ES2153136T3 - Composicion mejorada de catalizador de polimerizacion de adicion de olefinas. - Google Patents
Composicion mejorada de catalizador de polimerizacion de adicion de olefinas.Info
- Publication number
- ES2153136T3 ES2153136T3 ES96945608T ES96945608T ES2153136T3 ES 2153136 T3 ES2153136 T3 ES 2153136T3 ES 96945608 T ES96945608 T ES 96945608T ES 96945608 T ES96945608 T ES 96945608T ES 2153136 T3 ES2153136 T3 ES 2153136T3
- Authority
- ES
- Spain
- Prior art keywords
- polymerization catalyst
- addition polymerization
- improved composition
- olefin addition
- complex
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/146—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of boron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/1608—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes the ligands containing silicon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/46—Titanium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Abstract
LA INVENCION SE REFIERE A COMPOSICIONES CATALIZADORAS QUE SON ALTAMENTE TOLERANTES A LOS VENENOS DE CATALIZADORES QUE COMPRENDEN UN COMPLEJO CATIONICO O ZWITERIONICO DE UN METAL DEL GRUPO 4, DE GEOMETRIA CONSTREÑIDA Y UN COMPUESTO DE HIDROCARBILOXIDO DE ORGANOALUMINIO, REPRESENTADO POR LA FORMULA R 1 2 AL(OR 2 ), DONDE R 1 Y R 2 CADA UNO INDEPENDIENTEMENTE SON HIDROCARBILO C 1-30 , ESTANDO COMPRENDIDA LA RELACION MOLAR DEL COMPLEJO AL COMPUESTO DE HIDROCARBILOXIDO DE ORGANOALUMINIO, ENTRE 1:0,1 Y 1:100.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US1076896P | 1996-01-26 | 1996-01-26 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2153136T3 true ES2153136T3 (es) | 2001-02-16 |
Family
ID=21747320
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES96945608T Expired - Lifetime ES2153136T3 (es) | 1996-01-26 | 1996-12-18 | Composicion mejorada de catalizador de polimerizacion de adicion de olefinas. |
Country Status (8)
Country | Link |
---|---|
US (1) | US6074977A (es) |
EP (1) | EP0876407B1 (es) |
AU (1) | AU1685597A (es) |
DE (1) | DE69611386T2 (es) |
ES (1) | ES2153136T3 (es) |
IL (1) | IL120065A0 (es) |
WO (1) | WO1997027228A1 (es) |
ZA (1) | ZA97566B (es) |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002519497A (ja) | 1998-07-01 | 2002-07-02 | エクソンモービル・ケミカル・パテンツ・インク | 結晶性プロピレンポリマーと結晶化可能プロピレンポリマーとを含んでなる弾性ブレンド |
JP2002520452A (ja) * | 1998-07-16 | 2002-07-09 | ユニベーション・テクノロジーズ・エルエルシー | オレフィン重合用のアルミニウム系ルイス酸助触媒 |
DE69902179T2 (de) | 1998-08-17 | 2003-03-13 | Dow Chemical Co | Aluminiumverbindungsmischung-enthaltende aktivatorzusammensetzung |
JP4435420B2 (ja) * | 1998-08-17 | 2010-03-17 | ダウ グローバル テクノロジーズ インコーポレーテッド | 3配位アルミニウム触媒活性剤組成物 |
US6225427B1 (en) * | 1998-10-15 | 2001-05-01 | Uniroyal Chemical Company, Inc. | Olefin polymerization process employing metallocene catalyst provided by cocatalyst activation of a metallocene procatalyst |
JP5156167B2 (ja) | 2001-04-12 | 2013-03-06 | エクソンモービル・ケミカル・パテンツ・インク | プロピレン−エチレンポリマー及び製造法 |
JP2005508415A (ja) | 2001-11-06 | 2005-03-31 | ダウ グローバル テクノロジーズ インコーポレイティド | アイソタクチックプロピレンコポリマー類、その製法および用途 |
US6960635B2 (en) * | 2001-11-06 | 2005-11-01 | Dow Global Technologies Inc. | Isotactic propylene copolymers, their preparation and use |
US6927256B2 (en) * | 2001-11-06 | 2005-08-09 | Dow Global Technologies Inc. | Crystallization of polypropylene using a semi-crystalline, branched or coupled nucleating agent |
US6943215B2 (en) | 2001-11-06 | 2005-09-13 | Dow Global Technologies Inc. | Impact resistant polymer blends of crystalline polypropylene and partially crystalline, low molecular weight impact modifiers |
US6906160B2 (en) | 2001-11-06 | 2005-06-14 | Dow Global Technologies Inc. | Isotactic propylene copolymer fibers, their preparation and use |
WO2004031250A1 (en) | 2002-10-02 | 2004-04-15 | Dow Global Technologies Inc. | Liquid and gel-like low molecular weight ethylene polymers |
BR0314562B1 (pt) * | 2002-10-17 | 2013-11-19 | Composição polimérica. | |
US7579407B2 (en) * | 2002-11-05 | 2009-08-25 | Dow Global Technologies Inc. | Thermoplastic elastomer compositions |
US7459500B2 (en) * | 2002-11-05 | 2008-12-02 | Dow Global Technologies Inc. | Thermoplastic elastomer compositions |
WO2004055067A1 (en) | 2002-12-13 | 2004-07-01 | Dow Global Technologies Inc. | Olefin polymerization catalyst composition comprising group 13 amide derivatives |
ES2337936T3 (es) | 2003-08-19 | 2010-04-30 | Dow Global Technologies Inc. | Interpolimeros adecuados para usar en colas termoplasticas y procesos para prepararlos. |
CN104892814B (zh) | 2004-06-16 | 2017-11-10 | 陶氏环球技术有限责任公司 | 选择聚合改性剂的方法 |
US8093341B2 (en) * | 2004-10-28 | 2012-01-10 | Dow Global Technologies Llc | Method of controlling a polymerization reactor |
EP1731535A1 (en) * | 2005-06-07 | 2006-12-13 | Saudi Basic Industries Corporation Inc. | Process for polymerization of olefins |
US7919569B2 (en) | 2005-06-07 | 2011-04-05 | Saudi Basic Industries Corporation | Process for the polymerizaion of olefins |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0314797B1 (en) * | 1987-04-20 | 1997-07-02 | Mitsui Petrochemical Industries, Ltd. | Olefin polymerization catalyst and process for polymerizing olefin |
ES2136132T3 (es) * | 1992-10-05 | 1999-11-16 | Exxon Chemical Patents Inc | Procedimiento de polimerizacion que emplea un sistema catalizador con productividad mejorada. |
BE1007614A3 (nl) * | 1993-10-11 | 1995-08-22 | Dsm Nv | Werkwijze voor de polymerisatie van een olefine in aanwezigheid van een katalysator gevormd uit halogeenmetalloceen. |
WO1995014024A1 (fr) * | 1993-11-18 | 1995-05-26 | Idemitsu Kosan Co., Ltd. | Compose de metal de transition, catalyseur de polymerisation d'olefines et procede pour produire un polymere d'olefines en utilisant ce catalyseur |
-
1996
- 1996-12-18 EP EP96945608A patent/EP0876407B1/en not_active Expired - Lifetime
- 1996-12-18 WO PCT/US1996/019968 patent/WO1997027228A1/en active IP Right Grant
- 1996-12-18 ES ES96945608T patent/ES2153136T3/es not_active Expired - Lifetime
- 1996-12-18 DE DE69611386T patent/DE69611386T2/de not_active Expired - Fee Related
- 1996-12-18 US US09/077,403 patent/US6074977A/en not_active Expired - Lifetime
- 1996-12-18 AU AU16855/97A patent/AU1685597A/en not_active Abandoned
-
1997
- 1997-01-23 ZA ZA97566A patent/ZA97566B/xx unknown
- 1997-01-23 IL IL12006597A patent/IL120065A0/xx unknown
Also Published As
Publication number | Publication date |
---|---|
DE69611386D1 (de) | 2001-02-01 |
IL120065A0 (en) | 1997-04-15 |
WO1997027228A1 (en) | 1997-07-31 |
US6074977A (en) | 2000-06-13 |
AU1685597A (en) | 1997-08-20 |
DE69611386T2 (de) | 2001-08-09 |
EP0876407B1 (en) | 2000-12-27 |
EP0876407A1 (en) | 1998-11-11 |
ZA97566B (en) | 1998-07-23 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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