ES2177995T3 - Composicion catalitica para la polimerizacion de olefinas que comprende un compuesto del grupo 13. - Google Patents
Composicion catalitica para la polimerizacion de olefinas que comprende un compuesto del grupo 13.Info
- Publication number
- ES2177995T3 ES2177995T3 ES97935016T ES97935016T ES2177995T3 ES 2177995 T3 ES2177995 T3 ES 2177995T3 ES 97935016 T ES97935016 T ES 97935016T ES 97935016 T ES97935016 T ES 97935016T ES 2177995 T3 ES2177995 T3 ES 2177995T3
- Authority
- ES
- Spain
- Prior art keywords
- group
- silyl
- substituted
- olefins
- polymerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title abstract 3
- 230000003197 catalytic effect Effects 0.000 title abstract 2
- 239000002131 composite material Substances 0.000 title abstract 2
- 150000001336 alkenes Chemical class 0.000 title 1
- 238000006116 polymerization reaction Methods 0.000 title 1
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 abstract 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 150000004696 coordination complex Chemical class 0.000 abstract 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002736 metal compounds Chemical class 0.000 abstract 1
- 239000002574 poison Substances 0.000 abstract 1
- 231100000614 poison Toxicity 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/46—Titanium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/48—Zirconium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/49—Hafnium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
COMPOSICIONES CATALIZADORAS QUE SON MUY TOLERANTES A VENENOS CATALIZADORES QUE COMPRENDEN UN DERIVADO CATALITICO DE UN COMPLEJO METALICO DEL GRUPO 4 Y UN COMPUESTO METALICO DEL GRUPO 13, DE ACUERDO CON LA FORMULA R 12 ME(NR 22 ), EN DONDE R 1 Y R 2 SON CADA UNO INDEPENDIENTEMENTE, EN ESTE CASO, UN GRUPO HIDROCARBILO, SILILO, HALOCARBILO, HALOHIDROCARBILO, SILILO HIDROCARBIL - SUSTITUIDO, SILILO HALOCARBIL SUSTITUIDO O SILILO HALOHIDROCARBIL - SUSTITUIDO, TENIENDO DICHOS R 1 Y R 2 DE 1 A 30 ATOMOS DE CARBONO, SILICIO O MEZCLAS DE CARBONO Y ATOMOS DE SILICIO Y M ES UN METAL DEL GRUPO 13, SIENDO LA RELACION MOLAR ENTRE EL COMPLEJO Y EL COMPUESTO DEL GRUPO 13 DE 1:0,1 A 1:100.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US2206196P | 1996-07-23 | 1996-07-23 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2177995T3 true ES2177995T3 (es) | 2002-12-16 |
Family
ID=21807620
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES97935016T Expired - Lifetime ES2177995T3 (es) | 1996-07-23 | 1997-07-18 | Composicion catalitica para la polimerizacion de olefinas que comprende un compuesto del grupo 13. |
Country Status (17)
Country | Link |
---|---|
US (1) | US6017842A (es) |
EP (1) | EP0914353B1 (es) |
JP (1) | JP2000514858A (es) |
KR (1) | KR100466733B1 (es) |
CN (1) | CN1092668C (es) |
AR (1) | AR010516A1 (es) |
AU (1) | AU718544B2 (es) |
BR (1) | BR9710511A (es) |
CA (1) | CA2261174C (es) |
CZ (1) | CZ293472B6 (es) |
DE (1) | DE69715213T2 (es) |
ES (1) | ES2177995T3 (es) |
HU (1) | HU223376B1 (es) |
PL (1) | PL331324A1 (es) |
TR (1) | TR199900080T2 (es) |
TW (1) | TW434271B (es) |
WO (1) | WO1998003558A1 (es) |
Families Citing this family (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6294625B1 (en) * | 1990-03-20 | 2001-09-25 | Exxonmobil Chemical Patents Inc. | Catalyst system of enhanced productivity and its use in polymerization process |
KR100422025B1 (ko) * | 1997-12-01 | 2004-03-10 | 아사히 가세이 가부시키가이샤 | 올레핀 중합용 촉매 및 상기 촉매를 사용한 올레핀의 중합방법 |
CA2330529A1 (en) | 1998-06-12 | 1999-12-16 | Univation Technologies Llc | Olefin polymerization process using activated lewis acid-base complexes |
AU743367B2 (en) | 1998-07-16 | 2002-01-24 | Univation Technologies Llc | Aluminum-based lewis acid cocatalysts for olefin polymerization |
JP4357747B2 (ja) | 1998-08-17 | 2009-11-04 | ダウ グローバル テクノロジーズ インコーポレーテッド | アルミニウム化合物混合物を含む活性剤組成物 |
DE69905728T2 (de) * | 1998-08-17 | 2003-12-24 | Dow Global Technologies Inc | Drei-koordinierte alluminium-katalysatoraktivatorverbindung |
US6559088B1 (en) * | 1999-02-22 | 2003-05-06 | Fina Technology, Inc. | Ziegler-Natta catalyst with amine for polymerization |
BE1012568A3 (fr) * | 1999-03-24 | 2000-12-05 | Solvay | Procede pour la polymerisation des alphaolefines. |
US6476164B1 (en) | 1999-10-22 | 2002-11-05 | Exxonmobil Chemical Patents Inc. | Carbenium cationic complexes suitable for polymerization catalysts |
US6475946B1 (en) | 1999-10-22 | 2002-11-05 | Exxonmobil Chemical Patents Inc. | Olefin polymerization catalysis with aryl substituted carbenium cationic complexes |
JP2004500359A (ja) * | 1999-12-09 | 2004-01-08 | エクソンモービル・ケミカル・パテンツ・インク | 15族化合物から誘導されるオレフィン重合助触媒及びその使用法 |
US6489480B2 (en) | 1999-12-09 | 2002-12-03 | Exxonmobil Chemical Patents Inc. | Group-15 cationic compounds for olefin polymerization catalysts |
US6822057B2 (en) | 1999-12-09 | 2004-11-23 | Exxon Mobil Chemical Patents Inc. | Olefin polymerization catalysts derived from Group-15 cationic compounds and processes using them |
MXPA02006197A (es) | 1999-12-20 | 2002-12-09 | Exxon Chemical Patents Inc | Procesos para la preparacion de resinas de poliolefinas usando catalizadores ionicos soportados. |
JP2002293818A (ja) * | 2001-03-30 | 2002-10-09 | Sumitomo Chem Co Ltd | オレフィン重合用触媒、およびオレフィン重合体の製造方法 |
US7541402B2 (en) * | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
CA2499951C (en) * | 2002-10-15 | 2013-05-28 | Peijun Jiang | Multiple catalyst system for olefin polymerization and polymers produced therefrom |
US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
CA2506144C (en) * | 2002-12-13 | 2011-09-20 | Dow Global Technologies Inc. | Olefin polymerization catalyst composition comprising group 13 amide derivatives |
CN103102442B (zh) * | 2004-06-16 | 2016-01-20 | 陶氏环球技术有限责任公司 | 选择聚合改性剂的方法 |
KR101084677B1 (ko) * | 2008-05-14 | 2011-11-22 | 주식회사 엘지화학 | 올레핀 중합체의 제조방법 |
CN104677777B (zh) * | 2013-11-29 | 2017-10-27 | 中国石油化工股份有限公司 | 岩石残余含气量测试装置及其测试方法 |
WO2016180539A1 (en) * | 2015-05-13 | 2016-11-17 | Sasol Performance Chemicals Gmbh | PROCESS FOR THE MANUFACTURE OF A ZIRCONIUM GUANIDINATO ALKYL COMPOUND AND A DI-μ-HALOGEN-BRIDGED BIS GUANIDINATO TETRAHALOGEN DI ZIRCONIUM COMPOUND |
KR20240052979A (ko) * | 2021-09-10 | 2024-04-23 | 다우 글로벌 테크놀로지스 엘엘씨 | 폴리올레핀 생산용 보레이트 공촉매 |
KR20240052978A (ko) * | 2021-09-10 | 2024-04-23 | 다우 글로벌 테크놀로지스 엘엘씨 | 올레핀 중합용 탄화수소 가용성 보레이트 공촉매 |
Family Cites Families (30)
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US3311604A (en) * | 1961-02-04 | 1967-03-28 | Snam Spa | Process for polymerizing isoprene with a catalyst consisting of titanium tetrachloride and an aluminum hydride |
US3255169A (en) * | 1961-05-03 | 1966-06-07 | Exxon Research Engineering Co | Aluminum hydroaminate activators in olefin polymerization |
US3624118A (en) * | 1961-08-09 | 1971-11-30 | Olin Mathieson | Reaction products of alkali metal amides and trialkyl aluminum compounds |
NL126040C (es) * | 1963-05-24 | |||
NL129055C (es) * | 1965-02-03 | 1900-01-01 | ||
NL125866C (es) * | 1965-02-03 | |||
NL129054C (es) * | 1965-02-03 | |||
NL125867C (es) * | 1965-02-03 | |||
US3489736A (en) * | 1965-04-23 | 1970-01-13 | Showa Denko Kk | Polymerization of olefins |
US3723348A (en) * | 1967-03-20 | 1973-03-27 | Du Pont | Coordination catalyst |
BE759186A (fr) * | 1969-11-26 | 1971-05-21 | Inst Francais Du Petrole | Nouveaux catalyseurs de deshydrogenation des alcools secondaires |
DE2110195C3 (de) * | 1970-03-11 | 1975-07-31 | Snam Progetti S.P.A., Mailand (Italien) | Aluminiumverbindung, Verfahren zu ihrer Herstellung und ihre Verwendung bei der Polymerisation von Olefinen, konjugierten oder nicht-konjugierten Dienen oder Gemischen davon |
IT953411B (it) * | 1972-02-15 | 1973-08-10 | Snam Progetti | Produzione di lubrificanti sinteti ci da alfa olefine con un sistema catalitico ternario |
US4094818A (en) * | 1977-02-11 | 1978-06-13 | Exxon Research & Engineering Co. | Ziegler type catalyst system |
US4224182A (en) * | 1979-03-07 | 1980-09-23 | Exxon Research & Engineering Co. | Novel hindered alkyl aluminum amide cocatalysts |
US5096867A (en) * | 1990-06-04 | 1992-03-17 | Exxon Chemical Patents Inc. | Monocyclopentadienyl transition metal olefin polymerization catalysts |
US5055438A (en) * | 1989-09-13 | 1991-10-08 | Exxon Chemical Patents, Inc. | Olefin polymerization catalysts |
NZ235032A (en) * | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
US5057475A (en) * | 1989-09-13 | 1991-10-15 | Exxon Chemical Patents Inc. | Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization |
US5064802A (en) * | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
BE1003968A3 (fr) * | 1990-11-08 | 1992-07-28 | Solvay | Solide catalytique utilisable pour la polymerisation stereospecifique des alpha-olefines, procede pour le preparer et procede pour polymeriser des alpha-olefines en sa presence |
JP3275211B2 (ja) * | 1991-05-20 | 2002-04-15 | ザ ダウ ケミカル カンパニー | 付加重合触媒の製造方法 |
US5721185A (en) * | 1991-06-24 | 1998-02-24 | The Dow Chemical Company | Homogeneous olefin polymerization catalyst by abstraction with lewis acids |
ES2165562T3 (es) * | 1992-01-06 | 2002-03-16 | Dow Chemical Co | Composicion catalitica mejorada. |
US5374696A (en) * | 1992-03-26 | 1994-12-20 | The Dow Chemical Company | Addition polymerization process using stabilized reduced metal catalysts |
US5296433A (en) * | 1992-04-14 | 1994-03-22 | Minnesota Mining And Manufacturing Company | Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom |
US6313240B1 (en) * | 1993-02-22 | 2001-11-06 | Tosoh Corporation | Process for producing ethylene/α-olefin copolymer |
US5470993A (en) * | 1993-06-24 | 1995-11-28 | The Dow Chemical Company | Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom |
US5539069A (en) * | 1993-08-10 | 1996-07-23 | Mitsui Petrochemical Industries, Ltd. | Olefin polymerization catalysts and methods of olefin polymerization |
US5486632A (en) * | 1994-06-28 | 1996-01-23 | The Dow Chemical Company | Group 4 metal diene complexes and addition polymerization catalysts therefrom |
-
1997
- 1997-07-18 ES ES97935016T patent/ES2177995T3/es not_active Expired - Lifetime
- 1997-07-18 WO PCT/US1997/012649 patent/WO1998003558A1/en active IP Right Grant
- 1997-07-18 TR TR1999/00080T patent/TR199900080T2/xx unknown
- 1997-07-18 PL PL97331324A patent/PL331324A1/xx unknown
- 1997-07-18 BR BR9710511A patent/BR9710511A/pt not_active IP Right Cessation
- 1997-07-18 AU AU38051/97A patent/AU718544B2/en not_active Ceased
- 1997-07-18 HU HU9903962A patent/HU223376B1/hu not_active IP Right Cessation
- 1997-07-18 KR KR10-1999-7000417A patent/KR100466733B1/ko not_active IP Right Cessation
- 1997-07-18 CZ CZ1999239A patent/CZ293472B6/cs not_active IP Right Cessation
- 1997-07-18 EP EP97935016A patent/EP0914353B1/en not_active Expired - Lifetime
- 1997-07-18 JP JP10506330A patent/JP2000514858A/ja not_active Ceased
- 1997-07-18 CN CN97196607A patent/CN1092668C/zh not_active Expired - Fee Related
- 1997-07-18 US US08/896,897 patent/US6017842A/en not_active Expired - Lifetime
- 1997-07-18 DE DE69715213T patent/DE69715213T2/de not_active Expired - Lifetime
- 1997-07-18 CA CA002261174A patent/CA2261174C/en not_active Expired - Fee Related
- 1997-09-27 TW TW086114148A patent/TW434271B/zh not_active IP Right Cessation
- 1997-10-08 AR ARP970104647A patent/AR010516A1/es unknown
Also Published As
Publication number | Publication date |
---|---|
HU223376B1 (hu) | 2004-06-28 |
BR9710511A (pt) | 1999-08-17 |
CZ23999A3 (cs) | 1999-04-14 |
AU718544B2 (en) | 2000-04-13 |
PL331324A1 (en) | 1999-07-05 |
CN1092668C (zh) | 2002-10-16 |
TW434271B (en) | 2001-05-16 |
JP2000514858A (ja) | 2000-11-07 |
CN1225644A (zh) | 1999-08-11 |
CZ293472B6 (cs) | 2004-05-12 |
EP0914353A1 (en) | 1999-05-12 |
US6017842A (en) | 2000-01-25 |
EP0914353B1 (en) | 2002-09-04 |
TR199900080T2 (xx) | 1999-04-21 |
KR100466733B1 (ko) | 2005-01-24 |
CA2261174C (en) | 2005-11-29 |
AU3805197A (en) | 1998-02-10 |
KR20000067938A (ko) | 2000-11-25 |
WO1998003558A1 (en) | 1998-01-29 |
DE69715213D1 (de) | 2002-10-10 |
CA2261174A1 (en) | 1998-01-29 |
DE69715213T2 (de) | 2003-04-30 |
AR010516A1 (es) | 2000-06-28 |
HUP9903962A2 (hu) | 2000-03-28 |
HUP9903962A3 (en) | 2000-06-28 |
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