ES2153136T3 - Composicion mejorada de catalizador de polimerizacion de adicion de olefinas. - Google Patents

Composicion mejorada de catalizador de polimerizacion de adicion de olefinas.

Info

Publication number
ES2153136T3
ES2153136T3 ES96945608T ES96945608T ES2153136T3 ES 2153136 T3 ES2153136 T3 ES 2153136T3 ES 96945608 T ES96945608 T ES 96945608T ES 96945608 T ES96945608 T ES 96945608T ES 2153136 T3 ES2153136 T3 ES 2153136T3
Authority
ES
Spain
Prior art keywords
polymerization catalyst
addition polymerization
improved composition
olefin addition
complex
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES96945608T
Other languages
English (en)
Inventor
Robert K Rosen
James C Stevens
John C Tracy
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Application granted granted Critical
Publication of ES2153136T3 publication Critical patent/ES2153136T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/146—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of boron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1608—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes the ligands containing silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)

Abstract

LA INVENCION SE REFIERE A COMPOSICIONES CATALIZADORAS QUE SON ALTAMENTE TOLERANTES A LOS VENENOS DE CATALIZADORES QUE COMPRENDEN UN COMPLEJO CATIONICO O ZWITERIONICO DE UN METAL DEL GRUPO 4, DE GEOMETRIA CONSTREÑIDA Y UN COMPUESTO DE HIDROCARBILOXIDO DE ORGANOALUMINIO, REPRESENTADO POR LA FORMULA R 1 2 AL(OR 2 ), DONDE R 1 Y R 2 CADA UNO INDEPENDIENTEMENTE SON HIDROCARBILO C 1-30 , ESTANDO COMPRENDIDA LA RELACION MOLAR DEL COMPLEJO AL COMPUESTO DE HIDROCARBILOXIDO DE ORGANOALUMINIO, ENTRE 1:0,1 Y 1:100.
ES96945608T 1996-01-26 1996-12-18 Composicion mejorada de catalizador de polimerizacion de adicion de olefinas. Expired - Lifetime ES2153136T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US1076896P 1996-01-26 1996-01-26

Publications (1)

Publication Number Publication Date
ES2153136T3 true ES2153136T3 (es) 2001-02-16

Family

ID=21747320

Family Applications (1)

Application Number Title Priority Date Filing Date
ES96945608T Expired - Lifetime ES2153136T3 (es) 1996-01-26 1996-12-18 Composicion mejorada de catalizador de polimerizacion de adicion de olefinas.

Country Status (8)

Country Link
US (1) US6074977A (es)
EP (1) EP0876407B1 (es)
AU (1) AU1685597A (es)
DE (1) DE69611386T2 (es)
ES (1) ES2153136T3 (es)
IL (1) IL120065A0 (es)
WO (1) WO1997027228A1 (es)
ZA (1) ZA97566B (es)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7232871B2 (en) 1997-08-12 2007-06-19 Exxonmobil Chemical Patents Inc. Propylene ethylene polymers and production process
US6921794B2 (en) 1997-08-12 2005-07-26 Exxonmobil Chemical Patents Inc. Blends made from propylene ethylene polymers
US6635715B1 (en) 1997-08-12 2003-10-21 Sudhin Datta Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers
DE69935815T2 (de) 1998-07-01 2007-12-27 Exxonmobil Chemical Patents Inc., Baytown Elastische Mischung mit Kristallpolymeren und kristallisierbaren Polymeren des Propens
JP2002520452A (ja) * 1998-07-16 2002-07-09 ユニベーション・テクノロジーズ・エルエルシー オレフィン重合用のアルミニウム系ルイス酸助触媒
AU4440399A (en) * 1998-08-17 2000-03-06 Dow Chemical Company, The Three coordinate aluminum catalyst activator composition
ATE220682T1 (de) 1998-08-17 2002-08-15 Dow Chemical Co Aluminiumverbindungsmischung-enthaltende aktivatorzusammensetzung
US6225427B1 (en) * 1998-10-15 2001-05-01 Uniroyal Chemical Company, Inc. Olefin polymerization process employing metallocene catalyst provided by cocatalyst activation of a metallocene procatalyst
JP5156167B2 (ja) 2001-04-12 2013-03-06 エクソンモービル・ケミカル・パテンツ・インク プロピレン−エチレンポリマー及び製造法
US6927256B2 (en) 2001-11-06 2005-08-09 Dow Global Technologies Inc. Crystallization of polypropylene using a semi-crystalline, branched or coupled nucleating agent
US6943215B2 (en) 2001-11-06 2005-09-13 Dow Global Technologies Inc. Impact resistant polymer blends of crystalline polypropylene and partially crystalline, low molecular weight impact modifiers
JP2005508415A (ja) * 2001-11-06 2005-03-31 ダウ グローバル テクノロジーズ インコーポレイティド アイソタクチックプロピレンコポリマー類、その製法および用途
US6906160B2 (en) * 2001-11-06 2005-06-14 Dow Global Technologies Inc. Isotactic propylene copolymer fibers, their preparation and use
US6960635B2 (en) * 2001-11-06 2005-11-01 Dow Global Technologies Inc. Isotactic propylene copolymers, their preparation and use
AU2003299143A1 (en) * 2002-10-02 2004-04-23 Dow Global Technologies Inc. Liquid and gel-like low molecular weight ethylene polymers
EP1554343B1 (en) * 2002-10-17 2008-07-23 Dow Global Technologies Inc. Highly filled polymer compositions
US7459500B2 (en) * 2002-11-05 2008-12-02 Dow Global Technologies Inc. Thermoplastic elastomer compositions
US7579407B2 (en) * 2002-11-05 2009-08-25 Dow Global Technologies Inc. Thermoplastic elastomer compositions
ATE472562T1 (de) * 2002-12-13 2010-07-15 Dow Global Technologies Inc Olefinpolymerisationskatalysatorzusammensetzung gruppe 13-amid derivate enthaltend
CN101831022B (zh) 2003-08-19 2012-07-04 陶氏环球技术有限责任公司 适用于热熔粘合剂的共聚体及其制备方法
CN104892814B (zh) * 2004-06-16 2017-11-10 陶氏环球技术有限责任公司 选择聚合改性剂的方法
WO2006049857A1 (en) 2004-10-28 2006-05-11 Dow Global Technologies Inc. Method of controlling a polymerization reactor
PL1888653T3 (pl) 2005-06-07 2016-08-31 Saudi Basic Ind Corp Sposób polimeryzacji olefin
EP1731535A1 (en) * 2005-06-07 2006-12-13 Saudi Basic Industries Corporation Inc. Process for polymerization of olefins

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1988008432A1 (fr) * 1987-04-20 1988-11-03 Mitsui Petrochemical Industries, Ltd. Catalyseur et procede de polymerisation d'olefines
DE69325716T2 (de) * 1992-10-05 2000-04-27 Exxon Chemical Patents, Inc. Polymerisationsverfahren mittels eines katalysatorsystems mit gesteigertem leistungsvermögen
BE1007614A3 (nl) * 1993-10-11 1995-08-22 Dsm Nv Werkwijze voor de polymerisatie van een olefine in aanwezigheid van een katalysator gevormd uit halogeenmetalloceen.
JP3795072B2 (ja) * 1993-11-18 2006-07-12 出光興産株式会社 遷移金属化合物，オレフィン重合用触媒，該触媒を用いたオレフィン系重合体の製造方法

Also Published As

Publication number Publication date
US6074977A (en) 2000-06-13
DE69611386T2 (de) 2001-08-09
ZA97566B (en) 1998-07-23
AU1685597A (en) 1997-08-20
EP0876407A1 (en) 1998-11-11
EP0876407B1 (en) 2000-12-27
DE69611386D1 (de) 2001-02-01
WO1997027228A1 (en) 1997-07-31
IL120065A0 (en) 1997-04-15

Similar Documents

Publication Publication Date Title
ES2153136T3 (es) Composicion mejorada de catalizador de polimerizacion de adicion de olefinas.
FR2801887B1 (fr) Complexes metalliques appropries a la catalyse de reactions d'hydrosilylation, composition catalytique les contenant et leur utilisation
AR010516A1 (es) Composiciones catalizadoras para la polimerizacion de olefinas que comprenden compuestos de elementos del grupo 13 y procedimiento de polimerizacion por adicion, de monomeros con la aplicacion de dichos catalizadores.
ES2099758T3 (es) Procedimiento para preparar catalizadores para polimerizacion por adicion mediante oxidacion del nucleo metalico.
ATE424422T1 (de) Dual-site- olefinpolymerisationskatalysatorzusammensetzung
WO2000050470A3 (en) Catalysts containing n-pyrrolyl substituted nitrogen donors
BR0017027A (pt) Método de polimerização
ES2085900T3 (es) Catalizador y procedimiento para la polimerizacion de olefinas.
ES2196493T3 (es) Catalizadores de fosfinimina-ciclopentadianil en ssoporte.
AR011387A1 (es) Una composicion catalitica y un procedimiento para la polimerizacion de una olefina
ES2154664T3 (es) Metalocenos, procedimientos para su obtencion, y su empleo como catalizadores.
DE69004446D1 (de) Katalysator für Olefinpolymerisation.
BR9814295A (pt) Catalisadores de diimina de nìquel com metilalumoxano como co-catalisador, método de polimerização de olefinas com os mesmos e polìmeros produzidos
ES2060781T3 (es) Componente de catalizador para la polimerizacion de olefinas, catalizador para la polimerizacion de olefinas y procedimiento para la polimerizacion de olefinas.
IT1269931B (it) Componenti e catalizzatori per la polimerizzazione di olefine
ZA200804073B (en) Catalytic oligomerization of olefinic monomers
MX9300536A (es) Componente y catalizadores para la polimerazacion de olefinas.
CA2119590A1 (en) Olefin Polymerization Catalyst Having a Multidentate Ligand
HUT56585A (en) Catalyst components and catalysts usable for olefin polymerization
ES2160757T3 (es) Catalizadores para la polimerizacion de alfa-olefinas.
BR0313087A (pt) Derivados de indenila tricìclico substituìdo com 4-arila contendo complexos de metais do grupo 4 e seu uso
BR0016134A (pt) Compostos, catalisador para a polimerização de olefinas e processos a preparação de compostos e de um catalisador e para a polimerização de olefinas
BR0203229A (pt) Catalisadores para a polimerização de olefina
ES2162473T3 (es) Procedimiento para preparar fosfinas ciclicas.
MXPA03003962A (es) Activadores de co-catalizador zwitterionicos, fluorados para polimerizacion de olefinas.

Legal Events

Date Code Title Description
FG2A Definitive protection

Ref document number: 876407

Country of ref document: ES