BR0111515A - Ativadores de cocatalisadores substituìdos com silóxi para polimerização de olefina - Google Patents

Ativadores de cocatalisadores substituìdos com silóxi para polimerização de olefina

Info

Publication number
BR0111515A
BR0111515A BR0111515-4A BR0111515A BR0111515A BR 0111515 A BR0111515 A BR 0111515A BR 0111515 A BR0111515 A BR 0111515A BR 0111515 A BR0111515 A BR 0111515A
Authority
BR
Brazil
Prior art keywords
cations
group
olefin polymerization
substituted
anilinium
Prior art date
Application number
BR0111515-4A
Other languages
English (en)
Inventor
George Rodriguez
Original Assignee
Exxonmobil Chem Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/602,289 external-priority patent/US6346636B1/en
Priority claimed from US09/599,909 external-priority patent/US6541410B1/en
Application filed by Exxonmobil Chem Patents Inc filed Critical Exxonmobil Chem Patents Inc
Publication of BR0111515A publication Critical patent/BR0111515A/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/643—Component covered by group C08F4/64 with a metal or compound covered by group C08F4/44 other than an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • C07F7/1804—Compounds having Si-O-C linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not

Abstract

"ATIVADORES DE COCATALISADORES SUBSTITUìDOS COM SILóXI PARA POLIMERIZAçãO DE OLEFINA". Esta descrição direciona composições iónicas de matéria compreendendo cátions [Ct]^ +^ e um ânions [A]^ -^, nas quais o ânion compreende um elemento do Grupo 13 ligado a ligantes fluorarila. Pelo menos um dos ligantes fluorarila é substituído com um grupo silóxi representado pelos símbolos -SiOR~ 3~, onde R é um substituinte de hidrocarbila ou hidrocarbilsilila C~ 1~-C~ 30~.[Ct]^ +^ pode ser selecionado de qualquer cátion capaz de uso com catalisadores de polimerização de olefina e tipicamente serão cátions de tritil carbênio de anilínio ou amónio, cátions de metais do Grupo 11, cátions de silílio, os cátions dos sais hidratados de metais de Grupo 1 ou 2, e derivados de cátions de anilínio, amónio, tritil carbênio, e silílio contendo substituintes de hidrocarbila, hidrocarbilsilila, ou hidrocarbilamina C~ 1~-C~ 20~ para um ou mais átomos de hidrogênio dos cátions. As composições iónicas descritas podem ser usadas para ativar catalisadores de polimerização de olefina, e podem ser preparadas para dissolver em solventes alifáticos. Sínteses e polimerização são ilustradas.
BR0111515-4A 2000-06-23 2001-06-18 Ativadores de cocatalisadores substituìdos com silóxi para polimerização de olefina BR0111515A (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/602,289 US6346636B1 (en) 2000-06-23 2000-06-23 Siloxy substituted cocatalyst activators for olefin polymerization
US09/599,909 US6541410B1 (en) 2000-06-23 2000-06-23 Siloxy substituted cocatalyst activators for olefin polymerization
PCT/US2001/019392 WO2002000666A1 (en) 2000-06-23 2001-06-18 Siloxy substituted cocatalyst activators for olefin polymerization

Publications (1)

Publication Number Publication Date
BR0111515A true BR0111515A (pt) 2003-05-06

Family

ID=27083479

Family Applications (2)

Application Number Title Priority Date Filing Date
BR0111515-4A BR0111515A (pt) 2000-06-23 2001-06-18 Ativadores de cocatalisadores substituìdos com silóxi para polimerização de olefina
BR0111487-5A BR0111487A (pt) 2000-06-23 2001-06-19 Ativadores de co-catalisador silóxi substituìdo para polimerização de olefina

Family Applications After (1)

Application Number Title Priority Date Filing Date
BR0111487-5A BR0111487A (pt) 2000-06-23 2001-06-19 Ativadores de co-catalisador silóxi substituìdo para polimerização de olefina

Country Status (8)

Country Link
EP (2) EP1296991B1 (pt)
JP (2) JP2004501926A (pt)
KR (2) KR20030019447A (pt)
CN (2) CN1227255C (pt)
BR (2) BR0111515A (pt)
CA (2) CA2412606A1 (pt)
MX (2) MXPA02012672A (pt)
WO (2) WO2002000666A1 (pt)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2353307A1 (fr) 2001-07-13 2003-01-13 Carmen Parent Appareil et procede pour le traitement des effluents gazeux
JP2003128720A (ja) * 2001-10-19 2003-05-08 Sunallomer Ltd オレフィン重合用固体助触媒成分、オレフィン重合用触媒およびイオン含有化合物
CA2405635A1 (en) 2002-09-27 2004-03-27 C02 Solution Inc. A process and a plant for the production of useful carbonated species and for the recycling of carbon dioxide emissions from power plants
JP5558103B2 (ja) * 2007-11-01 2014-07-23 株式会社Ａｄｅｋａ 塩化合物、カチオン重合開始剤およびカチオン重合性組成物
TW200936619A (en) 2007-11-15 2009-09-01 Univation Tech Llc Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom
JP5688236B2 (ja) 2010-05-25 2015-03-25 出光興産株式会社 触媒組成物及び当該触媒組成物を用いるオレフィン系重合体の製造方法
CN103917292B (zh) 2011-11-08 2016-11-23 尤尼威蒂恩技术有限责任公司 制备催化剂体系的方法
WO2015122414A1 (ja) * 2014-02-13 2015-08-20 三井化学株式会社 エチレン／α－オレフィン共重合体の製造方法
KR20210148178A (ko) * 2019-03-28 2021-12-07 다우 글로벌 테크놀로지스 엘엘씨 올레핀 중합 촉매 활성화제를 위한 약한 배위결합 음이온으로서의 음이온성 iii 족 착물

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL276385A1 (en) 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5198401A (en) 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
FR2679564A1 (fr) 1991-07-23 1993-01-29 Inst Nat Sante Rech Med Nouveaux acylmercaptoalcanoldipeptides, leur preparation et les compositions qui les contiennent.
US5296433A (en) 1992-04-14 1994-03-22 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
US5635573A (en) 1992-12-01 1997-06-03 Exxon Chemical Patents Inc. Method for preparing alpha-olefin/cycloolefin copolymers
US5502017A (en) * 1994-03-10 1996-03-26 Northwestern University Metallocene catalyst containing bulky organic group
US5447895A (en) 1994-03-10 1995-09-05 Northwestern University Sterically shielded diboron-containing metallocene olefin polymerization catalysts
EP0698825A1 (en) 1994-07-29 1996-02-28 AT&T Corp. An energy sensitive resist material and a process for device fabrication using the resist material
ES2188751T3 (es) * 1995-03-10 2003-07-01 Dow Global Technologies Inc Componente catalitico soportado, catalizador soportado, procedimiento de preparacion, procedimiento de polimerizacion, compuestos complejos, y su preparacion.
CZ162698A3 (cs) * 1995-11-27 1998-08-12 The Dow Chemical Company Nosičový materiál, nanesený katalyzátor obsahující volně poutaný aktivátor tvořící kation a způsob adiční polymerace za použití tohoto katalyzátoru
US5856256A (en) 1996-02-20 1999-01-05 Northwestern University Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations
US5763556A (en) 1996-05-21 1998-06-09 Exxon Chemical Patents Inc. Copolymers of ethylene and geminally disubstituted olefins
US5895771A (en) 1997-06-05 1999-04-20 Akzo Nobel Nv Fluorinated alkoxy and/or aryloxy aluminates as cocatalysts for metallocene-catalyzed olefin polymerizations
WO1999030822A1 (en) 1997-12-16 1999-06-24 Exxon Research And Engineering Company Group 11 transition metal amine catalysts for olefin polymerization
ES2196835T3 (es) 1998-02-20 2003-12-16 Dow Global Technologies Inc Activadores cataliticos que comprenden aniones expandidos.
DE19808253A1 (de) 1998-02-27 1999-09-02 Aventis Res & Tech Gmbh & Co Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen

Also Published As

Publication number Publication date
CN1227255C (zh) 2005-11-16
CA2412606A1 (en) 2002-01-03
CA2412608A1 (en) 2002-01-03
KR20030019447A (ko) 2003-03-06
MXPA02012672A (es) 2004-04-21
EP1296991A1 (en) 2003-04-02
JP2004501989A (ja) 2004-01-22
EP1297027A1 (en) 2003-04-02
CN1437607A (zh) 2003-08-20
CN1178960C (zh) 2004-12-08
JP2004501926A (ja) 2004-01-22
WO2002000666A1 (en) 2002-01-03
WO2002000738A1 (en) 2002-01-03
MXPA02012673A (es) 2003-10-14
CN1437618A (zh) 2003-08-20
EP1296991B1 (en) 2013-05-15
KR20030011363A (ko) 2003-02-07
BR0111487A (pt) 2003-03-25

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Legal Events

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B08F Application fees: application dismissed [chapter 8.6 patent gazette]

Free format text: REFERENTE 6A., 7A. E 8A. ANUIDADES.

B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

Free format text: REFERENTE AO DESPACHO PUBLICADO NA RPI 2008 DE 30/06/2009.