 2010-04-30 2011-11-02 Ineos Europe Limited Polymerization process
CA2713042C (en) 2010-08-11 2017-10-24 Nova Chemicals Corporation Method of controlling polymer architecture
US9394381B2 (en) 2010-11-29 2016-07-19 Ineos Sales (Uk) Limited Polymerisation control process
US8383740B1 (en) 2011-08-12 2013-02-26 Ineos Usa Llc Horizontal agitator
US9181367B2 (en) 2011-10-17 2015-11-10 Ineos Europe Ag Polymer degassing process control
SG11201404170XA (en) 2012-02-29 2014-10-30 Trinseo Europe Gmbh Process for producing diene polymers
CN109369830A (zh) * 2012-07-11 2019-02-22 亚培烯科技(杭州)有限公司 固体活化剂体系及其制备方法
CA2783494C (en) 2012-07-23 2019-07-30 Nova Chemicals Corporation Adjusting polymer composition
JP2015051936A (ja) * 2013-09-06 2015-03-19 株式会社日本触媒 ホウ素化合物の製造方法
US20160215112A1 (en) 2015-01-23 2016-07-28 Nova Chemicals (International) S.A. Enhanced foam resin
CN106336423A (zh) * 2015-07-09 2017-01-18 中国石油化工科技开发有限公司 一类高热稳定性全氟芳基硼酸盐化合物及其制备
EP3480031A1 (en) 2017-11-03 2019-05-08 Trinseo Europe GmbH Polymer blend
US12466902B2 (en) 2019-08-02 2025-11-11 Exxonmobil Chemical Patents Inc. Non-coordinating anion type activators for use with polyolefin polymerization catalysts

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4542119A (en) * 1984-04-11 1985-09-17 Sun Tech, Inc. Hydroformylation catalyst and process
PL276385A1 (en) * 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5096867A (en) * 1990-06-04 1992-03-17 Exxon Chemical Patents Inc. Monocyclopentadienyl transition metal olefin polymerization catalysts
US5055438A (en) * 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
FR2616785B1 (fr) * 1987-06-19 1989-10-06 Solvay Composes guanidiniques comprenant un ion tetraphenylborate substitue et procede d'obtention de ces composes et utilisation des composes lors de la synthese peptidique
US5015749A (en) * 1987-08-31 1991-05-14 The Dow Chemical Company Preparation of polyhydrocarbyl-aluminoxanes
NZ235032A (en) * 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5057475A (en) * 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
US5064802A (en) * 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
US5387568A (en) * 1989-10-30 1995-02-07 Fina Technology, Inc. Preparation of metallocene catalysts for polymerization of olefins
DE69033368T3 (de) * 1990-01-02 2008-07-03 Exxon Chemical Patents, Inc. Ionische Metallocenkatalysatoren auf Träger für Olefinpolymerisation
JP2545006B2 (ja) * 1990-07-03 1996-10-16 ザ ダウ ケミカル カンパニー 付加重合触媒
EP0567584B1 (en) * 1991-01-18 1994-12-28 The Dow Chemical Company Silica supported transition metal catalyst
US5206197A (en) * 1991-03-04 1993-04-27 The Dow Chemical Company Catalyst composition for preparation of syndiotactic vinyl aromatic polymers
ES2108861T3 (es) * 1991-11-25 1998-01-01 Exxon Chemical Patents Inc Composiciones cataliticas polionicas de metales de transicion.
US5374696A (en) * 1992-03-26 1994-12-20 The Dow Chemical Company Addition polymerization process using stabilized reduced metal catalysts
US5330948A (en) * 1992-03-31 1994-07-19 Northwestern University Homogeneous catalysts for stereoregular olefin polymerization
US5296433A (en) * 1992-04-14 1994-03-22 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
CA2141616A1 (en) * 1992-08-05 1994-02-17 Gregory G. Hlatky Gas phase polymerization of ethylene and c to c olefins
EP1110974B1 (en) * 1992-08-05 2007-11-28 ExxonMobil Chemical Patents Inc. Method for preparing a supported activator component
US5354721A (en) * 1993-06-22 1994-10-11 Phillips Petroleum Company Organo-aluminoxy product and use
HUT74312A (en) * 1993-06-24 1996-12-30 Dow Chemical Co Titanium or zirconium complexes, process for producing thereof, polymerization catalysts containing thereof and polymerization process
US5412131A (en) * 1993-07-09 1995-05-02 Albemarle Corporation Teritary amino-aluminoxane halides
US5447895A (en) * 1994-03-10 1995-09-05 Northwestern University Sterically shielded diboron-containing metallocene olefin polymerization catalysts
US5643847A (en) * 1994-08-03 1997-07-01 Exxon Chemical Patents Inc. Supported ionic catalyst composition
US5721183A (en) * 1995-03-10 1998-02-24 The Dow Chemical Company Catalyst system comprising amine or phosphine adducts of tris(organyl)borane compounds
US5587439A (en) * 1995-05-12 1996-12-24 Quantum Chemical Corporation Polymer supported catalyst for olefin polymerization

Also Published As

Publication number Publication date
NO315977B1 (no) 2003-11-24
US5834393A (en) 1998-11-10
HUP9801224A3 (en) 1998-11-30
NO974166L (no) 1997-11-07
NO974166D0 (no) 1997-09-09
WO1996028480A1 (en) 1996-09-19
AR001183A1 (es) 1997-09-24
DE69626531D1 (de) 2003-04-10
PL322177A1 (en) 1998-01-19
HUP9801224A2 (hu) 1998-08-28
BR9604776A (pt) 1998-06-23
TW372240B (en) 1999-10-21
MX9706874A (es) 1997-11-29
CN1116309C (zh) 2003-07-30
CN1181091A (zh) 1998-05-06
IL117408A0 (en) 1996-07-23
CO4560463A1 (es) 1998-02-10
RU2160283C2 (ru) 2000-12-10
EP0856014B1 (en) 2003-03-05
DE69626531T2 (de) 2004-01-15
JPH11503113A (ja) 1999-03-23
AU5357496A (en) 1996-10-02
TR199700932T1 (xx) 1998-01-21
ZA961910B (en) 1997-09-08
CZ285397A3 (cs) 1998-02-18
PL186697B1 (pl) 2004-02-27
AU712417B2 (en) 1999-11-04
KR100420432B1 (ko) 2004-07-23
KR19980702921A (ko) 1998-09-05
EP0856014A1 (en) 1998-08-05
ATE233790T1 (de) 2003-03-15

Similar Documents

Publication Publication Date Title
CO4560463A1 (es) Componente de catalizador soportado, catalizador soportado, proceso de preparacion, proceso de polimerizacion, compuestos complejos, y su preparacion
MX9302668A (es) Catalizador soportado para la (co) polimerizacion de 1-olefinas.
MX168016B (es) Catalizadores mejorados y su uso en la produccion de amoniaco
MX173536B (es) Espuma de poliisocianurato
BR9102815A (pt) Processo para preparar um catalisador de polimerizacao por adicao,catalisador de polimerizacao por adicao,uso como um catalisador de polimerizacao por adicao de um catalisador e processo de polimerizacao por adicao catalitica
BR9806251A (pt) Composição catalìtica para a produção de polìmeros olefìnicos.
BR0007152B1 (pt) processo para produzir catalisador revestido obtido pelo revestimento da composição de componente cataliticamente ativo em um veìculo inativo.
ES2110437T3 (es) Copolimeros de bloques a partir de catalizadores ionicos.
MY115716A (en) Components and catalysts for the polymerization of olefins
DE60002056D1 (de) Olefinpolymerisationsverfahren
BR9814410A (pt) Sistema catalisador suportado, uso do mesmo, e, processos para preparar um polìmero de olefina e, um sistema catalisador suportado.
MX170804B (es) Procedimiento mejorado para la hidrogenolisis/deshidrohalogenacion de fluorohalocarburos o fluorohalohidrocarburos
BR9801063A (pt) Processo para produzir um sistema líquido, e, uso do sistema líquido
ES2160634T3 (es) Sistemas catalizadores de polimerizacion, su produccion y uso.
BR9804750A (pt) Método para modernização, no local, de um reator de sìntese heterogênea exotérmica.
ES2053820T3 (es) Un procedimiento para la sintesis directa de eter dimetilico utilizando un sistema de reactor en fase liquida.
ES2129737T3 (es) Procedimiento para la obtencion de alcoholes opticamente activos mediante reduccion catalitica de acidos carboxilicos opticamente activos.
PT1087759E (pt) Processo para a producao de um laminado compreendendo varias camadas individuais
ES2178775T3 (es) Procedimiento para producir hidroxialdehidos.
ES2184102T3 (es) Procedimiento para la destilacion catalitica.
BR0014456A (pt) Processos para ativação por hidrogênio em alta temperatupa e alta pressão de ferro passivado, e para hidrogenação na presença d um catalizador heterogênio, métodos para uso de nitrilas, e para uso de ferro, e, ferro catalìtico
BR9708622A (pt) Método de adição de ouro em duas etapas para preparar um catalisador de acetato de vinila
BR8504994A (pt) Carga ou um suporte para substancias cataliticamente ativas,um processo para produzir a referida carga ou suporte,um catalizador produzido a partir do referido suporte,e o uso do referido catalisador
ES2022118B3 (es) Un procedimiento para producir catalizadores.
ES2159161T3 (es) Procedimiento para producir acido prusico y catalizador.