NZ333877A - metal complex of a substituted indene derivative and use of the complex in an olefin polymerization process - Google Patents

metal complex of a substituted indene derivative and use of the complex in an olefin polymerization process

Info

Publication number
NZ333877A
NZ333877A NZ333877A NZ33387797A NZ333877A NZ 333877 A NZ333877 A NZ 333877A NZ 333877 A NZ333877 A NZ 333877A NZ 33387797 A NZ33387797 A NZ 33387797A NZ 333877 A NZ333877 A NZ 333877A
Authority
NZ
New Zealand
Prior art keywords
metal complex
complex
groups
olefin polymerization
independently
Prior art date
Application number
NZ333877A
Inventor
Jerzy Klosin
William J Kruper
Peter N Nickias
Jasson T Patton
David R Wilson
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of NZ333877A publication Critical patent/NZ333877A/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/10—Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Abstract

The metal complex has the formula I wherein: M is Ti, Zr or Hf; j is 1 or 2; each RA is independently optionally substituted hydrocarbyl or hydrocarbylsilyl having up to 80 non-hydrogen atoms or two RA groups can be covalently linked with each other to form one or more fused rings or ring systems; RB, RW, RX, RY and RZ independently are H or optionally substituted hydrocarbyl, hydrocarbylsilyl having up to 80 non-hydrogen atoms or two or more of RB, RW, RX, RY and RZ groups can be covalently linked with each other to form one or more fused rings or ring systems; Z is a divalent moiety bound to both Cp and M via s-bonds with Z being boron or a member of group 14 of the periodic table of elements or nitrogen, phosphorus, sulphur or oxygen; X is anionic or di-anionic ligand group of up to 60 atoms exclusive of the class of ligands that are cyclic, delocalised p-bound ligands groups; each X' is independently a neutral lewis base ligating compound of up to 20 atoms; p is 0 to 2 and is two less than the formal oxidation state of M when X is an anionic ligand or when X is a di-anionic ligand group p is 1 and q is 0 to 2. The metal complex is used in a catalyst system for olefin polymerization which also contains a co-catalyst.
NZ333877A 1996-08-08 1997-07-28 metal complex of a substituted indene derivative and use of the complex in an olefin polymerization process NZ333877A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US2376896P 1996-08-08 1996-08-08
PCT/US1997/013171 WO1998006728A1 (en) 1996-08-08 1997-07-28 2-heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process

Publications (1)

Publication Number Publication Date
NZ333877A true NZ333877A (en) 2000-08-25

Family

ID=21817090

Family Applications (1)

Application Number Title Priority Date Filing Date
NZ333877A NZ333877A (en) 1996-08-08 1997-07-28 metal complex of a substituted indene derivative and use of the complex in an olefin polymerization process

Country Status (21)

Country Link
EP (1) EP1021454A1 (en)
JP (1) JP2000516608A (en)
KR (1) KR20000029853A (en)
CN (1) CN1231668A (en)
AR (1) AR009034A1 (en)
AU (1) AU716659B2 (en)
BR (1) BR9711115A (en)
CA (1) CA2262377A1 (en)
CO (1) CO4870709A1 (en)
CZ (1) CZ42499A3 (en)
HU (1) HUP9904148A3 (en)
ID (1) ID18005A (en)
NO (1) NO990546L (en)
NZ (1) NZ333877A (en)
PL (1) PL331526A1 (en)
RU (1) RU2196776C2 (en)
SA (1) SA97180735B1 (en)
SK (1) SK15299A3 (en)
TR (1) TR199900589T2 (en)
WO (1) WO1998006728A1 (en)
ZA (2) ZA976999B (en)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI971565A (en) * 1997-04-14 1998-10-15 Borealis As Substituted metallocene compounds for catalyst systems intended for polymerization of olefins, intermediates and processes for their preparation
DE19809159A1 (en) * 1998-03-04 1999-09-09 Bayer Ag Organometallic compounds
US6326493B1 (en) * 1999-01-25 2001-12-04 Chisso Corporation Metallocene compounds, processes for the preparation thereof, catalyst components for olefin polymerization, and processes for the production of olefin polymers
EP1177198B1 (en) 1999-04-29 2002-11-20 Dow Global Technologies Inc. Bis(n,n-dihydrocarbylamino)- substituted cyclopentadienes and metal complexes thereof
DE60001557T2 (en) 1999-05-13 2004-01-08 Dow Global Technologies, Inc., Midland METAL COMPLEXES WITH HETEROATOM-CONTAINING BRIDGE FOR OLEFIN POLYMERIZATION PROCESSES
AU3764600A (en) 1999-05-13 2000-12-05 Dow Chemical Company, The Di- and tri-heteroatom substituted indenyl metal complexes
WO2000075146A1 (en) 1999-06-04 2000-12-14 The Dow Chemical Company Boron-substituted cyclopentadienes and metal complexes thereof
US6825295B2 (en) 1999-12-10 2004-11-30 Dow Global Technologies Inc. Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process
EP1253158A1 (en) * 1999-12-10 2002-10-30 Dow Global Technologies Inc. Substituted group 4 metal complexes, catalysts and olefin polymerization process
EP1242471B1 (en) * 1999-12-10 2012-02-29 Dow Global Technologies LLC Substituted group 4 metal complexes, catalysts and olefin polymerization process
JP2003520869A (en) 2000-01-18 2003-07-08 バセル テクノロジー カンパニー ビー．ブイ． Process for producing a substantially amorphous propylene-based polymer
GB0001232D0 (en) * 2000-01-19 2000-03-08 Borealis Polymers Oy Polymerisation catalysts
WO2001053362A1 (en) * 2000-01-19 2001-07-26 Borealis Technology Oy Metallocene catalysts comprising monocyclic siloxy substituted cyclopentadienyl group(s) for the polymerisation of olefins
JP4062929B2 (en) 2002-02-08 2008-03-19 住友化学株式会社 Transition metal complex, ligand, catalyst for olefin polymerization, and method for producing olefin polymer
CA2477776C (en) 2002-03-14 2011-11-15 Dow Global Technologies Inc. Substituted indenyl metal complexes and polymerization process
US6927264B2 (en) 2003-05-28 2005-08-09 Dow Global Technologies Inc. Metal complexes and polymerization process using same
KR101678247B1 (en) 2009-07-28 2016-11-21 유니베이션 테크놀로지즈, 엘엘씨 Polymerization process using a supported constrained geometry catalyst
WO2012036164A1 (en) * 2010-09-15 2012-03-22 株式会社日本触媒 Composition usable as heat-latent polymerization initiator
CN102101897B (en) * 2010-12-24 2013-02-06 上海化工研究院 Heterocyclic-side-chain-containing metallocene catalyst and application thereof in olefinic polymerization
KR101791810B1 (en) 2014-03-21 2017-10-30 엑손모빌 케미칼 패턴츠 인코포레이티드 Process to produce ethylene propylene copolymers
CN107107025A (en) 2015-01-06 2017-08-29 Scg化学有限公司 SiO2Layered double-hydroxide microballoon and their preparation method
KR102010630B1 (en) * 2016-01-20 2019-08-13 한화토탈 주식회사 Catalyst for olefin polymerization and olefin polymerization method thereof
GB201608384D0 (en) 2016-05-12 2016-06-29 Scg Chemicals Co Ltd Unsymmetrical metallocene catalysts and uses thereof
WO2018175073A1 (en) * 2017-03-23 2018-09-27 Exxonmobil Chemical Patents Inc. Catalyst systems and methods for preparing and using the same
KR102643986B1 (en) 2017-09-29 2024-03-07 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 A novel indene-based transition metal complexes, catalysts composition containing the same, and methods for preparing ethylene homopolymers or copolymers of ethylene and α-olefins using the same
KR20200105409A (en) 2019-02-28 2020-09-07 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 Novel tetraaryl borate compounds, catalysts composition containing the same, and methods for preparing ethylene homopolymers or copolymers of ethylene and α-olefins using the same
WO2020174346A1 (en) 2019-02-28 2020-09-03 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 NOVEL TETRAARYLBORATE COMPOUND, CATALYST COMPOSITION COMPRISING SAME, AND METHOD FOR PREPARING ETHYLENE HOMOPOLYMERS OR COPOLYMERS OF ETHYLENE AND α-OLEFIN BY USING SAME

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NZ235032A (en) * 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
PL166690B1 (en) * 1990-06-04 1995-06-30 Exxon Chemical Patents Inc Method of obtaining polymers of olefins
ES2153368T3 (en) * 1992-08-03 2001-03-01 Targor Gmbh PROCEDURE FOR OBTAINING AN OLEFINE POLYMER UNDER THE USE OF SPECIAL METALOCENES.
DE4406963A1 (en) * 1994-03-03 1995-09-07 Basf Ag Metallocene complexes with heterofunctional groups on the cyclopentadienyl system
DE4406964A1 (en) * 1994-03-03 1995-09-07 Basf Ag Supported metal oxide complexes with heterofunctional groups on the cyclopentadienyl system as catalyst systems

Also Published As

Publication number Publication date
ID18005A (en) 1998-02-19
NO990546D0 (en) 1999-02-05
HUP9904148A2 (en) 2000-03-28
WO1998006728A1 (en) 1998-02-19
PL331526A1 (en) 1999-07-19
HUP9904148A3 (en) 2003-03-28
CA2262377A1 (en) 1998-02-19
AR009034A1 (en) 2000-03-08
ZA976999B (en) 1999-02-08
SA97180735B1 (en) 2006-10-08
SK15299A3 (en) 2000-03-13
NO990546L (en) 1999-03-29
CN1231668A (en) 1999-10-13
CO4870709A1 (en) 1999-12-27
AU3964797A (en) 1998-03-06
EP1021454A1 (en) 2000-07-26
JP2000516608A (en) 2000-12-12
RU2196776C2 (en) 2003-01-20
CZ42499A3 (en) 1999-07-14
KR20000029853A (en) 2000-05-25
TR199900589T2 (en) 1999-07-21
BR9711115A (en) 1999-08-17
AU716659B2 (en) 2000-03-02
ZA976998B (en) 1999-02-08

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