AR009034A1 - METAL COMPLEXES CONTAINING CYCLOPENTADIENYL SUBSTITUTED BY HETEROATOMES IN POSITION 2, CATALYST SYSTEMS INCLUDING SUCH COMPLEXES; PROCESS TO POLYMERIZE OLEFINS BY APPLYING SUCH SYSTEMS; OLEFINS POLYMERIZATION PRODUCTS OBTAINED WITH SUCH PROCESS; THE - Google Patents

METAL COMPLEXES CONTAINING CYCLOPENTADIENYL SUBSTITUTED BY HETEROATOMES IN POSITION 2, CATALYST SYSTEMS INCLUDING SUCH COMPLEXES; PROCESS TO POLYMERIZE OLEFINS BY APPLYING SUCH SYSTEMS; OLEFINS POLYMERIZATION PRODUCTS OBTAINED WITH SUCH PROCESS; THE

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Publication number
AR009034A1
AR009034A1 ARP970103616A ARP970103616A AR009034A1 AR 009034 A1 AR009034 A1 AR 009034A1 AR P970103616 A ARP970103616 A AR P970103616A AR P970103616 A ARP970103616 A AR P970103616A AR 009034 A1 AR009034 A1 AR 009034A1
Authority
AR
Argentina
Prior art keywords
olefins
complexes
systems
heteroatomes
applying
Prior art date
Application number
ARP970103616A
Other languages
Spanish (es)
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of AR009034A1 publication Critical patent/AR009034A1/en

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/10—Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Abstract

Complejos de metales que tienen ciclopentadienilo que en la posicion 2 tienen heterátomo, de formula (I) donde Ra o Ro, T, M, Z, Xp, Xq tienen losvalores indicados en la descripcion. Dichos complejos son utiles como ligandos en la preparacion de sistemas catalíticos para la polimerizacion de olefinas, atemperaturas elevadas para producir polímeros de elevado peso molecular. También se proponen procesos de polimerizacion de olefinas con aplicacion delos sistemas mencionados y las poliolefinas resultantes y además los ligandos de ciclopentadienilo y el uso de los mismos en la preparacion de los complejosmencionados.Metal complexes having cyclopentadienyl which in position 2 have a hetero atom, of formula (I) where Ra or Ro, T, M, Z, Xp, Xq have the values indicated in the description. Such complexes are useful as ligands in the preparation of catalytic systems for the polymerization of olefins, at elevated temperatures to produce high molecular weight polymers. Olefin polymerization processes are also proposed with application of the mentioned systems and the resulting polyolefins and in addition the cyclopentadienyl ligands and the use thereof in the preparation of the mentioned complexes.

ARP970103616A 1996-08-08 1997-08-08 METAL COMPLEXES CONTAINING CYCLOPENTADIENYL SUBSTITUTED BY HETEROATOMES IN POSITION 2, CATALYST SYSTEMS INCLUDING SUCH COMPLEXES; PROCESS TO POLYMERIZE OLEFINS BY APPLYING SUCH SYSTEMS; OLEFINS POLYMERIZATION PRODUCTS OBTAINED WITH SUCH PROCESS; THE AR009034A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US2376896P 1996-08-08 1996-08-08

Publications (1)

Publication Number Publication Date
AR009034A1 true AR009034A1 (en) 2000-03-08

Family

ID=21817090

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP970103616A AR009034A1 (en) 1996-08-08 1997-08-08 METAL COMPLEXES CONTAINING CYCLOPENTADIENYL SUBSTITUTED BY HETEROATOMES IN POSITION 2, CATALYST SYSTEMS INCLUDING SUCH COMPLEXES; PROCESS TO POLYMERIZE OLEFINS BY APPLYING SUCH SYSTEMS; OLEFINS POLYMERIZATION PRODUCTS OBTAINED WITH SUCH PROCESS; THE

Country Status (21)

Country Link
EP (1) EP1021454A1 (en)
JP (1) JP2000516608A (en)
KR (1) KR20000029853A (en)
CN (1) CN1231668A (en)
AR (1) AR009034A1 (en)
AU (1) AU716659B2 (en)
BR (1) BR9711115A (en)
CA (1) CA2262377A1 (en)
CO (1) CO4870709A1 (en)
CZ (1) CZ42499A3 (en)
HU (1) HUP9904148A3 (en)
ID (1) ID18005A (en)
NO (1) NO990546L (en)
NZ (1) NZ333877A (en)
PL (1) PL331526A1 (en)
RU (1) RU2196776C2 (en)
SA (1) SA97180735B1 (en)
SK (1) SK15299A3 (en)
TR (1) TR199900589T2 (en)
WO (1) WO1998006728A1 (en)
ZA (2) ZA976999B (en)

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FI971565A (en) * 1997-04-14 1998-10-15 Borealis As Substituted metallocene compounds for catalyst systems intended for polymerization of olefins, intermediates and processes for their preparation
DE19809159A1 (en) * 1998-03-04 1999-09-09 Bayer Ag Organometallic compounds
US6326493B1 (en) * 1999-01-25 2001-12-04 Chisso Corporation Metallocene compounds, processes for the preparation thereof, catalyst components for olefin polymerization, and processes for the production of olefin polymers
EP1177198B1 (en) 1999-04-29 2002-11-20 Dow Global Technologies Inc. Bis(n,n-dihydrocarbylamino)- substituted cyclopentadienes and metal complexes thereof
DE60001557T2 (en) 1999-05-13 2004-01-08 Dow Global Technologies, Inc., Midland METAL COMPLEXES WITH HETEROATOM-CONTAINING BRIDGE FOR OLEFIN POLYMERIZATION PROCESSES
AU3764600A (en) 1999-05-13 2000-12-05 Dow Chemical Company, The Di- and tri-heteroatom substituted indenyl metal complexes
WO2000075146A1 (en) 1999-06-04 2000-12-14 The Dow Chemical Company Boron-substituted cyclopentadienes and metal complexes thereof
US6825295B2 (en) 1999-12-10 2004-11-30 Dow Global Technologies Inc. Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process
EP1253158A1 (en) * 1999-12-10 2002-10-30 Dow Global Technologies Inc. Substituted group 4 metal complexes, catalysts and olefin polymerization process
EP1242471B1 (en) * 1999-12-10 2012-02-29 Dow Global Technologies LLC Substituted group 4 metal complexes, catalysts and olefin polymerization process
JP2003520869A (en) 2000-01-18 2003-07-08 バセル テクノロジー カンパニー ビー．ブイ． Process for producing a substantially amorphous propylene-based polymer
GB0001232D0 (en) * 2000-01-19 2000-03-08 Borealis Polymers Oy Polymerisation catalysts
WO2001053362A1 (en) * 2000-01-19 2001-07-26 Borealis Technology Oy Metallocene catalysts comprising monocyclic siloxy substituted cyclopentadienyl group(s) for the polymerisation of olefins
JP4062929B2 (en) 2002-02-08 2008-03-19 住友化学株式会社 Transition metal complex, ligand, catalyst for olefin polymerization, and method for producing olefin polymer
CA2477776C (en) 2002-03-14 2011-11-15 Dow Global Technologies Inc. Substituted indenyl metal complexes and polymerization process
US6927264B2 (en) 2003-05-28 2005-08-09 Dow Global Technologies Inc. Metal complexes and polymerization process using same
KR101678247B1 (en) 2009-07-28 2016-11-21 유니베이션 테크놀로지즈, 엘엘씨 Polymerization process using a supported constrained geometry catalyst
WO2012036164A1 (en) * 2010-09-15 2012-03-22 株式会社日本触媒 Composition usable as heat-latent polymerization initiator
CN102101897B (en) * 2010-12-24 2013-02-06 上海化工研究院 Heterocyclic-side-chain-containing metallocene catalyst and application thereof in olefinic polymerization
KR101791810B1 (en) 2014-03-21 2017-10-30 엑손모빌 케미칼 패턴츠 인코포레이티드 Process to produce ethylene propylene copolymers
CN107107025A (en) 2015-01-06 2017-08-29 Scg化学有限公司 SiO2Layered double-hydroxide microballoon and their preparation method
KR102010630B1 (en) * 2016-01-20 2019-08-13 한화토탈 주식회사 Catalyst for olefin polymerization and olefin polymerization method thereof
GB201608384D0 (en) 2016-05-12 2016-06-29 Scg Chemicals Co Ltd Unsymmetrical metallocene catalysts and uses thereof
WO2018175073A1 (en) * 2017-03-23 2018-09-27 Exxonmobil Chemical Patents Inc. Catalyst systems and methods for preparing and using the same
KR102643986B1 (en) 2017-09-29 2024-03-07 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 A novel indene-based transition metal complexes, catalysts composition containing the same, and methods for preparing ethylene homopolymers or copolymers of ethylene and α-olefins using the same
KR20200105409A (en) 2019-02-28 2020-09-07 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 Novel tetraaryl borate compounds, catalysts composition containing the same, and methods for preparing ethylene homopolymers or copolymers of ethylene and α-olefins using the same
WO2020174346A1 (en) 2019-02-28 2020-09-03 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 NOVEL TETRAARYLBORATE COMPOUND, CATALYST COMPOSITION COMPRISING SAME, AND METHOD FOR PREPARING ETHYLENE HOMOPOLYMERS OR COPOLYMERS OF ETHYLENE AND α-OLEFIN BY USING SAME

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Also Published As

Publication number Publication date
ID18005A (en) 1998-02-19
NO990546D0 (en) 1999-02-05
HUP9904148A2 (en) 2000-03-28
WO1998006728A1 (en) 1998-02-19
PL331526A1 (en) 1999-07-19
HUP9904148A3 (en) 2003-03-28
CA2262377A1 (en) 1998-02-19
ZA976999B (en) 1999-02-08
SA97180735B1 (en) 2006-10-08
SK15299A3 (en) 2000-03-13
NO990546L (en) 1999-03-29
CN1231668A (en) 1999-10-13
CO4870709A1 (en) 1999-12-27
AU3964797A (en) 1998-03-06
EP1021454A1 (en) 2000-07-26
JP2000516608A (en) 2000-12-12
RU2196776C2 (en) 2003-01-20
CZ42499A3 (en) 1999-07-14
KR20000029853A (en) 2000-05-25
TR199900589T2 (en) 1999-07-21
BR9711115A (en) 1999-08-17
NZ333877A (en) 2000-08-25
AU716659B2 (en) 2000-03-02
ZA976998B (en) 1999-02-08

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