ATE504349T1 - Verfahren zur auswahl von polymerisationsmodifikatoren - Google Patents

Verfahren zur auswahl von polymerisationsmodifikatoren

Info

Publication number
ATE504349T1
ATE504349T1 AT05761065T AT05761065T ATE504349T1 AT E504349 T1 ATE504349 T1 AT E504349T1 AT 05761065 T AT05761065 T AT 05761065T AT 05761065 T AT05761065 T AT 05761065T AT E504349 T1 ATE504349 T1 AT E504349T1
Authority
AT
Austria
Prior art keywords
reaction products
molar reaction
hydroxysilane
diphenylphenol
butyldi
Prior art date
Application number
AT05761065T
Other languages
English (en)
Inventor
Daryoosh Beigzadeh
Campbell, Jr
David Devore
Duane Romer
James Stevens
Francis Timmers
Hendrik Tuinstra
Paul Vosejpka
Original Assignee
Dow Global Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Inc filed Critical Dow Global Technologies Inc
Application granted granted Critical
Publication of ATE504349T1 publication Critical patent/ATE504349T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00274—Sequential or parallel reactions; Apparatus and devices for combinatorial chemistry or for making arrays; Chemical library technology
    • B01J2219/00583—Features relative to the processes being carried out
    • B01J2219/00585—Parallel processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00274—Sequential or parallel reactions; Apparatus and devices for combinatorial chemistry or for making arrays; Chemical library technology
    • B01J2219/00583—Features relative to the processes being carried out
    • B01J2219/0059—Sequential processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00274—Sequential or parallel reactions; Apparatus and devices for combinatorial chemistry or for making arrays; Chemical library technology
    • B01J2219/0068—Means for controlling the apparatus of the process
    • B01J2219/00702—Processes involving means for analysing and characterising the products
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00274—Sequential or parallel reactions; Apparatus and devices for combinatorial chemistry or for making arrays; Chemical library technology
    • B01J2219/00718—Type of compounds synthesised
    • B01J2219/0072—Organic compounds
    • B01J2219/00736—Non-biologic macromolecules, e.g. polymeric compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00274—Sequential or parallel reactions; Apparatus and devices for combinatorial chemistry or for making arrays; Chemical library technology
    • B01J2219/00718—Type of compounds synthesised
    • B01J2219/0072—Organic compounds
    • B01J2219/00738—Organic catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts
AT05761065T 2004-06-16 2005-05-13 Verfahren zur auswahl von polymerisationsmodifikatoren ATE504349T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US58033004P 2004-06-16 2004-06-16
PCT/US2005/016792 WO2006007094A2 (en) 2004-06-16 2005-05-13 Technique for selecting polymerization modifiers

Publications (1)

Publication Number Publication Date
ATE504349T1 true ATE504349T1 (de) 2011-04-15

Family

ID=35134396

Family Applications (1)

Application Number Title Priority Date Filing Date
AT05761065T ATE504349T1 (de) 2004-06-16 2005-05-13 Verfahren zur auswahl von polymerisationsmodifikatoren

Country Status (9)

Country Link
US (4) US7553917B2 (de)
EP (3) EP1763542B1 (de)
JP (3) JP5188178B2 (de)
CN (4) CN1968973B (de)
AT (1) ATE504349T1 (de)
DE (1) DE602005027351D1 (de)
ES (1) ES2642131T3 (de)
TW (1) TW200617043A (de)
WO (1) WO2006007094A2 (de)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1763542B1 (de) * 2004-06-16 2011-04-06 Dow Global Technologies Inc. Verfahren zur auswahl von polymerisationsmodifikatoren
US8153243B2 (en) 2005-12-09 2012-04-10 Dow Global Technologies Llc Interpolymers suitable for multilayer films
CN101326203A (zh) 2005-12-09 2008-12-17 陶氏环球技术公司 乙烯/α-烯烃组合物中控制分子量分布的方法
CN101711258B (zh) * 2007-03-07 2012-07-04 陶氏环球技术有限责任公司 系连负载型过渡金属络合物
US7868107B2 (en) * 2007-03-09 2011-01-11 Zeon Corporation Process for producing cycloolefin addition polymer, catalyst for addition polymerization of cycloolefin, and transition metal compound
US20110003940A1 (en) * 2009-07-01 2011-01-06 Dow Global Technologies Inc. Ethylene-based polymer compositions for use as a blend component in shrinkage film applications
US8629214B2 (en) 2009-07-01 2014-01-14 Dow Global Technologies Llc. Ethylene-based polymer compositions for use as a blend component in shrinkage film applications
KR101212637B1 (ko) 2011-06-09 2012-12-14 에스케이종합화학 주식회사 신규한 사이클로펜타［ｂ］플루오레닐 전이금속 화합물, 이를 포함하는 전이금속 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법
CN103857706B (zh) 2011-09-30 2016-09-28 埃克森美孚化学专利公司 金属茂催化剂的动力学调制
WO2014083037A1 (en) * 2012-11-27 2014-06-05 Total Research & Technology Feluy Device and method for quantification of polymerisation reaction
CN111247175B (zh) * 2018-04-05 2023-01-06 Lg化学株式会社 具有阳离子金属配合物和基于硼酸根的大体积阴离子的有机金属催化剂，其制备方法，以及使用该催化剂制备低聚物或聚合物的方法
KR20210069662A (ko) 2018-09-28 2021-06-11 다우 글로벌 테크놀로지스 엘엘씨 4작용성 장쇄 분지형 폴리올레핀 수지를 중합하는 방법
KR20210069661A (ko) 2018-09-28 2021-06-11 다우 글로벌 테크놀로지스 엘엘씨 4작용성 장쇄 분지형 에틸렌계 중합체
US11912799B2 (en) 2018-09-28 2024-02-27 Dow Global Technologies Llc Tetra-functional long-chain branched ethylene-based polymers
WO2020069364A1 (en) 2018-09-28 2020-04-02 Dow Global Technologies Llc Tetra-functional long-chain branched ethylene-based polymers
CN111408410B (zh) * 2019-01-04 2023-03-24 中国石油化工股份有限公司 一种催化剂组合物、其制备方法及其在乙烯选择性二聚化合成1-丁烯的反应中的应用
JP2022528489A (ja) 2019-03-29 2022-06-13 ダウ グローバル テクノロジーズ エルエルシー 三官能性長鎖分岐ポリオレフィン
EP3947482A1 (de) 2019-03-29 2022-02-09 Dow Global Technologies LLC Verfahren zur polymerisierung von trifunktionalem langkettigem verzweigtem olefin
KR20210148207A (ko) 2019-03-29 2021-12-07 다우 글로벌 테크놀로지스 엘엘씨 삼작용성 장쇄 분지형 올레핀의 중합 방법

Family Cites Families (100)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US204017A (en) 1878-05-21 Improvement in cartridge-packages
US142912A (en) 1873-09-16 Improvement in machines for turning wheels
US3397183A (en) * 1963-04-30 1968-08-13 Dai Cellu Kabushiki Kaisha Method for producing crystalline aldehyde copolymers
US4224182A (en) * 1979-03-07 1980-09-23 Exxon Research & Engineering Co. Novel hindered alkyl aluminum amide cocatalysts
PL276385A1 (en) 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5153157A (en) 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
DE3726067A1 (de) * 1987-08-06 1989-02-16 Hoechst Ag Verfahren zur herstellung von 1-olefinpolymeren
NZ235032A (en) 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
JP2545006B2 (ja) 1990-07-03 1996-10-16 ザ ダウ ケミカル カンパニー 付加重合触媒
US5189192A (en) 1991-01-16 1993-02-23 The Dow Chemical Company Process for preparing addition polymerization catalysts via metal center oxidation
US5721185A (en) 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5519098A (en) * 1991-10-03 1996-05-21 Novacor Chemicals (International) Sa Activation of catalyst in ethylene polymerization at high temperatures
KR100262023B1 (ko) 1992-01-06 2000-07-15 그레이스 스티븐 에스. 개선된 촉매 조성물
US5374696A (en) 1992-03-26 1994-12-20 The Dow Chemical Company Addition polymerization process using stabilized reduced metal catalysts
US5296433A (en) 1992-04-14 1994-03-22 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
US5350723A (en) 1992-05-15 1994-09-27 The Dow Chemical Company Process for preparation of monocyclopentadienyl metal complex compounds and method of use
BE1005957A5 (fr) 1992-06-05 1994-04-05 Solvay Procede de preparation d'un systeme catalytique, procede de (co)polymerisation d'olefines et (co)polymeres d'au moins une olefine.
CA2146012A1 (en) 1992-10-02 1994-04-14 Brian W. S. Kolthammer Supported homogenous catalyst complexes for olefin polymerization
TW298593B (de) 1993-02-12 1997-02-21 Hoechst Ag
BE1007148A3 (fr) 1993-05-17 1995-04-11 Solvay Support pour catalyseurs, procede pour la fabrication d'un gel precurseur d'un support pour catalyseurs, procede de preparation d'un support pour catalyseurs, catalyseur pour la polymerisation d'olefines et procede pour la polymerisation d'olefines au moyen de ce catalyseur.
US5470993A (en) 1993-06-24 1995-11-28 The Dow Chemical Company Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom
US5372682A (en) 1993-06-24 1994-12-13 The Dow Chemical Company Electrochemical preparation of addition polymerization catalysts
BE1007614A3 (nl) * 1993-10-11 1995-08-22 Dsm Nv Werkwijze voor de polymerisatie van een olefine in aanwezigheid van een katalysator gevormd uit halogeenmetalloceen.
WO1995014044A1 (en) 1993-11-19 1995-05-26 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
JPH07144455A (ja) 1993-11-25 1995-06-06 Canon Inc インクジェット記録装置
US5486632A (en) 1994-06-28 1996-01-23 The Dow Chemical Company Group 4 metal diene complexes and addition polymerization catalysts therefrom
US5527929A (en) 1994-08-02 1996-06-18 The Dow Chemical Company Zwitterionic biscyclopentadienyl complexes
US5495036A (en) 1994-09-12 1996-02-27 The Dow Chemical Company Metal (III) complexes containing conjugated, non-aromatic anionic II-bound groups and addition polymerization catalysts therefrom
US5625087A (en) 1994-09-12 1997-04-29 The Dow Chemical Company Silylium cationic polymerization activators for metallocene complexes
US6030917A (en) 1996-07-23 2000-02-29 Symyx Technologies, Inc. Combinatorial synthesis and analysis of organometallic compounds and catalysts
US6045671A (en) 1994-10-18 2000-04-04 Symyx Technologies, Inc. Systems and methods for the combinatorial synthesis of novel materials
US5985356A (en) 1994-10-18 1999-11-16 The Regents Of The University Of California Combinatorial synthesis of novel materials
US6004617A (en) 1994-10-18 1999-12-21 The Regents Of The University Of California Combinatorial synthesis of novel materials
US5712171A (en) 1995-01-20 1998-01-27 Arqule, Inc. Method of generating a plurality of chemical compounds in a spatially arranged array
US5721183A (en) 1995-03-10 1998-02-24 The Dow Chemical Company Catalyst system comprising amine or phosphine adducts of tris(organyl)borane compounds
US5869723A (en) 1995-06-08 1999-02-09 Showa Denko K.K. Ionic compound and olefin polymerization catalyst containing the same
US5854362A (en) 1995-12-11 1998-12-29 The Dow Chemical Company Supported biscyclopentadienyl metal complexes
DE69611386T2 (de) 1996-01-26 2001-08-09 Dow Chemical Co Katalysatorzusammensetzung für die additionspolymerisation von olefinen
JPH09255710A (ja) * 1996-03-27 1997-09-30 Mitsui Petrochem Ind Ltd オレフィン重合用触媒およびオレフィンの重合方法
WO1997035867A1 (en) 1996-03-27 1997-10-02 The Dow Chemical Company Heterocyclic metal complexes and olefin polymerization process
BR9708232A (pt) 1996-03-27 1999-08-03 Dow Chemical Co Ativador de catalisador sistema de catalisador para polimerização de alfa-olefinas e processo de polimerização
BR9708243A (pt) 1996-03-27 1999-07-27 Dow Chemical Co Complexo metalico coposiçÃo catalisadora sistema catalisador suportado e processo para polimerizar uma olefina
CN1214698A (zh) 1996-03-27 1999-04-21 陶氏化学公司 采用分散的催化剂活化剂进行的溶液聚合方法
AU718884B2 (en) * 1996-06-17 2000-04-20 Exxon Chemical Patents Inc. Mixed transition metal catalyst systems for olefin polymerization
BR9710518A (pt) 1996-07-22 1999-08-17 Dow Chemical Co Complexo de metal composi-Æo de catalisador e processo de polimeriza-Æo
ES2177995T3 (es) * 1996-07-23 2002-12-16 Dow Chemical Co Composicion catalitica para la polimerizacion de olefinas que comprende un compuesto del grupo 13.
ATE210620T1 (de) 1996-07-23 2001-12-15 Symyx Technologies Inc Kombinatorische synthese and analyse von metallorganischen verbindungen und katalysatoren
ATE276263T1 (de) 1996-08-08 2004-10-15 Dow Global Technologies Inc Metallkomplexe enthaltend ein an position 3 substituierte cyclopentadienylgruppe und ein olefinpolymerisationsverfahren
US5854166A (en) 1996-08-19 1998-12-29 Northwestern University Synthesis and use of (perfluoroaryl) fluoro-aluminate anion
EP0927201B1 (de) 1996-09-06 2004-04-14 Hyundai Petrochemical Co., Ltd. Katalysatorsystem für die (co)polymerisierung von olefinen und verfahren zur herstellung von olefin-(co)polymeren unter verwendung des katalysatorsystems
US6015868A (en) 1996-10-03 2000-01-18 The Dow Chemical Company Substituted indenyl containing metal complexes and olefin polymerization process
DE19641349A1 (de) 1996-10-08 1998-04-09 Willing Gmbh Dr Ing Beleuchtungsanordnung zur visuellen und automatisierten Inspektion von Oberflächenfehlern
CA2267897C (en) 1996-10-09 2005-12-06 Symyx Technologies Infrared spectroscopy and imaging of libraries
US5783512A (en) 1996-12-18 1998-07-21 The Dow Chemical Company Catalyst component dispersion comprising an ionic compound and solid addition polymerization catalysts containing the same
US5965756A (en) 1996-12-19 1999-10-12 The Dow Chemical Company Fused ring substituted indenyl metal complexes and polymerization process
JP2001506260A (ja) 1996-12-19 2001-05-15 ザ ダウ ケミカル カンパニー ３―アリール置換インデニル含有金属錯体及び重合方法
CN1074771C (zh) * 1996-12-30 2001-11-14 中国科学院长春应用化学研究所 聚合物载体茂金属催化剂的制备
FI970349A (fi) 1997-01-28 1998-07-29 Borealis As Uudet metalloseeniyhdisteiden aktivaattorisysteemit
CA2204803C (en) 1997-05-08 2005-11-15 Nova Chemicals Ltd. Process to prepare bridged phosphole-cyclopentadienyl compounds
FR2764524B1 (fr) * 1997-06-17 1999-07-16 Inst Francais Du Petrole Composition catalytique et procede pour l'oligomerisation de l'ethylene, en particulier en butene-1 et/ou hexene-1
US6103657A (en) 1997-07-02 2000-08-15 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers
EP1000093B1 (de) 1997-08-01 2001-12-12 The Dow Chemical Company Zwiterionischer katalysator aktivator
TR200000665T2 (tr) 1997-09-15 2000-09-21 The Dow Chemical Company Çift metalli kompleksler ve bunlardan elde edilen polimerizasyon katalizatörler.
US6150297A (en) 1997-09-15 2000-11-21 The Dow Chemical Company Cyclopentaphenanthrenyl metal complexes and polymerization process
CN1270595A (zh) 1997-09-19 2000-10-18 陶氏化学公司 改性铝氧烷催化剂活化剂
US6696379B1 (en) 1997-09-19 2004-02-24 The Dow Chemical Company Supported modified alumoxane catalyst activator
DE19744102A1 (de) 1997-10-06 1999-04-15 Targor Gmbh Katalysatorsystem
JP4722287B2 (ja) 1998-02-20 2011-07-13 ダウ グローバル テクノロジーズ インコーポレーテッド 拡大したアニオンを含む触媒活性化剤
AR015731A1 (es) 1998-03-11 2001-05-16 Dow Global Technologies Inc Procedimiento para preparar complejos de metales de formula (l-a-l)md o de los aductos de las bases de lewis de los mismos; complejos de metales de formulamx2d o bases de lewis de los mismos, de aplicacion de dicho procedimiento, y procedimiento para preparar los complejos de dichos compuestos mx2d.
CA2337380C (en) 1998-08-11 2010-11-09 The Dow Chemical Company Catalyst activator composition
US6140521A (en) 1998-08-11 2000-10-31 The Dow Chemical Company Ansa group 4 metal bis (μ-substituted) aluminum complexes
DE69902179T2 (de) 1998-08-17 2003-03-13 Dow Chemical Co Aluminiumverbindungsmischung-enthaltende aktivatorzusammensetzung
ATE233772T1 (de) * 1998-08-17 2003-03-15 Dow Global Technologies Inc Drei-koordinierte alluminium- katalysatoraktivatorverbindung
HUP0104654A3 (en) 1998-10-08 2003-08-28 Univ Michigan Ann Arbor Bridged metal complexes
US6521793B1 (en) 1998-10-08 2003-02-18 Symyx Technologies, Inc. Catalyst ligands, catalytic metal complexes and processes using same
AU2722700A (en) * 1999-01-08 2000-07-24 Symyx Technologies, Inc. Apparatus and method for combinatorial research for catalysts and polymers
CN1334817A (zh) 1999-02-19 2002-02-06 陶氏化学公司 制备三氟芳基铝醚合物的方法
CA2368111A1 (en) 1999-05-13 2000-11-23 The Dow Chemical Company Di- and tri-heteroatom substituted indenyl metal complexes
US6369176B1 (en) * 1999-08-19 2002-04-09 Dupont Dow Elastomers Llc Process for preparing in a single reactor polymer blends having a broad molecular weight distribution
CN1409729A (zh) 1999-12-10 2003-04-09 陶氏环球技术公司 取代的第4族金属配合物,催化剂和烯烃聚合方法
US6825295B2 (en) 1999-12-10 2004-11-30 Dow Global Technologies Inc. Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process
US6627571B1 (en) 2000-03-01 2003-09-30 Symyx Technologies, Inc. Method and system for the situ synthesis of a combinatorial library of supported catalyst materials
JP2001288207A (ja) * 2000-04-07 2001-10-16 Idemitsu Petrochem Co Ltd α−オレフィン−芳香族ビニル化合物系共重合体の製造法
EP1211264A4 (de) * 2000-04-13 2005-03-09 Idemitsu Kosan Co Verfahren zur herstellung von alpha-olefin/aromatischem vinyl-copolymer
DE60138708D1 (de) 2000-06-30 2009-06-25 Dow Global Technologies Inc Polyzyklische, kondensierte ringverbindungen, meta
WO2002046249A2 (en) 2000-11-07 2002-06-13 Symyx Technologies, Inc. Methods of copolymerizing ethylene and isobutylene and polymers made thereby
MY137183A (en) * 2001-03-16 2009-01-30 Dow Global Technologies Inc Method of making interpolymers and products made therefrom
US6825147B2 (en) 2001-05-14 2004-11-30 Dow Global Technologies Inc. 3-aryl-substituted cyclopentadienyl metal complexes and polymerization process
WO2003010171A1 (en) 2001-07-23 2003-02-06 Dow Global Technologies, Inc. Salt of lewis acid/acid adducts and catalyst activators therefrom
JP2003128720A (ja) * 2001-10-19 2003-05-08 Sunallomer Ltd オレフィン重合用固体助触媒成分、オレフィン重合用触媒およびイオン含有化合物
US6960635B2 (en) 2001-11-06 2005-11-01 Dow Global Technologies Inc. Isotactic propylene copolymers, their preparation and use
DE10206988A1 (de) * 2002-02-19 2003-08-21 Basf Ag Verfahren mit hohem Probendurchsatz zur Bestimmung der Qualität von Polymerisationskatalysatoren
WO2003078483A1 (en) 2002-03-14 2003-09-25 Dow Global Technologies Inc. Substituted indenyl metal complexes and polymerization process
AU2003216477A1 (en) 2002-03-14 2003-09-29 Dow Global Technologies Inc. Polycyclic, fused heteroring compounds, metal complexes and polymerization process
JP2004035767A (ja) * 2002-07-04 2004-02-05 Asahi Kasei Chemicals Corp オレフィン重合用触媒及び該触媒を用いた重合方法
JP4273078B2 (ja) * 2002-09-17 2009-06-03 バーゼル・ポリオレフィン・ゲーエムベーハー 重合触媒の選択とこれを行なうための装置
US6953764B2 (en) * 2003-05-02 2005-10-11 Dow Global Technologies Inc. High activity olefin polymerization catalyst and process
US7205363B2 (en) * 2003-06-11 2007-04-17 Exxon Mobil Chemical Patents Inc. Polymerization processes using antistatic agents
EP1763542B1 (de) * 2004-06-16 2011-04-06 Dow Global Technologies Inc. Verfahren zur auswahl von polymerisationsmodifikatoren

Also Published As

Publication number Publication date
EP2345677A2 (de) 2011-07-20
US7943546B2 (en) 2011-05-17
WO2006007094A3 (en) 2006-05-04
US20070219327A1 (en) 2007-09-20
WO2006007094A2 (en) 2006-01-19
DE602005027351D1 (de) 2011-05-19
CN102321201A (zh) 2012-01-18
EP2345677A3 (de) 2014-04-16
JP2014077145A (ja) 2014-05-01
CN102321201B (zh) 2013-06-26
JP2008503603A (ja) 2008-02-07
JP5579142B2 (ja) 2014-08-27
TW200617043A (en) 2006-06-01
JP5795789B2 (ja) 2015-10-14
US20110196117A1 (en) 2011-08-11
EP3009459B1 (de) 2017-08-02
EP1763542A2 (de) 2007-03-21
CN104892814A (zh) 2015-09-09
CN1968973B (zh) 2011-08-17
CN103102442A (zh) 2013-05-15
JP5188178B2 (ja) 2013-04-24
US8343886B2 (en) 2013-01-01
US7553917B2 (en) 2009-06-30
EP3009459A1 (de) 2016-04-20
JP2012007178A (ja) 2012-01-12
CN1968973A (zh) 2007-05-23
US20110184135A1 (en) 2011-07-28
US8383542B2 (en) 2013-02-26
CN103102442B (zh) 2016-01-20
CN104892814B (zh) 2017-11-10
EP1763542B1 (de) 2011-04-06
ES2642131T3 (es) 2017-11-15
US20090264605A1 (en) 2009-10-22

Similar Documents

Publication Publication Date Title
ATE504349T1 (de) Verfahren zur auswahl von polymerisationsmodifikatoren
EP0521908B1 (de) Katalysatorsystem mit gesteigertem leistungsvermögen
DE60138481D1 (de) Verfahren zur herstellung eines katalysators für die homo- oder copolymerisation von ethylen
ATE514485T1 (de) Verfahren zur herstellung eines festen olefinpolymerisationskatalysators
DE602006004607D1 (de) Katalysatorsystem zur polymerisation von olefinen
WO2001023448A1 (en) Hydrolytically degradable olefin copolymers
EP0277004A1 (de) Katalysatoren, Verfahren zur Herstellung derselben und Verfahren zu deren Anwendung
BRPI0417550A (pt) composto de metal de transição organometálico, sistema de ligante bisciclopentadienila, sistema catalisador e preparação de poliolefinas
WO2002092649A3 (en) Solution polymerization process
DE602005020294D1 (de) Geträgerter chrompolymerisationskatalysator und verfahren damit
CN103502290B (zh) 烯烃嵌段共聚物
ATE541868T1 (de) Verfahren zur herstellung eines katalysators für die olefinpolymerisation
DE60122581D1 (de) Verfahren zur herstellung eines katalysators für die homo- oder copolymerisation von ethylen
JP2004035623A (ja) 変性ポリプロピレン及びその製造方法
ATE452915T1 (de) Übergangsmetallkatalysatoren zur olefinpolymerisation
DK1485416T3 (da) Haglbestandig laminatacrylglas og fremgangsmåde til fremstilling heraf
ATE470652T1 (de) Verfahren zur aufarbeitung eines flüssigen reaktionsaustrages der kationischen polymerisation von isobuten
TW200738766A (en) Method for producing cyclic olefin-based addition polymer
ATE324389T1 (de) Zweistufen-polymerisationsverfahren
PL373261A1 (en) Process for the preparation of block copolymers
CA2425588A1 (en) A method for preparing a catalyst system and its use in a polymerization process
ATE469927T1 (de) Verfahren zur herstellung von polyolefinen mit kontrollierter morphologie
DE602004016198D1 (de) Verfahren zur polymerisation von olefinen
ATE356103T1 (de) Verfahren zur herstellung von oligomeren
ATE310021T1 (de) Verfahren zur herstellung hochreaktiver polyisobutene

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties