FR2659337B1 - Procede de preparation d'un catalyseur a base de zirconium, de titane et/ou de vanadium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines. - Google Patents
Procede de preparation d'un catalyseur a base de zirconium, de titane et/ou de vanadium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines.Info
- Publication number
- FR2659337B1 FR2659337B1 FR9003368A FR9003368A FR2659337B1 FR 2659337 B1 FR2659337 B1 FR 2659337B1 FR 9003368 A FR9003368 A FR 9003368A FR 9003368 A FR9003368 A FR 9003368A FR 2659337 B1 FR2659337 B1 FR 2659337B1
- Authority
- FR
- France
- Prior art keywords
- catalyst
- titanium
- prepolymer
- zirconium
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
- C08F4/74—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals
- C08F4/76—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals selected from titanium, zirconium, hafnium, vanadium, niobium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerization Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Graft Or Block Polymers (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (18)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9003368A FR2659337B1 (fr) | 1990-03-12 | 1990-03-12 | Procede de preparation d'un catalyseur a base de zirconium, de titane et/ou de vanadium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines. |
CA002036767A CA2036767A1 (fr) | 1990-03-12 | 1991-02-20 | Catalyseur et prepolymere utilises pour la polymerisation d'olefines, et polymere (co-) d'ethylene qu'on peut obtenir ainsi |
ZA911294A ZA911294B (en) | 1990-03-12 | 1991-02-21 | Catalyst and prepolymer used for polymerising olefins,and (co-)polymer of ethylene obtainable therefrom |
AU71345/91A AU640452B2 (en) | 1990-03-12 | 1991-02-25 | Catalyst and prepolymer used for polymerising olefins, and (co-)polymer of ethylene obtainable therefrom |
AT91301672T ATE121758T1 (de) | 1990-03-12 | 1991-02-28 | Katalysator und prepolymere für die polymerisation von olefinen und daraus erhältliches ethylen(co)polymer. |
ES91301672T ES2071211T3 (es) | 1990-03-12 | 1991-02-28 | Catalizador y prepolimero usados para la polimerizacion de olefinas y (co)polimero de etileno obtenible a partir de la misma. |
EP91301672A EP0447070B1 (fr) | 1990-03-12 | 1991-02-28 | Catalyseur et prépolymère utilisés pour la polymérisation d'oléfines et (co)polymère d'éthylène ainsi obtenu |
DE69109161T DE69109161T2 (de) | 1990-03-12 | 1991-02-28 | Katalysator und Prepolymere für die Polymerisation von Olefinen und daraus erhältliches Ethylen(co)polymer. |
PL28937691A PL289376A1 (en) | 1990-03-12 | 1991-03-11 | Solid catalyst for olefin polymerization, prepolymer, method or its synthesis, and the method of ethylene polymerization or copolymerization |
NO910954A NO177389C (no) | 1990-03-12 | 1991-03-11 | Katalysator og prepolymer, fremstilling av slike og polymerisasjon av etylen |
PT97007A PT97007B (pt) | 1990-03-12 | 1991-03-11 | Processo para a preparacao de catalisadores solidos a base de zirconio e de pre-polimeros para a polimerizacao heterogenea de uma ou mais olefinas e de polimerizacao de olefinas que os utiliza |
CS91633A CS63391A2 (en) | 1990-03-12 | 1991-03-11 | Catalyst and prepolymer applicable for olefins' polymerization and ethylene (co)polymer that can be prepared from them |
JP3044933A JPH04220406A (ja) | 1990-03-12 | 1991-03-11 | オレフィン類の重合化に使用される触媒とプレポリマー、及びこれらから得られるエチレンの(共)重合体 |
HU91791A HUT60296A (en) | 1990-03-12 | 1991-03-11 | Process for producing and applying catalyst and prepolymer in polymerization of olefins |
FI911215A FI911215A (fi) | 1990-03-12 | 1991-03-12 | Katalysator och prepolymer foer anvaendning vid polymerisation av olefiner och fraon dessa framstaellbar (ko)polymer av eten. |
CN91101482A CN1054776A (zh) | 1990-03-12 | 1991-03-12 | 用于烯烃聚合的催化剂和预聚物以及由其制得的乙烯(共)聚合物 |
KR1019910003943A KR910016782A (ko) | 1990-03-12 | 1991-03-12 | 올레핀 중합에 사용된 촉매 및 예비 중합체 및 그로부터 수득가능한 에틸렌의 (공) 중합체 |
IDP72291A ID891B (id) | 1990-03-12 | 1991-10-29 | Katalis dan prapolimer yang digunakan untuk mempolimerkan olefin dan (ko-) polimer etilena |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9003368A FR2659337B1 (fr) | 1990-03-12 | 1990-03-12 | Procede de preparation d'un catalyseur a base de zirconium, de titane et/ou de vanadium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines. |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2659337A1 FR2659337A1 (fr) | 1991-09-13 |
FR2659337B1 true FR2659337B1 (fr) | 1992-06-05 |
Family
ID=9394799
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR9003368A Expired - Lifetime FR2659337B1 (fr) | 1990-03-12 | 1990-03-12 | Procede de preparation d'un catalyseur a base de zirconium, de titane et/ou de vanadium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines. |
Country Status (17)
Country | Link |
---|---|
EP (1) | EP0447070B1 (fr) |
JP (1) | JPH04220406A (fr) |
KR (1) | KR910016782A (fr) |
CN (1) | CN1054776A (fr) |
AT (1) | ATE121758T1 (fr) |
AU (1) | AU640452B2 (fr) |
CA (1) | CA2036767A1 (fr) |
CS (1) | CS63391A2 (fr) |
DE (1) | DE69109161T2 (fr) |
ES (1) | ES2071211T3 (fr) |
FI (1) | FI911215A (fr) |
FR (1) | FR2659337B1 (fr) |
HU (1) | HUT60296A (fr) |
NO (1) | NO177389C (fr) |
PL (1) | PL289376A1 (fr) |
PT (1) | PT97007B (fr) |
ZA (1) | ZA911294B (fr) |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2659336B1 (fr) * | 1990-03-12 | 1993-05-07 | Bp Chemicals Snc | Catalyseur a base de zirconium, de titane et/ou de vanadium, supporte sur un chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines. |
WO1994004578A1 (fr) * | 1992-05-28 | 1994-03-03 | Idemitsu Petrochemical Co., Ltd. | Procede de production de polyolefine |
EP0578838A1 (fr) * | 1992-04-29 | 1994-01-19 | Hoechst Aktiengesellschaft | Catalysateur de polymérisation d'oléfines, procédé pour sa préparation et son utilisation |
TW298593B (fr) * | 1993-02-12 | 1997-02-21 | Hoechst Ag | |
EP0724604B2 (fr) * | 1993-10-21 | 2005-12-14 | Exxonmobil Oil Corporation | Melanges de polyolefines a repartition bimodale de poids moleculaires |
IT1269931B (it) * | 1994-03-29 | 1997-04-16 | Spherilene Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
DE69518104T2 (de) * | 1994-04-07 | 2000-12-14 | Bp Chem Int Ltd | Polymerisationsverfahren |
IT1270070B (it) | 1994-07-08 | 1997-04-28 | Spherilene Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
US5622906A (en) * | 1994-09-16 | 1997-04-22 | Phillips Petroleum Company | Compositions useful for olefin polymerization and processes therefor and therewith |
US5529965A (en) * | 1994-10-28 | 1996-06-25 | Exxon Chemical Patents Inc. | Polymerization catalyst systems, their production and use |
US5714424A (en) * | 1995-01-09 | 1998-02-03 | W. R. Grace & Co.-Conn. | Multi-component polyolefin catalysts |
US5882750A (en) * | 1995-07-03 | 1999-03-16 | Mobil Oil Corporation | Single reactor bimodal HMW-HDPE film resin with improved bubble stability |
FR2738829B1 (fr) | 1995-09-19 | 1997-10-17 | Atochem Elf Sa | Prepolymere pour la polymerisation des olefines, associant plusieurs composantes catalytiques solides |
ES2129323B1 (es) * | 1996-04-18 | 2000-09-16 | Repsol Quimica Sa | Procedimiento para la obtencion de un sistema catalitico para la polimerizacion de alpha-olefinas en suspension en fase gas a bajas y altas temperaturas o en masa a altas presiones y altas o bajas temperaturas |
AU2411797A (en) * | 1996-05-03 | 1997-11-26 | Dsm N.V. | A process for making polyolefins having broad molecular weight distributions |
US6136747A (en) * | 1998-06-19 | 2000-10-24 | Union Carbide Chemicals & Plastics Technology Corporation | Mixed catalyst composition for the production of olefin polymers |
CN1096474C (zh) | 1998-12-30 | 2002-12-18 | 化学工业部北京化工研究院 | 用于合成宽分布乙烯聚合物的复合催化剂及其制法和应用 |
US6265037B1 (en) | 1999-04-16 | 2001-07-24 | Andersen Corporation | Polyolefin wood fiber composite |
DE19962129A1 (de) | 1999-12-21 | 2001-06-28 | Targor Gmbh | Verfahren zur Herstellung eines Katalysatorfeststoffs zur Olefinpolymerisation |
US6703458B2 (en) | 2000-12-22 | 2004-03-09 | Basell Polyolefine Gmbh | Catalyst components for the polymerization of olefins |
CA2874344C (fr) | 2014-12-15 | 2021-08-31 | Nova Chemicals Corporation | Catalyseur spheroide de polymerisation d'olefines |
CA2890606C (fr) | 2015-05-07 | 2022-07-19 | Nova Chemicals Corporation | Procede de polymerisation au moyen de catalyseur de type ziegler-natta spherique dense |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1268754A (fr) * | 1985-06-21 | 1990-05-08 | Howard Curtis Welborn, Jr. | Catalyseur de polymerisation sur support |
US4659685A (en) * | 1986-03-17 | 1987-04-21 | The Dow Chemical Company | Heterogeneous organometallic catalysts containing a supported titanium compound and at least one other supported organometallic compound |
IT1221654B (it) * | 1987-11-27 | 1990-07-12 | Ausimont Spa | Catalizzatori per la polimerizzazione delle olefine |
FR2656315B1 (fr) * | 1989-12-22 | 1992-04-17 | Bp Chemicals Snc | Procede de preparation d'un catalyseur a base de zirconium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines. |
FR2656314B1 (fr) * | 1989-12-22 | 1992-04-17 | Bp Chemicals Snc | Catalyseur a base de zirconium supporte sur du chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines. |
FR2659336B1 (fr) * | 1990-03-12 | 1993-05-07 | Bp Chemicals Snc | Catalyseur a base de zirconium, de titane et/ou de vanadium, supporte sur un chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines. |
-
1990
- 1990-03-12 FR FR9003368A patent/FR2659337B1/fr not_active Expired - Lifetime
-
1991
- 1991-02-20 CA CA002036767A patent/CA2036767A1/fr not_active Abandoned
- 1991-02-21 ZA ZA911294A patent/ZA911294B/xx unknown
- 1991-02-25 AU AU71345/91A patent/AU640452B2/en not_active Ceased
- 1991-02-28 DE DE69109161T patent/DE69109161T2/de not_active Expired - Fee Related
- 1991-02-28 EP EP91301672A patent/EP0447070B1/fr not_active Expired - Lifetime
- 1991-02-28 ES ES91301672T patent/ES2071211T3/es not_active Expired - Lifetime
- 1991-02-28 AT AT91301672T patent/ATE121758T1/de not_active IP Right Cessation
- 1991-03-11 HU HU91791A patent/HUT60296A/hu unknown
- 1991-03-11 PL PL28937691A patent/PL289376A1/xx unknown
- 1991-03-11 NO NO910954A patent/NO177389C/no unknown
- 1991-03-11 JP JP3044933A patent/JPH04220406A/ja active Pending
- 1991-03-11 PT PT97007A patent/PT97007B/pt not_active IP Right Cessation
- 1991-03-11 CS CS91633A patent/CS63391A2/cs unknown
- 1991-03-12 CN CN91101482A patent/CN1054776A/zh active Pending
- 1991-03-12 FI FI911215A patent/FI911215A/fi not_active Application Discontinuation
- 1991-03-12 KR KR1019910003943A patent/KR910016782A/ko not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
NO910954D0 (no) | 1991-03-11 |
PL289376A1 (en) | 1992-03-09 |
HUT60296A (en) | 1992-08-28 |
CA2036767A1 (fr) | 1991-09-13 |
CS63391A2 (en) | 1991-10-15 |
JPH04220406A (ja) | 1992-08-11 |
ATE121758T1 (de) | 1995-05-15 |
DE69109161T2 (de) | 1995-08-31 |
HU910791D0 (en) | 1991-09-30 |
AU640452B2 (en) | 1993-08-26 |
NO177389C (no) | 1995-09-06 |
CN1054776A (zh) | 1991-09-25 |
EP0447070A1 (fr) | 1991-09-18 |
ES2071211T3 (es) | 1995-06-16 |
PT97007B (pt) | 1998-07-31 |
FI911215A (fi) | 1991-09-13 |
NO177389B (no) | 1995-05-29 |
FI911215A0 (fi) | 1991-03-12 |
EP0447070B1 (fr) | 1995-04-26 |
PT97007A (pt) | 1991-10-31 |
DE69109161D1 (de) | 1995-06-01 |
FR2659337A1 (fr) | 1991-09-13 |
NO910954L (no) | 1991-09-13 |
KR910016782A (ko) | 1991-11-05 |
ZA911294B (en) | 1992-10-28 |
AU7134591A (en) | 1991-09-12 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |