JPS5628206A - Polymerization of ethylene - Google Patents
Polymerization of ethyleneInfo
- Publication number
- JPS5628206A JPS5628206A JP10355679A JP10355679A JPS5628206A JP S5628206 A JPS5628206 A JP S5628206A JP 10355679 A JP10355679 A JP 10355679A JP 10355679 A JP10355679 A JP 10355679A JP S5628206 A JPS5628206 A JP S5628206A
- Authority
- JP
- Japan
- Prior art keywords
- compound
- organic
- mixture
- polymerization catalyst
- reaction product
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
PURPOSE: To prepare the titled polymer having narrow molecular weight distribu- tion and high moldability, by the use of a polymerization catalyst obtained by contacting a reaction product of a specific solvent-soluble organic magnesium compound and a silicon compound, etc. with a mixture of a titanium compound and a vanadium compound, and then compounding the contact product with an organic aliminum compound.
CONSTITUTION: Ethylene is polymerized at 120W350°C in the presence of a polymerization catalyst composed of (A) a component obtained by (1) reacting (a) an organic Mg compound soluble in hydrocarbon solvents and expressed by the formula (M is IWIII group metal atom; β is ≥1; α, p, q, r and s are ≥0, provided that p+q+r+s=mα+2β, and 0≤(r+s)/(α+β)≤1; m is valence of M; R1, R2 are 1W20C hydrocarbon; X1, X2 are H, alkoxide, etc.) with (b) one or more halides of B, Si, Ge, Sn, Pb, P, As, Sb, Bi, and Hg, and (2) mixing the reaction product with a mixture of a Ti compound and a V compound wherein the molar ratio of Ti/V is 100/1W1/100, and (B) an organic Al compound.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10355679A JPS6011044B2 (en) | 1979-08-16 | 1979-08-16 | How to polymerize ethylene |
US06/170,385 US4330646A (en) | 1979-08-13 | 1980-07-21 | Polymerization of an α-olefin |
GB8023928A GB2056998B (en) | 1979-08-13 | 1980-07-22 | Process and catalyst for polymerisation of an -olefin |
DE3028479A DE3028479C2 (en) | 1979-08-13 | 1980-07-26 | Process for the polymerization of ethylene and for its copolymerization with an α-olefin having 3 to 20 carbon atoms or with butadiene or isoprene in the liquid phase and a titanium-containing or titanium and vanadium-containing catalyst component for carrying out this process |
CA000357696A CA1138405A (en) | 1979-08-13 | 1980-08-06 | POLYMERIZATION OF AN .alpha.-OLEFIN |
NLAANVRAGE8004492,A NL186320C (en) | 1979-08-13 | 1980-08-06 | Catalysts for the polymerization of 1-olefins and polymerization of 1-olefins. |
BR8004964A BR8004964A (en) | 1979-08-13 | 1980-08-07 | PROCESS FOR THE POLYMERIZATION OF AN ALPHA-OLEFINE AND ULTILE CATALYST FOR THE POLYMERIZATION OF DITA-OLEFINE |
IT24097/80A IT1132545B (en) | 1979-08-13 | 1980-08-08 | PROCEDURE FOR POLYMERIZING AN ALPHA-OLEPHINE, AND CATALYST USED IN IT |
FR8017771A FR2463155A1 (en) | 1979-08-13 | 1980-08-12 | PROCESS FOR POLYMERIZATION OF A-OLEFIN AND CATALYST FOR CARRYING OUT SAID METHOD |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10355679A JPS6011044B2 (en) | 1979-08-16 | 1979-08-16 | How to polymerize ethylene |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5628206A true JPS5628206A (en) | 1981-03-19 |
JPS6011044B2 JPS6011044B2 (en) | 1985-03-22 |
Family
ID=14357086
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP10355679A Expired JPS6011044B2 (en) | 1979-08-13 | 1979-08-16 | How to polymerize ethylene |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6011044B2 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61287909A (en) * | 1985-06-06 | 1986-12-18 | ザ ダウ ケミカル カンパニ− | Novel catalyst and method for producing olefin polymer having relatively narrow molecular weight distribution |
KR100334164B1 (en) * | 1998-04-17 | 2002-09-25 | 삼성종합화학주식회사 | A PRODUCTION METHOD OF A SUPPORTED T i / V CATALYST FOR ETHYLENE POLYMERIZATION AND ETHYLENE/ α-OLEFIN COPOLYMERIZATION |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10888747B2 (en) | 2008-07-15 | 2021-01-12 | Taylor Made Golf Company, Inc. | Aerodynamic golf club head |
US8858359B2 (en) | 2008-07-15 | 2014-10-14 | Taylor Made Golf Company, Inc. | High volume aerodynamic golf club head |
US20100016095A1 (en) | 2008-07-15 | 2010-01-21 | Michael Scott Burnett | Golf club head having trip step feature |
-
1979
- 1979-08-16 JP JP10355679A patent/JPS6011044B2/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61287909A (en) * | 1985-06-06 | 1986-12-18 | ザ ダウ ケミカル カンパニ− | Novel catalyst and method for producing olefin polymer having relatively narrow molecular weight distribution |
KR100334164B1 (en) * | 1998-04-17 | 2002-09-25 | 삼성종합화학주식회사 | A PRODUCTION METHOD OF A SUPPORTED T i / V CATALYST FOR ETHYLENE POLYMERIZATION AND ETHYLENE/ α-OLEFIN COPOLYMERIZATION |
Also Published As
Publication number | Publication date |
---|---|
JPS6011044B2 (en) | 1985-03-22 |
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