ZA911294B - Catalyst and prepolymer used for polymerising olefins,and (co-)polymer of ethylene obtainable therefrom - Google Patents

Catalyst and prepolymer used for polymerising olefins,and (co-)polymer of ethylene obtainable therefrom

Info

Publication number
ZA911294B
ZA911294B ZA911294A ZA911294A ZA911294B ZA 911294 B ZA911294 B ZA 911294B ZA 911294 A ZA911294 A ZA 911294A ZA 911294 A ZA911294 A ZA 911294A ZA 911294 B ZA911294 B ZA 911294B
Authority
ZA
South Africa
Prior art keywords
catalyst
prepolymer
ethylene
olefins
solid catalyst
Prior art date
Application number
ZA911294A
Other languages
English (en)
Inventor
Jean-Claude Andre Bailly
Andre Bailly Jean-Claude
Christine Jacqueline Charand
Jacqueline Charand Christine
Original Assignee
Bp Chem Int Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bp Chem Int Ltd filed Critical Bp Chem Int Ltd
Publication of ZA911294B publication Critical patent/ZA911294B/xx

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C08F4/74Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals
    • C08F4/76Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals selected from titanium, zirconium, hafnium, vanadium, niobium or tantalum
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65904Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
ZA911294A 1990-03-12 1991-02-21 Catalyst and prepolymer used for polymerising olefins,and (co-)polymer of ethylene obtainable therefrom ZA911294B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9003368A FR2659337B1 (fr) 1990-03-12 1990-03-12 Procede de preparation d'un catalyseur a base de zirconium, de titane et/ou de vanadium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines.

Publications (1)

Publication Number Publication Date
ZA911294B true ZA911294B (en) 1992-10-28

Family

ID=9394799

Family Applications (1)

Application Number Title Priority Date Filing Date
ZA911294A ZA911294B (en) 1990-03-12 1991-02-21 Catalyst and prepolymer used for polymerising olefins,and (co-)polymer of ethylene obtainable therefrom

Country Status (17)

Country Link
EP (1) EP0447070B1 (fr)
JP (1) JPH04220406A (fr)
KR (1) KR910016782A (fr)
CN (1) CN1054776A (fr)
AT (1) ATE121758T1 (fr)
AU (1) AU640452B2 (fr)
CA (1) CA2036767A1 (fr)
CS (1) CS63391A2 (fr)
DE (1) DE69109161T2 (fr)
ES (1) ES2071211T3 (fr)
FI (1) FI911215A (fr)
FR (1) FR2659337B1 (fr)
HU (1) HUT60296A (fr)
NO (1) NO177389C (fr)
PL (1) PL289376A1 (fr)
PT (1) PT97007B (fr)
ZA (1) ZA911294B (fr)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2659336B1 (fr) * 1990-03-12 1993-05-07 Bp Chemicals Snc Catalyseur a base de zirconium, de titane et/ou de vanadium, supporte sur un chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines.
WO1994004578A1 (fr) * 1992-05-28 1994-03-03 Idemitsu Petrochemical Co., Ltd. Procede de production de polyolefine
EP0578838A1 (fr) * 1992-04-29 1994-01-19 Hoechst Aktiengesellschaft Catalysateur de polymérisation d'oléfines, procédé pour sa préparation et son utilisation
TW298593B (fr) * 1993-02-12 1997-02-21 Hoechst Ag
EP0724604B2 (fr) * 1993-10-21 2005-12-14 Exxonmobil Oil Corporation Melanges de polyolefines a repartition bimodale de poids moleculaires
IT1269931B (it) * 1994-03-29 1997-04-16 Spherilene Srl Componenti e catalizzatori per la polimerizzazione di olefine
DE69518104T2 (de) * 1994-04-07 2000-12-14 Bp Chem Int Ltd Polymerisationsverfahren
IT1270070B (it) 1994-07-08 1997-04-28 Spherilene Srl Componenti e catalizzatori per la polimerizzazione di olefine
US5622906A (en) * 1994-09-16 1997-04-22 Phillips Petroleum Company Compositions useful for olefin polymerization and processes therefor and therewith
US5529965A (en) * 1994-10-28 1996-06-25 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
US5714424A (en) * 1995-01-09 1998-02-03 W. R. Grace & Co.-Conn. Multi-component polyolefin catalysts
US5882750A (en) * 1995-07-03 1999-03-16 Mobil Oil Corporation Single reactor bimodal HMW-HDPE film resin with improved bubble stability
FR2738829B1 (fr) 1995-09-19 1997-10-17 Atochem Elf Sa Prepolymere pour la polymerisation des olefines, associant plusieurs composantes catalytiques solides
ES2129323B1 (es) * 1996-04-18 2000-09-16 Repsol Quimica Sa Procedimiento para la obtencion de un sistema catalitico para la polimerizacion de alpha-olefinas en suspension en fase gas a bajas y altas temperaturas o en masa a altas presiones y altas o bajas temperaturas
AU2411797A (en) * 1996-05-03 1997-11-26 Dsm N.V. A process for making polyolefins having broad molecular weight distributions
US6136747A (en) * 1998-06-19 2000-10-24 Union Carbide Chemicals & Plastics Technology Corporation Mixed catalyst composition for the production of olefin polymers
CN1096474C (zh) 1998-12-30 2002-12-18 化学工业部北京化工研究院 用于合成宽分布乙烯聚合物的复合催化剂及其制法和应用
US6265037B1 (en) 1999-04-16 2001-07-24 Andersen Corporation Polyolefin wood fiber composite
DE19962129A1 (de) 1999-12-21 2001-06-28 Targor Gmbh Verfahren zur Herstellung eines Katalysatorfeststoffs zur Olefinpolymerisation
US6703458B2 (en) 2000-12-22 2004-03-09 Basell Polyolefine Gmbh Catalyst components for the polymerization of olefins
CA2874344C (fr) 2014-12-15 2021-08-31 Nova Chemicals Corporation Catalyseur spheroide de polymerisation d'olefines
CA2890606C (fr) 2015-05-07 2022-07-19 Nova Chemicals Corporation Procede de polymerisation au moyen de catalyseur de type ziegler-natta spherique dense

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1268754A (fr) * 1985-06-21 1990-05-08 Howard Curtis Welborn, Jr. Catalyseur de polymerisation sur support
US4659685A (en) * 1986-03-17 1987-04-21 The Dow Chemical Company Heterogeneous organometallic catalysts containing a supported titanium compound and at least one other supported organometallic compound
IT1221654B (it) * 1987-11-27 1990-07-12 Ausimont Spa Catalizzatori per la polimerizzazione delle olefine
FR2656315B1 (fr) * 1989-12-22 1992-04-17 Bp Chemicals Snc Procede de preparation d'un catalyseur a base de zirconium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines.
FR2656314B1 (fr) * 1989-12-22 1992-04-17 Bp Chemicals Snc Catalyseur a base de zirconium supporte sur du chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines.
FR2659336B1 (fr) * 1990-03-12 1993-05-07 Bp Chemicals Snc Catalyseur a base de zirconium, de titane et/ou de vanadium, supporte sur un chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines.

Also Published As

Publication number Publication date
NO910954D0 (no) 1991-03-11
PL289376A1 (en) 1992-03-09
HUT60296A (en) 1992-08-28
CA2036767A1 (fr) 1991-09-13
CS63391A2 (en) 1991-10-15
JPH04220406A (ja) 1992-08-11
ATE121758T1 (de) 1995-05-15
DE69109161T2 (de) 1995-08-31
HU910791D0 (en) 1991-09-30
AU640452B2 (en) 1993-08-26
NO177389C (no) 1995-09-06
CN1054776A (zh) 1991-09-25
EP0447070A1 (fr) 1991-09-18
ES2071211T3 (es) 1995-06-16
PT97007B (pt) 1998-07-31
FI911215A (fi) 1991-09-13
NO177389B (no) 1995-05-29
FI911215A0 (fi) 1991-03-12
EP0447070B1 (fr) 1995-04-26
PT97007A (pt) 1991-10-31
DE69109161D1 (de) 1995-06-01
FR2659337A1 (fr) 1991-09-13
NO910954L (no) 1991-09-13
KR910016782A (ko) 1991-11-05
FR2659337B1 (fr) 1992-06-05
AU7134591A (en) 1991-09-12

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