DE69516258D1 - Verfahren zur Gewinnung von Polyolefinen mit breiter bimodularer oder multimodaler Molekulargewichtsverteilung - Google Patents
Verfahren zur Gewinnung von Polyolefinen mit breiter bimodularer oder multimodaler MolekulargewichtsverteilungInfo
- Publication number
- DE69516258D1 DE69516258D1 DE69516258T DE69516258T DE69516258D1 DE 69516258 D1 DE69516258 D1 DE 69516258D1 DE 69516258 T DE69516258 T DE 69516258T DE 69516258 T DE69516258 T DE 69516258T DE 69516258 D1 DE69516258 D1 DE 69516258D1
- Authority
- DE
- Germany
- Prior art keywords
- molecular weight
- catalysts
- catalyst
- multimodal molecular
- broad
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/905—Polymerization in presence of transition metal containing catalyst in presence of hydrogen
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ES09402690A ES2116188B1 (es) | 1994-12-30 | 1994-12-30 | Proceso de obtencion de poliolefinas con distribuciones de pesos moleculares anchas, bimodales o multimodales. |
ES9402690 | 1994-12-30 |
Publications (3)
Publication Number | Publication Date |
---|---|
DE69516258D1 true DE69516258D1 (de) | 2000-05-18 |
DE69516258T2 DE69516258T2 (de) | 2000-11-30 |
DE69516258T3 DE69516258T3 (de) | 2004-11-18 |
Family
ID=8288443
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE1995616258 Expired - Fee Related DE69516258T3 (de) | 1994-12-30 | 1995-12-20 | Verfahren zur Gewinnung von Polyolefinen mit breiter bimodularer oder multimodaler Molekulargewichtsverteilung |
Country Status (9)
Country | Link |
---|---|
US (1) | US6605676B1 (de) |
EP (1) | EP0719797B2 (de) |
JP (1) | JP3292649B2 (de) |
AT (1) | ATE191723T1 (de) |
DE (1) | DE69516258T3 (de) |
ES (1) | ES2116188B1 (de) |
FI (1) | FI956289A (de) |
NO (1) | NO315240B1 (de) |
PT (1) | PT719797E (de) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1582525B1 (de) * | 1996-12-20 | 2014-12-17 | Sumitomo Chemical Company, Limited | Borverbindung in Form feiner Teilchen, Katalysatorkomponente für die Olefinpolymerisation, die diese enthalten und Verfahren zu dessen Herstellung |
US6696379B1 (en) | 1997-09-19 | 2004-02-24 | The Dow Chemical Company | Supported modified alumoxane catalyst activator |
PL339339A1 (en) * | 1997-09-19 | 2000-12-18 | Dow Chemical Co | Modified alumoxanate-type catalyst activator |
DE69935332T2 (de) * | 1998-07-16 | 2007-10-31 | Univation Technologies, LLC, Houston | Lewis-säure cokatalysatoren auf aluminium-basis für die olefinpolymerisation |
GB9816940D0 (en) | 1998-08-05 | 1998-09-30 | Bp Chem Int Ltd | Polymerisation catalysts |
US6444765B1 (en) | 2000-06-14 | 2002-09-03 | Equistar Chemicals, Lp | Olefin polymerization process for producing broad MWD polymers |
US6812304B2 (en) | 2000-06-14 | 2004-11-02 | Equistar Chemicals, Lp | Process for producing improved premixed supported boraaryl catalysts |
GB0111443D0 (en) | 2001-05-10 | 2001-07-04 | Borealis Tech Oy | Olefin polymerisation process |
CN101724110B (zh) | 2002-10-15 | 2013-03-27 | 埃克森美孚化学专利公司 | 用于烯烃聚合的多催化剂体系和由其生产的聚合物 |
US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
US8153243B2 (en) | 2005-12-09 | 2012-04-10 | Dow Global Technologies Llc | Interpolymers suitable for multilayer films |
RU2008127854A (ru) | 2005-12-09 | 2010-01-20 | Дау Глобал Текнолоджиз Инк. (Us) | Способы регулирования молекулярно-массового распределения в этилен/альфа-олефиновых композициях |
WO2008132035A1 (en) * | 2007-04-27 | 2008-11-06 | Basell Poliolefine Italia S.R.L. | Butene-1 terpolymers and process for their preparation |
KR101850984B1 (ko) * | 2015-06-15 | 2018-04-20 | 주식회사 엘지화학 | 섬유 제조용 폴리올레핀 및 이를 포함하는 섬유 |
WO2016204387A1 (ko) * | 2015-06-15 | 2016-12-22 | 주식회사 엘지화학 | 섬유 제조용 폴리올레핀 및 이를 포함하는 섬유 |
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JPH05331228A (ja) | 1971-11-18 | 1993-12-14 | Idemitsu Kosan Co Ltd | ポリオレフィンの製造方法 |
DE2608863A1 (de) | 1976-03-04 | 1977-09-08 | Basf Ag | Verfahren zum herstellen von polyaethylen |
US4414369A (en) | 1977-08-17 | 1983-11-08 | Nippon Oil Company, Limited | Continuous process for the preparation of polyolefins having widely distributed molecular weights |
JPS56166208A (en) | 1980-05-27 | 1981-12-21 | Mitsui Petrochem Ind Ltd | Gas-phase polymerization of olefin |
JPS6045645B2 (ja) | 1980-10-09 | 1985-10-11 | 三井化学株式会社 | オレフイン類の気相重合方法 |
US4530914A (en) | 1983-06-06 | 1985-07-23 | Exxon Research & Engineering Co. | Process and catalyst for producing polyethylene having a broad molecular weight distribution |
FR2577558B1 (fr) | 1985-02-19 | 1987-03-06 | Bp Chimie Sa | Polymerisation en plusieurs etapes d'alpha-olefines en phase gazeuse |
EP0594218B1 (de) * | 1986-09-24 | 1999-03-17 | Mitsui Chemicals, Inc. | Verfahren zur Olefinpolymerisation |
IL85097A (en) | 1987-01-30 | 1992-02-16 | Exxon Chemical Patents Inc | Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes |
US5153157A (en) * | 1987-01-30 | 1992-10-06 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
US4939217A (en) | 1987-04-03 | 1990-07-03 | Phillips Petroleum Company | Process for producing polyolefins and polyolefin catalysts |
US5064797A (en) | 1987-04-03 | 1991-11-12 | Phillips Petroleum Company | Process for producing polyolefins and polyolefin catalysts |
US4794096A (en) * | 1987-04-03 | 1988-12-27 | Fina Technology, Inc. | Hafnium metallocene catalyst for the polymerization of olefins |
ATE114323T1 (de) | 1987-09-11 | 1994-12-15 | Fina Technology | Katalysatorsystem für polyolefinproduktion mit breiter molekulargewichtsverteilung. |
US5155080A (en) | 1988-07-15 | 1992-10-13 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
DE69018376T3 (de) | 1989-10-30 | 2002-05-16 | Fina Technology, Inc. | Herstellung von Metallocenkatalysatoren für Olefinpolymerisation. |
JP3217416B2 (ja) † | 1990-11-30 | 2001-10-09 | 出光興産株式会社 | オレフィン系重合体の製造方法 |
WO1992009640A1 (en) * | 1990-11-30 | 1992-06-11 | Idemitsu Kosan Co., Ltd. | Process for producing olefinic polymer |
CA2060019A1 (en) | 1991-03-04 | 1992-09-05 | Phil Marvin Stricklen | Process for producing polyolefins having a bimodal molecular weight distribution |
CA2058383A1 (en) * | 1991-05-17 | 1992-11-18 | Ted M. Pettijohn | Olefin polymerization |
CA2069995C (en) * | 1991-05-31 | 1996-04-09 | Mitsui Chemicals, Incorporated | Olefin polymerization solid catalyst, olefin polymerization catalyst and olefin polymerization |
DE69222700T2 (de) * | 1991-07-11 | 1998-03-26 | Idemitsu Kosan Co | Verfahren zur Herstellung von Polymeren auf Olefinbasis und Olefin-Polymerisationskatalysatoren |
JPH05140221A (ja) | 1991-11-25 | 1993-06-08 | Mitsui Toatsu Chem Inc | オレフインの重合方法 |
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JPH05310829A (ja) | 1992-03-12 | 1993-11-22 | Tosoh Corp | オレフィン重合用触媒及びオレフィンの重合方法 |
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JPH05320258A (ja) | 1992-05-15 | 1993-12-03 | Mitsui Petrochem Ind Ltd | 環状オレフィン共重合用触媒および環状オレフィンの共重合方法 |
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US5434115A (en) | 1992-05-22 | 1995-07-18 | Tosoh Corporation | Process for producing olefin polymer |
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JP3262137B2 (ja) | 1992-05-26 | 2002-03-04 | 出光興産株式会社 | エチレン系重合体の製造方法 |
JPH05320259A (ja) | 1992-05-27 | 1993-12-03 | Idemitsu Kosan Co Ltd | エチレン系共重合体の製造方法 |
JPH05331219A (ja) | 1992-05-29 | 1993-12-14 | Idemitsu Kosan Co Ltd | オレフィン重合体の製造方法 |
JPH05339316A (ja) | 1992-06-05 | 1993-12-21 | Tosoh Corp | オレフィン重合用触媒およびオレフィンの重合方法 |
BE1005957A5 (fr) * | 1992-06-05 | 1994-04-05 | Solvay | Procede de preparation d'un systeme catalytique, procede de (co)polymerisation d'olefines et (co)polymeres d'au moins une olefine. |
JP3153000B2 (ja) | 1992-06-11 | 2001-04-03 | 三菱化学株式会社 | α‐オレフィン重合体の製造法 |
EP0588208A3 (en) † | 1992-09-12 | 1994-07-06 | Hoechst Ag | Polyolefin moulding composition with broad melt range, process and use therefore |
JP3202349B2 (ja) * | 1992-09-22 | 2001-08-27 | 三菱化学株式会社 | 触媒組成物およびそれを用いるオレフィンの重合法 |
EP0590486A3 (en) † | 1992-09-24 | 1994-08-24 | Idemitsu Kosan Co | Polymerization catalysts and process for producing polymers |
NL9201970A (nl) * | 1992-11-11 | 1994-06-01 | Dsm Nv | Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen. |
JP3332051B2 (ja) † | 1992-12-18 | 2002-10-07 | 出光興産株式会社 | 重合用触媒及び該触媒系を用いる重合体の製造方法 |
US6313240B1 (en) * | 1993-02-22 | 2001-11-06 | Tosoh Corporation | Process for producing ethylene/α-olefin copolymer |
NL9400758A (nl) * | 1994-05-06 | 1995-12-01 | Dsm Nv | Werkwijze voor de bereiding van een hoogmoleculair polymeer uit etheen, alfa-olefine en eventueel dieen. |
-
1994
- 1994-12-30 ES ES09402690A patent/ES2116188B1/es not_active Expired - Fee Related
-
1995
- 1995-12-20 PT PT95500174T patent/PT719797E/pt unknown
- 1995-12-20 EP EP95500174A patent/EP0719797B2/de not_active Expired - Lifetime
- 1995-12-20 AT AT95500174T patent/ATE191723T1/de not_active IP Right Cessation
- 1995-12-20 DE DE1995616258 patent/DE69516258T3/de not_active Expired - Fee Related
- 1995-12-27 NO NO19955298A patent/NO315240B1/no unknown
- 1995-12-28 FI FI956289A patent/FI956289A/fi not_active Application Discontinuation
- 1995-12-28 US US08/580,734 patent/US6605676B1/en not_active Expired - Fee Related
-
1996
- 1996-01-04 JP JP00005496A patent/JP3292649B2/ja not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
EP0719797B1 (de) | 2000-04-12 |
FI956289A (fi) | 1996-07-01 |
NO955298D0 (no) | 1995-12-27 |
EP0719797A2 (de) | 1996-07-03 |
ATE191723T1 (de) | 2000-04-15 |
ES2116188A1 (es) | 1998-07-01 |
ES2116188B1 (es) | 1999-04-01 |
DE69516258T3 (de) | 2004-11-18 |
NO315240B1 (no) | 2003-08-04 |
JPH08245712A (ja) | 1996-09-24 |
DE69516258T2 (de) | 2000-11-30 |
US6605676B1 (en) | 2003-08-12 |
EP0719797B2 (de) | 2004-03-03 |
FI956289A0 (fi) | 1995-12-28 |
NO955298L (no) | 1996-07-01 |
JP3292649B2 (ja) | 2002-06-17 |
PT719797E (pt) | 2000-08-31 |
EP0719797A3 (de) | 1997-04-23 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8363 | Opposition against the patent | ||
8366 | Restricted maintained after opposition proceedings | ||
8339 | Ceased/non-payment of the annual fee |