ZA976999B - 2-Heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process - Google Patents

2-Heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process

Info

Publication number
ZA976999B
ZA976999B ZA976999A ZA976999A ZA976999B ZA 976999 B ZA976999 B ZA 976999B ZA 976999 A ZA976999 A ZA 976999A ZA 976999 A ZA976999 A ZA 976999A ZA 976999 B ZA976999 B ZA 976999B
Authority
ZA
South Africa
Prior art keywords
polymerization process
metal complexes
containing metal
olefin polymerization
substituted cyclopentadienyl
Prior art date
Application number
ZA976999A
Inventor
Jerzy Klosin
William J Kruper Jr
Peter N Nickias
Jasson T Patton
David R Wilson
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of ZA976999B publication Critical patent/ZA976999B/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/10—Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
ZA976999A 1996-08-08 1997-08-06 2-Heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process ZA976999B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US2376896P 1996-08-08 1996-08-08

Publications (1)

Publication Number Publication Date
ZA976999B true ZA976999B (en) 1999-02-08

Family

ID=21817090

Family Applications (2)

Application Number Title Priority Date Filing Date
ZA976999A ZA976999B (en) 1996-08-08 1997-08-06 2-Heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process
ZA976998A ZA976998B (en) 1996-08-08 1997-08-06 3-Heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process

Family Applications After (1)

Application Number Title Priority Date Filing Date
ZA976998A ZA976998B (en) 1996-08-08 1997-08-06 3-Heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process

Country Status (21)

Country Link
EP (1) EP1021454A1 (en)
JP (1) JP2000516608A (en)
KR (1) KR20000029853A (en)
CN (1) CN1231668A (en)
AR (1) AR009034A1 (en)
AU (1) AU716659B2 (en)
BR (1) BR9711115A (en)
CA (1) CA2262377A1 (en)
CO (1) CO4870709A1 (en)
CZ (1) CZ42499A3 (en)
HU (1) HUP9904148A3 (en)
ID (1) ID18005A (en)
NO (1) NO990546L (en)
NZ (1) NZ333877A (en)
PL (1) PL331526A1 (en)
RU (1) RU2196776C2 (en)
SA (1) SA97180735B1 (en)
SK (1) SK15299A3 (en)
TR (1) TR199900589T2 (en)
WO (1) WO1998006728A1 (en)
ZA (2) ZA976999B (en)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI971565A (en) * 1997-04-14 1998-10-15 Borealis As Substituted metallocene compounds for catalyst systems intended for polymerization of olefins, intermediates and processes for their preparation
DE19809159A1 (en) * 1998-03-04 1999-09-09 Bayer Ag Organometallic compounds
US6326493B1 (en) * 1999-01-25 2001-12-04 Chisso Corporation Metallocene compounds, processes for the preparation thereof, catalyst components for olefin polymerization, and processes for the production of olefin polymers
AU3902300A (en) 1999-04-29 2000-11-17 Dow Chemical Company, The Bis(n,n-dihydrocarbylamino)- substituted cyclopentadienes and metal complexes thereof
JP2002544282A (en) 1999-05-13 2002-12-24 ザ ダウ ケミカル カンパニー Di- and tri-heteroatom-substituted indenyl metal complexes
DE60001557T2 (en) 1999-05-13 2004-01-08 Dow Global Technologies, Inc., Midland METAL COMPLEXES WITH HETEROATOM-CONTAINING BRIDGE FOR OLEFIN POLYMERIZATION PROCESSES
US6420299B1 (en) 1999-06-04 2002-07-16 Dow Global Technologies Inc. Boron-substituted cyclopentadienes and metal complexes thereof
EP1253158A1 (en) * 1999-12-10 2002-10-30 Dow Global Technologies Inc. Substituted group 4 metal complexes, catalysts and olefin polymerization process
US6825295B2 (en) 1999-12-10 2004-11-30 Dow Global Technologies Inc. Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process
WO2001042315A1 (en) * 1999-12-10 2001-06-14 Dow Global Technologies Inc. Substituted group 4 metal complexes, catalysts and olefin polymerization process
CN100457787C (en) 2000-01-18 2009-02-04 巴塞尔技术有限公司 Process for producing substantially amorphous propylene-based polymers
EP1248806A1 (en) * 2000-01-19 2002-10-16 Borealis Technology Oy Metallocene catalysts comprising monocyclic siloxy substituted cyclopentadienyl group(s) for the polymerisation of olefins
GB0001232D0 (en) * 2000-01-19 2000-03-08 Borealis Polymers Oy Polymerisation catalysts
JP4062929B2 (en) 2002-02-08 2008-03-19 住友化学株式会社 Transition metal complex, ligand, catalyst for olefin polymerization, and method for producing olefin polymer
AU2003216476A1 (en) 2002-03-14 2003-09-29 Dow Global Technologies Inc. Substituted indenyl metal complexes and polymerization process
US6927264B2 (en) 2003-05-28 2005-08-09 Dow Global Technologies Inc. Metal complexes and polymerization process using same
RU2549541C2 (en) 2009-07-28 2015-04-27 Юнивейшн Текнолоджиз, Ллк Method of polymerisation with application of applied catalyst with constrained geometry
EP2617752B1 (en) * 2010-09-15 2018-07-25 Nippon Shokubai Co., Ltd. Composition usable as thermal-latent polymerization initiator
CN102101897B (en) * 2010-12-24 2013-02-06 上海化工研究院 Heterocyclic-side-chain-containing metallocene catalyst and application thereof in olefinic polymerization
WO2015142547A1 (en) 2014-03-21 2015-09-24 Exxonmobil Chemical Patents Inc. Process to produce ethylene propylene copolymers
EP3492532A1 (en) 2015-01-06 2019-06-05 Scg Chemicals Co. Ltd. Sio2-layered double hydroxide microspheres and methods of making them
KR102010630B1 (en) * 2016-01-20 2019-08-13 한화토탈 주식회사 Catalyst for olefin polymerization and olefin polymerization method thereof
GB201608384D0 (en) 2016-05-12 2016-06-29 Scg Chemicals Co Ltd Unsymmetrical metallocene catalysts and uses thereof
WO2018175073A1 (en) * 2017-03-23 2018-09-27 Exxonmobil Chemical Patents Inc. Catalyst systems and methods for preparing and using the same
KR102643986B1 (en) 2017-09-29 2024-03-07 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 A novel indene-based transition metal complexes, catalysts composition containing the same, and methods for preparing ethylene homopolymers or copolymers of ethylene and α-olefins using the same
KR102714698B1 (en) 2019-02-28 2024-10-10 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 Novel tetraaryl borate compounds, catalysts composition containing the same, and methods for preparing ethylene homopolymers or copolymers of ethylene and α-olefins using the same
WO2020174346A1 (en) 2019-02-28 2020-09-03 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 NOVEL TETRAARYLBORATE COMPOUND, CATALYST COMPOSITION COMPRISING SAME, AND METHOD FOR PREPARING ETHYLENE HOMOPOLYMERS OR COPOLYMERS OF ETHYLENE AND α-OLEFIN BY USING SAME
EP3865517A4 (en) 2019-09-27 2022-05-18 LG Chem, Ltd. Supported hybrid catalyst and method for preparing polyolefin by using same

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NZ235032A (en) * 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
PL166690B1 (en) * 1990-06-04 1995-06-30 Exxon Chemical Patents Inc Method of obtaining polymers of olefins
EP0582195B1 (en) * 1992-08-03 2000-12-20 TARGOR GmbH Process for the preparation of polymers using specific metallocenes
DE4406964A1 (en) * 1994-03-03 1995-09-07 Basf Ag Supported metal oxide complexes with heterofunctional groups on the cyclopentadienyl system as catalyst systems
DE4406963A1 (en) * 1994-03-03 1995-09-07 Basf Ag Metallocene complexes with heterofunctional groups on the cyclopentadienyl system

Also Published As

Publication number Publication date
KR20000029853A (en) 2000-05-25
NZ333877A (en) 2000-08-25
RU2196776C2 (en) 2003-01-20
JP2000516608A (en) 2000-12-12
TR199900589T2 (en) 1999-07-21
SA97180735B1 (en) 2006-10-08
CN1231668A (en) 1999-10-13
NO990546L (en) 1999-03-29
WO1998006728A1 (en) 1998-02-19
HUP9904148A3 (en) 2003-03-28
SK15299A3 (en) 2000-03-13
HUP9904148A2 (en) 2000-03-28
AR009034A1 (en) 2000-03-08
AU716659B2 (en) 2000-03-02
PL331526A1 (en) 1999-07-19
CZ42499A3 (en) 1999-07-14
ID18005A (en) 1998-02-19
CO4870709A1 (en) 1999-12-27
NO990546D0 (en) 1999-02-05
ZA976998B (en) 1999-02-08
AU3964797A (en) 1998-03-06
EP1021454A1 (en) 2000-07-26
CA2262377A1 (en) 1998-02-19
BR9711115A (en) 1999-08-17

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