ES2116188B1 - Proceso de obtencion de poliolefinas con distribuciones de pesos moleculares anchas, bimodales o multimodales. - Google Patents

Proceso de obtencion de poliolefinas con distribuciones de pesos moleculares anchas, bimodales o multimodales.

Info

Publication number
ES2116188B1
ES2116188B1 ES09402690A ES9402690A ES2116188B1 ES 2116188 B1 ES2116188 B1 ES 2116188B1 ES 09402690 A ES09402690 A ES 09402690A ES 9402690 A ES9402690 A ES 9402690A ES 2116188 B1 ES2116188 B1 ES 2116188B1
Authority
ES
Spain
Prior art keywords
bimodal
different
wide
molecular weight
multimodal molecular
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
ES09402690A
Other languages
English (en)
Other versions
ES2116188A1 (es
Inventor
Vega Wilfried Michiels
Lafuente Antoni Munoz-Escalona
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Repsol Quimica SA
Original Assignee
Repsol Quimica SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=8288443&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2116188(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Repsol Quimica SA filed Critical Repsol Quimica SA
Priority to ES09402690A priority Critical patent/ES2116188B1/es
Priority to PT95500174T priority patent/PT719797E/pt
Priority to EP95500174A priority patent/EP0719797B2/en
Priority to DE1995616258 priority patent/DE69516258T3/de
Priority to AT95500174T priority patent/ATE191723T1/de
Priority to NO19955298A priority patent/NO315240B1/no
Priority to FI956289A priority patent/FI956289A7/fi
Priority to US08/580,734 priority patent/US6605676B1/en
Priority to JP00005496A priority patent/JP3292649B2/ja
Publication of ES2116188A1 publication Critical patent/ES2116188A1/es
Publication of ES2116188B1 publication Critical patent/ES2116188B1/es
Application granted granted Critical
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/905—Polymerization in presence of transition metal containing catalyst in presence of hydrogen
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

PROCESO DE OBTENCION DE POLIOLEFINAS CON DISTRIBUCIONES DE PESOS MOLECULARES ANCHAS, BIMODALES O MULTIMODALES. EL PROCEDIMIENTO ESTA CARACTERIZADO POR EL EMPLEO DE SISTEMAS CATALITICOS COMPUESTOS DE UN SOLO CATALIZADOR METALOCENO ACTIVADO CON MEZCLAS DE AL MENOS DOS COCATALIZADORES. LOS COCATALIZADORES SON ALQUILOS DE ALUMINIO, ALUMINOXANOS O COMPUESTOS DE BORO. MEDIANTE EL EMPLEO DE ESTOS SISTEMAS COCATALITICOS MIXTOS SE PRODUCEN DIFERENTES CENTROS ACTIVOS EN EL CATALIZADOR, CADA UNO CON DIFERENTES VELOCIDADES DE INICIACION Y TERMINACION DE LA REACCION DE POLIMERIZACION, LOS CUALES PRODUCEN POLIOLEFINAS CON DIFERENTES PESOS MOLECULARES, DANDO COMO RESULTADO PRODUCTOS CON DISTRIBUCIONES DE PESO MOLECULARES ANCHAS, BIMODALES O MULTIMODALES. LAS DISTRIBUCIONES DE PESO MOLECULARES, Y LA INCORPORACION DE COMONOMERO, SE PUEDE CONTROLAR MEDIANTE LA SELECCION ADECUADA DEL METALOCENO Y EL EMPLEO DE LAS COMBINACIONALES DE LOS DIFERENTES TIPOS DE COCATALIZADORES, ASI COMO VARIANDO LA PRESION DEL REACTOR, LA TEMPERATURA DE LA REACCION Y LAS RELACIONES MOLARES ENTRE LOS DIFERENTES COMPONENTES DEL SISTEMA CATALITICO. LA DISTRIBUCION DE PESOS MOLECULARES ANCHA, BIMODAL O MULTIMODAL SE PUEDE CONSEGUIR TANTO EN AUSENCIA COMO EN PRESENCIA DE HIDROGENO DURANTE LA REACCION DE POLIMERIZACION. DE IGUAL FORMA SE PUEDEN CONSEGUIR DISTRIBUCIONES DE PESOS MOLECULARES ANCHAS, BIMODALES Y MULTIMODALES EN LOS POLIMEROS VARIANDO EL ORDEN DE ADICION DE LOS COMPONENTES DEL SISTEMA CATALITICO. ESTE PROCEDIMIENTO SE PUEDE EMPLEAR TANTO EN EL CASO DE CATALIZADORES METALOCENO HOMOGENEOS COMO HETEROGENEOS. FIG. 1.
ES09402690A 1994-12-30 1994-12-30 Proceso de obtencion de poliolefinas con distribuciones de pesos moleculares anchas, bimodales o multimodales. Expired - Fee Related ES2116188B1 (es)

Priority Applications (9)

Application Number Priority Date Filing Date Title
ES09402690A ES2116188B1 (es) 1994-12-30 1994-12-30 Proceso de obtencion de poliolefinas con distribuciones de pesos moleculares anchas, bimodales o multimodales.
PT95500174T PT719797E (pt) 1994-12-30 1995-12-20 Processo para obter poliolefinas que possuem largas distribuicoes de pesos moleculares bimodais ou multimodais
EP95500174A EP0719797B2 (en) 1994-12-30 1995-12-20 Process for obtaining polyolefins with broad bimodal or multimodal molecular weight distributions
DE1995616258 DE69516258T3 (de) 1994-12-30 1995-12-20 Verfahren zur Gewinnung von Polyolefinen mit breiter bimodularer oder multimodaler Molekulargewichtsverteilung
AT95500174T ATE191723T1 (de) 1994-12-30 1995-12-20 Verfahren zur gewinnung von polyolefinen mit breiter bimodularer oder multimodaler molekulargewichtsverteilung
NO19955298A NO315240B1 (no) 1994-12-30 1995-12-27 Katalysatorsystem og fremgangsmåte til fremstilling av polyolefiner
FI956289A FI956289A7 (fi) 1994-12-30 1995-12-28 Menetelmä laajan bimodaalisen tai multimodaalisen molekyylipainojakauman omaavien polyolefiinien aikaansaamiseksi
US08/580,734 US6605676B1 (en) 1994-12-30 1995-12-28 Process for obtaining polyolefins with broad bimodal or multimodal molecular weight distributions
JP00005496A JP3292649B2 (ja) 1994-12-30 1996-01-04 α−オレフィンの単独重合体又は共重合体の製造方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES09402690A ES2116188B1 (es) 1994-12-30 1994-12-30 Proceso de obtencion de poliolefinas con distribuciones de pesos moleculares anchas, bimodales o multimodales.

Publications (2)

Publication Number Publication Date
ES2116188A1 ES2116188A1 (es) 1998-07-01
ES2116188B1 true ES2116188B1 (es) 1999-04-01

Family

ID=8288443

Family Applications (1)

Application Number Title Priority Date Filing Date
ES09402690A Expired - Fee Related ES2116188B1 (es) 1994-12-30 1994-12-30 Proceso de obtencion de poliolefinas con distribuciones de pesos moleculares anchas, bimodales o multimodales.

Country Status (9)

Country Link
US (1) US6605676B1 (es)
EP (1) EP0719797B2 (es)
JP (1) JP3292649B2 (es)
AT (1) ATE191723T1 (es)
DE (1) DE69516258T3 (es)
ES (1) ES2116188B1 (es)
FI (1) FI956289A7 (es)
NO (1) NO315240B1 (es)
PT (1) PT719797E (es)

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Also Published As

Publication number Publication date
ATE191723T1 (de) 2000-04-15
DE69516258D1 (de) 2000-05-18
JPH08245712A (ja) 1996-09-24
ES2116188A1 (es) 1998-07-01
FI956289A7 (fi) 1996-07-01
FI956289A0 (fi) 1995-12-28
JP3292649B2 (ja) 2002-06-17
PT719797E (pt) 2000-08-31
DE69516258T3 (de) 2004-11-18
EP0719797A2 (en) 1996-07-03
US6605676B1 (en) 2003-08-12
DE69516258T2 (de) 2000-11-30
NO315240B1 (no) 2003-08-04
NO955298D0 (no) 1995-12-27
EP0719797A3 (en) 1997-04-23
EP0719797B1 (en) 2000-04-12
EP0719797B2 (en) 2004-03-03
NO955298L (no) 1996-07-01

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