FI956289A - Menetelmä laajan bimodaalisen tai multimodaalisen molekyylipainojakauman omaavien polyolefiinien aikaansaamiseksi - Google Patents

Menetelmä laajan bimodaalisen tai multimodaalisen molekyylipainojakauman omaavien polyolefiinien aikaansaamiseksi Download PDF

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Publication number
FI956289A
FI956289A FI956289A FI956289A FI956289A FI 956289 A FI956289 A FI 956289A FI 956289 A FI956289 A FI 956289A FI 956289 A FI956289 A FI 956289A FI 956289 A FI956289 A FI 956289A
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FI
Finland
Prior art keywords
molecular weight
catalysts
catalyst
multimodal molecular
metallocene
Prior art date
Application number
FI956289A
Other languages
English (en)
Swedish (sv)
Other versions
FI956289A0 (fi
Inventor
Vega Wilfried Michiels
Lafuente Antoni Munoz-Escalona
Original Assignee
Repsol Quimica Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
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Application filed by Repsol Quimica Sa filed Critical Repsol Quimica Sa
Publication of FI956289A0 publication Critical patent/FI956289A0/fi
Publication of FI956289A publication Critical patent/FI956289A/fi

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61908Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61916Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/905Polymerization in presence of transition metal containing catalyst in presence of hydrogen
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
FI956289A 1994-12-30 1995-12-28 Menetelmä laajan bimodaalisen tai multimodaalisen molekyylipainojakauman omaavien polyolefiinien aikaansaamiseksi FI956289A (fi)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES09402690A ES2116188B1 (es) 1994-12-30 1994-12-30 Proceso de obtencion de poliolefinas con distribuciones de pesos moleculares anchas, bimodales o multimodales.

Publications (2)

Publication Number Publication Date
FI956289A0 FI956289A0 (fi) 1995-12-28
FI956289A true FI956289A (fi) 1996-07-01

Family

ID=8288443

Family Applications (1)

Application Number Title Priority Date Filing Date
FI956289A FI956289A (fi) 1994-12-30 1995-12-28 Menetelmä laajan bimodaalisen tai multimodaalisen molekyylipainojakauman omaavien polyolefiinien aikaansaamiseksi

Country Status (9)

Country Link
US (1) US6605676B1 (fi)
EP (1) EP0719797B2 (fi)
JP (1) JP3292649B2 (fi)
AT (1) ATE191723T1 (fi)
DE (1) DE69516258T3 (fi)
ES (1) ES2116188B1 (fi)
FI (1) FI956289A (fi)
NO (1) NO315240B1 (fi)
PT (1) PT719797E (fi)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0887355B1 (en) * 1996-12-20 2006-09-06 Sumitomo Chemical Company, Limited Process for preparing olefin polymers
US6696379B1 (en) 1997-09-19 2004-02-24 The Dow Chemical Company Supported modified alumoxane catalyst activator
BR9812485A (pt) * 1997-09-19 2000-09-19 Dow Chemical Co Ativador catalisador de aluminoxano modificado
EP1097175B1 (en) 1998-07-16 2007-02-28 Univation Technologies LLC Aluminum-based lewis acid cocatalysts for olefin polymerization
GB9816940D0 (en) * 1998-08-05 1998-09-30 Bp Chem Int Ltd Polymerisation catalysts
US6812304B2 (en) 2000-06-14 2004-11-02 Equistar Chemicals, Lp Process for producing improved premixed supported boraaryl catalysts
US6444765B1 (en) 2000-06-14 2002-09-03 Equistar Chemicals, Lp Olefin polymerization process for producing broad MWD polymers
GB0111443D0 (en) 2001-05-10 2001-07-04 Borealis Tech Oy Olefin polymerisation process
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
JP4972284B2 (ja) 2002-10-15 2012-07-11 エクソンモービル・ケミカル・パテンツ・インク オレフィン重合のための複数触媒系及びそれらから生成されたポリマー
US8153243B2 (en) 2005-12-09 2012-04-10 Dow Global Technologies Llc Interpolymers suitable for multilayer films
BRPI0620567B1 (pt) 2005-12-09 2018-05-29 Dow Global Technologies Inc. Processo para produzir uma composição de interpolímero de etileno/(alfa)-olefina
ATE482982T1 (de) * 2007-04-27 2010-10-15 Basell Poliolefine Srl Buten-1-terpolymere und herstellungsverfahren dafür
KR101850984B1 (ko) * 2015-06-15 2018-04-20 주식회사 엘지화학 섬유 제조용 폴리올레핀 및 이를 포함하는 섬유
WO2016204387A1 (ko) * 2015-06-15 2016-12-22 주식회사 엘지화학 섬유 제조용 폴리올레핀 및 이를 포함하는 섬유

Family Cites Families (51)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05331228A (ja) 1971-11-18 1993-12-14 Idemitsu Kosan Co Ltd ポリオレフィンの製造方法
DE2608863A1 (de) 1976-03-04 1977-09-08 Basf Ag Verfahren zum herstellen von polyaethylen
US4414369A (en) 1977-08-17 1983-11-08 Nippon Oil Company, Limited Continuous process for the preparation of polyolefins having widely distributed molecular weights
JPS56166208A (en) 1980-05-27 1981-12-21 Mitsui Petrochem Ind Ltd Gas-phase polymerization of olefin
JPS6045645B2 (ja) 1980-10-09 1985-10-11 三井化学株式会社 オレフイン類の気相重合方法
US4530914A (en) 1983-06-06 1985-07-23 Exxon Research & Engineering Co. Process and catalyst for producing polyethylene having a broad molecular weight distribution
FR2577558B1 (fr) 1985-02-19 1987-03-06 Bp Chimie Sa Polymerisation en plusieurs etapes d'alpha-olefines en phase gazeuse
DE3786013T2 (de) * 1986-09-24 1993-09-02 Mitsui Petrochemical Ind Polymerisierungsverfahren fuer olefine.
IL85097A (en) 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
US5153157A (en) * 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US4794096A (en) * 1987-04-03 1988-12-27 Fina Technology, Inc. Hafnium metallocene catalyst for the polymerization of olefins
US4939217A (en) 1987-04-03 1990-07-03 Phillips Petroleum Company Process for producing polyolefins and polyolefin catalysts
US5064797A (en) 1987-04-03 1991-11-12 Phillips Petroleum Company Process for producing polyolefins and polyolefin catalysts
DE3750776T2 (de) 1987-09-11 1995-04-27 Fina Technology Katalysatorsystem für Polyolefinproduktion mit breiter Molekulargewichtsverteilung.
US5155080A (en) 1988-07-15 1992-10-13 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
DK0426637T4 (da) 1989-10-30 2002-01-14 Fina Technology Fremgangsmåde til fremstilling af metallocenkatalysatorer til polymerisation af olefiner
JP3217416B2 (ja) 1990-11-30 2001-10-09 出光興産株式会社 オレフィン系重合体の製造方法
EP0513380B2 (en) * 1990-11-30 2011-02-23 Idemitsu Kosan Company Limited Process for producing olefinic polymer
CA2060019A1 (en) 1991-03-04 1992-09-05 Phil Marvin Stricklen Process for producing polyolefins having a bimodal molecular weight distribution
CA2058383A1 (en) * 1991-05-17 1992-11-18 Ted M. Pettijohn Olefin polymerization
EP0516458B2 (en) * 1991-05-31 2007-12-19 Mitsui Chemicals, Inc. Olefin polymerization solid catalyst, olefin polymerization catalyst and olefin polymerization
EP0522581B1 (en) * 1991-07-11 1997-10-15 Idemitsu Kosan Company Limited Process for producing olefin based polymers and olefin polymerization catalyst
JPH05140221A (ja) 1991-11-25 1993-06-08 Mitsui Toatsu Chem Inc オレフインの重合方法
JPH05155927A (ja) 1991-12-11 1993-06-22 Mitsui Toatsu Chem Inc オレフィンの重合方法
DE69310390T2 (de) 1992-01-23 1997-10-23 Mitsui Petrochemical Ind Verfahren zur Herstellung eines Polyolefins
JPH05239140A (ja) 1992-02-26 1993-09-17 Tosoh Corp オレフィン重合用触媒及びこれを用いたポリオレフィンの製造方法
JPH05310829A (ja) 1992-03-12 1993-11-22 Tosoh Corp オレフィン重合用触媒及びオレフィンの重合方法
JPH05255423A (ja) 1992-03-12 1993-10-05 Tosoh Corp オレフィン重合用触媒及びオレフィンの重合方法
JP3268005B2 (ja) 1992-03-18 2002-03-25 出光興産株式会社 オレフィン系共重合体及びその製造方法
JP3255697B2 (ja) 1992-03-26 2002-02-12 出光興産株式会社 透明性オレフィン系合成ワックス及びその製造方法
JPH05295021A (ja) 1992-04-22 1993-11-09 Mitsubishi Petrochem Co Ltd オレフィンの重合法
JPH05301919A (ja) 1992-04-27 1993-11-16 Tosoh Corp オレフィン重合用触媒及びオレフィンの重合方法
JPH05320258A (ja) 1992-05-15 1993-12-03 Mitsui Petrochem Ind Ltd 環状オレフィン共重合用触媒および環状オレフィンの共重合方法
JPH05320245A (ja) 1992-05-18 1993-12-03 Idemitsu Kosan Co Ltd エチレン系重合体組成物の製造法
JP3186218B2 (ja) 1992-05-20 2001-07-11 出光興産株式会社 末端ビニルエチレン−プロピレン共重合体およびその製造方法
JPH05320247A (ja) 1992-05-21 1993-12-03 Idemitsu Kosan Co Ltd エチレン系重合体組成物の製造方法
US5434115A (en) 1992-05-22 1995-07-18 Tosoh Corporation Process for producing olefin polymer
JP3262137B2 (ja) 1992-05-26 2002-03-04 出光興産株式会社 エチレン系重合体の製造方法
JP3264332B2 (ja) 1992-05-26 2002-03-11 出光興産株式会社 エチレン系重合体組成物の製造方法
JPH05320259A (ja) 1992-05-27 1993-12-03 Idemitsu Kosan Co Ltd エチレン系共重合体の製造方法
JPH05331219A (ja) 1992-05-29 1993-12-14 Idemitsu Kosan Co Ltd オレフィン重合体の製造方法
BE1005957A5 (fr) * 1992-06-05 1994-04-05 Solvay Procede de preparation d'un systeme catalytique, procede de (co)polymerisation d'olefines et (co)polymeres d'au moins une olefine.
JPH05339316A (ja) 1992-06-05 1993-12-21 Tosoh Corp オレフィン重合用触媒およびオレフィンの重合方法
JP3153000B2 (ja) 1992-06-11 2001-04-03 三菱化学株式会社 α‐オレフィン重合体の製造法
EP0588208A3 (en) 1992-09-12 1994-07-06 Hoechst Ag Polyolefin moulding composition with broad melt range, process and use therefore
JP3202349B2 (ja) * 1992-09-22 2001-08-27 三菱化学株式会社 触媒組成物およびそれを用いるオレフィンの重合法
EP0590486A3 (en) 1992-09-24 1994-08-24 Idemitsu Kosan Co Polymerization catalysts and process for producing polymers
NL9201970A (nl) * 1992-11-11 1994-06-01 Dsm Nv Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen.
JP3332051B2 (ja) 1992-12-18 2002-10-07 出光興産株式会社 重合用触媒及び該触媒系を用いる重合体の製造方法
US6313240B1 (en) * 1993-02-22 2001-11-06 Tosoh Corporation Process for producing ethylene/α-olefin copolymer
NL9400758A (nl) * 1994-05-06 1995-12-01 Dsm Nv Werkwijze voor de bereiding van een hoogmoleculair polymeer uit etheen, alfa-olefine en eventueel dieen.

Also Published As

Publication number Publication date
NO955298L (no) 1996-07-01
ES2116188B1 (es) 1999-04-01
NO955298D0 (no) 1995-12-27
JP3292649B2 (ja) 2002-06-17
ES2116188A1 (es) 1998-07-01
EP0719797B2 (en) 2004-03-03
DE69516258T2 (de) 2000-11-30
DE69516258T3 (de) 2004-11-18
US6605676B1 (en) 2003-08-12
FI956289A0 (fi) 1995-12-28
EP0719797A2 (en) 1996-07-03
NO315240B1 (no) 2003-08-04
ATE191723T1 (de) 2000-04-15
EP0719797B1 (en) 2000-04-12
PT719797E (pt) 2000-08-31
DE69516258D1 (de) 2000-05-18
EP0719797A3 (en) 1997-04-23
JPH08245712A (ja) 1996-09-24

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