HUP9903962A2 - A 13. csoport vegyületét tartalmazó olefin polimerizációs katalizátorkészítmények - Google Patents

A 13. csoport vegyületét tartalmazó olefin polimerizációs katalizátorkészítmények

Info

Publication number
HUP9903962A2
HUP9903962A2 HU9903962A HUP9903962A HUP9903962A2 HU P9903962 A2 HUP9903962 A2 HU P9903962A2 HU 9903962 A HU9903962 A HU 9903962A HU P9903962 A HUP9903962 A HU P9903962A HU P9903962 A2 HUP9903962 A2 HU P9903962A2
Authority
HU
Hungary
Prior art keywords
regardless
catalyst
compound
tube
substituted silyl
Prior art date
Application number
HU9903962A
Other languages
English (en)
Inventor
Robert K. Rosen
James C. Stevens
Original Assignee
The Dow Chemical Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Dow Chemical Company filed Critical The Dow Chemical Company
Publication of HUP9903962A2 publication Critical patent/HUP9903962A2/hu
Publication of HUP9903962A3 publication Critical patent/HUP9903962A3/hu
Publication of HU223376B1 publication Critical patent/HU223376B1/hu

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/49—Hafnium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

A találmány tárgya katalizátőrkészítmény, amely az alábbiak együtteséttartalmazza. a) egy L1MXpX'q általánős képletű fémkőmplex, amelyet egyaktiváló kőkatalizátőrral történő egyesítéssel vagy egy aktiválásimódszer alkalmazásával katalitikűsan aktívvá tettek vagy tesznek, ésahől M jelentése az elemek periódűsős rendszerének 4. csőpőrtjába tartőzófém, amelynek őxidációs állapőta +2, +3 vagy +4, amely egy vagy több Lcsőpőrthőz h5 helyzetben kapcsőlódik; L jelentése - függetlenül egyes előfőrdűlásainál -, adőtt esetbenszűbsztitűált ciklőpentadienil-, indenil-, tetrahidrőindenil-,flűőrenil-, tetrahidrőflűőrenil- vagy őktahidrőflűőrenilcsőpőrt, vagytővábbá adőtt esetben két ilyen L csőpőrt egy kétértékűszűbsztitűenssel kapcsőlódhat össze, amelyet az alábbiak közülválasztanak; hidrőkarbadiil-, halőhidrőkarbadiil-, hidrőkarbilén-őxi-,hidrőkarbilén-aminő-, sziladiil- halősziladiil- és kétértékű aminő-szilán-csőpőrt; X jelentése - függetlenül egyes előfőrdűlásainál - egy egyértékűaniőnős, s-kötéssel kapcsőlódó ligandűmcsőpőrt, amely egyikvegyértékével az M-hez kapcsőlódik, egy vegyértékével pedig egy L-csőpőrthőz; X' jelentése - függetlenül egyes előfőrdűlásainál - egy semlegesLewis-bázis ligandűmképző vegyület; l értéke 1 vagy 2; p értéke - bizőnyős megkötések mellett - 0, 1 vagy 2; és q értéke 0, 1 vagy 2; és b) egy R12Me(NR22) általánős képletűvegyület, ahől R1 és R2 jelentése - függetlenül egyes előfőrdűlásainál - egyhidrőkarbil-, szilil-, halőkarbil-, halőhidrőkarbil-, hidrőkarbil-szűbsztitűált szilil-, halőkarbil-szűbsztitűált szilil- vagyhalőhidrőkarbil-szűbsztitűált szililcsőpőrt; és Me jelentése egy 13. csőpőrtba tartőzó fém, az a) : b) mólaránya (1 : 0,1) - (1 : 100), vagy a keletkezőszármazékőt, reakcióterméket vagy egyensúlyi keveréket, amely az ilyenvegyületek egyesítéséből származik. A találmány szerinti eljárásban, afenti katalizátőrkészítményt tartalmazó katalizátőrrendszerjelenlétében addíciósan pőlimerizálható mőnőmereket vagy azők elegyeitpőlimerizálják. ŕ
HU9903962A 1996-07-23 1997-07-18 A 13. csoport vegyületét tartalmazó olefin polimerizációs katalizátor készítmények HU223376B1 (hu)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US2206196P 1996-07-23 1996-07-23
PCT/US1997/012649 WO1998003558A1 (en) 1996-07-23 1997-07-18 Olefin polymerization catalyst composition comprising group 13 compound

Publications (3)

Publication Number Publication Date
HUP9903962A2 true HUP9903962A2 (hu) 2000-03-28
HUP9903962A3 HUP9903962A3 (en) 2000-06-28
HU223376B1 HU223376B1 (hu) 2004-06-28

Family

ID=21807620

Family Applications (1)

Application Number Title Priority Date Filing Date
HU9903962A HU223376B1 (hu) 1996-07-23 1997-07-18 A 13. csoport vegyületét tartalmazó olefin polimerizációs katalizátor készítmények

Country Status (17)

Country Link
US (1) US6017842A (hu)
EP (1) EP0914353B1 (hu)
JP (1) JP2000514858A (hu)
KR (1) KR100466733B1 (hu)
CN (1) CN1092668C (hu)
AR (1) AR010516A1 (hu)
AU (1) AU718544B2 (hu)
BR (1) BR9710511A (hu)
CA (1) CA2261174C (hu)
CZ (1) CZ293472B6 (hu)
DE (1) DE69715213T2 (hu)
ES (1) ES2177995T3 (hu)
HU (1) HU223376B1 (hu)
PL (1) PL331324A1 (hu)
TR (1) TR199900080T2 (hu)
TW (1) TW434271B (hu)
WO (1) WO1998003558A1 (hu)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6294625B1 (en) * 1990-03-20 2001-09-25 Exxonmobil Chemical Patents Inc. Catalyst system of enhanced productivity and its use in polymerization process
KR100422025B1 (ko) * 1997-12-01 2004-03-10 아사히 가세이 가부시키가이샤 올레핀 중합용 촉매 및 상기 촉매를 사용한 올레핀의 중합방법
CA2330529A1 (en) 1998-06-12 1999-12-16 Univation Technologies Llc Olefin polymerization process using activated lewis acid-base complexes
AU743367B2 (en) 1998-07-16 2002-01-24 Univation Technologies Llc Aluminum-based lewis acid cocatalysts for olefin polymerization
JP4357747B2 (ja) 1998-08-17 2009-11-04 ダウ グローバル テクノロジーズ インコーポレーテッド アルミニウム化合物混合物を含む活性剤組成物
DE69905728T2 (de) * 1998-08-17 2003-12-24 Dow Global Technologies Inc Drei-koordinierte alluminium-katalysatoraktivatorverbindung
US6559088B1 (en) * 1999-02-22 2003-05-06 Fina Technology, Inc. Ziegler-Natta catalyst with amine for polymerization
BE1012568A3 (fr) * 1999-03-24 2000-12-05 Solvay Procede pour la polymerisation des alphaolefines.
US6476164B1 (en) 1999-10-22 2002-11-05 Exxonmobil Chemical Patents Inc. Carbenium cationic complexes suitable for polymerization catalysts
US6475946B1 (en) 1999-10-22 2002-11-05 Exxonmobil Chemical Patents Inc. Olefin polymerization catalysis with aryl substituted carbenium cationic complexes
JP2004500359A (ja) * 1999-12-09 2004-01-08 エクソンモービル・ケミカル・パテンツ・インク １５族化合物から誘導されるオレフィン重合助触媒及びその使用法
US6489480B2 (en) 1999-12-09 2002-12-03 Exxonmobil Chemical Patents Inc. Group-15 cationic compounds for olefin polymerization catalysts
US6822057B2 (en) 1999-12-09 2004-11-23 Exxon Mobil Chemical Patents Inc. Olefin polymerization catalysts derived from Group-15 cationic compounds and processes using them
MXPA02006197A (es) 1999-12-20 2002-12-09 Exxon Chemical Patents Inc Procesos para la preparacion de resinas de poliolefinas usando catalizadores ionicos soportados.
JP2002293818A (ja) * 2001-03-30 2002-10-09 Sumitomo Chem Co Ltd オレフィン重合用触媒、およびオレフィン重合体の製造方法
US7541402B2 (en) * 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
CA2499951C (en) * 2002-10-15 2013-05-28 Peijun Jiang Multiple catalyst system for olefin polymerization and polymers produced therefrom
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
CA2506144C (en) * 2002-12-13 2011-09-20 Dow Global Technologies Inc. Olefin polymerization catalyst composition comprising group 13 amide derivatives
CN103102442B (zh) * 2004-06-16 2016-01-20 陶氏环球技术有限责任公司 选择聚合改性剂的方法
KR101084677B1 (ko) * 2008-05-14 2011-11-22 주식회사 엘지화학 올레핀 중합체의 제조방법
CN104677777B (zh) * 2013-11-29 2017-10-27 中国石油化工股份有限公司 岩石残余含气量测试装置及其测试方法
WO2016180539A1 (en) * 2015-05-13 2016-11-17 Sasol Performance Chemicals Gmbh PROCESS FOR THE MANUFACTURE OF A ZIRCONIUM GUANIDINATO ALKYL COMPOUND AND A DI-μ-HALOGEN-BRIDGED BIS GUANIDINATO TETRAHALOGEN DI ZIRCONIUM COMPOUND
KR20240052979A (ko) * 2021-09-10 2024-04-23 다우 글로벌 테크놀로지스 엘엘씨 폴리올레핀 생산용 보레이트 공촉매
KR20240052978A (ko) * 2021-09-10 2024-04-23 다우 글로벌 테크놀로지스 엘엘씨 올레핀 중합용 탄화수소 가용성 보레이트 공촉매

Family Cites Families (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3311604A (en) * 1961-02-04 1967-03-28 Snam Spa Process for polymerizing isoprene with a catalyst consisting of titanium tetrachloride and an aluminum hydride
US3255169A (en) * 1961-05-03 1966-06-07 Exxon Research Engineering Co Aluminum hydroaminate activators in olefin polymerization
US3624118A (en) * 1961-08-09 1971-11-30 Olin Mathieson Reaction products of alkali metal amides and trialkyl aluminum compounds
NL126040C (hu) * 1963-05-24
NL129055C (hu) * 1965-02-03 1900-01-01
NL125866C (hu) * 1965-02-03
NL129054C (hu) * 1965-02-03
NL125867C (hu) * 1965-02-03
US3489736A (en) * 1965-04-23 1970-01-13 Showa Denko Kk Polymerization of olefins
US3723348A (en) * 1967-03-20 1973-03-27 Du Pont Coordination catalyst
BE759186A (fr) * 1969-11-26 1971-05-21 Inst Francais Du Petrole Nouveaux catalyseurs de deshydrogenation des alcools secondaires
DE2110195C3 (de) * 1970-03-11 1975-07-31 Snam Progetti S.P.A., Mailand (Italien) Aluminiumverbindung, Verfahren zu ihrer Herstellung und ihre Verwendung bei der Polymerisation von Olefinen, konjugierten oder nicht-konjugierten Dienen oder Gemischen davon
IT953411B (it) * 1972-02-15 1973-08-10 Snam Progetti Produzione di lubrificanti sinteti ci da alfa olefine con un sistema catalitico ternario
US4094818A (en) * 1977-02-11 1978-06-13 Exxon Research & Engineering Co. Ziegler type catalyst system
US4224182A (en) * 1979-03-07 1980-09-23 Exxon Research & Engineering Co. Novel hindered alkyl aluminum amide cocatalysts
US5096867A (en) * 1990-06-04 1992-03-17 Exxon Chemical Patents Inc. Monocyclopentadienyl transition metal olefin polymerization catalysts
US5055438A (en) * 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
NZ235032A (en) * 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5057475A (en) * 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
US5064802A (en) * 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
BE1003968A3 (fr) * 1990-11-08 1992-07-28 Solvay Solide catalytique utilisable pour la polymerisation stereospecifique des alpha-olefines, procede pour le preparer et procede pour polymeriser des alpha-olefines en sa presence
JP3275211B2 (ja) * 1991-05-20 2002-04-15 ザ ダウ ケミカル カンパニー 付加重合触媒の製造方法
US5721185A (en) * 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
ES2165562T3 (es) * 1992-01-06 2002-03-16 Dow Chemical Co Composicion catalitica mejorada.
US5374696A (en) * 1992-03-26 1994-12-20 The Dow Chemical Company Addition polymerization process using stabilized reduced metal catalysts
US5296433A (en) * 1992-04-14 1994-03-22 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
US6313240B1 (en) * 1993-02-22 2001-11-06 Tosoh Corporation Process for producing ethylene/α-olefin copolymer
US5470993A (en) * 1993-06-24 1995-11-28 The Dow Chemical Company Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom
US5539069A (en) * 1993-08-10 1996-07-23 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalysts and methods of olefin polymerization
US5486632A (en) * 1994-06-28 1996-01-23 The Dow Chemical Company Group 4 metal diene complexes and addition polymerization catalysts therefrom

Also Published As

Publication number Publication date
HU223376B1 (hu) 2004-06-28
BR9710511A (pt) 1999-08-17
CZ23999A3 (cs) 1999-04-14
AU718544B2 (en) 2000-04-13
PL331324A1 (en) 1999-07-05
CN1092668C (zh) 2002-10-16
TW434271B (en) 2001-05-16
JP2000514858A (ja) 2000-11-07
CN1225644A (zh) 1999-08-11
CZ293472B6 (cs) 2004-05-12
EP0914353A1 (en) 1999-05-12
US6017842A (en) 2000-01-25
EP0914353B1 (en) 2002-09-04
TR199900080T2 (xx) 1999-04-21
KR100466733B1 (ko) 2005-01-24
CA2261174C (en) 2005-11-29
AU3805197A (en) 1998-02-10
KR20000067938A (ko) 2000-11-25
WO1998003558A1 (en) 1998-01-29
ES2177995T3 (es) 2002-12-16
DE69715213D1 (de) 2002-10-10
CA2261174A1 (en) 1998-01-29
DE69715213T2 (de) 2003-04-30
AR010516A1 (es) 2000-06-28
HUP9903962A3 (en) 2000-06-28

Similar Documents

Publication Publication Date Title
HUP9903962A2 (hu) A 13. csoport vegyületét tartalmazó olefin polimerizációs katalizátorkészítmények
HUP9802868A2 (hu) Szubsztituált indenilcsoportot tartalmazó fémkomplexek és eljárás olefinek polimerizálására
HUP0104654A2 (hu) Hidas szerkezetű fémkomplexek
HUP9801224A2 (hu) Hordozós katalizátorkomponens, valamint eljárás előállítására, hordozós katalizátor, polimerizálási eljárás, komplex vegyületek, továbbá eljárás azok előállítására
FI114157B (fi) Titaani(II)- tai sirkonium(II)-komplekseja ja niistä valmistettuja additiopolymerointikatalyyttejä
EP0842939A4 (en) TRANSITION METAL COMPLEX, METHOD FOR THE PRODUCTION THEREOF, THE COMPLEX CONTAINING POLYMERIZATION CATALYST, AND METHOD FOR THE PRODUCTION OF OLEFIN POLYMERS
NZ333878A (en) 3-heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process
ES446441A1 (es) Procedimiento para preparar componentes de catalizadores u- tiles para polimerizar olefinas.
ES2188235T3 (es) Complejos metalicos puenteados para polimerizaciones en fase gaseosa.
EP0643066A3 (en) Monocyclopentadienyl transition metal olefin polymerization catalysts
NO306679B1 (no) Fast organo-aluminoksyprodukt, fremgangsmÕte til dets fremstilling, olefinpolymerisasjonskatalysatorsystem og fremgangsmÕte til fremstilling av en polymer
FI863216A0 (fi) Polymerisation av olefiner under anvaendning av en ziegler-natta-katalysator och tvao metallorganiska foereningar.
CA2068938A1 (en) Preparation of addition polymerization catalysts
WO2003033545A3 (en) Metal complex compositions and their use as catalysts to produce polydienes
NZ333877A (en) metal complex of a substituted indene derivative and use of the complex in an olefin polymerization process
JPS5340696A (en) Olefin polymerization catalyst
JPS5274686A (en) Process for polymerizing olefins
JPS6466214A (en) Production of alpha-olefin polymer
JPS5628206A (en) Polymerization of ethylene
PT1225179E (pt) Catalisadores de polimerizacao de olefinas
JPS5690810A (en) Production of polyethylene
JPS5759915A (en) Preparation of highly stereoregular alpha-olefinic polymer
JPS5659806A (en) Polymerization of ethylene
JPS5456994A (en) Polymerization catalyst for alpha-olefin
JPS5759914A (en) Preparation of highly stereoregular alpha-olefinic polymer

Legal Events

Date Code Title Description
HFG4 Patent granted, date of granting

Effective date: 20040429

MM4A Lapse of definitive patent protection due to non-payment of fees