SG11201808184YA - Olefin polymerization catalyst systems and methods of use thereof - Google Patents

Olefin polymerization catalyst systems and methods of use thereof

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Publication number
SG11201808184YA
SG11201808184YA SG11201808184YA SG11201808184YA SG11201808184YA SG 11201808184Y A SG11201808184Y A SG 11201808184YA SG 11201808184Y A SG11201808184Y A SG 11201808184YA SG 11201808184Y A SG11201808184Y A SG 11201808184YA SG 11201808184Y A SG11201808184Y A SG 11201808184YA
Authority
SG
Singapore
Prior art keywords
dow
michigan
international
midland
substituted
Prior art date
Application number
SG11201808184YA
Inventor
Brad C Bailey
Matthew D Christianson
Anna V Davis
Jasson T Patton
Tomas Paine
Original Assignee
Dow Global Technologies Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Llc filed Critical Dow Global Technologies Llc
Publication of SG11201808184YA publication Critical patent/SG11201808184YA/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/64003—Titanium, zirconium, hafnium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/64006—Bidentate ligand
    • C08F4/64041—Monoanionic ligand
    • C08F4/64044—NN
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/01—High molecular weight, e.g. >800,000 Da.
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/03—Narrow molecular weight distribution, i.e. Mw/Mn < 3

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property -, Organization 1111111101111011101010111110101111101110101111111111111101101111101111011111 International Bureau ... ..... ..)d (10) International Publication Number .... .....1 (43) International Publication Date WO 2017/173080 Al 5 October 2017 (05.10.2017) WIP0 I PCT (51) International Patent Classification: (74) Agents: EARLE, Ashley, J. et al.; Dinsmore & Shohl C08F 210/16 (2006.01) C08F 4/642 (2006.01) LLP, One South Main Street, Suite 1300, Dayton, Ohio 45402 (US). (21) International Application Number: PCT/US2017/025022 (81) Designated States (unless otherwise indicated, for every kind of national protection available): AE, AG, AL, AM, (22) International Filing Date: AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, 30 March 2017 (30.03.2017) BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, (25) Filing Language: English DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KH, KN, (26) Publication Language: English KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, (30) Priority Data: MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, 62/316,015 31 March 2016 (31.03.2016) US NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, (71) Applicant: DOW GLOBAL TECHNOLOGIES LLC TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, [US/US]; 2040 Dow Center, Midland, Michigan 48674 ZA, ZM, ZW. (US). (84) Designated States (unless otherwise indicated, for every (72) Inventors: BAILEY, Brad C.; c/o Dow Global Technolo- kind of regional protection available): ARIPO (BW, GH, gies LLC, 2040 Dow Center, Building 1776/D3C, Mid- GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, land, Michigan 48674 (US). CHRISTIANSON, Matthew TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, D.; c/o Dow Global Technologies LLC, 2040 Dow Center, TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, _ Building 1776/D2A, Midland, Michigan 48674 (US). DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, — DAVIS, Anna V.; c/o Dow Global Technologies LLC, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, — 2040 Dow Center, Building 1776/D4A, Midland, Michigan SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, 48674 (US). PATTON, Jasson T.; c/o Dow Global Tech- GW, KM, ML, MR, NE, SN, TD, TG). nologies LLC, 2040 Dow Center, Building 1776, Midland, Michigan 48674 (US). PAINE, Tomas; c/o Dow Global Published: = = Technologies LLC, 2040 Dow Center, Midland, Michigan — with international search report (Art. 21(3)) 48674 (US). = = = = Title: OLEFIN POLYMERIZATION CATALYST SYSTEMS AND METHODS OF USE THEREOF (54) = R1 (X) n R10 = R2 N M N / \ _ ,-, © GC R 3 N N R4 I R 7 R6 0 R5 en IN (I) 1-1 ---- (57) : Olefin polymerization catalyst systems are provided that include a procatalyst component having a metal-ligand com- L N plex of Formula (I): [formula] (I) where each X is a neutral, monoanionic, or dianionic, monodentate or polydentate ligand such that ::::) the complex of Formula (I) is neutral; each R 1 and R 19 is a (C 6 -C 4o )aryl, substituted (C 6 -C 4o )aryl, (C 3 -C 4o )heteroaryl, or substituted ei (C3-C4o)heteroaryl; each R 2 , R, R 3 4 , R 7 , R 8 , and R 9 is a hydrogen; (Ci-C4o)hydrocarbyl; substituted (Ci-C4o)hydrocarbyl; (Ci-C4o)het- O erohydrocarbyl; substituted (C-C i 4o )heterohydrocarbyl; halogen; or nitro (NO 2 ) group; and each R 5 and R 6 is a (C i -C)alkyl; substi- tuted (Ci-C4o)alkyl; or [(Si)i-(C+Si)4o] substituted organosilyl. Additionally, olefm-based polymers and processes for polymerizing one or more olefin-based polymers in the presence of the olefm polymerization catalyst systems are also provided.
SG11201808184YA 2016-03-31 2017-03-30 Olefin polymerization catalyst systems and methods of use thereof SG11201808184YA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201662316015P 2016-03-31 2016-03-31
PCT/US2017/025022 WO2017173080A1 (en) 2016-03-31 2017-03-30 Olefin polymerization catalyst systems and methods of use thereof

Publications (1)

Publication Number Publication Date
SG11201808184YA true SG11201808184YA (en) 2018-10-30

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Country Status (9)

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US (1) US10968289B2 (en)
EP (1) EP3436487B1 (en)
JP (1) JP7023238B2 (en)
KR (1) KR102314329B1 (en)
CN (1) CN108779204B (en)
BR (1) BR112018069231B1 (en)
ES (1) ES2775787T3 (en)
SG (1) SG11201808184YA (en)
WO (1) WO2017173080A1 (en)

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US20230183401A1 (en) 2019-04-30 2023-06-15 Dow Global Technologies Llc Alkene functionalized activators and their use in electrical applications
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JP2023508106A (en) 2019-12-30 2023-02-28 ダウ グローバル テクノロジーズ エルエルシー Process for preparing alpha-substituted acrylates
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Publication number Publication date
ES2775787T3 (en) 2020-07-28
KR20180133249A (en) 2018-12-13
KR102314329B1 (en) 2021-10-20
CN108779204A (en) 2018-11-09
US20200277411A1 (en) 2020-09-03
BR112018069231B1 (en) 2022-08-30
BR112018069231A2 (en) 2019-01-22
EP3436487A1 (en) 2019-02-06
JP2019518085A (en) 2019-06-27
US10968289B2 (en) 2021-04-06
JP7023238B2 (en) 2022-02-21
EP3436487B1 (en) 2020-01-22
WO2017173080A1 (en) 2017-10-05
CN108779204B (en) 2021-06-18

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