TR199900589T2 - Process for polymerization of metal complexes and olefins containing 2 heteroatom substituted cyclopentadienyl. - Google Patents

Process for polymerization of metal complexes and olefins containing 2 heteroatom substituted cyclopentadienyl.

Info

Publication number
TR199900589T2
TR199900589T2 TR1999/00589T TR9900589T TR199900589T2 TR 199900589 T2 TR199900589 T2 TR 199900589T2 TR 1999/00589 T TR1999/00589 T TR 1999/00589T TR 9900589 T TR9900589 T TR 9900589T TR 199900589 T2 TR199900589 T2 TR 199900589T2
Authority
TR
Turkey
Prior art keywords
metal complexes
heteroatom
heteroatom substituted
substituted cyclopentadienyl
polymerization
Prior art date
Application number
TR1999/00589T
Other languages
Turkish (tr)
Inventor
Klosin Jerzy
William J. Kruper, Jr.
N. Nickias Peter
T.Patton Jasson
R. Wilson David
Original Assignee
The Dow Chemical Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Dow Chemical Company filed Critical The Dow Chemical Company
Publication of TR199900589T2 publication Critical patent/TR199900589T2/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/10—Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Abstract

Bulus heteroatom ikameli siklopentadienil içeren ligandlarla, bu ligandlari içeren metal kompleksleriyle ve bu metal komplekslerini içeren katalizör bilesenlerinden elde edilen katalizör sistemleriyle ilgilidir. Bu metal kompleksleri Cp'nin 2 konumunda bir heteroatom-Cp bagina ya da bir halka heteroatomu-Cp bagina sahiptir. Tercih edilen metal komplekslerinde ligand bir 2-heteroatom ikameli indenil grubudur. Olefin polimerizasyonu için bu katalizör sistemleri yüksek sicakliklarda kullanilabilmektedir, yüksek ölçüde aktiftir ve molekül agirligi yüksek polimerler vermektedir.The invention relates to ligands containing heteroatom substituted cyclopentadienyl, metal complexes containing these ligands, and catalyst systems obtained from catalyst components containing these metal complexes. These metal complexes have a heteroatom-Cp bond at the 2 position of Cp or a ring heteroatom-Cp bond. In preferred metal complexes, the ligand is a 2-heteroatom substituted indenyl group. These catalyst systems for olefin polymerization can be used at high temperatures, are highly active and give high molecular weight polymers.

TR1999/00589T 1996-08-08 1997-07-28 Process for polymerization of metal complexes and olefins containing 2 heteroatom substituted cyclopentadienyl. TR199900589T2 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US2376896P 1996-08-08 1996-08-08

Publications (1)

Publication Number Publication Date
TR199900589T2 true TR199900589T2 (en) 1999-07-21

Family

ID=21817090

Family Applications (1)

Application Number Title Priority Date Filing Date
TR1999/00589T TR199900589T2 (en) 1996-08-08 1997-07-28 Process for polymerization of metal complexes and olefins containing 2 heteroatom substituted cyclopentadienyl.

Country Status (21)

Country Link
EP (1) EP1021454A1 (en)
JP (1) JP2000516608A (en)
KR (1) KR20000029853A (en)
CN (1) CN1231668A (en)
AR (1) AR009034A1 (en)
AU (1) AU716659B2 (en)
BR (1) BR9711115A (en)
CA (1) CA2262377A1 (en)
CO (1) CO4870709A1 (en)
CZ (1) CZ42499A3 (en)
HU (1) HUP9904148A3 (en)
ID (1) ID18005A (en)
NO (1) NO990546L (en)
NZ (1) NZ333877A (en)
PL (1) PL331526A1 (en)
RU (1) RU2196776C2 (en)
SA (1) SA97180735B1 (en)
SK (1) SK15299A3 (en)
TR (1) TR199900589T2 (en)
WO (1) WO1998006728A1 (en)
ZA (2) ZA976999B (en)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI971565A (en) * 1997-04-14 1998-10-15 Borealis As Substituted metallocene compounds for catalyst systems intended for polymerization of olefins, intermediates and processes for their preparation
DE19809159A1 (en) 1998-03-04 1999-09-09 Bayer Ag Organometallic compounds
US6326493B1 (en) * 1999-01-25 2001-12-04 Chisso Corporation Metallocene compounds, processes for the preparation thereof, catalyst components for olefin polymerization, and processes for the production of olefin polymers
AU3902300A (en) 1999-04-29 2000-11-17 Dow Chemical Company, The Bis(n,n-dihydrocarbylamino)- substituted cyclopentadienes and metal complexes thereof
US6555634B1 (en) 1999-05-13 2003-04-29 The Dow Chemical Company Di- and tri-heteroatom substituted indenyl metal complexes
WO2000069870A1 (en) 1999-05-13 2000-11-23 The Dow Chemical Company Metal complexes containing bridging heteroatom for olefin-polymerization-process
DE60020968T2 (en) 1999-06-04 2006-05-11 Dow Global Technologies, Inc., Midland BORSUBSTITUTED CYCLOPENTADIENES AND METAL COMPLEXES OF THESE LIGANDS
US6825295B2 (en) 1999-12-10 2004-11-30 Dow Global Technologies Inc. Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process
EP1242471B1 (en) * 1999-12-10 2012-02-29 Dow Global Technologies LLC Substituted group 4 metal complexes, catalysts and olefin polymerization process
EP1253158A1 (en) * 1999-12-10 2002-10-30 Dow Global Technologies Inc. Substituted group 4 metal complexes, catalysts and olefin polymerization process
DE60138657D1 (en) 2000-01-18 2009-06-18 Basell Polyolefine Gmbh Ligand for a metallocene catalyst for the polymerization of propylene and its production process
GB0001232D0 (en) * 2000-01-19 2000-03-08 Borealis Polymers Oy Polymerisation catalysts
AU2001226937A1 (en) * 2000-01-19 2001-07-31 Borealis Technology Oy Metallocene catalysts comprising monocyclic siloxy substituted cyclopentadienyl group(s) for the polymerisation of olefins
JP4062929B2 (en) 2002-02-08 2008-03-19 住友化学株式会社 Transition metal complex, ligand, catalyst for olefin polymerization, and method for producing olefin polymer
KR101002620B1 (en) 2002-03-14 2010-12-21 다우 글로벌 테크놀로지스 인크. Substituted indenyl metal complexes and polymerization process
US6927264B2 (en) 2003-05-28 2005-08-09 Dow Global Technologies Inc. Metal complexes and polymerization process using same
US8957167B2 (en) 2009-07-28 2015-02-17 Univation Technologies, Llc Polymerization process using a supported constrained geometry catalyst
CN103249755A (en) * 2010-09-15 2013-08-14 株式会社日本触媒 Composition usable as heat-atent polymerization initiator
CN102101897B (en) * 2010-12-24 2013-02-06 上海化工研究院 Heterocyclic-side-chain-containing metallocene catalyst and application thereof in olefinic polymerization
KR101791810B1 (en) 2014-03-21 2017-10-30 엑손모빌 케미칼 패턴츠 인코포레이티드 Process to produce ethylene propylene copolymers
PL3245258T3 (en) 2015-01-06 2020-01-31 Scg Chemicals Co., Ltd. Sio2-layered double hydroxide microspheres and methods of making them
KR102010630B1 (en) * 2016-01-20 2019-08-13 한화토탈 주식회사 Catalyst for olefin polymerization and olefin polymerization method thereof
GB201608384D0 (en) 2016-05-12 2016-06-29 Scg Chemicals Co Ltd Unsymmetrical metallocene catalysts and uses thereof
CN110612313A (en) * 2017-03-23 2019-12-24 埃克森美孚化学专利公司 Catalyst system and methods of making and using the same
KR102643986B1 (en) 2017-09-29 2024-03-07 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 A novel indene-based transition metal complexes, catalysts composition containing the same, and methods for preparing ethylene homopolymers or copolymers of ethylene and α-olefins using the same
WO2020174346A1 (en) 2019-02-28 2020-09-03 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 NOVEL TETRAARYLBORATE COMPOUND, CATALYST COMPOSITION COMPRISING SAME, AND METHOD FOR PREPARING ETHYLENE HOMOPOLYMERS OR COPOLYMERS OF ETHYLENE AND α-OLEFIN BY USING SAME
KR20200105409A (en) 2019-02-28 2020-09-07 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 Novel tetraaryl borate compounds, catalysts composition containing the same, and methods for preparing ethylene homopolymers or copolymers of ethylene and α-olefins using the same

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Also Published As

Publication number Publication date
NO990546L (en) 1999-03-29
CA2262377A1 (en) 1998-02-19
RU2196776C2 (en) 2003-01-20
ZA976999B (en) 1999-02-08
KR20000029853A (en) 2000-05-25
SA97180735B1 (en) 2006-10-08
HUP9904148A3 (en) 2003-03-28
BR9711115A (en) 1999-08-17
JP2000516608A (en) 2000-12-12
NZ333877A (en) 2000-08-25
ZA976998B (en) 1999-02-08
AU3964797A (en) 1998-03-06
HUP9904148A2 (en) 2000-03-28
NO990546D0 (en) 1999-02-05
ID18005A (en) 1998-02-19
CZ42499A3 (en) 1999-07-14
SK15299A3 (en) 2000-03-13
CO4870709A1 (en) 1999-12-27
AR009034A1 (en) 2000-03-08
WO1998006728A1 (en) 1998-02-19
CN1231668A (en) 1999-10-13
AU716659B2 (en) 2000-03-02
EP1021454A1 (en) 2000-07-26
PL331526A1 (en) 1999-07-19

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