SG11201808185XA - Olefin polymerization catalyst systems and methods of use thereof - Google Patents

Olefin polymerization catalyst systems and methods of use thereof

Info

Publication number
SG11201808185XA
SG11201808185XA SG11201808185XA SG11201808185XA SG11201808185XA SG 11201808185X A SG11201808185X A SG 11201808185XA SG 11201808185X A SG11201808185X A SG 11201808185XA SG 11201808185X A SG11201808185X A SG 11201808185XA SG 11201808185X A SG11201808185X A SG 11201808185XA
Authority
SG
Singapore
Prior art keywords
substituted
international
heterohydrocarbyl
hydrocarbyl
michigan
Prior art date
Application number
SG11201808185XA
Inventor
Brad C Bailey
Matthew D Christianson
Sanil Sreekumar
Original Assignee
Dow Global Technologies Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Llc filed Critical Dow Global Technologies Llc
Publication of SG11201808185XA publication Critical patent/SG11201808185XA/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/64003—Titanium, zirconium, hafnium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/64006—Bidentate ligand
    • C08F4/64041—Monoanionic ligand
    • C08F4/64044—NN
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Catalysts (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property -, Organization 111111110111101110101011111010111110111010111111111011111101111101111011111 International Bureau ... ./ j (10) International Publication Number .... .....1 (43) International Publication Date WO 2017/173079 Al 5 October 2017 (05.10.2017) WIP0 I PCT (51) International Patent Classification: AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, C08F 210/16 (2006.01) C08F 2/38 (2006.01) BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, CO8F 4/642 (2006.01) DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KH, KN, (21) International Application Number: KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, PCT/US2017/025021 MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, (22) International Filing Date: NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, 30 March 2017 (30.03.2017) RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, (25) Filing Language: English ZA, ZM, ZW. (26) Publication Language: English (84) Designated States (unless otherwise indicated, for every (30) Priority Data: kind of regional protection available): ARIPO (BW, GH, 62/315,984 31 March 2016 (31.03.2016) US GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, (71) Applicant: DOW GLOBAL TECHNOLOGIES LLC TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, [US/US]; 2040 Dow Center, Midland, Michigan 48674 DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, (US). LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, (72) SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, Inventors: BAILEY, Brad C.; 2040 Dow Center, Build- GW, KM, ML, MR, NE, SN, TD, TG). ing 1776/D3C, Midland, Michigan 48674 (US). CHRIS- TIANSON, Matthew D.; 2040 Dow Center, Building Declarations under Rule 4.17: 1776/D2A, Midland, Michigan 48674 (US). SREEKU- as to applicant's entitlement to apply for and be a granted MAR, Sanil; 2040 Dow Center, Building 1776/D6A, Mid patent (Rule 4.17(ii)) land, Michigan 48674 (US). — as to the applicant's entitlement to claim the priority of the — (74) Agents: MCNEELY, Richard J. et al.; Dinsmore & Shohl earlier application (Rule 4.17(iii)) LLP, One South Main Street, Fifth Third Center, Suite = 1300, Dayton, Ohio 45402 (US). Published: Designated States (unless otherwise indicated, for every — with international search report (Art. 21(3)) kind of national protection available): AE, AG, AL, AM, (81) OLEFIN POLYMERIZATION CATALYST SYSTEMS AND METHODS OF USE THEREOF (54) Title: R1 (X) n R10 I I R 2 ..... .... y1 M v1 0 p 9 .....- 1 ........ , , 1 v y2 \".. .Z. \"' N ----- N y' i 1 I I (I) .Y3 ,....y8 '',.. .. R 3 Y 4 N N Y7 R 8 I I 1-1 c:r IN © M 1 I R 4 R 7 R 5 R 6 N (57) : An olefin polymerization catalyst system includes a procatalyst component chosen from metal-ligand complexes of 1-1 ---- Formula (I): In Formula (I), each X is independently a monodentate or polydentate ligand that is neutral, monoanionic, or dianionic; N the metal-ligand complex of Formula (I) is overall neutral; each Y 1 -Y 4 and Y 7 -Y 10 independently is selected from C or N such that 1-1 C six membered diaza (N 2 ) or triaza (N 3 ) rings are formed; wherein each R 1 and R I° independently are chosen from (C1-C40) hydro- ei carbyl, substituted (C1-C40) hydrocarbyl, (C1-C40) heterohydrocarbyl, and substituted (C1-C40) heterohydrocarbyl or is absent; each en. ) R 2 , R 3 , R 4 , R 7 , R 8 , and R 9 is chosen from hydrogen; (C 1 -C 40 ) hydrocarbyl; substituted (C 1 -C 40 ) hydrocarbyl; (C 1 -C 40 ) heterohydro- carbyl; substituted (C1-C40) heterohydrocarbyl; halogen, nitro (NO2) or is absent; each R 5 and R 6 independently is chosen from (CI- C 40 ) hydrocarbyl, substituted (C 1 -C 40 ) hydrocarbyl, (C 1 -C 40 ) heterohydrocarbyl, and substituted (C 1 -C 40 ) heterohydrocarbyl.
SG11201808185XA 2016-03-31 2017-03-30 Olefin polymerization catalyst systems and methods of use thereof SG11201808185XA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201662315984P 2016-03-31 2016-03-31
PCT/US2017/025021 WO2017173079A1 (en) 2016-03-31 2017-03-30 Olefin polymerization catalyst systems and methods of use thereof

Publications (1)

Publication Number Publication Date
SG11201808185XA true SG11201808185XA (en) 2018-10-30

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ID=58547848

Family Applications (1)

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SG11201808185XA SG11201808185XA (en) 2016-03-31 2017-03-30 Olefin polymerization catalyst systems and methods of use thereof

Country Status (9)

Country Link
US (1) US10919995B2 (en)
EP (1) EP3436486B1 (en)
JP (1) JP6916809B2 (en)
KR (1) KR102320610B1 (en)
CN (1) CN108884196B (en)
BR (1) BR112018069252B1 (en)
ES (1) ES2820365T3 (en)
SG (1) SG11201808185XA (en)
WO (1) WO2017173079A1 (en)

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JP2022543558A (en) * 2019-07-31 2022-10-13 ダウ グローバル テクノロジーズ エルエルシー Polymerization catalyst for producing polyethylene with high molecular weight
CN114364706A (en) * 2019-09-30 2022-04-15 陶氏环球技术有限责任公司 Bidentate biaryl phenoxy group IV transition metal catalysts for olefin polymerization with chain transfer agents
KR20220123255A (en) * 2019-12-27 2022-09-06 다우 글로벌 테크놀로지스 엘엘씨 Ethylene/butene multiblock copolymer and method for preparing same

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Also Published As

Publication number Publication date
ES2820365T3 (en) 2021-04-20
BR112018069252A2 (en) 2019-01-22
CN108884196B (en) 2021-06-18
JP6916809B2 (en) 2021-08-11
US10919995B2 (en) 2021-02-16
KR102320610B1 (en) 2021-11-03
KR20180132679A (en) 2018-12-12
CN108884196A (en) 2018-11-23
US20200299430A1 (en) 2020-09-24
BR112018069252B1 (en) 2022-11-08
JP2019511601A (en) 2019-04-25
WO2017173079A1 (en) 2017-10-05
EP3436486B1 (en) 2020-08-05
EP3436486A1 (en) 2019-02-06

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