DE3750776T2 - Katalysatorsystem für Polyolefinproduktion mit breiter Molekulargewichtsverteilung. - Google Patents

Katalysatorsystem für Polyolefinproduktion mit breiter Molekulargewichtsverteilung.

Info

Publication number
DE3750776T2
DE3750776T2 DE3750776T DE3750776T DE3750776T2 DE 3750776 T2 DE3750776 T2 DE 3750776T2 DE 3750776 T DE3750776 T DE 3750776T DE 3750776 T DE3750776 T DE 3750776T DE 3750776 T2 DE3750776 T2 DE 3750776T2
Authority
DE
Germany
Prior art keywords
molecular weight
weight distribution
catalyst system
broad molecular
polyolefin production
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE3750776T
Other languages
English (en)
Other versions
DE3750776D1 (de
Inventor
A John Ewen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fina Technology Inc
Original Assignee
Fina Technology Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fina Technology Inc filed Critical Fina Technology Inc
Publication of DE3750776D1 publication Critical patent/DE3750776D1/de
Application granted granted Critical
Publication of DE3750776T2 publication Critical patent/DE3750776T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63904—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with another component of C08F4/62
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/63927—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
DE3750776T 1987-09-11 1987-09-21 Katalysatorsystem für Polyolefinproduktion mit breiter Molekulargewichtsverteilung. Expired - Lifetime DE3750776T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US9575587A 1987-09-11 1987-09-11

Publications (2)

Publication Number Publication Date
DE3750776D1 DE3750776D1 (de) 1995-01-05
DE3750776T2 true DE3750776T2 (de) 1995-04-27

Family

ID=22253445

Family Applications (1)

Application Number Title Priority Date Filing Date
DE3750776T Expired - Lifetime DE3750776T2 (de) 1987-09-11 1987-09-21 Katalysatorsystem für Polyolefinproduktion mit breiter Molekulargewichtsverteilung.

Country Status (7)

Country Link
EP (1) EP0310734B1 (de)
JP (1) JP2669833B2 (de)
KR (1) KR950008152B1 (de)
AT (1) ATE114323T1 (de)
CA (1) CA1323621C (de)
DE (1) DE3750776T2 (de)
ES (1) ES2064322T3 (de)

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2587251B2 (ja) * 1987-11-09 1997-03-05 チッソ株式会社 立体規則性オレフィン重合体製造用触媒
DE3743321A1 (de) * 1987-12-21 1989-06-29 Hoechst Ag 1-olefinpolymerwachs und verfahren zu seiner herstellung
JP2720392B2 (ja) * 1988-07-12 1998-03-04 三井化学株式会社 オレフィン重合用触媒およびオレフィンの重合方法
ATE136040T1 (de) 1991-05-27 1996-04-15 Hoechst Ag Verfahren zur herstellung von polyolefinen mit breiter molmassenverteilung
DE59204800D1 (de) * 1991-05-27 1996-02-08 Hoechst Ag Verfahren zur Herstellung von syndiotaktischen Polyolefinen mit breiter Molmassenverteilung
JP3822633B2 (ja) * 1991-11-07 2006-09-20 エクソンモービル・ケミカル・パテンツ・インク ポリオレフィンの製造方法
US6143854A (en) * 1993-08-06 2000-11-07 Exxon Chemical Patents, Inc. Polymerization catalysts, their production and use
EP0588208A3 (en) * 1992-09-12 1994-07-06 Hoechst Ag Polyolefin moulding composition with broad melt range, process and use therefore
JP2902784B2 (ja) * 1993-05-25 1999-06-07 エクソン・ケミカル・パテンツ・インク 新規なポリオレフィン繊維及びそれらの布
EP0719287B1 (de) * 1993-08-06 1999-12-29 Exxon Chemical Patents Inc. Polymerisationskataylsatoren, ihre herstellung und verwendung
DE4333128A1 (de) * 1993-09-29 1995-03-30 Hoechst Ag Verfahren zur Herstellung von Polyolefinen
JPH07309910A (ja) * 1994-05-19 1995-11-28 Chisso Corp 改質ポリプロピレンの製造方法および成形品
ES2116188B1 (es) 1994-12-30 1999-04-01 Repsol Quimica Sa Proceso de obtencion de poliolefinas con distribuciones de pesos moleculares anchas, bimodales o multimodales.
US5516848A (en) * 1995-01-31 1996-05-14 Exxon Chemical Patents Inc. Process to produce thermoplastic elastomers
US5539056A (en) * 1995-01-31 1996-07-23 Exxon Chemical Patents Inc. Thermoplastic elastomers
US5786291A (en) * 1996-02-23 1998-07-28 Exxon Chemical Patents, Inc. Engineered catalyst systems and methods for their production and use
EP1083188A1 (de) 1999-09-10 2001-03-14 Fina Research S.A. Katalysator und Verfahren zur Herstellung von syndiotaktischen / ataktischen Block-Polyolefinen
US6576306B2 (en) 1996-09-04 2003-06-10 Exxonmobil Chemical Patents Inc. Propylene polymers for films
KR20000068428A (ko) 1996-09-04 2000-11-25 엑손 케미칼 패턴츠 인코포레이티드 배향 필름용의 개선된 프로필렌 중합체
US6583227B2 (en) 1996-09-04 2003-06-24 Exxonmobil Chemical Patents Inc. Propylene polymers for films
EP1059332A1 (de) * 1999-06-10 2000-12-13 Fina Research S.A. Polypropylen mit hoher Schmelzsteifigkeit und Tiefziehfähigkeit
US6943227B2 (en) 2001-06-29 2005-09-13 Japan Polypropylene Corporation Catalyst for olefin polymerization and method of polymerization of olefin
EP1300423A1 (de) * 2001-09-27 2003-04-09 Atofina Research S.A. Katalysatorsystem aus einer Mischung von Katalysatorbestandteilen zur Herstellung einer Polyolefinmischung
EP1620479B1 (de) 2002-10-15 2013-07-24 ExxonMobil Chemical Patents Inc. Polyolefinklebstoffzusammensetzungen und daraus hergestellte gegenstände
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
EP1650232A1 (de) * 2004-10-25 2006-04-26 Total Petrochemicals Research Feluy Herstellung von LDPE-Polymeren mittels Bisindenyl-Liganden, die verschiedene Ringsysteme enthalten
WO2011087520A1 (en) 2009-12-22 2011-07-21 Univation Technologies, Llc Catalyst systems having a tailored hydrogen response
TW200936619A (en) 2007-11-15 2009-09-01 Univation Tech Llc Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom
JP5754940B2 (ja) 2008-08-19 2015-07-29 三井化学株式会社 混合触媒によるプロピレン重合体の製造方法
BRPI1010927A2 (pt) 2009-05-14 2016-04-05 Univation Tech Llc sistemas catalisadores de metal misturados que têm uma resposta de hidrogênio sob medida.
WO2020189676A1 (ja) * 2019-03-19 2020-09-24 三井化学株式会社 プロピレン系樹脂組成物、成形体およびプロピレン重合体

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4522982A (en) * 1983-06-06 1985-06-11 Exxon Research & Engineering Co. Isotactic-stereoblock polymers of alpha-olefins and process for producing the same
US4530914A (en) * 1983-06-06 1985-07-23 Exxon Research & Engineering Co. Process and catalyst for producing polyethylene having a broad molecular weight distribution
EP0128046B1 (de) * 1983-06-06 1987-10-21 Exxon Research And Engineering Company Verfahren und Katalysator zur Herstellung einer Mischung von Polyolefinen in einem Reaktor
ZA844157B (en) * 1983-06-06 1986-01-29 Exxon Research Engineering Co Process and catalyst for polyolefin density and molecular weight control
DE3443087A1 (de) * 1984-11-27 1986-05-28 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von polyolefinen
DE3508887A1 (de) * 1985-03-13 1986-09-25 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von optisch aktiven polyolefinen

Also Published As

Publication number Publication date
ES2064322T3 (es) 1995-02-01
EP0310734A1 (de) 1989-04-12
EP0310734B1 (de) 1994-11-23
KR890005155A (ko) 1989-05-13
DE3750776D1 (de) 1995-01-05
JPS6474202A (en) 1989-03-20
ATE114323T1 (de) 1994-12-15
CA1323621C (en) 1993-10-26
JP2669833B2 (ja) 1997-10-29
KR950008152B1 (ko) 1995-07-25

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