SG11201900653RA - Silyl-bridged bis-biphenyl-phenoxy catalysts for olefin polymerization - Google Patents

Silyl-bridged bis-biphenyl-phenoxy catalysts for olefin polymerization

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Publication number
SG11201900653RA
SG11201900653RA SG11201900653RA SG11201900653RA SG11201900653RA SG 11201900653R A SG11201900653R A SG 11201900653RA SG 11201900653R A SG11201900653R A SG 11201900653RA SG 11201900653R A SG11201900653R A SG 11201900653RA SG 11201900653R A SG11201900653R A SG 11201900653RA
Authority
SG
Singapore
Prior art keywords
dow
jackson
abner
herbert
texas
Prior art date
Application number
SG11201900653RA
Inventor
Hien Q Do
Philip P Fontaine
Andrew J Young
Susan G Brown
Johnathan E Delorbe
Tulaza Vaidya
Zach T Rickaway
Amy E Floeck
Chunming Zhang
Ruth Figueroa
Jerzy Klosin
Original Assignee
Dow Global Technologies Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Llc filed Critical Dow Global Technologies Llc
Publication of SG11201900653RA publication Critical patent/SG11201900653RA/en

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/64003—Titanium, zirconium, hafnium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/64168—Tetra- or multi-dentate ligand
    • C08F4/64186—Dianionic ligand
    • C08F4/64193—OOOO
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/01—High molecular weight, e.g. >800,000 Da.
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/03—Narrow molecular weight distribution, i.e. Mw/Mn < 3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/08—Low density, i.e. < 0.91 g/cm3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12—Melt flow index or melt flow ratio
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

GelPelliNin Cliornatcgra* .00 2.50 3.00 3.50 4.00 450 5.00 W O 20 18/022975 Al (12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (43) International Publication Date 01 February 2018 (01.02.2018) WIP0 I PCT olimion °nolo omolomommoiniflom (10) International Publication Number WO 2018/022975 Al (51) International Patent Classification: C08F 210/16 (2006.01) C08F 4/659 (2006.01) (21) International Application Number: PCT/US2017/044338 (22) International Filing Date: 28 July 2017 (28.07.2017) (25) Filing Language: English (26) Publication Language: English (30) Priority Data: 62/368,706 29 July 2016 (29.07.2016) US (71) Applicant: DOW GLOBAL TECHNOLOGIES LLC [US/US]; 2040 Dow Center, Midland, Michigan 48674 (US). (72) Inventors: DO, Hien Q.; The Dow Chemical Company, 230 Abner Jackson Parkway, Herbert H. Dow Building, Lake Jackson, Texas 77566 (US). FONTAINE, Philip P.; The Dow Chemical Company, 230 Abner Jackson Park- way, Herbert H. Dow Building, Lake Jackson, Texas 77566 (US). YOUNG, Andrew J.; The Dow Chemical Compa- ny, 230 Abner Jackson Parkway, Herbert H. Dow Build- ing, Lake Jackson, Texas 77566 (US). BROWN, Susan G.; The Dow Chemical Company, 230 Abner Jackson Parkway, Herbert H. Dow Building, Lake Jackson, Texas 77566 (US). DELORBE, Johnathan E.; The Dow Chemical Compa- ny, 230 Abner Jackson Parkway, Herbert H. Dow Build- ing, Lake Jackson, Texas 77566 (US). VAIDYA, Tulaza; The Dow Chemical Company, 230 Abner Jackson Park- way, Herbert H. Dow Building, Lake Jackson, Texas 77566 (US). RICKAWAY, Zach T.; The Dow Chemical Compa- ny, 230 Abner Jackson Parkway, Herbert H. Dow Building, Lake Jackson, Texas 77566 (US). DUCHNOWSKI, Amy E.; The Dow Chemical Company, 230 Abner Jackson Park- way, Herbert H. Dow Building, Lake Jackson, Texas 77566 (US). CHUNMING, Zhang; 2040 Dow Center, Mid- land, Michigan 48674 (US). FIGUEROA, Ruth; Building 1776, Washington Street, Midland, Michigan 48674 (US). KLOSIN, Jerzy; Building 1776, Washington Street, Mid- land, Michigan 48674 (US). (74) Agent: MOLLOY, Matthew A. et al.; Dinsmore & Shohl LLP, Fifth Third Center, One South Main Street, Suite 1300, Dayton, Ohio 45402 (US). (81) Designated States (unless otherwise indicated, for every kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JO, JP, KE, KG, KH, KN, KP, (54) Title: SILYL-BRIDGED BIS-BIPHENYL-PHENOXY CATALYSTS FOR OLEFIN POLYMERIZATION (57) : Embodiments are directed to a metal complex formed, wherein the metal complexes are used as pro-catalyst in polyolefin poly- merization and comprise the following structure (Formula (I)). 1.4 Winder Weight (by GPC) FIG. 1 [Continued on next page] WO 2018/022975 Al IMEDIMOMMIDIRE10101011010HOIROMMEMOE# KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (84) Designated States (unless otherwise indicated, for every kind of regional protection available): ARIPO (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG). Published: — with international search report (Art. 21(3))
SG11201900653RA 2016-07-29 2017-07-28 Silyl-bridged bis-biphenyl-phenoxy catalysts for olefin polymerization SG11201900653RA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201662368706P 2016-07-29 2016-07-29
PCT/US2017/044338 WO2018022975A1 (en) 2016-07-29 2017-07-28 Silyl-bridged bis-biphenyl-phenoxy catalysts for olefin polymerization

Publications (1)

Publication Number Publication Date
SG11201900653RA true SG11201900653RA (en) 2019-02-27

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SG10202101020PA SG10202101020PA (en) 2016-07-29 2017-07-28 Silyl-bridged bis-biphenyl-phenoxy catalysts for olefin polymerization

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Country Status (7)

Country Link
US (1) US11111318B2 (en)
EP (1) EP3491034A1 (en)
KR (1) KR102423018B1 (en)
CN (1) CN109476783B (en)
BR (1) BR112019001111B1 (en)
SG (2) SG11201900653RA (en)
WO (1) WO2018022975A1 (en)

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CN109476783B (en) 2016-07-29 2022-11-01 陶氏环球技术有限责任公司 Silyl-bridged bis-biphenyl-phenoxy catalysts for olefin polymerization
WO2020047384A1 (en) * 2018-08-30 2020-03-05 Dow Global Technologies Llc Bis-phenyl-phenoxy polyolefin procatalysts having two anthracenyl ligands
CN113710678A (en) * 2019-03-31 2021-11-26 陶氏环球技术有限责任公司 Method for preparing catalyst precursor material
WO2021128126A1 (en) * 2019-12-26 2021-07-01 Dow Global Technologies Llc Alpha-olefin interpolymers with improved molecular design for photovoltaic encapsulants
WO2021155158A1 (en) * 2020-01-31 2021-08-05 Dow Global Technologies Llc Group iii and lanthanide bis-phenyl-phenoxy metal-ligand complexes
EP4097152A1 (en) * 2020-01-31 2022-12-07 Dow Global Technologies LLC Polymerization processes that include group iii and lanthanide bis-phenyl-phenoxy metal-ligand complexes and chain transfer agents
US20230146294A1 (en) 2020-02-24 2023-05-11 Dow Global Technologies Llc Non-cryogenic synthesis of heteroatom-bridge precursors of metal-ligand complex catalysts
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Publication number Publication date
US20200247917A1 (en) 2020-08-06
CN109476783A (en) 2019-03-15
BR112019001111B1 (en) 2022-08-23
KR102423018B1 (en) 2022-07-21
WO2018022975A1 (en) 2018-02-01
SG10202101020PA (en) 2021-03-30
KR20190036535A (en) 2019-04-04
CN109476783B (en) 2022-11-01
BR112019001111A2 (en) 2019-04-30
US11111318B2 (en) 2021-09-07
EP3491034A1 (en) 2019-06-05

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