ES2162473T3 - Procedimiento para preparar fosfinas ciclicas. - Google Patents
Procedimiento para preparar fosfinas ciclicas.Info
- Publication number
- ES2162473T3 ES2162473T3 ES98952862T ES98952862T ES2162473T3 ES 2162473 T3 ES2162473 T3 ES 2162473T3 ES 98952862 T ES98952862 T ES 98952862T ES 98952862 T ES98952862 T ES 98952862T ES 2162473 T3 ES2162473 T3 ES 2162473T3
- Authority
- ES
- Spain
- Prior art keywords
- phosphins
- procedure
- prepare cyclic
- phosphine
- alkylating agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 abstract 6
- 229910000073 phosphorus hydride Inorganic materials 0.000 abstract 3
- 229940100198 alkylating agent Drugs 0.000 abstract 2
- 239000002168 alkylating agent Substances 0.000 abstract 2
- 230000029936 alkylation Effects 0.000 abstract 1
- 238000005804 alkylation reaction Methods 0.000 abstract 1
- 230000001588 bifunctional effect Effects 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 125000004122 cyclic group Chemical group 0.000 abstract 1
- 238000006073 displacement reaction Methods 0.000 abstract 1
- 125000000524 functional group Chemical group 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/505—Preparation; Separation; Purification; Stabilisation
- C07F9/5063—Preparation; Separation; Purification; Stabilisation from compounds having the structure P-H or P-Heteroatom, in which one or more of such bonds are converted into P-C bonds
- C07F9/5072—Preparation; Separation; Purification; Stabilisation from compounds having the structure P-H or P-Heteroatom, in which one or more of such bonds are converted into P-C bonds from starting materials having the structure P-H
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
- C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
- C07F9/65683—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms the ring phosphorus atom being part of a phosphine
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Crystallography & Structural Chemistry (AREA)
Abstract
Procedimiento para la preparación de una fosfina cíclica a partir de la fosfina primaria correspondiente y un agente alquilante bifuncional, donde la alquilación, y el desplazamiento de cada uno de los grupos funcionales, tiene lugar en presencia de una base fuerte, que comprende añadir la base fuerte, en una cantidad suficiente para la ciclización, a una mezcla o producto de reacción, preformados, de la fosfina primaria y el agente alquilante.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB9723583.2A GB9723583D0 (en) | 1997-11-07 | 1997-11-07 | Process for cyclic phosphines |
US6867597P | 1997-12-24 | 1997-12-24 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2162473T3 true ES2162473T3 (es) | 2001-12-16 |
Family
ID=26312567
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES98952862T Expired - Lifetime ES2162473T3 (es) | 1997-11-07 | 1998-11-05 | Procedimiento para preparar fosfinas ciclicas. |
Country Status (9)
Country | Link |
---|---|
US (1) | US6545183B1 (es) |
EP (1) | EP1028967B1 (es) |
JP (1) | JP4397524B2 (es) |
AT (1) | ATE206128T1 (es) |
AU (1) | AU1041099A (es) |
CA (1) | CA2307192A1 (es) |
DE (1) | DE69801841T2 (es) |
ES (1) | ES2162473T3 (es) |
WO (1) | WO1999024444A1 (es) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003531098A (ja) * | 1998-06-30 | 2003-10-21 | カイロテック・テクノロジー・リミテッド | アリールホスフィンの調製 |
GB9814170D0 (en) | 1998-06-30 | 1998-08-26 | Chirotech Technology Ltd | The preparation of arylphosphines |
GB9823716D0 (en) * | 1998-10-29 | 1998-12-23 | Isis Innovation | Diphosphines |
KR20010086436A (ko) * | 1998-11-05 | 2001-09-12 | 마르크 젠너 | 비대칭 촉매반응용 키랄 리간드 |
CA2428778A1 (en) | 2000-12-13 | 2002-06-20 | Warner-Lambert Company Llc | P-chirale bisphospholane ligands, their transition metal complexes |
DE10106348A1 (de) * | 2001-02-09 | 2002-08-14 | Basf Ag | Als Katalysator oder zur Herstellung eines Katalysatorsystems geeignete Verbindung |
US7169953B2 (en) * | 2001-11-09 | 2007-01-30 | The Penn State Research Foundation | P-chiral phospholanes and phosphocyclic compounds and their use in asymmetric catalytic reactions |
EP1451133B1 (en) * | 2001-11-09 | 2017-10-25 | The Penn State Research Foundation | P-chiral phospholanes and phosphocyclic compounds and their use in asymmetric catalytic reactions |
ITMI20020415A1 (it) * | 2002-03-01 | 2003-09-01 | Chemi Spa | Catalizzatori metallici per reazione chemo- regio- stereo-selettive erelativi precursori |
US7411096B2 (en) * | 2003-07-28 | 2008-08-12 | Nippon Chemical Industrial Co., Ltd. | Process for producing optically active phosphorus heterocyclic dimer |
DE10353831A1 (de) * | 2003-11-18 | 2005-06-23 | Degussa Ag | Verfahren zur Herstellung von Bisphospholanliganden |
US7767833B2 (en) * | 2004-08-12 | 2010-08-03 | Sigma-Aldrich Co. | Stabilized borane-tetrahydrofuran complex |
EP1874711A2 (en) * | 2005-04-22 | 2008-01-09 | Dow Gloval Technologies Inc. | Asymmetric hydroformylation process |
US7750168B2 (en) * | 2006-02-10 | 2010-07-06 | Sigma-Aldrich Co. | Stabilized deuteroborane-tetrahydrofuran complex |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5171892A (en) * | 1991-07-02 | 1992-12-15 | E. I. Du Pont De Nemours And Company | Chiral phospholanes via chiral 1,4-diol cyclic sulfates |
DE4141299C2 (de) | 1991-12-14 | 2000-09-21 | Celanese Chem Europe Gmbh | Verfahren zur Herstellung von tertiären Phosphanen |
US5399771A (en) | 1994-06-01 | 1995-03-21 | Merck & Co., Inc. | Process of synthesizing binaphthyl derivatives |
ATE223924T1 (de) | 1996-07-15 | 2002-09-15 | Chirotech Technology Ltd | Liganden für asymmetrische katalysen |
-
1998
- 1998-05-11 US US09/530,845 patent/US6545183B1/en not_active Expired - Lifetime
- 1998-11-05 AT AT98952862T patent/ATE206128T1/de not_active IP Right Cessation
- 1998-11-05 AU AU10410/99A patent/AU1041099A/en not_active Abandoned
- 1998-11-05 CA CA002307192A patent/CA2307192A1/en not_active Abandoned
- 1998-11-05 WO PCT/GB1998/003321 patent/WO1999024444A1/en active IP Right Grant
- 1998-11-05 ES ES98952862T patent/ES2162473T3/es not_active Expired - Lifetime
- 1998-11-05 JP JP2000520453A patent/JP4397524B2/ja not_active Expired - Fee Related
- 1998-11-05 DE DE69801841T patent/DE69801841T2/de not_active Expired - Lifetime
- 1998-11-05 EP EP98952862A patent/EP1028967B1/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
AU1041099A (en) | 1999-05-31 |
ATE206128T1 (de) | 2001-10-15 |
EP1028967A1 (en) | 2000-08-23 |
EP1028967B1 (en) | 2001-09-26 |
DE69801841T2 (de) | 2002-05-16 |
US6545183B1 (en) | 2003-04-08 |
JP4397524B2 (ja) | 2010-01-13 |
WO1999024444A1 (en) | 1999-05-20 |
CA2307192A1 (en) | 1999-05-20 |
JP2001522855A (ja) | 2001-11-20 |
DE69801841D1 (de) | 2001-10-31 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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