ES2156153T3 - Procedimiento de produccion de polimero olefinico, y catalizador para la polimerizacion de una olefina. - Google Patents

Procedimiento de produccion de polimero olefinico, y catalizador para la polimerizacion de una olefina.

Info

Publication number
ES2156153T3
ES2156153T3 ES94917804T ES94917804T ES2156153T3 ES 2156153 T3 ES2156153 T3 ES 2156153T3 ES 94917804 T ES94917804 T ES 94917804T ES 94917804 T ES94917804 T ES 94917804T ES 2156153 T3 ES2156153 T3 ES 2156153T3
Authority
ES
Spain
Prior art keywords
catalyst
polymerization
molecular weight
olefin polymer
olefine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94917804T
Other languages
English (en)
Inventor
Syoji Naganuma
Masami Watanabe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Idemitsu Kosan Co Ltd
Original Assignee
Idemitsu Kosan Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=15340962&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2156153(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Idemitsu Kosan Co Ltd filed Critical Idemitsu Kosan Co Ltd
Application granted granted Critical
Publication of ES2156153T3 publication Critical patent/ES2156153T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

SE EXPONEN UN CATALIZADOR PARA LA POLIMERIZACION DE UN OLEFIN, QEU INCLUYE (A) UN COMPUESTO COMPLEJO DE UN METAL DE TRANSICION REPRESENTADO POR LA FORMULA GENERAL (I) DONDE LOS SIMBOLOS RESPECTIVOS SON COMO DEFINIDOS EN LA ESPECIFICACION, (B) UN ACIDO LEWIS O UN COMPUESTO IONICO CAPAZ DE REACCIONAR CON EL COMPUESTO COMPLEJO DE METAL DE TRANSICION DEL COMPONENTE (A) O SU DERIVADO PARA FORMAR UN COMPLEJO IONICO, Y (C) UN COMPUESTO DE ALUMINIO ORGANICO, Y UN PROCESO PARA PREPARAR UN POLIMERO DE OLEFIN EN LA PRESENCIA DE UN CATALIZADOR. EL CATALIZADOR DE LA PRESENTE INVENCION ES INEXPRESIVO Y TIENE UNA ALTA ACTIVIDAD Y, DE ACUERDO CON LA INVENCION, EL DETERIORO DE LA ACTIVIDAD PUEDE SER INHIBIDO Y, EL PESO MOLECULAR DEL POLIMERO OBTENIDO, FACILMENTE AJUSTADO, DE TAL MODO QUE EL POLIMERO DE OLEFIN PUEDE SER PREPARADO EFICAZMENTE CON UN PESO MOLECULAR OPCIONAL Y PUEDE POSEER UNA DISTRIBUCION DE PESO MOLECULAR CON PORCIONES DE BAJOS Y ALTOS PESOS MOLECULARES DISMINUIDAS.
ES94917804T 1993-06-15 1994-06-14 Procedimiento de produccion de polimero olefinico, y catalizador para la polimerizacion de una olefina. Expired - Lifetime ES2156153T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP14353393 1993-06-15

Publications (1)

Publication Number Publication Date
ES2156153T3 true ES2156153T3 (es) 2001-06-16

Family

ID=15340962

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94917804T Expired - Lifetime ES2156153T3 (es) 1993-06-15 1994-06-14 Procedimiento de produccion de polimero olefinico, y catalizador para la polimerizacion de una olefina.

Country Status (6)

Country Link
US (1) US6462154B1 (es)
EP (1) EP0705849B2 (es)
CA (1) CA2164968A1 (es)
DE (2) DE69426648D1 (es)
ES (1) ES2156153T3 (es)
WO (1) WO1994029356A1 (es)

Families Citing this family (24)

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Publication number Priority date Publication date Assignee Title
DE69331777T2 (de) * 1992-06-23 2002-08-29 Dow Chemical Co Verfahren zur herstellung von tetrakisfluorophenylborat
DE19522013A1 (de) * 1995-06-21 1997-01-02 Hoechst Ag Übergangsmetallverbindung
WO1997007141A1 (de) * 1995-08-18 1997-02-27 Targor Gmbh Katalysatorkomponente und katalysatorsystem mit hoher polymerisationsaktivität zur herstellung von polymeren
DE69629178T2 (de) * 1995-12-22 2004-05-27 Tokuyama Corp., Tokuyama Dentale haftmittelzusammensetzung und polymerisationskatalysator
ID16442A (id) * 1996-01-22 1997-10-02 Dow Chemical Co Polimer etilena berat molekul ultra rendah
ID17196A (id) 1996-03-14 1997-12-11 Dow Chemical Co Bahan-bahan perekat yang mengandung polimer-polimer olefin
PL188465B1 (pl) * 1996-05-17 2005-02-28 Bp Chem Int Ltd Kopolimer a-olefinowy, sposób wytwarzania kopolimeru a-olefinowego i folia z kopolimeru a-olefinowego
JPH09309926A (ja) 1996-05-17 1997-12-02 Dow Chem Co:The エチレン共重合体の製造方法
DE59703850D1 (de) † 1996-08-13 2001-07-26 Basell Polyolefine Gmbh Geträgertes Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
US6894131B2 (en) 1998-08-21 2005-05-17 Univation Technologies, Llc Polymerization process using a metallocene catalyst system
US6632901B2 (en) * 1998-08-21 2003-10-14 Univation Technologies, Llc Polymerization process using an improved bulky ligand metallocene-type catalyst system
EP1640386A3 (en) * 1998-08-21 2006-04-12 Univation Technologies, LLC Polymerization process using an improved bulky ligand metallocene-type catalyst-system
KR100662954B1 (ko) 1999-01-21 2006-12-28 이데미쓰 고산 가부시키가이샤 알파-올레핀 제조용 촉매 및 알파-올레핀의 제조 방법
US6303718B1 (en) * 1999-09-17 2001-10-16 Bayer Aktiengesellschaft Composition based on fluorine-containing metal complexes
US6753390B2 (en) 2002-09-04 2004-06-22 Univation Technologies, Llc Gas phase polymerization process
US6884748B2 (en) 2002-09-04 2005-04-26 Univation Technologies, Llc Process for producing fluorinated catalysts
US6875828B2 (en) 2002-09-04 2005-04-05 Univation Technologies, Llc Bimodal polyolefin production process and films therefrom
DE60304595T3 (de) 2002-10-02 2012-01-12 Dow Global Technologies Inc. Flüssige und gelartige niedermolekulare ethylenpolymere
DE60322410D1 (de) 2002-10-17 2008-09-04 Dow Global Technologies Inc Hochgefüllte polymerzusammensetzungen
US6869903B2 (en) 2002-11-07 2005-03-22 Univation Technologies, Llc Synthesis of polymerization catalyst components
US6890876B2 (en) 2002-11-26 2005-05-10 Univation Technologies, Llc Processes for producing fluorided catalysts from nitrogenous metallocenes
US7282546B2 (en) * 2005-06-22 2007-10-16 Fina Technology, Inc. Cocatalysts for reduction of production problems in metallocene-catalyzed polymerizations
US7759489B2 (en) * 2006-01-27 2010-07-20 Idemitsu Kosan Co., Ltd. Transition metal complex compound and organic electroluminescence device using the compound
US8455415B2 (en) * 2009-10-23 2013-06-04 Exxonmobil Research And Engineering Company Poly(alpha-olefin/alkylene glycol) copolymer, process for making, and a lubricant formulation therefor

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JPH0699519B2 (ja) 1984-05-28 1994-12-07 出光興産株式会社 エチレン共重合体の製造方法
DE3752260T2 (de) † 1986-09-24 1999-09-02 Mitsui Chemicals Verfahren zur Olefinpolymerisation
US5055438A (en) 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
US5096867A (en) * 1990-06-04 1992-03-17 Exxon Chemical Patents Inc. Monocyclopentadienyl transition metal olefin polymerization catalysts
US5041584A (en) † 1988-12-02 1991-08-20 Texas Alkyls, Inc. Modified methylaluminoxane
NZ235032A (en) * 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5763547A (en) * 1992-10-02 1998-06-09 The Dow Chemical Company Supported catalyst complexes for olefin in polymerization
US5057475A (en) * 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
US5420217A (en) * 1989-09-13 1995-05-30 Exxon Chemical Patents Inc. Process for producing amorphous poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
US5064802A (en) † 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
ES2087145T3 (es) * 1989-10-10 1996-07-16 Fina Technology Catalizadores metalocenos con acidos de lewis y alkilo-aluminios.
ATE147761T1 (de) 1990-06-22 1997-02-15 Exxon Chemical Patents Inc Aluminiumfreie monocyclopentadienyl- metallocenkatalysatoren für olefinpolymerisation
US5272236A (en) * 1991-10-15 1993-12-21 The Dow Chemical Company Elastic substantially linear olefin polymers
JP3115595B2 (ja) † 1990-07-24 2000-12-11 三井化学株式会社 α―オレフィンの重合触媒及びそれを用いたポリ―α―オレフィンの製造方法
US5369196A (en) * 1990-11-30 1994-11-29 Idemitsu Kosan Co., Ltd. Production process of olefin based polymers
DE69222700T2 (de) * 1991-07-11 1998-03-26 Idemitsu Kosan Co Verfahren zur Herstellung von Polymeren auf Olefinbasis und Olefin-Polymerisationskatalysatoren
US5278272A (en) † 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers
WO1993013140A1 (en) * 1991-12-23 1993-07-08 Exxon Chemical Patents Inc. A modified monocyclopentadienyl transition metal/alumoxane catalyst system for polymerization of olefins
DE69232297T2 (de) * 1992-01-06 2002-08-14 Dow Chemical Co Katalysatorzusammensetzung
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BE1005957A5 (fr) * 1992-06-05 1994-04-05 Solvay Procede de preparation d'un systeme catalytique, procede de (co)polymerisation d'olefines et (co)polymeres d'au moins une olefine.
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JP3202349B2 (ja) * 1992-09-22 2001-08-27 三菱化学株式会社 触媒組成物およびそれを用いるオレフィンの重合法
KR100287389B1 (ko) † 1992-10-02 2001-04-16 그래햄 이. 테일러 올레핀 중합반응을 위한 지지된 균일한 촉매(supported homogeneous catalyst complexes for olefin polymerization)
JP3370331B2 (ja) * 1992-10-05 2003-01-27 エクソンモービル・ケミカル・パテンツ・インク 改善された生産性の触媒系及びその重合プロセスにおける使用
JP3188092B2 (ja) 1994-02-25 2001-07-16 三菱重工業株式会社 脱水シューブレード

Also Published As

Publication number Publication date
DE69426648T4 (de) 2002-06-13
WO1994029356A1 (fr) 1994-12-22
EP0705849A1 (en) 1996-04-10
EP0705849A4 (en) 1996-10-23
DE69426648D1 (de) 2001-03-08
EP0705849B2 (en) 2004-06-16
DE69426648T3 (de) 2005-02-03
DE69426648T2 (de) 2001-05-31
US6462154B1 (en) 2002-10-08
CA2164968A1 (en) 1994-12-22
EP0705849B1 (en) 2001-01-31

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