BR0111487A - Ativadores de co-catalisador silóxi substituìdo para polimerização de olefina - Google Patents

Ativadores de co-catalisador silóxi substituìdo para polimerização de olefina

Info

Publication number
BR0111487A
BR0111487A BR0111487-5A BR0111487A BR0111487A BR 0111487 A BR0111487 A BR 0111487A BR 0111487 A BR0111487 A BR 0111487A BR 0111487 A BR0111487 A BR 0111487A
Authority
BR
Brazil
Prior art keywords
cations
group
olefin polymerization
siloxy
anilinium
Prior art date
Application number
BR0111487-5A
Other languages
English (en)
Inventor
George Rodriguez
Original Assignee
Exxonmobil Chem Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/599,909 external-priority patent/US6541410B1/en
Priority claimed from US09/602,289 external-priority patent/US6346636B1/en
Application filed by Exxonmobil Chem Patents Inc filed Critical Exxonmobil Chem Patents Inc
Publication of BR0111487A publication Critical patent/BR0111487A/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/643—Component covered by group C08F4/64 with a metal or compound covered by group C08F4/44 other than an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • C07F7/1804—Compounds having Si-O-C linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not

Abstract

"ATIVADORES DE CO-CATALISADOR SILóXI SUBSTITUìDO PARA POLIMERIZAçãO DE OLEFINA". A invenção refere-se a composições iónicas de substância compreendendo cátions positivamente carregados [Ct]^ +^ e ânions negativamente carregados [A]^ -^, o dito ânion compreendendo um elemento do Grupo 13 no núcleo central ao qual são ligados dois ligantes fluorarila, pelo menos um dos ditos ligantes fluorarila sendo substituído com um grupo silóxi representado pelos símbolos -SiOR~ 3~, onde R é um substituinte C~ 1~-C~ 30~ hidrocarbila ou hidrocarbilsilila. [Ct]^ +^ pode ser selecionado de qualquer um capaz de uso com catalisadores de polimerização de olefina e tipicamente será do grupo consistindo em cátions de anilinio e amónio, cátions de tritil carbênio, cátions de metal do Grupo 11, cátions de silílio, os cátions dos sais hidratados dos metais do Grupo 1 ou 2, e derivados dos cátions de anilinio, amónio, tritil carbênio e silílio acima contendo substituintes C~ 1~-C~ 20~ hidrocarbila, hidrocarbilsilila ou hidrocarbilamina para um ou mais átomos de hidrogênio dos ditos cátions. As composições iónicas descritas podem ser usadas para ativar os catalisadores de polimerização de olefina, e podem ser preparadas de modo a serem solúveis em solventes alifáticos. Síntese e polimerização são mostradas.
BR0111487-5A 2000-06-23 2001-06-19 Ativadores de co-catalisador silóxi substituìdo para polimerização de olefina BR0111487A (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/599,909 US6541410B1 (en) 2000-06-23 2000-06-23 Siloxy substituted cocatalyst activators for olefin polymerization
US09/602,289 US6346636B1 (en) 2000-06-23 2000-06-23 Siloxy substituted cocatalyst activators for olefin polymerization
PCT/US2001/019585 WO2002000738A1 (en) 2000-06-23 2001-06-19 Siloxy substituted cocatalyst activators for olefin polymerization

Publications (1)

Publication Number Publication Date
BR0111487A true BR0111487A (pt) 2003-03-25

Family

ID=27083479

Family Applications (2)

Application Number Title Priority Date Filing Date
BR0111515-4A BR0111515A (pt) 2000-06-23 2001-06-18 Ativadores de cocatalisadores substituìdos com silóxi para polimerização de olefina
BR0111487-5A BR0111487A (pt) 2000-06-23 2001-06-19 Ativadores de co-catalisador silóxi substituìdo para polimerização de olefina

Family Applications Before (1)

Application Number Title Priority Date Filing Date
BR0111515-4A BR0111515A (pt) 2000-06-23 2001-06-18 Ativadores de cocatalisadores substituìdos com silóxi para polimerização de olefina

Country Status (8)

Country Link
EP (2) EP1296991B1 (pt)
JP (2) JP2004501926A (pt)
KR (2) KR20030019447A (pt)
CN (2) CN1227255C (pt)
BR (2) BR0111515A (pt)
CA (2) CA2412606A1 (pt)
MX (2) MXPA02012672A (pt)
WO (2) WO2002000666A1 (pt)

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CA2353307A1 (fr) 2001-07-13 2003-01-13 Carmen Parent Appareil et procede pour le traitement des effluents gazeux
JP2003128720A (ja) 2001-10-19 2003-05-08 Sunallomer Ltd オレフィン重合用固体助触媒成分、オレフィン重合用触媒およびイオン含有化合物
CA2405635A1 (en) 2002-09-27 2004-03-27 C02 Solution Inc. A process and a plant for the production of useful carbonated species and for the recycling of carbon dioxide emissions from power plants
EP2223948B1 (en) * 2007-11-01 2013-01-23 Adeka Corporation Salt compound, cationic polymerization initiator and cationically polymerizable composition
TW200936619A (en) 2007-11-15 2009-09-01 Univation Tech Llc Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom
JP5688236B2 (ja) 2010-05-25 2015-03-25 出光興産株式会社 触媒組成物及び当該触媒組成物を用いるオレフィン系重合体の製造方法
EP2750797B1 (en) 2011-11-08 2020-04-01 Univation Technologies, LLC Methods of preparing a catalyst system
CA2936511C (en) * 2014-02-13 2019-06-11 Mitsui Chemicals, Inc. Process for producing ethylene/.alpha.-olefin copolymer
WO2020198196A1 (en) * 2019-03-28 2020-10-01 Dow Global Technologies Llc Anionic group iii complexes as weakly coordinating anions for olefin polymerization catalyst activators

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US5198401A (en) 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
PL276385A1 (en) 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
FR2679564A1 (fr) 1991-07-23 1993-01-29 Inst Nat Sante Rech Med Nouveaux acylmercaptoalcanoldipeptides, leur preparation et les compositions qui les contiennent.
US5296433A (en) 1992-04-14 1994-03-22 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
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US5447895A (en) 1994-03-10 1995-09-05 Northwestern University Sterically shielded diboron-containing metallocene olefin polymerization catalysts
US5502017A (en) * 1994-03-10 1996-03-26 Northwestern University Metallocene catalyst containing bulky organic group
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BR9611772A (pt) * 1995-11-27 1999-02-23 Dow Chemical Co Suporte para uso na preparação de catalisadores para polimerizações por adição catalisador suportado e processo de polimerização por adição
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US5895771A (en) 1997-06-05 1999-04-20 Akzo Nobel Nv Fluorinated alkoxy and/or aryloxy aluminates as cocatalysts for metallocene-catalyzed olefin polymerizations
WO1999030822A1 (en) 1997-12-16 1999-06-24 Exxon Research And Engineering Company Group 11 transition metal amine catalysts for olefin polymerization
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DE19808253A1 (de) 1998-02-27 1999-09-02 Aventis Res & Tech Gmbh & Co Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen

Also Published As

Publication number Publication date
CN1178960C (zh) 2004-12-08
CA2412606A1 (en) 2002-01-03
CA2412608A1 (en) 2002-01-03
WO2002000738A1 (en) 2002-01-03
EP1296991A1 (en) 2003-04-02
WO2002000666A1 (en) 2002-01-03
KR20030019447A (ko) 2003-03-06
CN1437618A (zh) 2003-08-20
MXPA02012673A (es) 2003-10-14
KR20030011363A (ko) 2003-02-07
JP2004501926A (ja) 2004-01-22
EP1297027A1 (en) 2003-04-02
CN1437607A (zh) 2003-08-20
JP2004501989A (ja) 2004-01-22
CN1227255C (zh) 2005-11-16
MXPA02012672A (es) 2004-04-21
BR0111515A (pt) 2003-05-06
EP1296991B1 (en) 2013-05-15

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Legal Events

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B08F Application fees: application dismissed [chapter 8.6 patent gazette]

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B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

Free format text: REFERENTE AO DESPACHO 8.6 DA RPI 2016 DE 25/08/2009.