ATE355308T1 - Lewis-säure cokatalysatoren auf aluminium-basis für die olefinpolymerisation - Google Patents
Lewis-säure cokatalysatoren auf aluminium-basis für die olefinpolymerisationInfo
- Publication number
- ATE355308T1 ATE355308T1 AT99935486T AT99935486T ATE355308T1 AT E355308 T1 ATE355308 T1 AT E355308T1 AT 99935486 T AT99935486 T AT 99935486T AT 99935486 T AT99935486 T AT 99935486T AT E355308 T1 ATE355308 T1 AT E355308T1
- Authority
- AT
- Austria
- Prior art keywords
- olefin polymerization
- lewis acid
- cocatatalyst
- aluminum
- arhal
- Prior art date
Links
- 150000001336 alkenes Chemical class 0.000 title abstract 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title abstract 3
- 238000006116 polymerization reaction Methods 0.000 title abstract 3
- 239000002841 Lewis acid Substances 0.000 title abstract 2
- 150000007517 lewis acids Chemical class 0.000 title 1
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- -1 Lewis acid aluminum compound Chemical class 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 125000002524 organometallic group Chemical group 0.000 abstract 1
- 229920000098 polyolefin Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polymerization Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US9301798P | 1998-07-16 | 1998-07-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE355308T1 true ATE355308T1 (de) | 2006-03-15 |
Family
ID=22236368
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT99935486T ATE355308T1 (de) | 1998-07-16 | 1999-07-09 | Lewis-säure cokatalysatoren auf aluminium-basis für die olefinpolymerisation |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US6147174A (de) |
| EP (1) | EP1097175B1 (de) |
| JP (1) | JP2002520452A (de) |
| AT (1) | ATE355308T1 (de) |
| AU (1) | AU743367B2 (de) |
| BR (1) | BR9912124A (de) |
| CA (1) | CA2330775A1 (de) |
| DE (1) | DE69935332T2 (de) |
| ES (1) | ES2283125T3 (de) |
| WO (1) | WO2000004058A1 (de) |
Families Citing this family (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6130302A (en) * | 1996-08-19 | 2000-10-10 | Northwestern University | Synthesis and use of (polyfluoroaryl)fluoroanions of aluminum, gallium and indium |
| US6262200B1 (en) | 1996-08-19 | 2001-07-17 | Northwestern University | (Polyfluoroaryl)fluoroanions of aluminum, gallium, and indium of enhanced utility, uses thereof, and products based thereon |
| EP1105398B1 (de) * | 1998-08-17 | 2002-07-17 | The Dow Chemical Company | Aluminiumverbindungsmischung-enthaltende aktivatorzusammensetzung |
| US6147173A (en) * | 1998-11-13 | 2000-11-14 | Univation Technologies, Llc | Nitrogen-containing group 13 anionic complexes for olefin polymerization |
| IT1304181B1 (it) * | 1998-12-17 | 2001-03-08 | Enichem Spa | Composizione attivante di complessi metallocenici nella catalisi deiprocessi di (co)polimerizzazione delle olefine. |
| US6294624B1 (en) * | 1999-01-22 | 2001-09-25 | Ube Industries, Ltd. | Modified diene elastomer and its preparation |
| CN1231506C (zh) * | 1999-08-13 | 2005-12-14 | 巴塞尔聚烯烃股份有限公司 | 乙烯与C3-C12α-烯烃的共聚物 |
| US6194527B1 (en) * | 1999-09-22 | 2001-02-27 | Equistar Chemicals, L.P. | Process for making polyolefins |
| US6395847B2 (en) | 1999-11-19 | 2002-05-28 | Exxonmobil Chemical Patents Inc. | Supported organometallic catalysts and their use in olefin polymerization |
| EP1237957B1 (de) * | 1999-11-19 | 2006-08-23 | ExxonMobil Chemical Patents Inc. | Vorbereitung eines geträgerten katalysatorsystems zur polymerisation von olefinen |
| BR0112516A (pt) * | 2000-07-17 | 2003-09-09 | Univation Tech Llc | Sistema catalisador e seu emprego em um processo de polimerização |
| GB0021301D0 (en) | 2000-08-30 | 2000-10-18 | Borealis Tech Oy | Supported catalyst |
| NL1021362C2 (nl) * | 2001-08-31 | 2003-08-05 | Inst Francais Du Petrole | Katalysator- en oplosmiddelsamenstelling en katalysewerkwijzen waarbij deze samenstelling wordt toegepast. |
| US6727331B2 (en) * | 2001-12-28 | 2004-04-27 | Equistar Chemicals, Lp | Preparation of polyethylene |
| US6806328B2 (en) * | 2002-01-28 | 2004-10-19 | Univation Technologies, Llc | Polymerization catalyst activator complexes and their use in a polymerization process |
| ATE380385T1 (de) * | 2002-09-10 | 2007-12-15 | Union Carbide Chem Plastic | Kabelummantelungs-zusammensetzungen aus polypropylen mit verbesserter schmelzstärke und physikalischen eigenschaften |
| US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| ES2394304T3 (es) | 2002-10-15 | 2013-01-30 | Exxonmobil Chemical Patents, Inc. | Sistema de múltiples catalizadores para la polimerización de olefinas y polímeros producidos a partir de éstos |
| US7223822B2 (en) | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
| US7541402B2 (en) | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
| US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| WO2004037871A1 (en) * | 2002-10-24 | 2004-05-06 | Exxonmobil Chemical Patents Inc. | Branched crystalline polypropylene |
| WO2004037872A2 (en) * | 2002-10-24 | 2004-05-06 | Exxonmobil Chemical Patents Inc. | Branched crystalline polypropylene |
| US6900154B2 (en) * | 2002-11-26 | 2005-05-31 | Univation Technologies, Llc | Methods of forming a supported activated catalyst composition |
| WO2004055061A1 (en) * | 2002-12-17 | 2004-07-01 | O & D Trading Limited | Supported olefin polymerization catalyst |
| KR100469470B1 (ko) * | 2003-01-30 | 2005-02-02 | 엘지전자 주식회사 | 열변형을 이용한 댐퍼 및 이를 구비한 세탁기 |
| US7094848B2 (en) | 2003-05-13 | 2006-08-22 | Exxonmobil Chemical Patents Inc. | Olefin polymerization catalyst system |
| US6958306B2 (en) * | 2003-08-28 | 2005-10-25 | Univation Technologies, Llc | Activated catalyst systems from substituted dialuminoxane complexes |
| US6870010B1 (en) | 2003-12-01 | 2005-03-22 | Univation Technologies, Llc | Low haze high strength polyethylene compositions |
| US7288596B2 (en) | 2003-12-22 | 2007-10-30 | Univation Technologies, Llc | Polyethylene compositions having improved tear properties |
| EP1559730A1 (de) * | 2004-01-30 | 2005-08-03 | Total Petrochemicals Research Feluy | Aktivierende Träger zur Metallocenkatalyse |
| JP4951351B2 (ja) * | 2004-01-30 | 2012-06-13 | トータル・ペトロケミカルズ・リサーチ・フエリユイ | メタロセン触媒用の活性化担体 |
| US7193017B2 (en) * | 2004-08-13 | 2007-03-20 | Univation Technologies, Llc | High strength biomodal polyethylene compositions |
| AU2005303610B2 (en) | 2004-11-12 | 2011-07-21 | Ucl Business Plc | Guanidine derivatives as inhibitors of DDAH |
| US7312279B2 (en) * | 2005-02-07 | 2007-12-25 | Univation Technologies, Llc | Polyethylene blend compositions |
| TW200936619A (en) | 2007-11-15 | 2009-09-01 | Univation Tech Llc | Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom |
| CN103917292B (zh) | 2011-11-08 | 2016-11-23 | 尤尼威蒂恩技术有限责任公司 | 制备催化剂体系的方法 |
| KR101924198B1 (ko) | 2015-12-23 | 2018-11-30 | 주식회사 엘지화학 | 필름 가공성 및 투명도가 우수한 저밀도 폴리에틸렌 공중합체 |
| EP3867287B1 (de) | 2018-10-15 | 2025-04-23 | TotalEnergies OneTech Belgium | Polyethylenharze |
Family Cites Families (42)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5153157A (en) * | 1987-01-30 | 1992-10-06 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
| IL85097A (en) * | 1987-01-30 | 1992-02-16 | Exxon Chemical Patents Inc | Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes |
| US5198401A (en) * | 1987-01-30 | 1993-03-30 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
| US5155080A (en) * | 1988-07-15 | 1992-10-13 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
| US5763547A (en) * | 1992-10-02 | 1998-06-09 | The Dow Chemical Company | Supported catalyst complexes for olefin in polymerization |
| US5763549A (en) * | 1989-10-10 | 1998-06-09 | Fina Technology, Inc. | Cationic metallocene catalysts based on organoaluminum anions |
| US5387568A (en) * | 1989-10-30 | 1995-02-07 | Fina Technology, Inc. | Preparation of metallocene catalysts for polymerization of olefins |
| EP0500944B1 (de) * | 1990-07-24 | 1998-10-07 | Mitsui Chemicals, Inc. | Katalysator für alpha-olefinpolymerisation und herstellung von poly(alpha)olefinen damit |
| JP2895199B2 (ja) * | 1990-10-02 | 1999-05-24 | 三井化学株式会社 | オレフィンの重合触媒 |
| US5369196A (en) * | 1990-11-30 | 1994-11-29 | Idemitsu Kosan Co., Ltd. | Production process of olefin based polymers |
| US5721185A (en) * | 1991-06-24 | 1998-02-24 | The Dow Chemical Company | Homogeneous olefin polymerization catalyst by abstraction with lewis acids |
| US5288677A (en) * | 1991-06-28 | 1994-02-22 | Exxon Chemical Patents Inc. | Immobilized Lewis acid catalysts |
| US5710224A (en) * | 1991-07-23 | 1998-01-20 | Phillips Petroleum Company | Method for producing polymer of ethylene |
| EP0614468B1 (de) * | 1991-11-25 | 1997-09-17 | Exxon Chemical Patents Inc. | Polyionische, uebergangsmetall enthaltende katalysatorzusammensetzung |
| EP0574561B1 (de) * | 1992-01-06 | 1998-01-28 | The Dow Chemical Company | Katalysatorzusammensetzung |
| US5374696A (en) * | 1992-03-26 | 1994-12-20 | The Dow Chemical Company | Addition polymerization process using stabilized reduced metal catalysts |
| US5296433A (en) * | 1992-04-14 | 1994-03-22 | Minnesota Mining And Manufacturing Company | Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom |
| US5407882A (en) * | 1992-08-04 | 1995-04-18 | Tosoh Corporation | Olefin polymerization catalyst and olefin polymerization process |
| KR100311244B1 (ko) * | 1993-02-22 | 2001-12-15 | 가지와라 야스시 | 에틸렌/α-올레핀공중합체의제조방법 |
| US6313240B1 (en) * | 1993-02-22 | 2001-11-06 | Tosoh Corporation | Process for producing ethylene/α-olefin copolymer |
| JPH09501707A (ja) * | 1993-08-06 | 1997-02-18 | エクソン・ケミカル・パテンツ・インク | 重合触媒、その製造及び使用 |
| US5498582A (en) * | 1993-12-06 | 1996-03-12 | Mobil Oil Corporation | Supported metallocene catalysts for the production of polyolefins |
| JP3369294B2 (ja) * | 1994-03-11 | 2003-01-20 | 出光興産株式会社 | 遷移金属化合物、それを用いた重合用触媒及び該重合用触媒を用いたスチレン系重合体の製造方法 |
| IT1273701B (it) * | 1994-07-29 | 1997-07-09 | Enichem Elastomers | Derivati metallorganici del grupo iiia e procedimento per la loro preparazione |
| PL318432A1 (en) * | 1994-08-03 | 1997-06-09 | Exxon Chemical Patents Inc | Ionic supported catalyst composition |
| US5643847A (en) * | 1994-08-03 | 1997-07-01 | Exxon Chemical Patents Inc. | Supported ionic catalyst composition |
| US5625087A (en) * | 1994-09-12 | 1997-04-29 | The Dow Chemical Company | Silylium cationic polymerization activators for metallocene complexes |
| ES2116188B1 (es) * | 1994-12-30 | 1999-04-01 | Repsol Quimica Sa | Proceso de obtencion de poliolefinas con distribuciones de pesos moleculares anchas, bimodales o multimodales. |
| US5554775A (en) * | 1995-01-17 | 1996-09-10 | Occidental Chemical Corporation | Borabenzene based olefin polymerization catalysts |
| US5939347A (en) * | 1995-01-25 | 1999-08-17 | W.R. Grace & Co. -Conn. | Supported catalytic activator |
| EP0891991A3 (de) * | 1995-03-01 | 1999-02-24 | Minnesota Mining And Manufacturing Company | Tris(pentafluorphenyl)borat Komplexe und hieraus abgeleitete Katalysatoren |
| US5721183A (en) * | 1995-03-10 | 1998-02-24 | The Dow Chemical Company | Catalyst system comprising amine or phosphine adducts of tris(organyl)borane compounds |
| ES2188751T3 (es) * | 1995-03-10 | 2003-07-01 | Dow Global Technologies Inc | Componente catalitico soportado, catalizador soportado, procedimiento de preparacion, procedimiento de polimerizacion, compuestos complejos, y su preparacion. |
| MX9708182A (es) * | 1995-04-25 | 1998-02-28 | Equistar Chem Lp | Complejos metalicos de azaborolinilo como catalizadores de polimerizacion de olefinas. |
| EP0857179A1 (de) * | 1995-08-18 | 1998-08-12 | Basell Polyolefine GmbH | Katalysatorkomponente und katalysatorsystem mit hoher polymerisationsaktivität zur herstellung von polymeren |
| JP4330176B2 (ja) * | 1995-10-19 | 2009-09-16 | ビーピー・コーポレーション・ノース・アメリカ・インコーポレーテッド | メタロセンを主成分とする高活性均一オレフィン重合系 |
| IT1275812B1 (it) * | 1995-10-27 | 1997-10-17 | Enichem Spa | Sistema catalitico attivato per la (co)polimerizzazione delle alfa-olefine |
| EP0876407B1 (de) * | 1996-01-26 | 2000-12-27 | The Dow Chemical Company | Katalysatorzusammensetzung für die additionspolymerisation von olefinen |
| JPH09309926A (ja) * | 1996-05-17 | 1997-12-02 | Dow Chem Co:The | エチレン共重合体の製造方法 |
| DE69715213T2 (de) * | 1996-07-23 | 2003-04-30 | The Dow Chemical Co., Midland | Olefinpolymerisationkatalysatorzusammensetzung die eine verbindung der gruppe 13 enthält |
| DE59712644D1 (de) | 1996-08-13 | 2006-06-14 | Basell Polyolefine Gmbh | Geträgerte chemische Verbindung |
| US5854166A (en) * | 1996-08-19 | 1998-12-29 | Northwestern University | Synthesis and use of (perfluoroaryl) fluoro-aluminate anion |
-
1999
- 1999-07-09 BR BR9912124-7A patent/BR9912124A/pt not_active Application Discontinuation
- 1999-07-09 EP EP99935486A patent/EP1097175B1/de not_active Expired - Lifetime
- 1999-07-09 AT AT99935486T patent/ATE355308T1/de not_active IP Right Cessation
- 1999-07-09 WO PCT/US1999/015618 patent/WO2000004058A1/en not_active Ceased
- 1999-07-09 DE DE69935332T patent/DE69935332T2/de not_active Expired - Fee Related
- 1999-07-09 CA CA002330775A patent/CA2330775A1/en not_active Abandoned
- 1999-07-09 US US09/350,521 patent/US6147174A/en not_active Expired - Lifetime
- 1999-07-09 JP JP2000560163A patent/JP2002520452A/ja active Pending
- 1999-07-09 AU AU50954/99A patent/AU743367B2/en not_active Ceased
- 1999-07-09 ES ES99935486T patent/ES2283125T3/es not_active Expired - Lifetime
-
2000
- 2000-07-20 US US09/620,687 patent/US6476166B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| AU5095499A (en) | 2000-02-07 |
| EP1097175B1 (de) | 2007-02-28 |
| BR9912124A (pt) | 2001-09-25 |
| CA2330775A1 (en) | 2000-01-27 |
| JP2002520452A (ja) | 2002-07-09 |
| ES2283125T3 (es) | 2007-10-16 |
| DE69935332T2 (de) | 2007-10-31 |
| EP1097175A1 (de) | 2001-05-09 |
| US6476166B1 (en) | 2002-11-05 |
| US6147174A (en) | 2000-11-14 |
| DE69935332D1 (de) | 2007-04-12 |
| WO2000004058A1 (en) | 2000-01-27 |
| AU743367B2 (en) | 2002-01-24 |
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